ML20073S852

Rev 2 to Calculation 1961-2.2-001, Verification of Toxpuff & Toxevap Lotus 1-2-3 Spreadsheet

ML20073S852
Person / Time
Site:	Monticello
Issue date:	04/30/1993
From:	TENERA, L.P. (FORMERLY TENERA CORP.)
To:
Shared Package
ML20073S848	List: ML20073S846 ML20073S849 ML20073S852
References
1961-2.2-001, 1961-2.2-001-R02, 1961-2.2-1, 1961-2.2-1-R2, NUDOCS 9407060295
Download: ML20073S852 (70)

Text

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CAICULATION l 1 ICP.2J 13C.1: VALUATION Ven entk.n of TOYPUFT and 10\\tT AP 1 OT13174 SpreAb.c,et, l l oTIIER StiljlCT:

r CONT.1.D. No. 1961 2.2 ml PROJECT: _ Wikello Tcsk Cbeenkal 9uh No. ol' Silis.

69 [w d,.b.A 1td CLIENT: Nnctheni %tei ro ee PURPOSE / DESCRIPTION The purpose of this calculation is to define the methodology for analyzing the buildup of toxic chemical vapors in the Monticello Control Room (CR) as a result of an accidental spill in the area immediately surrounding the plant. Because the methodology is calculation-intensive, as well as being iterative in some aspects, this calculation also describes two LOTUS 1-2 3 (Version 3.1) spreadsheets (called TOXPUFF and TOXEVAP) developed as tools for the analysis process. Manual calculations are performed to verify each of the spreadsheets for an example chemical release.

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O_ TENERA SUBJECT Verificatinn of TO\\' PUTT nnd TOWVAP PREPARED BY s'

DATE 3/R/9L CHtcKro By M DATE LOTUS 12 3 Snreadsheets O

i PROJECT Mnnlittllo Tmle Chemical Studt PREL shfET OF CONTROLI.O NO.

1961 2,2-001 REV.

O sHtrT 2

or 64 sHttTs 1.0 PUe PO';C The purpose of this calculation is to descrite the prels, present esamtes, and verif y the correctness of two separate spreadsheets developed using Lotus (Version 3.1) to support the dstermination of inside control roam tonicity levels subsequent to e postulated chemical spiti.

The technical approach is identical to that imlemented in response to NURIG 0737, Requirement

!!!.D.3.4, for de*ermining toxic material release ef fects on control Room (cR) Habitability. Major essetions used in this modeling process, consistent with WUREG 0570, are noted throughout this calculation where appropriate.

Section 6.1 of 1 A ulculation verifles the 10XPUFF spreadsheet, which evaluates toalc chemical spill ef f ects on. sntrol Room operators where the spilled materiet is either a comrassed gas or a 11guld with a boiling point temerature at atmospheric pressure less than ancient terserature. As an eammle, a chlorine spilt f rom the Burlington Northern Line is modeled and evaluated. $tction 6.2 of this calculation verifles a spreadsheet that is a variation of the T0XPurr spreadsheet. This modified spreadsheet, called tortvAP, mdels the situation in which there is no initial puf f release, which occurs when the spilled chemical has a bolling point temerature (at atmospheric conditions) that exceeds the anblent temerature. In this verification, an emavle is constructed using a spilt f rom the Burlington korthern Line of (thyt Alcohol.

1.1 pad amyg The original CR Habitability study (Ref.1) used one of two models, consistent with WUREG*0570 (Ref.

2), to evaluate the rate of toalc chemical buildap in the CR subsequent to en accidental spilt outside the CR.

The rate of chemical buildap and subsegaent CR purging were modeled, in conjunction with the incapacitation nodels of WUR[G/CD1741 (Ref. 3), to determine how soon after the accidental spilt a CR operator might becone incapacitated. Model 1 was used f or comressed gas or liquid spills whose boiling point is below antalen temerature. M Ael 2 was used for liquid spills whose a

boiling point exceeds ancient teversture. Both models are presented in separate sections below.

Where identical techniques are i@lemented, the pode' is only described once, However, as two separate spreadsheets were developed, ena@tes are provided f or both nodels f or the purpose of verification.

2.0 MHHmol0CY The nethodology f or perf orming this study is aescribed in section 6.0 (AhALYsts) of this calculation as part of the verification of the 10XPUf f and 10xtvAP spreadsheets, included in the development in that Section is the ref erencing to the regulatory docunents that establish the bases f or the approach used in this study.

3.0 AccrPT AWCT CPlffRI A Regulatory Culde (RG) 1.78 (Ref erence 9) stipulates that there be at least two minutes f rom the time of detection of a toxic chemical in the control room (CR) until incanacitation of the operators Section C.7.8, f ootnote 6, states that "two minutes is cont.idered suf ficient time f or a occurs.

trair ed operator to put a self contained breathing apparatus into operation, if these are to be used." One goal of this ef fort is to evaluate, for the chemicals ttermined to be applicable, the time operators have ovellable to take appropriate protective actions f ollowing an accidental tonic spilt cccuring in the vicinity of the plant, if the time f rorn d?tection to incapacitation (at defined and determined using the methodology of this calculation) is in escess of two minutes, then the addition of CR "ionitors f or that chemical to ensure adequate CR isolation need not be considered.

This calculation has two specific acceptance criteria. The first involves the vert?lcation of the i

10XPUF F and 10X[VAP spreadsheets. Reasonable agreement between the results of manual calculations and the results obtained using these spreadsheets (using the cethodology described in this calculation) is necessary in order to consider these spreadsheets to be suitable tools to f acilitate f

O_TENERA suturcT Verification of TOXPtTF nnd TO\\TV AP PFLEpARED BY f _ DATE 4/I6/93 i OTt?S 12 3 Spreadsheets cHtcKrD BY.d4Y.DATE Yie_k V

PQOJECT Monticello Tmic Chernical Study PRCL., sHCET or i

CONTROL l.D. No.

1961 2.2 001 ncv.

I sHttT 3

or H

sHttTs further analysis. the second acceptance criteria invokes the RG 1.78 guidance regarding the two minute operator response time to the results of the examle chemicals used in this verification.

$*0 1.!iW various plant and chemical compound inf ormation are needed to perf orm the annysis in Sec tice. 6.

The following is a se nary of the inputs used.

Quentity of Chlorine corried in a typical railrced cse is 13,NO gallons (Ref eren.e 1).

f cuantity of (thyt Alcohol carried in a typice railroad.ar is '9,M Cattons (Reference e

12).

5.0 819soflows The following assumed values are used in the analysist Ambient temperature e 20'c hote: This value is reasonable based on a review of USAR fable 2.3 1.

f Wind Speed 1 m/s Note: This value is reasonable based on a review of USAR fable 2.3*12.

Also, it is consistent with the value used in WUR[G 0570. gf uorg s ns m.,g,, g g p, $3.g 6.0 Akattsis M asew.n 6 n, po%,

omte*Mh or a own f,4 The analysis presented here involves two cases. The first tooks at the situation in which the y* f c chemical compound spilled has a botting teg>erature less that ambient; i.e., upon release from Ita pj,,

container, the chemical will bolt and f orm a tonic cloud. In this case, the methodology is described and the 10XPUFF spreadsheet that incorporates this methodology is verified f or use. The second case toots at the situation in which the spilled chemical has a boiling teTerature that is higher than ambient. In this case, the chemical f orms a toxic cloud through evaporation. The spreadsheet that incorporate the methodology f or this scenario la cetted 10XtvAP. The analysis for each case is presented in the f ollowing two subsections.

6.1 Model 1. T.

• T.

Torpur F This section describes the 10XPUFF model, presents examples, and verifies the LOTUS 12 3 i

The 10xPUFF model was developed to evaluate toxic chemical spilt ef fects on Control spreadsheet.

Room operators where the spilled materlat is either a compressed gas or a liquid whose boiling point temeratura (f.) et atmespheric pressure is less than ambient temperature (f.).

For liquids, the chemical release is modeled as both an instantaneous puf f and vaporltet ton of the remalning tiquid.

Comressed gases are asswied to be released as an instantaneous puf f in their entirety provided they are contained at ambient temperature. A step by step approach has been developed to describe the comtete model. separate subsections have been developed f or this purpose as noted t>elows 6.1.1 Mass of Instantaneous Puf f Release e f f Release at CR Intake 6.1.2 concentration of Instantaneous u

6.1.3 Conversion to PrM 6.1.4 Growth of spill Area 6.1.5 vaporitation Rate of Remaining spilt 6.1.6 Concentration of Vaporitation Release at CR Intale 6.1.7 Buildup Inside Control Room 6.1.8 Incapacitation Mooet A l

1 The completion of each separate step is identical for both liquid and compressed ga spitts, except as noted above.

The example chemical used is chlorine. The developed modets are wenticet to those presented in NUREG 0570. 10xPUFF cett locations where a particular f ormula, value, or output

O~TENERA susarcT Verifiention of TO\\ TUFF und TO\\TVAP entPAFl[D BY

[ _ DATE.4/16/93 LOTUS 12 3 Snreadshnts catcKED BY.h#

DATE N 5' a

Part sHar7 or PROJECT },fonticello Toxic Chemical Stmis CONTRot.1.D. NJ.

1961 2,2 001

- REV.

I SHIET 4

0F 69 SHEETS result is located are noted in brackets next to each parameter. Where e value is shown as an input, it was entered into both the manuel calculation shown below and to 70KPUFF es a design input.

Where a value is shown as an output, both the hand calculated and 10XPUFF cattuteted values are shown for verification purposes. A printout which contains selected time steps of the 10xPUFF. hulated outputs is included in Appendl* 1 A printout of the 10xPVf F f ornutes, with the fir t few rows of the time step forrutas, is Included in Appemfla 2.

Only a few rows of Individuet ?l.i step f ornutes were printed as att rows (except the first) are identical.

6.1.1 kass of instantancru Puff Release As noted in Section 2 of Ref. 2, it is conservatively asstaned that the entire container of toalc meterial ruptures and is available for immediate rettese. If stored in a container' r 4 as a liquid at ambient tenversture, or stored as a conpressed gas at lower storage tenperature, a percentage will instantaneously release as a puf f.

The remainder will If the entire shipment is in a ptseous state, it vaportte as described in teter sections.

l le assumed that the entire mess is released in the form of a puff as described in Sections 6.1.1 through 6.1.3, to cetrulate the mass of the instantaneous puf f, the following equation is solved:

% = % C,-(f T,)/M.

(Ref. 2, eq. 2.1 3) where: g a mass of instantaneous release (grams.g) m, a total Initiet mass of split (g)

C, a heet capacity of liquid (cal /g'C) 1 s ambient temperature ('C)

T, a normal bot ting point of liquid ('C) et 1 atmosphere H. s beat cf vaportretion of liqafd (cal /g) is demonstra'.ed in the f ollowing example.

Application of this formul 4

Emanple 61 Using date from Ref erence 1 (f or a 13,750 gatton (90 ton) Chlorine Spit ():

V, = 13,750 (get tons) 3.785 10' (cm'/galton)

= 5.204 10' (cm', container volwne)

(F10, irgut)

Note: Conversion coef ficient to cm' obtained f rom Table A3 of Ref erence 4.

N = V. D E N S, s 8,17 10' g From 10xPUFf, m, = B.17 10' s (F45, output) where DE N$ s Censity of liqJid

--am.-

O_TENERA sVBJtCT Verifkation of TO\\Tt'IT and TO\\TVAl' PREPAnto sv F DAir 3/R/03_

N/95 cHtcKtD ev _,@

DATE l.OTUS 12 3 Sorea@.heets o

PuoJtcT Monticello Tmic Chmiiral Study PREL.THEET OF CONTRot. l.D. No.

1961 7.2-001 Rev.

O sHtrT 5

or 60 sHtrTs

= 1.57 g/cm' /

(Ref. 1, tab'e 2) (F27, legut) '

Inputs m, e 8.17 10' s (contuted above)

C, e 0.226 cal /g*C (Ref. 1, table 2) (f3D, irgut) /

f,e 20'C e 293.16'K (assurned) If17, irgut) #

/

1,. 34,1'c. 239.06'E h

(Ref. 1, Table 2) [F28, irgut) /

H, a 68.8 cal /g (8ef.1, Table 2) (F31, tryut)

Celes g

• 8.17 10' 0.226-(293.10 239.06)/68.8

= 1.452 10' g /

From 10KPUFF, ga 1.452 10' g

[E54, cutsut) '

% = g g (remaining mass af ter suf f release)

/

= 8.17 10' 1.452 10' '

• 6.71B + 10' g

/

From 70KPUFF,

/

g a 6.718+10' s (TST, tut;ut]

As shown above, excettent agreement between 10XPUf f generated resatts and those manually calculated were obtained.

Note: If the released chemical consists cocptetely of a conpressed gas stared at some container (or ant > lent) tenperature (f ), the totel mass (ustrig the Ideal Gas Law) !s calculated as follows:

mi = (W P, V,)/(R T,)

where. W = molecular weight of the gas (g/ mote)

P, a container pressure (atnosphere, atm)

R s Universal Gas Constant

• 8.205 10' atm m'/ mote 'K I

4_TENERA sa PREPARED BY f _ DATE.1/16/93

' sun.itcT Verificatlog of TOYPUIT and TOXEVAP pf_ DATE */NtO cHtcKED BY 1 OTUS 12 3 Sorcadsheets Pr.tt. s HtET or PQOJECT Stonticelin Tosic Chemical Setsdt CONTROL l.D. NO.

1961 2,2 001 REv.

1 SHEET 6

OF 69 CHEETS (Ref. 6, pg. F 221)

T, a container temperature (*K) included in TexPuf f.

If Nta for calculating conpressed gas initial mass is not This for:

required, the f ormula in cell f 45 would be overwritten with a manually calculated value of mi.

the formuts in cett D4 would also be overwritten with m, as g would equal mi.

I f 1,si.,

6.1.2 Correntration of Instantaneous Puf f Release at CR Intake thernical spilt concentration at the CR intake f or en instantaneous puf f release is calculated as follows:

' b4 M x(x,y,3,h) e Ig/ (2 s.2' t " a,, a,, a,,)).

p,v.4 64 S.03. 7 4 72x* * *

• empt %-(m'/a,'+y'/a,,8))*

fu pd $W NW m-n J

544*IT&v Dd/*AIJ I"" NN (exp( %-(

h)'/ag,') +

G. 3 m sv 84w 7e how? M

' empt %-(teh)'/a,,83) 9(

, p (trr,s em reop, y (Ref. 8, eq. 3.1.1.3) %

b

• f where:

puf f concentration at point (n,y,2) asstaning spilt release at point x(x,y,3,h) a (0,0,0){g/m$

a,,'

=

z dispersion coefficient (m)

(Ref. 2, eq. 2.2 2) a '

• a,*

a,,'

s y dispersion coef ficient (m)

(Ref. 2, eq. 2.2 3) a, ' + a,'

• dispersion coef ficient (m) af,'

=

(k+f. 2, eq. 2.2 4) a, '

• a,'

a,,'

s a,,' (due ta spl1i synynetry)

(Ref. 2, eq. 2.2 5) f or the initial puf f voturie.

It is Note:

a,' is a correction f actor to account calculated as follows:

o e, = (m,./( 2

• r s " DE N S.)l "# (m)

(Ref. 2, eq. 2.2 7)

DENS. = chemical vapor density (g/m')

where:

,m_._

O_TENERA SUEJECT VerMetition of TOXPUFF and TO\\TVAP PREPARED BY [, DATE 3/8/93

[OL DATEN*M LOTUS 12 3 Spre:idsheett CHECKED BY PQOJECT Monticello Tmic Chemical Studt PREL SHEET OF CONTROL l.D. N O.

1961-2,2-001 REv.

0 SHEET 7

OF 69 SHEETS Using the Ideal Gas Law, DEWS. is calculated as followst

!kS, a ww.PjR.T. ( g/m')

/

(Ref. 1 App. A, eq. 3.1 8) where MW = notecular weight (g/ mote)

P, e asthospheric pressure (el atm)

T, e act lent tecperature (*K) are the atmospherig dispersion coef ficients. These values are normally obtained a, a,,

and an frora Figures 1 and 2 of Reg Guic3

..'t (Ref. 9).

However, a mathematical representation of the curves shown in Figures 1 and ? of Ref. 9 was developed in the original stuff (Ref.1, pg.

A 14).

This mathematical model alsys conputer calculation of dispersion coef ficients and provides f airly accurate results when ca.y"ed to the figures.

The values for Class G Stability Category are shown below (as obtainee. from Ref. 1).

Class G was chosen based on Appendix A of Reg. Guide 1.78 (Ref. 9) and Table ?.312 of the MWGP USAR (Ref.10), i.e., the worse case stability category that ealsts f or mor" than 5% of the time was chosen (Class G).

Logi a, = 1.6212+1.0648-(log,,X,) 0.014857 (Log,,x.)'-

0. 0020555 - ( l og,,x,)*

(Ref. 1, App. A, eq. 3.3 1)

L og,,a, = 1.8981+1.1243'(logi,x ) 0.036447-(log,,x.)'-

0. 0086351 - ( l og,,x.)*

(Ref. 1, App. A, eq. 3.3 1) /

where x,a distance from spill ~o CR intake in meters Note Since a,a e y,,a, no separate equation is presented f or calculating a, above (Ref. 2, eq.

n 2.2 5).

According to both References 1 and 2, it is normatty asstned that the spill tocate is aligned on the x axis with the CR intake. This sipplifies the equation for x(x,y,1,h) as y=0.

The model outlined in this calculation uses y=0.

It is also conservatively asstaned that for DENS, heavier than air density :=h=0 and for DENS, Lighter than air reh.

DENS, is calculated in 10xPUFF using the Ident G6s Law as shown previously, finally, x in the above equation is replace as follows to determine the CR intake concentration buildup and deplettor, over times x = mf u t

/

(Ref. 1, pg. A 10) where x, a distance f rom spill to CR intake (m)

U = wind speed (m/sec) t e elapsed time since spill (seconds) xcU t is used to account f or the delay time between initial release and transport to the CR intake.

Example 6-2:

O_TENERA Verification of TOXPUFT and TOXEVAP PREPARED BY f _CATE 3/8/93 SUBJECT CHECKED BY MV DATE )<//tM 3 LOTUS 12-3 Spreadsheets 4

PREL. SHEET

. OF PROJECT Monticello Tmic Chemical Study CONTROL l.D. NO, 1961-2.2-001 REv.

0 SHEET 8

OF 69 SHEETS Contiruing with the chlorine chemicet emanple f rom above in conjtnction with available data from Reference is

/

tryuts:

x, =

3.218 km (=2 miles)

(Ref. 1, Section 2.0, pg. 3) LF11, Irgut)

MW =

70.9 g/ mote /

/

(Ref.1, Table 2) (F29, irgut)

P, e 1 atm

[

(essmed) (F19, Irvast)

R=

8.205 10' atm m'/ mote *K (F34, irgut) #

U=

1 m/sec /

(assuned) [F18, irgut) #

1.452 10' s /

m. =

( onguted above) (E54, outgut)

T, a 20*C (asstsned) (F17, irgut) a factor of Conversion Factors: Adding 273.16 to centigrade tenpe etures converts *C to 'K; 10' is used to convert m' to em'.

Cate:

T, a 273.16+20 293.16*K /

=

(F46, output)

• la stored at cett location F37 in the TexPUFF spreadsheet. value input is 3.1415926.

Note:

Catc L og,,a, =

1.6212 + 1.0648 Itog, (3218)]

0.014857- (log, (3218)) * -

./

0.0020555 Itog,,(3218))*

c, =

69.532 m -

From TCrPUFF, a, s 69.532 m (E103, outgut) t og,,a, =

1.8981 + 1.1243- (Log, (3218)) -

O_TENERA

~ PREPARED BY DATE 3/8/93 Verincation of TOYPtf}T nnd TOYEVAP SUIUECT cHEcKEDBY;_[/4 DATE JhtNS 1,OTUS 12 3 Spreadthats PREt.sHLET

. or _

PROJECT Monticello Toxie Chernical Sttede CONTROL 1.D. N O, 1961 2.2-001 REY.

O SHEET 9

or 69 SHEETS 0.036447- [t og,,(3218)) 8 0.0086351.(l09.(3218))8 a, a 16.766 m y From TOKPurF, e,

• 16.766 m (Etti, output)

As an additional confirmation of the a, and a, values, a conparison was made with the These graphs plot the family of curves for Note:

graphs presented in RG 1.78 as figures 1 ard 2.the horltontal ard vertical standard devia Eorresponding to Pasquilt C, and using the 3218 meter distance, the above values of

Types, a, and a, coppare very well with those calculated above.

(70.9 1)/(8.205 10' 293.1641 10' DENS,=

2.948 10

• g/cm' /

=

2.948* 10' g/m'

/

a From 70xPUTF, 2.948 + 10' g/m'

/

[L91, outp;t)

(1.452 10'/(2" e 2.948 10'))*

a, =

=

8.552 m y

from TOXPUff,

=

8.552 m j

[E95, outgut) v

[( 69.532 )'+ (8.552)') " /

a,=

v

=

70.056 m

/

From TorPUFF, a

70.056 m (E114, output}

[( 16,766)'+ (8.552 )'3 " /

ai, =

=

18.82 m

/

From 10XPUf f,

/

18.821 m

=

i

_. ~

G_TENERA

[

DATE 3/8/03.

PREPARED BY SUBJtcT Verification of TOXPUIT and TOXEV AP DATE}/hkl cHtexEnsY.

U LOTUS 12 3 Sorendsheets PRLL SHEET OF PROJtcT Montkello Tode Chnnical Studt CONTROL 1.D. No.

14til 2.2-001 REV.

O SHEET 10 OF 69 SHEL78 LE120, outFut) /

a, e a,, a 70.056 m /

n from 70XPUFF,

=

70.056 m (E117, cutput)

OtW:.., a 1.29 10' g/ca'

)

(Ref.13, f able 348)

Note: This value of air density is at 0*C.

Correcting it for 7,=20'C only further demonstrates that DENS,

• DEWS.,.

As DtWS, > DEWS,,,, ashs0. In 10xPUF F D[W$,,si.2 10' g/cm' tr36, irput). DtWE, is cornpared to verified run DENS,, at cett location D191 either 0 or F22 (CR intake height) is displayed, I

indicates 0 et D191 which is correct (see Arpendis 13.

t Corrbining att data points gives xe (1.452 10'/(2-(s)' 70.056 70.056 18.821)).

j exp[ Yr(3218 t)'/(70.056)') *(exp!0)+emp!01) e 19.96 expt-(3218 t)'/9.81610') g/m' Results f or verlous time steps using this cate will 12e conpared to the 10XPUFF equation Notes in the next section subsequent to conversion to pra units.

3 I

6.1.3 Corwersian to Pf5 The f ollowing equation, based on the ideal Gas Law, is used to convert x frtwn g/m' to parts per mittion (ptn):

x(prn) = x(g/m') R T.10*/ Hit P, (Ref. 1. App. A, eq. 5 3)

Emanple 6 3' for chlorine using values f rorn stevet x(ppm) x(g/m') 8.205 10

• 293.16* 10'/(70.9 1)

• x(g/m') 339.26 t/

s/

[value of 339.26 calculated ty ToxPuf f, E136, outgut)

= 6.77210' erpt-(3218 t)'/9.81610 ) ppm /

8 is calculated once and then used with the exponentist term at In 70xPUFF, the above constant The constant is calculated at cett location K188 and in this eaarrple has a each time step.

value of 6.772 10', which agrees well as shown above.

Calculating x(ppm) values at selected time steps of 3000 and 3200 seconds gives x(3000) e 6.772 10' expt-(3218 3000)8 /9.81610')

O_T5NERA

^ DEI sunstcT Ytrinention of TOVI'tTF and TOX1WAl' PREPAntD BY [

DATE)j!fi, cHicKtD BY f/4 DATE)[/0 l.OTUS 124 Spreadshttts PREL &Hitf OF pQoJcci )f onticelin Tmic Chmilcal Study CONTROL t.D. No.

1961 2,2-001 rity.

O sHtti 11 or 69 sHrtic

.e.-

e 53.47 gn /

x(3200) e 6.77210' e pI-(3218 3200)'/9.81610')

e 6.552 10' ppm /

In 10xPuf f, time steps at i secord intervata are calculated and displayed in rows A198 through A2598 and represent time steps f rom t=0 to 2, A00 secords; at 2 second intervals in rows A2599 tlpe steps from ts!,402 to 3,600 setords; ard et 100 second through A3198 and represent intervals in rows A3199 through A3450 and represent time steps f rom t:3,700 to 28,800 seconds x is calculated in the corresponding tows in Cottam M (i.e., N198 through N3450).

(8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />).

The final concentration outside the CR Intele dae to the puff is presented in Cotwn 8 (0198 through 83450). A check is first performed in Colmn B to ensure the value calculated in the corresponding Colmn H cent enceeds 1.0 10 "

nn, otherwise 0 is printed.

This check eliminates the potential f or error messages due tJ calculated Values less than thit abriunt.

Such a roundof f has no ef f ect on the final results. For 1:3000 and 3200 seconds, the x values As shown calculated by 10KPUFF are displayed in cell locations B2898 ard $29YS, respectively.

in Appendia 1, these values match identicalLy with those calculated ateve.

6.1.4 Crowth of spill Area the remaining spitt, which was not released as an instantaneous puf f, will t o reteesed through vaporitetton. The rate of vaportantion is proportional to the split area. The spilt area changes with time as follows:

A(t) e e-(r,8 + 2 t to V.-(DtWS, OtWS..)/(s DENS))")

(Ref. 2, eq. 2.1 1) e A, o Ac,, t V, a remaining spill volme ef ter reteese of instantaneous puf f where a m,,/Dt hs, e e r,' cm' y SpitL essmed initially cyt trdricot with height equal to radius of t,ase, Ref.

Note:

2, Section 2.1.1.

r, e initial radius of spill (cm) ga gravitational constant

• 981 cm/sec' /

(Ref. 2, Section 2.1.1) area rate of change (cm'/sec)

A e

n OtES, e density of chemical (3/cm')

Oths.,,

• 1.2910' g/cm' 273.16/293.16 Notes the ideat Gas Law is used to adjust the value of density cited in $ection 6.1.2 above to 20'C frce O'C.

• 1.20 10' g/cm' t a time (sec)

O TENERA PREPARED BY ',aI. DATE 3/ft/93 SUEJECT YorifirDtion of TOXPtifT and TOND' AP Eb CHtcKtDsv_Jfil.DATE 1.0T11912 3 Spreadsheets

_/

P att. s Hi n or PROJECT _Montirelin Tmic Chemical Study CONTROL l.D. NO.

1961 2,2-001 Rev.

O sutn n

w p

wm the equation for Att) ebove la applicable f rom time t=0 (A=A,n r,8) untit A e %.

L is celined as that point where the split thickness egsels one centimeter. Dnce A is reached, the spill eres remains constant es the remaining waterf el vaporites (Ref. 2, Sect f un 2.1.1).

L is calculated 68 follows:

L

• V. (ca')/1 cm /

The tire (t.,,,) et which A*L can be calculated by solving the f o((ow{ng eqJetion for t,,,,

t.,,,, o (L. A,) /A,,, /

10kPUFF uses t to determine when to start catcyteting contf ruous concentretjon using A in plees of A(t).

Esanple 6 as inputs:

N

• 6.718 10' s (f rcan above calculation)

From 70xPUFF, a 6.718 10' g /

[EST, outrut)

DENS,

• 1.57 g/ce' (F27, issut)

DEks., a 1.2 13 g/ce' /

8

/

(F36, irgut) '

9 s 981 cm/sec' (F38, irsut) !

Cates

r.

• LN/(DEN % s))

• 16.718 10'/(1.57 e '8 e 238.8 cm /

From TUxPUFF, / = 238.8 cm [E62, output) # A, e e.(238.8)'

• 1.792 10' cm' From 10XPUfF, a 1.792 10' cm'

[t65, output) /

G_TENERA sunJtcT Verincation of TOXPUIT and TOXrV AP PREPARED BY _ D ATE 3/8/9.1 CHECKED BY _III DA1E 3/ EMS LOTUS 12 3 Sercadshttt4 a PROJECT MonticeHo Tmic Chemical Studi PRtt. SHEET or CONTROL I D. P40. 1961 2.2-001 Rty. O SHEET 13 cr 69 sHEris 2 e- (581 -(6.718 10'/1.57)-(1.57 1.2 10 )/(e 1.5 7)3"' / 8 Ag e 7.260 10' cm'/sec From 10KPUFF, a 7.26010' cm'/sec / tt69, cutsut) A, e 6.718 10'/1.57 1 / e 4.279 10' cm',/ F r om 10KPUF F, a 4.279 t0' cm' / [t72, outrut] # t,,,, * (4.279 10' i.792 10')/7.260 10' = 58.69 sec / From 10xPUTF, a 58.69 sec / it75, outrut) As shown above, the spreadsheet values are {n agreement with manual relculations. 6.1.5 Vagoritatlan Rate of Resnainitg sp((t The remaining chemical will be released through vaporitetton over time as f ollows: ch/dt, a A( t ) [V, + V,,/t,*] / c (Ref. 2, eq. 2.1 12) V, [q + h,. (f,1,)) / M, Vc,, = 197-(T T )/H, / where ch/dt,e rate of vaporitation (0/sec) q

• atrospheric ard solar heat flux

= 212 cal /m' sec (Ref. 2, section 2.1.2.1, pg. 7) Reference 2, section 2.4.2, recortrrends the use of 275 cal /m' see when g is Note: unknown. Consistent with kef erence 1, 212 cal /m' sec is used in this calculation. 212 is the highest value measured in the south western region between 27'N ard 40*N Latitudes (Ref. 2). As the latitude of MNGP {s closer to 50*N, the value of 212 is conservative. h, a forced convection heat transfer

OTENERA suaJECT. Verification of TOYPlfFT and TOYEVAP PRcPARED BY DATE 3/8/93 cHEcKro sy Mr DATc54/73 LOTUS 12 3 Sorendsheets 0 PROJECT _Monticello Toxic Chemient Sitidy Pact. SHEET _ or CONTROL l.D. NO. 1961 2.2-001 Rtv. O sHtti 14 or 69 sHccTs a 1.6 cal /msec *C (f or Us1 m/ste and f,*20'c f rom Ref 2, Sec. 2.1.2.2) is

• ground (earth) tepperature (*?)

(typicatty assmed mat to T.) t, e t

• x,N Vaporitation effects do not reach the CR intake instantaneously but over time as wind

) transports the split, therefore Wdt, s 0 f or tsa,/U Also, Adt *0 once the spill is conpletely released ard has passed by the CR intake. This time (t,,,,) is determined by solving the f ollowing equation for t,,,,3 [ t,,,, [t, / %

• i OVdt,*dt, a J A( t,)
• IV, + V /( t,)')
• dt, c

0 0 A( t,) is replac ed by A,,,, f or t imes uhen t, > t,,,,,, This audifles the above equation as follows: %

• I (t,,,,A, + Ac ' t ) * (V,
• Vcup ( t.)")
• dt, +

l 0 / I t l A,,,,' (V + Ven/(t,)")

• dt, t,,,,

If t,,,,, > t,,,,, then the A,,,, ters (second Integral) as shown below will not esist at the t entire spilt would have vaporized prior to reaching its maalaun area. Such a situation is not typically anticipated and would require manuel catrulation and entry into 10KPUFF, Solving the above integtets gives I % * ( A, V,* t, + % Ac V,* t,' + 2 A,.Vc,. t,* "' + (2/3 )

• A,* Ven ' t,)!

+ c 0 ( A,,,. V. t, + 2 A, Vc. t,"')l / t,,,, The above equation is stored as a macro (\\m) at cett location I180 It obtahs a value of t,,,,, entered at cell location E180 ord computes and outputs a value et % at cett location C179. Values of t,,,, are entered at E180 manually on an iterative basis until % is reached. Example 6-5: Inputs: h, = 1.6 ul/m'a sec 'c [F40, Irtut) t m- - - -., - + - r ..m..

'O._TENERA SUBJECT Ytrificatinn of TOXPttiT and TONEYAP PREPARED BY DATE 3/8/93 cHtcKED BY _MZ.DATE3/ok5 1 OTU912-3 Sr.cadthetti e i PHEL. SHEET OF PQOJECT finnti(,dlo Tosie Chiinical Stodt j CONTROL i D. NO. 196I 2,2-001 _Arv. O SHEET 15 or 69 . sHtrTs / 7

• 20'C e 293.16't (assuned) (F46, irgut) g o til cal /m'asec /

I } (741, irsut1 / / 7,a 20*C l (F17,irsut) V t,e.34.t*C e 239.06'r (f 28, f rgut! ' N,a 68.8 cal /g V tr31, iryut) # s,/U e 3218 sec l m, a 6.718 10' g ( e 4.279 10' m' A,

• 17.92 m' A,, a 72.6 m'/see c

t,,,, = 58.69 see cates V, * (212 + 1.6-(293.16 239.06))/68.8 I e 4.34 g/m'+ sec / 1 l F rorn 70xPUFF, a 4.34 10' g/cm' cee / [L83, outgut] V., a 197-(20 34.1)/68.8 c 154.9 g/m' sec* / e f a From T0XPUFF, 1.549 10' g/cm' sec* / a / [I86, output] I J

OTENERA D ATE 3 /8 /03.. SUtutCT Verification (4 TOYPU}T and TOYFV AP PREPARED BY / CHECKED BY d- _ D AT E 3k' 3 I OTUS 12 3 Spreadsheett PROJECT Monticello Tmic Chemical Studv PRtt. SHEET or CONTROL 1.D. NO. 196 f.2.2-001 .Rty. O SHEET 16 0F 69 SHEETS Cates solving for t,,,t 6.71* 10' e [(17.92 4.34 t )+((1/2) 72.6 4.34 t,')+ ( 2

• 7.92 154.9 t,)+

58.69 l ((2/3) 72.6 1$4.9 t,))I + 0 8 [(4.279 10 4.34 t.) + (2 4.279 10 154.9 r,"'))I 8 58.69 i / a 3.961 10' + (1.257 10' t,,,, + 1.326 10* t,,,, 1.125 10') tolving iteratively gives t,,,,, a 1369 secorids. / The value of the first integral above (evaluated f rom 0 to 58.69 seconds) is calculated t>y# 10xPVFF at cett Location E163. In 10xPUFF this value equals 3.961*10' which agrees with the pacivetty calculated value of 3.961 10'. A value of 1369, seconds f or t,,,, is indicated in 10XPUFF cet t location E180 and calculates the value show6 n cet t G179 which equat s vn,, ' ~. 3 9si lo' ' w., w. n.cs In conclusion, Wdt, is calculated as f ollows over the various time intervals: Wdt, e 0, ft t, s x,/U / Wdt, e A( t )-(V + Vc,./ t,), f or x/U < t, 5 x/U+ t,,, W d t, = A.,,,,,- ( V, + Vc / t,), / f or x,/U+ t,,,,, < t 1 x,/U + t,, + t,,,,, dm/dt,

• 0,

/ l f or t, > s/U+ t,,,+ t, 6.1.6 Cancentration of vaporitation Release at CR Intate Chemical spilt concentration at the CR Intake for a vaporitation release is calculated as follows: x(x,y,2,h) = (Wdt )-(1/(2 e U c,v a,4) er. ' %-(y'/a,,'))- / (empt h-( h)'/civ') + empt h-(2+h)'/a,')) r (Ref. 2, eq. 2.2 9) / i l a = calculated as described in Section 6.1.2 where: h

• calculated as described in Section 6.1.2 f

i

O_TENERA PREPARED BY .DATE 3/8/03 sutu[c7 Verifiedon of TO'.'NfiT and TO\\TV AP I OTl'S 12 3 Snr adsheets CHECKED BY fGLDATE h /O PnEL. sHtET ._ or PROJECT Montirelin Tosie C Nemical Sip + CONTROL 1.D. NO. 1961 2.2-001 REV. __0 SHEET 17 OF 60 SHEETS y e calculated as descritied in Section 6.1.2 dvdt, e calculated as descrited in section 6.1.5 a,,' s a,'+a,,' (Ref. 2, Section 2.2.2) a,,8 e a,s.,,,a (seg. 2, section 2.2.2) a,' e calculated as descrited in Section 6.1.2 r a,e e calculated as descrited in Section 6.1.2 / a,,8 e e r'/4.3' (Ref. 2, eq. 2.2 10) a,,' e 0 (Ref. 2, section 2.2.2) / The a,, term above was assteed to be tero as suggested by Ref erence 2 since it is a smat t value. The a,, correction term is to accomt f or spilt area w5f ch resides perperdicular to the CR intake (in the y direction). For circular spills (spill shape assiped in all calculations), r equals the radius of the spill. As r may change with time, a,, may also change with tire. This is accounted f or as f ollows: a..(t) e s* r(t)/4.3 / As the ef f ect at the CR Intake is delay d by s/U seconds, a,,(t) is calculated as follows: a,,(t) e ( A, + A.,- (t m/U)] '/4. '. / c s/U 4 for z/U t t < t + o, e A.'/4.3 / for t,,, + s/U $ t Finally, the conversion of final cateuteted concentrations f rom g/m' to ppm is performed in the same f ashion as shown in Section 6.1.3. Example 6 6: Inputs: hO te 11.28 m / (F22, irgut) J Wotet :=0 is used in the concentration calculation as DEks, e DEks... The value of 2 used in this examples comes f rom the location of the MonticeL Lo CR intake; i.e., intake at elevation 967' 0" (Reference 15) and grade elevation is at 930' Da (Ref erence 10, section 2.4.1), the difference being 378, w& f ch corresponds to 11.28 meters. ye 0 / U = 1 m/sec

'OTENERA sunJEc7 Verification of TOA'PITF and TO\\TVAP PREPARED BY DATE 3/8/93 CHECKED BY /(d DATE /s/O LOTUS 1-2 3 Sorradshirts u i PREL. SHEET OF PROJECT hfonticello Tmle Chevnical Studv CONTROLID.NO. 1061 2,2-001 P.EV. 0 EHEET 18 OF 69 SHEETS (F18, f rp>tJ ' / a, e 69.532 m (see (**.tlon 6.1.2) a, a 16.766 m (ses fon 6.1.2) # / a,' = 0 s a,

• 16.766 g

,i F rorn 10xPUF F, 16.766 m / (E123, outpJt) # / a,,(t) = (( 69. 5 32 )' +a,,( t )' 3 ' i a,,( t )' s (17.92 + 72.6-(t 3218)1/4.3' f or 3218 s t < 3277 a 4.279 10'/4.3' e 231.4 f or 3277 s t x = (en/dt.)-(1/(2 t 16.766 a,,(t) 1)). f emp(0)-(emp(0) + exp(03) 339.26 = (ds/dt,)- (1/a,, - 11 6.441 Exanple values of X (ppm) will now be calculated for each of the various time intervals: t 5 3218 see (t 5 a./U): I d., dt, = 0 g/sec j X = 0 ppm From T0XPUFF, = 0 ppm / (C198 to C3007, t=0 to 3218, outp4t1 i t = 3220 sec (x,/O < t s x,/U + to,) : dVdt = A(t-3218) V(t 3218) (17.92 + 72.6-(3220 3218)1-(4.34 + 154.9/(3220 - 3218)"'1 = 1.85710' g/sec / a,y(t) * (69.5328 + (17.92 + 72.6-(3220 3218)1/4.38)* = 69.60 m / From 10xPUFF, a 69.60 m

m ~_ O_TENERA SUBJECT Verification 6f TOVPITFF and TOYEVAP PREPARED BY _ DATE 3/8/93 LOTUS 12 3 Spreadsheeft CHECKED BY _.((2 DATENck5 g 8 PREL SHEET OF PROJECT Monticello Tosic CNsnical Stude CONTROL 4.D. ND. 1961 2,2-001 REv. 0 SHEET 19 _ OF 69 SHEETS DG008, autost) ' x = 1.85710*-(1/69.60) 6.441 = 1,719 10' ppm / Frra T0XPUFF, = 1.719 10 ppm / ' l / ) (C3008, outpJt) s t = 3500 see (x/U + t,,, < t < m/U + t,, + t,)r Wdt, = A.,,, V( t-3218) = 4.27910' (4.34 + 154.9/(3500 3218)*J / 4 = 5.804 10' g/sec avv(t) = 71,18 m x = 5.804 10'-(1/71.18) 6.441 = 5.252 10' porn / From T0XPUTF, = 5.253 10' ppa / / (C3148, output) t > 4646 sec (t > m/U + t, + t,) dm/dt. = 0 g/see x = 0 ppm / From TOXPUFF, = t, pp / (C3209 to C3450, t=4700 to 28,800, output) As noted above, the values corpare very well with TOKPUFF results. For each time step i (A198 to A3450) toXPUTF calculates the outside control room concentration due to the vaporitation release and displays the results in cell locations C198 to C3450. Cell locations C198 through C3450 select one of these values to print depending on the corresponding time valurs in colums A198 through A3450, respectively. If t = x/U + t,. + t,,,,,, a value of tero is displayed. If t x/u < t,,,,, the value in the correspording I colum location is displayed, else the corresponding value in the J colunn. The I colum first checks if t s x/U and displays zero if it is. Otherwise, the value of x is corrputed i and d(splayed by using A(t x/u), V(t x/U), and a,y(t x/U) in the conputation. Colum I obtains the value of a,y(t) f rom the corresponding row of colum W. If J colum is selected it irrpties that t,,, + x/U 5 t 5 t, + t,,,, + x/U. For this case, x is calcul6ted by using A(t) = A, , V(t x/U), and a,,(t) = a (t ). vv r 9 d W

O_TENERA ) susJECT Verif1 cation of TOXPl4T and TOXEVAP PREPARED BY 7 DATE 4/26/93 CHECKED BY. M _ DATE Y 4[M LOTUS 12 3 Soreadshttts o / 4 PROJECT Mnnticetto Toxic Chemical Studt PREL. SHEET OF CONTROL 1.D. No. 1961 2.2-001 REV. _2 SHEET 20 OF 69 SHEETS 6.1.7 BuBoup inside Control Floom Once the concentration outside the CR is k.nown, the concentration inside can be calculated as follows: Cc.( t,)

• Cc.( t,) + (x(t,)

Cc,(t )] * [1 exp( ta (t, t.)* W/60 Vc.)) (Ref. 2, eq, 2.4 2) wheret C.(t,) e control room concentration at time tat, (ppm) c C,(to) e control rocra concentration at time tot,, (Fism) c K(t,) e outside CR Intake concentration at time tat, (gyn) V, a control room voltsne (f t') c 8 V e intake air flow rate (f t / min, cfm) 60 = minutes to seconds conversion The above equation is used when no isolation is setoyed and the exhaust flow rete exiting the control room equals the air intake flow rate (W). This equation can be developed frenn Equation 4 5 of Ref erence 1 for small time intervals (t, to) with the asstoption that Xtt,) is constant.with respect to time over the intervat. An emanple of this a;proach is provided below which utilites results from Appendix 1. The buildup and depletion tetween various time steps were verified to ensure the above egaatfan was correctly incorporated into T0XPUFF. Three time intervals which cover different areas of X,,,(t) were selected. Emample 6 7: Inputs: W = 7440 cfm (Ref. 5,16) (F24, input! Note: It is conservatively asstsned that the entire design flow rate of 7440 cfm enters the control room even though, by design, some flow is diverted to other areas of the EFT Bullding. V. = 2T,000 ft' (Ref.11,16) [F23, input! c Note: As noted in Reference 16, tw use of the above is reasonable based on physical measurenent of the control roorn voltsne. Cc.(t,1) = obtained f rom Appendf x 1 r(t,) e obtained f rom Appendix 1 At t = 3200 seconds: l x..,(3200) = 0 prrn [C2998, output! Cc.,,,(31'v5) = 0 ppm (F2997, output] Cc,,..,(3200) = 0 + (0 01 II exp(-1-(3200 - 3198) 7440/(60 2/000))) = 0 ppn k i

_.. ~ OTENERA ~~ g suaJECT VedUcation of TOSJPUlT and TO\\TV AP pr++ra n 1 CAT. DATE 3/8/93 I.OTUS 12 3 Spreadsheets cHEcxEo wy _-((A.DATE_3k'O PRELSWT' OF PROJECT }1onticelin Tosie Chernical $ttsdt CONTH OL l.D. NO. 19fI 2.2-001 _REv. O SHEET d' DJ 69 SHLETS -m.,,, Frorn 10rPUFF, 4 e O ppt tr2998, outrut) y,(3200) e 6.552 1f pga x (32W8, outgut) l Cc,(3198) e 1.73610' sg ([2W7, outrut) C.,,,,,(3200) = 1.736 10' + (6.552 10 1.736 10')- 8 c (1 tap ( 1-(3200 3198) 7440/(60 27000))) e 1.780 10* ppm / e f rom 10xPV8 F, a 1.780 10' (C2998, outgut) # ( At t e 3500 seconds: x,,,(3500) = 5.253 10' ppn (c3148, out;ut) Cc.,(3.98) = 4.567 10' ppm tr3147, outrutt C.,,(350tt) e 4.367 10' + (5.253 10' 4.567 10'). (1 - 3 exp( 1 (3500 3498) 7440/(60 27000))) e 4.'i73 10' ppn./ Frcun T0XPVll, a 4.57,$ 10' ppn (13148, output) xy,(3500) e 2.0:52 ppn (E3148, ontrut) / Cc,y,(3498) = 1.582 10' ppm (E3147, output) Cc%,,(3500) = 1.552 10' + I2.052 1,$82 10') = [1 l - exp( 1-(3500 - 3498) 7440/(60 27000))) l i = (- i

@TENERA ~ PREPARED BY DATE 218/93 st v[c7 Verification of TOVI'tflT and TO\\TVAP NtM CHECKED sy MT DATE .1,OTUS 12 3 Spreadsheets a PRtt sHEtT or PROJECT jjonticelin Tosic Chemical Stude c0NTROL 1.D. No. 1961 2,2-001 FtEV. 0 SHEET 23 OF 69 SHEETS e 1.568+10' gn y Frora 10xPUF F,

• 1.568 + 10' nn IE3148, wtrut; At t a 4800 secorriss

/ x,,,(4800)

• 0 nn (C3210, wtrut)

J ) i / %(4'/00) = 2. f 6U *n' nn at t tr3209, wtrut) E Cc..,(4800)

• 2.166 10'
• 10 2.168 10'1 11
• i up( 1*(4800 4700).7440/(60 27000; n I

21 = 1.170 10' pin / Frem iOXPUFF

• 1.370 10' g n tr3210, wtrut) #

/ l x,,,(4800)

• 0 gn (113210, wtrut) #

l tc %,a.700) = 6.337 M n (E3209, wtruti l te,,.,(4800) = 6.'37 * (6 6.3371 11 - exp( 1-(4800 + 4700).7440/(t n.27000)s) I = 4.003 n n From 70xPUFt. l = 4. 003 gn [E3210, catput! As the above exanple demonstrates, the equation that enodels chemical tuitdup eM sut' sequent depletion in the control roorn was correctly incorporated into T0XPUFF. 6.l.8 trcapacitatico Mcel A 'he rokults can be used to Incapacitaiton models are net INLWied in fr@UFF, alth> r assess incapacitation potential. Mxiet A at described in ;,,tvck 1741 (Reference 3; is 'o o termine lu npacitailan i spoticable f c' chlorine releases (Innediate sensory irritont). l l ~- t 'N i -~

O_TENERA d PREPARED BY I DATE 3/8/93 - **%iECTj[erification of TO\\'PitFT nnd TOWV AP 1,OTUS 12 3 Spreadsheets cHEcrED By lC DATE NNf 3 PROJECT Monticello Tosie Chemical Studt PREL. SHEET OF CONTROL 1.D. NO. 1961 2.2-001 REv. O SHEET 23 or 69 SHEETS

.i.

time, the following equation is solved to determine the total tuber (N) of time intervals re:pired to Fe-e the equation feath a value greater than one: u (Ref. 3, eq. (331 E t/f t,

• 1 11 where: T I,. 665 -(RO /C,)" ( sec) [Ref. 3, eq. (2)]

t,. time interval (sec) C,. total inside CR concentration at t.t, For chlorine R0u,. 9.34 ppm Itef. 3, fat;te il The above equations are first used when the inside CR concentration reaches the TLV. Note: For chlorine, a conservative TLV of 1 pun is used (Ref. 3, Tabte 1).s incapacitation models, in accordance with Ref erence 3, will be invoked t.ly as needed in actual toxic chemical calculations. such modeling wiLL be performed manually and clearly outIined whenever used. Eummte 6-8: In this example, the concentration values (C,) f rom the 10KPUFF examle constructed through the previous emanples will be utilited. The values in colteri G (Total Inside CR Conc. - ppm) are scanned to locate the time at which the concentration reaches the TLV for chlorine. Mich is conservatively taken to be a value of 1 ppn. The above equation is then applied to determine the time at which incapacitation occurs. In the following, the time vs concentration values are extracted f rom 'he 10xPUFF spreadsheet and incorporated into the following table. Incapacitation Analysis del 8N Q T0XPUFF Time ilme Interval Cl fli tt/fli I ti/fli I gy: iCM , m-p.g,, ,3 W 2c(8 0 9.576E-01 N/A N/A N/A t y * *. g g y,' 1 29l. 2 1.066E +00 4.688E+03",4.266E 04j j. 4.266L 04 s 2972 4 1.187E + 00 4.258E+03 4.697E 04 8.963[ 04 e /.c73^ # '- 3 / 297', 6 1.320E+00 3.870E*03 5.16BE 04 1.413E 03 . y, (,9 wu 2976 8 1.466E+00 3.520E+03 5.682E 04 1.981E 03 3 s g ' ,".,o, g g 3, a 2978 10 1.62BE*00 3.203E*03 6.243E 04 2.606E 03 2980 12 1.806E+00 2.918t+03 6.855E-04 3.291E 03 ,,, p p. 2982 14 2.002E+00 2.659E+03 7.521E 04 4.043E 03 4.868E03[ /g * [Y. f u + Y. 417

• 2954 16 2.218E+00 2.425E+03 8.246E 04
• p /

/. 5.771E 03 2986 18 2.455E+00 2.214E*03 9.035E 04 Y g yj 2983 20 2.715E+00 2.022E+03 9.893E 04 6.761E 03 2990 22 3.001E+00 1.848E+03 1.082E 03 7.843E 03 g, g, g, g,gy3,g. gy At 2992 24 3.314E+00 1.690E+03 1.183E-03 9.027E 03 , 'y,1 M 2994 26 3.656E*00 1.54 7E + 03 1.293E 03 1.032E 02 #7,gn,ggj.gg4 c 2996 28 4.032E+00 1.416E + 03 1.412E 03 1.173E-02 y 2998 30 4.442E+00 1.298E+03 1.541E 03 1.327E 02 9' g 8E V /413 # 3000 32 4.890E+00 1.191E*03 1.680E 03 1.495E 02 3002 34 5.379E+00 1.093E* 03 ' 1.830E 03 1.678E 02 /#I'D # /T/7 * /5 W e 3004 36 5.913E+00 1.003E+03 1.993E 03 1.878E 02 ( 3006 38 6.495E+00 9.222E+02 2.169E 03 2.094E 02' go,43 9 I.GLn ni' / \\

O"TENERA PREPARED BY 7~ DATE 3/8/93 SUBJECT Verification of TOXPUFF and TOYEYAP CHECKED SY M DATE N M LOTUS 12-3 Spreadsheett M A.SHtET OF PQOJECT Monticello Tmic Chemical Study CONTROL l.D. NO. 1961 2.2-001 REV. _0 SHEET 21 OF 69 SHEETS 3008 40 7.128E+00 8.481E*02 2.358E 03 2.330E 02 3010 42 7.817E+00 7.805E+02 2.562E r1 2.586E 02 3012 44 7.367t+00 7.188t+02 2.782E. 2.865E 02 3014 46 9.381E+00 6.624E+02 3.019E 03 3.167E 02 3016 48 1.026E+01 6.109E+0/ 3.274E 03 3.494E 02 3018 SD 1.122E+01 5.637E+02 3.548E 03 3.849E 02 3020 52 1.226E+01 5.206E+02 3.842E 03 4.233E 02 3022 $4 1.338E+01 4.810E+02 4.158E 03 4.649E 02 3024 56 1.460E+01 4.446D 02 4.496E 03 5.098E-02 3026 58 1.592E+01 4.116E+02 4.859E 03 5.534E 02 3028 60 1.733E +01 3.812E+02 5.247E 03 6.109E 02 3030 62 1.887E+01 3.532E+02 5.663E 03 6.675E 02 3032 64 2.052E+01 3.275E+02 6.107E 03 7.286E 02 3034 66 2.230E+01 3.039E+02 6.582E 03 7.944E 02 3036 68 2.421E+01 2.821E+02 7.089E 03 8.653E 02 3038 70 2.627E+01 2.622E+02 7.629E-03 9.416E 02 3040 72 2.849E+01 2.437E+02 8.205E 03 1.024E 01 3042 74 3.087E+01 2.268E+02 8.810E 03 1.112E 01 3044 76 3.342E+01 2.111E+02 9.473E 03 1.207E 01 3046 78 3.615E+01 1.967E*02 1.017E 02 1.30BE 01 3048 80 3.908E+01 1.834E+02 1.091E 02 1.417E 01 3050 82 4.221E+01 1.711E+02 1.169E 02 1.534E 01 . {) 3052 84 4.557E+01 1.597E+02 1.252E 02 1.659E 01 3054 86 4.915E+01 1.492E+02 1.340E 02 1.793E 01 3056 c8 5.297E+01 1.395E+02 1.434E 02 1.937E 01 3058 90 5.705E+01 1.305E+02 1.533E 02 2.090E 01 3060 92 6.139E+01 1.221E+02 1.63BE 02 2.254E-01 3062 94 6.602E+01 1.144E+02 1.748E-02 2.429E 01 3064 96 7.094E+01 1.072E+02 1.865E 02 2.6151-01 3066 98 7.618E+01 1.006E+02 1.989E 02 2.814E-01 3068 100 8.174E+01 9.440E+01 2.119E 02 3.026E 01 3070 102 8.764E+01 8.866E+01 2.256E-02 3.252E 01 3072 104 9.390E+01 8.332E+01 2.400E 02 3.492E 01 3074 106 1.005E+02 7.836E+01 2.552E 02 3.747E-01 3076 108 1.075E+02 7.374E+01 2.712E 02 4.018E-01 3078 110 1.150E+02 6.944E+01 2.880t-02 4.306E 01 3030 112 1.22BE+02 6.544E+01 3.056E 02 4.612E 01 3082 114 1.311E+02 6.170E+01 3.241E 02 4.936E 01 3084 116 1.398E+02 5.822E+01 3.435E 02 5.279E-01 3086 118 1.491E+02 5.497E+01 3.638E 02 5.643E 01 3088 120 1.588E+02 5.194E+01 3.851E 02 6.028E-01 3090 122 1.690E+02 '.910L+01 4.073E 02 6.436E 01 3092 124 1.797E+02 4.645E+01 4.305E-02 6.866E 01 3094 126 1.910E+02 4.398E+01 4.548E-02 7.321E 01 3096 128 2.02BE+02 4.166E+01 4.801E-02 7.801E 01 3098 130 2.153E+02 3.949E+01 5.065E-02 8.308E-01 3100 132 2.283E+02 3.745E+01 5.340E-02 8.841E-01 3102 134 2.419E+02 3.555E+01 5.626E 02 9.404E 01 3104 136 2.562E+02 2.376E+01 5.924E 02 9.996E-01 3106 138 2.711E+02 3.209E+01 6.233f 02 1.062E+00 At in the above table, the concentration in the CR reaches the TLV at time 2970 seconds. CM U M N-T this point, the term "ti/Tli" is sunwa until that sum exceeds the value of 1, with the elapsed time being the time to incapacitation. The above table shows that the time to This result indicates that CR operators have ggg A4 g incapacitation is 2 minutes 18__syd. suffic8ent time, according to RG 1.78 (see Section 3.0 above), to respond to the detection fMD N U M cf the chlorine and don protective air masks. This result r:ontains ariditional margin by virtue of the detection limit selected (i.e., 1 ppm). In Reference 14, an odor threshold h 57/u C4 value of 0.080 p,r. is cited, which is based on a critical evaluation of a nurber of exposure studies to achieve mo e realistic detection threshold values for hunans. // 3ho)*th

G_TENERA enammmmme - $UiUECT Verificatinn nf TOVI'UFF an_d TOVEV AP PREPARED BY ( _ DATE 4/16/93 CHECKED BY E DATE d e#3 LOTUS 1 MSpreadsheett PREL. SHEET , OF PROJECT Monticello Tm::e Ciiernical Study CONTROL 1.C. No. 1961;2.2-001 Rev. I SHEET 25 OF 69 SHEETS 6.2 wodel 2. T. < T. ToxtvAP For chemicals that have a bolting point temperature at atmospheric conditions that evca ambient The spilt release s ete {dm/dt) temerature the spill is modeled entirely as an evaporation release. The remaining aspects of the is calculated differently than as described in section 6.1.5 above. modet, inctvfing control room buildup, are identical to those outlined above for the continuous release and are not restated in this section. The models for puff release mass and atmospheric dispersion in Sections 6.1.1 and 6.1.2, respectively, are not apolicable as there is no initial puff release. Though only the dm/dt model is described below, a complete example has been developed using ethyl ateobot and included in this section. This example served as the model against which the T0XEVAP was developed by modifying the program TOXEVAP was verified similar to 10XPUFF above. verified copy of T0XPUFF above to eliminate the puf f release model and replace the mass release rate A printout which contains Ae ToxEVAP calculated outputs is included in Appendix 3. A model. printout which contains the 10XEVAP formulas is included in Appendix 4. This section has beer. subdivided as follows: 6.2.1 Concentration of Evaporation Release at Control Room Intake 6.2.2 Buildup Inside Control Room As previously. ToxEVAP results are identified and compared to the appropriate Input and output values. 6.2.1 Concentration of Evaporation Release at Control Room For liquid spills whose bolting point is above ambient temerature, the evaporation rate (mass release rate) is calculated as follows: dm/ot = h, M.l A( t )-(P P,)/(R T,) (Ref. 2, eq. 2.1-18) where: MW, A(t), R, and T, are as defined previously. P, = sat. vapor pressure of liquid at T. (m Ng) P, = 0 (m Hg) (Ref. 2, sec. 2.1.3.2) h, = 0.664 0-(Re)'*-(Sc)"'/L (cm/s, t aminar flo") (Ref. 2, eq. 2.1-19) h, = 0.037 D-(Re)"-(Sc)"'/L (cm/s,turb. flow) (Ref. 2, eq. 2.1 20) Re a L U DENS,,/g Sc = g/(D DENS,) g = viscosity of air (g/cm s) U = wind speed (cm/s) L = 2 r(t) m..

OTENERA s SUBJECT Verification of TOXPUIT and TOXEVAP PCEPARED BY I DATE 3/R/93 f4*t DATE3loIi) CHECKED ey LOTUS 12-3 Spreadsheets PROJECT Monticello Twie Chemical Study PREL SHEET OF CONTROL 1.D. NO. 1961-2,2-001 REV. O SHEET 26 OF 69 SHEETS liote L = 2.r was used in the original stuct/ due to the rapid growth of r(t) (Ref. 11. In the T0XEVAP program, r(t) has been modeled instead to accomt for this groeth. D = dif fusion coef f'clent (cm'/ss = 0.2 cs'/s (for chemicals where att required data to calculate D is / movaltable, Ref. 2, Section 2.4.2) = 0.0018583 T.-(1/MV, + 1/PW.)"/(P. a 8 0 ) / (Ref. 2, eq. 2.1 14) / T. = ambient tenversture (*K) MW, si molecular weight of air (g/ mote) = 28.84 g/ mote / (Ref.1, pg. A 7) MW = molecular weight of spl(L materip( P = 1 atm 5 a., = ( a, + a.) / 2 / (Ref. 2, eq. 2.1 15) # a,= 3.617 Angstroms for air (Aef. 1, pg A-7 and Ref 7, Tabte B-1)

a. = 2.44- (T,/P,)"

(Ref. 1, eq. 2.2 7 and Ref. 7, eq. 1.4 13) T. = spilt critical point temperature ('K) P, a spill critical point pressure (otml C.,= table tookup from Table B 2 of Ref. 7 using LT/t.,to find D., (Jk =.77 T, = 97*K (f or air) (Re'.1, eq. 2.2-6 and Ref. 7, eq 1.4 11 and Table B-1) adk =.77 T, (f or spi (() / (hf.1, eq. 2.2-6 and Ref. 7, eq.1.4 11) a,,/k = (t/k adk)" - (97. 77 T,)" (Ref.1, eq. 2.2 5 alwi Ref. 2, eq. 2.1-16) --~ _- - _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

O_YENERA $UBJECT Verification of TOYPUIT and TOYEVAP PREPARED BY [ D ATE,3/8/93 LOTUS 12-3 Spreadsheets CHECKED BY dN-DATE 3 /vh5 / PROJECT hionticello Tosie Chemical Studv PRct.. sHtcT Or CONTROL l.D. NO. 1961-2.2-001 REv. O SHEET 27 OF 69 SHEETS l The value for D is calculated manually and entered as design input into T0XEVAP. Note: Exasuple 6-9 (ethyl alcohot): ng: Inputs: V = 29,200 gal Lons - 3.785 10' cm'/ gal ' on = 1.105 10' em' j (F10, irput) Note: Conversion c'.f fic!ent to em' obtained from Tabte A3 of Reference 4 DENi,= 0.789 g/cm' j / (Ref. 6, pg. C290) (F27, irput) I Cale: u,= V, DENS, = 1.105 10' D.789 / = 8.718 10' o / From T0XEVAP, = 8.718 10' g / / (F42, output) l A(t): Inputs: ny e 8.718 10' g DENS, = 0.739 g/cm',/ g = 981 cm/sec' (see Section 6.1.4) / l (F37, input) j DENS = 1.20 10 ' g/cm' (see section 6.1.4) / IF35, f rput] Cale: r, = (V,/s )"8 / ./ = (1.105 10*/s)"' = 327.6 cm From ToxEVAP, = 327.6 cm LT.50, output) A, = s-(327.6)8 = 3.3 73 10' cm' / l

O_TENERA y~ SUBJECT Verif"ication of TOYPITF and TOXEVAP PREPARED BY DATE 3/8/93 LOTUS 1-2 3 Spreadsheets CHECKED BY I h U _DATE N08} e PROJECT Mont;ceilo Toxic Chemical Studv PREL, SHEET OF CONTROL 1.D. NO. 1961-2,2-001 REV. O SHEET 28 OF 69 SHEETS From T0XEVAP, = 3.373 10' cm' (E53, output) / A,, = 2 r- (981 1.105 10'-(0.789-1.2 10')/(r 0.7893)"' s c = 1.166 10' cm'/sec / i From 10XEVAP, = 1.166 10' cm'/sec j IE57, output) A, = 1.105 10'/1 = 1.105 10' cm' / From T0XEVAP, = 1.105 10' cm' / t = ( l.105 10' 3.373 10')/1.166 10' o, = 94.48 see From TCXEVAP, = 94.46 sec / [E63, output) PPM Conversion: Inputs: R = 8.205 10' atm m'/ mote 'K IF33, Irvut] MW = 46.07 g/ mote / (Ref. 6, pc. C290) (F29,lrput] T, a 293.16*K (see sectie 1.2) s IF43, output) / P, = 1 atm (see section 6.1.2) / IF19, Irput] Cale: / o x(ppm) = x(g/m') 8.205 10* 293.16 10'/(46.171) = x(g/m') 522.1 /

O_TENERA SUBJECT Verification of TOYPlfFT and TOXEVAP PRET PIO BY 7 DATE 3/8/93 /A _DATE 3 e b CHECKED BY LOTUS 12 3 Spreadsheet 9 PROJECT Monticello Toxic Chemical Study PREL. SHEET OF CONTROL l.D. NO. 1961 2.2-001 REV. O SHEET 29 OF 69 SHEETS 'eca T0XEVAP, f = x(g/m') 522.11 / (E114, outrot) { dVdt: Irputs: U = 1 m/sec (see section 4.2) (F18, trymt] / / i = 100 cm/sec / L = 2 r(t) = 2-(A(t)/s)" A = 1.834 10 g/cm sec / d j (Ref. 6, pg. f 56, interpolated to 20*C) (r38, irput) / } DENS., = 1.20 10 g/cm' 8 / (see section 6.1.2) (F35, irput) P, = 0 m-Mg T, = 293.16*K / MV, = 28.84 g/ mot e t. ef.1, pg. A 7) 7 l MV, = 46.07 g/ mote / a, = 3.617 Angstroms (Ref.1, pg. A 7) e/k = 97'K (f or air f rom Ref.1, eq. 2.2 6) T = 516*K (Ref.13) I P, = 63.1 atm (Ref.13) j P, = 40 m-Hg W (Ref. 6, pg D172, value at 19't) I l Cate: a, = 2.44 -(516/63.1)"' = 4.916 Angstroms a., = (3.671 + 4.916)/2 = 4.293 Angstroms j </k = 0.77 516 = 397.3*K t /k = (97 397.3)" = 196.3*K / kf,/t., = 293.16/196.3 = 1.49 I f rom Table B-2 of Ref. 7: I l i

O_ HNERA SUBJECTJrification of TOXPUFF and TOXEVAP PREPARED BY I DATE 3/8/93 _! OTUS 12-3 SpreadshMtt CHECKED BY // X..DATE 3[d 5 a PROJECT Monticello Toxie Chemical Study PREL. SHEET or CONTROL 1.D. NO, 1961 2.2-001 Rev. O SHEET 30 oF 69 SHEETS

c. = 1.201 (based on Linear Interpolation)

D = 0.0018583-(293.16)*-(1/26.84 + 1/46.07)*/(14.293' 1.201) # = 0.10 ca'/sec < (F30, Irput) (Sc)'* = (1.834 10'/0.1 1.20 10 )'* / 8 = 1.152 y From T0XEVAP, = 1.152 / 1t45, output) As most spitts wlil spread to large areas, h, is conservatively calculated in 10XEVAP by using the turbulent model. A laminar model value of h, can be entered, if required, by modifying the equations f or ch/dt, h, and t,,,,, of 10XEVAP. (R e) = (2 r(t ) 100 1.20 10'*/1.834 10*)" / = 311.5 r(t)' / h, = 0.037 0.1 311.5 r(t)" 1.152/(2 r(t)) = 0.6639/r(t )' / c5/dt = (0.6639/r(t)* *) 46.07 A(t)-(40 0)/8.205 10 293.16 10* 760 Note:R converted f rom atm m'/ mote *K to m-Hg cm'/ mote 'K above using 10' em'/m' and 760mn-Hg/atm. = 6.692 10 A(t)/(( At t)/s)')" = 7.5 04 10 ' A( t )" / from T0XEVAP, = 7.503 10~' A(t)" / [E75, output) t: t is determined (as previously) by solving the f ollowing ecuation for t,,,,,: [ t,,,,, m, = 1 dm/dt dt 0 / [ t,,,,, =It7.503 10

• At t)' dt + J 7.503 10 *- ( A_)"* dt o.

0 t,,, / CNL*[g' Ag $ pgg : t,,,.., h WwO O h! N O f Shu%' g44 3l*fr) 1

O_TENERA SUBJECT Veriflention of TOXPtTFF and TOYEYAP PREPARED B I DATE 3/8/93 /DL.DATE 3!/0 3 CHECKED BY 1,OTUS 12 3 Sorendsheets 6 PROJECT Monticello Tosie Chemical Study PREL SHEET OF CONTROL l.D. No. 1961 2.2-001 REv. O SHEET 31 OF 69 SHEETS 7.503 10 '-( A, + Aco t)' *-(1/1.9)-(1/A )I + c = / 0

7. 5 03 10 ' A,,,,"- ( t,,,,,

t.,, ) t, = (m, 7.503 10-(1/1.9)-(1/Ac.) t( A, + Aca t )" - A,))/ f / (7.503 10

• A,,,,")

+ t,,,, = 67060 sec j From T0XEVAP, = 67060 sec # [E82, output) a and X: Inputs: x, = 3218 m (=2 miles) (F11, input] x, is unchanged from the chlorine exenple in Section 6.1.0 abova, the dispersion At coefficients for the continuous release remain unchanged. a, = 69.532 m (see section (.1.6) / 69.532 m (E91, output) = a, = 16.766 m (see section 6.1.6) 16.766 m [E99, output) / = As CR intake height is unchanged, the calculation of a is unchanged: rv 8av = 16.766 m (see section 6.1.6) Frczn T0xEVAP, = 16.766 m / [E102, outpst) / As A(t) is dif ferent, a,, will change as follows: ((69.532)' + a,,(t)')* (see section 6.1.6) a,y = a,,(t)' = (33.73 + 116.6-(t 3218))/4.38 m / for 3218 s t < 3312 a,m, = ((69.532)' + (597.6))* = 73.70 m / for 3312 5 t From T0XEVAP, = 73.704 m y [E106, outpJt) /

O_TENERA SUBJECT Verification of TOVPUFF and TOXEVAP PREPARED BY DATE 3/8/93 3!M/3 LOTUS 12-3 Spreadsheets CHECKED BY IU/ DATE 4 PROJECT Monticello Toxic Chemical Study PREL. SHECT OF CONTROL l.D. NO. 1961-2.2-001 P,EV. O SHEET 32 oF G SHEETS i x = (an/dt) 522.11-[1/(2 e 16.766 a,y(t) 1)] exp(0)-{expIO) + explo)) (prn) = (dn/dt)- [1/a,v(t)) 9.912 (ptn) t-Exa ples of values of x(prn) will now be calculated for each of the various time Intervalst 0 5 t < x,/U = 3218 sees x(t) = 0 ppm Frca T0XEVAP, = 0 ppu / / [s147 to 82955, output) t = 3220 sec [3218 s t < 3218 + (t = 94.48)): x(3220) = 7.503 10'-(3.373 10' + 1.166 10'-(3220 3218))"-(1/ [(69.532)8 + (33.73 + 116.6-(3220 - 3218))/4.3'1") 9.912 = 6.49 ppm / From T0XEVAP, 6.492 ppm / = [B2957, output) 3312 s t < 3312 + (t,, = 67060): x(t) = 7.503 10 '-(1.105 10')"-(1/73.70) 9.912 i I = 175.0 pom f From 10xEVAP, = 175.0 ppm (E3004 to aI399 and E137, output) As shown above, excellent agreement in values of x(t) between 10xEVAP and manual calculations are obtained. l 6.2.2 Buildp inside Control Roca As before, once the concentration outside the CR is known, inside concentration can be calculated as follows: Cc.( t.) = Cr..( t,,) + IX(t,) Cc,( to)) - [1 - exp( 1-(t,-tg} W/(60 Vc.)) (see Section 6.1.7 e

f. 2, eq. 2.4 2)

The above equation is used when no isolation is enployed and the exhau<.. = rate exiting the control room equals the air intake flow rate (W). An example of this approach is provided below which utilizes results from Appendly 3. The buildup and depletion between I various time steps were verified to ensure the at:ove equation was correctly incorporated into T0XEVAP. Three time intervals which cover dif ferent areas of X..,(t) were selected. l

O_TENERA PREPARED BY Nr DATE 4/16/93 SUBJECT Verincation of TOXPUFF and TOYEV AP CHECKED BY _ Mk DATE E b LOTUS 12-3 Snreadsheet4 v / < PREL. SHEET OF PROJECT Monticello Tos"ic Chemical Study CONTROL l.D. No. 1961-2.2-001 REV. I SHEET 33 OF 69 SHEETS Emanple 6-10: Inputs: W = 7440 cfm tr24, input) v. = 27000 f t* tr23, input) c Cc.(t,,) = obtained f rom Appendix 3 X,,,,(t,) = obtained f rom Appendix 3 t = 20 secondst x.,(20) = 0 ppm (D167, output) Cc.,,,,(19) = 0 ppm [C166, output) Cc.,(20) = 0 + (0 01-(1 exp( 1-(20

19) 7440/(60 27000)))

= 0 pprn From 10XEVAP, = 0 ppm [C167, output) t = 3220 seconds: X,,,,(3220) = 6.492 ppm [B2757, output) C .,(3218) = 9.234 10 ' ppm (C2956, output) c Cc.,(3220) = 9,234 10' + [6.492 - 9.234 10 1 - (1 exp(-1-(3220-3218) 7440/(60 27000))) 2 8 = 6.851 10 pan From T0XEVAP, 8 = 6.851 10 ppm (C2957, output) t = 23,000 seconds kote: at these later time steps t, t,.,= 100 seconds). X,,,,(23,000) = 175.0 ppm Is3341, output) C.,,,,(22,900) = 175.0 ppm [C3340, output) c Cc%,,,(23,000) = 175.0 ppm (C3341, output) As the above example demonstrates, the equation which models chemical buildup and The subsequent depletion in the control room was correctly incorporated into T0xEVAP. value itself (i.e., 175.0 ppm) is insignificant since the TLV for ethyl alcohot is 1000 ppm k (9eference 14). The results above clearly indicate tFat the concentration of the chetnical realized in the CR never reaches the TLV and, therefore, cannot pose a threat. Reference 14 also notes that the. threshold for detection is 180 ppm and that the threshold for recognition is 100 ppn. (Note: The fact that the recognition value is less than the detection value is a reflection of the statistical approach used in Reference 14, involving an averaging of various cheenical studies to obtain the published results. If the higher value was conservatively used for the detection threshold, the conclusions would not -_m___,______m__

O"TENERA ~ SUBJECT Verification of TOXPUFF nnd TOKEVAP PREPARED BY [ DATE 4/16/93 LOTUS 1-2-3 Snreadsheets CHECKED BY N DATE V b h PROJECT Monticello Toxic Chemical Study PREL. SHEET OF E CONTROL l.D. NO. 1961-2.2-001 REV. I SHEET 34 OF 69 SHEETS change). bith the maxirrasn concentration f alling within this range, operators will be alerted to the need to consider taking protective actions, even though they will not be exposed to an incapacitating quantity. 7.0 Ct*CLUS10WS The T0XPUFF and 10XEVAP spreadsheets have been verified to provida reliable results when compared to manual calculations for the examples of chlorine and ethyl alcohol, respectively. Based on the results for the two exanples, the following conclusions can be drawn: Chlo*inet A conservative detection level of 1 ppm is used, even though Ref erence 14 cites a value of 0.08 ppn. The concer/: ration in the CR reaches the 1 ppm levet at time equals 2970 seconds after the spilt from the railroad car 2 miles away. The incapacitation analysis performed indicates that an incapacitating concentration in the CR is reached at time equats 3106 seconds after the spill. The time span between detection and reaching an incapacitating concentration is 136 seconds (2 minutes and 16 seconds). This exceeds the timit of 2 minutes set in RG 1.78, meaning that operators have sufficient time to take protective actions. Using the conservative detection Level of 1 ppm (verses the mere realistic 0.08 ppm value) means that operators would actually have more time to respond to the potential threat. Because the 2 minute limit is exceeded, automatic detection for Chlorine is not required. Ethyl At eohel; The concentration in the CR never exceeds 175.0 ppm over the eight hour period modeled which, when corrpared to the TLV value of 1000 ppm, indicates that CR operator incapacitation will not occur. The maxismam concentration seen in the CR (i.e.,175 ppn) is within a range that will alert operators that a forlegn substance is present and that protective actions may be appropelate, even though the analysis shews that an incapacitating concentration will not be reached. Therefore, automatic detection for Ethyl Alcohol is not required. 8.0 FtfTURE NEEDS None. t 9.0 A wENDICES arrf ATTACHMFNTS 9.1 App W ices 1. TCXPUFF Results for Chlorine Example 2. T0XPUFF Formula Listinw 3. T0XEVAP Results for Ethyl Alcohol Example 4. T0XEVAP Formula Listing 9.2 Attachments None.

10.0 REFERENCES

1. "Morticello Nuclear Generating Plant, Main Control Room Toxic Chemical Study", prepared by Bechtel Power Corporation, January, 1981. Submitted as Attachment 4 in response to NUREG-0737, DSS Sequence Number M.IS00962. 2. NUREG-0570, " Toxic Vapor concentration in the Control Room Following a Postulated Accidental Release," June, 1979. 3. NUREC/CR-1741, "Models for the Estimation of incapacitation Times Following Exposures to 4 Toxic Cases or vapors," December, 19B0. l

- GTENERA SuaJECT Verification of TOXPUFF and TOXEVAP PREPARED BY [ DATE 4/2d/93 78lb LOTUS 12-3 Spreadsheets CHECKED BY [ DATE j w PROJECT Monticello Toxic Chemical Shdv PREL. SHFET __ OF CONTROL l.D. N O. 1961 2.2-001 REV. 2 SHEET 35 OF fW SHEETS 4. bineerino Thermtyyty, second edition, tsy Wittime C. Reynolds and Henry C. Perkins, 19TT. 5. Monticette uclear Generating Plant, Operations Manual section B.S.13 02, Description of Equipnent, Revision 1. i. j 6. Handbook of Chmistry and *hystes, CRC Press, 55th Edition, 1974 1975. 7. Transport phenmena, R. Byron Bird, et al., copyright 1960. 8. Meteorology and Atomic Energy 1968, TID 24190, edited by David H. Stade. 9. NRC Regulatory Guide 1.78, "Assunctions for Evaluating the Habitability of a Nuclear Power Plant Control Room During a Postulated Hazardous Chemical Release," June 1974. 10. Monticello Nuclear Generating Plant, Updated Safety Analysis Report. 11. SRI 90-013, " Justification for Closing VD 9094A and VD-90948", DSS Sequence Nat2er PxR00802. 12. CATx Tank Car Manual, 5th Edition, pub!!shed by General American Transportatiori corporation, j 13. Perry's Chemicet Engineer's Handbook. Fourth Edition, published by McGraw-Hit t. 2 45 14 Oder thresholds for Chemicals with Established occunationst Health Standards, published by the American Industrial Hygiene Association, copyright 1989. 15. Monticet to Drawing NF-93486, Rev. B. 16. NSP Letter, dated 4/22/93. Dirk Foster to David Sexton, "Monticello Toxic Chemical Study 21 Update, Calculation 196101 2.2, control volune and Design Fresh Air Intake Input Concerns," N TENERA Control 10 No.196101-2.4-048.

O_TENERA SUBJECT Verificatinn of TOXPUFF and TOXEVAP - 2 PREPARED BY

1. DATE 3/8/93 CHECKED BY 4 DATE '>h&NS LOTUS 1-2-3 Sorendsheets PROJECT Mnnticelin Tmic Chemical Study PREL. SHEET OF

= CONTROL I.D. NO. 1961-2,2-001 REV. O SHEET 36 Or 69 SHEETS APPENDIX 1 TOXPUFF Results for Chlorine Because of the size of the spreadsheet (tength and width), the following r.rintout has been blocked in Note: ranges. The range is cited before each block. Range: A1 - G200 A A B C D E F G 1 Toxic Chemical Spill Calculation 2 (For chemical boiling point less than anbient terperature) 3 4 Last Updated: 5 Mar-93 Analyzed Chemical: Chlorine 5 6

==========================================================

7 Design inputs: 8 9 Spill Data: / 10 Container votume (VC, cm"3): 5.204E+07 11 Spilt to CR Intake Distance (x0, m): 3218.0 12 Spill type: Circular / 13 14 15 Meteorological Data: 16 Pasquill's Stability Category: G / 17 Arnblent Tenperature (Tac, degrees C): 20 18 Wind Speed (U, m/sec): 1 / 19 Air Pressure (PA, atm): 1 / 20 21 Control Room Data: 22 control Room HvAC Intake Height (z, m): 11.28 23 control Room volune (CRV, f t"3): 2.700E+04 24 CR HVAC Intake Rate (CF:N, f t."3/ minute): 7440 / 25 26 Chemical Data: 27 Chemical Density (DENS, g/ca"3): 1.570 28 Bolling Point (Tb, degrees C): 34.1 ' 29 Molecular Weight (MW, g/ mote): 70.90 # 30 Heat capacity (Cp, cal /g degree C): 0.226 f r itation (Hv, cal /g): 68.8 31 Heat of Va r 32 33 Constants: / 34 Ideal Gas constant (R, atm-m"3/ mote-degrte K): 8.20SE 05 35 Air Density (DAIR, g,cm**3, 7 36 at 1 atmosphere r M 20 degrees C): 1.20E-03 37 P1: 3.1415927 # 38 Gravitational Constant (G, em/sec"2): 981 ' 39 Forced Convection heat Transfer Coefficient f 40 (he, cal /cm"2 see-degree C): 1.6E 04 7 41 Atmos. and Solar Heat Flux (qr, cal /cm"2-sec): 2.12E 02 42 43 Calculated Design Inputs: 44 45 Initial Chemical Mass (MT=VC* DENS, g): 8.170E+07 46 Ambient Temperature (Ta=Tec+273.16, degrees K): 293.16 47 Chemical Boiling Point (Tb, degrees K): 239.06 48 Ground (Earth) Temperature (Te=Ta): 293.16 1

<?f!!)1rl!IklEilqLilt sdBJECT Verification of TOXPUFT and TOYEVAP PREPARED BY I DATE 3/8/93 LOTUS 1-2-3 Spreadsheets CHECKED BY /(I-DATE5/4h 0 PROJECT Monticello Toxic Chemical Study PREL. SHEET OF CONTROL 1.D. NO. 1961 2.2-001 REV. 0 4HEET 37 , OF 69 SHEETS 49 50====================================================================== 51 Chemical Mass Calculations: 52 53 Mass of Inittet Puf f Release (MO, g) = MT*Cp*(Ta-Tb)/Hy 54 = 1.452E+07 55 56 Renmining Mass (MR, g) = MT M0 57 = 6.718E+07 e 58====================================================================== 59 Spill Area Calculations: 60 61 Initial Spill Radius (RO, cm) = (MR/(DENS *PI))**(1/3) 62 = 2.388E+02 j-63 64 Initial spilt Area (AO, em**2) = Pl*(RO**2) 65 = 1.792E+05 66 67 Area Change Rate (ACH, cm**2/sec) = Pl*2*(g*(MR/ DENS)* 68 = (DENS DAIR)/(DENS *PI)]**1/2 69 = 7.260E*05 70 71 Maximum spill Area (Amax, cm**2) = (MR/ DENS)/1 cm 72 = 4.279E+07 ,, / 73 74 Time When Amax Reached (imax, see) = ( Amax AO)/ACH = 58.69 75 i 76====================================================================== 77 Mass vaporization Rate Calculation 78 79 Mass vaporization Rate (V(t), 80 g/see-em**2) = V0+VCM/(t**(1/2)) 81 where: 82 VO (g/sec-em**2) = (qr+hc*(Ta Tb))/Hy 83 = 4.340E 04,/' B4 85 VCH (g/cm**2'sec'*(1/2)) = 197*(Te-Tb)/(Hv'10,000) 86 = 1.549E 02 87

=rs=======================================================

88 Calculation of Sigmas (Dispersion coef ficients) 89 90 Spill Vapor Density (DVAP, g/m**3) = (MW'PA)/(R*Ta) ' 91 = 2.94BE+03 92 93 Initial Puf f Std. Dev (SIG0, m) = (M0/((2**(1/2))*(Pl**(3/2))* 94 DVAP))**(1/3) 8.552 95 = 96 97 Pasq.-Gif f. Y Disp Coef f tog (SIGY, m) = A+B* log (x0)+C*(tog (x0))**2 98 +D*( L og(x0))**3 99 where: A= -1.6212 100 B= 1.0648 101 C = -0.014857 102 0 = -0.002056 103 $10Y = 69.532 104 105 Pasq.-Gif f. Z Disp Coef f tog (SIGZ, m) = A+B* tog (x0)+C*(tog (x0))**2 106 +0*(tog (x0))**3 107 where: A= -1.8981 108 e= 1.1243 109 C = -0.0364J.7

- S_TENERA -- _ usuaa - O SUGJECT Verification of TOXPUFF and TOYEVAP PREPARED BY di7 DATE 3/8/93 CHECKED BY Ab DATE /C } LOTUS 12-3 Spreadsheeft PROJECT Monticello Tmic Chemical Study PREt SHEET OF CONTROL 1.D. NO. 1961 2.2-001 REv. O SHEET 3R or 69 sHtETs e-110 D = -0.008635 111 $1C2 = 16.766 / 112 113 Inst Puf f Y Disp Coef f (SIGYI, m) = (51Gf"2+slG0"2)"(1/2) 70.056,/ = 114 115 116 Inst Puff x Disp Coeff ($1CXI, m) = flGYI 70.vi6 / = 117 118 119 Inst Puf f 2 Disp Coef f ($1GZl, m) = ($1czu2*stC0"2)"(1/2) 18.821 / = 120 121 122 Cont actease Disp Coef f (slGZM. m) = (slG:) 16.766 /, = 123 124 125 Cont Retense Disp Coef f (SICYM. m) = (slGY"2+(Ref f *Pl"(1/2)/4.3) 126

• • 2)"(1/2) 71.177 (at Amax)

= 127 128 Note: 129 for Circular spitt, Reff = (A(t)/PI)'*(1/2) 130 131 132====================================================================== 133 Conversion of g/m"3 to ppm 134 135 Conversion to PPM (PPM, ppn/(g/m"3)) = (R*ta*1.0E+06)/(MJ*Pa) 339.26 / = 136 137

========6.================================================

138 Calculation of Puff Concentration Outside Control Room 139 140 Puff Conc a CR Intske (CRP(t), ppm) = (M0/(2"(3/2)* (PI )* * (3/2)* SI GX 141 SIGYl'slGZI))*exp( 1/2*x"2/ 142 where t=h=0 for DVAP>DAIR, $1Gxt"2)*(exp( 1/2*( h)**2/ 143 2=h f or DVAP<DAIR, S t G21"2] + exp (- 1/2* ( z+ h)"2/ 144 y=0, and x=x0 U*t SIGZl"2])* PPM 145

==============rar=========================================

146 Calculation of Contirnous Release Conc outside Control Room 147 148 Cont Cone a CR Intake (CRC (t), ppm) = ( A0+ ACH*t)*(V0+VCH/t"(1/2))* 149 (1/(2*Pl'U*$lGYM*SIGZM))*(exp[ 150 where zah=0 f or DVAP>DAIR, 1/2*(z h)"2/SIGZM"2)+exp[ 151 t=h for DVAP<DAIR, - 1/2* ( z+h )"2/ s1 CZM"21)* PPM 152 y=0, A0+ACH*t=Amax for 153 t>Tmax, and t=t-x0/U 154 Notes CRC (t)=0 for t<x0/U and for t> time when entire spilt evaporates 155 plus x0/U (Tgone+1 max +x0/U) 156====================================================================== 157 Calculation of Entire $ pill Evaporation Time 158 159 spill Mass Released by time tifmax 160 (MAmax, g) = V0* A0*tmax+VO* ACH*(Tmax"2)/ 161 2+2*VCH*A0*(imax**(1/2))+VCH* 162 ACH*(imax**(3/2))*2/3 163 = 3.961E+06 / 164 165 Note: If MAmax > MR, Tgone is determined by solving the following 166 equation for Igone: 167 168 MR = VO*A0*Tgone+VO* ACH*(Tgone* *2)/2+2*VCH+ A0*(T gone" 169 (1/2))+VCH*ACH'(Tgone**(3/2))*2/3 170

O_TENERA c SUBJECT Verification of TOYPUFF and TOYEVAP PREPARED BY DATE 3/R/911 [O LOTUS 12-3 Spreadsheets CHECKED BY.p f DATF PROJECT Monticello Toxic Chemical Study PREL. SHEET OF _ CONTROL 1.D. N O. 1961-2,2-001 REv. O SHEET 39 OF 69 SHEETS 1/1 Note: If MAman a MR, toone is determined by solving the following 172 equation for Tg oes 173 174 MR MAmax = VD' Amax*Tgone+VCH*Amax*(Toone"(1/2))*2-175 Arnax*Tman*v0 Amax*vCH'2*(iman)"(1/2) 176 Note: Due to he interative nature of solving for Tgone, it is 177 conputed manually and entered into the appropriate cett, 178 Amax = 4.279E+07 VCH = 1.549E 02 imax = $8.7 170 VD = 4.340E*04 MR MAmax =6.322E+07 MR KAmaxc=6.322E+07 180 Tgone (sec) = 1368.8 # 181

===========================================================r

182 Calculation of Concentration inside Control Room I 183 Concentration in the CR is corputed in a time step-by-step 184 manner by adding the the inside CR concentration Wth pJf f 185 ard continuous) at the previous time step to the o..ference 186 between the current outside concentration minus the p.vious 187 inside concentration times an exponential buitdup f actor. 1M 189 190====================================================================== 191 Analysis Results ha 0 / 192 Chemical Analyzed: Chlorine 193 Outside Outside Total Inside inside Total 194 CR Cone CR Conc outside CR Conc CR Conc Inside 195 Puff Continuous CR Cone Puff Continuous CR Conc 196 Time (sec) (ppn) (ppn) (ppm) { ppm) (ppn) (ppm)

=

197=============== y===== 198 0 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 199 1 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 200 2 0.000E+00 0.000E+00 0.000E+00 0.000C+00 0.000E+00 0.000E+00 Range: H180 - Q190 A H I J K L M 180 \\m (L.ET G179,C179*C178*E180+E178'C178*2*(E180*(1/2)) C178*C179*G178-C178*E17B*2*(C178"(1/2))) 181 182 183 184 185 186 187 188 Constant for outside Puff: 6.772E+03 189 Constant for Cont, w/Amaxt 3.872E+06 190 Constant for Contin. A(t): 6.785E*02 Range: A2800 - c3450 A A B C D E F G 2800 2S04 1.767E-04 0.000E+00 1.767E-04 9.69BE-06 0.000E+00 9.698E 06 2801 2806 2.091E 04 0.000E+00 2.091E 04 1.152E-05 0.000E+00 1.152E-05 2802 2808 2.473E-04 0.000E+00 2.473E 04 1.368E-05 0.000E+00 1.36eE 05 2803 2810 2.921E-04 0.000E+00 2.921E 04 1.622E 05 6.000E+00 1.622E-05 2804 2812 3.448E-04 0.000E+00 3.448E-04 1.923E-05 0.000E+00 1.923E 05 2805 2814 4.067E 04 0.000E+00 4.067E-04 2.277E-05 0.000E+00 2.277E 05 2806 2816 4.793E-04 0.000E+00 4.793E-04 2.694E 05 0.000E+00 2.694E-05 2807 2818 5.644E-04 0.000E+00 5.644E 04 3.186E 05 0.000E+00 3.186E 05

O_TENERA l SUBJECT Verification of TO\\ TUFF and TOXEV AP PREPAl.EC eV ~~ DATE 3/8/93 LOTUS 14 3 Spread (httts CHECKED BY J DATE f3 PROJECT Monticello Tmic Chnnical Studs PREL. SHEET OF CONTROL 1.D. NO. 1961-2.2 001 REV. O SHEET 40 OF 69 SHEETS 2808 2820 6.640E 04 0.000E+00 6.640E 04 3.764E 05 0.000E+00 3.764E 05 2809 2822 7.806E-D4 0.000E+00 7.806E-04 4.443E*05 0.000E+00 4.443E-05 2810 2824 9.169E D4 0.000E+00 9.169E 04 5.241E 05 0.000E+00 5.241E-05 2811 28261.076E 03 0.000E+001.076E 03 6.177E 05 0.000E+00 6.177E-05 2812 2828 1.262E-03 0.000E+00 1.262E 03 7.274E 05 0.000E+00 7.274E-05 2813 28301.479E 03 0.000E*001.479E 03 8.560E-05 0.000E+00 8.560E 05 2814 2832 1.731E 03 0.000E+00 1.731E-03 1.006E 04 0.000E+001.006E 04 2815 2834 2.026E-03 0.000E+00 2.026E 031.182E D4 0.000E+001.182E D4 2816 2836 2.368E-03 0.000E*00 2.368E 031.388E C 900E+00 1.388E 04 2817 2838 2.765E-03 0.000E+00 2.765E 03 1.628E D4 J00E +00 1.628E-D4 2818 2B40 3.227E-03 0.000E+00 3.227E 03 1.909E 04 0.000E+00 1.909E D4 2819 2B42 3.763E 03 0.000E+00 3.763E 03 2.235E 04 0.000E+00 2.235E D4 2820 2844 4.385E-03 0.000E+00 4.385E 03 2.616E-04 0.000E+00 2.616E 04 2821 2S46 5.104E 03 0.000E+00 5.104E 03 3.058E 04 0.000E+00 3.058E-04 2822 2848 5.938E 03 0.000E+00 5.938E-03 3.573E-04 0.000E+00 3.573E 04 2823 2850 6.901E 03 0.000E+00 6.901E 03 4.172E 04 0.000E+00 4.172E-04 2824 2852 8.014E-03 0.000E+00 8.01&E 03 4.866E 04 0.000E+00 4.866E-04 2825 2854 9.300E 03 0.000E+00 9.300E 03 5.672E 04 0.000E+00 5.672E 04 2826 28561.078E 02 0.000E+001.078E 02 6.606E 04 0.000E+00 6.606E 04 2827 2858 1.249E 02 0.000E+00 1.249E 02 7.688E 04 0.000E+00 7.688E-04 2828 2860 1.446E 02 0.000E+00 1.446E 02 8.939E 04 0.000E+00 8.939E 04 2829 2862 1.672E-02 0.000E+00 1.672E 02 1.039E 03 0.000E+001.039E 03 2830 2864 1.933E 02 0.000E+00 1.933E 02 1.206E 03 0.000E+00 1.206E 03 2831 2866 2.232E-02 0.000E+00 2.232E-02 1.399E 03 0.000E+00 1.399E 03 2832 2868 2.575E 02 0.000E+00 2.575E 02 1.621E 03 0.000E+001.621E 03 2833 2870 2.968E 02 0.000E+00 2.968E 02 1.878E-03 0.000E+00 1.878E 03 2834 2872 3.419E 02 0.000E+00 3.419E 02 2.173E 03 0.000E+00 2.173E 03 2835 2874 3.935E-02 0.000E+00 3.935E 02 2.513E 03 0.000E+00 2.513E 03 2836 2876 4.526E 02 0.000E+00 4.526E-02 2.904E-03 0.000E+00 2.904E 03 2837 2878 5.200E 02 0.000E+00 5.200E 02 3.353E 03 0.000E+00 3.353E 03 2838 2880 5.971E 02 0.000E+00 5.971E 02 3.868E 03 0.000E+00 3.868E 03 2839 2882 6.849E 02 0.000E+00 6.B49E 02 4.459E 03 0.000E+00 4.459E 03 2840 2884 7.851E-02 0.000E+00 7.851E 02 5.136E 03 0.000E+00 5.136E-03 2S41 2886 8.992E 02 0.000E+00 8.992E-02 5.912E-03 0.000E+00 5.912E-03 2842 2888 1.029E 01 0.000E+00 1.029E 01 6.798E 03 0.000E+00 6.79BE-03 2843 2890 1.177E-01 0.000E +00 1.177E -01 7.812E -03 0.000E+00 7.812E-03 2S44 2892 1.344E-01 0.000E+00 1.344E 01 8.970E-03 0.000E+00 8.970E-03 2S45 2894 1.535E 01 0.000E+00 1.535E-01 1.029E-02 0.000E+00 1.029E*02 2B46 2896 1.751E 01 0.000E+00 1. 751E 01 1.180E 02 0.000E+00 1.180E-02 2547 2898 1.995E-01 0.000E+00 1.995E-01 1.351E 02 0.000E+00 1.351E 02 2S48 2900 2.273E-01 0.000E+00 2.273E-01 1.547E-02 0.000E+00 1.547E 02 2849 2902 2.586E 01 0.000E+00 2.586E-01 1.769E-02 0.000E+00 1.769E 02 2850 2904 2.940E 01 0.000E+00 2.940E-01 2.022E-02 0.000E+00 2.022E 02 2851 2906 3.340E-01 0.000E+00 3.340E 01 2.309E-02 0.000E+00 2.309E-02 2852 2908 3.791E 01 0.000E+00 3.791E-01 2.634E 02 0.000E+00 2.634E 02 2853 2910 4.300E-01 0.000E+00 4.300E-01 3.003E 02 0.000E+00 3.003E-02 2854 2912 4.873E 01 0.000E+00 4.873E 013.421E 02 0.000E+00 3.421E-02 2855 2914 5.518E 01 0.000E+00 5.518E 01 3.895E-02 0.000E+00 3.895E-02 2856 2916 6.243E 01 0.000E+00 6.243E-01 4.430E-02 0.000E+00 4.430E-02 2857 2918 7.058E 01 0.000E+00 7.05BE 01 5.035E 02 0.000E+00 5.035E-02 2858 2920 7.973E 01 0.000E+00 7.973E 01 5.718E 02 0.000E+00 5.718E 02 2859 2922 8.998E-01 0.000E+00 8.998E 01 6.488E-C' O.000E+00 6.488F-02 2860 29241.015E+00 0.000E+001.015E+00 7.357E 02 0.000E+0087 357E 02 g 2861 2926 1.143E+00 0.000E+00 1.143E+00 8.335E 02 0.000E+00 8.335E-02 2862 2928 1.287E+00 0.000E+00 1.287E+00 9.436E 02 0.000E+00 9.436E-02 2863 2930 1.448E+00 0.000E+00 1.448E+00 1.067E 01 0.000E+00 1.067E-01 2864 2932 1.62BE+00 0.000E+00 1.628E+00 1.206E 01 0.000E+00 1.206E 01 2865 2934 1.829E+00 0.000E+00 1.829E+00 1.363E 01 0.000E+00 1.363E 01 2866 2936 2.052E+00 0.000E+00 2.052E+00 1.53BE 01 0.000E+00 1.538E-01 2867 2938 2.301E+00 0.000E+00 2.301E+00 1.734E-01 0.000E+00 1.734E 01 2868 2940 2.578E+00 0.000E+00 2.57BE+00 1.954E 01 0.000E +00 1.954E 01

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• 2621 L'5223+01 0'0003+00 L *2E93+01 L *t993+00 00003+00 l'9293+0 2995 t993+00 2629 t 2C93+ot 0' 2999 2629 t'*6L53+OL 0'0003+00 L*6L53+0L L*9293+00 0'0003+00 l' 2992 2999 2690 2* tt t3+ot 0*0003+00 2*LL L3+ at L *9093+00 0'0003+00 l'9093+00 2996 2692 2*t253+ot 0*0003+00 2*E253+ot 2*0023+00 0*0003+00 2*0023+00 0003+00 2'5563+01 2*2t93+00 0 0003+00 2*2L93+00 2697 2'5563+ot 0'0003+00 2*9Lt3+ot 2*t553+00 00003+00 2*t553+00 2960 2699 2*9Lt3+01 0' 296L 0003+00 2*2L53+00 2699 C*06L3+010'0003+00 C*06t3+OL 2*2t53+00 0'0003+00 E*00L3+00 2962 2660 C* tot 3+01 0'0003+00 C*t6?3+01 t'0013+00 0' 296f 2961 2662 C* 22f3 +01 0'0003+00 t*22E3+ot C *ELt3+00 0'0003+00 C *ttt3+00 2865 266? t'0903+OL 0'0003+00 1'0903+01 t'9593+00 0'0003+00 t'9593+00 0003+00 t't993+01 t*0f 23+00 0'0003+00 ?*0123+00 2669 t*t993+OL O' 0003+00 ?'9603+ot ?*?t23+00 0'0003+00 t'1723+00 2969 2669 t*0603+OL 0' 2962 2969 E000 5*tt93+OL 0'0003+00 5*t793+01 t'0603+00 0'0003+00 1*9603+00 2966 E002 5
• 9703+OL o*0003+00 S'9?03+01 5 *t263+00 0'0003+00 S *1263+00 2600 1007 9*E253+OL 0 0003+00 9'E253+OL S'6Lt3+00 0'0003+00 5 *6113+00 2601 t009 9*6513+0t 0'*0003+00 9'65E3+OL 9'7653+00 0'0003+00 9*1653+00 0003+00 2*t293+00 t009 2*5223+OL 0'0003+00 2*5223+ot 2* t293+00 0'0003+00 2*9L23+00 2602 1010 9*25 L 3+ot 0'0003+00 8'25L3+ot 2* 9123 +00 0' 2601 5923+00 0*0003+00 8'5923+00 E012 9*6223+010'0003+00 9'6223+OL 8't9t3+00 0'0003+00 6'f9L3+00 1

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2609 E022 t *t523+02 0*0003+00 L *E523+02 L

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26t2 9t63+02 0'0003+00 L *9t63+02 L *9923+OL 0 t0EC L'6653+02 0'0003+00 t*6653+02 2'0523+OL 00003+00 2'0523+OL 26LC l 26Lt 10EZ L* 26LS E0tt 2*L523+02 0 0003*00 2* t523+02 2'2t03+OL 0'0003+00 2*2E03+01 EDE9 2 *Et93+02 00003+00 2 *tt93+02 2 *92t3+01 0'0003+00 2*12L3* 'L 26L9 26L2 10ES 2*7693+02 0'0003+00 2*7693+02 2*9223+OL 0'0003+00 2'9223+OL 0003+00 2'9953+02 2 9163+ot 0'0003+00 2*9163+OL COTO 2*9953+02 0'0003+00 2*9953+02 E'*0921+OL 0*0003+00 E*0923+ot 26L9 E072 2*9953+02 0'0003+00 E'0663+02 t'Et23+010'0003 00 E 9L53 2ot6 tc?? E'0663+02 0' 0003+00 E*t723+ot 2620 E079 E*E253+02 0'0003+00 E t253+02 E'9L53+OL 0 + 262L 1079 t'5953+02 0'0003+00 E5953+02 E'6093+01 00003+00 E*6093+OL 2622 262E E050 E"9t63+02 0'0003+00 E'9t63+021*22t3+OL 0'0003+00 t'22L3+0L 2621 E052 t*0993+02 0*0003+00 t'0993+02 t'5s23+ot 0'0003+001*5523+OL 2625 EOST 1*E223+02 0'0003+001*E223+02 t'6t53+OL 0'0003+00 t'6L53+01 2629 C059 t'9zE3+02 0'0003+00 t'92E3+02 5 *2623+01 0'0003+00 5 *2623+OL 2622 E059 1*6961+02 C*0003+00 ?*6963+02 S'2053+OL 0'0003+00 5*2053+DL 0003+00 S EZE3+02 9* LE63+OL 0*0003+00 9*tE63+01 E090 5*C2E3+02 0'0003+00 S9253+02 9'9023+OL 0*0003+00 9'9023+OL 2629 E092 S'9253+02 0* 2626 4

O_TENERA SUBJECT Verification of TOVPUFF and TOYEVAP PREPARED BY I _ DATE 3/R/93 LOTUS 12 3 Spreadtheett CHECKED BY M-- DATE N8 D PL3 JECT Monticello Tmic Chemical Study PREL SHEET OF CONTROL l.D. NO. 1961-2,2-001 REv. O SHEET 42 OF 69 _ SHEETS 2930 3064 6.045E+02 0.000E+00 6.045E+02 7.094E+01 0.000E+00 7.094E+01 2931 3066 6.434E+02 0.000E+00 6.434E+02 7.618E+01 0.000E+00 7.618E+01 2932 3068 6.842E+02 0.000E+00 6.842E+02 8.174E+01 0.000E+00 8.174E+01 2933 3070 7.271E+M 0.000E+00 7.271E+02' 8.764E+01 0.000E+00 8.764E+01 2934 3072 7.720E+02 0.000E+00 7.720E+02 9.390E+01 0.000E+00 9.390E+01 2935 3074 8.189E+02 0.000E+00 8.189E+02 1.005E+02 0.000E+00 1.005E+02 2936 3076 8.681E+02 0.000E+00 8.681E+02 1.075E+02 0.000E+00 1.075E+02 2937 3078 9.194E+02 0.000E+00 9. '.94E+02 1.150E+02 0.000E+00 1.150E+02 2938 3080 9.730E+02 0.000E+00 9.730E+02 1.228E+02 0.000E+00 1.228E+02 2939 3082 1.029E+03 0.000E+00 1.029E+03 1.311E+02 0.000E+00 1.311E+02 2940 3084 1.087E+03 0.000E+00 1.087E+03 1.398E+02 0.000E+00 1.398E+02 2941 3086 1.148E+03 0.000E+00 1.14BE+03 1.491E+02 0.000E+00 1.491E+02 2942 3088 1.211E+03 0.000E+00 1.211E+03 1.588E+02 0.000E+00 1.588E+02 2943 3090 1.276E+03 0.000E*00 1.276E+03 1.690E+02 0.000E+00 1.690E+02 2944 3092 1.344E+03 0.000E+00 1.344E+03 1.797E+02 0.000E+00 1.797E+02 2945 3094 1.414E+03 0.000E+00 1.414E+03 1.910E+02 0.000E+00 1.910E+02 2946 3096 1.487E+03 0.000E+00 1.487E+03 2.02BE+02 0.000E+00 2.028E+02 2947 3098 1.562E+03 0.000E+00 1.562E+03 2.153E+02 0.000E+00 2.153E+02 2948 3100 1.639E+03 0.000E+00 1.6J9E+03 2.283E+02 0.000E+00 2.283E+02 2949 3102 1.719E+03 0.000E+00 1.719E+03 2.419E+02 0.000E+00 2.419E+02 2950 3104 1.802E+03 0.000E+00 1.802E+03 2.562E+02 0.000E+00 2.562E+02 2951 3106 1.887E+03 0.000E+00 1.887E+03 2.711E+02 0.000E+00 2.711E+02 2952 3108 1.974E+03 0.000E+00 1.974E+03 2.867E+02 0.000E+00 2.867E+02 2953 3110 2.064E+03 0.000E+00 2.064E+03 3.029E+02 0.000E+00 3.029E+02 2954 3112 2.156E+03 0.000E+00 2,156E+03 3.198E+02 0.000E+00 3.198E+02 2955 3114 2.250E+03 0.000E+00 2.250E+03 3.375E+02 0.000E+00 3.375E+02 2956 3116 2.346E+03 0.000E+00 2.346E+03 3.559E+02 0.000E+00 3.559E+02 2957 3118 2.445E+03 0.000E+00 2.445E+03 3.750E*02 0.000E+00 3.750E+02 2958 3120 2iS46E+03 0.000E+00 2.546E+03 3.948E+02 0.000E+00 3.94BE+02 2959 3122 2.648E+03 0.000E+00 2.648E+03 4.154E+02 0.000E+00 4.154E+02 2960 3124 2.753E+03 0.000E+00 2.753E+03 4.368E+02 0.000F+00 4.368E+02 2961 3126 2.859E+03 0.000E+00 2.859E+03 4.589E+02 0.000E+00 4.589E+02 2962 3128 2.967E+03 0.000E+00 2.967E+03 4.810E+02 0.000E+00 4.819E+02 2963 3130 3.077E+03 0.000E+00 3.077E+03 5.056E+02 0.000E+00 5.056E+02 2964 3132 3.188E+03 0.000E+00 3.188E+03 5.301E+02 0.000E+00 5.301E+02 l l 2965 3134 3.300E+03 0.000E+00 3.300E+03 5.554E+02 0.000E+00 5.554E+02 2966 3136 3.414E+03 0.000E+00 3.414E+03 5.816E+02 0.000E+00 5.816E+02 l 2967 3138 3.528E+03 0.000E+00 3.528E+03 6.085E+02 0.000E+00 6.085E+02 2968 3140 3.644E+03 0.000E+00 3.644E+03 6.363E+02 0.000E+00 6.363E+02 r 2969 3142 3.760E+03 0.000E+00 3.760E+03 6.648E+02 0.000E+00 6.640E+02 2970 3144 3.876E+03 0.000E+00 3.6T6E+03 6.942E+02 0.000E+00 6.942E+02 l 2971 3146 3.993E+03 0.000E+00 3.993E+03 7.243E+02 0.000E+00 7.243E+02 2972 3148 4.111E+03 0.000E+00 4.111E+03 7.553E+02 0.000E+00 7.553E+02 2973 3150 4.228E+03 0.000E+00 4.228E+03 7.871E+02 0.0005+00 7.871E+02 2974 3152 4.345E+03 0.000E+00 4.345E+03 8.196E+02 0.000E+00 8.196E+02 2975 3154 4.462E+03 0.000E+00 4.462E+03 8.529E+02 0.000E+00 8.529E+02 2976 3156 4.578E+03 0.000E+00 4.578E+03 8.869E+02 0.000E+00 8.869E+02 2977 3158 4.693E+03 0.000E+00 4.693E+03 9.217E+02 0.000E+00 9.217E+02 2978 3160 4.807E+03 0.000E+00 4.807E+03 9.573E+02 0.000E+00 9.573E+02 2979 3162 4.920E+03 0.000E+00 4.920E+03 9.935E+02 0.000E+00 9.935E+02 2980 3164 5.031E+03 0.000E+00 5.031E+03 1.030E+03 0.000E+00 1.030E+03 2981 3166 5.141E+03 0.000E+00 5.141E+03 1.068E+03 0.000E+00 1.06BE+03 2982 3168 5.249E+03 0.000E+00 5.249E+03 1.106E+03 0.000E+00 1.106E+03 2983 3170 5.355E+03 0.000E+00 5.355E+03 1.145E+03 0.000E+00 1.145E+03 2984 3172 5.459E+03 0.000E+00 5.459E+03 1.185E+03 0.000E+00 1.185E+03 2985 3174 5.560E+03 0.000E+00 5.560E+03 1.225E+03 0.000E+00 1.22SE+03 2986 3176 5.65BE+03 0.000E+00 5.658E+03 1.265E+03 0.000E+00 1.265E+03 2987 3178 5.753E+03 0.000E+00 5.753E+03 1.306E+03 0.000E+00 1.306E+03 2988 3180 5.846E+03 0.000E+00 5.846E+03 1.348E+03 0.000E+00 1.348E+03 2989 3182 5.934E+03 0.000E+00 5.934E+03 1.390E+03 0.000E+00 1.390E+03 2990 3184 6.020E+03 0.000E+00 6.020E+03 1.432E+03 0.000E+00 1.432E+03

OTENERA SUBJECT Verificalitm of TOXPUFT and TOXEVAP PREPARED BY DATE 3/8/93 CHECKED BY ME DATE NMb LOTUS 12 3 Spreadsheeft ~1T PREL. SHEET OF PROJECT MonticeHo Tmic Chemical Studt CONTROL t.D. No. 1961 2.2 001 REV. 0 SHEET 43 OF 69 SHEETS 3186 6.101E+03 0.000E+00 6.101E+03 1.473E+03 0.000E+00 1.475E+J3 2991 2992 3188 6.179E+03 0.000E+00 6.179E+03 1.518E+03 0.000E+00 1.518E+03 2993 3190 6.252E+03 0.000E+00 6.252E+03 1.5f1E+03 0.000E+00 1.561E+03 3192 6.321E+03 0.000E+00 6.321E+03 1.604E+03 0.000E+00 1.604E+03 2994 3194 6.3B6E+03 0.000E+00 6.386E+03 1.648E+03 0.000E+00 1.648E+03 2995 .000E+00.692E+03 2996 3196 6.446E+03 0.000E+00 6.446E+03 1.692E+03. 000E + 00,)1. 736E + 03 2997 3198 6.502E+03 0.000E+00 6.502E+03 1.736E+03 3200 6.552E+03 0.000E+00 6.552E+03 1.780E+03.000E+004.780E+03 2998 2999 3202 6.598E+03 0.000E+00 6.598E+03 1.824E+03 0.000E+00 1.824E+03 3204 6.63BE+03 0.000E+00 6.638E+03 1.868E+03 0.000E+00 1.868E+03 3000 3206 6.673E+03 0.000E+00 6.673E+03 1.912E+03 0.000E+00 1.912E+03 3001 3208 6.703E+03 0.000E+00 6.703E+03 1.956E+03 0.000E+00 1.956E+03 3002 3003 3210 6.728E+03 0.000E+00 6.728E+03 1.999E+03 0.000E+00 1.999E+03 3004 3212 6.747E+03 0.000E+00 6.747E+03 2.043E+03 0.000E+00 2.043E+03 3005 3214 6.761E-03 0.000E+00 6.761E+03 2.086E+03 0.000E+00 2.036E+03 3006 3216 6.769E+03 0.000E+00 6.769E+03 2.129E+03 0.000E+00 2.129E+03 3007 3218 6.772E+03 0.000E+00 6.772E+03 2.171E+03 0.000E+00 2.171E+03 3008 3220 6.769E+03 1.719E+03 8.488E+03 2.213E+03 1.572E+01 2.229E+03 3009 3222 6.761E+03 2.332E+03 9.093E+03 2.255E+03 3.690E+01 2.292E+03 3010 3224 6.747'+03 2.832E+03 9.579E+03 2.296E*03 6.246E+01 2.358E+03 3011 3226 6.728E+03 3.267E+03 9.995E+03 2.336E+03 9.176E+01 2.428E+03 3012 3228 6.703E+03 3.660E+03 1.036E+04 2.376E+03 1.244E+02 2.501E*03 3013 3230 6.673E+03 4.021E+03 1.069E+04 2.416E+03 1.600E+02 2.576E+03 3014 3232 6.638E+03 4.358E+03 1.100E+04 2.454E+03 1.984E+02 2.653E+03 3015 3234 6.59BE+03 4.675E+031.127E+04 2.492E+03 2.393E+02 2.731E+03 3016 3236 6.552E+03 4.977E+031.153E+04 2.529E+03 2.826E+02 2.812E+03 3017 3238 6.502E+03 5.265E+03 1.177E+04 2.566E+03 3.282E+02 2.894E+03 3018 3240 6.446E+03 5.541E+031.199E+04 2.601E+03 3.758E+02 2.977E+03 3019 3242 6.386E+03 5.807E+03 1.219E+04 2.636E+03 4.255E+02 3.061E+03 3020 3244 6.321E+03 6.065E+03 1.239E+04 2.669E+03 4.771E+02 3.146E+03 3021 3246 6.252E+03 6.314E+03 1.257E+04 2.702E+03 5.304E+02 3.233E+03 3022 3248 6.179E+03 6.556E+03 1.273E+04 2.734E+03 5.855E+02 3.319E+03 3023 3250 6.101E+03 6.792E+031.289E+04 2.765E+03 6.423E+02 3.407E+03 3024 3252 6.020E+03 7.022E+03 1.304E*04 2.794E+03 7.006E+02 3.495E+03 3025 3254 5.934E+03 7.246E+03 1.318E+04 2.823E+03 7.604E+02 3.584E+03 3026 3256 5.846E+03 7.465E+03 1.331E+04 2.851E+03 8.217E+02 3.673E+03 3027 3258 5.753E+03 7.680E+03 1.343E+04 2.877E+03 8.B45E+02 3.762E+03 3028 3260 5.658E+03 7.890E+03 1.355E *04 2.903E+03 9.485E+02 3.851E+03 3029 3262 5.560E+03 8.097E+03 1.366E+04 2.927E+03 1.014E+03 3.941E+03 3030 3264 5.459E+03 8.299E+03 1.376E+04 2.950E+03 1.080E+03 4.031E+03 3031 3266 5.355E+03 S.499E+03 1.385E+04 2.972E+03 1.148E+03 4.121E+03 3032 3268 5.249E+03 8.694E+03 1.394E+04 2.993E+03 1.217E+a3 4.210E+03 3033 3270 5.141E+03 8.887E+03 1.403E+04 3.013E+03 1.287E+03 4.300E+03 3034 3272 5.031E+03 9.076E+03 1.411E+04 3.031E+03 1.359E+03 4.390E+03 3035 3274 4.920E+03 9.263E+03 1.418E+04 3.048E+03 1.431E+03 4.479E+03 3036 3276 4.807E+03 9.447E+03 1.42SE+04 3.064E+03 1.504E+03 4.569E+03 3037 3278 4.693E+03 9.425E+03 1.412E+04 3.079E+03 1.577E+03 4.656E+03 3038 3280 4.578E+03 9.299E+03 1.388E+04 3.093E+03 1.647E+03 4.740E+03 3039 3282 4.462E+03 9.179E+03 1.364E+04 3.106E+03 1.716E+03 4.822E+03 3040 3284 4.345E+03 9.064E+03 1.341E+04 3.117E+03 1.783E+03 4.900E+03 3D41 3286 4.22SE+03 8.955E+03 1.318E+04 3.127E+03 1.849E+03 4.976E+03 3041 3288 4.111E+03 8.850E+03 1.296E+04 3.136E+03 1.913E+03 5.049E+03 3043 3290 3.993E+03 8.750C+03 1.274E+04 3.144E+03 1.975E+03 5.119E+03 3044 3292 3.876E+03 8.654E+03 1.253E+04 3.151E+03 2.036E+03 5.187E+03 3045 3294 3.760E+03 8.562E+03 1.232E+04 3.156E+03 2.096E+03 5.252E+03 3046 3296 3.644E+03 8.473E+03 1.212E+04 3.161E+03 2.154E+03 5.315E+03 3047 3298 3.52SE+03 8.387E+03 1.192E+04 3.164E+03 2.211E+03 5.375E+03 3048 3300 3.414E+03 8.305E+03 1.172E+04 3.166E+03 2.267E+03 5.433E+03 3049 3302 3.300E+03 8.226E+03 1.153E+04 3.167E+03 2.322E+03 5.489E+03 3050 3304 3.188E+03 8.149E+03 1.134E+04 3.168E+03 2.375E+03 5.543E+03 3051 3306 3.077E+03 8.075E+03 1.115E+04 3.167E+03 2.427E+03 5.594E+03

O_TENERA SUBJECT Verification of TOYPtTF and TOYEVAP PREPARED 8Y ~ DATE 3/8/93 CHECKED BY M ..DATE b LOTUS 12-3 Spreadsheets PREL. SHEET OF PROJECT jinnticello Toxic Chemical Studv CONTROL l.D. No. 1961 2.2 001 REv. O SHEET 44 OF 69 SHEETS j l 3052 3308 2.967E+03 8.004E+031.097E+04 3.165E+03 2.478E+03 5.643E+03 3053 3310 2.859E+03 7.935E+031.079E+04 3.162E+03 2.528E+03 5.690E+03 I 3054 3312 2.753E+03 7.868E+031.062E+04 3.158E+03 2.577E+03 5.735E+03 3055 3314 2.64BE+03 7.803E+03 1.045E+04 3.154E+03 2.624E+03 5.778E+03 3056 3316 2.546E+03 7.740E+03 1.029E+04 3.148E+03 2.671E+03 5.820E+03 3057 3318 2.445E+03 7.679E+03 1.012E+04 3.142E+03 2.717E+03 5.859E+03 3058 3320 2.346E+03 7.620E+03 9.966E+03 3.135E+03 2.762E+03 5.896E+03 3059 3322 2.250E+03 7.563E+03 9.813E+03 3.126E+03 2.806E+03 5.932E+03 3060 3324 2.156E+03 7.507E+03 9.663E+03 3.1W+03 2.849E+03 5.966E+03 3061 3326 2.064E+03 7.453E+03 9.516E+03 3-s08E+03 2.891E+03 5.999E+03 3062 33281.974E+03 7.400E+03 9.374E+03 '.r.098t+03 2.932E+03 6.030E+03 3063 33301.887E+03 7.349E+03 9.235E+N 3.087E+03 2.972E+03 6.059E+03 3064 33321.802E+03 7.299E+03 9.101E+03 3.0/5E+03 3.012E+03 6.087E+03 3065 3334 1.719E+03 7.250E+03 8.969E+03 3.062E+05 3.051E+03 6.113E+03 3066 33361.639E+03 7.203E+03 8.842E+03 3.049E+03 3.089E+03 6.13SE+03 3067 33381.562E+03 7.157E+03 8.718E+03 3.036E+03 3.126E+03 6.162E+03 3068 33401.487E+03 7.111E+03 8.59BE+03 3.022E+03 3.162E+03 6.154E+03 3069 3342 1.414E+03 7.068E+03 8.481E+03 3.007E+03 3.198E+03 6.205E+03 3070 3344 1.344E+03 7.025E+03 8.368E+03 2.992E+03 3.233E+03 6.225E+03 3071 3346 1.276E+03 6.983E*03 8.25CE+03 2.976E+03 3.26TE+03 6.243E+03 3072 33481.211E+03 6.9'.2E+03 S.152E+03 2.960E+03 3.301E+03 6.261E+03 3073 3350 1.148E+03 6.90."+03 8.049E+03 2.943E+03 3.334E+03 6.277E+03 3074 3352 1.087E+03 6.861?+03 7.950E+03 2.926E+03 3.366E+03 6.292E+03 3075 3354 1.029E+03 6.824E+03 7.853E+03 2.909E+03 3.398E+03 6.307E+03 3076 3356 9.730E+02 6.787E+03 7.760E+03 2.891E+03 3.429E+03 6.320E+03 3077 3358 9.194E+02 6.750E+03 7.670E+03 2.873E+03 3.45%+03 6.332E+03 3078 3360 8.681E+02 6.715E+03 7.583E+03 2.855E+03 3.489E+03 6.344E+03 3079 3362 8.189E+02 6.679E+03 7.498E+03 2.836E+03 3.518E+03 6.354E+03 3080 3364 7.720E+02 6.645E+03 7.417E+03 2.817E+03 3.547E+03 6.364E+03 3081 3366 7.271E+02 6.611E+03 7.338E+03 2.798E+03 3.575E+03 6.373E+03 3082 3368 6.842E+02 6.578E+03 7.263E+03 2.779E+03 3.602E+03 6.381E+03 3083 3370 6.434E+02 6.546E+03 7.189E+03 2.759E+03 3.629E+03 6.388E+03 l 3084 3372 6.045E+02 6.514E+03 7.'19E+03 2.740E+03 3.655E+03 6.395E+03 3085 3374 5.675E+02 6.483E+03 7,051E+03 2.720E+03 3.681E+03 6.401E+03 1 3036 3376 5.323E+02 6.453E+03 6.985E+03 2.700E+03 3.707E+03 6.406E+03 l 3087 3378 4.989E+02 6.423E+03 6.922E+03 2.680E+03 3.731E+03 6.411E+03 3088 3380 4.673E+02 6.394E+03 6.861E+03 2.660E+03 3.756E+03 6.415E+03 3089 3382 4.372E+02 6.365E+03 6.802E+03 2.639E+03 3.780E+03 6.419E+03 l 3090 3384 4.088E+02 6.336E+03 6.745E+03 2.619E+03 3.803E+03 6.422E+03 c l 3091 3386 3.819E+02 6.309E+03 6.691E+03 2.598E+03 3.826E+03 6.424E+03 i 3092 3388 3.565E+02 6.281E+03 6.638E+03 2.578E+03 3.848E+03 6.426E+03 3093 3390 3.325E+02 6.254E+03 6.587E+03 2.557E+03 3.870E+03 6.428E+03 3094 3392 3.099E+02 6.228E+03 6.538E+03 2.537E+03 3.892E+03 6.429E+03 3095 3394 2.8+5E+02 6.202E+03 6.491E*03 2.516E+03 3.913E+03 6.429E+03 3096 3396 2.685E+02 6.177E+03 6.445E+03 2.496E+03 3.934E+03 6.429E+03 3097 3398 2.496E+02 6.152E+03 6.401E* 03 2.475E+03 3.954E+03 6.429E+03 3098 3400 2.318E+02 6.127E+03 6.359E+03 2.455E+03 3.974E+03 6.429E+03 3099 3402 2.152E+02 6.103E+03 6.318E+03 2.434E+03 3.993E+03 6.428E+03 3100 3404 1.995E+02 6.079E+03 6.278E+03 2.414E+03 4.012E+03 6.426E+03 3101 3406 1.849E+02 6.056E+03 6.240E+03 2.393E+03 4.031E+03 6.424E+03 3102 3408 1.712E+02 6.032E+03 6.204E+03 2.373E+03 4.049E+03 6.422E+03 3103 3410 1.584E+02 6.010E+03 6.168E+03 2.353E+03 4.067E+03 6.420E+03 3104 3412 1.464E+02 5.987E+03 6.134E+03 2.333E+03 4.085E+03 6.417E+03 3105 3414 1.352E+02 5.965E+03 6.100E+03 2.313E+03 4.102E+03 6.415E+03 3106 3416 1.248E+02 5.944E+03 6.068E+03 2.293E+03 4.119E+03 6.411E+03 3107 34181.151E+02 5.922E+03 037E+03 2.273E+03 4.135E+03 6.408t+03 3108 3420 1.060E*02 5.901E+03 6.007E+03 2.25TE+03 4.152E+03 6.404E+03 3109 3422 9.759E+01 5.880E+03 5.978E+03 2.233E+03 4.167E+03 6.400E+03 3110 3424 8.977E+01 5.860E+03 5.950E+03 2.213E+03 4.183E+03 6.396E+03 3111 3426 8.251E+01 5.840E+03 5.922E+03 2.194E+0', 4.198E+03 6.392E+03 3112 3428 7.577E+01 5.820E+03 5.896E+03 2.175E+03 4.213r+03 6.3P'r+03

- - @TENERA Verincation of TOXPUTT and'TO\\TVAP PREPARED BY [ DATE 3/8/93 SUBJECT LOTUS 12 3 Soreadsheett CHECKED BY bd DATE 3 4 PROJECT Monticello Tmic Chemical Study PREL. SHET or I CONTROLID NO, 1961 2.2-001 REV. O SHEET 15 OF 69 SHEETS 3113 3430 6.953E+01 5.800E+03 5,870E+03 2.155E+03 4.227E+03 6.383E+03 3114 3432 6.375E+015.781E+03 5.845E+03 2.136E+03 4.242E+03 6.378E+03 3115 3434 5.840E+015.762E+03 5.821E+03 2.117E+03 4.255E+03 6.373E+03 3116 3436 5.346E*01 5.743E+03 5.797E+03 2.098E+03 4.269E+03 6.367E+03 3117 3438 4.890E+015.725E+03 5.774E+03 2.080E+03 4.282E+03 6.362E+03 3118 3440 4.468E+015.707E*03 5.751E+03 2.061E+03 4.295E+03 6.356E+03 3119 3442 4.080E+01 5.689E+03 5.729E+03 2.043E+03 4.308E+03 6.351E+03 3120 3444 3.723E+01 5.671E+03 5.708E+03 2.024E+03 4.321E+03 6.345E+03 3121 3446 3.394E+01 5.653E+03 5.687E+03 2.006E+03 4.333E+03 6.339E+03 3122 3448 3.091E+01 5.636E+03 5.667E+03 1.988E+03 4.345E+03 6.333E+03 3123 3450 2.814E+01 5.619E+03 5.647E+03 1.970E+03 4.356E+03 6.326E+03 3124 3452 2.559E+01 5.602E+03 5.628E+03 1.952E+03 4.368E+03 6.320E+03 3125 3454 2.325E+01 5.585E+03 5.609E+03 1.935E+03 4.379E+03 6.313E+03 3126 3456 2.111E+01 5.569E+03 5.590E+03 1.917E+03 4.390E+03 6.307E+03 3127 3458 1.915E+01 5.553E+03 5.572E+03 1.900E+03 4.400E+03 6.300E+03 3128 3460 1.736E+01 5.537E+03 5.554E+03 1.883E+03 4.411E+03 6.293E+03 3129 3462 1.572E+01 5.521E+03 5.536E+03 1.866E+03 4.421E+03 6.286E+03 3130 3444 1.423E+01 5.505E+03 5.519E+03 1.849E+03 4.431E+03 6.279E+03 i 3131 34o6 1.287E+01 5.490E+03 5.503E+03 1.832E+03 4.440E+03 6.272E+03 3132 3468 1.163E+01 5.474E+03 5.486E+03 1.815E+03 4.450E+03 C.265E+03 3133 3470 1.050E+01 5.459E+03 5.470E+03 1.799E+03 4.459E+03 6.258E+03 3134 3472 9.467E+00 5.444E+03 5.454E+03 1.782E+03 4.468E+03 6.250E+03 3135 3474 8.533E+00 5.430E+03 5,438E+03 1.766E+03 4.477E+03 6.243E+03 3136 3476 7.684E+00 5.415E *03 5.423E+03 1.750E+03 4.486E+03 6.236E+03 3137 3478 6.915E+00 5.401E+03 5.408E+031.734E+03 4.494E+03 6.228E+03 3138 3480 6.217t+00 5.387E+03 5.393E+031.718E+03 4.502E+03 6.220E+03 3139 3482 5.585E+00 5.372E+03 5.378E+03 1.703E+03 4.510E+03 6.213E+03 3140 3484 5.013E+00 5.359E+03 5.364E+03 1.687E+03 4.518E+03 6.205E+03 3141 3486 4.497E+00 5.345E+03 5.349E+03 1.672E+03 4.525E-03 6.197E+03 3142 34C8 4.030E+00 5.331E+03 5.335E+03 1.656E+03 4.533E+03 6.189E+03 3143 3490 3.608E+00 5.318E+03 5.321E+03 2.641E+03 4.540E+03 6.181E+03 3144 3492 3.228E+00 5.304E+03 5.308E+03 1.626E+03 4.547E+03 6.173E+03 1 3145 3494 2.886E+00 5.291E+03 5.294E+03 1.612E+03 4.554E+03 6.165E+03 3:10 3496 2.578E+00 5.278E+03 5.281E+031.597E+03 p560E+03 157E +03 3498 2.301E+00 J.265E+03 5 149E+03 35002.052E+00'5.253E+03i.268E+031.582E+03*4.567E+03 3147 .255E+03 1.568E+034.573E+03.141E+03 3148 j 3502 1.829E+00 5.240E+03 5.242E+03 1.553E+03 4.579E+03 6.133E+03 3149 1 3150 3504 1.628E+00 5.22BE+03 5.229E+03 1.539E+03 4.585Et03 6.124E+03 3151 3506 1.448E+00 5.215E+03 5.217E+03 1.525E+03 4.591E+03 6.116E+03 l 3152 3508 1.287E+00 5.203E+03 5.204E+03 1.511E+03 4.596E+03 6.10BE+03 i i 3153 3510 1.143E+00 5.191E+03 5.192E+03 1.497E+03 4.602E+03 6.099E+03 3154 3512 1.015E+0J 5.179E+03 5.180E+03 1.484E+03 4.607E+03 6.091E+03 3155 3514 8.998E-01 5.167E+03 5.168E+03 1.470E+03 4.612E+03 6.083E+03 3156 3516 7.973E 01 5.155E+03 5.156E+03 1.457E+03 4.617E+03 6.074E+03 3157 3518 7.058E-01 5.144E+03 5.145E+03 1.444E+03 4.622E+03 6.066E+03 3158 3520 6.243E-01 5.132E+03 5.133E+03 1.430E+03 4.627E+03 6.057E+03 3159 3522 5.518E 01 5.121E+03 5.122E+03 1.417E+03 4.631E+03 6.048E+03 3160 3524 4.873E 01 5.110E+03 5.110E+03 1.404E+03 4.636E+03 6.040E+03 3161 3526 4.300E 01 5.099E+03 5.099E+03 1.391E+03 4.640E+03 6.031E+03 3162 3528 3.791E-01 5.088E+03 5.088E+03 1.379E+03 4.644E+03 6.023E+03 3163 3530 3.340E-01 5.077E+ J3 5.077E+03 1.366E+03 4.648E+03 6.014E+03 3164 3532 2.940E-01 5.066E+13 5.066E+03 1.354E+03 4.652E+03 6.005E+03 3165 3534 2.586E-01 5.055E+03 5.055E+03 1.341E+03 4.655E+03 5.997E+03 3166 3536 2.273E 01 5.044E+03 5.045E+03 1.329E+03 4.659E+03 5.988E+03 3167 3538 1.995E 01 5.034E+03 5.034E+03 1.317E+03 4.662E+03 5.979E+03 3168 3540 1.751E-01 5.023E+03 5.024E+03 1.30$E+03 4,666E+03 5,970E+03 3169 3542 1.535E-01 5.013E+03 5.013E+03 1.293E+03 4.669E+03 5.962E+03 3170 3544 1.344E 01 5.003E+03 5.003E+03 1.281E+03 4.672E+03 3.953E+03 3171 3546 1.177E 01 4.993E +03 4.993E+03 1.269E+03 4.675E+03 5.944E+03 3172 3548 1.029E-01 4.983E+03 4.983E+03 1.258E+03 4.678E+03 5.935D 43 3173 3550 8.992E-02 4.973E+03 4.973E+03 1.246E+03 4.680E+03 5.927E+03

- - - - - - - - - ~ - - - - - O_TENERA PREPARED BY _DATE 3/8/93 SUBJECT Verific tion of TOXPUFF and TOYEVAP CHECKED BY dA DATE NM3 LOTUS 1-2-3 Spreadsheets J PREL. SHEET OF PROJECT Monticel 9 Tosic Chemical Studt CONTROL l.D. No. Idl-2.2 001 REv. O SHEET M OF 69 SHEETS 3552 7.851E 02 4.963E+03 4.963E+03 1.235E+03 4.683E+03 5.918E+03 3174 3554 6.849E 02 4.953E+03 4.953E+03 1.224E+03 4. 585E+03 5.909E+03 3175 3556 5.971E-02 4.943E+03 4.943E+03 1.212E+03 4.688E+03 5.900E+03 3176 3558 5.200E-02 4.934E+03 4.934E+03 1.201E+03 4.690E *03 5.891E+03 3177 3560 4.526E 02 4.924E +03 4.924E+03 1.190E+03 4.692E+03 5.882E+03 3178 3562 3.935E 02 4.915E+03 4.915E+03 1.179E+03 4.694E+03 5.874E+03 3179 3564 3.419E 02 4.905E+03 4.905E+03 1.169E+03 4.696E+03 5.865E+03 3180 3566 2.968E 02 4.896E+03 4.896E+03 1.158E+03 4.698E+03 5.856E+03 3181 3568 2.5 75E 02 4.887E+03 4.887E+03 1.147E+03 4.700E+03 5.847E+03 3182 3570 2.232E-02 4.878E+03 4.878E+031.137E+03 4.701E+03 5.838E+03 3183 3572 1.933E 02 4.869E+03 4.869E+03 1.126E+03 4.703E+03 5.829E+03 3184 3574 1.672E 02 4.860E+03 4.860E+03 1.116E+03 4.704E+03 5.820E+03 3185 3576 1.446E 02 4.851E+03 4.851E+03 1.106E+03 4.706E+03 5.812E+03 3186 3578 1.249E-02 4.842E+03 4.842E+03 1.096E+03 4.707E+03 5.803E+03 3187 3580 1.078E-02 4.833E+03 4.833E+03 1.086E+03 4.708E*03 5.794E+03 3188 35B2 9.300E 03 4.825E+03 4.825E+03 1.076E+03 4.709E+03 5.785E+03 3189 3584 8.014E-03 4.816E+03 4.816E+03 1.066E+03 4.710E+03 5.776E+03 3190 3191 3586 6.901E-03 4.808E+03 4.808E+03 1.056E+03 4.711E+03 5.767E+03 3192 3588 5.938E-03 4.799E+03 4.799E+03 1.047E+03 4.712E+03 5.758E+03 3193 3590 3.104E 03 4.791E+03 4.791E+03 1.037E+03 4.712E+03 5.750E+03 3592 4.385E 03 4.782E+03 4.782E+03 1.028E+03 4.713E*03 5.741E+03 3194 3195 3594 3.763E-03 4.774E+03 4.774E+03 1.018E+03 4.714E+03 5.732E+03 3196 3596 3.227E-03 4.766E+03 4.766E+03 1.009E+03 4.714E+03 5.723E+03 3197 3598 2.765E-03 4.758E+03 4.758E+03 9.997E+02 4.715E+03 5.7'.4E+03 3198 3600 2.368E-03 4.750E+03 4.750E+03 9.906E+02 4.715E+03 S.705E+03 3700 3.561E 07 4.413E+03 4.413E+03 6.258E+02 4.604E+03 5.229E+03 3199 3200 3800 6.982E 12 4.167E+03 4.167E+03 3.953E+02 4.443E+03 4.838E+03 3900 1.784E 17 3.978E+03 3.97BE+03 2.498E+02 4.271E+03 4.521E+03 e 3201 3202 4000 5.943E 24 3.826E+03 3.826E+03 1.578E+02 4.107E+03 4.265E+03 i 3203 4100 2.580E 31 3.700E+03 3.700E+03 9.968E+01 3.957E+03 4.057E+03 3204 4200 1.460E-39 3.595E+03 3.595E+03 6.297E+01 3.824E+03 3.887E+03 3205 4300 1.077E 48 3.504E+03 3.504E+03 3.978E+01 3,706E+03 3.746E+03 3206 4400 1.036E-58 3.425E+03 3.425E+03 2.513E+01 3.603E+03 3.628E+03 3207 4500 1.298E-69 3.356E+03 3.356E+03 1.588E+01 3.512E+03 3.528E+03 4600 2.121E-81 3.294E+03p294E+03 1.003E+01 3.432E+03 3.442E+03 3208 4700 4.517E 94 0.000E+00 4.517E 94 6.337E+00'2.168E+03*1.174E+03 3209 3210 4800 0.000E +00 'O.000E+00'D.000E+00 4.003E+00v1.370E+ 03 1.374 E+ 03 4900 0.000E+00 0.000E+00 0.000E+00 2.529E+00 8.652E+02 8.678E+02 3211 3212 5000 0.000E+00 0.000E+00 0.000E+001.598E+00 5.466E+02 5.482E+02 3213 5100 0.000E+00 0.000E+00 0.000E+00 1.009E+00 3.453E+02 3.463E+02 3214 5200 0.000E+00 0.000E+00 0.000E+00 6.377E 01 2.182E+02 2.188E+02 3215 5300 0.000E+00 0.000E+00 0.000E+00 4.029E-01 1.378E+02 1.382E+02 3216 5400 0.000E+00 0.000E+00 0.000E+00 2.545E 01 8.707E+01 8.733E+01 3217 5500 0.000E+00 0.000E+00 0.000E+00 1.608E 01 5.501E+01 5.517E+01 3218 5600 0.000E+00 0.000E+00 0.000E+00 1.016E-01 3.475E+01 3.485E+01 3219 5700 0.000E+00 0.000E+00 0.000E+0F 6.417E 02 2.195E+01 2.202E+01 3220 5800 0.000E+00 0.000E+00 0.000E+00 4.054E-02 1.387E+01 1.301E+01 3221 5900 0.000E+00 0.000E+00 0.000E+00 2.561E-02 8.762E+00 8. bdE+00 3222 6000 0.000E+00 0.000E+00 0.000E+00 1.618E-02 5.535E+00 5.552E+00 3223 6100 0.000E+00 0.000E+00 0.000E+00 1.022E-02 3.497E+00 3.507E+00 3224 6200 0.000E+00 0.000E+00 0.000E+00 6.458E 03 2.209E+00 2.216E+00 3225 6300 0.000E+00 0.000E+00 0.000E+00 4.080E 03 1.396E+00 1.400E+00 3226 6400 0.000E+00 0.000E+00 0.000E+00 2.577E 03 8.817E-01 8.843E 01 3227 6500 0.000E+00 0.000E+00 0.000E+00 1.62BE 03 5.5 70E-01 5.587E-01 3228 6600 0.000E+00 0.000E+00 0.000E+00 1.02?E 03 3.519E-01 3.529E-01 3229 6700 0.000E+00 0.000E+00 0.000E+00 6.499E-04 2.223E 01 2.230E-01 3230 6800 0.000E+00 0.000E+00 0.000E*00 4.105E 04 1.404E-01 1.40?E 01 3231 6900 0.000E+00 0.000E+00 0.000E+00 2.594E-04 8.873E-02 8.899E-02 3232 '000 0.000E+00 0.000E+00 0.000E+00 1.63?E-04 5.605E-02 5.622E-02 3233 7100 0.000E+00 0.000E+00 0.000E+00 1.035E-04 3.541E-02 3.552E 02 3234 7200 0.000E+00 0.000E+00 0.000E+00 6.540E-05 2.237E 02 2.244E 02

i - OTENERA PREPARED BY I DATE 3/8/93 Verification of TOYPUFF and TOXEVAP SUBJECT CHECKED BY dif DATE LOTUS 12-3 Spreadsheeft PREL. SHEET OF _ PROJECT Monticello Toxic Chemical Study CONTROL 1.D No. 1961 2.2-001 REV. O SHEET 47 OF 69 SHEETS 7300 0.000E+00 0.000E+00 0.000E+00 4.131E 051.413E-021.417E-02 <235 7400 0.000E+00 0.000E+00 0.000E+00 2.610E 05 8.929E-03 8.955E 03 3236 7500 0.000E+00 0.000E+00 0.000E+00 1.649E-05 5.641E-03 5.657E 03 '237 7600 0.000E+00 0.000E+00 0.000E+001.042E 05 3.564E 03 3.574E 03 3238 7700 0.000E+00 0.000E+00 0.000E+00 6.581E 06 2.251E 03 2.258E 03 3239 7800 0.000E+00 0.000E+00 0.000E+00 4.157E 06 1.422E 03 1.426E 03 3240 7900 0.000E+00 0.000E+00 0.000E+00 2.626E 06 8.985E-04 9.011E 04 3241 8000 0.000E+00 0.000E+00 0.000E+001.659E 06 5.676E 04 5.693E 04 3242 8100 0.000E*00 0.000E+00 0.000E+001.048E 06 3.586E-04 3.597E 04 3243 8200 0.000E+00 0.000E+00 0.000E+00 6.622E 07 2.266E-04 2.272E 04 3244 8300 0.000E+00 0.000E+00 0.000E+00 4.184E 07 1.431E-04 1.435E 04 3245 8400 0.000E+00 0.000E+00 0.000E+00 2.643E-07 9.042E-05 9.068E 05 3246 8500 0.000E+00 0.000E+00 0.000E+00 1.670E 07 5.712E 05 5.729E 05 3247 8600 0.000E+00 0.000E+00 0.000E+00 1.055E-07 3.609E-05 3.619E 05 3248 8700 0.000E+00 0.000E+00 0.000E+00 6.664E-08 2 ?80E 05 2.286E 05 3249 8800 0.000E+00 0.000E+00 0.000E+00 4.210E 08 1.440E-05 1.444E-05 3250 8900 0.000E+00 0.000E+00 0.000E+00 2.660E 08 9.099E-06 9.126E 06 3251 9000 0.000E+00 0.000E+00 0.000E+00 1.680E 08 5.748E-06 5.765E 06 3252 9100 0.000E+00 0.000E+00 0.000E+001.062E 08 3.631E 06 3.642E 06 3253 9200 0.000E+00 0.000E+00 0.000E+00 6.706E 09 2.294E-06 2.301E 06 3254 9300 0.000E+00 0.000E+00 0.000E+00 4.237E 091.449E 061.454E 06 3255 9400 0.000E+00 0.000E+00 0.000E+00 2.676E 09 9.156E 07 9.183E-07 3256 9500 0.000E+00 0.000E+00 0.000E+001.691E 09 5.785E 67 5.801E 07 3257 9600 0.000E+00 0.000E+00 0.000E+001.068E 09 3.654E 07 3.665E 07 3258 9700 0.000E+00 0.000E+00 0.000E+00 6.748E 10 2.309E-07 2.315E-07 3259 9800 0.000E+00 0.000E+00 0.000E+00 4.263E 101.458E 071.463E-07 3260 9900 0.000E+00 0.000E+00 0.000E+00 2.693E-10 9.214E 08 9.241E-08 3261 10000 0.000E+00 0.000E+00 0.000E+00 1.702E-10 5.821E 08 5.838E-08 3262 10100 0.000E+00 0.000E+00 0.000E+00 1.075E-10 3.677E 08 3.68SE-08 3263 10200 0.000E+00 0.000E+00 0.000E+00 6.791E 11 2.323E-08 2.330E-08 3264 10300 0.000E+00 0.000E+00 0.000E+00 4.290E-11 1.468E-08 1.472E 08 3265 10400 0.000E+00 0.000E+00 0.000E+00 2.710E 11 9.272E 09 9.299E-09 3266 10500 0.000E+00 0.000E+00 0.000E+00 1.712E 11 5.858E 09 5.875E-09 3267 10600 0.000E+00 0.000E+00 0.000E+00 1.082E-11 3.701E-09 3.711E-09 3268 10700 0.000E+00 0.000E+00 0.000E+00 6.834E 12 2.338E-09 2.345E-09 3269 10800 0.000E+00 0.000E+00 0.000E+00 4.317E-12 1.477E 09 1.481E-09 3270 10900 0.000E+00 0.000E+00 0.000E+00 2.727E-12 9.331E 10 9.358E-10 3271 11000 0.000E+00 0.000E+00 0.000E+00 1.723E-12 5.895E-10 5.912E-10 3272 11100 0.000E+00 0.000E+00 0.000E+001.089E 12 3.724E 10 3.735E 10 3273 11200 0.000E+00 0.000E+00 0.000E+00 6.877E-13 2.353E-10 2.360E-10 3274 11300 0.000E+00 0.000E+00 0.000E+00 4.345E 13 1.486E-10 1.491E 10 3275 11400 0.000E+00 0.000E+00 0.000E+00 2.745E 13 9.390E 11 9.417E-11 3276 11500 0.000E+00 0.000E+00 0.000E+00 1.734E*13 5.932E-11 5.949E-11 3277 11600 0.000E+00 0.000E+00 0.000E+00 1.095E 13 3.747E-11 3.758E 11 3278 11700 0.000E+00 0.000E+00 0.000E+00 6.920E 14 E.367E-112.374E-11 3279 11800 0.000E+00 0.000E+00 0.000E+00 4.372E-14 1.496E 11 1.500E-11 3280 11900 0.000E+00 0.000E+00 0.000E+00 2.762E-14 9.449E-12 9.476E-12 3281 12000 0.000E+00 0.000E+00 0.000E+001.745E 14 5.969E-12 5.987E-12 3282 12100 0.000E+00 0.000E+00 0.000E+00 1.102E 14 3.771E-12 3.782E-12 3283 12200 0.000E+00 0.000E+00 0.000E+00 6.964E-15 2.382E-12 2.389E-12 3284 12300 0.000E+00 0.000E400 0.000E+00 4.399E 15 1.505E-12 1.509E 12 3285 12400 0.000E+00 0.000E+00 0.000E+00 2.779E-15 9.50BE 13 9.536E-13 3286 12500 0.000E+00 0.010E+00 0.000E+00 1.756E-15 6.007E-13 6.025E-13 d 3287 12600 0.000E+00 0.000E+00 0.000E+00 1.109E-15 3.795E-13 3.806E-13 3288 12700 0.000E+00 0.000E+00 0.000E+00 7.008E 16 2.397E-13 2.404E-13 3289 12800 0.000E+00 0.000E+00 0.000E+00 4.427E-16 1.515E-13 1.519E-13 3290 12900 0.000E+00 0.000E+00 0.000E+00 2.797E 16 9.568E-14 9.596E-14 3291 13000 0.000E+00 0.000E+00 0.000E+00 1.767E-16 6.045E-14 6.063E-14 3292 13100 0.000E+00 0.000E+00 0.000E+00 1.116E 16 3.819E-14 3.830E-14 3293 13200 0.000E+00 0.000E+00 0.000E+00 7.052E-17 2.413E 14 2.420E 14 3294 13300 0.000E+00 0.000E+00 0.000E+00 4.455E-17 1.524E-14 1.529E-14 3295 i

O_TENERA SUBJECT Verification of TOXPUFT and TOKEVAP PREPARED BY DATE 3/8/93 ~ LOTUS l-2-3 Spreadsheets CHECKED BY 4/C DATE 3 /tM PROJECT f1'";ce!!n Tmic Chamical Study PREL. SHEET OF l I CONTROL 1.D. NC. 1961-2.2-001 REv. O SHEET 48 OF 69 SHEETS 1 3296 13400 0.000E+00 0.000E+00 0.000E+00 2.815E 17 9.629E 15 9.657E-15 3297 13500 0.000E+00 0.000E+00 0.000E+00 1.77BE-17 6.083E 15 6.101E-15 3298 13600 0.000E+00 0.000E+00 0.000E+00 1.123E 17 3.843E*15 3.854E 15 3299 13700 0.000E+00 0.000E+00 0.000E+00 7.097E 18 2.42SE 15 2.435E-15 k l I I l i \\ 1 I i

~ O_TENERA - 1 cuaJECT, Verificatinn of TOTPLTF and TO};TFyAP PREPARED BY DATE _3/8/93_ LOTUS 143 Spread heef t CHECKED BY M DATEh!cD / PREL SHEET OF l l PROJf.CT Bnnticello Tgic Chemical Studt CONTROL l.D. No. 1961-2.2-001 RD/. 0 SHEET 49 OF 69 SHEETS APPENDIK 2 i 10K7UFF Fornuta Listing 1 i Toxic Chemical Spill Calcutation A:81: ' A:A2: (WO) ' 1Fu chemical boiling point tesa than ancierit tenperature) A:A4: IV10) Last UpJated:

1. C4: (D1) '5 Mar-93 f'

Analyzed Chanicals Chlorine A:D4: ' l A:A6: fW10) '====================s============a=======o============================ A:A7 IV101 ' Design InWtt,: A A?: 04101 ' Spill Deta: A:C10: 'Contalmr volume (VC, cm"3): A:F10: (53) 52040000 Spill to CR Intake Distence (x0, m): A;B11: ' A:(11:{F1) 3218 Spilt type: Circoiar A:012:

• Meteorologicil Data:

A:A15: tw10) Pasquitt's Sts.bility Category: A:816 A:F16: ' G Ambieht Temperatu'e (tac, degrees C): l A:B17: * [ A:F17: 20 Vind Speed (U, m/sec): i A:C18: ' } A:F18: 1 Air Freasure (PA, atm): A:C19: ' A:F19: 1 A:A2!: tul0]

• Control Room Data:

A:B22: icontrol Room CC IntNe Height (z, m): A:F22: 11.25 Control R,om volunw (CRV, f t"3): A;B23:

• 6 A:F23: (S3) 270C0 CR HVAC Inte.ke Rate (CFIN. ft.**3/ minute):

l A:A24: fv10] 8 A:F24: 74 f,0 Chemicat Casa: l A:A26: (Vib) ( Chenacat Density (DENS, g/cm"3): l Ais27:

• l A f27: (F3) 1.57 Bolting Point (ib. degrees C):

i A:628: ' [ A:F28: 34.1 Moleculai Weight (MW, c/ mole): AsB29:

• A:F24: (F2) 70.9 e

Hest Capacity (Cp, cal /g-degreve C): A:A3E: (W10) A:F30: 0.226 Heat of Veporization (Hv, cal /g): A:A31: tW10] A:F31: 68.8 A:AJ2: tw10) ' Constants: ideal Cas Constart (R, atm m"3/ mote dest ee K): A:A34: (V10) A:F34: (S3) 8.215E 05 l A:C35: ' Air censity (DAIR, s/cm**3, at 1 atmosphtre and 20 deg*ees C): 1.B36: ' A:F36: (S2) 0.(,012 A:E37: PI: A:F37: *1P t Gravitational Constant (c, em/see"2): A:A30: (V10) A:FL8: 981 A:A3?: (W10) ' Forced Convection Heat fransfer Coefficient A:A40: (W10; ' (he, cal /r,m**2*sec-degree C): A:F40: (51) 0.00016 A:441: [W101 ' At:nos. and Solar Heat Flux (qr, cal /cm**2 sec): A:F41: (52) 0.0212 At#43: (V10) ' Calculated Design inputs: i

x a ) L @TENERA I I _ DATE 3/8 _3 SUBJECT'. VeriUcation of TG*iPITFF and TOKEVAP PREPARED BY d,DATE 5/ @ LOTUS 1-2-3 Soreadshee(M CHECKED BY 0 i PROJECT Monticello Toxic Chernical Study PREL SHEET OF CONTROL l.D. NO. 1901-2.7-001 REV. O SHEET 50 OF fi9 SHF.ETS i; . - =, =. l l A:%51 ' b Itt al Cheinical Mass (MT=VC*DEhs, g)* A F45: (53) +F10*F27 l I l A:A46: [V101 ' Ambient Tenperature (Ta= Tac +273.16, decrees K): i i A:F46: +F17+273.16 i A:B47: 'thrmical Bolling Point (Tb, degrees K): 1 A:F47: +F2C+273.16 A: B.8: ' Gr w nd ('.arth) Temperature (Te=Ta): 1 AtF48: +F46 l A:A50: N10 3 ' = = = = = = = = = = = = = = = = = = = = = = = = = = = s r = = = = = = r - .==n===========e=======u l A:A5*: (W101 'Chemies Mass calculat ions: 1 A:A53: tulo)

• Mass of Initial Paf f s elease (MO, g) e. t*Cr*(ta-Fb)/Hv A:054 (53) '

= AE54: (53) +F45'F30*(F46-547)/F31 4:056:

• Remaining M ss (MR, g) = MT MO A:037: '

A:E57: (53) v4*,-E!4 A A33: N101*-===ta================s=======nn=====n========n========n=== A:A59: N10; 'SpiL L Aree Calculations: A:A61: (V10.1 ' Initial SpitL Radius (RO, cm) = (MR/(CENS*PI))**(1/3) A:062: = A:E62: (P) (E57dF37+F27))'(1/3) / A:A64: (v101 '

nitial spil t Area ( AO, em"2) =

l A:E64: 'Pl*(R0"2) A 065: * = A:ESS : (53) + F37*(E62*E62) A367. N10)

• Area Change Rate (ACH, em"2/sec) = Pl*2* (g*(MR/ DEWS)*

A:A63: (W10] * = (DENS-DA!R)/(CEhS*PI))**1/2 4 A:C69: ' = A;E19: (53) =F37 2*((F38*(f 57/F27)*(IN F36)/(F27*F37))* (1/2)) 4: A '1: W10)

• Maximtn Spill Arei (, ex, cm"2) = (KR/ DENS)/1 cm

( A:DT2: ' = A:E72: (53) +E$7/F27 i A:A74: N101 Tire When Amax Reachut tTmax, st.c) = (Amax-AO)/ACH A:075 : = A:E75: (F2) (E72 E65)/E69 A:A76: N10] '==a======a=======-==n======n========n=======u=nu..==n====== k A:A77: N101 'Nass Vawritetton Rate Calculation A:A79: N10) Fass vaporization Rate (V(t), A:ASO: N10] g/see-cm"2) = V0+VCH/(t"(1/2)) A:681: 8where: A:CS2: ' v0 (g/see em**2) = (qr+he(Ta-Tb))/Hv A:083: ' = A:E83: (53) (F41+F40*(F46-F47))/F11 A:B85: VCH (g/cm"2*sec"(1/2)) = 197*(Te Tb)/(M'0,001) A:036: ' A:E86: (53) 197*(F48 F47)/(r31*10000) i j A:A87: (V10] '===========================r======nu=============>=*===u====,;==== h q A:AES: N101 'Cateulation of Sigmas (0(spersion Coef ficients) A:A90: [.J10)

• Spill Vapor Density (DVAP, g/m"3) = (W'P A)/(R* 42 A 091:

= A:E91: (535 (F19'F29)/(F34*F46) A:A93: N10] ' initia\\ Puf f Std. Dev. (SIGO, m) * (M1/t :2"(1/2))*(f l**(3/2))* A:E94: '3VAP)]**(1/3) A:095: ' = A:E95: (F35 (t S4/(2*(1/2)* tJ7'(3/2)*E91))*(1/3) 4 A:A97: N10] Yasq.-Gif f.

• Disp Coef f log (SiCY, m) =

4:E97: ' A+B* log (x0)+C*(t og(x05 )"2 A:A E N101

• k j

A:E93; ' +0*( tv;'x0))"3 I A:C79; where: 4:L99: ' A= monumaamammarammmmmme w amammmmmassaq _ _ a,wsspeueramradaer aw summerammmmmmeum a f \\ ' i /H V

G_TENERA t _ DATE 3/8/93 SUIUECT Verification of TOXPtTFF and TOXFNAP PREPARED BY ) h LOT 11S 1-2 3 Screadsheets CHECKED BY [/jL DATE3hoM i 1 g 5.OJECT Monticello Toxic Chemical Study PREL. SHEET OF

• CONTROL l.D. NO.

1961 2.2 001 REv. 0 SHEET 51 OF 69 SHEETS w A:E99 -1.6212 A:0100:

• B=

A:E100: 1.0648 A:0101: ' C= A:E101: -0.014857 A:0102:

• 0=

AE102: 0.0020555 A D103:

• SICY =

A E103: (F3) 10"(+E99+E100'QLOG(F11)+E101*("J oc(F11)* 2)+E102*(DLOG(F11)*3)) A:A105: (V10) 'Pasq.-Giff. Z Disp Coeff Log (SIC 7, m) = A:E105: ' A+B* log (XO)+C*(tog (XO))"2 A:A106: [W10)

• A:E106: ' +D* ( L og(X0 ))"3 A C107: '

where A:D107:

• A=

AE107: 1.E981 A:0105: ' T= A:E108: 1.1243 A:D109: ' C= A:E109: -0.036447 A:0110:

• A:E110: 0.f( W e A:0111:
• FIGZ =

g A:li11: ('3) 10 * ( + E 107+ t i us*aLOG ( F 11 ) + F 10Vi NL TC ( F li )"2 )e.110* GLC. :2 s l'3)? 4:A113: [W10' Inst Puff Y nigp.f3eff (,1,1, m: 1 A:E113: 'O TY '2+0170"2)"t i,4) A:D114: ' s 5 A:E114: (F D (E95*r+ES.03*2)'tb t) inst vuf f 1 ;;: p Coef f.StGXI, m) = ':Atil: IV10) ' s, 110: ' sigil % '7: ' = a f l1.1 (F*, + Ell 4 l Inst Puf8 Z ftirp Coeft (SIGZl, m) = A:*119 (W10) A:E1?9: ' (11 7"2+ t%0* *t )"(1/2 ) j s b i t A;D120: 0 A:E120: (FI) (E95'2+Etti'f)"(1 2) / i A:A112: tw10. '

e.t Releal? tilsk Co.f (SICZM, m) =

-f A:E122: 8(StGZ) 'A:D1 1 8 = A:E123: (F3) (E111)cont Release Disp Coef f (SIG1M, m) = l A:A125: tw10) A:E125: '($1 GY"2< (Re!f"I"(1/2)/4.3 > A:E126: ' "2 )"(1/ 2 ) A:0127: ' = Y A:E127: (F3) (E103'2+E72/184900)"( /2) A:F127: (F3) '(at Amax) A:B128: ' Note:For Circular Spid, Ref f = (A(t)/PI)"(1/2) A:8129: ' A:A132: (W10) ' = = = a n n = = = = u u = = n = = = = u n u r u n e n = = = = = = = = = = ==== = = = a n= 2= = i A:A133: IW10) ' Conversion of g/m"3 to ppm A:A135: IV10) ' Conversion to PPM (PPM, ppm /(g/m"3)) = A:E135: '(R*1a*1.0E+06)/(MW'Pa) A:0136: 8 = A:E136: (F2) (F34*F46*1000000)/(F19'F29) A:A137: [V10) '===========na===unun==================>======nuu==u'= A:A138: IV10) ' Calculation of Puf f Contentration Outside Control Room A:4140: [W10] 8 Puf f Conc 9 CR Intake (CRP(t), pyn) = A:E140: ' [> 1/ (2"(3/ 2)* (P1 )"(3/ 2 )* SI CX I

• A:E141: ' S I GY l
• G I GZ l )]
• e x p [- 1/2* x"2 /

l where Z=h=0 for DVAP>DA!R, A:A142: [W10] A:E142: 'SICx t**2)*(expt 1/2*(1 h)"2/ i

7 O_YENERA war - DATE 3/R/03. $UBJtcT Verification of TO\\'PlTF and TOYEY AP PREPARED BY f cHtcKtD 'sY [M DATE NO3 I OTUS 12 3 Sorcadsheets 6mostcT Montkello Tmic Chemical Studv Pntl., s 4tti _ _ or i CONTROL 1.D. fio. 1061 2.2-001 nty. O sHtcT __,f ? or 69 sutr7s m.mme.. A:A143: TV10] 8 .sh for DVAP<DAlt, AE143: '$1CZl"2]+eapl*i/Z'(t+h)"2/ Y AaB144: 'y.0, and max 0 U*t Ast144 '$1CZi"21)' PPM AIA145: [W10)

• essassensenenennessessess nessensunneseesannessenesennesse A:A146: [W10) ' Calculation of Conttruous Retesse Conc outside Control Room Cont Cone a CR Intake (CRC (t), gn) e A A148: (W10] '

Ast148: '(A0+ACH't) A 7148: ' * (V0+vC H / t"(1/2 ))* A (149: '(1/(2*PI'U'$1CYM*$1CT.))*(exp! A:A150: (W10] 8 where geheh for DVAP>0 AIR, Ast150: ' 1/2*( h)"2/$1CZM* *2)+empt tah f or DVAP<DA!R, A A151: [W10) ' Ant 151: '

• 1/ 2* ( t +h )" 2 / $1 CIM" 21)* P PM A B152: 'y 0, AD*ACH*t= Aman for A 8153: 't*Tmax, and tot x0/U A:A154: (wi0) 'kote CRC (t)e0 tot t<x0/U and f or t> tine when entire spilt evaporates plus x0/W gone+1mam*x0/U)

A A155: (W10) ' A:A156: [W10) 's=== n an n n e n-u n n = = = = s e n=== = n n s s as * = === e n s u u s s un = n us k i a:A157: [W10) ' Calculation of Entire spilt tvaporation Time split kass teleased by time talman A A159: !V10) ' A:B160s ' (MAuma, g) r-k A t ti60s 'V0* A0'f amn+V0' ACH'(1 man"2)/ A:E161: 8 2+ 2*VCH' AD'(imaa"(1/2 ))* VC H* A:(162: ' ACH'(iman"(3/2))* 2/3 A D163: s Att163: ($3)

• t B3* t 65+ t75+ t B3N69* (t75'2 ) / 2+ 2't B6* t 65' (175* (1/2 ))4 86* t 69* (175'(3/ 2 ))* 2 /3 A A165: [W10)
• hote: If Mamas > Mt, icone is determined by solving the f ollowing equation for igone:

AIA166 [W10] 8 A8168: 'MR e VO* A0*f gone+V0' ACH'(igone"2)/2+2*VCH' A0*(igone** (1/2 ))*VCH' ACH* (I gone"(3/2 ))*2/3 A B169: 8 A:A171: (W10)

• Notes if MAmax < MR, 'Jone is determined by solving the following equation f or igone:

A: A172: (W10) ' A0174: 'MR MAmax = V0' Aman'igone+VCH' Aman *(T gone"(1/2))* 2 + Amam*1 max'V0 Amax'VCH'2'(iman)**(1/2) AB175: AIA176: !W101

• Note: Que to the interative nature of solving f or igone, it is comuted manually and entered into the appropriate cell.

A A177: [V10) ' A:B178:

• Amat =

A:C178: ($3) +t72 A:D178: 8 VCH s Att178: ($3) +tB6 AIF178: ' imax e AG178: (F1) *tT5 A:B179: 8 VD e AtC179: ($3) +EB3 A D179: 'MR MAmax = Att179: ($3) +t$7 E163 A:F179 'MR MAmancs AC179: ($3) 63221105.5346888537 1 A:C180: Ygone (sec) A:(180: 1368.8 1 A H180: ' \\m ? A:1180: (f 3) ' GET G179,C179*C178'(180+E178*C178'2'([180'(1/2)) C178*C179* C178 C178'[17B* 2'(G178'(1/2))? A:A131: IW10) * =sessnesu== s uussa ann su s====== sus==us asussesennussesansas A:A182: IW10] ' Calculation of Concentration Inside Control Room Concentration in the CR is comuted in a time step by step A:A183: (W10) manner by adding the the inside CR concentration (botF puf f AIA184: [W10) and continuous) at the previon ;ime st=p to the dif ference A:A185: [W10) between the current outside concentration minus the previous A:A186: [W10] ' inside concentration times an exponentia'. buildup f ac' or. A:A187 [W10) Constaet f or vatside Puf f: A:H188: 8 a

OTENERA m. r. sVsJCCT Verincation of TOYPUIT and TOYT: val' PRCPARtD BY DATC 3/R/93 - Ch3 I GTUS 12 3 Spreadthttt* CHtCKLD BY

• 1 DATC 6

PRt 5ct Monticello Tmir Chemical Study PRCL.satCT, or

)NTR A l.D. No.

1961 2.2-001 nty. O sHtCT F3 or 69 sHtCTs A,K188: ($3)

• tt t 136* ( St l54 / ( ( 2 * ( 3/2 ) )* ( S t S 17 * ( 3 /2 ) )
• St $ 117'I t t 114
• S t t 120 ) )* ( 1 + ct xP ( 0. 5' ( (101191
• S01191 )
• 2 )/ ( $

(1120*2))) Constant for Cont. w/ Aman: AHit9:

• A Kit 9: (53 ) + 1t l136'St 172* (1/(2* 5 t 137'lt $127'ttt123*st 518))* (1 +0E KP( 0.5* ((505191* t05191)* 2 3 / (St $123* 2 )))

A A190: (W10) 'essssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssses Constant for Contin. A(t): A:H190:

• A K190s ($3) +1t$136'(1*GtxP( 0.5'((tC1191*tet191)*2)/(til123*2)))

A:A191: (W10) 8 Analysis aesults A C191:

• he A D1911 Elftt91/1000000sf36,0,F22)

A:A192: (W10) 'Che W ol Analysed: Chlorine A31192. 'for A(t) A J192: 'for Aman A0193:

• Outside AIC193: 8 Outside AfD193:
• T ot v.

A:(193: ' tr,ide Alfi93 8 'nside A0193:

• istat A:H193:
• Outt';*e A:1193 8 Outside A.'193 8 OutsIde A K193
• jnside A:(1931 8 Inside A:B194:
• CR Conc A:C194: ' CR Cone A:D194: ' Outside AE194 ' CR Cone Anfi94: ' CR Conc A G194:
• Inside A N194: 8 CR Cone A:1194:

' CR Conc A:Ji94: ' CR Conc A K194 ' CR Conc A:(194 ' CR Conc A:B195: ' Puff AC195: ' Continuous AD195: ' CR Cone AE195:

• Puff Asft95: ' Continuous A:G195:
• CR Cone AtH195: '

Puff A:1195: ' Continuous A J195: ' Continuous A:K195:

• Puff A:L195: ' Continuous AM195: 8 $1 GYM (t)

A:A1963 (W10) 'line (sec) AiB196: ' (ppm) A:C196 8 (pin) A0196: 8 (pgn) Att196: * ( ptn) A:F196: ' (ppn) A:0196: (pFn) A:H196: ' (pin) A31196 8 (p;n) A:J196: ' (ppm) A:K196: ' (ppe) A:L196 8 (prn) A:M196: ' (m)

O_T2NERA SUBJECT Verincatinn of TOYi'UFT and TOYEV AP PREPARED BY l DATE 3/8/93 3 /14 / 3 1 OTUS 12-3 Spreadsheeft cHtetLD BY IK _DATE J PREL. sHttT OF PRORCT finnticello Tmic Chwnical Study CONTROL 1.D. No. 1 % 1 2.2-001 Rtv. _0 sHtcT 9 or 69 sHtcis A A197: (W10) 'e=esesses. A B197: 3 seus A:C197 ' enese A0197: 8 seus AE197: ' e --s u A:F197: # uen A G197: 8 scene A Hi97: 8 esen A31197 8 ense A J197: ' esses A Kjg7: 8 eesse A L197:

• sees.

A:A.J7: see A:A198: (W101 0 A!$198: ($3) CIF(N198<1E 99,0,N198) A:C198: ( 53 ) S I F ( (SE S160* SCS 178* S F S11/S F S18 A198 ) <0,0, CI F ( ( A198 S F S 11/ S F S 18 ) <$E S75,1198 J 198)) A:0198: (53) +B198+C198 A:(198 (53) 0 A:F198: ($3) 0 AIGi988 (53) +E198+F198 AtH198 ($3) *SKS188*GEXP( 0.5(SFS11 SFS18'A198)*2)/(SES117*2)) 5 A !198: ($3) EIF(( A198 SFS11/SFS18)<so,0,(SES65*5ES69'( A198 SFS11/SFS18))*(StS83+5tS86/(( A198 SFS11/SFS18)*(1/2 ) ) ) * ( 1/ ( 2

• S F S37* M 198' S E S 123
• S F S 18 ) )
• SKS 190 )

A J198: ($3) (StS83+1tS86/(( A198 SFS11/SFliB)*(1/2)))*SKS189 A:K198: (53) 0 AIL 198: (53) 0 A:M198: ($3) (SLS103*2+(SES65+SES69*(A198 SFS11/SFS18))/184900)*(1/2) A:A1993 (W10] +A198+1 A:6199: (53) GIF(H199<1E 99,0,H199) A:C199 ( $3 ) E l F ( ( SE S160+ $CS178+ 5 F S 11/S F S 18 A199 ) <0,0, El F (( A199 S F S11/S F S 18) <$t S75,1199, J i99) ) A:D199: ($3) *B199+C199 A:E199 (53) elf (K199<1E 99,0,K199) AF1992 (13) CIF(L199<1E 99,0,L199) A:G199: (53) +E199+F199 A:H199 ($3) +5KS188'cExP( 0.5'((SFS11*SFS1B*A199)*23/(St$117*2)) A 1399 (53) G1F(( A199 SFS11/SFS18)<=0,0,(tES65+SES69'( A199 SFS11/SFS18))*(StS83+5E186/(( A199 SFS11/SFS18)*(1/2 )))*(1/(2*STS37'M199'$tS123*SFS18))*SKS190) A:Ji99: (53) (StS83+SES$6/((A199 SFS11/STS18)*(1/2)))*SK$189 A:K199 (S3) +E198+(6199 E198)*(1 GEXP( 1*SFS24*( A199 (1981/(SFS23*60))) A:L199: (53) +F198+(C179 F198)*(1 EtxP( 1*SFS24*(A199 A198)/($FS23*60))) A:M199: ($3) (Sif103*2+(SES65+SES69*( A199 SFS11/SFS18))/184900)*(1/2) A A200: (W10] +A199+1 A:B200 ($3) GIF(H200<11 99,0,H200) A:C200 ( 53 ) E l F ( ( SES180+ SCS178 + S F S11/S F S18 A200) < 0,0, E l F ( ( A200 S F S11/S F S18) <SE S75,1200, J200)) A02003 (53) +B200+C200 AE200 (53) CIF(K200<1E-99,0,K200) AF200: (53) CIF(L200<1E 99,0,t200) A G200 (51) +E200+F200 A:H200 (53) *SKS188'etxP( 0.5*((SFS11 SFS18'A200)*2)/(SIS 117*2)) A:12003 (s)) elf (( A200 Sr$11/SFS18)<e0,0,(SES65+5ES69*( A200 SFt11/SFS18))*(StSB3+5ESJ6/(( A200 SFS11/SFS18)*(1/2 )))*(1/(2*SFS37'M200'StS123*SFS18))*SKS100) A:J200 (53) (SIS 83+SES$6/(( A200 SFS11/$FS18)*(1/2)))*SKS.J9 A:K200 (53) + E199+(b200 E199)*(14EXP( 1*SFS24*( A200 A199)/(SFS23*60))) A:L200 ($3) + F199+(C200 F199)*(1*QCxP( 1*SFS24*( A200 A199)/(SFS23*60))) A:M200: (53) (SIS 103*2+(SES65+SES69*( A200 SFS11/SFS18))/184900)*(1/2) a n

O_TENERA p= sulWECT VerMention of TOYPUTT and TO\\TVAP PREPARED BY DATE 3/8/93 CHECKED BY ME. DATE M71 LOTUS 12 3 Sprend4ttt? i PREL. sHCl'T Or PROJECT Monticello Tosieffemilcal Study CONTROL 1.D. NO. 1961 2.2-001 nov. O SHEET FF or 69 sHtrTs i APPlWD1X 3 70kEVAP Results for Ethyl Alcohol Analysis Range A1 Gi$0 l j A A B C D E F G l l 1 fonic Chemical spill Calculation 2 (For chemical botting point greater than anblent terperature) 3 f 4 Last 11pdated: 06 Mar 93 Anstyred themical: Ethyt Alcohol 5 6

e==========u=============================================

7 Design inputs: 5 8 /[ 9 Spill Date 10 Container volme (VC, em"3): 1.10$E+08 11 Spill to CR Intake Distance (x0, en 3218.0 12 Spill type: Circular / 13 14 15 meteorological Data / 16 Pasquit t's $tability category: G / 17 Anblent Tecperature (f ac, degrees C): 20 e j 18 Wind speed (V, m/sec): 1 19 Air Pressure (PA, atm): 1 y d 20 Air Pressure (Pa, m Hg): 0 21 Control Room Datas y a 22 control Room HvAC Intake Height (3, m): 11.28 / a 23 control Room voluw (CRV, f t"3): 2.700E*04 f 24 CR HVAC Intake Rate (CFIN, f t."3/ minute): 7440 25 26 Chemicat Data f 27 Chemical Density (DEhs, g/ce"3): 0.789 28 Bolting Point (ib, degrees C): 78.5 e 29 Molecular Weight (MW, s/trole): 46.07 Q i 30 Dif fusion Coef ficient (0, cm"2/see): 0.1 / 31 vapor Presssure (Ps, m Hg): 40 / 32 constants: 33 Ideal Gas Constant (k, atm m"3/ mote degree K): 8.205E 05 34 Air Density (DAIR, g/cm*=3, f p 35 at 1 atmosphere and 20 degrees C): 1.20E 03 / p 36 PI 3.1415927 / p 37 cravitational Constant (G, cm/sec"2): 981 / 38 Air Viscosity (VISC D Te, g/cm sec): 1.834E 04 39 40 Calculated Design Inputs: 41 / 42 Initial Chemical Mass (M1=vC'CENS, g): 8.718E+07 / 43 Arbient Temperature (Ta=Tec+273.16, degrees K): 293.16 ,7 44 Chemical Bolling Point (ib, riegrees K): 351.66 45 Schmidt hurcer (sc'*(1/3), (vlsC/D*D Al%W i/3);t 1.152E+00 46 s u = = = u n = n = = = = n e n n u = = = = u s u = = = = = = = = = = = = = n u ma :- = = = = = = = n w 47 Spilt Area Calculations: 48 49 Initial spill Radius (RD, cm) = (VC/PI)"(1/3) 50 = 3.276E+02 y

O._TENERA s e-susJECT Veririention of TO\\ TUFF and TO\\TVAP PREPARED BY I DATE 3/8/93 N/r /b CHECKED BY _I//[ DATE l.OTUS 12 3 SoreadshMit V PQOJECT Monticello Toste Chemical Study PREL. SHEET OF CON 1ROL l.D. N O. 1961 2.2-001 REv. O sHEri M or 69 SHEETS 51 52 Inittet $ pill Area (AO, ca"2) Pl*(R0"2) / 53 a "#.373t+05 54 55 Area Change Rate ( ACH, es**2/sec) e Pl*2*(g*(VC)* (Dths DAlt)/iDths*PI)]"1/2 m 56 57 = 1.166t+06 / 58 59 Manina spill Area (Aman, em"2) e VC/1 cm y 60

1.105E+08 61 62 Time When Aman Reached (fman, see) = (Aman AD)/ACH f 63 94.46 64 asa sss sse ssensenessass ssss eme ss essa s s e s s n e s e s san ess e nessans a s s e======

65 Calculation of dn/dt and igone (turbulent flow) 66 67 W dt (g/sec) = hd*A(t)* Met *(Ps Pa)/R*Ta i 68 69 hd (cm/sec) = (0.037*, :"(1/3))*D*(Pl**0.1) 70 f u'Du*pA R/YISC)"0.81/ 71 ((. *0.2)*( A;t)"D.1)) 72 Cottbining these eqs. glves 73 Wdt (g/sec) = K'( A(t)"(0.9)) 74 where: 75 Ke 7.503E 05 76 The following eq. Is solved for Tgone when igone > Tmant 77 78 Mt a K'(1/t.9)*(1/ACH)*((A0 + ACH* 79 imax)"(1.9) A0"(1.9)) + 80 K'( Aman"(0.9))*(f oone 1 max) 81 y 82 Toone (sec) = 6.706t+0* 83 asssesassanassassisenssiassessassenssenessenessnessa,essnessessenesses 84 Calculation of Sigmas (Dispersion Coefficients) 85 Pasq.-Gif f. Y Disp Coef f tog (510Y, m) e A*S* tog (x0,*C'(Log (10))"2+ 86 D*(togtX0)l"3 87 where A= 1.6212 SS 8a 1.0648 89 C a 0.01485' 90 D = 0.002056 / 91 SICY s 69.532 92 93 Pasq. Giff. Z Disp toeff log ($1GZ, m) e A+B* log (x0)+C'(tog (x0)','*2+ 94 D'(Log (x0))"3 95 where: A= 1.8981 96 8= 1.1243 97 C = 0.036447 98 D = 0.008635 / 99 SIGZ s 16.766 100 101 Cont Release Disp Coeff (SICZM, m) = (slCZ) 16.766 102 a 103 104 Cont Release Disp Coef f ($1 GYM, m) = (SIGY"2*(Ref f *P!"(1/2)/4.3) 105 "2)"(1/2) 73.704 (at Amax) / 106 s 107 Notes 108 For Circular Spitt, Reff a ( A( t )/P I )"(1/2) 109 110 esessassenessssssses=seneses===nesess=esesssssssss=es===ssssssssesass ill Conversion of g/m**3 to ppe l 1

@TENERA sunJEc7 Verification of TONI'UIT und TOYl:V Al' PREPARED BY I DATE 3/R/03 cHEcKEDsy.8 46 DATE 3 b/O 1.OTUS 121L Snreadsheets a PROJECT Slontirelin Tmic Chemical Study PREL. SHEET OF i CONTROL I D. NO. 1961 2.2 001 REV. _0 SHEET $7 OF _ 60 $HEETS 112 113 Conversion to PPM (PPM, mrv (g/m"3)). (R*1a*1.0E*06)/(Md*Pa) $22.11 / 114 ,,5 .s..................=..s.........s................................... p, mp 116 Calculation of Continuous Release Conc outside Control Room

• 1. M M M Cont Conc 4 CR Intake (CRC (t), gn). K*( A0+ ACH*t)* 4" (1/(2*PI'U* S I GtM* s t CIM))* (e s p [ M MV #5 N #M 119 W

where :=h*0 for DVAP>0 AIR,

• 1/2*(s h)**2/$lGZM"22 + esp!

i 121

• • h for OvAPs0 Alt, 1/2* ( a + h)"2/ 51 CIM"21 )' PPM q g,3 yy. g g y 122 y 0, AD ACH't= Amax f or agol (4 n N fy,d n ya m '

ilk t>fman, a M t t=x0/U 124 kote: CRC (t)=0 f or tex 0/U aM f or t> time when entire spilt evaporates 1 plus x0/0 (imax+Toone+x0/U) [tg %}3 127 DVAP (g/cm"3). Md=PA/R*f a 1.915E 03 a 128 129

=====s**s=*e=========*s==========s======***s===================**s

130 Calculation of Concentration inside Control R. 131 Concentration in the CR *s conpated in a th step by step 132 manner by eMing the the inside CR concentration 133 at the previous time step to the dif ference 134 between the current outside concentration minus the previous 135 inside concentration times an exponential buitdap f actor. 136 ses=====esseassese ss eesssss es== =s s es ssso m s s ===ses se === ss===s s==se==ssa 137 x(t) f or igone+1manex0/vit:1maa+x0/U: 1.750E*02 / 138 x(t) Constant for 1 man +x0/U> t = x0/U: 7.437E 04 139........ n a s s e s u s u u n.s n e n s a s u n a... s n.n = = = =.s.s n u s..... 140 Analysis Results hs 0 141 142 Outside inside Outside Inside themical Analysed: 143 CR Cone CR Conc CR Conc CR Cone Ethyl Alcohol 144 ContinuousContinuouscontinuousContinuous 145 Time (sec) (nn) (gn) (p;n) (Mn) 146====== essa===== sensa

=

147 0 0.000E+00'0.000E+00 0.000E *00 0.000E

• 00 148 1 0.000E+00 0.000F +00 0.000E +00 0.000E *00 149 2 0.000E+00 0.000E+00 0.000E*00 0.000E+00 150 3 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Range: A2950 G3400 A

A 8 C D E F G 2950 3206 0.000E+00 0.000E+00 0.000E+00 C.000E+00 2051 1205 0.000E+00 0.000E+00 0.000E+00 0.000E+00 2952 3210 0.000E+00 0.000E+00 0.000E+00 0.000E+00 2953 3212 0.000E+00 0.000E+00 0.000E+00 0.000E+00 2954 3214 0.000E+00 0.000E+00 0.000E+00 0.000E+00 .000E+00 0.000E+00 3216 0.000E+00 0.000E+00)1.010E+00 9.234E 03 2955 3218 1.010E+00 9.234E 03 2956 2957 3220 6.492E+0 /6.851E 02 6.492E+00 6.BS'E 02 2958 3222 1.141E+01 1.722C 01 1.141E+01 1.722E 01 2959 3224 1.60BE+01 3.177E-01 1.60BE+ 01 3.177E 01 2960 322b 2.059E+0i 5.030E 012.059E+015.030E 01 2961 3228 2.49BE+01 7.26SE 01 2.49BE*01 7.268[ 01 2962 3230 2.927E+01 9.87BE 01 2.927E+01 9.87BE 01 2963 3232 3.348E+01 1.285E+00 3.34tt+01 1.285E+00 2964 3234 3.763E*01 1.617E+00 3.763E+ 01 1.617E+00 2965 3236 4.171[+01 1.984E+00 4.171[+01 1.9B4E*00 1

O_TENERA sV8. JECT Verification of TOYPUIT and TO\\TV AP PREPARED BY DATE 3/8!93 1.OTUS 12-3 Spreadsheett CHECKED BY, "U DATE N d U PROJECT Monticello Tmic Chemical Studv PREL. SHEET OF CONTROL LD. NO. 1961 2.2-001 REv. O SHEET FR or 69 sHtETs 2966 3238 4.573E*01 2.364E+00 4.573t+01 2.384t+00 2967 3240 4.971t+01 2.816t+00 4.971t+01 2.2162 00 2968 32.2 5.363t+01 3.281E+00 5.363t+01 3.281t+00 2969 3244 5.752t+01 3.777t+00 5.752t+01 3.777t*00 2970 3246 6.137t+01 4.303t+00 6.137E+01 4.303t+00 2971 3248 6.51BE+01 4.660t+00 6.518t*01 4.860t+00 2972 3250 6.895t+015.446t+00 6.895E+015.446E400 2973 3252 7.269t+01 6.061t+00 7.269E+01 6.061t+00 2974 3254 7.640t+01 6.704E*00 7.640t+01 6.704E + 00 2975 3256 8.00ct+01 7.375t+00 8.008t+01 7.375E+ 00 2976 3258 8.373t+01 8.073t+00 8.373t+01 8.073E *00 2977 3260 8.735E+01 8.798t+00 8.735t+01 8.798t+00 2978 3e62 9.095t+01 9.549t+00 9.095t+01 9.549E +00 2979 3264 9.452E+01 1.033t*01 9.452t+01 1.033t+01 2980 3266 9.807E*01 1.113t+01 9.807t +01 1.113t + 01 2981 3268 1. 016t+ 02 1.196t + 01 1. 016t + 02 1.196t+ 01 2982 3270 1.051E+02 1.281E+01 1.051t402 1.281t+01 2983 3272 1.086t+02 1.36tE+01 1.086t+02 1.36BE +01 2984 3274 1.120E*02 1.458E*01 1.120E+02 1.45BE+01 2985 3276 1.155E+02 1.550t+01 1.155E*02 1.550t+01 29B6 3278 1.189t+02 1.645t + 01 1. iB9E+02 1.645t+01 2987 32B0 1.223t+02 1.742t+01 1.223E+02 1.742t+01 2988 3282 1.257t+02 1.841E+01 1.257t+02 1.B41t+01 2989 3284 1.290E+02 1.942f+01 1.290E*02 1.942E+01 2990 32861.324E*02 2.045E+01 1.324E+02 2.045E+01 2991 3288 1.357t+02 2.150E*01 1.357t+02 2.150E+01 2992 3290 1.390E+02 2.258t+01 1.390E+02 2.258t+01 2993 3292 1.423E+02 2.367E+01 1.423E+02 2.367t*01 2994 3294 1.455E+02 2.479E+01 1.455t+02 2.479E+01 2995 32961.488t+02 2.592E+01 1.4BBE*02 2.592E*01 2996 3/98 1.520t+02 2.7071-01 1.520t*02 2.707t+01 2997 3300 1.552t*02 2.824E+01 1.552E+02 2.E24E*01 2998 3302 1.584E+02 2.944t+01 1.584t+02 2.944t+01 2999 3304 1.616E+02 3.064t+01 1.616t+02 3.064E +01 3000 3306 1.648t*02 3.187E*01 1. '48t+02 3.187E+01 3001 3308 1.680E+02 3.312E+01 1.6BOE+02 3.312t*01 3002 3310 1.711t+02 3.43BE+01 1.711t+02 3.43Bt*01 3003 3312 1.742t+02 ).566t*01 1.74?E+02 3.566E+01 3004 3314 1.750t+02 3.693E+01 1.750E+02 3.693E+01 3005 3316 1.750E+02 3.819E+01 1.750E+02 3.819t+01 3006 3318 1.750E+02 3.944E+01 1.750E+02 3.944(+01 3007 3320 1.750E*02 4.068E+01 1.750E+02 4.06PE+01 3008 3322 1.750E+02 4.191E*01 1.750E*02 4.191E+01 3009 3324 1.750t+02 4.313E+01 1.750E+02 4.313E+01 3010 33261.750E+02 4.433E+01 1.750E+02 4.433E+01 3011 3328 1.750E+02 4.553E+01 1.750f+02 4.553E+01 3012 3330 1.750E+02 4.671t+01 1.750E+02 4.671E*01 3013 3332 1.750E+02 4.788E+01 1.750t+02 4.788E+01 3014 3334 1.750E+02 4.904E*01 1.750E+02 4.904t+01 3015 3336 1.750t*02 5.019E+01 1.750!*02 5.019E+01 3016 3338 1.750E+02 5.134E+01 1.750E+02 5.134E+01 3017 33401.750E+02 5.247E+01 1.750t+02 5.247E*01 3018 3342 1.750E+02 5.359E+01 1.750E+02 5.359E+01 3019 3344 1.750E+02 5.470t+01 1.750E+02 5.470E+01 3020 33461.750E+02 5.580E+01 1.750E+02 5.580E+01 3021 334B 1.750E+02 5.6BBE+01 1.750E+02 5.6BBE+01 3022 3350 1.750E+02 5.796E+01 1.750E+02 5.796E+01 3023 3352 1.750E+02 5.903E+01 1.750E+02 5.903E+01 3024 3354 1.750E+02 6.009E+01 1.750E+ 02 6.009E+01 3025 3356 1.750t*0? 6.114t+01 1.750E+02 6.114E+01 3026 3355 1.750E+02 6.218t+01 1.750E+02 6.41SE*01

@TENERA SUBJECT Verification of TO\\TUlT and ~,0\\TV AP PREPARED BY I DATE.3/R/93 LOTUS 12 3 Snreadsheets CHECKED BY N DATE MC A J PROJECT hlonticello Tmic Chemic I Study PREL.&HEET OF CONTROL i D. No. 1%12.2001 REv. O sHttT M or 69 sHECTs 3027 33601.750t+02 6.322t+01 1.750t+02 6.322t+0i 3028 3362 1.750E*02 6.424t*01 1.750E*02 6.424t*01 3029 3364 1.750t+02 6.525t+01 1.750t+02 6.525E+01 3030 33661.750E*02 6.625E*01 1.750t+02 6.625t+01 3031 3365 1.750t<2 6.725t+01 1.750E+02 6.725t+01 3032 3370 1.750t+02 6.823E*01 1.750t+02 6.823t+01 3033 3372 1.750t+02 6.921t+01 1.750E+02 6.921E*01 3034 3374 1.750E*02 7.017t+01 1,750E+02 7.017t+01 1035 33761.750E+02 7.113t+01 1.750t+02 7.113E+01 3036 3376 1.750t+02 7.208t*01 1.750E*02 7.208t+01 3037 33801.750E+02 7.302t+01 1.50t*02 7.302E+01 3038 3382 1..'50E*02 7.396t+01 1.750E 02 7.396t+01 3039 3384 1.750t+02 7.48BE*01 1.750t +02 7.488t+01 3040 33b6 1.750t +02 7.579t+01 1.750E+ 02 7.579t+01 3041 3388 1.750t+02 7.670E+01 1.750t+02 7.670t+01 3042 3390 1.750E*02 7.760E*01 1.750E +02 7.760E+01 3043 3392 1.750t+02 7.849E+01 1.750E+02 7.849E*01 3044 3394 1.50t+02 7.937E+01 1.750E+02 7.937E +01 3045 33961.750E*02 8.025t+01 1.750t+02 8.025E+01 3046 3398 1.750t+02 8.111t+01 1.750E*02 8.111E*01 3047 3400 1.750t+02 8.197t+01 1.750E +02 8.197t+01 3048 3402 1.750E+02 8.282t+01 1.750E*02 8.252E+01 3049 3404 1.750t*02 8.366E+01 1.750t+02 8.366t+01 3050 3406 1.750E+02 8.450E*01 1.750E+02 t.450E+01 3051 3408 1.750t+02 8.532E+01 1.750E+02 8.532t+01 3052 3410 1.750E+02 8.614E+01 1.750E+02 8.614E+01 3053 3412 1.750t+02 8.696t+01 1.750E*02 0.696t +01 3054 3414 1.750t+02 8.776E +01 1.750E +02 8.776t+01 3055 3416 1.750E+02 8.856t*01 1.750t+02 8.856t+01 3056 3418 1.750t+02 8.935E+01 1.750E+02 8.935t*01 3057 3420 1.750E*02 9.013E*01 1.75CE+02 9.013t+01 3058 3422 1.750E*02 9.091t+01 1,750E+02 9.091t+01 3059 3424 1.'50t*02 9.167E+01 1.750E+02 9.167E+01 3060 3426 1.750E+02 9.244t+01 1.750E+02 9.244E*01 3061 3428 1.750t+02 9.319E+01 1.750E *02 9.319E+01 4 3062 3430 1.750E+02 9.394E+01 1.750t +02 9.394E+01 3063 3432 1.750t+04 9.468t+01 1.750E+02 9.46BE+01 3064 3434 1.750E*02 9.541E *01 1.750t+02 9.541t+01 3065 3436 1.750E+02 9.614E+01 1.750t+ 02 9.614E+01 3066 3438 1.750t+02 9.686t+01 1.750E *02 9.686E+01 3067 34401.750E+02 9.758E+01 1.750t+02 9.758E*01 3068 3442 1.750E+02 9.828t+01 1.750E+02 9.82BE*01 3069 3444 1.750E+02 9.89BE+01 1.750E*02 9.89BE+01 3070 3446 1.750E+02 9.96BE*01 1.750t+ 02 9.96BE*01 3071 3448 1.750t + 02 1.004E + 02 1. 750E + 02 1.004t + 02 3072 3450 1. 750t+ 02 1.010E + 02 1.750E + 02 1.010E+02 3073 3452 1. 750E + 02 1. 017t + 02 1. 750E + 02 1. 017t + 02 3074 3454 1.750E+02 1.024E+02 1.750t+02 1.024t+02 3075 3456 1. 75 0E

• 02 1.031 E + 02 1.75 0E + 02 1.031[
• 02 3076 3458 1.750E+ 02 1.037E + 02 1.750E+ 02 1.037t+ 02 3077 3460 1.750E+02 1.044E+02 1.750t+02 1.044E+02 3078 3462 1.750E+02 1.050E+02 1.750E+02 1.050E+02 3079 34 64 1. 750t + 02 1.057E + 02 1. 750E + 02 1. 057E + 02 30B0 3466 1. 750E + 02 1. 063 E + 02 1. 750E + 02 1. 063 E
• 02 3081 3468 1.750E+02 1.069E+02 1. T t+02 1.069E+02 3082 3470 1.750t+02 1.075E+02 1 %:+02 1.075E+02 3472 1.750E+02 1.082t+02 ',.+02 1.082E+02 3083 3474 1.750E+02 1.08BE+ 02. h.",E + 02 1.0BBE
• 02 3054 3085 3476 1.750t + 02 1.094 E
• 02 1. 75 DE + 02 1.094E + 02 3086 3478 1.750E+02 1.100E+02 1.750E+02 1.100E+02 3087 3480 1. 750E + 02 1.106E + 02 1. 750E + 02 1.106E + 02

.m O_TENERA sututCT Verification of TO\\*Pt4T and TO\\TV AP PREPARED BY I DATE 3/8/03 CHECKED BY dh4_. DATE N3 i OTUS 12 3 Sorcadsheett i PRE 1.. sHE ET OF PROJECT Monticello Tosic Chemical Study CONTROL i D. No. 1061 2.2-001 REv. O SHEET 60 or 60 sHtris 3088 3482 1. 750t +02 1.112E + 02 1. 750E +02 1.112E* 02 3089 34 64 1. 750E + 02 1.117t + 02 1. 750E + 02 1.117E

• 02 3090 3486 1. 750E + 02 1.123E+02 1.750E
• 02 1.123E+ 02 3091 34 B8 1. 750E + 02 1.12 ?E + 02 1. 750E + 02 1.129E + 02 3092 3490 1. 750E +02 1.155E
• 02 1. 750E + 02 1.135E+02 3093 3492 1.750E+ 02 1.140E+ 02 1. 750E
• 02 1.140E + 02 3094 3494 1. 750E + 02 1.146t + 02 1. 750E + 02 1.146E + 02 3095 3496 1.750E+02 1.151E+02 1.750E+02 1.151E*02 3096 3498 1.750E + 02 1.15 7E + 02 1.750E + 02 1.157E + 02 3097 35 00 1. 750E
• 02 1.162E + 02 1. 750E + 02 1.162E
• 02 3098 3502 1.750E +02 1.16SE *02 1.750E + 02 1.168E+ 02 3099 3504 1.750E
• 02 1.173E +02 1.750E
• 02 1.173E + 02 3100 3506 1. 750E + 02 1.17BE + 02 1.750l +02 1.11 BE
• 02 3101 3508 1.750E + 02 1.183 E
• 02 1. 750E + 02 1.183[
• 02 3102 3510 1. 750E
• 02 1.189E
• 02 1. 750E + 02 1.189E
• 02 3103 3512 1.750E + 02 1.194E +02 1.750E
• 02 1.194E+02 3104 3514 1. 750E + 02 1.190E + 02 1. 750E + 02 1.199E + 02 3105 3516 1. 750E + 02 1.204t
• 02 1. 750E + 02 1. 204E +32 3106 3518 1.750E +02 1. 209E* 02 1. 750E+ 02 1.209E* 02 3107 3520 1.750E+02 1.214E*02 1.750E*02 1.214E+02 3108 3522 1.750E*02 1.219E*02 1.750E+02 1.219E+02 3109 3524 1.750E+02 1.223E*02 1.750E+02 1.223E+02 3110 3526 1.750E+02 1.22EE+02 1.750E*02 1.22BE*02 3111 3528 1. 750E + 02 1. 233E + 02 1. 750E+ 02 1.233E
• 02 3112 3530 1. 750E
• 02 1.23BE + 02 1. 750E + 02 1. 23BE + 02 3113 3532 1.750E+02 1.242E*02 1.750E+02 1.242E+02 3114 3534 1.750E*02 1.247E*02 1.750E+02 1.247E*02 3115 3536 1.750E+02 1.252E*02 1.750E+02 1.252E+02 3116 3538 1.750E + 02 1. 256E + 02 1.750E
• 02 1. 256E +02 3117 3540 1.750E
• 02 1. 261 E
• 02 1. 750E + 02 1. 261 E
• 02 3118 3542 1. 750E + 02 1.265E + 02 1.750E + 92 1.265E +02 3119 3544 1.750E+02 1.270E*02 1.750E+02 1.270E*02 3120 3546 1.750E + 02 1.274E + 02 1. 750E + 02 1.274E + 02 3121 3548 1.750E + 02 1.2 ?BE
• 02 1. 750E + 02 1.27BE + 02 3122 3550 1.750E + 02 1.283E + 02 1.750E+ 02 1.283E + 02 3123 3551 1.750E
• 02 1.287E+02 1.750E+02 1.287E+02 3124 3554 1.750E
• 02 1.291E + 02 1.750E +02 1.291E +02 3125 3556 1.750E + 02 1. 295E + 02 1. 750E + 02 1. 295E
• 02 1

3126 3558 1. 750E + 02 1.300E + 02 1. 750E + 02 1.300E + 02 3127 3560 1. 750E +02 1.304E *02 1.750E+ 02 1.304E

• 02 3128 3562 1.750E+02 1.30SE*02 1.750E*02 1.30BE*02 3129 35 64 1. 750E + 02 1. 312 E + 02 1. 750E
• 02 1.312E + 02 3130 3566 1. 750E+02 1.316E + 02 1.750E+02 1.316t+ 02 3131 3568 1.750E +02 1.320E + 02 1.750E
• 02 1.320E +02 3132 3570 1. 750E + 02 1.324E +02 1.750E + 02 1.324E +02 3133 3572 1.750E + 02 1.32BE+02 1.750E + 02 1.32tE* 02 3134 3574 1.750E+02 1.331E+02 1.750E+02 1.331E+02 3135 3576 1.750E+02 1.335E*02 1.750E+02 1.335E+02 3136 3578 1.750E+02 1.339E+02 1.750E+02 1.339E+02 3137 3580 1. 750E
• 02 1.343E+ 02 1.750E + 02 1.343E + 02 3138 3582 1.750E+ 02 1.347E+02 1.75 CE + 02 1.347E + 02 3139 3584 1.750E+02 1.350E+02 1.750E+02 1.350E*02 3140 3586 1.750E + 02 1.354E +02 1.750E +02 1.354E + 02 3141 3585 1.750E + 02 1.357E+ 02 1.750E + 02 1.357E + 02 3142 3590 1.750E+02 1.361E+02 1.750E+02 1.361E+02 3143 3592 1.750E +02 1.365E +02 1.750E + 02 1.365E+ 02 3144 35 94 1. 750E + 02 1.36SE +02 1. 750E + 02 1.3 58E
• 02 3145 3596 1.750E+02 1.372E+02 1.750E+02 1.372E+02 3146 3598 1.750E+02 1.375E+02 1.750E+02 1.375E+02 3147 3600 1. 750E + 02 1.378E
• 02 1. 75 0E + 02 1. 37BE+ 02 3148 3700 1.750E + 02 1.515 E + 02 1.750E
• 02 1.515E *02

G_TENERA SUlWECT Verific *lon <J TO\\'I'tTF and TOYD' A P PREPARED BY DATE 3/8/03 I/ k LOTt'S 12 3 Sorcadsbets cHEcKtD BY.k 4 DATE ) PROJE CT Montictiln Tmir Chemical Study PREL SHEET OF CONTROL l.D. NO. 1961 2.2-001 REv. O SHECT 6I OF 60 SHEETS 3149 3800 1.750E +02 1. 602E + 02 1. 750E + 02 1. 602E

• 02 3150 3900 1. 750t + 02 1.656E +02 1. 75 0E + 02 1. 656E + 02 3151 4000 1.750E+02 1.691E + 02 1.75 DE
• 02 1.691E+02 3152 4100 1.750E+02 1.712E*02 1. M 0E+02 1.712E+02 3153 4200 1.750E* 02 1.726t + 02 1.750E + 02 1.726t+02 3154 4300 1. 750E +02 1. 735E + 02 1. 750E + 02 1. 735E + 02 3155 4400 1. 750E
• 02 1. 740E+ 02 1. 75 0E + 02 1. 740E + 02 3156 45 00 1. 750E
• 02 1. 744 E
• 02 1. 750E + 02 1. 744 E + 02 3157 4600 1. 750E + 02 1. 746E + 02 1. 750E + 02 1. 746t + 02 3158 4700 1. 750E + 02 1. 747u02 1. 750E + 02 1.747t +02 3159 4 B00 1. 750E
• 02 1. 74 BE + 02 1. 750E
• 02 1. 74 BE + 02 3160 4900 1.750E +02 1.749E
• 02 1. 750E + 02 1. 749E
• 02 3161 5000 1. 750E
• 02 1. 749E
• 02 1. 750E + 02 1. 749E
• 02 3)62 5100 1.750E+02 1.749E+ 02 1.750E + 02 1.749E + 02 3163 5200 1.750E+02 1.749E+02 1.750E*02 1.749E+02 3164 5300 1.750E
• 02 1.749E + 02 1. 750E
• 02 1.749E
• 02 3165 5400 1.750E+02 1.750E+02 1.'r50E+02 1.750E+02 3166 5500 1.750E*0e 1.750E+02 1.750E*02 1.750E+02 3167 5600 1.750E + 02 1.750E
• 02 1. 750C + 02 1.750E
• 02 3165 5700 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E + 02 3169 5800 1. 750E + 02 1. 750E + 02 1.750E +02 1. 750E + 02 3170 5900 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E +02 3171 6000 1.750E +02 1.750E* 02 1.750E + 02 1. 750E + 02 3172 6100 1. 750E
• 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 3173 6200 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3174 6300 1. 750E + 02 1. 750E + 02 1. 750E
• 02 1. 750E +02 3175 6400 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E+ 02 3176 65 00 1. 750E
• 02 1. 750E
• 02 1. 750E
• 02 1. 750E
• 02 3177 6600 1. 7' 0E + 02 1. 750E
• 02 1. 750E
• 02 1. 750E + 02 3178 6700 1. 750E
• 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3179 6800 1. 750E
• 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3180 6 900 1. 750E + 02 1.7! DE
• 02 1. 750E + 02 1. 750C +02 3181 7000 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3182 7100 1.750E +02 1.750E+ 02 1.750E
• 02 1.750E* 02 3183 7200 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3184 7100 1.750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3185 7400 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 3186 7500 1 750E + 02 1.750E
• 02 1.750E + 02 1. 750E +02 3187 7600 1. 750E
• 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3188 7700 1.750E+02 1.750E+02 1.750E+02 1.750E*02 3189 7800 1. 750E + 02 1.750E + 02 1.750E + 02 1.75DE +02 3190 7900 1. 750E
• 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3191 8000 1.750E + 02 1.750E + 02 1.750E
• 02 1.750E+02 3192 8100 1.750E+02 1.750E*02 1.750E+02 1.750E+02 3193 8200 1.750E+02 1.750E+02 1.750E+02 1.750E+02 3194 C300 1.750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3195 8400 1.750E+ 02 1.750E +02 1.750E+ 02 1.750E +02 3196 85 00 1.750E + 02 1.750E + 02 1. 750E + 02 1.750E + 02 3197 B600 1.750E + 02 1.750E +02 1. 750E + 02 1. 750E + 02 3198 8700 1. 750E + 02 1.750E
• 02 1.75 0E + 02 1.750E +02 3199 8800 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3200 8900 1. 750E+ 02 1. 750E + 02 1. 750E + 02 1.750E + 02 3201 9000 1. 750E
• 02 1. 750E +02 1. 750E
• 02 1. 750E + 02 1

3202 9100 1.750E+02 1.750E*02 1.750E+02 1.750E+02 3203 9200 1. 750E +02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3204 9300 1.750E*02 1.750E+02 1.750E+02 1.750E*02 3205 9400 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750 E + 02 3206 9500 1.750E+ 02 1.750E + 02 1.750E +02 1. 750E + 02 3207 9600 1. 750E +02 1.750E

• 02 1. 750E + 02 1. 750E + 02 3208 97UD 1.750E*02 1.750E+t? 1.750E+02 1.750E+02 3209 9500 1,750E+ 02 1.75 0E + 02 1.750E + 02 1. 750E + 02

O_TENERA sVEUECT Verification of TO\\ TUFT and TO\\TVAI' PREPARED BY DATE 3/8/93 CHECKED BY d6_ DATE NM i OTUS 12 3 Spreadsheets / PROJECT Monticello Tmic Chemical Study PnEL. SHEET OF CONTROL l.D. NO. 1961 2.2 001 REV. O SHEET 62 or 69 SHEETS 3210 9900 1. 50E

• 02 1. 750E
• 02 1. 750t + 02 1.750E +02 3211 10000 1. 50E + 02 1. 750E +02 1. 750t + 02 1. 750E+02 3212 10100 1. BOE + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3213 10200 1. 750E
• 02 1. 750E + 02 1. 750t + 02 1. 750t + 02 I

3214 10300 1. BOE + 02 1. 750E + 02 1. 750E

• 02 1. 750t +02 3215 10400 1.750E + 02 1.750E + 02 1. 750E + 02 1. 750E + 02 3216 10500 1. B 0t + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 1

3217 10600 1.B0E +02 1.750E+ 02 1.750t + 02 1. 750E +02 3218 10700 1.7SOE + 02 1. 750E+ 02 1. 750t + 02 1. 750E +02 3219 10800 1.750E + 02 1.750E +02 1. 750E + 02 1. 750E + 02 3220 10000 1.750E + 02 1. 750t + 02 1. 750E

• 02 1. 750t +02 3221 11000 1. 7SDE +02 1.750E + 02 1. 750t + 02 1.750E + 02 3222 11100 1. BOE + 02 1. 750E + 02 1. 750E + 02 1. 750t + 02 3223 11200 1. 750E + 02 1.750t +02 1.750E + 02 1.750E *02 3224 11300 1. BOE + 02 1. 750E + 02 1. 5 0t + 02 1. 750t + 02 3225 11400 1. 50E +02 1. 750E + 02 1. 750E + 02 1.750E +02 3226 11500 1. 50E + 02 1. 750E
• 02 1. 750 E
• 02 1. 750l+ 02 3227 11600 1. 50E + 02 1. 750E
• 02 1. 750E + 02 1. 750E + 02 3228 11700 1. BOE + 02 1. 750t + 02 1. 750E + 02 1. 750E* 02 3229 11800 1. 50E + 02 1.750t + 02 1. 750E
• 02 1. 750E + 02 3230 11900 1.710E+ 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 3231 12000 1. 50E + 02 1. 750E + 02 1. 75 0E + 02 1. 750E + 02 3232 12100 1.7!.0E + 02 1.750E+ 02 1.750E + 02 1. 750E + 02 3233 12200 1.7! 0E + 02 1. 750E+ 02 1. 75 0E + 02 1.750E + 02 3234 12300 1. 710E +02 1.750E* 02 1.750E + 02 1. 750E + 02 3235 12400 1. 7!.0E + 02 1. 75 0E + 02 1. 750E + 02 1. 750E + 02 3236 12500 1.7! 0E + 02 1.750E +02 1.750E+02 1.750E
• 02 3237 12600 1.75 0E +02 1.750E* 02 1.750E+ 02 1.750E *02 3238 12700 1. 7!.0E + 02 1.750E + 02 1. 750E + 02 1.750E +02 3239 12800 1.750E + 02 1.750E + 02 1. 75 0E + 02 1.750E + 02 3240 12900 1. 750E +02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3241 13000 1. 750E + 02 1.75 DE
• 02 1. 750t + 02 1. 750t + 02 3242 13100 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3243 13200 1. 50E + 02 1. 750E* 02 1. 750E
• 02 1. 750E + 02 3244 13300 1. 750E + 02 1.750t + 02 1.750E+ 02 1. 750E + 02 3245 13400 1. 50E + 02 1.750E
• 02 1. 750E
• 02 1. 750E + 02 3246 13500 1.750E + 02 1.750E + 02 1.750E + 02 1. 750E +02 3247 13600 1. BOE + 02 1.750E + 02 1. 750E + 02 1. 750E + 02 3248 13700 1. 750E
• 02 1. 750E+ 02 1. 750E+ 02 1. 750E + 02 3249 13800 1.7SOE+02 1.750E+ 02 1. 750E
• 02 1. 750E+ 02 3250 13900 1. 750E + 02 1.750E +02 1. 750E + 02 1.750E+02 3251 14000 1.750E +02 1.750E +02 1.750E +02 1.750t+ 02 3252 14100 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3253 14200 1. 750E+ 02 1.750E +02 1. 75DE + 02 1. 750E +02 3254 14300 1. 750E + 02 1. 750E + 02 1. 750E + 02 1.750E + 02 3255 14400 1. 750E
• 02 1. 750E+ 02 1. 750E + 02 1.750E+ 02 3256 14500 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3257 14600 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3258 14700 1. 750E + 02 1. 750 E + 02 1. 75 0E + 02 1. 7' ? + 02 3259 14800 1.750E+02 1.750E+02 1.750EU '. 750E+4 3260 14900 1.750E+ 02 1.750E+ 02 1.750E + 01 1. 750E
• 02 3261 15000 1. 750E + 02 1. 75 C E + 02 1. 750E + 02 1. 750E + 02 3262 15100 1.75DE+ 02 1.750E+ 02 1.750E +02 1.750E + 02 3263 15200 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3264 15300 1.750E + 02 1.750E+02 1.750E+ 02 1.750E + 02 3265 15400 1. 750E + 02 1. 750E
• 02 1. 75 0E + 02 1. 750E + 02 3266 15500 1.750E
• 02 1.750E +02 1.750E + 02 1.750E+ 02 3267 15 600 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E +02 3268 15 700 1. 750E + 02 1.750E + 02 1. 750E +02 1.750E + 02 3269 15800 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3270 15 900 1.750E + 02 1.750E + 02 1.75 0E + 02 1.750E+ 02

O_TENERA SutuEc7 Verification of TOVPt'IT and TO\\TY AP PREPARED BY DATE 3/R/93 CHECKED ev A A DATE N/N O LOTI'; 12 3 Screadsheets J PROJECT Wnticello Tosic Chemical Study PREL SHEET OF CONTROL i D. NO. 1961 2.2-001 REV. 0,,,,,,, SHElT 63 OF 69 SHEETS 3271 16000 1. 750E

• 02 1. ME + 02 1. 750E + 02 1. 750E + 02 3272 16100 1.750E + 02 1. 750t o2 1. 750E + 02 1. 750E +02 3273 16200 1.750E* 02 1.750E +c2 ;. r50E+02 1.750E+02 3274 16300 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3275 16400 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 3276 16500 1.750E + 02 1.750E
• 02 1.750E +02 1. 750E+02 3277 16600 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3278 16700 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. D DE
• 02 3279 16800 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E + 02 3280 16000 1. 750E + 02 1. 750E + 02 1. 750! + 02 1. 750E + 02 3281 17000 1.750E + 02 1.750E+02 1. 750L + 02 1. 750E + 02 3282 17100 1.750E
• 02 1. 750E
• 02 1. 750t + 02 1. 750E
• 02 3283 17200 1. 75 0E + 02 1. 750E* 02 1. 750E + 02 1. 750E
• 02 3284 17300 1. 750E + 02 1. 750E + 02 1.750E + 02 1.750E
• 02 3285 17400 1. 750E + 02 1. 750E +02 1. 750E + 02 1. 750E + 02 3266 175 00 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E + 02 3287 17600 1. 750 E
• 02 1. 750E
• 02 1. 750t + 02 1. 750E
• 02 3288 17700 1. 750E + 02 1. 750E
• 02 1. 750E
• 02 1. 750E + 02 3289 17800 1. 750E
• 02 1. 750E + 02 1. 750E
• 02 1. 750E
• 02 3290 17900 1. 750E + 02 1. 750E
• 02 1. 750E
• 02 1. 750E + 02 3291 18000 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E + 02 3292 18100 1.750E+02 1.750E+02 1.750E+02 1.750E+02 3293 18200 1. 750E + 02 1. 750E + 02 1. 750E 4 02 1. 750E
• 02 3294 18300 1. 750E + 02 1. 750E + 02 1. 75 0E + 02 1. 750E + 02 3295 18400 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3296 12500 1. 750E
• 02 1.750E + 02 1.750t + 02 1. 750E + 02 3297 15600 1.750E
• 02 1.750E
• 02 1.750E + 02 1.750E +02 3298 18700 1. 750E
• 02 1.750E + 02 1. 750E + 02 1.750E +02 3299 18B00 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E +02 3300 18900 1. 750E
• 02 1. 750E
• 02 1.750E + 02 1.750E + 02 3301 19000 1. 75 DE
• 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 3302 19100 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E
• 03 3303 19200 1.750t + 02 1.750E + 02 1. 750E + 02 1. 750E +02 3304 19300 1. 750 E + 02 1. 750E + 02 1. 750E
• 02 1. 750E + 02 3305 19400 1.750E + 02 1.750E + 02 1. 750E + 02 1. 750E
• 02 3306 19500 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 3307 19600 1.750E +02 1.750E + 02 1.750E + 02 1. 750r+ 02 3308 19700 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3309 19800 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3310 19900 1. 750E + 02 1.750E+ 02 1. 750E +02 1.750E+ 02 3311 20000 1.750E + 02 1.750E + 02 1. 750E +02 1. 750E +02 3312 20100 1. 750E + 02 1. 750E
• 02 1.750E + 02 1. 750E *02 3313 20200 1. 750E
• 02 1. 750E + 02 1. 750E
• 02 1. 750E + 02 3314 20300 1.750E
• 02 1.750E+02 1.750E +02 +.750E +02 3315 20400 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. %ve 3316 20500 1. 750E + 02 1. 750E + 02 1. 750E +02 1. 750E + 02 3317 20600 1. 750E + 02 1. 750E + 02 1. 750E
• 02 1. 750E + 02 3318 20700 1. 750E + 02 1. 750E + 02 1. 750E
• 02 1. 750E
• 02 3319 20000 1.750902 1.750E + 02 1.750E + 02 1.750E + 02 3320 20900 1.750E+02 1.750E*02 1.750E+02 1.750E+02 3321 21000 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1. 750E + 02 3322 21100 1. 750E + 02 1. 750E + 02 1. 750E
• 02 1. 750E + 02 1

3323 21200 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3324 21300 1. 750 E + 02 1. 750E + 02 1. 750E + ')2 1.750E + 02 3325 21400 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E

• 02 33?6 21500 1.750E+02 1.750E+02 1.750E+02 1.750E+02 3327 21600 1.750E+02 1.750E+02 1.750E+02 1.750E+02 3328 21700 1.750E+02 1.750E+02 1.750E+02 1.750E*02 21900 1. 750E + 02,1. 750E + 02 1. 750E + 02 1. 750E + 02 21800 1.750E+02 3329 1.750E+02 1.750E+02 1.750E*02 3330 3331 22000 1.750E+02 1.750E+02 1.750E+02 1.750E+02 e - mums

O_TENERA SUBJECT Verification of TO\\*PtTF and TOLEY AP PREPARED BY DATE 3/8/93 /0__DATE A b I OTl'S 12 3 Snreadthtetc CHECKED BY 3 PROJECT hfonticelin Tmic Chemical Study PREL SHEET _ OF CONTROL l.D. NO. 1061 2.2-001 REV. O SHEET 4 OF 60 sHEE7s 3332 22100 1. 750E + 02 1. 750E

• 02 1. 750E + 02 1. 750E + 02 3333 22200 1. 50E
• 02 1. 75 DE
• 02 1. 750E + 02 1. 750E + 02 3334 22300 1.750E+0? 1.750t+02 1.750t+02 1.750E+02 3335 22400 1.750E +02 1.750E +02 1.750E +02 1.750E +02 3336 22500 1. 50E
• 02 1. 750t + 02 1. 750E + 02 1. 750E + 02 3337 22600 1.750E*02 1.750t+02 1.750t+02 1.750E
• 02 3338 22700 1. 750t + 02 1. 750t + 02 1. 750E + 02 1. 750t
• 02

. 750t + 02 1.750E+ 02 228001.750E*021.750t+02))1750E 021750E 02 3339 229001.750E*02J.750E+02 750E+02 1.750E*02 3340 23000 1.750E

• 02' 1.750E* 02

+ + 3341 3342 23100 1. 750E *02 1. 750E +02 1. 750E + 02 1. 750E+ 02 3343 23200 1. 750t + 02 1.750E+02 1.750E +02 1.750E+02 3344 23300 1. 750t + 02 1. 750E + 02 1. 750t + 02 1. 750E + 02 3345 23400 1.750E + 02 1. 750t + 02 1. 750t + 02 1. 750t + 02 3346 23500 1.750t + 02 1.750E +02 1. 750E + 02 1.750E + 02 3347 23600 1.750E+02 1.750t + 02 1.750E + 02 1.750E + 02 3348 23700 1.750E +02 1.750E +02 1. 750E

• 02 1. 750E +02 3349

' 23800 1.750E+02 1.750t+02 1.750E+02 1.750E+02 3350 23900 1.750E+02 1. 750f

• 02 1. 750E + 02 1. 750E + 02 3351 24000 1. 750!+ 02 1.750E + 02 1. 750E + 02 1. 750002 3352 24100 1. 750E + 02 1.750E + 02 1. 750E + 02 1. 750E + 02 3353 24200 1.750E +02 1. 750E +02 1. 750t +02 1.750t + 02 3354 24300 1.M0t +02 1. 750E + 02 1. 750E* 02 1.750E+ 02 3355 44400 1. 750E
• 02 1. 750E + 02 1. 750E
• 02 1. 750t + 02 3356 245 00 1. 750t
• 02 1. 750t + 02 1. 750t + 02 1. 750E + 02 3357 MO 1.750N 1.750t+02 1.750E+02 1.750t+02 3358 24700 1. 750t + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3359 24800 1. 750t
• 02 1. 750 E + 02 1. 750t
• 02 1. 750E + 02 3360 24900 1.750E +02 1.750E *02 1.750E *02 1.750E *02 3361 25000 1. 750E
• 02 1. 750t + 02 1. 750E + 02 1. 750E
• 02 3362 25100 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750t + 02 3363 25 200 1. 750E + 02 1. 750E + 02 1. 750E + 02 1.750E
• 02 3364 25300 1. 750E + 02 1.750E
• 02 1.750E + 02 1. 750E+02 3365 25400 1.750t +02 1.750E
• 02 1.750E
• 02 1.750E
• 02 3366 25500 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E + 02 3367 25600 1.750E
• 02 1.750t + 02 1.750E
• 02 1.750E + 02 3365 25700 1. 750E + 02 1.750E + 02 1. 750E + 02 1.750E +02 3369 25800 1.750E+02 1.750t+02 1.750E+0Z 1.750E+02 3370 25900 1. 750t +02 1. 750t + 02 1. 750E + 02 1. 750E + 02 3371 26000 1.750E* 02 1.750E+ 02 1.750E+ 02 1.750E
• 02 3372 26100 1. 750t + 02 1.750E
• 02 1. 750E + 02 1. 750E + 02 3373 26200 1.750E + 02 1.750E + 02 1.750E+02 1.750E +02 3374 2 6300 1.750E+02 1.750t+02 1.750E+ 02 1.750E+ 02 3375 26400 1. 750E
• 02 1. 750t + 02 1. 750E
• 02 1. 750E
• 02 3376 26500 1.750E + 02 1.750E +02 1.750t + 02 1.750E + 02 3377 26600 1.750!+02 1.750E+02 1.750E +02 1.750E +02 3378 26700 1.750E+ 02 1.750t* 0' 1.750E + 02 1.750E*02 3379 26B00 1.750E+02 1.750E+02 1.750t*02 1.750E+02 3380 26900 1.750t
• 02 1.750E
• 02 1.750E +02 1.750E+02 3351 27000 1. 750E + 02 1. 750E + 02 1. 750E + 02 1. 750E
• 02 s

3382 2710 0 1. 750t + 02 1. 750E

• 02 1. 750t + 02 1. 750E
• 02

[ 3323 272]O 1.750E + 02 1.750E +02 1.750E+02 1.750E+02 ( 1 33S4 27300 1. 750E + 02 1. 750t + 02 1. 750 E + 02 1. 750E + 02 3325 27400 1.750E + 02 1. 750E + 02 1. 750E

• 02 1. 750E* 02 4

3386 27500 1. 750E + 02 1. 750E +02 1. 750E + 02 1. 750E

• 02 3387 27600 1. 750E + 02 1. 750t + 02 1. 750t + 02 1. 750E + 02 3338 27700 1.750t + 02 1. 750E +02 1. 750E + 02 1. 75 DE + 02 3389 27800 1. 750E + 02 1.750E + 02 1.750E + 02 1.750E
• 02 3390 27900 1. 750t + 02 1. 750t + 02 1. 750E + 02 1. 750E 402 3391 28000 1.750E+02 1.750t+0? 1.750t+02 1.750E+02 3302 28100 1. 750E + 02 1. 750t + 02 1. 750E + 02 1. 750E + 02

- @TENERA SututcT Verification of TO\\'PtfiT and TO\\TVAP PREPARED BY DATE 3 /R /93 cHtcKED BY Mkg._ DATE 3 d' N3 1 OTUS 12 3 Inreadshttts PROJtcT hiontirello Tosic Chemical Study PREL. &HEET OF CONTROL 1.D. NO. 1961 2,2-001 REv. 0 GHEET 6.C OF 69 . C HIET S j 3393 28200 1. 750! + 02 1. 750t + 02 1. M 0t + 02 1. 750t + 02 3394 2 E500 1. 50E + 02 1. 50t

• 02 1. 50t + 02 1.750t + 02 3395 26400 1. M 0t + 02 1. 750t
• 02 1.750t + 02 1. 750E + 02 3396 28500 1. 750t + 02 1. 750t + 02 1. 750E + 02 1. 750t + 02 3397 28600 1. 750t + 02 1. 750t + 02 1. 750t + 02 1. 750t + 02 l

3395 28700 1. 750t + 02 1. 750t + 02 1.750E + 02 1.750E + 02 3399 28800 1. 750t + 02 1. 750E

• 02 1. 750t + 02 1. 750t +02 i

3400 i

O_TENERA sucJtcT Verifiention of TOXPUFT and TO\\TVAP PREPARED BY I_ DATE 3/8/93 1,OTUS 12 3 Snreadsheett CHECKED BY I/O DATE M4[93, a i PROJE CT Mnnticello Tmic Chemical Study PREL. SHEET OF CONTROL i D. No. 1961 2.2 001 nty. O SHEET 66 or 60 sHtris APPLWDIX 4 10xEVAP f ornuta listing A Bis ' foale Chemical spill Calculation (for chemical bolting point greater than ambient tecperature) A:A2: (W10) Last Updated: A:A4: [W10) ' A:C4: (D1) GlWT(GNDW) Analyted Chemicals Ethyl Alcohol AD4 8 A:A6: [W10) ' as sesse s essn es e s.. ss ees sses.......................assesseme ses s a s s ess A A7 [W10) ' Design inputs: A:A9: [W10) ' Spill Dates A C10: ' Container Volme (VC, em"3): A F10 (53) 110500000 $ pill to CR Intake Distance (x0, m): A B11:

• A:Fils (F1) 3218 A:012: '

spilt type: Circular meteorotegical Dates A A15: [W10) PasqullL's Stability Category: A:816: 8 A F16: 8 G Ambient Tecperature (fac, degrees C): A 817: ' A F17 20 Wind Speed (V, m/sec): A:C18: ' A F18 1 AC19

• Air Pressure (PA, atm):

A F19 1 Air Pressure (Pa, m Mg): AC20: 8 A:F20: 0 AtA21: [W10) ' control Room Data: A B223 ' Control Room HVAC Intake Height (1, m): AIF22: 11.28 Control Room Voluwe (CRV, f t"3): A B23: ' A:F23: ($3) 27000 CR HVAC Intake Rate (CFIN, f t."3/ minute): A A24: (W10) A F24: 7440 A:A26: [V10) ' Chemicat Data: Chemical Density (DEN $, g/cm"3): A B27:

• AsF27: (F3) 0.789Boiling Point (fb, degrees C):

A:B28: ' A F28: 78.5 A:B29: 8 Molecular Weight (MW, g/ mote): A:F29: (F2) 46.07 Dif fusion Coef ficient (D, em"2/sec): A:A30: IW10)

• A F30: 0.1 Vapor Presssure (Ps, m Mg):

A:C31:

• A:F31: 40 A:A32: (V10) ' Constants:

ident cas constant (R, atm-m"3/ mote degree 1:): A:A33: (W10) ' A:F33: (53) 8.205E 05 A C34:

• Air Density (DAlR, g/cm"3, at 1 atmosphere and 20 degrees C):

A:B35: ' A:F35: (S2) 0.0012 A:E36:

• PI A:F36: GPl Cravitational Constant (C, em/sec"2):

A A37: IW10)

• AIF37: 981 Air Viscosity (VISC S Ta, g/cm sec):

A B38:

• A:F38: ($3) 0.0001834 A:A40: [W10) ' Calculated Design Inputs:

Initial Chemical Mass (MTsVC'0 ENS, g): A:B42: '

O_TENERA l Sur. JECT Verification of TO\\TitiT and TO\\TVAP PREPARED BY I DATE 3 /R/93 1stEi3 1.OT1'S 12 3 Soreadshnts CHECKED BY.866-DATE 0 PQOJECT Montirelin Tosie Chemical Study PRrL SHEET OF CONTROL i D. NO. 1961 2.2 001 REv. O SHrET 67 OF 69 SHEETS Att42: ($3) +F10*F27 A:A43: (W101

• Arcient Tem erature (fastac+273.16, degrees K):

A F43: + F 17+ 273.16 A:Bi43 'Chemiest Bolling Point (1b, degrees K): A F44: +F26*2T3.16 A A45: (W10) *schmidt water (se"(1/3), (VisC/D'DAIR)"(1/3)): A:F45: ($3) (F38/(F30'F35))*(1/3) A A46: (W10) 'esassssssssssssssssssssssssesneesssssssssssssssssssssssssssssssssssssa A A47: [W10) ' spill Area Calculations: inittet spill Radius (RO, cm) = (VC/PI)"(1/3) A:A49: (W10) ' A 050: ' s A:E50: ($3) (F10/F36)*(1/3) Initial spill Area ( AO, cm"2) = A A52: (W10) AE52: ' P l * ( R 0"2 ) AID 53: 8 s AE53: ($3) *F36'(E50*t$0) Area Change Rate (ACM, em"2/sec) = PI'2'(g*(VC)* A A55: (W10) = (DEhs DAIR)/(DENS *PI))"1/2 A A56: [W10)

• AD57:
• s A:E57: (53) +F36*2*((F37*F10*(F27 F35)/(F27'F36))*(1/2))

A A59: (W101

• Maximn spill Area (Amax, cm"2) s VC/1 cm A:060: '

s A:E60: ($3) '10 A:A62: (W10) Time When Aman Reached (irnax, sec) a (Aman AO)/ACM AD63: ' s A:E63: (F2) (E60 E53)/E57 A A64: [W10)

• ssees sassanuas ssss s sssss ssssasusassesasss==sesassessessessansasses A:A65: [W10) ' Calculation of ch/dt and f gone (turbulent flow)

A:C67: 8 dn/dt (g/sec)

• AE67: 'hd'A(t)*MW'(Ps Pa)/R*Ta A:C69: 8 bd (cm/sec) e A:E69: ' (0. 037* ( sc *'(1/3 )) *D'(P l"0.1 )

A:E70: (U+100*DAIR/vlsC)**0.81/ A:E71: ($3) * ((2"0.2)*( A(t)"0.1)) Combining these eqs. gives: A:A72: (W10) AC73 8 ch/dt (g/sec) s A:E73: 'K'( A( t )"(0.9)) A:C74: ' where A:075: *

=

A:E 75. (53) ((F36*0.1)*0.037'F45'F30*(((FIB *100*F35/F38)*0.8)/(2*0.2)))*F29'(F31 F20)/(F33*F43'1000000*760) A:A76: (W101 ' The following eq. is solved for igone when Tuone > Tmax: A:C78: ' MT a A:E78: 'K'(1/1.9)*(1/ACH)*((A0 + ACH* A E79: (53) 'imax)"(1.9) A0**(1.9)) + A:E80: 'K*( Aman"(0.9))'(f gone Tmax) A:C82: ' Toone (sec) s AE82: ($3) (F42 E75*(1/1.9)*(1/E57)*((E53+E57*E63)*(1.9) E53*(1.9)))/(E75*(E60*(0.9)))+E63 A:AB3: (W10) 'assanssenes=======ssasses==sssssses========ss==s===ssssssssssss======a A:A64: [W10) ' Calculation of sigmas (Dispersion coefficients) A: ABS: [W10) 'Pasq. Gif f. Y Disp Coef f tog ($1CY, m) = A:EB5: ' A+B* t og(x0)+C'( t og(x0))"2+ A AS6: [W10) A:ES6: 'D'( t og(x 0))"3 A C87: where A:DB7:

• Aa A:ES7: 1.6212 A:DBS:
• Bs A:ESS: 1.0648 A:DS9: '

C= A:E89: -0.014857

O_TENERA SUBJECT Verification of TOYP(TF and TOYEVAP PREPARED BY DATE 3/A/93 CHECKED BY M DATE

1. 1. 3 LOTUS 12 3 Snreadsheet, PREL. SHEET OF PROJECT Monticello Tosic Chernical Study CONTROL l.D. NO.

1961 2.2-001 REY. 0 SHEET M OF SHEET S A D90: 8 0= AE90: 0.0020555 A D91: * $10f = A:E91: ( F 3 ) 10* ( + E 87+ E 88* GL O;( F 11 ) + E 89'( DLO3 ( F 11 )'2 )+E 90* ( DL00 ( F 11 )

• 3 ))

A A93 (V10) ' Paso. Ciff. 2 Disp Coeff log ($1CZ, e) e A:E93: ' A+ B* t og(x0)+C'( t og(x0))"2+ A:A94: (W10)

• A:E94: 'D*( t og(x0))"3 A C95 '

where: A:D95: 8 A= A:E952 1.8981 A3096 8 g. AE96: 1.1243 AD97:

• Ce A:E978 0.036447 A098: '

Ds AE981 0.0086351 A:D99: 8 $1CZ s AE993 (F3) 10*(*E95+E96*GLOG(F11)+E97*(DLOG(F11)*2)+E98'(DLOC(F11)*3)) cont Release Disp Coef f ($1CZM, m) = A A101: [W10) ' A (101: '($1C2) A0102: s A:E102: (F3) (E99)Cont Release Disp Coeff ($10YM, m) s A: 1104: IV10) ' A:E104: '($1CY"2+(Ref f *Pl**(1/2)/4.3) A E105: '"2)"(1/2) A:D106: = A:E106: (F3) (E91*2*E60/184900)*(1/2) A:F106: (F3) '(at Amax) A:B107: 'hote:For Circular spill, Reff a ( A( t )/PI )"(1/2) A:B108: ' A A110: [W10) 8

========s::::ss======s*s===========ssessssssssssssss=====sssses==esas A:A111: [W10] ' Conversion of g/m"3 to ppm A A113 [W10) ' Conversion to PPM (PPM, ppm /(g/m**3)) e AE113: ' ( R

• T a* 1. 0E + 06)/ (Md* P a )

A0114: 8 s A:E114: (F2) (F33*F43*1000000)/(F19'F29) A:A115: Iv10) 'se s s enn es e s== s e na m e ssss e n s ass san===== ss === = = =nes sss =u s es= =ssse A:A116: (W10) ' Calculation of Continuous Release Cone Outside Control Room

1. [

A A118: [W10) ' Cont Cone a CR Intake (CRC (t), prn) = Y& 8 AE118: 'K'( A0+ ACH* t )* (- "dE AE119: 8 (1/(2*PI*U'$101M*$1CZM ))* (exp t A A120: IV10) ' where ash =0 for DVAP>DAIR, j/D A:E120: ' 1/2*(2 h)"2/$1CZM"2)+ expt tsh f or DVAP<D AIR, A:A121: [W10) ' A:E121: ' 1/2*(t+h)"2/$1C M"2])* PPM Ass 122: 'y=0, A0+A H*t=Amax for A:B123: 't>fmax, and tat x0/U AIA124: [W10) ' Note: CRC (t)s0 f or t<x0/U and for t> time when entire spill evaporates plus x0/U (imax+Tgone+x0/U) A:A125: [W10)

• DVAP (g/cm**3) s A:C127: '

A:E127: 'Md*PA/R*Ta A:D128: 8 s A:E128: ($3) (F29'F19)/(F33*F43*1000000) A:A129: (W10] 8 s s== = = = = = = === s r s s s a s s a s s = = = = = s s = = = = = = = = = = = = = = = = = = = = ===ss= = s s s ss s sis== 1 A:A130: [W10] ' Calculation of Concentration inside Control Room Concentration in the CR is conputed in a time step by step A:A131: [W10) manner by adding the the inside CR concentration A:A132: [V10) ' at the previous time step to the difference A A133: (W10) between the current outside concentration minus the previous A:A134: [W10)

• inside concentration times an esponential buitdup f actor.

A:A135: (W10) i ) l

STENERA sulVECT Vedfication of TOXPITF and TO\\TVAP PREPARED BY DATE 3/8/93 DATE 3 N3 LOTUS 124 Sorcadsheets CHECKED BY _/,/// PROJECT Monticello Tmle Chemical Study PREL. sHLET OF CONT 30L 1 D. No. 1961 2,2-001 REv. O SHEET 69 or 69 SHEETS A:A136: (W10) 'essessen e ssesseeessesse esse======sessessee ssessessenesse===*sessessen. A A.37: (W10) * *(t) f or Teorw+1maa+x0/u>t>1mam+x0/U A E137: ($3) (SIS 60'(0.9))*ltl114'SEl75';1/(2'tFS36'Sts102'St1106*tFS18))*(1+ctxP( 0.5'((505140+505140)*2)/(S s 102*2))) A:A138: (W10) 'X(t) Constant for imam *x0/Us t > XO/U (53) +Stt114'$tS75'(1/(2*1f $36'5El102'SFS18))*(i DrtP( 0.5'.((101140*t01140)*23/(St5102*2))) AE138: .seeen ......ases. A A139: IW101 'se es== = =.......e a s eeeee e ee e e e e ss esse.... se....... A A140: (W101 ' Analysis Resulta A C140: ' he A:D140: elf (E128sF35,0,F22) A8142: ' Outside Inside A:C142: A:0142: ' Outside A:E142: ' Inside A F142: 'Chemlcal Analyzed: AB143: ' CR Conc AC143: 8 CR Conc A0143: ' CR Cone AE143: 8 CR Conc Ethyt Alcohol A F143: ' A38144: ' Continuous A:C144: ' Continuous A D144: ' Continuous AE144: ' Cont inuous A:A145: (W10) ' fire (sec) AB145: (p;n) A:C145: (ppm) A:D145: 8 (ppm) AE145: (ptn) A A146: (W10) 'seesseseos 4 AtB146: ' essen A:C146g 8 ese== A:D146: '. se. AE146: ' sense A:A147: IW101 0 A 8147: ($3) CIF(D147<1E 98,0,D147) A:C147: ($3) GIF(Eld 7<1E 98,0,E147) A:D147: (53) 0 A:E147: ($3) 0 A:A148: (W10) +A147+1 A B148: (53) DIF(0148<1E 98,0,0148) A:C148: (53) SIF(Ell 8<1E 98,0,E148) A D148: (53) Cl F(( A1481f 511/SF S18)<0,0,QlF( A148>eSFS11/SFS18+tESS2*SE563,0,GIF( Ai48> SF$11/tF$1845ES63,$rS137, SES138'((SE$53*SES$7*( A148 1FS11/t FS18))*(0.9))*(1/((SES91*2+(SE553+$tt$7*( A148 SFS11/SFs ta))/1849 00)*(1/2)))))) AE148: ($3) *:147+($148 C147)'(1 EEXP( 1 SF$24'( A148. A147)/($f s23*60))) -}}