ML16231A028

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Response to NRC Questions Related to Request for 20.2002 Disposal of Contaminated Water
ML16231A028
Person / Time
Site: Vermont Yankee File:NorthStar Vermont Yankee icon.png
Issue date: 08/11/2016
From: Silko T B
Entergy Corp
To: Jack Parrott
Reactor Decommissioning Branch
PARROTJ , 415-6634, T-8E47
References
SDG: 395827
Download: ML16231A028 (52)
v • d • e


Text

From: Silko, Thomas B. [1] Sent: Thursday, August 11, 2016 11:26 AM To: Parrott, Jack <Jack.Parrott@nrc.gov>

Subject:

[External_Sender] Response to NRC Questions dated 7-28-16 Jack, Based upon our conversation on Wednesday 8/3/16, VY agreed to provide a copy of the Part 61 analysis which was used to identify the radionuclide concentrations on the Torus water. Accordingly, please find attached a copy of the Part 61 report from GEL Laboratories, dated April 26, 2016.

In response to the Staffs second question, VY and the NRC discussed the process for sampling of material prior to making radioactive shipments. VY procedure V-EN-RW-102, Shipment of Radioactive Material, requires an isotopic be performed to ensure the material is appropriately classified per 10 CFR 61.55 requirements. The isotopic is performed on a sample of the material (in this case a water sample) prior to completing the shipment manifest. As such, VY is committed to sampling water prior to shipment to satisfy the requirements of 10CFR61.55.

In addition, Vermont Yankee commits to the following: Vermont Yankee will perform a representative sample prior to each shipment of water and will confirm that the radionuclide concentrations result in doses that are equal to or less than, the doses delineated within the Summary of Project Alternative Disposal Dose Results, in our June 28, 2016 letter (BVY 16-021; ADAMS Accession No. ML16182A035).

For example, the above could be satisfied in the following manner: A representative sample is taken prior to a shipment and the radionuclide concentrations are verified to be equal to or less than those concentrations shown on the Data Input Worksheet, of our June 28, 2016 letter. An alternative method to be used, such as when a radionuclide is identified as being slightly above the concentrations (while others may be lower), then sample radionuclide concentrations would be input into the Site Specific Dose Assessment Methodology (SSDA) used in our June 28, 2016 letter and the dose consequences verified to be equal to or less than that delineated within the Summary of Project Alternative Disposal Dose Results.

Please let me know if there are any further questions. Thank You. Tom Silko (802) 451-3166

April 26, 2016

Mr. Mark Vandale Entergy Nuclear Operations, Inc., VY 530 Governor Hunt Road PO Box 250 Vernon, Vermont 05354

Re: Vermont Yankee Part 61 Work Order: 395827

Dear Mr. Vandale:

GEL Laboratories, LLC GEL appreciates the opportunity to provide the enclosed analytical results for the samples we received on April 21, 2016. This original data report has been prepared and reviewed in accordance with GEL's standard operating procedures.

Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at 843 556-8171, ext. 4504.

Sincerely,PM_SIGN_HEREErin TrentProject ManagerPurchase Order: 10287833 Enclosures Table of ContentsCase Narrative......................................................................................1Chain of Custody..................................................................................3 Laboratory Certifications......................................................................7 Radiological Analysis...........................................................................9Case Narrative............................................................................10 Sample Data Summary...............................................................33 Quality Control Summary..........................................................37 Case NarrativePage 1 of 49 Case Narrative for Vermont Yankee, Entergy Nuclear Operations Inc. SDG: 395827 April 26, 2016 Laboratory Identification:

GEL Laboratories LLC 2040 Savage Road Charleston, South Carolina 29407 843 556-8171 Summary Sample Receipt The sample arrived at GEL Laboratories LLC, Charleston, South Carolina on April 21, 2016 foranalysis. Chain of Custody form did not contain a relinquished signature. All sample containers arrived without any visible signs of tampering or breakage. There are no additional comments concerning sample receipt. Sample Identification The laboratory received the following sample: Laboratory IDClient ID395827001Torus Water #2Case Narrative Sample analyses were conducted using methodology as outlined in GEL Laboratories, LLC GELStandard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package. Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody andSupporting Documentation, and data from the following fractions: Radiochemistry.

PM_SIGN_HEREErin Trent Project ManagerPage 2 of 49 Chain of CustodyPage 3 of 49 Page 4 of 49 Page 5 of 49 Page 6 of 49 LaboratoryCertificationsPage 7 of 49 StateCertificationAlaskaArkansasCLIACalifornia ColoradoConnecticutDelawareDoD ELAP/ ISO17025 A2LAFlorida NELAPForeign Soils PermitGeorgiaGeorgia SDWAHawaiiIdaho ChemistryIdaho RadiochemistryIllinois NELAPIndianaKansas NELAPKentucky SDWAKentucky WastewaterLouisiana NELAPLouisiana SDWAMarylandMassachusettsMichiganMississippiNebraskaNevadaNew Hampshire NELAPNew Jersey NELAPNew MexicoNew York NELAPNorth CarolinaNorth Carolina SDWANorth DakotaOklahomaPennsylvania NELAPS.Carolina RadchemSouth Carolina ChemistryTennesseeTexas NELAPUtah NELAPVermontVirginia NELAPWashingtonWest VirginiaUST-011088-065142D09040462940 SC00012PH-0169SC000122567.01E87156P330-15-00283, P330-15-00253SC00012967SC00012SC00012SC00012200029C-SC-01E-10332901299012903046 (AI33904)LA160006270M-SC0129976SC00012NE-OS-26-13SC000122016-1205415SC002SC000121150123345709R-158990468-004851012000210120001TN 02934T104704235-16-11SC000122016-20VT87156460202C780997404List of current GEL Certifications as of 26 April 2016Page 8 of 49 Radiological AnalysisPage 9 of 49 Case NarrativePage 10 of 49 Radiochemistry Technical Case Narrative Vermont Yankee, Entergy Nuclear Operations Inc. NTRG SDG #: 395827 Method/Analysis Information Product: Alphaspec Pu242, LiquidAnalytical Method: DOE EML HASL-300, Pu-11-RC ModifiedAnalytical Batch Number: 1562629Sample IDClient ID395827001 Torus Water #21203535939Method Blank MB1203535941Laboratory Control Sample LCS1203535940395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-011 REV# 26. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Page 11 of 49 Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts Sample 395827001 Torus Water #2 was recounted due to a suspected false positive. The recount is reported. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Alphaspec Am241, Cm, LiquidAnalytical Method: DOE EML HASL-300, Am-05-RC ModifiedAnalytical Batch Number: 1562630Sample IDClient ID395827001 Torus Water #21203535946Method Blank MB1203535948Laboratory Control Sample LCS1203535947395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance withPage 12 of 49 GL-RAD-A-011 REV# 26. Calibration Information: Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Page 13 of 49 Method/Analysis Information Product: Alphaspec Np, LiquidAnalytical Method: ASTM C 1476-00 ModifiedAnalytical Batch Number: 1562631Sample IDClient ID395827001 Torus Water #21203535949Method Blank MB1203535951Laboratory Control Sample LCS1203535950395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-032 REV# 20. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis Page 14 of 49 None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Gammaspec, Gamma, Liquid Standard ListAnalytical Method: EPA 901.1Analytical Batch Number: 1561698Sample IDClient ID395827001 Torus Water #21203533384Method Blank MB1203533386Laboratory Control Sample LCS1203533385395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 25. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met. Page 15 of 49 Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples meet the required acceptance limits with the following exceptions: Refer to Data Exception Report DER.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. The following DER was generated for this SDG: DER 1513408 was generated due to RDL less than MDA. The following RDLs in sample 395827001 were not achieved: Cs-134, Fe-59, Nb-95 and Zr-95. The following RDLs in DUP 1203533385 were not achieved: Cs-134, Fe-59, Nb-95 and Zr-95. Samples did not meet the required detection limit due to high sample activity. Reporting results.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Page 16 of 49 Product: Gamma I129, LiquidAnalytical Method: DOE EML HASL-300,I-01 ModifiedAnalytical Batch Number: 1562602Sample IDClient ID395827001 Torus Water #21203535843Method Blank MB1203535846Laboratory Control Sample LCS1203535844395827001Torus Water #2 Sample Duplicate DUP1203535845395827001Torus Water #2 Matrix Spike MSThe samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-006 REV# 21. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Page 17 of 49 Miscellaneous Information: Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Gamma Ni59, LiquidAnalytical Method: DOE RESL Ni-1Analytical Batch Number: 1562693Sample IDClient ID395827001 Torus Water #21203536149Method Blank MB1203536151Laboratory Control Sample LCS1203536150395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 17. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Page 18 of 49 Quality Control QC Information: Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: GFPC, Sr89&Sr90, LiquidAnalytical Method: EPA 905.0 Modified/DOE RP501 Rev. 1 ModifiedAnalytical Batch Number: 1562716Sample IDClient IDPage 19 of 49 395827001 Torus Water #21203536197Method Blank MB1203536199Laboratory Control Sample LCS1203536198395827001Torus Water #2 Sample Duplicate DUPThe samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 17. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Recounts Sample 1203536198 Torus Water #2DUP was recounted due to a suspected total strontium false positive. The recount is reported. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG. Page 20 of 49

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Pu241, LiquidAnalytical Method: DOE EML HASL-300, Pu-11-RC ModifiedAnalytical Batch Number: 1562632Sample IDClient ID395827001 Torus Water #21203535952Method Blank MB1203535954Laboratory Control Sample LCS1203535953395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 16. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Page 21 of 49 QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts Samples 1203535952 MB, 1203535953 Torus Water #2DUP and 395827001 Torus Water #2 were recounted due to high MDCs. The recounts are reported. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Fe55, LiquidAnalytical Method: DOE RESL Fe-1, ModifiedAnalytical Batch Number: 1562672Sample IDClient ID395827001 Torus Water #21203536076Method Blank MB1203536078Laboratory Control Sample LCS1203536077395827001Torus Water #2 Sample Duplicate DUPPage 22 of 49 The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 12. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Page 23 of 49 Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Ni63, LiquidAnalytical Method: DOE RESL Ni-1, ModifiedAnalytical Batch Number: 1562678Sample IDClient ID395827001 Torus Water #21203536092Method Blank MB1203536094Laboratory Control Sample LCS1203536093395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 17. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Page 24 of 49 Technical Information: Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Tc99, LiquidAnalytical Method: DOE EML HASL-300, Tc-02-RC ModifiedAnalytical Batch Number: 1562683Sample IDClient ID395827001 Torus Water #21203536111Method Blank MB1203536113Laboratory Control Sample LCS1203536112395827001Torus Water #2 Sample Duplicate DUP The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-059 REV# 4. Page 25 of 49 Calibration Information: Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples meet the required acceptance limits with the following exceptions: Refer to Data Exception Report DER.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts Samples were recounted due to high relative percent difference/relative error ratio. The recount results are similar to the original results. Original results are reported. Miscellaneous Information:

Data Exception DER Documentation A data exception report DER 1517546 was generated for samples in this SDG/batch. DER 1517546 was generated due to Failed RPD for DUP. 1. Sample 395827001 and duplicate 1203536112 do not meet the relative percent difference requirement or the relative error ratio requirement due to the matrix of the sample. 1.

Reporting results.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Page 26 of 49 Method/Analysis Information Product: LSC, Tritium Dist, LiquidAnalytical Method: EPA 906.0 ModifiedAnalytical Batch Number: 1562687Sample IDClient ID395827001 Torus Water #21203536126Method Blank MB1203536129Laboratory Control Sample LCS1203536127395827001Torus Water #2 Sample Duplicate DUP1203536128395827001Torus Water #2 Matrix Spike MSThe samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 21. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples meet the required acceptance limits with the following exceptions: The Matrix Spike 1203536128 Torus Water #2MS did not meet recovery requirements due to the sample activity being greater than five times the spiked nominal concentration.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Page 27 of 49 Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts Sample 1203536129 LCS was recounted due to low recovery. The recount is reported. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments The matrix spike, 1203536128 Torus Water #2MS, aliquot was reduced to conserve sample volume. Qualifier Information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint C14, LiquidAnalytical Method: EPA EERF C-01 ModifiedAnalytical Batch Number: 1562691Sample IDClient ID395827001 Torus Water #21203536141Method Blank MB1203536144Laboratory Control Sample LCS1203536142395827001Torus Water #2 Sample Duplicate DUP1203536143395827001Torus Water #2 Matrix Spike MS The samples in this SDG were analyzed on an "as received" basis.

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure SOP. The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 15. Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Page 28 of 49 Standards Information Standard solutions for these analysis are NIST traceable or verified with a NIST traceable standard and used before the expiration dates.

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards. Quality Control QC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

QC Information All of the QC samples met the required acceptance limits.

Designated QC The following sample was used for QC: 395827001 Torus Water #2. Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Recounts None of the samples in this sample set were recounted. Miscellaneous Information:

Data Exception DER Documentation Data exception reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A data exception report DER was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Sample-Specific MDA/MDC The MDA/MDC reported on the certificate of analysis is a sample-specific MDA/MDC.

Additional Comments Additional comments were not required for this sample set. Qualifier Information Manual qualifiers were not required.

Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Page 29 of 49 GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.comVERM001 Vermont Yankee, Entergy Nuclear Operations Inc.Client SDG: 395827 GEL Work Order: 395827Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with GEL Laboratories LLCstandard operating procedures. Please direct any questions to your Project Manager, Erin Trent.Reviewed by Sample(s) Contained within this report:395827001Lab Sample IDClient Sample IDSample DescriptionTorus Water #2N/ACollected04/11/2016 09:10Signature:Name:Date:Title:05 MAY 2016Theresa AustinGroup LeaderPage 30 of 49 1513408DER Report No.:1Revision No.:Spencer CollinsOriginator's Name:22-APR-16Shenise Gerideau Data Validator/Group Leader:22-APR-16Instrument Type:Client Code:Quality Criteria:GAMMA SPECTROMETERSpecificationsVERMType:ProcessDivision:RadiochemistryMo.Day Yr.

22-APR-16GEL Laboratories LLCForm GEL-DERDATA EXCEPTION REPORT DER Disposition:Samples did not meet the required detection limit due to high sample activity. Reporting results. Specification and Requirements Exception

Description:

The following RDLs in sample 395827001 were not achieved: Cs-134, Fe-59, Nb-95 and Zr-95.

The following RDLs in DUP 1203533385 were not achieved: Cs-134, Fe-59, Nb-95 and Zr-95. Application Issues:RDL less than MDABatch ID:1561698Test / Method:

EPA 901.1LiquidMatrix Type:See Below Sample Numbers:Potentially affected work order(s)(SDG):395827Page 31 of 49 1517546DER Report No.:2Revision No.:Elizabeth KrouseOriginator's Name:05-MAY-16Lyndsey Pace Data Validator/Group Leader:05-MAY-16Instrument Type:Client Code:Quality Criteria:LSCSpecificationsVERMType:ProcessDivision:RadiochemistryMo.Day Yr.

05-MAY-16GEL Laboratories LLCForm GEL-DERDATA EXCEPTION REPORT DER Disposition:1. Reporting results. Specification and Requirements Exception

Description:

1. Sample 395827001 and duplicate 1203536112 do not meet the relative percent difference requirement or the relative error ratio requirement due to the matrix of the sample.Application Issues:Failed RPD for DUPBatch ID:1562683Test / Method:

DOE EML HASL-300, Tc-02-RCModifiedLiquidMatrix Type:See Below Sample Numbers:Potentially affected work order(s)(SDG):395827Page 32 of 49 Sample Data SummaryPage 33 of 49 GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Note(s):1. Calculated MDAs are a-posteriori values at the 95% confidence level.2. Activity is reported on a dry weight basis unless otherwise indicated in the case narrativeand is decay corrected to the sample collect date.

3. Results are statistically positive at the 95% confidence level. (activity is greater than or equal to the two sigmauncertainty) U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.10 CFR Part 50/61 Certificate of AnalysisGEL Sample ID:Matrix:Geometry Received:Client:Collect Date:Receive Date:Client Sample ID:395827001WaterVermont Yankee, Entergy Nuclear OperatioApril 11, 2016April 21, 2016Torus Water #2Report Date:May 05, 2016AnalyteRun DateActivityMDAQualifier2 SigmaUncertaintyRL Alpha SpecGamma SpecH-3C-14Fe-55Ni-63Sr-89Sr-90Tc-99Pu-241Np-237Pu-238Pu-239/240Pu-242Am-241Cm-242Cm-243/244Be-7Na-22K-40Cr-51Mn-54Fe-59Co-56Co-57 Co-58Co-60Ni-59Zn-65Y-88Zr-95Nb-94Nb-95Ru-106Ag-110mSn-11304/29/1605/03/1604/28/1604/29/1605/02/1605/02/1605/03/1605/04/1604/30/1605/02/1605/02/1605/02/1604/30/1604/30/1604/30/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/16 04/21/1604/21/1604/28/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/16 1.70E+06 1.49E+01 9.53E+01 7.94E+02 1.08E+00 3.31E-01 3.89E+03 7.38E+00 -1.66E-01 1.96E-02 4.85E-02 1.91E-01 4.31E-02 0.00E+00 -5.11E-03 3.92E+01 6.07E+00 1.14E+01 3.07E+01 4.71E+02 2.87E+01 7.28E+00 3.24E+00 9.00E+01 2.07E+04 5.85E+00 1.95E+03 -1.32E+00 2.37E+01 -7.62E+00 6.97E+00 3.19E+01 -4.46E+00 9.02E+00 3.33E+04 2.41E+01 6.05E+01 7.12E+01 1.29E+00 9.80E-01 9.37E+01 1.13E+01 3.14E-01 2.14E-01 2.13E-01 2.99E-01 7.39E-02 4.66E-02 4.41E-02 9.40E+01 7.93E+00 5.16E+01 9.82E+01 2.43E+01 3.55E+01 1.52E+01 7.66E+00 2.06E+01 7.10E+01 6.40E+00 6.85E+01 5.08E+00 2.40E+01 1.13E+01 1.34E+01 1.04E+02 2.14E+01 1.28E+01 1.75E+03 4.08E+01 8.07E+01 7.04E+01 2.18E+00 2.66E+00 4.26E+01 1.91E+01 9.68E-01 4.50E-01 3.86E-01 4.10E-01 6.47E-02 6.93E-02 1.02E-01 1.59E+02 1.35E+01 8.56E+01 1.69E+02 2.38E+01 6.01E+01 2.61E+01 1.28E+01 2.46E+01 1.26E+01 1.01E+01 5.59E+01 8.67E+00 4.17E+01 1.84E+01 2.31E+01 1.72E+02 3.65E+01 2.19E+01 2.00E+03 5.00E+01 1.10E+02 5.30E+02 2.30E+01 3.50E+00 5.00E+01 2.50E+01 1.50E+01 1.50E+01 1.50E+01 1.50E+01 1.50E+01 1.50E+01 1.50E+01 1.50E+01 3.00E+01 1.50E+01 1.50E+01 2.00E+01 3.00E+01 3.00E+01 1.50E+013U33U U3UUUUUUUUUUUU3UUU33U3U UUUUUU12pCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/L pCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LUnitsPage 34 of 49 GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Note(s):1. Calculated MDAs are a-posteriori values at the 95% confidence level.2. Activity is reported on a dry weight basis unless otherwise indicated in the case narrativeand is decay corrected to the sample collect date.
3. Results are statistically positive at the 95% confidence level. (activity is greater than or equal to the two sigmauncertainty) U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.10 CFR Part 50/61 Certificate of AnalysisGEL Sample ID:Matrix:Geometry Received:Client:Collect Date:Receive Date:Client Sample ID:395827001WaterVermont Yankee, Entergy Nuclear OperatioApril 11, 2016April 21, 2016Torus Water #2Report Date:May 05, 2016AnalyteRun DateActivityMDAQualifier2 SigmaUncertaintyRLSb-124Sb-125I-129Cs-134Cs-136Cs-137Ba-133Ba-140Ce-139Ce-141Ce-144Nd-147Pm-144Pm-146Eu-152Eu-154Eu-155Ir-192Hg-203Tl-208Pb-210Pb-212Pb-214 Bi-212Bi-214Ra-228Ac-228Th-234U-235U-238Np-239Am-24104/21/1604/21/1604/27/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/16 04/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/1604/21/16 -3.65E+00 8.30E+00 -3.73E-02 -1.30E+01 5.93E+00 1.13E+03 -7.26E+00

-1.12E+01 -8.99E+00 -9.12E+00 3.42E+01 -8.63E+01 1.21E+00 4.46E+00 1.35E+01 1.78E+01 1.43E+01 -2.79E+00 8.62E+00 8.75E+00 9.04E+02 -1.47E+00

-6.77E+00

-6.90E+01 -1.64E+00 4.22E+01 4.22E+01 3.77E+02 -3.80E+01 3.77E+02 7.01E+01 -2.43E+01 1.09E+01 2.74E+01 8.59E-01 1.47E+01 3.45E+01 2.43E+01 1.32E+01 6.57E+01 8.66E+00 1.67E+01 5.98E+01 1.33E+02 1.14E+01 1.29E+01 2.86E+01 2.25E+01 3.04E+01 9.96E+00 1.07E+01 1.20E+01 1.07E+03 1.92E+01 2.15E+01 1.77E+02 2.21E+01 6.30E+01 6.30E+01 3.56E+02 5.95E+01 3.56E+02 7.43E+01 4.16E+01 1.88E+01 4.64E+01 1.51E+00 2.52E+01 5.84E+01 2.06E+01 2.09E+01 1.10E+02 1.42E+01 2.77E+01 9.96E+01 2.22E+02 1.88E+01 2.19E+01 4.91E+01 3.83E+01 5.10E+01 1.71E+01 1.86E+01 1.91E+01 1.84E+03 3.09E+01 3.65E+01 2.89E+02 3.64E+01 1.08E+02 1.08E+02 5.78E+02 9.77E+01 5.78E+02 1.32E+02 7.09E+01 2.00E+00 1.50E+01 1.80E+01UUUUU3UUUUUUUUUUUUUUUUU UUUU3,UU3,UUU12pCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/L pCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LUnitsPage 35 of 49 GEL LABORATORIES, LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com 10 CFR Part 50/61 Isotope Abundance ReportGEL Sample ID:Matrix:Client:Collect Date:Receive Date:Client Sample ID:395827001WaterVermont Yankee, Entergy Nuclear Operations Inc.April 11, 2016April 21, 2016Torus Water #2AnalyteActivity Alpha SpecGamma SpecNi-63Tc-99 H-3Cs-137Co-60Mn-54Zn-65 7.94E+02 3.89E+03 1.70E+06 1.13E+03 2.07E+04 4.71E+02 1.95E+03pCi/LpCi/L pCi/LpCi/LpCi/LpCi/LpCi/LUnits% Abundance 000.05 000.22 098.31 000.07 001.20 000.03 000.11Total Activity: 1.73E+06Total % Abundance: 100.00Page 36 of 49 Quality ControlSummaryPage 37 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Alpha Spec15626291562630Batch BatchPlutonium-238Plutonium-239/240 Plutonium-242Plutonium-238Plutonium-239/240 Plutonium-242Plutonium-238Plutonium-239/240 Plutonium-242Americium-241Curium-242Curium-243/244Americium-241Curium-242 Curium-243/244Americium-241Curium-242ParmnameMr. Mark VandaleContact:Entergy Nuclear Operations, Inc., VY530 Governor Hunt RoadVernon, Vermont May 5, 2016Report Date:Units pCi/LpCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/LpCi/LpCi/LpCi/LAnlstDateTimeMXS2MXS204/30/16 11:0304/30/16 11:0304/30/16 11:0504/30/16 11:0504/30/16 11:0804/30/16 11:05QC0.1320.08240.07630.04755.710.05450.0605-0.01350.02150.07650.000.02525.270.01446.220.0246-0.00542NOMSample0.01960.04850.1910.04310.00-0.00511RangeN/A N/A N/A(75%-125%)N/AN/AN/A(75%-125%)(75%-125%)QualUU UUUUU UUUU UUQC1203535940 395827001QC1203535941 QC1203535939 QC1203535947 395827001QC1203535948 QC1203535946 N/AN/AN/A16.6N/AN/AREC%11610794.14.94 4.936.61DUPLCSMBDUPLCS MB395827Workorder:PO Box 250UUUUU U+/-0.214

+/-0.213+/-0.299+/-0.0739+/-0.0466

+/-0.0441+/-0.142

+/-0.113+/-0.113+/-0.107+/-0.770

+/-0.108+/-0.0977

+/-0.0611+/-0.0828+/-0.101+/-0.055+/-0.0707+/-0.623+/-0.0539+/-0.671+/-0.0949

+/-0.0468RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 1 of 12Page 38 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Alpha SpecRad Gamma Spec1562630156263115626321561698BatchBatchBatchBatchCurium-243/244Neptunium-237Neptunium-237 Neptunium-237Plutonium-241Plutonium-241Plutonium-241Actinium-228Americium-241Antimony-124 Antimony-125 Barium-133 Barium-140Beryllium-7Bismuth-212 Bismuth-214 Cerium-139ParmnameUnits pCi/LpCi/LpCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LAnlstDateTimeMXS2MXS2MJH104/30/16 10:5704/30/16 10:59 04/30/16 10:5705/04/16 15:2505/03/16 14:1905/04/16 13:5404/22/16 06:34QC0.006290.22591.80.0941-1.65216-1.4-83.9-30.21.84-5.76-11.255.051.4 27.2 1.581.86NOMSample-0.1667.3842.2-24.3-3.658.30-7.26

-11.239.2-69-1.64-8.99RangeN/A(75%-125%)N/A(75%-125%)N/A N/AN/A N/A N/A N/AN/AN/A N/A N/AQualUUUUUUUUU U

U U

UUUQC1203535950 395827001QC1203535951 QC1203535949 QC1203535953 395827001QC1203535954 QC1203535952 QC1203533385 395827001N/AN/AN/AN/A N/A N/A N/AN/AN/A N/A N/A N/AREC%10311189.3194DUPLCSMBDUPLCSMBDUP395827Workorder:UUUU U

U UUU U

U U+/-0.314+/-11.3+/-63.0+/-41.6

+/-10.9

+/-27.4

+/-13.2+/-65.7+/-94.0+/-177+/-22.1

+/-8.66+/-0.0657+/-0.654+/-6.94+/-0.422+/-7.13+/-27.4

+/-7.62+/-95.8+/-50.5

+/-15.8

+/-41.9

+/-20.8+/-103

+/-144

+/-257+/-34.0

+/-12.7RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 2 of 12Page 39 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma Spec1561698BatchCerium-141Cerium-144Cesium-134Cesium-136 Cesium-137 Chromium-51 Cobalt-56Cobalt-57Cobalt-58 Cobalt-60 Europium-152 Europium-154Europium-155Iridium-192 Iron-59 Lead-210 Lead-212Lead-214Manganese-54 Mercury-203 Neodymium-147 Neptunium-239ParmnameUnits pCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/LAnlstDateTimeMJH104/22/16 06:34QC-1216.8-8.32

-39.411503.78 5.84 6.90 89.120400-7.8117.7 20.9-2.06-55.9-4140.3657.394810.957-52.1-65.9NOMSample-9.1234.2-135.93113030.7 7.28 3.24 90.02070013.5 17.8 14.3-2.7928.7904-1.47

-6.774718.62-86.370.1RangeN/A N/AN/AN/A(0%-20%)N/A N/AN/A(0% - 100%)(0%-20%)N/AN/AN/AN/A N/A N/A N/AN/A(0%-20%)N/AN/A N/AQualU U

UUUU UUU UUU U

U UUU UN/AN/AN/A N/A2.28N/AN/AN/A0.9821.55N/AN/AN/A N/A N/A N/AN/AN/A1.95N/A N/AN/AREC%395827Workorder:U UU UUUUUUU U

U UUUUUU+/-16.7

+/-59.8+/-14.7

+/-34.5

+/-24.3

+/-98.2+/-15.2+/-7.66

+/-20.6

+/-71.0

+/-28.6+/-22.5+/-30.4

+/-9.96

+/-35.5+/-1070+/-19.2

+/-21.5

+/-24.3

+/-10.7+/-133+/-74.3+/-24.6+/-87.5+/-22.6

+/-53.9

+/-36.7+/-147+/-23.3

+/-12.0

+/-28.7+/-103+/-42.7+/-31.6+/-44.2

+/-15.4

+/-53.1+/-1020+/-26.2

+/-32.0

+/-36.4

+/-15.9+/-208+/-115RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 3 of 12Page 40 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma Spec1561698BatchNiobium-94Niobium-95Potassium-40Promethium-144 Promethium-146 Radium-228 Ruthenium-106Silver-110mSodium-22 Thallium-208 Thorium-234 Tin-113Uranium-235Uranium-238 Yttrium-88 Zinc-65 Zirconium-95Actinium-228Americium-241 Antimony-124 Antimony-125 Barium-133ParmnameUnits pCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/LAnlstDateTimeMJH104/22/16 06:3404/22/16 06:39QC14.9 22.9 16.1 1.11-18.9

-83.913640.9 6.22-15.11550.62216.4155-5.551870-5.381223970015.9-15727.6NOMSample-7.626.97 11.4 1.214.4642.2 31.9-4.466.078.753779.02-38377-1.32195023.7RangeN/AN/AN/AN/A N/A N/A N/AN/AN/A N/A N/A N/AN/AN/A N/A(0%-20%)N/A(75%-125%)QualU U

UUU U

U UUU U

U UUUUUUU UQC1203533386 N/AN/AN/A N/A N/A N/AN/AN/A N/A N/A N/AN/AN/A N/A N/A3.98N/AREC%11534400LCS395827Workorder:UUU U

U UUU U

U UUU U

UU+/-11.3+/-13.4+/-51.6

+/-11.4

+/-12.9

+/-63.0+/-104+/-21.4

+/-7.93

+/-12.0+/-356+/-12.8

+/-59.5+/-356+/-5.08

+/-68.5+/-24.0+/-16.4

+/-23.5+/-69.1

+/-16.5

+/-19.7

+/-95.8+/-159+/-33.1

+/-11.1

+/-19.0+/-425+/-19.4

+/-85.7+/-425+/-7.20

+/-96.7+/-36.8+/-399+/-1740+/-46.1+/-241RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 4 of 12Page 41 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma Spec1561698BatchBarium-140Beryllium-7Bismuth-212 Bismuth-214 Cerium-139 Cerium-141Cerium-144Cesium-134 Cesium-136 Cesium-137 Chromium-51Cobalt-56Cobalt-57 Cobalt-58 Cobalt-60 Europium-152Europium-154Europium-155 Iridium-192 Iron-59 Lead-210ParmnameUnits pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/LAnlstDateTimeMJH104/22/16 06:39QC153-119540-68.543.7-75.7-26823.7-66.413700-19981.9267-46.914200-10143.314657.9 45.34.51E+05NOMSampleRange(75%-125%)(75%-125%)QualUUUU U

U UUUUUUUUUU UREC%10210313500 13800395827Workorder:+/-103+/-282+/-768+/-1080+/-142+/-66.4+/-112

+/-478+/-94.4+/-158

+/-354+/-630+/-88.7+/-108+/-87.5+/-408

+/-237+/-136

+/-300+/-74.3+/-199+/-50700RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 5 of 12Page 42 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma Spec1561698BatchLead-212Lead-214Manganese-54Mercury-203 Neodymium-147 Neptunium-239 Niobium-94Niobium-95Potassium-40 Promethium-144 Promethium-146 Radium-228Ruthenium-106Silver-110m Sodium-22 Thallium-208 Thorium-234Tin-113Uranium-235 Uranium-238 Yttrium-88 Zinc-65ParmnameUnits pCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/LAnlstDateTimeMJH104/22/16 06:39QC-41.7

-66.522.0-25.5-2593569.74 28.1-26.76.91-31.7122 16678.214.5-13.8-1950-66.5147-1950-3.091030NOMSampleRangeQualUU UUU U

U UUU U

U UUU U

U UUU UREC%395827Workorder:+/-143+/-183+/-87.1+/-77.1+/-538

+/-781+/-68.8

+/-77.3+/-253+/-68.5+/-124+/-399+/-727

+/-140+/-47.5

+/-73.8+/-5510+/-108

+/-479+/-5510+/-28.7+/-363RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 6 of 12Page 43 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma Spec1561698BatchZirconium-95Actinium-228Americium-241Antimony-124 Antimony-125 Barium-133 Barium-140Beryllium-7Bismuth-212 Bismuth-214 Cerium-139 Cerium-141Cerium-144Cesium-134 Cesium-136 Cesium-137 Chromium-51Cobalt-56Cobalt-57 Cobalt-58 Cobalt-60 Europium-152ParmnameUnits pCi/LpCi/LpCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/LAnlstDateTimeMJH104/22/16 06:34QC31.9-7.16

-1.73-0.03870.9600.347-0.895-8.8614.21.92-0.5332.38 5.240.137-1.240.1341.840.706-0.1720.6801.03 1.98NOMSampleRangeQualUUUUU U

U U

UUU U

U UUU U

U UUU UQC1203533384 REC%MB395827Workorder:+/-141+/-8.38

+/-9.55

+/-2.87

+/-4.35

+/-2.37+/-6.51+/-12.3

+/-25.1

+/-4.84

+/-1.59+/-2.53+/-10.6

+/-1.84

+/-2.06

+/-1.80+/-13.4+/-1.49

+/-1.53

+/-1.64

+/-1.93RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 7 of 12Page 44 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma Spec1561698BatchEuropium-154Europium-155Iridium-192 Iron-59 Lead-210 Lead-212Lead-214Manganese-54 Mercury-203 Neodymium-147 Neptunium-239Niobium-94Niobium-95 Potassium-40 Promethium-144 Promethium-146Radium-228Ruthenium-106 Silver-110m Sodium-22 Thallium-208ParmnameUnits pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/L pCi/L pCi/LpCi/LpCi/L pCi/LAnlstDateTimeMJH104/22/16 06:34QC-0.771-2.76-0.3172.12-1321.26 1.93-0.121.53-3.95-0.573

-0.765-0.074314.30.643 0.158-7.16

-15.7-0.238

-0.342-2.26NOMSampleRangeQualU UUU U

U UUU U

U UUU U

U UUU U

UREC%395827Workorder:+/-4.87+/-4.66+/-6.43

+/-1.62

+/-2.97+/-275+/-4.97

+/-5.83

+/-1.62

+/-1.59

+/-11.0+/-14.9+/-1.67

+/-1.40

+/-24.8

+/-1.79+/-2.18+/-8.38

+/-18.9

+/-1.98

+/-1.62+/-2.16RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 8 of 12Page 45 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gamma SpecRad Gas Flow1561698156260215626931562716BatchBatchBatchBatchThorium-234Tin-113Uranium-235Uranium-238 Yttrium-88 Zinc-65 Zirconium-95Iodine-129Iodine-129Iodine-129 Iodine-129Nickel-59Nickel-59 Nickel-59Strontium-89Strontium-90Strontium-89ParmnameUnits pCi/LpCi/L pCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/L pCi/L pCi/LpCi/LpCi/L pCi/LpCi/LpCi/LpCi/LAnlstDateTimeMJH1MJH1CXS7KSD104/22/16 06:34 04/27/16 09:2004/27/16 11:0404/27/16 09:19 04/27/16 09:2004/28/16 15:3604/29/16 06:45 04/28/16 15:3605/02/16 16:2405/02/16 16:24QC60.30.153-0.38860.3-0.7980.806-1.70.38850.2-0.1757.53.143722.87-1.39-0.222550NOMSample-0.0373-0.03735.851.080.331RangeN/A(75%-125%)(75%-125%)N/A(75%-125%)N/AN/A(75%-125%)QualU U

UUU U

UUUUUUUQC1203535844 395827001QC1203535846 QC1203535843 QC1203535845 395827001QC1203536150 395827001QC1203536151 QC1203536149 QC1203536198 395827001QC1203536199 N/AN/AN/AN/AREC%96.411188.810552.052.0419522DUPLCSMBMSDUPLCSMBDUPLCS395827Workorder:UUUUU+/-0.859+/-0.859+/-6.40+/-1.29+/-0.980+/-140+/-2.10+/-13.5+/-140+/-1.85

+/-3.61+/-2.56+/-1.13+/-6.44+/-0.835+/-6.83+/-2.49+/-26.7

+/-5.02+/-1.93+/-1.22RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 9 of 12Page 46 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Gas FlowRad Liquid Scintillation1562716156267215626781562683 1562687BatchBatchBatchBatch BatchStrontium-90Strontium-89Strontium-90Iron-55Iron-55 Iron-55Nickel-63Nickel-63 Nickel-63Technetium-99Technetium-99 Technetium-99TritiumTritiumParmnameUnits pCi/L pCi/LpCi/LpCi/LpCi/L pCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LpCi/LAnlstDateTimeKSD1CXS7CXS7MYM1GXR105/02/16 16:2405/02/16 16:2704/28/16 23:2604/29/16 00:13 04/28/16 22:3904/29/16 14:5304/29/16 15:09 04/29/16 14:3705/03/16 15:1205/03/16 15:28 05/03/16 14:5504/29/16 23:1104/30/16 11:54QC445-1.50.11691.21440-42.58402090-6.46254841-11.41.72E+062410NOMSample95.379438901.70E+06Range(75%-125%)(0% - 100%)(75%-125%)(0%-20%)(75%-125%)(0%-20%)(75%-125%)(0%-20%)(75%-125%)QualUUUU UQC1203536197 QC1203536077 395827001QC1203536078 QC1203536076 QC1203536093 395827001QC1203536094 QC1203536092 QC1203536112 395827001QC1203536113 QC1203536111 QC1203536127 395827001QC1203536129 4.425.651751.36REC%8386.812497.71025361660 16908612350MBDUPLCSMBDUPLCS MBDUPLCS MBDUPLCS395827Workorder:+/-60.5+/-71.2

+/-93.7+/-33300+/-13.0+/-10.4+/-1.18+/-1.00+/-58.8+/-86.2

+/-58.1+/-71.1+/-101+/-37.6

+/-33.3+/-48.9

+/-24.1+/-33700+/-461*RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Page 10 of 12Page 47 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comRad Liquid Scintillation15626871562691Batch BatchTritiumTritiumCarbon-14Carbon-14 Carbon-14 Carbon-14ParmnameUnits pCi/LpCi/LpCi/LpCi/LpCi/L pCi/LAnlstDateTimeGXR1TXJ104/29/16 22:55 04/29/16 23:1305/03/16 17:2305/03/16 18:26 05/03/16 16:51 05/03/16 17:54QC1361.62E+0628.01310-4.591400NOMSample1.70E+0614.914.9Range(75%-125%)N/A(75%-125%)(75%-125%)QualUUUQC1203536126 QC1203536128 395827001QC1203536142 395827001QC1203536144 QC1203536141 QC1203536143 395827001The Qualifiers in this report are defined as follows:N/AREC%N/A103111471012601260MBMSDUPLCSMBMS395827Workorder:**<

>

BDFAH J

KLM MN/AN1 ND NJQR UAnalyte is a Tracer compound Result is less than value reported Result is greater than value reportedResults are either below the MDC or tracer recovery is lowFailed analysis.

Analytical holding time was exceeded Value is estimatedAnalyte present. Reported value may be biased high. Actual value is expected to be lower.Analyte present. Reported value may be biased low. Actual value is expected to be higher.

M if above MDC and less than LLD REMP Result > MDC/CL and < RDLRPD or %Recovery limits do not apply.See case narrative Analyte concentration is not detected above the detection limitConsult Case Narrative, Data Summary package, or Project Manager concerning this qualifierOne or more quality control criteria have not been met. Refer to the applicable narrative or DER.

Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.UU+/-33300+/-24.1+/-24.1+/-301+/-31600+/-24.9+/-47.0

+/-23.6

+/-49.8RPD%Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Uncertainty Notes:Counting Uncertainty is calculated at the 95% confidence level (1.96-sigma).Page 11 of 12Page 48 of 49 QC SummaryGEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.comParmnamePage 12 of 12Units AnlstDateTimeQCNOMSampleRangeQualREC%395827Workorder:UIUJUL X

Y^hGamma Spectroscopy--Uncertain identification Gamma Spectroscopy--Uncertain identification Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.

Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifierOther specific qualifiers were required to properly define the results. Consult case narrative.RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.

Preparation or preservation holding time was exceededN/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.

  • Indicates that a Quality Control parameter was not within specifications.

For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.RPD%Page 49 of 49

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