GNRO-2005/00011, 2004 Annual Radiological Environmental Operating Report for 2004

From kanterella
Jump to navigation Jump to search
2004 Annual Radiological Environmental Operating Report for 2004
ML051180323
Person / Time
Site: Grand Gulf Entergy icon.png
Issue date: 04/27/2005
From: Bottemiller C
Entergy Operations
To:
Document Control Desk, Office of Nuclear Reactor Regulation
References
GNRO-2005/00011
Download: ML051180323 (63)


Text

GNRO-2005/00011 April 27, 2005 US. Nuclear Regulatory Commission Washington, D.C. 20555 Attention:

Document Control Desk

Subject:

Grand Gulf Nuclear Station (GGNS) 2004 Annual Radiological Environmental Operating Report (AREOR)

Grand Gulf Nuclear Station Docket No. 50-416 License No. NPF-29 Ladies & Gentlemen:

In accordance with the Grand Gulf Nuclear Station Unit 1 Technical Specification 5.6.2, attached is the Annual Radiolouical Environmental Operatinq Report for the period January 1,2004 through December 31,2004.

is lett sn in

. If you have questions or require additional information concerning these reports, please contact Mr. Bruce D. Bryant at (601) 437-6316, or this office at (601) 437-6685.

Yours truly, CAB/M J L attachment:

cc:

(See Next Page) 2004 Annual Radiological Environmental Operating Report

April 27, 2005 Page 2 of 2 GNRO-2005/00011 CC:

cc:

NRC Senior Resident Inspector Grand Gulf Nuclear Station Port Gibson, MS 39150 U. S. Nuclear Regulatory Commission ATTN: Dr. Bruce S. Mallet (w/2)

Regional Administrator, Region IV 61 1 Ryan Plaza Drive, Suite 400 Arlington, TX 7601 1-4005 U. S. Nuclear Regulatory Commission ATTN: Mr. Bhalchandra Vaidya, NRR/DLPM (w/2)

ATTN: ADDRESSEE ONLY ATTN: U. S. Postal Delivery Address Only Mail Stop OWFN/7D-1 Washington, DC 20555-0001 Mr. D. E. Levanway (Wise Carter)

Mr. L. J. Smith (Wise Carter)

Mr. N. S. Reynolds Mr. H. L. Thomas

ENTERGY OPERATIONS, INC.

GRAND GULF NUCLEAR STATION I

Prepared By ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT January 1,2004-December 31,2004 Reviewed By Approved By I

TABLE OF CONTENTS

SUMMARY

6

1.0 INTRODUCTION

I.I Radiological Environmental Monitoring Program 1.2 Pathways Monitored 1.3 Land Use Census 2.0 INTERPRETATION AND TRENDS OF RESULTS 2.1 Air Paaticuiate and Radioiodine Sample Results 2.2 Theraoluminescent Dosimetry (TLD) Sample Results 2.3 Water Sample Results 2.4 Sediment Sample Results 2.5 Milk Sample Results 2.6 Fish Sample Results 2.7 Food Product Sample Results 2.8 Land Use Census Results 2.9 Interlaboratory Comparison Results 3.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

3.1 Program Results Summary 11 11 11 12 23 23 23 25 25 26 26 26 27 28 29 29 2

TABLE 1.1 TABLE 3.1 LIST OF TABLES RADIOLOGICAL ENVIRONMENTAL SAMPLING PROGRAM 13 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

30 3

FIGURE 1-1 FIGURE 1-2 FIGURE 1-3 FIGURE 2-1 LIST OF FIGURES EXPOSURE PATHWAYS SAMPLE COLLECTION SITES - NEAR FIELD SAMPLE COLLECTION SITES - FAR FIELD TLD READINGS 20 21 22 24 4

LIST OF ATTACHMENTS ATTACHMENT I RADIOLOGICAL MONITORING REPORT

SUMMARY

OF MONITORING RESULTS 35 5

Summary The Annual Radiological Environmental Operating Report presents data obtained through analyses of environmental samples collected for Grand Gulf Nuclear Stations (GGNS)

Radiological Environmental Monitoring Program (REMP) for the period January 1, 2004 through December 31, 2004. This report fulfills the requirements of GGNS Technical Specification 5.6.2.

To supplement the REMP, GGNS personnel collected duplicate surface water, ground water, vegetation, sediment and fish samples during the reporting period. Special samples collected during the reporting period included vegetation and venison. GGNS did not detect any plant-related radionuclides in these samples.

Radiological Environmental Jlonitoring Program GGNS established the REMP in 1978 prior to the station becoming operational (1985) to provide data on background radiation and radioactivity normally present in the area. GGNS has continued to monitor the environment by sampling air, water, sediment, fish and food products, as well as measuring radiation directly. GGNS also samples milk if commercial milk production is occurring within five miles of the plant.

The REMP includes sampling indicator and control locations within an 18-mile radius of the plant. The REMP utilizes indicator locations near the site to show any increases or buildup of radioactivity that might occur due to station operation, and control locations farther away fi-om the site to indicate the presence of only naturally occurring radioactivity. GGNS personnel compare indicator results with control and preoperational results to assess any impact GGNS operation might have had on the surrounding environment.

In the current year, GGNS personnel collected environmental samples for radiological analysis. They compared results of indicator locations with control locations and previous studies, and concluded that overall no significant relationship exists between GGNS operation and effect on the plant environs. Their review of current year data, in many cases, showed undetectable radiation levels in the environment and near background level in significant pathways associated with GGNS.

6

Harmful Effects or Irreversible Damage The REMP monitoring did not detect any harmfil effects or evidence of irreversible damage in the current year. Therefore, no analysis or planned course of action to alleviate problems was necessary.

GGNS' review indicates that no samples equaled or exceeded reporting levels for radioactivity concentration in environmental samples, as outlined in ODCM Specifications Table 6.12.1-2 when averaged over any calendar quarter, due to GGNS effluents. Therefore, results did not trigger any Radiological Monitoring Program Special Reports.

Radioactivity Not Attributable to GGNS In previous years, the GGNS REMP detected radioactivity attributable to other sources twice.

These include the 25th Chinese nuclear test explosion in 1980, and the radioactivity plume release due to reactor core degradation at the Chernobyl Nuclear Power Plant in 1986.

Comparison to Federal and State Programs GGNS personnel compared REMP data to federal and state monitoring programs as results became available. Historically, the programs used for comparison have included the U.S.

Nuclear Regulatory Commission (NRC) TLD Direct Radiation Monitoring Network and the Mississippi State Department of Health (MSDH), Division of Radiological Health.

The NRC TLD Network Program was discontinued in 1998. Historically these results have compared favorably to those from the GGNS REMP. GGNS TLD results remain similar to the historical average and continue to verify that plant operation is not affecting the ambient radiation levels in the environment.

The MSDH and the GGNS REMP entail similar radiological environmental monitoring program requirements. These programs include concurrent air sampling and splitting or sharing sample media such as water, sediment, fish and food products. Both programs have obtained similar results over previous years. The results of MSDH's monitoring program for the reporting period compared favorably with the GGNS REMP and did not indicate elevated levels of radiation or radioactivity build-up attributed to plant operations.

7

Sample Deviations

+ Milk The REMP did not include milk sampling within five miles (8 km) of GGNS in the current year due to unavailability. ODCM Specifications require collection of milk samples if available commercially within 8 km (5 miles) of the plant. GGNS personnel collected vegetation samples to monitor the ingestion pathway, as specified in ODCM Specifications Table 6.12.1 - 1, because of milk unavailability.

+ Required Lower Limit of Detection (LLD) Values LLDs during this reporting period were within the acceptable limits required by the ODCM specifications.

8

+ Air Samples The following air sample locations had reduced run times due to weather-related outages or mechanical problems. As described in footnote (a) to ODCM Specification Table 6.12.1-1, deviations from the required sampling schedule are permitted due to malfunction of sampling equipment and other legitimate reasons.

Sample Date In Date Out RunTime out-of-Service Comments Location hours hours AS-1 PG 1 1 /23/04 1 1 /30/04 166.69 1.46 Power Outage AS-7 UH 11/23/04 1 1 /30/04 166.67 1.46 Power Outage AS-1 PG 1011 9/04 1 0126104 132.73 36.94 Sample pump failure AS-7 UH 09/07/04 09/14/04 172.94 0.43 Power Outage AS-7 UH 08/03/04 08/10/04 168.47 0.63 Power Outage AS-1 PG 07/13/04 07/20/04 166.62 1.03 Power Outage AS-1 PG 06/29/04 07/06/04 158.74 10.59 Power Outage AS-7 UH 05/25/04 06/01 104 171.23 0.60 Power Outage AS-3 61 VA 04/20/04 04/27/04 167.99 0.24 Power Outage AS-7 UH 04/20/04 04/27/04 169.10 2.17 Power Outage AS-I PG 03/30/04 04/06/04 166.06 1.10 Power Outage.

Based on the sample collection period reductions, air samples were collected the following percentages of the available time:

AS-1 PG 99.4%

AS-3 61VA 99.9%

AS-7 UH 99.9%

+ TLDs TLD station M-48 (Outer Ring, Sector K, 4.8 miles) was displaced from its designated location by unknown causes during the 1 quarter of 2004 This data was excluded from reporting. Although the 1 quarter exposure at location M-48 is unknown, GGNS' review of results for similarly located TLDs indicated no abnonnal readings.

9

+ Missed Samples There were no missed samples in the reporting period.

+ Unavailable Results GGNS received analytical results in adequate time for inclusion in this report.

addition, GGNS review identified no missing results.

In Program Modifications No program modifications occurred during the reporting period.

Attachments contains results of TLD, air, water, sediment, fish, food products and special samples collected. TLDs were analyzed by Waterford-3 Dosimetry. All remaining samples were analyzed by River Bend Stations (RBS) Environmental. Attachment 1 also contains RBS results from participation in the interlaboratory coinparison program.

10

1.0 Introduction 1.1 Radiological E ~ ~ i r o n ~ e ~ t ~ ~

Monitoring Program GGNS established the REMP to ensure that plant operating controls properly function to minimize any associated radiation endangerment to human health or the environment. The REMP is designed for:

Analyzing important pathways for anticipated types and quantities of radionuclides released into the environment.

Considering the possibility of a buildup of long-lived radionuclides in the environment and identiQing physical and biological accumulations that may contribute to human exposures.

Considering the potential radiation exposure to plant and animal life in the environment surrounding GGNS.

0 Correlating levels of radiation and radioactivity in the environment with radioactive releases fi-om station operation.

1.2 Pathways Monitored The airborne, direct radiation, waterborne and ingestion pathways, as seen in Figure 1 - 1, are monitored as required by GGNS ODCM Table 6.12.1 - 1. A description of the GGNS REMP utilized to monitor the exposure pathways is provided in Table 1.1 and shown in Figures 1-2 and 1-3. GGNS may supplement this program with additional sampling in order to provide a comprehensive and well-balanced program.

Section 2.0 of this report provides a discussion of sampling results with Section 3.0 providing a summary of results for the monitored exposure pathways.

11

1.3 Land Use Census GGNS personnel conduct a land use census biannually, as required by ODCM Specification 6.12.2. The purpose of this census is to identify changes in uses of land within five miles of GGNS that would require modifications to the REMP or the ODCM. The most recent land use census was conducted in 2003. Details of the 2003 Land Use Census were included in the 2003 AREOR. The next Land Use Census will be conducted in 2005.

12

Exposure Pathway Airborne Direct Radiation Table 1.1 Radiological Environmental Sampling Program Requirement Radioiodine and Particulates 1

sample close to the SITE BOUNDARY having the highest calculated annual average groundlevel DIQ.

Radioiodine and Particulates 1 sample from the vicinity of a community having the highest calculated annual average groundlevel D/Q.

Radioiodine and Particulates 1 sample from a control location 15 -

30 km (10 - 20 miles) distance.

TLDs An inner ring of stations in the general areas of the SITE BOUNDARY.

Sample Point Description, Distance and Direction AS-7 UH (Sector H, Radius 0.5 Miles) -

South-southeast of GGNS at the IBEW Union Hall.

AS-1 PG (Sector G, Radius 5.5 Miles) -

Southeast of GGNS at the Port Gibson City Barn.

AS-3 61VA (Sector B, Radius 18 Miles) -

North-northeast of GGNS on Hwy 61, North of the Vicksburg Airport.

M-16 (Sector A, Radius 0.9 Miles) -

Meteorological Tower.

M-17 (Sector C, Radius 0.5 Miles) -

South Side, Grand Gulf Road.

M-I9 (Sector E, Radius 0.5 Miles) -

Eastern SITE BOUNDARY Property line, North-northeast of HWSA.

Sampling and Collection Frequency Continuous sampler operation with sample collection per 7 days or as required by dust loading, whichever is more frequent 92 days Type and Frequency Of Analyses Radioiodine Cannister 1 31 ;

7 days Particulate Sampler - Gross beta radioactivity following filter change, composite (by location) for gamma isotopic; 92 days Gamma dose; 92 days 13

Exposure Pathway Direct Radiation Table 1.1 Radiological Environmental Sampling Program Requirement TLDs An inner ring of stations in the general areas of the SITE BOUNDARY.

An outer ring approximately 3 to 5 miles from the site.

Sample Paint Description, Distance and Direction M-21 (Sector J, Radius 0.4 Miles) - Near Former Training Center Building on Bald Hill Road.

M-22 (Sector G, Radius 0.5 Miles) -

Former RR Entrance Crossing On Bald Hill Road.

M-23 (Sector Q, Radius 0.5 Miles) - Gin Lake Road 50 Yards North of Heavy Haul Road on Power Pole.

M-25 (Sector N, Radius 1.6 Miles) -

Radial Well Number 1.

M-28 (Sector L, Radius 0.9 Miles) -

Former Glodjo Residence.

M-94 (Sector R, Radius 0.8 Miles) -

Sector R Near Meteorological Tower.

M-36 (Sector P, Radius 5.0 Miles) -

Curve on HW 608, Point Nearest GGNS at Power Pole.

M-40 (Sector M, Radius 2.3 Miles) -

Headly Drive, Near River Port Entrance.

Sampling and Collection Frequency 92 days Type and Frequency Of Analyses Gamma dose; 92 days 14

xposure Pathway Direct Radiation Table 1.1 Radiological Environmental Sampling Program Requirement TLPs An outer ring approximately 3 to 5 miles from the site.

TLDs 8 stations in special interest areas such as population centers, nearby residences, schools, and in 1 or 2 areas to serve as control stations.

Sample Point Description, Distance and Direction M-48 (Sector K, Radius 4.8 Miles) - 0.4 Miles South on Mont Gomer Road on West Side.

M-49 (Sector H, Radius 4.5 Miles) - Fork in Bessie Weathers Road/Shaifer Road.

M-50 (Sector B, Radius 5.3 Miles) - Paiiola Hunting Club Entrance.

M-55 (Sector D, Radius 5.0 Miles) - Near lngelside Karnac Ferry RoadlAshland Road Intersection.

M-57 (Sector F, Radius 4.5 Miles) - Hwy 61, Behind the Welcome to Port Gibson Sign at Glensdale Subdivision.

M-01 (Sector E, Radius 3.5 Miles) - Across the road from Lake Claiborne Entry Gate.

(Special Interest)

M-07 (Sector G, Radius 5.5 Miles) - AS-1 PG, Port Gibson City Barn. (Special Interest)

M-09 (Sector D, Radius 3.5 Miles) - Warner Tully Y-Camp. (Special Interest)

M-10 (Sector A, Radius 1.5 Miles) - Grand Gulf Military Park. (Special Interest)

Sampling and Collection Frequency 92 days Type and Frequency Of Analyses Gamma dose; 92 days 15

Exposure Pathway Direct Radiation Table 1.1 Radiological Environmental Sampling Program Requirement TLDs 8 stations in special interest areas such as population centers, nearby residences, schools, and in 1 or 2 areas to serve as control stations Sample Point Description, Distance and Direction M-I4 (Sector B, Radius 18.0 Miles) - AS 61VA, Hwy 61, North of Vicksburg Airport.

(Control)

M-33 (Sector P, Radius 12.5 Miles) -

Newellton, Louisiana Water Tower. (Special Interest)

M-38 (Sector M, Radius 9.5 Miles) - Lake Bruin State Park, Entrance Road. (Special Interest)

M-39 (Sector M, Radius 13.0 Miles) - St.

Joseph, Louisiana, Auxiliary Water Tank.

(Special Interest)

Sampling and Collection Frequency 92 days Type and Frequency Of Analyses Gamma dose; 92 days 16

Exposure Pathway Sampling and Collection Frequency Waterborne Type and Frequency Of Analyses Table 1.1 Radiological Environmental Sampling Program Requirement Surface Water 1 sample upstream.

1 sample downstream.

1 sample downstream during a Liquid Radwaste Discharge.

Sample Point Description, Distance and Direction MRUP (Sector R, Radius 1.8 Miles) - At least 4500 ft upstream of the GGNS discharge point into the Mississippi River to allow adequate mixing of the Mississippi and Big Black Rivers.

MRDOWN (Sector N, Radius 1.6 Miles) - At least 5000 ft downstream of the GGNS discharge point into the Mississippi River near Radial Well No. 1.

MRDOWN (Sector P,

Radius 1.3 Miles) -

Downstream of the GGNS discharge point into the Mississippi River near Radial Well No. 5.

92 days 366 days Gamma isotopic and tritium analyses; 92 days Gamma isotopic and tritium analyses; 366 days 17

Exposure Pathway Waterborne Ingestion Table 1.1 Radiological Environmental Sampling Program Requirement Groundwater Samples from 2 sources.

Sediment From Shoreline 1 sample from downstream area.

1 sample from upstream area.

Milk 1 sample from milking animals within 8 km if milk is available commercially.

1 control sample (only if indicator exists) r8 km if milk is available.

Sample Point Description, Distance and Direction PGWELL (Sector G, Radius 5.0 Miles) -

30rt Gibson Wells - Take from distribution system or one of the five wells.

CONSTWELL (Sector Q, Radius 0.4 Miles)

- GGNS Construction Water Well - Taken From distribution system or the well.

SEDHAM (Sector N, Radius 1.6 Miles) -

Downstream of the GGNS discharge point in the Mississippi River near Hamilton Lake outlet.

SEDCONT (Minimum of 100 yds) -

Upstream of the GGNS discharge point in the Mississippi River.

Currently, no available milking animals within 8 km of GGNS.

ALCONT (Sector K, Radius 10.5 Miles) -

Located South-southwest of GGNS at AIcorn State University.

Sampling and Collection Frequency 366 days 366 days 92 days when required Type and Frequency Of Analyses Gamma isotopic and tritium analyses; 366 days Gamma isotopic; 366 days Gamma isotopic and 1-131; 92 days 18

Exposure Pathway Ingestion Table 1.1 Radiological Environmental Sampling Program Requirement Fish 1 sample in vicinity of GGNS discharge point.

1 sample uninfluenced by GGNS discharge.

Food Products 1 sample of broadleaf vegetation grown in one of two different offsite locations with highest anticipated annual average ground level D/Q if milk sampling is not performed.

1 sample of similar vegetation grown 15 - 30 km distant if milk sampling is not performed.

Sample Point Description, Distance and Direction FISHDOWN - Downstream of the GGNS discharge point into the Mississippi River FISHUP - Upstream of the GGNS discharge point in the Mississippi River uninfluenced by plant operations.

VEG-J (Sector J, Radius 0.4 Miles) - South of GGNS near former Training Center on Bald Hill Road.

VEG-CONT (Sector K, Radius 10.5 Miles) -

AIcorn State University south-southwest of GGNS when available, otherwise a location 15-30 km distant.

Sampling and Collection Frequency 366 days

~

92 days when available Type and Frequency Of Analyses Gamma isotopic on edible portion; 366 days Gamma isotopic and 1-131; 92 days 19

FIGURE 1-1 EXPOSURE PATHWAYS FIGURE 1-1 Exposure Pathways 20

FIGURE 1 SAMPLE COLLECTION SITES NEAR FIELD FIGURE 3.0-1 Collection Site Locations 0-4 Mile Area Map LEGEND Air Sampler (3 Surface Water A Ground Water 5 Broadleaf Vegetation 0 Sediment r~

W TLD

  • Ranney Wells Milk

,P fish ENTERGY GRAND GULF NUCLEAR STATION 0-4 Mile Environmental

-(,Jy-Sampling Location Map y-y I

/,

<\\

SCALE I N MILES Grand Gulf, Unit 1 3.0-7 Revision 29 OW5

t-igure 3.0-1 FIGURE 1-3 SAMPLE COLLECTION SITES - FAR FlEL FIGURE 3.0-2 Collection Site Locations, General Area Map 4-10 Mile Area Map

~~

LEGEND Air Sampler 0

Surface Water A Ground Wider Broadleaf Vegetation Sediment (J TLD

  • Ranney Wells
  • Milk VICKSGUitG AIRPORT 18 MILES FROM GRAND GULF TO VICKSBURG AIRPORT Sector (8)

HERMANVILLE Located 13 Miles irom Grand Gulf - Sector {F)

ENTERGY GRAND GULF NUCLEAR STATION 4-10 Mile Environmental Sampling Location Map Grand Gulf, Unit 1 3.0-8 Revision 29 01x35 I

2.0 Interpretation and Trends of Results 2.1 GGNS did not detect any plant related gamma emitting radionuclides in the quarterly air particulate composites or Iodine-1 3 1 in the radioiodine cartridges during the reporting period, as has been the case in previous years. The REMP detected radioactivity in this pathway attributable to other sources twice. These include the 25th Chinese nuclear test explosion in 1980, and the radioactive plume release due to reactor core degradation at Chernobyl Nuclear Power Plant in 1986. Therefore, the airborne exposure pathway has been unaffected by the operation of GGNS and airborne concentrations continue to be at background levels.

Air Particulate and Radioiodine Sample Results Table 3.1, which includes gross beta concentrations, provides a comparison of the indicator and control means and ranges, further emphasizes that the airborne pathway continues to remain at background levels. In the absence of plant-related gamma radionuclides, gross beta activity is attributed to naturally occurring radionuclides.

Consistent trends are present for control and indicator locations. This further supports the presence of naturally occurring activity.

2.2 Thermolumineseent Dosimetry Sample Results GGNS calculates dose by subtracting shield readings from control and indicator location readings and reports measured dose as net exposure normalized to 92 days.

GGNS relies on comparison of the indicator locations to the control location as a measure of plant impact. Gamma radiation dose in the reporting period is compared to control location readings for previous years as shown in Figure 2-1.

GGNS comparison of the indicator results to the control and to previous indicator results, as seen in Figure 2-1 and Table 3.1, indicates that plant operations had no significant impact on ambient radiation levels during the reporting period.

With the exception of TLD location M-21 (Sector J, 0.4 miles), levels continue to remain at or near background. An increase in the dose rate at location M-21 was due to implementation of moderate hydrogen injection to the feed water system. Hydrogen injection provides protection against Intergranular Stress Corrosion of plant components. An increase in direct radiation dose rates associated with implementation of hydrogen injection has been documented at other nuclear power plants. This increase is not a result of increased liquid or gaseous releases to the environment. Location M-2 1 dose rate of 3.7 millirem per quarter greater than the Control location M-14 (sector 3, 18.0 miles) remains well below the limitations of 10 CFR 20.1301(a)(l) and 20CFR 20.1302@)(2)(ii).

23

Figure 2-1 mFUqtr 20.0 16.0 1999-2004 TLD Readings A

c1 X

a A

A 12.0 A

+

, A A

X 8.0

+ Qtr 1,2004 Qtr 2,2004 A Qtr 3,2004 x Qtr 4,2004 4.0 1999-2003 Control Location,

Maximum

(+2 Stdev) 1999-2003 Control Location Mnimum

(-2 Stdev) 24

2.3 Water Sample Results Analytical results for surface water and groundwater samples were similar to those reported in previous years.

Surface water samples were collected from two indicator and one control location and analyzed for gamma emitting radionuclides and tritium. Plant related gamma emitting radionuclides and tritium remained undetectable in the upstream and downstream Mississippi River locations, which is consistent with preoperational and previous operational years.

In addition, gamma emitting radionuclides and tritium were undetectable in the downstream sample collected during a liquid radwaste discharge.

Groundwater samples were collected from two locations (indicator and control) and analyzed for gamma emitting radionuclides and tritium. GGNS did not detect any plant related gamma emitting radionuclides or tritium in groundwater samples during the reporting period.

Based on review of results and previous historical data, GGNS concluded that plant operations had no significant impact on this pathway during the reporting period.

2.4 Sediment Sample Results Sediment samples were collected fi-om two ODCM Specification locations (indicator and control) and analyzed for gamma emitting radionuclides. In this reporting period, plant related gamma emitting radionuclides were below detectable concentrations in the upstream (control) location. In this reporting period, Cobalt-60 was detected at 17.87 rt 10.26 pCi/kg and Cesium-137 was detected at 15.48 rt 8.39 pCi/kg in the downstream (indicator) location.

A review of REMP data collected at the downstream location from 1983 through 2003 indicates the Cesium-137 concentration has ranged from less than detectable to 300 pCi/Kg. The presence of Cesium-137 is attributed to atmospheric weapons testing.

From 1983 through 2003 the concentration of plant related gamma emitting radionuclides similar to Cobalt-60 [Manganese-%, Cobalt-581 has ranged from less than detectable to 20 pCi/kg. Cobalt-60 at the concentration of 17.87 If: 10.26 pCi/kg is near the detection level for this nuclide and was less than detectable in a duplicate sample.

Based on the above review, 2004 REMP data is consistent with the previous monitoring periods. Therefore, GGNS concluded that plant operations Mad no significant impact on this pathway during the reporting period.

25

2.5 Milk Sample Results GGNS personnel did not collect inilk samples within five i d e s of the site in the reporting period due to the absence of milking animals. Since there are no dairies within five miles of GGNS, it is concluded GGNS operation had no impact on this pathway.

2.6 Fish Sample Results Fish samples were collected from two locations (indicator and control) and analyzed for gamma emitting radionuclides. GGNS did not detect any plant related gamma emitting radionuclides in fish samples during the reporting period, as has been the case in preoperational and previous operational years. These results indicate that this pathway has not been affected by plant operations.

2.7 Food Product Sample Results Food product samples were collected from control and indicator locations when available and analyzed for gamma emitting radionuclides. GGNS did not detect any plant related gamma emitting radionuclides in vegetation samples during the reporting period. Nuclides detected previously at the control and indicator locations are attributed to the Chernobyl release and atmospheric weapons testing. These results indicate that this pathway has not been affected by plant operations.

Five special samples of vegetation were collected at an offsite location to supplement the REMP. The location is under evaluation for a control sample location. GGNS did not detect any plant related gamma emitting radionuclides in vegetation samples during the reporting period.

One special sample of venison was collected on the GGNS property to supplement the REMP. GGNS did not detect any plant related gamma emitting radionuclides in the venison sample during the reporting period.

26

2.8 Land Use Census Results The next Land Use Census will be conducted in 2005.

27

2.9 interlaboratory Comparison Results River Bend Station (RBS) Environmental Laboratory analyzed interlaboratory comparison samples to fulfill the requirements of the ODCM Specifications 6.12.1.

Attachment I, Radiological Environmental Monitoring Report, contains these results in Table 9.1. GGNS review of RBS interlaboratory comparison indicated that 100%

of the sample results for accuracy and 100% of the results for precision were within the acceptable control limits of the three normalized deviations.

28

3.0 Radiological Environmental Monitoring Program Summary 3.1 Program Results Summary Table 3.1 summarizes the REMP results.

GGNS personnel did not use values reported as less than the lower limit of detection (<LLD) when determining ranges and means for indicator and control locations.

29

TABLE 3.1 RadioloPical Environmental Monitoring Program Summary Name of Facility: Grand Gulf Nuclear Station Docket No: 50-416 Locatioii of Facility: Claiborne Countv, Mississippi Reporting Period: Januarv - December 2004 Sample Type

( Units )

Type & Number of Analyses a LLD Indicator Locations Mean ( F 1

[ Range I Control Locations Mean ( F )

[ Range 1 Number of Nonroutiiie Results Location with Highest Annual Mean Mean ( F )

[ Range ]

0.023 ( 52 / 52 )

[ 0.009 - 0.046 ]

Location d (Sector G, 5.5 mi )

AS-1 PG Air Particulates (p~i/m3 GB 156 GS 12 CS-134 CS-137 0.01 0.05 0.06 0.023 ( 104 / 104)

[ 0.008 - 0.046 ]

0.023 { 52 1 52 )

[ 0.009 - 0.045 ]

<LLD

<LLD

<LLD

<LLD NIA NIA NiA NiA Airborne Iodine

( pci/ni3 1-131 156

<LLD NiA NIA

<LLD 0

M-2 1

( Sector J, 0.4 mi. )

M-49

( Sector H, 4.5 mi. )

M-0 1

( Sector E, 3.5 mi. )

NIA 14.3 ( 4 1 4 )

[ 11.5 - 16.1 ]

11.2 ( 4 i 4 )

[ 10.2-12.1 ]

[ 9.9 - 12.1 ]

11.2 ( 4 / 4 )

NIA N/A Inner Ring TLDs

( W Q t r 1 Gamma 36 9.8 ( 36 1 36 )

[ 6.8 - 16.1 ]

Gamma 27 9.4 ( 27i 27 )

[ 6.1 -- 12.4 ]

NiA Special Interest TLDs

( W Q t r 1 Ganma 28 9.1(28128)

[ 7.1 - 12.1 ]

NIA Control TLDs

( W Q t r 1 Gamma 4

NIA 10.6 ( 4 1 4 )

[ 9.1 - 12.2 ]

30

TABLE 3.1 Radiolopica1 Environmental Monitoring Program Summary Name of Facility: Grand Gulf Nuclear Station Docket No: 50-416 Location of Facility: Claiborne County, Mississippi Reporting Period: January - December 2004

< LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD NIA NIA NIA N/A NIA N/A NIA NIA NIA N/A N/A N/A NIA NIA NIA N/A NIA NIA NIA NIA N/A NIA NIA N/A NIA NIA

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD Number of Nonroutine Results 0

0 0

0 0

0 0

0 0

0 0

0 0

31

TABLE 3.1 Radiological Environmental Monitoring Program Summarv Sample Type

( Units )

Groundwater

( PC21)

Name of Facility: Grand Gulf Nuclear Station Docket No: 50-416 Location of Facility: Claiborne County. Mississippi Reporting Period: January - December 2004 Type & Number of Analyses a H-3 2

1-131 2

GS 4

Mn-54 Fe-59 co-58 CO-60 Zn-65 Zr-95 Nb-95 CS-134 CS-137 Ba-140 La-140 GS 4

CS-134 (3-137 co-60 LLD 2000 1

15 30 15 15 30 30 15 15 18 60 15 150 180 NIA Indicator Locations Mean ( F )

L Range 1

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD CLLD CLLD

<LLD

<LLD

<LLD

<LLD

<LLD 15.48 (112)

[One Sample]

17.87 (112)

[One Sample]

Location with Highest Annual Mean Location d NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA SEDHAM (Sector N, 1.6 Miles)

SEDHAM (Sector N, 1.6 Miles)

Mean ( F )

[ Range ]

NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA 15.48 (112) 17.87 (112)

Control Locations Mean ( F )

I Range I

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD Number of Nonroutine Results 0

0 0

0 0

0 0

0 0

0 0

0 0

0 0

32

Sample Type

( Units )

Fish

( pCiJkg 1 Food Products

( pCiJkg )

TABLE 3.1 Radiological Environmental Monitorhe Program Summary Name of Facility: Grand Gulf Nuclear Station Docket No: 50-416 Location of Faciiity: Claiborne County, iclississippi Reporting Period: January - December 2004 Type & Number of Analyses a GS 4

Fe-59 Co-60 Zn-6 5 M11-S 4 (20-58 CS-134 CS-137 1-131 10 CIS 10 CS-134 cs-137 LLD 130 260 130 130 260 130 150 60 60 80 Indicator Location Mean ( F )

I Range 1

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD Location with Highest Annual Mean Location d NIA N/A NIA NIA NIA NIA hr/A NIA N/A NIA M e a n ( F ) C

[ Range 1 NIA NIA NIA NIA N/A NJA NIA N/A NIA N/A Control Locations M e a n ( F ) C I Range 1

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD Number of Nonroutine Results 33

TABLE 3.1 Location with Highest Annual Mean Mean ( F )

[ Range I

- Location d Radiological Environmental Monitorinp Propram Summary Control Locations Mean ( F )

[ Range ]

Sample Type

( Units )

Venison (Special)

( P C W )

Food Products (Special) pCi/Kg NIA Name of Facility: Grand Gulf Nuclear Station Docket No: 50-416 Location of Facility: Claiborne County. Mississippi Reporting Period: Januarv - December 2004 NIA

<LLD Type & Number of Analyses a GS 1

Mn-54 Fe-59 CO-60 CO-58 Zn-65 CS-134 CS-137 1-131 5

GS 5

CS-134 CS-137 LLD b 130 260 130 130 260 130 150 60 60 80 Indicator Location Mean ( F )

[ Range I

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD

<LLD NIA NIA NIA NiA NIA NIA NIA NIA NiA NIA NIA NIA NIA NiA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA NIA

<LLD

<LLD Number of Nonroutine Results 0

0 0

0 0

0 0

0 0

0 a

= Gross beta; 1-131 = Iodine-131; H-3 = Tritium; GS = Gamma scan.

LLD = Required lower limit of detection based on GGNS ODCM Table 6.12.1-3.

Mean and range based upon detectable measurements only. Fraction of detectable measurements at specified locations is indicated in parenthesis (F).

Where applicable, locations are specified by name, distance from reactor site and meteorological sector.

Nsn-routine results are those which exceed ten times the control station value. If no control station value is available, the result i s considered non-routine if it exceeds ten times the preoperational value for the location.

LLD is not defined in GGNS ODCM Table 6.12.1-3.

34 Radiological Monitoring Report Summary of Monitoring Results 35

TABLE OF CONTENTS TABLE 1.1 TABLE 1.2 TABLE 2.1 TABLE 2.2 TABLE 2.3 TABLE 3.1 TABLE 3.2 TABLE 4.1 TABLE 4.2 TABLE 4.3 TABLE 5.1 TABLE 6.1 TABLE 7.1 TABLE 8.1 TABLE 9.1 AIR PARTICULATE FILTER GROSS BETA AND CHARCOAL CARTRIDGE IODINE-131 AIR PARTICULATE FILTER GAMMA T H E ~ M O ~ U ~ ~ N E S C ~ N T DOSIMETERS THERMOLUMINESCENT DOSIMETERS THERMOLUMINESCENT DOSIMETERS SURFACE WATER GAMMA SURFACE WATER TRITIUM GROUNDWATER GAMMA GROUNDWATER TRITIUM GROUNDWATER IODINE-131 SEDIMENT FISH FOOD PRODUCTS SPECIAL SAMPLES INTERLABORATORY COMPARISON 37 46 47 48 49 50 51 52 53 54 55 56 57 58 59 36

Table 1.1 Sample Type: Air Particulate Filter and Radioiodine Cartridge Analysis: Gross Beta and 1-1 3 1 Units: pCi/m' AIR SAMPLE AS-1 PG - GGNS Nearest Community LLD (pCilm"3)

AS-1 LAB ID 20040009 20040029 20040042 20040074 20040088 20040 1 17 200401 44 20040160 20040 186 20040209 20040236 20040253 20040290 20040328 20040363 20040377 20040405 20040429 START DATE END DATE 12/30/2003 11612004 111 312004 1/20/2004 1 /27/2004 2/3/2004 211012004 2/17/2004 2/24/2004 3/2/2004 3 /9/2 004 311612004 3/23/2004 3 I3 0/2 004 4/6/2004 4/13/2004 412012004 4/27/2004 1/6/2004 111 312004 11'2012004 1/27/2004 2/3/2004 2/10/2004 211712004 2124/2004 3/2/2004 3/9/2004 3/16/2004 312312004 313012004 4/6/2004 4/13/2004 4/20/2004 412712004 5/4/2004 0.07 1-131

< 0.014

< 0.016

< 0.017

< 0.018

< 0.013

< 0.016

< 0.018

< 0.014

< 0.015

< 0.016

< 0.015

< 0.018

< 0.014

< 0.016

< 0.016

< 0.016

< 0.012

< 0.015 0.01 GROSS BETA 0.017 +I- 0.002 0.035 +I- 0.003 0.033 +/-0.002 0.044 +/-0.003 0.035 +/- 0.003 0.032 +I- 0.002 0.025 +I- 0.002 0.030 +I- 0.002 0.018 +/- 0.002 0.014 +I- 0.002 0.021 +/- 0.002 0.019 +I- 0.002 0.015 +/- 0.002 0.020 +I- 0.002 0.018 +/- 0.002 0.023 +I- 0.002 0.020 +I-0.002 0.017 +I- 0.002 37

LLD (pCilm"3)

AS-1 LAB ID 20040483 200405 19 2004054 1 20040546 20040576 20040593 20040627 20040649 20040695 200407 10 20040765 20040798 20040840 20040869 20040889 20040893 20040929 20040936 20040977 20041003 START DATE END DATE 5/4/2004 511 112004 51'1 812004 5/25/2004 61 1 12004 61812004 61 1512004 6/22/2004 6/29/2004 71612004 7/1312004 712012004 712712004 813/2004 8110/2004 811 712004 812412004 813 112004 91712004 911 412004 511 112004 511 812004 512512004 hI112004 6/8/2004 611512004 612212004 612912004 71612004 7/13/2004 7!2012004 712712004 81312004 8/1012004 811 712004 812412004 813 112004 9/7/2004 911412004 9/2 112004 0.07 1-131

< 0.016

< 0.019

< 0.016

< 0.017

< 0.020

< 0.018

< 0.015

< 0.017

< 0.018

< 0.013

< 0.013

< 0.017

< 0.017

< 0.017 0.014

< 0.015

< 0.018

< 0.015

< 0.018

< 0.016 0.01 GROSS BETA 0.030 +/- 0.002 0.01 1 +I- 0.002 0.016 +I- 0.002 0.02 1 +I-0.002 0.019 +I-0.002 0.012 +I- 0.002 0.013 +I- 0.002 0.009 +I- 0.002 0.016 +I- 0.002 0.015 +I- 0.002 0.026 +I-0.002 0.024 +I- 0.002 0.029 +/- 0.002 0.032 +I- 0.002 0.025 +1- 0.002 0.019 +I- 0.002 0.016 +I- 0.002 0.024 +/- 0.002 0.018 +I- 0.002 0.018 +I- 0.002 38

D (pCilm"3)

AS-1 LAB ID 20041 024 20041056 20041 102 2004 1 133 2004 1 177 20041 2 14 20041274 2004 13 19 20041340 20041361 20041393 20041405 2004 1445 20041456 Average:

Maximum Minimum:

START DATE END DATE 912 112004 912812004 101512004 10112/2004 1 01 1912004 1 012612004 111212004 1 1 1912004 1111612004 11/23/2004 1113012004 121712004 1211412004 1212 112004 912 812004 101512004 1 01 1212004 1011 912004 1012612004 1 11212004 I11912004 1111612004 11123l2004 1113012004 12/7/2004 1211412004 1212112004 12/28/2004 0.07 1-131

.= 0.017

< 0.016

< 0.016

< 0.013

< 0.048

< 0.014

< 0.017

< 0.014

< 0.016

< 0.013

< 0.016

< 0.015

< 0.024

< 0.016 0.01 GROSS BETA 0.032 +I- 0.002 0.046 +I- 0.003 0.028 +i- 0.002 0.024 +I- 0.002 0.042 +I- 0.004 0.021 +I- 0.002 0.023 +/- 0.002 0.024 +I- 0.002 0.016 +I- 0.002 0.019 +I-0.002 0.023 +I- 0.002 0.019 +I- 0.002 0.030 +f- 0.002 0.024 +I-0.002 0.023 0.046 0.009 39

Table 1.1 Sample Type: Air Particulate Filter and Radioiodine Cartridge Analysis: Gross Beta and 1-1 3 1 Units: pCi/m' AIR SAMPLE AS-3 61VA - GGNS - Control LLD (pCilm"3)

LAF3 ID 200400 10 20040030 20040043 20040075 20040054 20040 1 18 20040145 20040161 20040187 200402 10 20040237 20040254 2004029 1 20040325 20040364 20040378 20040406 20040430 START DATE 1213012003 1 I612004 111 312004 112Ol2004 1 I2712004 2/3/2004 211 012004 211712004 212312004 31 1 12004 3/8/2004 311612004 312312004 313012004 4/6/2004 411312004 412012004 412712004 END DATE 11612004 1 I1 312004 1l20l2004 112712004 2/3/2004 21 1012004 211712004 212 3 12 004 31112004 31812004 311 612004 312312004 313012004 41612004 411312004 412012004 412712004 5/4/2004

-07 1-131

< 0.013

< 0.022

< 0.014

< 0.014

< 0.017

< 0.015

< 0.015

< 0.017

< 0.012

< 0.015

< 0.017

< 0.020

< 0.015

< 0.017

< 0.017

< 0.020

< 0.017

< 0.018 0.01 GROSS BETA 0.017 +/- 0.002 0.03 1 +I- 0.002 0.036 +I-0.003 0.045 +I-0.003 0.035 +I- 0.003 0.033 +I- 0.002 0.028 +I- 0.002 0.031 +I- 0.003 0.019 +I- 0.002 0.016 +I- 0.002 0.023 +I- 0.002 0.018 +I-0.002 0.015 +I- 0.002 0.013 +I- 0.002 0.013 +I-0.002 0.027 +I- 0.002 0.020 +I-0.002 0.017 +I- 0.002 40

LLD (pCb'm"3)

AS-3 61VA LAB ID 20040484 20040520 20040542 20040547 20040577 20040594 20040628 20040650 20040696 200407 1 1 20040766 20040799 20040841 20040870 20040890 20040894 20040930 20040937 20040978 20041004 START DATE END DATE 51412004 511112004 511812004 512512004 61 1 I2004 61812004 611 512004 612212004 612912004 71612004 711312004 712012004 712712004 81312004 811 012004 811 712004 812412004 813 112004 91712004 91 1412004 51 1 1 I2004 511812004 512512004 61 112004 61812004 611 512004 612212004 612912004 7/6/2004 711 312004 712012004 7/27/2004 81312004 811 Ol2004 811712004 812412004 813 112004 91712004 91 1412004 912 112004 0.07 1-131

< 0.017

< 0.019

< 0.018

< 0.014

< 0.015

< 0.018

< 0.012

< 0.018

< 0.019

< 0.013

< 0.016

< 0.016

< 0.011

< 0.017

< 0.019

< 0.017

< 0.015

< 0.016

< 0.025

< 0.019 0.01 GROSS BETA 0.026 +I- 0.002 0.009 +i- 0.002 0.019 +I- 0.002 0.019 +I-0.002 0.020 +I-0.002 0.012 +I- 0.002 0.013 +I- 0.002 0.009 +I- 0.002 0.015 +/- 0.002 0.029 +I- 0.002 0.026 +I-0.002 0.024 +I- 0.002 0.025 +/- 0.002 0.029 +I- 0.002 0.025 +I- 0.002 0.020 +!- 0.002 0.016 +I- 0.002 0.024 +I- 0.002 0.021 +I- 0.002 0.018 +I- 0.002 41

D (pCilm"3)

AS-3 61VA LAB ID 20041025 2004 1057 20041 103 2004 1 134 2004 1 178 200412 15 20041275 2004 1320 2004 134 1 2004 1 362 2004 1394 20041406 2004 1446 2004 1457 Average:

bfaxirnuin Minimum:

START DATE END DATE 9/21/2004 9/28/2004 101512004 101 1212004 101 1912004 1012612004 11/2/2004 11/9/2004 11116/2004 11/23/2004 11/30/2004 12/7/2004 1211412004 12/2112004 9/28/2004 101512004 1011 212004 101 19/2004 10126/2004 11/2/2004 1119/2004 11/16/2004 11/23/2004 11/3012004 1217/2004 12114l2004 1212 112004 12/2812004 0.07 1-131

< 0.014

< 0.017

< 0.014

< 0.014

< 0.018

< 0.015

< 0.010

< 0.017

< 0.018

< 0.011

< 0.016

< 0.016

< 0.021

< 0.012 0.01 GROSS BETA 0.03 1 +/- 0.002 0.038 +i- 0.003 0.028 +/- 0.002 0.021 +I- 0.002 0.020 +I- 0.002 0.020 +I- 0.002 0.022 +I- 0.002 0.024 +I- 0.002 0.014 +/- 0.002 0.019 +/- 0.002 0.023 +I- 0.002 0.021 +/- 0.002 0.029 +I- 0.002 0.024 +I-0.002 0.023 0.045 0.009 42

Table 1.1 Sample Type: Air Particulate Filter and Radioiodine Cartridge Analysis: Gross Beta and 1-131 Units: pei/m3 AIR SAMPLE AS GGNS - Indicator LAB ID 200400 1 1 2004003 1 20040044 20040076 20040095 20040 I 19 20040146 20040 162 20040188 200402 1 1 2004023 8 20040255 20040292 20040326 20040365 20040379 20040407 2004043 1 AS-7UH START DATE 1213012003 1/6/2004 1 I1 312004 1l2012004 1 12 712 004 213i2004 211012004 211712004 212412004 31212004 3/9/2004 311 612004 312312004 313012004 416i2004 411312004 412012004 412712004 END DATE 11612004 1/13/2004 112012004 1 I2712004 2/3/2004 2110l2004 2/17/2004 2/24/2004 31212004 3i912004 31 1612004 312312004 313012004 41612004 411 312004 412012004 412712004 51412004 0.07 1-131

< 0.018

< 0.018

< 0.018

< 0.017

< 0.016

< 0.016

< 0.016

< 0.018

< 0.016

< 0.015

< 0.021

< 0.015

< 0.018

< 0.015

< 0.014

< 0.014

< 0.017

< 0.015 0.01 GROSS BETA 0.017 +I- 0.002 0.037 +I- 0.003 0.035 +I-0.003 0.044 +I-0.003 0.034 +I- 0.003 0.032 +i- 0.002 0.027 +/- 0.002 0.032 +I- 0.002 0.017 +I- 0.002 0.015 +I- 0.002 0.022 +I- 0.002 0.020 +I-0.002 0.016 +I- 0.002 0.02 1 +i- 0.002 0.018 +I- 0.002 0.027 +I- 0.002 0.023 +I-0.002 0.018 +/- 0.002 43

D (pCilm"3)

AS-7UH LAB ID 20040485 2004052 1 20040543 20040548 20040578 20040595 20040629 20040651 20040697 200407 12 20040767 20040800 20040842 20040871 20040891 20040895 2004093 1 20040938 20040979 20041005 START DATE END DATE 514l2004 511 112004 511812004 512512004 6/1/2004 61812004 611512004 612212004 612912004 71612004 711312004 712012004 712712004 8/3/2004 81 1012004 811 712004 812412004 813 112004 91712004 911412004 511 112004 511 812004 512.512004 61 112004 6/8/2004 6/15/2004 612212004 6/29/2004 71612004 711312004 712012004 7/27/2004 81312004 81 1012004 811 712004 812412004 813 112004 91712004 911412004 912112004 0.07 1-131

< 0.016

< 0.013

< 0.017

<: 0.014

< 0.017

< 0.017

< 0.016

< 0.016

< 0.017

< 0.016

< 0.018

< 0.016

< 0.018

< 0.018

< 0.017

< 0.014

< 0.017

< 0.013

< 0.023

.= 0.015 0.01 GROSS BETA 0.032 +I- 0.003 0.014 +1- 0.002 0.016 +1- 0.002 0.020 +I-0.002 0.017 +I-0.002 0.012 +1- 0.002 0.01 1 +I- 0.002 0.008 +I- 0.002 0.012 +I- 0.002 0.017 +I- 0.002 0.025 +I-0.002 0.026 +/- 0.002 0.027 +1- 0.002 0.03 1 +I- 0.002 0.024 +1- 0.002 0.017 +/- 0.002 0.013 +I- 0.002 0.024 +1- 0.002 0.019 +1- 0.002 0.014 +I- 0.002 44

D (pCilm"3)

AS-7UII LAB ID 2004 1026 2004 1058 20041 104 20041 135 20041 179 20041216 2004 1276 2004 132 1 2004 1342 20041363 2004 1 3 95 20041407 20041447 20041458 Average:

Maximum Minimum:

START DATE END DATE 912 112004 912812004 1015l2004 1 O i l 212004 10/1912004 1012612004 11/2/2004 11/9/2004 11/16/2004 11/23/2004 11/30/2004 121712004 1211412004 1212112004 9/2812004 101512004 1011212004 1011912004 1 Of 2 612 004 111212004 11/9/2004 11/16/2004 1 U2312004 1113012004 12/7/2004 12/14/2004 1212112004 12/2812004 0.07 1-131

< 0.016

< 0.014

< 0.016

.= 0.016

< 0.018

< 0.014

< 0.014

< 0.016

< 0.016

< 0.016

< 0.016

< 0.012

< 0.022

< 0.015 0.01 GROSS BETA 0.029 +I- 0.002 0.043 +i- 0.003 0.027 +I- 0.002 0.023 +I- 0.002 0.020 +/- 0.002 0.020 +/- 0.002 0.022 +/- 0.002 0.023 +I- 0.002 0.015 +/- 0.002 0.016 +I- 0.002 0.022 +I- 0.002 0.021 +I- 0.002 0.028 +/- 0.002 0.026 +/-0.002 0.022 0.044 0.008 45

Table 1.2 Sample Type: Air Particulate Filter Analysis: Ganma Isotopic Units: pCi/m3 IR PARTICULATE F LTER QUARTERLY COMPOSITES (GAMMA) - GGNS LD (pCilm"3)

AB ID LOCATZON 20040359 20040360 2004036 1 20040748 20040749 20040750 20041 119 2004 1 120 20041 121 20041499 2004 1 SO0 2004 150 1 AS-1 PG AS-3 61VA AS-7 UH AS-1 PG AS-3 61VA AS-7 UH AS-1 PG AS-3 61VA AS-7 UH AS-1 PG AS-3 61VA AS-7 UH DATE 211312004 2113/2004 211312004 511412004 511412004 51 1412004 811 312004 811312004 811312004 1111212004 11l1212004 1111212004 0.05 CS-134

< 0.005

< 0.005

< 0.004

< 0.004

< 0.003

< 0.003

< 0.004

< 0.005

< 0.004

< 0.004

< 0.004

< 0.004 0.06 CS-137

< 0.004

< 0.003

< 0.003

< 0.004

< 0.003

< 0.004

< 0.003

< 0.003

< 0.004

< 0.004 c: 0.003

< 0.003 46

Table 2.1 Sample Type: Thermoluminescent Dosimeters Analysis: Gamma Dose Units: mem/Qtr Inner Ring - Within General Area of Site Boundary (ODCM Specifications)

Station 1st Qtr 2nd Qtr 3rd Qtr 4th Qtr Annual Mean M-16 9.1 10.3 10.5 10.1 10.0 M-17 9.1 9.6 11.3 9.3 9.8 M-19 8.2 9.5 10.7 9.3 9.4 M-21*

11.5 15.2 16.1 14.3 14.3 M-22 7.8 9.7 10.0 10.1 9.4 M-23 6.8 7.9 9.0 7.7 7.9 M-25 7.6 7.2 9.5 7.3 7.9 M-28 8.9 10.0 11.9 10.3 10.3 M-94 8.3 9.2 10.0 9.7 9.3 Outer Ring - Approximately Three (3) to Five (5) Miles from the Site (ODCM Specifications)

Station 1st Qtr 2nd Qtr 3rd Qtr 4th Qtr Annual M-36 7.6 7.9 8.5 9.4 8.3 M-40 6.1 7.2 6.8 7.5 6.9 M-48 9.2 9.1 9.6 9.3 M-49

  • 10.2 10.4 12.1 11.9 11.2 Mean M-50 8.2 9.3 8.8 9.8 9.0 M-55 9.4 10.8 10.1 10.7 10.3 M-57 10.0 10.3 12.4 10.9 10.9
  • Location with highest annual mean.
    • Excluded from reporting, see Sample Deviations Section, TLD.

47

Table 2.2 Sample Type: Thermoluminescent Dosimeters Analysis: G a m a Dose Units: rnredQtr Special Interest Areas - Population Centers & Schools (ODCM Specifications)

Station 1st Qtr 2nd Qtr 3rd Qtr 4th Qtr Annual Mean M-Q 1

  • 9.9 12.1 11.6 11.1 11.2 M-07 8.7 10.6 10.1 10.2 9.9 M-09 8.1 9.6 10.6 9.6 9.5 M-10 7.1 8.5 8.9 8.1 8.1 M-33 7.7 7.8 8.7 7.7 8.0 M-38 7.9 8.4 9.2 8.9 8.6 M-39 8.0 8.2 9.3 9.4 8.7
  • Location with highest annual mean.

48

Table 2.3 Sample Type: Thermoluminescent Dosimeters Analysis: Gamma Dose Units: mrem/Qtr Special Interest Areas - Control (ODCM Specifications)

Station 1st Qtr 2nd Qtr 3rd Qtr 4th Qtr Annual Mean M-14 9.1 10.5 12.2 10.7 10.6 49

Table 3.1 Sample Type: surface Water Aialysis: Gamma Isotopic Units: pCi/l SlJRFACE WATER SAMPLES (GAMMA) - GGNS LLD (pCi/l)

LAB ID LOCATION DATE 20040013 MK DOWN 1/6/2004 20040014 MR DOWN GG lihi2004 20040017 MRUP 1/6/2004 2004001 8 MRUP GG 1/6/2004 20040341 MR DOWN 4/6/2004 20040343 MRUP 4/6/2004 20040691 MR DOWN 7,612004 20040693 MRLJP 7/6/2004 20041098 MR DOWN 10/12/2004 2004 I 100 MRUP 10/12/2004 20041286 MR DOWN 11/9/2004 20041288 MR DOWN GG* 11/9/2004 15 MN-54

< 10.71

< 9.25

< 11.14

< 7.70

< 8.74

< 7.94

< 5.47

< 7.15

< 10.42

< 8.81 10.71

< 7.88 15 CO-58

< 9.92

< 8.99

< 6.84

< 8.52

<: 7.40

< 9.98

< 10.09

< 7.12

< 11.90

< 10.17

< 7.69

< 9.94 30 FE-59

< 20.05

< 12.12

.c 20.89

< 13.79

< 16.09

< 18.40

< 11.27

< 17.81

< 20.04

< 20.82

< 12.40

< 18.23 15 CO-60

< 13.84 c: 10.09

< 7.55

< 5.87

< 7.55

< 9.94

< 4.82

< 10.17

< 4.10

< 10.83

< 7.43

< 5.05 30 ZN-65

< 15.42

.< 22.63

< 23.09 17.43

< 18.33

< 16.64

< 13.76

< 20.19

< 19.52 4 13.94

< 12.37

< 23.42 15 NB-95

< 11.50

< 9.95

< 11.33

< 6.62

< 8.22

< 8.86

< 9.57

< 7.38

< 7.83

< 9.01

< 13.71

< 8.85 30 ZR-95

< 18.61

< 16.73

< 16.58

< 15.09

< 8.47

< 13.00

< 22.11

< 14.53

< 15.13

< 11.20

< 15.76

< 19.13 15 1-131

< 9.84

< 11.64

< 10.68

< 8.14

< 11.67

< 9.20

< 10.88

< 8.71

< 9.53

< 9.93

< 11.89

< 12.56 15 CS-134

< 9.73

< 10.02

< 8.87

< 9.25

< 8.57

< 8.93 9.99

< 10.14

< 8.52

< 9.95

< 12.59

< 9.81 18 CS-137

< 10.22

< 10.80

< 10.32

< 9.56

< 6.93

< 9.40

< 10.24

.c 9.42 9.67

< 11.19

< 11.47

< 10.03 60 BA-140

< 27.20

< 30.83

< 35.82

< 28.11

< 27.37

< 27.12

< 33.06

< 33.72

< 30.10

< 30.12

< 46.70

< 32.43 15 LA-140

< 10.47

< 13.15

< 13.00

< 7.42

< 14.57

< 13.56

< 8.50

< 13.78

< 11.23

< 8.37

<: 4.49

< 7.40

  • Annual Saiiiple collected during liquid discharge GG - indicates duplicate sample.

50

Table 3.2 Sample Type: Surface Water Analysis: Tritium Units: pCi/l SURFACE WATER SAMPLES (TRITIUM) - GGNS LLD (pCi/l)

LAB ID 200400 15 200400 16 20040019 20040020 20040342 20040344 20040345 20040346 20040692 20040694 20041099 20041 101 2004 1287 LOCATION MR DOWN MR DOWN GG MRUP MRUP GG MR DOWN MRUP MRDOWN GG MRUP GG MR DOWN M R W MR DOWN MRUP MR DOWN*

DATE 11612004 1/6/2004 1/6/2004 1/6/2004 4/6/2004 41612004 4/6/2004 4/6/2004 7/6/2004 7/6/2004 I 011 212004 101 1 2/2004 11/9/2004 3000 TRITIUM

< 591

< 585

< 578

< 584

< 605

< 607

< 607

< 612

< 568

< 552

< 571

< 580

< 589

  • Annual Sample collected during liquid discharge GG - indicates duplicate sample.

51

Table 4.1 Sample Type: Groundwater Analysis: G a m a Isotopic Units: pCi/l GROUND WATER SAMPLES (GAMMA) - GGNS LL,D (pCi/l) 15 15 30 15 30 15 30 15 18 60 15 LAB ID LOCATION DAT MN-54 C0-58 FE-59 CO-60 ZN-65 NB-95 ZR-95 CS-134 CS137 BA-140 LA-140 2004 1 109 PGWELL 10/13/04

< 9.24

< 8.91

< 20.08 1 9.19

< 17.52

< 13.57

< 17.74

< 11.36

< 10.81

< 34.86

< 8.29 20041112 CONSTWELL 10/13/04

< 9.86 1 10.65 < 19.52 < 9.06

< 21.20

< 14.16

< 17.88

< 10.94

< 11.00

< 37.42

< 12.88 20041115 CONSTWELLGG 10113104

< 9.63

< 9.76

< 20.23 1 11.88

< 28.57

< 14.79

< 17.81

< 11.71 111.99

.: 44.21

< 13.86 33.50

< 14.74 20041 116 PGWELL GG 10/13/04 < 5.13

< 9.42 i 11.76 1 1002

< 17.32 10.14

< 14.51

< 8.34

<9.12 "GG" - indicates duplicate sample.

52

Table 4.2 Sample Type: Groundwater Analysis: Tritium Units: pCi/l GROUND WATER SAMPLES ( T TIUM) - GGNS LLD (pCi/l)

LAB ID LOCATION 20041 11 1 PGWELL 20041 114 CONSTWELL DATE 1 Oil312004 1 Oi 1312004 2000 TRITIUM

< 583.70

< 566.08 53

Table 4.3 Sample Type: Groundwater Analysis: Iodine Units: pCi/l GROUND WATER SAMPLES (Iodine-131) - GGNS LLD(pCi/l)

LAB ID LOCATION DATE 1.o 1-131 20041 I10 PGWELL 10/13/2004

.<: 0.86 20041 113 CONSTWELL 1011312004

< 0.88 54

Table 5.1 Sample Type: Sediment Analysis: Gamma Isotopic Units: pCi/kg SEDIMIENT SAMPLES (GAMMA) - GGNS LLD (pCilkg) 150 180 N/A LAB ID LOCATION DATE CS-134 CS-137 co-60 20040957 SEDHAM 9/8/2004

< 26.18

<33.24 17.87 +/- 10.26 20040958 SEDCONT 91812004

< 32.10

<32.51 20040969 SEDHAM GG 91812004

< 22.01 15.48-1 8.39 20040970 SEDCONT GG 9/8/2004

< 26.28

<37.87 GG - indicates duplicate sample.

55

Table 6.1 Sample Type:

Analysis: Gamma Isotopic Units: pCiikg FISH SAMPLES (GAMMA) - GGNS LLD (pCi/kg)

LAB LOCATION 130 130 260 130 260 DATE MN-54 CO-58 FE-59 CO-60 ZN-65 2004080 FISHUP 7/27/2004

< 17.84

< 15.03

< 27.47

< 23.62

< 50.74 2004080 FESHW GG 712712004

< 14.15

< 13.39

< 41.14

< 10.39

< 41.85 2004080 FISHDOWN 7/27/2004

< 15.45

< 9.88

< 29.67

< 16.51

< 28.08 2004080 FISHDOWN GG 7/27/2004 20.53

< 18.56

< 28.68

< 19.72

< 47.03 130 150 CS-134 CS-137

< 13.39

< 16.99

< 14.39

< 13.85

< 17.15

< 16.35

< 17.08

< 16.52 GG - indicates duplicate sample.

56

Table 7.1 Sample Type: Food Products Analysis: Iodine-1 3 1 and Gamma Isotopic Units: pCiikg VEGETATION SAMPLES (GAMMA) - GGNS LLD (pCi/kg)

LAB ID 2004002 1 20040022 20040347 20040348 20040349 20040350 20040705 20040706 2004 1077 2004 1078 LOCATION VFG-CONT VE G-J VEG-CONT VE G-J VEG-CONT GG VE G-J GG VEG-CONT VEG-J VEG-CONT VEG-J DATE 11712004 11712004 41612004 41612004 41612004 41612004 71612004 71712004 10/512004 101512004 60 1-131

< 56.09

< 48.72

< 47.02 i

42.40

< 59.43

< 43.54

< 59.26

< 51.88

< 40.71

< 35.84 60 CS-134

< 36.70

< 36.09

< 45.09

< 51.55

< 45.58

< 34.04

< 37.94

< 36.63

< 35.85

< 42.12 80 CS-137

< 54.30

< 47.60

< 48.00

< 51.10

< 54.41

< 17.35

< 34.41

< 38.78

< 31.02

< 36.54 GG - indicates duplicate sample.

57

Table 8.1 Sample Type: Special Samples Analysis: Gamma Isotopic Units: pCiikg ECIAL VENISON SAMPLES (GAMMA) - GGNS LLD (pCiikg) 130 130 260 130 260 LAB SAMPLE ID DATE MN-54 CO-58 FE-59 CO-60 ZN-65 2004109 VENISON 10/8/2004

< 11.93

< 10.61

< 34.19

< 18.46

< 31.71 ECIAL VEGETATION SAMPLES (GAMMA) - GGNS LLD (pCi/kg) 60 LAB ID LOCATION DATE 1-131 20040023 VEG-SPECIAL 1/7/2004

< 51.80 20040351 VEG-SPECIAL 4160 004

< 57.65 20040352 VEG-SPECIAL GG 41612004

< 33.13 20040707 VE,G-SPECIAL 7/7/2004

< 59.43 2004 1079 VEG-SPECIAL 10/5/2004

< 24.40 60 CS-134

< 35.81

< 57.09

< 25.68

< 38.29 18.70 130 150 CS-134 CS-137

< 11.41

< 11.13 80 CS-137

< 32.78

< 54.30

< 30.59

< 46.91

< 31.52 GG - indicates duplicate sample.

58

Table 9.1 Sample Type: Interlaboratory Comparison Analysis: Gross Beta, Tritium, Iodine-1 3 1 and Gamma Isotopic Analysis 1-1 31 BETA CR-51 MN-54 CO-58 FE-59 CO-60 ZN-65 1-1 31 CS-134 CS-137 CE-141 H-3 BETA CR-51 MN-54 CO-58 FE-59 CO-60 ZN-65 CS-134 cs-137 CE-141 CR-51 MN-54 CO-58 FE-59 CO-60 ZN-65 CS-134 CS-137 CE-141 Sample Type (units)

Known RBS Value value 81.9 84 286 251 250 234 77.4 84.3 50.8 46.3 48.9 55.3 189 198 109 107 84.3 87.0 111 109 171 176 172.00 181 12000 11685 67.7 66.7 129 115 105 104.7 54.8 55.5 53.0 56.4 72.5 72.3 103 97.1 55.8 50.6 124 117 145.0 143 0.348 0.293 0.252 0.264 0.132 0.128 0.127 0.140 0.174 0.174 0.248 0.264 0.134 0.130 0.403 0.426 0.348 0.352 Charcoal Cartridge (pcilfilter)

Water (pcilliter)

Air Filter

( pC ilfil ter)

Sediment (pCilgram)

Analytics #

E4171-125 E4170-I 25 E4169-I 25 E4242-125 E4240-125 E4243-125 E4241-125 Date 611 712004 611 712004 611 712004 911 612004 911 612004 911612004 911 612004 RANGE 0.361 1

-1.43 0.028

-1.09 0.142 1.55 0.91 6

-1.52 0.465 2.28 0.725 0.86 0.188

-0.26 0.108 0.55 0.841

-0.36 0.319 0.51 0.069 0.94 0.61 8

-0.45 0.224

-0.26 0.174

-1.83 0.458

-0.05 0.338 0.23 0.614 1.12 0.256

-0.05 0.807

-0.99 0.241

-1.60 0.191

-1.02 0.143

-0.20 0.244

-2.72 0.424 0.82 0.141

-0.52 0.492 1.77 0.558 0.03 0.339 I.09 0.333

-0.52 0.485 1.oo 0.132 0.20 0.424 59

Table 9.1 Sample Type: Interlaboratory Comparison Analysis: Gross Beta, Tritium, Iodine-13 1 and Gamma Isotopic Date Analysis Known RBS Value RBS N-DEV Value 611 7/2004 CR-51 228 251 1.72 MN-54 70.5 74.0 0.86 CO-58 46.2 46.0

-0.07 FE-59 44.5 44.4

-0.04 Sample Type (units)

Milk (pcilliter)

RBS N-RANGE 0.181 0.335 0.384 1.818 Analytics #

E4172-225 NOTES:

(a) The known value as determined by Analytics.

(b) The normalized deviation from the known value is computed from the deviation and the standard error of the mean; k2.00 is the warning limit, and 23.00 is the control limit. This is a measure of accuracy of the analytical methods.

(c) The normalized range is computed from the mean range, the control limit, and the standard error of the range;

+2.000 is the warning limit and +3.000 is the control limit. This is a measure of precision of the analytical methods.

60

Table 9.1 Sample Type: Interlaboratorv Comparison Analysis: Gross Beta, Tritium, Iodine-13 1 and Gamma Isotopic All results were within control limits.

61