ML20237K545

Forwards Results of Nonradiological Chemistry Stds Insp Activities for All Region I Licensees for 1985 - 1986. Facility Identified by Codes 7 & 8

ML20237K545
Person / Time
Site:	FitzPatrick
Issue date:	08/12/1987
From:	Martin T NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I)
To:	Radford Converse POWER AUTHORITY OF THE STATE OF NEW YORK (NEW YORK
References
NUDOCS 8708190303
Download: ML20237K545 (2)

Text

.

i 2 AUG GBT j

l Docket No. 50-333-Power Authority of the State of New York j

James A. FitzPatrick Nuclear Power Plant j

1 ATTN..Mr. Radford-J.-Converse Resident: Manager P

O. Box 41' Lycoming, New York 13093 i

Gentlemen:

-l

Subject:

Results of Non-Radiological Chemistry Standards Inspection Activities for All Region I Licensees Routine safety inspections were conducted by this office during the period' 1985 to 1986 'at VSNRC. Region I licensees in the area of non-radiological water I

chemistry laboratory operations.

The purpose'of this report is to present results of all licensees inspected, as well as results of measurements made by Brookhaven. National Laboratory.

Each licensee is identified by a code.

Your.

codes'are.7, 8~.

No reply to this letter i.s required.

Sincerely, Oricinal Signed CL M Thomas T.

artin, Director j

Division of Radiation Safety anj Safeguards

(

Enclosure:

Combined Results of Non-radiological Standards Comparison Inspection Activities for Region I Licensees

+

'l l

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w OFFICIAL RECORD CCPY LTR RAD RESULTS - 0021.0.0 i

06/09/87 870E1190303 870812 PDR ADOCK 05000333 G

PDR Iii

12 AUG 19871 Power Authority of the State 2

of New York cc w/ enc 1:

L. W. Sinclair, President J. P. Bayne, First Executive Vice President and Chief Operations Officer A. Klausmann, Vice President - Quality Assurance and Reliability R. L. Patch, Quality Assurarice Superintendent George M. Wilverding, Chairman, Safety Review Committee Gerald C. Goldstein, Assistant General Counsel NRC Licensing Project Manager Dept. of Public Service, State of New York Public Document Room (POR)

Local Public Document Room (LPOR)

Nuclear Safety Information Center (NSIC)

NRC Resident Inspector State of New York bec w/ encl:

Region I Docket Room (with concurrences)

Management Assistant, ORMA (w/o enc 1)

Section Chief, ORP Robert J. Bores, DRSS l

R.

SS RI:0RSS IOS RI:0RSS R K SS Kottan/geb/mlb Zibulsky s i, k Bellamy Mar in f

/87 6/17/87

/ 2.f 87 6/S/87 6/ l 7

0FFICIAL RECORD COPY LTR RAD RESULTS - 0022.0.0 06/09/87 i

t U.S. NUCLEAR REGULATORY COMMISSION REGION I Combined Results of Nca-Radiological Standards Ccmparison Inspection Activities for

)

Region I Licensces Inspectors:

b Harvey Zibulsky Rhemist, Ef fibents Radiation Protection Secti

,JPfRPB,ORSS

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N James J. Kottan,/ Radiation Laboratory Specialist, Ef fluents Radiat'on Pr tion Section, EP&RPB, DRSS f

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AM M cA /

Approved By:

Valter ~J! Pascial., ChT6f, ~ Ef fluents Radiation ProtectionSecpion,EP&RPB,DRSS J

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i Details 1.

Introduction Region I has implemented an inspection program in the area of cer-radio-logical water chemistry.

As part of this inspection program, lfcensees are required to analyze test standards prepared by Brookhaven National Laboratory (BNL) for NRC Region I.

The data from the first rourd of this part of the inspection prcgram are now available from all power reactors in Region I and are presented here.

The data as presented permits each Region I nuclear power plant chemistry laboratory to compare its performance with all other Region I nuclear power plant laboratories.

The data for the BNL known values are alsb presented so that comparison of the average from all Region I sites to the known value may be mace. The data were taken from inspecticn reports, but are coded he-e.

The letter transmitting this repc-:

ide rtified the individual code (s) for each addressee.

Section 3.0 lists the inspection reports data were taken from.

The data are presented in ApperHix 8.

2.

Data Analysis The data were analjzed as follows.

1.

The analytical data from all Region I sites were entered irto a data base at BNL. Tre analytical data consisted of each if tensee's result for each analyte at each analyzed concentration.

2.

At each concentration a grand average and standard deviaticn were calculated using the data from all sites.

3.

A range consisting of the grand average plus or minus two standard deviations was established. Any values outside of this ra ge were considered outliers.

4.

A new grand average and standard deviation were calculated excluding f

the outliers determined in step 3.

5.

A range consisting of the grand average plus or minus two standard deviations was again established.

Any values outside this range were considered outliers.

(

6.

The above process was repeated until a range was obtained with no outliers. This range was used for the data comparison.

A sample calculation is presented in Appendix A.

I i

I i

.._________________-_w

O It must be recognized that the data used to generate the averages are not.

of equal weight.

For example, some laboratories were permitted to reanalyze the standards.if problems could be identified and corrected during the inspection. Also some of the BNL standards were diluted to

)

different final concentrations by the licensees prior to analysis to allow them to analyze within their calibration range.

The results were then normalized back to the original dilution in order to enable comparison.

In addition, a'll methods of analysis for a particular analyte were grouped together.

3.

Referencesi i

Site Docket No.

Inspection No.

Beaver Valley #1

' 50-334 85-07 Beaver Valley #2 50-412 86 Calvert Cliffs #1 50-317 86-08 Calvert Cliffs #2 50-318 86-08 t

-FitzPatrick 50-333 85-23 Ginna 50-244 85-14 Ct. Yankee 50-213 85-24 Hope Creek 50-354 85-59 Indian Pt. #2 50-247 86-07 Indian Pt. #3 50-286 86-04 Limerick 50-352 86-10 Maine Yankee 50-309 85-33 Millstone #1 50-245 86-04 l

Millstone #2 50-336 86-04 Millstone #3 50-423 86-13 Nine Mile Pt. #1 50-220 85-10 Oyster Creek 50-219 86-16 Peach Bottom #2 50-277 85-28 Peach Bottom #3 50-278 85-26 Pilgrim 50-293 85-23 Salem #1 50-272 86-03 Salem #2 50-311 86-03 Seabrook 50-443 86-22 Shoreham 50-322 86-11 l

Susquehanna #1 50-387 85-27 Susquehanna #2 50-388 85-22 Three Mile Island #1 50-289 85-17 Vermont Yankee 50-271 85-38 Yankee Atomic 50-29 85-21 i

_ _ _. _ _ - _ _ - _ -.. - _ _ _ _ _ _ _ - - _ _ _ =

/

-4 Appendix A Sample Calculation The chloride measurements at approximately 30 ppb were chosen for this example.

Step 1 The following data were in the BNL data base for chloride at approximately 30 ppb.

Site No.

Value (ppb)

Site No.

Value (ppb)

Site No.

Value (ppb) 1 30.7 16 27.1 31*

26.7 2

30 17 39.3 32*

71 1

3 30.2 18 28.8 33 not analyzed 4

24.3 19 28 5

30.9 20 29.3 i

6 30.9 21 23.3 7

32.7 22 28.9 8

38.3 23 not analyzed 9

32 24 30.7 10 34.2 25 not analyzed 11 37 26*

41.3 12 28.7 27 33 13 not analyzed 28 14 30.7 29 52

• normalized data

' 15*

43.35 30 29.7 Step 2 A grand average and standard deviation were calculated for all 28 values:

Grand average = 33.6804 I xi n

i Standard deviation = 9.5116 "I (xi-x)2

/z n-1 Step 3 l

From step two above, a range of 52.7036 - 14.6572 was established.

The value from site 32 was determined to be an outlier.

Step 4 j

A new grand average and standard deviation wsre calculated excluding the l

outlier determined in Step 3.

I l

grand average = 32.2981 (n=27) standard deviation - 6.1966 l

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Appendix A 1

Sample Calculation (continued)

Steps 5 g '.

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t From stepi4 above e ra'nge of 44.6914 - 19.9048 was established. -The value from site 29 is determined to be an outlier.

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'30.6417 3.8514 38.3444 - 22.9390 17 30.2652.

3.4571 37.1794 - 23.3510 8, 21 h'23

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21 30.2143 2.7368 35.6880 -'24.7406 4, 11' 19 30.1684 1.9542 34.0768 - 26.2600 10.

18 29.9444 1.7419 33.4283 ' 26.4605 None l

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41hus out of a. total 'of 28 values 10 were outliers.

The range of 33.4283 -

s' 26.4605, which contained no outliers, was used for final comparison.

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