ML061320200

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E-mail from R. Lavera of Entergy to Various, Regarding Requested Sample Analysis Data
ML061320200
Person / Time
Site: Indian Point  Entergy icon.png
Issue date: 02/22/2006
From: Ronald Lavera
Entergy Nuclear Operations
To: Kottan J
NRC/FSME
References
FOIA/PA-2006-0140
Download: ML061320200 (99)
v • d • e


Text

James Kottan -Requested Sample Analysis Data Page1 From: "Lavera, Ron" <RLavera@entergy.com>

To: "'jjk @nrc.gov"' <jjk@ nrc.gov>, "Croulet, Donald" <dcroule@entergy.com>, "Mayer, Don"

<DMayerl @entergy.com>, "Axelson, William L" <WAxelso~entergy.com>, "Jones, T. R."

<tjones2 @ entergy.com>, "Wilson, Daniel" <DWilson ©entergy.com>, "Hinrichs, Gary"

<ghinric @entergy.com>, "Sandike, Steven" <SSandik @entergy.com>

Date: 2/22/06 12:42PM

Subject:

Requested Sample Analysis Data Mr. Kotton Please see the attached files which contain the following information:

  • MW-l1 10-14-05 o HTO IPEC 10-23-05 o GS IPEC-74419 o SR None Taken

iJames Kottan - Requested Sample Analysis Data Page 2:

0

<<L26839-1.pdf>> <<EntergyL27296.pdf>> <<EntergyL27310.pdf>>>

<<IPEC_74419_mw-111_10-14-05-GS.txt>> <IPEC-MW111-10-14-05-HTO.pdf>>

<<IPEC-MW111-HTO.pdf>> <<JAF-20053238.pdf>> <<JAF-20053238-B.pdf>>

<<JAF-20053238-GS.pdf>> <<JAF-MW38-MW 101-MW 105-MW 107-LW 1-LW3.pdf>>

<<JAF-Quarry-Gypsum-Algonquin-5th-GS.pdf>> <<JAF-Quarry-Gypsum-Algonquin-5th-HTO.pdf>>

Please let me know if you have any questions or comments.

Ron LaVera RLaVera entergy.com <mailto: RLaVera ©entergy.com>

914-736-8433 914-736-8419 FAX Indian Point 3 Entergy Nuclear Northeast Entergy Nuclear Operations, Inc.

Indian Point Energy Center 295 Broadway, Suite 3 P.O. Box 308 Buchanan, NY 10511-0308

Report of Analysis V1T O1 TELEDYNE BROWN ENGINEERING, INC.

10/27/05 15:19 A Tdadyn Tachoototlgs Company L26839 mw-w) 9q71,05 Entergy Nuclear Northeast Floyd Hood, Chem EN002-3P501P3-04 Sample ID: IP3-05-65 Collect Start: 09/29/2005 00:00 Matrix: Liquid Radwaste (LR)

Station: Collect Stop: Volume:

Description:

Receive Date: 10/17/2005  % Moisture:

LIMS Number: L26839-1 Activity Uncertainty Run Aliquot Aliquot Reference Count Count Count]

Radionuclide SOP# Conc 2 Sigma MDC Units t Volume Units Date Date Time Units Flag Values

_ _FE-55 20061 < i 3.11E07 uCi/mI 50 ml 09/29/05 00:00 110/26/05 10813  : U I Noi Tl 20081

-R-A < 1 1 4.68E-08 -uCi/ml I I 10 ml I 110/27/051 50 M U I GR-B !2008! < 1 8.79E-08 uCi/ml 10 I ml 1 10/27/051 50 1 M IU!

I NI-63 2013 _ _-

1.57E-07 i uCi/ml I 10 ml

--- I _--_ _ _ __

1I 10/261051 A_

100 M I U I I I SR-89 _

r21 J019 *_; ;  ;  ;

3.06E-08 I uCi/ml I 100 ml 09/29/05 00:00 I 10/261051 100 M I UI I I SR-90 019 1.50E-08 I uCi/ml I I 100 ml 09/29/05 00:00 I 10/26/051 15 M I UI I t-4 Flag Values t'3 U = Compound/Analyte not detected or less than 3 sigma No = Peak not identified in gamma spectrum a' OD

+ = Activity concentration exceeds MDC and 3 sigma; peak identified(gamma only) Yes - Peak identified in gamma specturm U. = Compound/Analytc not detected. Peak not identified, but forced activity concentration exceeds MDC and 3 sigma **** Results are reported on an as received basis to High = Activity concentration exceeds customer reporting value unless otherwise noted W Spec = MDC exceeds customer technical specification '-,

L = Low recovery Page 1 of MDC - Minimum Detectable Concentration H High recovery Bolded text indicates reportable value. 0 1-h

4VA& TELEDYNE BROWN ENGINEERING, INC.

ATeledyneTechnologies Company 2508 Quality Lane Knoxville, TN 37931-3133 Floyd Hood, Chem Entergy Nuclear Northeast Indian Point Energy Center 295 Broadway - Suite 3, P.O. Box 308 Buchanan NY 10511-0308 Report of Analysis/Certificate of Conformance 12/30/2005 LIMS #: L27296 Project ID#: EN002-3P50IP3-04 Received: 12/09/2005 Delivery Date: 12/23/2005 P.O.#: 4500539361 Release #:

SDG #:

This is to certify that Teledyne Brown Engineering - Environmental Services located at 2508 Quality Lane, Knoxville, Tennessee, 37931, has analyzed, tested and documented samples as specified in the applicable purchase order.

This also certifies that requirements of applicable codes, standards and specifications have been fully met and that any quality assurance documentation which verified conformance to the purchase order is on file and may be examined upon request.

I her that the above statements are true and correct.

Keith Jeter Operations Manager Cross Reference Table Client ID Laboratory ID Station ID(if applicable)

IP3-05-80 L27296-1 GYPSUM PLNT IP3-05-81 L27296-2 ALGONQUIN CREEK 1P3-05-82 L27296-3 TRAP ROCK QUARRY IP3-05-83 L27296-4 5TH ST WELL IP3-05-84 L27296-5 LEFARGE #I IP3-05-85 l L27296-6 LEFARGE #3

Report of Analysis Alor J, TELEDYNE 12/30/05 08:5 1 BROWN ENGINEERING, INC.

ATeledyne Techn*lgiS COMPanY L27296 Entergy Nuclear Northeast Floyd Hood, Chem EN002-3P501P3-04 Sample ID: IP3-05-80 Collect Start: 11/30/2005 15:20 Matrix: Secondary Coolant (SC)

Station: GYPSUM PLNT Collect Stop: Volume:

Description:

Receive Date: 12/09/2005  % Moisture:

LIMS Number: L27296-1 S IRun Radionuclide SOP JActivity, Conc Uncertainty 2 Sigma MDC Units #

Aliquot Volume Aliquot Units Reference Date Count Date Count Time Count Units Flag Values SR-90 [ 2019 1 < I 1 1.52E-08 I uCi/ml [ 100 ml 111/30/05 15:20 1 12/28/051 15 lM U I 1I l Sample ID: 1P3-05-81 Collect Start: 11/30/2005 15:30 Matrix: Secondary Coolant (SC)

Station: ALGONQUIN CREEK Collect Stop: Volume:

Description:

Receive Date: 12/09/2005  % Moisture:

LIMS Number: L27296-2 I Activity Uncertainty Run Aliquot Aliquot Reference Count Count Count Radionuclide SOP# Conc 2 Sigma MDC Units # Volume Units Date l Date Time Units Flag Values SR-90 1 2019 1 < I 2.07E-08 i uCi/mi 1 100 I1130/0515:30 1 1229./05! 15 [M  !  !

Sample ID: IP3-05-82 Collect Start: 11/30/2005 15:50 Matrix: Secondary Coolant (SC)

Station: TRAP ROCK QUARRY Collect Stop: Volume:

Description:

Receive Date: 12/09/2005  % Moisture:

LIMS Number: L27296-3 1 Activity Uncertainty l Run Aliquot Aliquot Reference l Count 1 Count l Count Radionuclide SOP# Cone 2 Sigma MDC Units # Volume Units Date Date ] Time Units l Flag Values SR-90 2019  ! < I 2.07E-08 uCi/mI 1 100 1 ml 11/30/05 15:50 1 12/28/051 15 I M i U _I_! _I Sample ID: 1P3-05-83 Collect Start: 11/30/2005 16:05 Matrix: Secondary Coolant (SC) l Station: 5TH ST WELL Collect Stop: Volume:

Description:

Receive Date: 12/09/2005  % Moisture:

LIMS Number: L27296-4 Activi Uncertainty 1 Radionuclide SOP# ACont U 2 Signta MDC Units Run

  1. [ Aliquot l Aliquot Volume l Units Reference Date Count Date l Time Count

[ Count Units Flag Values SR-90 1 2019  ! < 1 1.26E-08 1 uCi/ml  ! 100 1 ml 11/30/0516:05 1 12/28/051 15 FM  ! U II Flag Values U = Compound/Analyte not detected or less than 3 sigma No = Peak not identified in gamma spectrum

+ = Activity concentration exceeds MDC and 3 sigma; peak identified(gamma only) Yes = Peak identified in gamma spectrum Us = Compound/Analyte not detected. Peak not identified, but forced activity concentration exceeds MDC and 3 sigma ***4 Results are reported on an as received basis High = Activity concentration exceeds customer reporting value unless otherwise noted Spec = MDC exceeds customer technical specification L = Low recovery Page I of 2 MDC - Minimum Detectable Concentration H = High recovery Bolded text indicates reportable value.

Report of Analysis ARMTELEDYNE BROWN ENGINEERING, INC.

12/30/05 08:51 ATeledyneTechnologies Company L27296 Entergy Nuclear Northeast Floyd Hood, Chem EN002-3P50IP3-04 Sample ID: 1P3-05-84 Collect Start: 12/06/2005 11:10 Matrix: Secondary Coolant (SC)

Station: LEFARGE #I Collect Stop: Volume:

Description:

Receive Date: 12/09/2005  % Moisture:

LIMS Number: L27296-5 Activity Uncertainty 1nt I RunI AliquotI Aliquot Reference Count{ Count1 Count Raincie~SOP# Cone 2 Sim MDC Unts # Volume IUnits j Date IDate ITime jUnits Flag Values SR-90 1'2019 F < 1 L4-8E-08 7____1 F uCi/rni I I' 100 I mil I12/06/05 11:10 F12/28/051 15 1 M7 -7 Sample ID: IP3-05-85 Collect Start: 12/06/2005 09:55 Matrix: Secondary Coolant (SC)

Station: LEFARGE #3 Collect Stop: Volume:

Description:

Receive Date: 12/09/2005  % Moisture:

LIMS Number: L27296-6 Sop Activity Uncertainty Run Aliquot Aliquot Reference Count I Count Count Radionuclide SO#j Conc j2 Sigma ] MDC Units [Volume I Units Date IDate Time jUnits t Flag Values S902019 1 < 1I_____ 1.36F,08 uCi/mI F 100 F1 ml-7 12/06/105 09:55 1 12/28/051 15 M U Flag Values U = Compound/Analyte not detected or less than 3 sigma No = Peak not identified in gamma spectrum

+ = Activity concentration exceeds MDC and 3 sigma; peak identified(gammia only) Yes = Peak identified in gamma spectrum U*= Compound/Analyte not detected. Peak not identified, but forced activity concentration exceeds MDC and 3 sigma *** Results are reported on an as received basis High = Activity concentration exceeds customer reporting value unless otherwise noted Spec = MDC exceeds customer technical specification L = Low recoveryi Page 2 of 2 MDC - Minimum Detectable Concentration H = High recovery Bolded text indicates reportable value.

12/09/05 13:28 Teledyne-Brown Engineering Sample Receipt Verification/Variance Report SR #: SR06132 Client: Entergy Nuclear Operations, Project #: ENO02-3P50IP3-04 LIMS #:L27296 Initiated By: PMARSHALL Init Date: 12/09/05 Receive Date: 12/09/05 Notification of Variance Person Notified: Flog I Contacted By:

Notify Date:

Notify Method:

Notify Comment:

Client Response Person Responding:

Response Date:

Response Method:

Response Comment Criteria Yes No NA Comment 1 Shipping container custody seals present NA and intact.

2 Sample container custody seals present NA and intact.

3 Sample containers received in good Y condition 4 Chain of custody received with samples Y 5 All samples listed on chain of custody Y received 6 Sample container labels present and Y legible.

7 Information on container labels N correspond with chain of custody IP3-05-080 Collection time on bottle is 15:20 IP3-05-081 Collection time on bottle is 15:30 IP3-05-082 Collection time on bottle is 15:50 IP3-05-083 Collection time on bottle is 16:05 8 Sample(s) properly preserved and in NA appropriate container(s) 9 Other (Describe) NA I

Teledyne Browne Engineering Environmental Services > I q Page I ofI from: Customer Sample Receipt Form Entergy - Nuclear Northeast Indian Point 3

/-coffectlon period =\

start stop volume amP MM-DDYY HHHH MM-DD.YY HHHH or area units typeI Notes iIP z2--I' Q05 i os<M~O 500 CC SC r- ___ __

e m o 5I~L I~hL ~ _ ' ~O ~ oO Cc ~___

1P3 QS60/1 (.-. LOX) _

IP3 1P3 1P3 1Pa 1P3:O5-IP3 1P3 IP3 P3 -

IP3 P305 -

Shipped 4 Received  ?/?C,

/,7-/7 10.r Distibuted

AL' TELEDYNE 01 BROWN ENGINEERING, INC.

ATeledyneTechnologies Company 2508 Quality Lane Knoxville, TN 37931-3133 Floyd Hood, Chem DEC 3; Entergy Nuclear Northeast b o JO5 Indian Point Energy Center 295 Broadway - Suite 3, P.O. Box 308 Buchanan NY 10511-0308 Report of Analysis/Certificate of Conformance 12/29/2005 LIMS #: L27310 Project ID#: EN002-3P50IP3-04 Received: 12/13/2005 Delivery Date: 12/27/2005 P.O. #: 4500539361 Release #:

SDG #:

This is to certify that Teledyne Brown Engineering - Environmental Services located at 2508 Quality Lane, Knoxville, Tennessee, 37931, has analyzed, tested and documented samples as specified in the applicable purchase order.

This also certifies that requirements of applicable codes, standards and specifications have been fully met and that any quality assurance documentation which verified conformance to the purchase order is on file and may be examined upon request.

I hereby certify that the above statements are true and correct.

GIA-Keith Jeter o

Operations Manager CrossRe erence Table

__ _ent____ Laboratory ID Station ID(if applicablej) I

]1P3-05-86 l L27310-1 MW-38 1P3-05-87 I L27310-2 i MW-107 IP3-05-88 _____ L27310-3 MW-105 IP3-05-89 L27310-4 - MW-101 .

ReXport of Analysis ON APr~kTELEDYNE

'¶ BROWN ENGINEERING, INC.

12/29/05 13:12 ATeledyne Technologies Company L27310 Entergy Nuclear Northeast Floyd Hood, Chem EN002-3P501P3-04

[ Sampic ID: IP3-05-86 Colict Start: 1210812005 10:30 Matrix: Secondary Coolant (SC)

Station: MW-38 Collect Stop: Volume:

Description:

Receive Date: 12/13/2005  % Moisture:

LI MS Number: L273 10-1 Activity Uncertainty Run Aliquot Aliquot Reference Count Coun Count I aincieISO~ Cone 2 Sigma MCUis volume Units Date Date Time Units R-90 <- l.S-8 uCi/nl too m 12108105 10:30 12/28/5 1 - lgVle Sample ID): 11P3-05-87 Collect Start: 12/08/2005 11:15 Matrix: Secondary Coolant (SC)

Station: MW-107 Collect Stop: Volume:

Description:

Receive Date: 12/13/2005  % Moisture:

IMS Number: 1L273 10-2 Rdouid o# Activity Uncertainty MDUnt Run Aliquot Aliquot Reference Count Count Count SR-90 - 09 < .i33E-i u imi 10Mc 20801l5 1 220 . 5.i .

Sample ID: IP3-05-88 Collect Start: 12/08/2005 12:20 Matrix: Secondary Coolant (SC)

Station: MW-105 Collect Stop: Volume:

Description:

Receive Date: 12/13/2005  % Moisture:

LIMS Number: L273 10-3 Activity Uncertaint IRn Aliquot Alqoieeec on ont Count RaineieSP oc zSigma MC -Uis Volume Units Date Date Time Units Flag Values

~09 I 19E-08 I 9 u / lI 001 ml [1/80 22 1 8/05 15 i M U F Sample ID: 1P3-05-89 Collect Start: 12/08/2005 12:50 Matrix: Secondary Coolant (SC)

Station: mW-l01 Collect Stop: Volume:

Description:

Receive Date: 12/13/2005  % Moisture:

LIMS Number: L273 10-4 Activity IUncertainty Run Aliquot Aliquot Reference Count Count [Count 11Radi( )nuclide IsoP# Conc 2 Sigma MDC I Units # Volume Units Date Dt Tie Uis Flag Values iR-90-. I..,- -... -- __ _ _ _- - - -- . ............. - - - _ __ _ _

2019 < __1.25E-08 uCi/mI 100 ml 12/08/05 12:50 12/28/051 15 Mli I-.-

Flag Values U Compound/Analye not detected or less than 3 sigma No = Peak not identified in gamma spectrum

+U -

Activity concenramtion exceeds MIX and 3 sigma; peak identifled(gamrna only) Yes = Peak identified in gamma spectrum Compound/Analyte not detected. Peak not identiried, but forced activity concentration exceeds MDC and 3sigma *** Results are reported on an as received basis High = Activity concentration exceeds customer reporting value unless otherwise noted Spec = MDC exceeds customer technical specification L - Low recovery Page 1 of I MDC - Minimum Detectable Concentration H - High recovery Bolded text indicates reportable value.

12/13/05 14:20 Teledyne Brown Engineering Sample Receipt Verification/Variance Report SR #: SR06156 Client: Entergy Nuclear Operations, Project #: EN002-3P50IP3-04 LIMS #:L27310 Initiated By: PMARSHALL Init Date: 12/13/05 Receive Date: 12/13/05 Notification of Variance Person Notified: Contacted By:

Notify Date:

Notify Method:

Notify Comment:

Client Response Person Responding:

Response Date:

Response Method:

Response Comment Criteria Yes No NA Comment 1 Shipping container custody seals present NA and intact.

2 Sample container custody seals present NA and intact.

3 Sample containers received in good Y condition 4 Chain of custody received with sampLes Y 5 All samples listed on chain of custody Y received 6 Sample container labels present and Y legible.

7 Information on container labels Y correspond with chain of custody 8 Sample(s) properly preserved and in NA appropriate containers 9 Other (Describe) NA

J' I0 Teledyne Browne Engineering Environmental Services L,) - Page 1 of 1 from: Customer Sample Receipt Form Entergy - Nuclear Northeast Indian Point 3

/----collection oeriod--\---

r 1 - F= F 9 I F start stop volume smp MM.DD-YY HHHH MM-OO-YY HHHH or area units type Notes IP3 86 MW-38 12/8/2005 1030 5.00E+02 CC SC Sr90 only expicite l P305 87 MW-107 121812005 1115 5.OOE+02 C SC Sr 90 Only expidite IP3 88 MW-1 05 12/8/2005 1220 j_5.00E+02 CC SC 1 Sr only expidite IP3 89  : MWV-101 12/8/2005 1250 5.00E+02 CC SC Sr90 only .xptdete IP3 - 05 -

IP3 I-'X-PL3E'-05-'"' , i' ~~~~~~~~~. ..:'"..

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IP3 IP3 ,..- ......... . ..

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- 05 - iP3 11 1 . .... I - . . . I .11 IP3 - 05 -

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I ............... II 1 11 P 3- 5 1P3 - 05 -

1P3 - 05 -

j l ,; \ X,, ,,,,~. ,...... , . ........-:

1P3 - 05 -

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Distributed_ __

IPEC-74419.mw-111-10-14-05-GS.txt

  • CHEMISTRY GAMMA SPECTROSCOPY REPORT 22-FEB-2006 08:00:02.20 *
  • RE-ANALYZED RE-ANALYZED RE-ANALYZED RE-ANALYZED
  • MW-111 10/14/5 Sample ID  : 74419
  • Sample Quant  : 5.OOOOOE+02 ml Sample Type : Poly Bottle
  • Efficiency  : sgs4O Pl Live Time: 0 01:00:00.00
  • Geometry  : on detector Live Time  : 0 01:00:00.00
  • Real Time  : 0 01:00:05.60 Sample Time : 14-OCT-2005 12:00:00
  • Acquire Time  : 18-OCT-2005 12:15:40 Decay Time : 4 00:15:40.42 *  % Dead Time  : 0.2%

offset  : 3.81508E-01

  • FWHM offset  : 7.25239E-01 Slope  : 4.99804E-01
  • FWHM slope  : 3.17892E-02 Quad Coef  : 6.28117E-08
  • Pk Start ch  : 50 calib Date  : 28-JUN-2005 02:12:29
  • Pk End ch  : 4050 Peak Search Sensitivity : 5;0000
  • Nuclide Library : MASTER Gaussian Sensitivity 10.00000
  • NO. of iterations : 10 Detector Name : adc4O
  • Eff Type  : SPLIN T 1/2 Ratio : 8.00000
  • Energy Tolerance : 1.25000 Library Based Eff : No
  • DO Key Line Analysis : Yes Abund Limit : 70.00000
  • Analysts name : JFJ Pk It Energy Area Bkgnd FWHM channel Left Pw Cts/Sec %Err Fit 1 0 92.74 50 57 1.02 184.78 180 11 1.40E-02 31.9 2 0 510.78 49 24 0.91 1021.06 1015 12 1.36E-02 24.6 Nuclide Line Activity Report Flag: "'" = Keyline unidentified Energy Lines It Energy Area Bkgnd FWHM channel Left Pw Cts/Sec %Err %Eff Flags 0 92.74 50 57 1.02 184.78 180 11 1.40E-02 31.9 1.18E+00 T

.0 510.78 49 24 0.91 1021.06 1015 12 1.36E-02 24.6 7.57E-01 Flags: "T" = Tentatively associated Rejected Report Half-Life Activity 1-Sigma Nuclide Half-life Ratio Energy %Abund (uCi/ml) %Error Rejected by GA-67 78.26H 1.24 93.31 38.30 3.953E-07 31.88 Abun.

184.60 20.90 --- Not Found ---

300.20* 16.80 --- Not Found ---

393.50 4.70 --- Not Found ---

% Abundances Found = 47.46 (Abn. Limit = 74.00%)

Page 1

IPEC-74419-mw-111-10-14-05-GS.txt Flag: "*" = Keyline Summary of Nuclide Activity Total number of lines in spectrum 2 Number of unidentified lines 1 Number of lines tentatively identifieedI by NID 1 50. 00%

        • There are no nuclides meeting sumniary criteria ****

Flags: "K" = Keyline not found "M" = Manually accepted E = Manually edited "A" = Nuclide specific abn. limit Minimum Detectable Activity Report Bckgnd Energy MDA Nuclide sum (kev) (uci/ml)

BE-7 15. 477.60 4.0218E-07 NA-24 5. 1368.53 4.6677E-06 K-40 20. 1460.85 9.3873E-07 AR-41 0. 1293.64 Half-Life too short SC-46 11. 889.20 5.8026E-08 CR-51 20. 320.08 3.8598E-07 MN-54 4. 834.83 3.5299E-08 MN-56 0. 1810.72 Half-Life too short CO-57 33. 122.06 3.5005E-08 Co-58 12. 810.75 5.5455E-08 FE-59 4. 1099.22 7.9165E-08 CQ-60 3. 1173.21 3.8156E-08 CU-64 11. 1345.90 2.9276E-03 NI-65 0. 1482.00 Half-Life too short ZN-65 7. 1115.52 1.0731E-07 GA-67 18. 300.20 4.4490E-07 AS-76 15. 559.10 1.2517E-06 BR-84 0. 1213.30 Half-Life too short KR-85 22. 513.99 1.1327E-05 KR-85M 0. 151.18 Half-Life too short SR-85 22. 513.99 5.1852E-08 KR-87 0. 402.58 Half-Life too short KR-88 0. 196.32 Half-Life too short RB-88 0. 898.03 Half-Life too short Y-88 3. 1836.04 5.3201E-08 RB-89 0. 1031.88 Half-Life too short SR-91 0. 1024.30 Half-Life too short Y-91 3. 1204.90 1.4282E-05 Y-91M 0. 555.63 Half-Life too short SR-92 0. 430.56 Half-Life too short Y-92 0. 934.50 Half-Life too short NB-94 10. 871.10 5.1575E-08 NB-95 8. 765.80 4.5189E-08 ZR-95 10. 756.70 8.9125E-08 NB-97 0. 1268.63 Half-Life too short ZR-97 21. 507.60 4.9477E-05 MO-99 16. 739.48 1.2458E-06 TC-99M 0. 140.51 Half-Life too short RU-103 10. 497.08 4.2514E-08 RH-105 21. 318.90 1.2288E-06 RU-105 0. 469.40 Half-Life too short RU-106 6. 1050.10 3.2870E-06 CD-109 41. 88.03 1.2460E-06 AG-110M 7. 657.70 3.8311E-08 SN-113 25. 391.70 6.8773E-08 Page 2

IPEC-74419-mw-111-10-14-05-GS.tXt SB-122 10. 692.60 3.2231E-06 TE-123M 38. 159.00 3.8005E-08 SB-124 2. 1691.02 9.5853E-08 SB-125 20. 427.90 1.3956E-07 SB-126 7. 666.30 4.5087E-08 XE-127 21. 374.96 2.4218E-07 TE-129 0. 1083.85 Half-Life too short 0

Minimum Detectable Activity Report (continued) Page 2 sample ID 74419 Acquisition date : 18-OCT-2005 12:15:40 Bckgnd Energy MDA Nuclide Sum (kev) (uci/ml)

BA-131 11. 496.30 1.0127E-07 i-131 18. 364.48 6.2441E-08 XE-131M 37. 163.93 2.0333E-06 I-132 0. 667.69 Half-Life too short TE-132 24. 228.16 8.1962E-08 BA-133 24. 356.00 6.3596E-08 I-133 11. 529.89 1.0746E-06 XE-133 24. 81.00 1.8526E-07 XE-133M 39. 233.18 1.3931E-06 CS-134 6. 795.84 4.4656E-08 I-134 0. 884.00 Half-Life too short TE-134 30. 210.47 3.3724E-07 I-135 0. 1260.41 Half-Life too short XE-135 0. 249.79 Half-Life too short XE-135M 0. 526.57 Half-Life too short CS-136 8. 1048.07 8.3116E-08 CS-137 13. 661.64 5.4431E-08 CS-138 0. 1435.86 Half-Life too short XE-138 0. 258.31 Half-Life too short CE-139 45. 165.85 4.3469E-08 BA-140 8. 537.30 1.6420E-07 LA-140 4. 1596.00 3.0089E-07 CE-141 33. 145.44 6.5066E-08 LA-142 0. 641.17 Half-Life too short CE-144 35. 133.50 2.7862E-07 PR-144 0. 1489.15 Half-Life too short ND-147 54. 91.11 2.2211E-07 EU-148 24. 611.30 3.1473E-07 PM-148 11. 1465.00 5.8695E-07 PM-148M 8. 1014.00 2.7495E-07 EU-152 12. 344.30 1.0753E-07 EU-154 6. 1004.70 2.5520E-07 EU-155 33. 105.30 1.5922E-07 EU-156 2. 1277.00 1.3700E-06 HF-181 8. 482.20 3.8395E-08 RE-182B 3. 1221.00 6.2836E-07 TA-182 7. 1189.00 3.4091E-07 w-187 10. 479.50 2.3446E-06 HG-203 29. 279.19 4.9183E-08 TL-208 0. 583.10 Half-Life too short RA-226 31. 609.30 1.3887E-07 TH-228 13. 583.15 1.3946E-07 TH-232 43. 238.63 9.2423E-08 PU-233 0. 534.80 Half-Life too short U-235 36. 143.80 2.8363E-07 AM-238 0. 918.70 Half-Life too short NP-239 31. 106.13 4.5521E-07 AM-241 32. 59.54 3.4399E-07 Page 3

IPEc-74419-mw-111O-10-4-05-GS.txt VMS Nuclide Identification Report V2.9 Generated 22-FEB-2006 08:00:05 EBAR configuration 1  : DKA100:[CHEMTECH.TRASH]RECALL3.CNF;2 Average Energy Report Activity 1-sigma Ave. Beta Ave. Gamma NUClide Hlife (uci/ml) %Error Energy Energy Total Activity O.OOOE+00 (uCi/ml)

Average Gamma Energy O.OOOE+00 MeV/dis Average Beta Energy O.OOOE+00 MeV/dis Total Average Energy O.OOOE+00 MeV/dis specific Activity Limit O.OOOE+00 (uci/ml)

Page 4

f-.

Weei. 1 2ZA Tritiunt .AReduction Data Processed: 10, i 7:17 AM

_______ SAMPLE INFOP1mAT1Q~ -A -- .

S\N Volume UnR # l ,Sample!D: . GPM-m .Notes 1 2.50 3 Blank . 6.96E+00 2 2.50 3 Calibration Standard 4.51 E-02 e 1.24E+05 3 2.50 3 Control Standard 2.66E-03 7.31 E+03 4 2.50 IPEC MW-l1 10/14/05 6.82E-06 11.87E+01 5 2.50 3 RAMS vent end 10/18/05 3.35E-06 9.21 E+00 6 2.50 3 VC #1 10/19/05 140 mis 1.26E-02 . 3.45E+04 7 2.50 3 VC #2 :10/19/05 186 mis 8.46E-04 2.32E+03 8 2.50 3 VC#3 10/19/05 111 mis 7.67E-05 / 2.11 E+02 9 2.50 3 Strorm Drain A-4 110/19/05 <MDA _ 7.50E-01 10 2.50 3 Strorm Drain B-8 10/19/05 8.41 E-07 2.31 E+00 11 2.50 IPEC MW- l1 10/21/05 0940 2.84E-04 ' 7.79E+02 12 0.50 2 WDST ME Sept'05 7.37E02 4.05E+04 13 2.50 3 blank <MDA  ; Q.OOE+00 14 2.50 3 Calibration Standard 4.51 E-02 1.24E+05 15 2.50 3 Control Standard 2.66E-03 7.30E+03 16 2.50 2 SFDS M/E Sept 'OS 9.54E-07 2.62E+_Oo 17 2.50 2 NCD M/E Sept'05 1.29E-05 3.53E+01 18 2.50 2 2 RWST 10/14/05 2.01 E-01 5.51 E+05 19 2.50 2 2 S/G M/E Sept'05 2.88E-06 . 7.910E+00 20 2.50 IPEC MW-111 10/07/05 1030 1.88E-04 ' 5.16E+02 21 2.50 2 NCD influent 10/07/05 2.25E-05 . 6.19E+01 22 0.50 2 2 RCS 10/09/05 1.42E+00 7.82E+05 23 2.5 2 2 SFP 10/10/05 2.71 E-02 M 7.43E+04 24 2.50 2 MW-111 10/14 6.32E-06 / 1.74E+01 CALIBRATION SOURCE DATA-S/N 66838-40 Crit Level = 1.76E+00 cpm Date of Source: 09/17/03 5.07E-02 uC/ml Efficiency= 49,4p/ cP /

Date & Time Samle Counted: 10/23/05 7:17 4.51 E02 uCi/mi Backcround- 6.96 cpm (NOTE: Background is automatically subtracted from sample counts)

Performed By:

Control Chart Updated: (initial)

Reviewed By: - SCINTILATOR USED:

1,0-- I5 I _ ' Tricarb 2900 l LSI

We, Wee .Tritiur. rP e""

a Reduction Data Procepted; 10.  ! 10:34 AM SAMINE9ATION, S\N Ilvotumqe :UR~TJ!. -,;` ~mple ly, LV-DA A DAY .

uUUM 11 1 2.50 3 Blan  : Ni)ti 2 2.50 7.08E+00 3 Calibration Standard 4.52E-02 3 2.50 7 1.27E+05 3 Control Standard 2.65E-03 4 2.50 7.48E+03 3 S/G Composite I15/5 00:05 550 dep F 8.01E-7 5 I 2.26E+00 2.50 2 MW-1 1t 9i2gl5 ttoray filtered 2.07E-04  : 5.84E+02 6 2.50 2 MW-1 I 9/29/5 unfiltered 2.05E-04 S 5.79E+02 Pat edw aLmpre t!u .52Em 0 u t'iltm gALIBRATION SOURCE DATA S/N 6683840-Crit Level 1.76E+00 cpm Dat: of Source: :09/17/03 5.07E-02 uCmlmj Efficiency-- 50.81% rm 10/6/05 ION3 ulmackground= B.2-2 7.08 c m A (NOTE: Background is automatically Performed By: subtracted from sample counts)

-. =-

Control Chart U pdated:> (initial)

Reviewed By:y 9q e SCINTILATQEJS I. I Beckman lTricarb 2900_)

ATTACHMENT 7.12 PAGE1 OF1 INDIAN POINT SPECIALS ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM WEEK # 39 CLIENT CODE 04 SAMPLE CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA DATEMPIME VOLUME ANALYSIS SAMPLE STATION TYPE CODE (UNITS) TYPE ID NUMBER NUMBER FROM TO H-3, GB 1P05-584 M/W 107 RR WA 9/2815 GSA 3 5-tl GAL IP 05-581 M/W 108 RR SL 912915 1 GAL GSAH-3 GB BUCHANAN SEWAGE IP 98 TREATMENT PLANT RR SL GAL GSA (Holdup Tank 2)

_1 H-3 IP 99 ALGONQUIN OUTFALL RR WA GAL GSA H-3 IP 100 GYPSUM PLANT RR WA GAL GSA STREAM H-3 IP 102 TRAP ROCK QUARRY RR WA GAL GSA 1P 05-582 Mm 109 RR WA 9/2915 1 GAL H-3 GSA GB IP 05-583 m/W 111 RR WA 9/29/5 1GAL HG3GSAGB REMARKS: INDIAN POINT SPECIALS - MONTHLY RR = Regular Routine

INDIAN POINT

SUMMARY

SHEET SAMPLE TYPE: Special Waters REPORTING UNITS IN: oCIIL Oct.05

... . . . . . ...... .... = W

: . 5... ..............

. ,....I...

Be-7 <31.17 <25.79 <31.1 <28.32 K-40 87.79+/-31.37 <29.8 187.6+/-39.82 249+/-52.56 Mn-54 <3.76 <3.09 <2.99 <4.56 Co-58 <3.76 <3.98 <3.38 <4.96 Fe-59 <8.42 <9.66 <7.65 <10.66 CO (7*5*) <4.51 <3.21 <3.19 <1.81 Zn-CS <5.44 <3.86 <10.97 <6.39 Zr-95 <6.08 <4.34 <4.57 <5.65 Nb-95 <3.01 <3.38 <3.65 <6.34 Ru-103 <3.58 <3.62 <3.64 <4.05 Ru-106 _ <34.64 <27.24 <44.24 <49.16 1-131 <5.43 <3.92 <4.14 <6.15 Cs-134 (7.5*) <2.45 <2.09 <2.03 <4.17 Cs-137 (9.0*) <3.86 <3.24 <3.74 <4.48 BalLa-140 <5.01 <3.84 <3.84 <5.8 Co-141 <7.24 <5.97 <5.03 <7.32 Ce-144 <29.70 <22.60 <26.60 <28.10 Ra-226 <97.94 <79.22 <76.69 <103.6 Ac-228 <10.78 <9.86 <12.96 <13.8 GROSS BETA, 15.7 +/- 0.9 18.8 +/-1.4 9.8 +/-0.7 12.5 +/-0.8 H-3 <420 <420 <420 211569 +/- 753 Results reported as < are CL values

  • Posted CLs correspond to LLD's listed In TS-5.104 (Rev.5)

CL Values Verified NOTE: The summary data sheet results have been provided to you to facilitate the review of analytical results. These summary sheets have not been Independently verified and should not be used for the final reporting of data without a second verification.

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-107 1ELMS #: 20053235 Sample On Date I Time: 09128/05 a 12:00 Client ID No. IP 05-584 Sample Off Date / Time: 09128105 a 12:00 Run No. 05-64 Sample Count Date: 10104105 a 12:00 Sample Distilled: I YES Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 CrItical Level (CL) CPM Sample Gross counts: 1260 Sample Count Time (minutes) 120 Sample CPM: 10.50 Sample Net CPM: 1.00 Sample DPM: 2.74 Background Counting Efficiency 0.357> I CL Ratio= 1.53 1 LLfn valuea (nr.iI1 I <A420 ZI ISample Counting Efficlency 0.358 309 I Comments: , j d B e <4' ,L1.

Note: If CL ratio Is <i. 0Act/Error Ratioy <2 th theLLDvalue is reported as a "Less Than" Activity.

Technician: (CR DIate:

~plrintg Supervisor review: B. Gorman n Date: id cs/o S print / sign p:\tritium program\tritium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-108 IELMS #: 20053236 Sample On Date I Time: 09129105 a 12:00 Client ID No. IP 05-581 Sample Off Date / Time: 09129/05 a 12:00 Run No. 05-64 Sample Count Date: 10104105 a 12:00 _Sample Distilled: I YES Elapsed Time (count date to off date) yrs 0.01 Deca Factor: 0.9992 Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Critical Level CL) CPM 0.65 Sample Gross counts: 1274 Sample Count Time (minutes) 120 Sample CPM: 10.62 Sample Net CPM: 1.12 Sample DPM: 2.95 le valume(L) 0.004 Bakrud Counting Efficiency / \/CL Ratio= 1.71 LLau (pCi/L) ( <420 ActlError Ratio= 2.6 Sample Counting Efficiency 0.359 Sample Activity (pC +/-L)1 sigma 332 +/- 128 Comments: r9~LcS 4zc

<'5e~, y(e~ (,X Note: If CL ratio Is <.0R ActlError Ratiq Is <2. tha the LLD value Is reported as a "Less Than" Activi Technician: llL. /0 Date:F/9J O Supervisor review: B. Gorman _ _ _Date:_______

print / sign A p:autium programunitium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID 1 MW-109 ELMS #: 20053237 Sample On Date I Time: 09129/05 a 12:00 Client ID No. IP 05-582 Sample Off Date I Time: 09129/05 a 12:00 Run No. 05-64 Sample Count Date: 10104/05 a 12:00 Sam le Distilled: YES Deca Factor: 0.9992 Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Critical Level (CL CPM 0.65 Sample Gross counts: 1205.6 Sample Count Time (minutes) 120 Sample CPM: 10.05 Sample Net CPM: 0.55 Sample DPM: 1.37 sample volume (L 0.004 Background Counting Efficiency 0.357 CL Ratlo= 0.84 U U <420 ActError Ratio= 1.2 Sample Counting Efficiency 0.359 sa~eActivity (pCilL) +/- 1 sigma 154 i 127 Note: If CL ratio Is <1.04inct/Error Ratio I <2.7 t an th LLD value Is reported as a "Less Than" Activity.

Technician: t 'IA' Date: /0/5 Supervisor review: B.Gorman .0_ Date: S print / sign p:ttuinum programutritium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-111 JELMS #: 20053238 Sample On Date I Time: 09129105 a 12:00 Client ID No. IP 05-583 Sample Off Date / Time: 09129/05 a 12:00 Run No. 05-64 Sample Count Date: 10104105 a 12:00 Sample Distilled: YES Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Sample Gross counts: 82354.8 Sample Count Time (minutes) 120 Sample CPM: 686.29 Sample Net CPM: 676.79 Sample DPM: 1877.29 n nfA Background Counting Efficiency 0.357 l CL Ratlo= 1034.14 I Di n valhrn InCriL I ISample Counting Efficiency L. 9)0.361 044AG 4

)

I Comments: f/6/tT46h sC 2/.e Note: If CL ratio Is <1.0 OR Ac ror Ratio is <2. than e LD value Is reported as a "Less Thanw Activity.

Technician: i"F 4 LA) Date:{

..... A rint I sign Supervisor review: B. Gorman /Ad ;A Date: td print / sign p:~titium program~trftium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID QC STD IELMS #: NA I

Sample On Date / Time: 03114102 12:00 Client ID No. E3050 a

Sample Off Date I Time: 03114/02 12:00 Run No. 05s4 a

Sample Count Date: 10104105 12:00 _Sample Distilled: NO nla.

Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Sample Gross counts: 4300.8 Sample Count Time (minutes) 120 X1-7C /

Sample CPM: 35.84 Mf 54-)L/d Sample Net CPM: 26.34 AWI aSL Sample DPM: 73.53 samole volume (L) jBackground Counting Efficlency 0.357 l CL Ratlo= 4025 j Sample Counting Efficiency 0.358 Sample Activity (pCliL) i I 10116 +/- 236 Comments: Wilk1 /I )2a - 01 0 dJ A AVAIAJ

// e C / /f riw Ar Note: If CL ratio is <1.0 OR ActlError Ratio is 2.7 fanth LIvalue is reported as a "Less Than" Activity.

Technician: Date:' 6 /5/05 fv ~prl / sign Supervisor review: B. Gorman IV Date: S print /sign p:Atrtium program\tritium activity calc.xit

===============-

e~=e======as=====================c===

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab

a==p=l= =D= =RI===I=N = =1= ====928 ======================5== ====== ==

Sample DESCRIPTION: M/W 107 9/28/05 Counting Start: 10/03/2005 10:09:36 Lab ID. . . . . . . . . . . . .20053235 Decay Time. . . . . . . 1.18E+02 Hrs Client ID . . . . . . . . . . IP-05-584 Sampling Stop . . 09/28/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L Sample Duration . . . . O.OOE+00 Hrs Yield . . . . . . . . . . . . . 1.0000 Sampling Start. . 09/28/2005 12:00:00 Geometry Code . . . . . . . . . 3_OMSO" Live Time (hr:min:sec). . . 001:12:04 Eff. Calib. Date. . 10/14/2003 11:21:08 Real Time (hr:min:sec). . . 001:12:07 Library File. . . . . . . . .MASTER.LIB "70/,-

REVIEWED BY: __

Detector #: 1 Energy(keV), -0.16+ 0.500*Ch+ 0.00e+00*ChA2 + 0.O0e+00*Ch43 10/03/2005 /

FWHM(keV) = 0.91+ 0.012*En+ 3.98e-04*EnA2 + 0.OOe+00*EnA3 09/29/2005 -

Where En = Sqrt(Energy in keV)

Eff.=l/[ 6.43e-02*En4-2.76e+00 + 1.76e+02*EnA 7.65e-01] 10/14/2003 CONCENTRATIONs Units: pCi/L

ee====ees===== = - - - = ==s= = === = - == ========

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

==== ==== = ==============:=========- X:= = = === ====es====== === = =

K-40 8.78E+01 3.14E+01 ---------- ---------- ---------- K-40 CO-57 ----- ---------- 4.05E+00 1.26E+01 8.48E+00 CO-57 CE-144 ---------- ---------- .2.97E+01 9.28E+01 6.21E+01 CE-144 CE-141 ---------- ---------- 7.24E+00 2.27E+01 1.52E+01 CE-141 RA-226 ---------- ---------- 9.79E+01 3.05E+02 2.05E+02 RA-226 NP-239 ---------- ---------- 1.01E+02 3.21E+02 2.16E+02 NP-239 SE-75 ---------- ---------- 4.47E+00 1.41E+01 9.58E+0O SE-75 CR-51 ---------- ---------- 3.63E+01 1.13E+02 7.74E+01 CR-51 EU-152 ---------- ---------- 1.20E+01 3.75E+01 2.57E+01 EU-152 I-131 ---------- ---------- 5.43E+00 1.72E+01 1.17E+01 I-131 AG-108M ---------- ---------- 3.19E+00 1.03E+01 6.97E+00 AG-108M BE-7 ---------- ---------- 3.12E+01 1.01E+02 6.81E+01 BE-7 RU-103 ---------- ---------- 3.58E+00 1.15E+01 7.90E+00 RU-103 I-133 ---------- ---------- 2.09E+02 6.54E+02 4.55E+02 I-133 CS-134 ---------- ---------- 2.45E+00 8.31E+00 5.70E+00 CS-134 RU-106 ---------- ---------- 3.46E+01 1.14E+02 7.73E+01 RU-106 CS-137 ---------- ---------- 3.86E+00 1.19E+01 8.53E+00 CS-137 MO-99 ---------- ---------- 8.34E+01 2.73E+02 1.88E+02 MO-99 ZR-95 ---------- ---------- 6.08E+00 1.97E+01 1.37E+01 ZR-95 NE-95 ---------- ---------- 3.01E+00 9.37E+00 6.92E+00 NB-95 CO-58 ---------- ---------- 3.76E+00 1.21E+01 8.41E+00 CO-58 MN-54 ---------- ---------- 3.76E+00 1.21E+01 8.39E+00 MN-54 AG-110M ---------- ---------- 4.47E+00 1.46E+01 1.02E+01 AG-llOM ACTH-228 ---------- ---------- 1.08E+01 3.63E+01 2.49E+01 ACTH-228 I-132 ---------- ---------- 5.06E+01 1.72E+02 1.16E+02 I-132 ZN-65 ---------- ---------- 5.44E+00 1.77E+01 1.30E+01 ZN-65 FE-59 ---------- ---------- 8.41E+00 2.74E+01 l.99E+01 FE-59

CONCENTRATIONs Units: pCi/L

============= i n

== = = s=====s=====-===c====

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

=========== === = == === = = ====wu====== ~

== = =e========

CO-60 ---------- ---------- 4.51E+00 1.44E+01 1.03E+01 CO-60 BALA-140 ---------- ---------- 5.01E+00 1.68E+01 1.20E+01 BALA-140 SB-124 ---------- ---------- 8.30E+00 2.82E+01 1.98E+01 SB-124 TOTAL MEASURED ACTIVITY: 8.78E+01 +- 3.14E+01 pCi/L Results TRANSFERRED to ELMS.

===~===== -=-=----== ==e= == = ====cs========:==== = - ==

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab

R=II==O===9=2======================================== es=======

Sample DESCRIPTION: M/W 108 9/29/05 Counting Start: 10/03/2005 10:12:03 Lab ID. . . . . . . . . . . . .20053236 Decay Time. . . . . . . 9.42E+01 Ers Client ID . . . . . . . . . . IP-05-581 Sampling Stop . . 09/29/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L '

Sample Duration . . . . O.OOE+00 Hrs Yield . . . . . . . . . . . . . 1.0000 Sampling Start. . 09/29/2005 12:00:00 Geometry Code . . . . 3 OMS0, Live Time (hr:min:sec). . . 001:00:01 Eff. Calib. Date. . 07/20/2004 12:40:07 Real Time (hr:min:sec). . . 001:00:17 Library File. . . . . . . . .MASTER.LIB REVIEWED BY;_ _ _ _ _

Detector #: 8 Energy(keV)= 0.18+ 0.500*Ch+ 0.00e+00*ChA2 + 0.OOe+00*ChA3 10/03/2005 I FWHM(keV) = 0.71+ 0.015*En+ 5.29e-04*EnA2 + 0.00e+00*EnA3 09/27/2005 Where En = Sqrt(Energy in keV)

Eff.=l/[ l.09e-01*En^-2.35e+00 + 1.67e+02*EnA 7.66e-01] 07/20/2004 CONCENTRATIONs Unite: pCi/L

====== -== = == =====s=========.========================================

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

==

= = === = = = a======:===================

======-=======s CO-57 ---------- ---------- 2.96E+00 9.38E+00 6.31E+00 CO-57 CE-144 ---------- ---------- 2.26E+01 7.09E+01 4.82E+01 CE-144 CE-141 ---------- ---------- 5.97E+00 1.86E+01 1.27E+01 CE-141 RA-226 ---------- ---------- 7.92E+01 2.51E+02 1.69E+02 RA-226 NP-239 ---------- ---------- 7.20E+01 2.26E+02 1.56E+02 NP-239 SE-75 ---------- ---------- 4.72E+00 1.46E+01 1.02E+01 SE-75 CR-51 ---------- ---------- 2.86E+01 9.14E+01 6.25E+01 CR-51 EU-152 ---------- ---------- 9.11E+00 2.95E+01 2.Q1E+01 EU-152 I-131 ---------- ---------- 3.91E+00 1.29E+01 8.75E+00 I-131 AG-108M ---------- ---------- 2.94E+00 9.54E+00 6.55E+00 AG-108M BE-7 ---------- ---------- 2.58E+01 8.33E+01 5.81E+01 BE-7 RU-103 ---------- ---------- 3.62E+00 1.14E+01 8.08E+00 RU-103 1-133 ---------- ---------- 7.12E+01 2.36E+02 1.61E+02 1-133 CS-134 ---------- ---------- 2.09E+00 7.06E+00 5.10E+00 CS-134 RU-106 ---------- ---------- 2.72E+01 9.74E+01 6.37E+01 RU-106 CS-137 ---------- ---------- 3.23E+00 1.06E+01 7.39E+00 CS-137 MO-99 ---------- ---------- 6.44E+01 2.07E+02 1.48E+02 MO-99 ZR-95 ---------- ---------- 4.34E+00 1.49E+01 1.04E+01 ZR-95 NB-95 ---------- ---------- 3.38E+00 1.12E+01 7.75E+00 NB-95 CO-58 ---------- ---------- 3.97E+00 1.26E+01 8.96E+00 CO-58 MN-54 ---------- ---------- 3.09E+00 1.01E+01 7.17E+00 MN-54 AG-lOM ---------- ---------- 4.09E+00 1.36E+01 9.62E+00 AG-110M ACTH-228 ---------- ---------- 9.86E+00 3.49E+01 2.35E+01 ACTH-228 I-132 ---------- ---------- 2.69E+01 1.04E+02 6.78E+01 I-132 ZN-65 ---------- ---------- 3.86E+00 1.48E+01 1.02E+01 ZN-65 FE-59 ---------- ---------- 9.66E+00 3.17E+01 2.27E+01 FE-59 CO-60 ---------- ---------- 3.21E+00 1.12E+01 7.84E+00 CO-60

CONCENTRATIONs Units: pCi/L

Ce======================- ========= ~===============~===-=s=

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide K-40 ---------- ---------- 2.98E+01 1.20E+02 7.37E+01 K-40 BALA-140 ---------- ---------- 3.84E+00 1.37E+01 9.77E+00 BALA-140 SB-124 ---------- ---------- 9.92E+00 3.33E+01 2.35E+01 SB-124 TOTAL MEASURED ACTIVITY: 0.OOE+00 +- O.OOE+00 pCi/L Results TRANSFERRED to ELMS.

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: M/W 109 9/29/05 Counting Start: 10/03/2005 10:13:06 Lab ID. . . . . . . . . . . . .20053237 Decay Time. . . . . . . 9.42E+01 Hrs Client ID . . . . . . . . . . IP-05-582 Sampling Stop . . 09/29/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L Sample Duration . . . . 0.00E+00 Hrs Yield . . . . . . . . . . . . . 1.0000o-Sampling Start. . 09/29/2005 12:00:00 Geometry Code . . . . . . . . . 3_0MS0-Live Time (hr:min:sec). . . 001:00:07 Eff. Calib. Date. . 10/28/2003 11:01:26, Real Time (hr:min:sec). . . 001:00:09 Library File. . . . . . . . .MASTER.LIB, REVIEWED BY: _ I__

Detector #: 3 Energy(keV), -0.49+ 0.500*Ch+ 0.00e+00*ChA2 + 0.00e+00*ChA3 10/03/2005 -

FWHM(keV) = 1.03+ -0.021*En+ 1.97e-03*En42 + -2.09e-05*En^3 09/27/2005 Where En = Sqrt(Energy in keV)

Eff.=l/[ 9.91e-02*EnA-2.44e+00 + 1.77e+02*En^ 7.BOe-01J 10/28/2003 CONCENTRATIONs Units: pCi/L

= -========== ==:= = = = ======== == = =- == == :=========================

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide K-40 1.88E+02 3.98E+01 ---------- ---------- ---------- K-40 CO-57 ---------- ---------- 3.18E+00 9.99E+00 6.77E+00 CO-57 CE-144 ---------- --- .2.66E+01 8.24E+01 5.63E+01 CE-144 CE-141 ---------- ---------- 5.03E+00 1.66E+01 1.08E+01 CE-141 RA-226 ---------- ---------- 7.67E+01 2.43E+02 1.64E+02 RA-226 NP-239 ---------- ---------- 8.68E+01 2.69E+02 1.86E+02 NP-239 SE-75 ---------- ---------- 4.55E+00 1.45E+01 9.86E+00 SE-75 CR-51 ---------- ---------- 2.81E+01 8.96E+01 6.18E+01 CR-51 EU-152 ---------- ---------- 9.59E+00 3.09E+01 2.12E+01 EU-152 I-131 ---------- ---------- 4.14E+00 1.32E+01 9.23E+00 I-131 AG-108M ---------- ---------- 3.60E+00 1.13E+01 7.91E+00 AG-108M BE-7 ---------- ---------- 3.11E+01 9.81E+01 6.90E+01 BE-7 RU-103 ---------- ---------- 3.64E+00 1.15E+01 8.14E+00 RU-103 I-133 ---------- ---------- 6.62E+01 2.22E+02 1.52E+02 1-133 CS-134 ---------- ---------- 2.03E+00 7.OOE+00 5.02E+00 CS-134 RU-106 ---------- ---------- 4.42E+01 1.39E+02 9.81E+01 RU-106 CS-137 ---------- ---------- 3.74E+00 1.20E+01 8.45E+00 CS-137 MO-99 ---------- ---------- 5.93E+01 1.87E+02 1.39E+02 MO-99 ZR-95 ---------- ---------- 4.57E+00 1.55E+01 1.09E+01 ZR-95 NB-95 ---------- ---------- 3.65E+00 1.19E+01 8.35E+00 NB-95 Co-58 ---------- ---------- 3.38E+00 1.08E+01 7.81E+00 CO-58 MN-54 ---------- ---------- 2.99E+00 1.05E+01 7.02E+00 MN-54 AG-llOM ---------- ---------- 4.51E+00 1.48E+01 1.05E+01 AG-110M ACTH-228 ---------- ---------- 1.30E+01 4.27E+01 3.OOE+01 ACTH-228 I-132 ---------- ---------- 3.11E+01 1.llE+02 7.70E+01 I-132 ZN-65 ---------- ---------- 1.10E+01 3.36E+01 2.45E+01 ZN-65 FE -5.9 7.65E+00 2.58E+O1 1.89E+01 FE-59

CONCENTRATIONs Units: pCi/L s======== -- ==-=-- = = =======- ========cc======= ========u~==========

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide CO-60 ---------- ---------- 3.19E+00 1.06E+01 7.88E+00 CO-60 BALA-140 ---------- ---------- 3.84E+00 1.42E+01 9.90E+00 BALA-140 SB-124 ---------- ---------- 8.12E+00 2.71E+01 2.01E+01 SB-124 TOTAL MEASURED ACTIVITY: 1.88E+02 +- 3.98E+01 pCi/L Results TRANSFERRED to ELMS.

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab

=a=ple DESCRI== TION:M I==ll 9/2905 Sample DESCRIPTION: M/W 111 9/29/05 Counting Start: 10/03/2005 10:15:04 Lab ID. . . . . . . . . . . . .20053238 Decay Time. . . . . . . 9.43E+01 Hrs Client ID . . . . . . . . . . IP-05-583 Sampling Stop . . 09/29/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L "

Sample Duration . . . . 0.00E+00 Ere Yield . . . . . . . . . . . . . 1.0000-Sampling Start. . 09/29/2005 12:00:00 Geometry Code . . . . . . . . . 3_OMS0,-

Live Time (hr:min:sec). . . 001:12:04 Eff. Calib. Date. . 10/14/2003 12:51:25, Real Time (hr:min:sec). . . 001:12:07 Library File. . . . . . . . .MASTER.LIB-REVIEWED BY:__

Detector #: 4 Energy(keV)= 0.34+ 0.500*Ch+ 0.00e+00*Ch^2 + 0.00e+00*ChA3 10/03/2005 -

FWHM(keV) = 0.62+ 0.018*En+ 3.23e-04*En^2 + 0.00e+00*EnA3 09/27/2005 -

Where En = Sqrt(Energy in keV)

Eff.=l/[ 4.84e-02*EnA-3.01e+00 + 2.74e+02*EnA 8.17e-01] 10/14/2003 CONCENTRATIONs Units: pCi/L

=======--=== ===-=========e===========s=e== = === = = ==========

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

==c

=== === === === = == = = ========

==:====== == = === === = === =_

K-40 2.49E+02 5.26E+01 ---------- ---------- ---------- K-40 CO-57 ---------- ---------- 3.95E+00 1.24E+01 8.41E+00 CO-57 CE-144 ---------- ---------- 2.81E+01 8.96E+01 6.01E+01 CE-144 CE-141 ---------- ---------- 7.32E+00 2.31E+01 1.56E+01 CE-141 RA-226 ---------- ---------- 1.04E+02 3.32E+02 2.20E+02 RA-226 NP-239 ---------- ---------- 9.33E+01 3.OOE+02 2.01E+02 NP-239 SE-75 ---------- ---------- 5.52E+00 1.77E+01 1.20E+01 SE-75 CR-51 ---------- ---------- 3.65E+01 1.18E+02 7.98E+01 CR-51 EU-152 ---------- ---------- 1.26E+01 4.10E+01 2.77E+01 EU-152 1-131 ---------- ---------- 6.15E+00 1.95E+01 1.35E+01 I-131 AG-108M ---------- ---------- 5.20E+00 1.61E+01 1.13E+01 AG-108M BE-7 ---------- ---------- 2.83E+01 9.68E+01 6.52E+01 BE-7 RU-103 ---------- ---------- 4.05E+00 1.37E+01 9.19E+00 RU-103 I-133 ---------- ---------- 9.80E+01 3.19E+02 2.21E+02 I-133 CS-134 ---------- ---------- 4.17E+00 1.36E+01 9.55E+00 CS-134 RU-106 ---------- ---------- 4.92E+01 1.56E+02 1.10E+02 RU-106 CS-137 ---------- ---------- 4.48E+00 1.49E+01 1.02E+01 CS-137 MO-99 ---------- ---------- 9.32E+01 2.97E+02 2.12E+02 MO-99 ZR-95 ---------- ---------- 5.65E+00 1.98E+01 1.36E+01 ZR-95 NB-95 ---------- ---------- 6.34E+00 1.97E+01 1.40E+01 NB-95 CO-58 ---------- ---------- 4.96E+00 1.54E+01 1.13E+01 CO-58 MN-54 ---------- ---------- 4.56E+00 1.51E+01 1.05E+01 MN-54 AG-110M ---------- ---------- 6.60E+00 2.26E+01 1.51E+01 AG-110M ACTH-228 ---------- ---------- 1.38E+01 4.73E+01 3.28E+01 ACTH-228 I-132 ---------- ---------- 5.08E+01 1.74E+02 1.21E+02 I-132 ZN-65 ---------- ---------- 6.39E+00 2.20E+01 1.61E+01 ZN-65 FE-59 ---------- ---------- 1.07E+01 3.55E+01 2.60E+01 FE-59

CONCENTRATIONs Units: pCi/L

====== = == == ==================

==== == = = ===z

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

= == = --

=-- ===-==- == = ---- ===z====-=======- == = = == = = == =

CO-60 ---------- ---------- 1.81E+00 8.01E+00 5.57E+OO CO-60 BALA-140 ---------- ---------- 5.80E+00 1.99E+01 1.45E+01 BALA-140 SB-124 ---------- ---------- 6.19E+00 2.62E+01 1.75E+01 SB-124 TOTAL MEASURED ACTIVITY: 2.49E+02 +- 5.26E+01 pCi/L Results TRANSFERRED to ELMS.

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID . ..............: 20053237 /

Client Sample ID . . ....... : IP-05-582 Sample Location . . ........: MISC. UNSPECIFIED IqI4..

Sample Start Date . . ....... % 09/29/05 Sample End Date . .............: 09/29/05 Analysis Recount # . .: 0 System Parameters Sample/Background Counting Date ...... : 10/04/Os Sample/Background Counting Time ...... : 0742 Background Sample Counts ............. : 80 counts Background Count Time ................  : 100 minutes Counter Efficiency ................... : 0.3870 cpm/dpm Sample Quantity ...................... : 0.5000 L

Note: Alpha subtraction was used for this calculation. ----

Gross Alpha Counts ................... : 18 counts Alpha Cross Talk ..................... : 0.2760 Net Alpha Counts ..................... : 4.9680 counts Sample Parameters Gross Sample Counts .................. : 370 counts Sample Count Time . ...........: 100 minutes Sample Yield/Self Absorption . ..... : 0.6800 Net Sample Counts . ...........: 3.7000 counts Corrected Count Rate (beta - alpha)..: 2.8503 cpm Analysis Results Gross Beta Concentration +- Error .... 9.7588 +- 0.7263 pCi/L (1 sigma)

System Specifications Instrument ...............  : LBC-A Procedure Number .................  : AM-03.07 Calibration Date ................. . : 06/20/05 Comments MW- 109 LLD/CL Values Checkad BT:

Reviewed By: __ _ X _

Ir

- _ /

4f

/ M Date: A Date: d 0  :

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID ..............  : 20053236/

Client Sample ID . ...........: IP-05-581 V Sample Location . .............  : MISC. UNSPECIFIED iA/

Sample Start Date .................... : 09/29/05 ,L4/ (VQ Sample End Date . ............: 09/29/05 Analysis Recount # ................... : 0 System Parameters Sample/Background Counting Date ...... : 10/04/05 Sample/Background Counting Time ...... : 0739 Background Sample Counts ............. : 80 counts Background Count Time ................ : 100 minutes Counter Efficiency ................... : 0.3870 cpm/dpm Sample Quantity ...................... : 0.2500 L

Note: Alpha subtraction was used for this calculation. ----

Gross Alpha Counts ................... : 25 counts Alpha Cross Talk ..................... : 0.2760 Net Alpha Counts ...  : 6.9000 counts Sample Parameters Gross Sample Counts . ..........: 370 counts Sample Count Time . ...........: 100 minutes Sample Yield/Self Absorption ......... : 0.7000 Net Sample Counts .................... : 3.7000 counts Corrected Count Rate (beta - alpha)..: 2.8310 cpm Analysis Results Gross Beta Concentration +- Error.... 18.8315 +- 1.4111 pCi/L (1 sigma)

System Specifications Instrument ...............  : LBC-A Procedure Number ..................... : AM-03.07 Calibration Date ..................... : 06/20/05 Comments MW- 108I LLD/CL Values Checked By: ilrl6/ e Date: e Reviewed By: a a H b ate:-

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Repo_______________t______Date:_________________10/0______________/05________

Report Date: 10/05/05 Sample Identification Lab Sample ID ..............  : 20053235/

Client Sample ID . ...........: IP-05-584 V'e Sample Location Sample Start Date

............: MISC. UNSPECIFIED

...........: 09/28/05 I / IL/dg Sample End Date . ............: 09/28/05 Analysis Recount # ................... : 0 System Parameters Sample/Background Counting Date ...... : 10/04/05 Sample/Background Counting Time ...... : 0737 Background Sample Counts ............. : 80 counts Background Count Time ................ : 100 minutes Counter Efficiency ................... : 0.3870 cpm/dpm Sample Quantity ...................... : 0.5000 L

Note: Alpha subtraction was used for this calculation. ----

Gross Alpha Counts ................... : 11 counts Alpha Cross Talk ..................... : 0.2760 Net Alpha Counts ..................... : 3.0360 counts Sample Parameters Gross Sample Counts . ..........: 542 counts Sample Count Time .................... : 100 minutes Sample Yield/Self Absorption . ..... : 0.6800 Net Sample Counts . ...........: 5.4200 counts Corrected Count Rate (beta - alpha)..: 4.5896 cpm Analysis Results Gross Beta Concentration +- Error .... 15.7139 +- 0.8539 pCi/L (1 sigma)

System Specifications Instrument...........................: LBC-A Procedure Number . ........... : AM-03.07 Calibration Date ..................  : 06/20/05 Comments MW -107/

LLD/CL Values Checked By: 4b¶l (W Date: 101 /3§ Reviewed By: ______________ Date: Ad/ SS

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID . . ........ : 20053238 /

Client Sample ID . . ....... : IP-05-583 /l Sample Location . . ........: MISC. UNSPECIFIED Sample Start Date .................... : 09/29/05 /1/

Sample End Date . . . : 0 0/29/05 Analysis Recount # ................... 0 System Parameters Sample/Background Counting Date ...... : 10/04/05 Sample/Background Counting Time ...... : 0745 Background Sample Counts ............. : 80 counts Background Count Time . ......... 100 minutes Counter Efficiency . .......... 0.3870 cpm/dpm Sample Quantity ...................... 0.5000 L

Note: Alpha subtraction was used for this calculation. ----

Gross Alpha Counts . .......... : 16 counts Alpha Cross Talk . ...........  : 0.2760 Net Alpha Counts ..................... : 4.4160 counts Sample Parameters Gross Sample Counts . ..........: 467 counts Sample Count Time . ...........: 100 minutes Sample Yield/Self Absorption . ..... : 0.7100 Net Sample Counts . ...........: 4.6700 counts Corrected Count Rate (beta - alpha)..: 3.8258 cpm Analysis Results

-M Gross Beta Concentration +- Error .... 12.5453 +- 0.7669 pCi/L (1 sigma)

System Specifications Instrument..........................: LBC-A Procedure Number ..................... : AM-03.07 Calibration Date . ........... : 06/20/05 Comments MW- 111 / /

LLD/CL Values Checked By: Date:

Reviewed By: Z-iOZthv _ Date: S

TRITIUM PROGRAM Tritium Analysis Sample Run ID Sheet Run No. 05-65 Plant Eff. 5 Environmental M Other El Sample Count Date 10/5/2005 Background Count Time(min.) 30 Background (CPM) 9.38 Background Counting Eff. 0.356 Background (DPM) 26.32 2-5 _ QC STD 3/14/2002 12:00 NA E3050 30 37.52 76.34 0.359 '10504 t 479 2-7 1MW-11 Reanalysis 9/29/2005 12:00 20053238 IP-05-583 30 684.64 1886.32 0.358 212620 +/- 1514

=L- ___

  • i 92cr pursue~ ,w;w-*446 Page / of (_ Completed By: Pae .f y goplte y:DaeDate: zVA/6-0

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-11 Reanalysis IELMS #: 20053238 Samole On Date I Time: 09/29/05 a 12:00 Client ID No. IP-05-583 Sample Off Date I Time: 09129105 a 12:00 Run No. 05-65 Sample Count Date: 10105/05 a 12:00 Sample Distilled: I YES Background Gross counts: 281.A3 Background count time (minutes) 30 Background Counts, CPM: 9.38 Background DPM 26.32 Sample Gross counts: 20539.3 Sample Count Time (minutes) 30 Sample CPM: 6B4.64 Sample Net CPM: 675.26 Sample DPM: 1886.32 Background Counting Efficiency 0.356 I CL Ratio= 519.07 1 LLD valiu In(' iLl -e:q51 Sample Counting Efficiency 0.358 151 IL%--I-A -A..:L. 1_n:11 % z A 15a 212620 + 1514N )/0 I Comments:

Note: If CL ratio Is c1.0 0_ct/Error Ratih is <2/f-thn the LLD value Is reported as a 'Less Than' Activity.

Technician: - l Date:P Supervisor review: B. Gorman TI - Date:

print /sign p:\tritium programrnritium activity calc.xit

INDIAN POINT

SUMMARY

SHEET SAMPLE TYPE: Special Waters REPORTING UNITS IN: pCI/L Oct-05 F:::-:-.:::::::::::::::: ......................

.. ... 5

.. . . .... CL j . 4 . : 2 .. .. . . . .. 5. B.. .. . . . .. . . .__.. ._. _. ...

i Be-7 <31.17 _ <25.79 <31.1 <28.32 l K-40 87.79+/-31.37 <29.8 187.6+/-l39.82 249+/-52.56 i Mn-54 <3.76 _ <3.09 <2.99 <4.56 Co-58 <3.76 _ <3.98 <3.38 <4.96 Fe-59 <8.42 <9.66 <7.65 <10.66 Co-60 (7.5*) <4.51 <3.21 <3.19 <1.81 Zn-C ________ <5.44 _ <3.86 <10.97- <6.39 Zr-95 <6.08 <4.34 <4.57 <5.65 Nb-95 ________ <3.01 <3.38 <3.65 <6.34 Ru-I103 ________ <3.58 _ <3.62 <3.64 <4.05 Ru-106 <34.64 <27.24 <44.24 <49.16 1-131 <5.43 <3.92 <4.14 <6.15 Cs-134 (7.5*) <2.45 <2.09 <2.03 <4.17 Cs-137 (9.-0*) <3.86 _ <3.24 <3.74 <4.48 Ba/La -140 <5.01 _ <3.84 <3.84 <5.8 Ce-141 ________ <7.24 <5.97 <5.03 <7.32 Ce-144 <29.70 _ 22.60 <26.60 <28.10 Ra-226 ________ <97.94 <79.22 <76.69 <103.6 Ac-228 <10.78 <9.86 <12.96 <13.8 GROSS BETA 15.7+/-+0.9 _ 18.8 +/- 1.4 9.8 +/-0.7 12.5 +/- 0.8 H-3 <420 <420 <420 211569+/-+753 Results reported as < are CL values

  • Posted CL's correspond to LLD's listed In TS-5.104 (Rev.5)

CL Values Verified By_.

NOTE: The summary data sheet results have been provided to you to facilitate the review of analytical results. These summary sheets have not been Independently verified and should not be used for the fina reporting of data without a second verification.

ATTACHMENT 7.12 PAGE1 OF1 INDIAN POINT SPECIALS ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM WEEK # 39 CLIENT CODE 04 SAMPLE CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA DATE/TIME VOLUME ANALYSIS SAMPLE STATION TYPE CODE (UNITS) TYPE ID NUMBER NUMBER FROM TO 1 _ H-3, GB IP 05-584

.StMW 107 RR WA 9128/5 1 GAL GSA IP 05-581 M1W 108 RR SL 912915 1 GAL GSAH-3 GB BUCHANAN SEWAGE IP 98 TREATMENT PLANT RR SL GAL GSA (Holdup Tank 2), _ _ _

H-3 IP 99 ALGONQUIN OUTFALL RR WA GAL GSA H-3 IP 100 GYPSUM PLANT RR WA GAL GSA STREAM GB H-3 IP 102 TRAP ROCK QUARRY RR WA GAL GSA IP 05-582 M/W 109 RR WA 9/29/5 1 GAL H-3 GSA GB IP 05-583 M/W 111 RR WA 9/2915 1 GAL H-3 GSA GB REMARKS: INDIAN POINT SPECIALS - MONTHLY RR = Regular Routine

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-11 Reanalysis IELMS #: 20053238 Samole On Date I Time: 09129105 a 12:00 Client ID No. IP-05-583 Sample Off Date / Time: 09129105 a 12:00 Run No. 05-65 Sample Count Date: 10105105 12:00 DistIlled:

lSamleI YES Background Gross counts: 281.43 Background count time (minutes) 30 Background Counts, CPM: 9.38 Background DPM 26.32 Sample Gross counts: 20539.3 Sample Count Time (minutes) 30 Sample CPM: 684.64 Sample Net CPM: 675.26 Sample DPM: 1886.32 Background Counting Efficiency 0.356 CL Ratios 519.07 .

LLD value (pCVL) <851 Act/Error Ratio= 140A Sample Counting Efficiency 0.358 Sample Activity (CUL I1 sli a 212620 1514 )

Comments:

Note: If CL ratio is <1.0 O&jctfError Ratic7 Is ken the LLD value is reported as a "Less Than" Activity.

Technician: 1'Date:g 1(/6(

Supervisor review: B. Gorman print / sign p:\tntium programutritium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-107 ELMS #: 20053235 Sample On Date I Time: 09128105 e 12:00 Client ID No. IP 05-SM Sample Off Date / Time: 09128105 o 12:00 Run No. 05-64 Sample Count Date: 10104105 e 12:00 Sampe Distilled: YES Ela sod Time (count date to off date) y 0.02_Fcr Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Critical Level CL CPM 0.65 Sample Gross counts: 1260 Sample Count Time (minutes) 120 Sample CPM: 10.50 Sample Net CPM: 1.00 Sample DPM: 2.74 sam le volume L 0.004 Background Counting Efficiency 037CL Ratio= 1.53 LLD value ( CIL1 <420 1/ ActError Ratio= 24 Sample Counting Efficiency 0.358 a Activit _CIL I sigma 309 i 129 Comments: ~

P*o 6  ;@SgP4t < 4'2eia Note: If CL ratio Is <16i. 0ActlError Ratio <2 (I thaA the LLD value Is reported as a nLess Than" Activih, Technician: 0 lKY ' I ) l Date:

print ign Supervisor review: B. Gorman ). 1 Date: 'dl 5 print / sign p:\tritlum programurtium activity calc.xlt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-108 JELMS #: 20053236 Sample On Date I Time: 09/29105 a 12:00 Client ID No. IP 05-581 Sample Off Date / Time: 09/29105 a 12:00 Run No. 05-64 Sample Count Date: 10/04105 a 12:00 Sample Distilled: I YES Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Sample Gross counts: 1274 Sample Count Time (minutes) 120 Sample CPM: 10.62 Sample Net CPM: 1.12 Sample DPM: 2.95 Background Counting Efficiency (t42 1/' CL Ratio= 1.71 LLD value (DCIIL) 1 Act/Error Ratlo= 2.6 Sample Counting Efficiency 0.359 Sample Activity (pCUIL +/- I sl ma 332 i 128 Comments: ~ Y e3 Olc*4Z~

Note: If CL ratio Is <R.0 Act/Error Rati Is <2./tha the LLD value Is reported as a "Less Than" Activity Technician: _ _ _ _ _ _ / _ ____hi)

_ Date:

Supervisor review: B. Goman Date: As print / sign p:ntritium program\ritium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-109 [ELMS #: 20053237 Sample On Date / Time: 09129105 a 12:00 Client ID No. IP 05.582 Sample Off Date / Time: 09129/05 a 12:00 Run No. 05-64 Sample Count Date: 10104J05 a 12:00 Sample Distilled: I YES Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 0.65 Sample Gross counts: 1205.6 Sample Count Time (minutes) 120 Sample CPM: 10.05 Sample Net CPM: 0.55 Sample DPM: 1.37 Background Counting Efficiency Q 0.357 ) I CL Ratio= 0.84 LLD value (pClIL) <420 ) I Act/Error Ratio= 1.2 Sample Counting EfficIency 0.359 Sample Activity pCI/L) +/-1 sigma 154 i 127 Comments: t $ZM; 6@2f 'fe >

.F /

Note: If CL ratio Is <1.0 ctLError Ratio I<2.7 tI/ant LD value Isoisrorted s a "Less Than" Activi Technician: < Date: IDS 051 Supervisor review: B. Gorman S1d Date: A4 d print I sign p:\tritium program\tritium activity calc.xft

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID 1 MW-111 ELMS #: 20053238 Sample On Date I Time: 09129105 a 12:00 Client ID No. IP 05-583 Sample Off Date I Tlime: 09129105 o 12:00 Run No. 05-64 Sample Count Date: 10/04/05 a 12:00 Sample Distilled: YES Deca Factor. 0.9992 Background Gross counts: 1139.60 Background count time (minutes) _120 Background Counts, CPM: 9.50 Background DPM 26.60 Critical Level jCL CPM 0.65 pie Gross counts: 82354.8 Sample Count Tlime (minutes) 120 Sample CPM: 686.29 Sample Net CPM: 676.79 Sample DPM: 1877.29 a lume 0.004 Background Counting Efficiency 0.357 CL Ratlo= 1034.14 LLaue (pCUL) <420 AUrror Ratio= 281.1 Sam Counting Efficiency 0 Note: If CL ratio Is -1.0 OR'Acft or Ratio Is <2. than ILD value Is reported as a "Less Than" Activty echnIcian: ii Vh'. IA Date:

Supervisor review:B..Gorman sl L...+ Date: 1l753 prnt/ si1n p:aritium programtritium activity cal~cxlt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID QC STD TELMS #: NA Sample On Date / Time: 03/14102 a 12:00 Client ID No. E3050 Sample Off Date i Time: 03114102 a 12:00 Run No. 05-64 Sample Count Date: 10/04105 12:00 Sample Distilled: NO Deca Factor: 0.8186 Background Gross counts: 1139.60 Background count time (minutes) 120 Background Counts, CPM: 9.50 Background DPM 26.60 Critical Level CL CPM 0.65 Sample Gross counts: 4300.8 Sample Count Time (minutes) 120 Sample CPM: 35.84 0 Sample Net CPM: 26.34 Sample DPM: 73.53 sample volume L 0.004 Background Counting Efficiency 0.357 CL Ratlo= 40.25 LLD value CL <513 ctlError Ratio= 42.8 Sample Counting Efficiency 0.358____

Sample Activity (pCllL +/- I sigma 10116 i 236 Note: If CL ratio Is <1.0 OR ActlError Ratio isF2.7 an LD value Is reported as a 'Less Than' Activity, Technician: L WitWI.

Supervisor review: B. Gorman Date:

print / sign p:tntium programntritium actvity calc.xit

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID ........................ : 20053237 Client Sample ID ..................... : IP-05-582 / FIE Sample Location . . ........: MISC. UNSPECIFIED Sample Start Date . ............: 09/29/05 Sample End Date . .............: 09/29/05 Analysis Recount # . .  : 0 System Parameters Sample/Background Counting Date ..... : 10/04/05 Sample/Background Counting Time ..... : 0742 Background Sample Counts . ....... : 80 counts Background Count Time . .........: 100 minutes Counter Efficiency ................... : 0.3870 cpm/dpm Sample Quantity . ............: 0.5000 L /

Note: Alpha subtraction was used for this calculation.

Gross Alpha Counts ................... : 18 counts Alpha Cross Talk ..................... : 0.2760 Net Alpha Counts ..................... : 4.9680 counts Sample Parameters Gross Sample Counts . ..........: 370 counts Sample Count Time .................... : 100 minutes Sample Yield/Self Absorption . ..... : 0.6800 Net Sample Counts . ...........: 3.7000 counts Corrected Count Rate (beta - alpha)..: 2.8503 cpm Analysis Results Gross Beta Concentration +- Error.... 9.7588 +- 0.7263 pCi/L (1 sigma)

System Specifications Instrument ...............  : LBC-A Procedure Number . ............: AM-03.07 Calibration Date .................  : 06/20/05 Comments MW -109()I LLD/CL Values CheCW y:M Date:

Reviewed By: Date:

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID ........................  : 20053236 Client Sample ID .....................  : IP-05-581- .

Sample Location ......................  : MISC. UNSPECIFIED Sample Start Date ....................  : 09/29/05 14C4(/ (V° Sample End Date ......................  : 09/29/05 Analysis Recount # ...................  : 0 System Parameters Sample/Background Counting Date ...... : 10/04/05 Sample/Background Counting Time ...... : 0739 Background Sample Counts ............. : 80 counts Background Count Time ................ : 100 minutes Counter Efficiency................... : 0.3870 cpm/dpm Sample Quantity ...................... : 0.2500 L A

Note: Alpha subtraction was used for this calculation. ----

Gross Alpha Counts ................... : 25 counts Alpha Cross Talk ...  : 0.2760 Net Alpha Counts ..................... : 6.9000 counts Sample Parameters Gross Sample Counts .................. : 370 counts Sample Count Time .................... : 100 minutes Sample Yield/Self Absorption ......... : 0.7000 Net Sample Counts .................... : 3.7000 counts Corrected Count Rate (beta - alpha)..: 2.8310 cpm Analysis Results Gross Beta Concentration +- Error....: 18.8315 +- 1.4111 pCi/L (1 sigma)

System Specifications Instrument ........................... : LBC-A Procedure Number ..................... : AM-03.07 Calibration Date ..................... : 06/20/05 Comments MW- 108 /

LLD/CL Values Checked By: ,rII/W Date: I Reviewed By: iE>,x,,

-eae

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID ........................ : 20053235 /

Client Sample ID ..................... : IP-05-584 f Sample Location ....................... : MISC. UNSPECIFIED l/N W/.

Sample Start Date .................... : 09/28/05 /

Sample End Date . ............: 09/28/05 Analysis Recount # . .  : 0 System Parameters Sample/Background Counting Date ...... 10/04/05 Sample/Background Counting Time ...... 0737 Background Sample Counts ............. : 80 counts Background Count Time ................ : 100 minutes Counter Efficiency ................... 0.3870 cpm/ pm Sample Quantity ... 0.5000 L 1

Note: Alpha subtraction was used for this calculation.

Gross Alpha Counts ................... : 11 counts Alpha Cross Talk ..................... : 0.2760 Net Alpha Counts .............. I....... : 3.0360 counts Sample Parameters Gross Sample Counts .................. : 542 counts Sample Count Time .................... : 100 minutes Sample Yield/Self Absorption . ..... : 0.6800 Net Sample Counts .................... : 5.4200 counts Corrected Count Rate (beta - alpha)..: 4.5896 cpm Analysis Results Gross___Beta___Concentration______-E--15__7_3____- 0 p_________(1___s____ma__

Gross Beta Concentration +- Error .... : 1573 +- 0.8539 pCi/L (I sigma)

System Specifications Instrument ........................... : LBC-A Procedure Number ..................... : AM-03.07 Calibration Date ..................... : 06/20/05 Comments MW-107/

LLD/CL Values Checked By: _-1 . W Date: t90S54 Reviewed By: 73. dA$/.,;5P Date: - 10i

James A. Fitzpatrick Nuclear Power Plant Environmental Laboratory Management System (ELMS)

Gross Beta Analysis Analytical Results Data Sheet Report Date: 10/05/05 Sample Identification Lab Sample ID ........................ : 20053238 7 Client Sample ID . ...........: IP-05-583 o Sample Location . ............: MISC. UNSPECIFIED ji Sample Start Date . ...........: 09/29/05 /{/ f //

Sample End Date . ............: 09/29/05 Analysis Recount # ................... : 0 System Parameters Sample/Background Counting Date ...... : 10/04/05 Sample/Background Counting Time ...... : 0745 Background Sample Counts ............. : 80 counts Background Count Time ................ : 100 minutes Counter Efficiency ................... : 0.3870 cpm/lpm Sample Quantity ...................... : 0.5000 Lv

Note: Alpha subtraction was used for this calculation. ----

Gross Alpha Counts ................... : 16 counts Alpha Cross Talk ..................... : 0.2760 Net Alpha Counts ..................... : 4.4160 counts Sample Parameters Gross Sample Counts ..................  : 467 counts Sample Count Time .................... : 100 minutes Sample Yield/Self Absorption . ..... : 0.7100 Net Sample Counts . ...........: 4.6700 counts Corrected Count Rate (beta - alpha)..: 3.8258 cpm Analysis Results Gross Beta Concentration +- Error.... 12.5453 +- 0.7669 pCi/L (1 sigma)

System Specifications Instrument ........................... : LBC-A Procedure Number ..................... : AM-03.07 Calibration Date ..................... : 06/20/05 Comments MW-ll/

LLD/CL Values Checked By: ,,, Date: la/

Reviewed By: Z Date:

==== = == = = ======= = = == ==s================-

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: 107928====05====

Sample DESCRIPTION: M/W 107 9/28/05 Counting Start: 10/03/2005 10:09:36 Lab ID. . . . . . . . . . . . .20053235 Decay Time. . . . . . . 1.18Ea02 Ers Client ID . . . . . . . . . . IP-05-584 Sampling Stop . .09/28/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L '

Sample Duration . . . . O.00E+00 Hrs Yield . . . . . . . . . . . . . '.0000" Sampling Start. . 09/28/2005 12:00:00 Geometry Code . . . . . . . . . 3OMSO' Live Time (hr:min:sec). . . 001:12:04 Eff. Calib. Date. . 10/14/2003 11:21:08 Real Time (hr:min:sec). . . 001:12:07 Library File. . . . . . . . .MASTER.LIB REVIEWED BY: _ _ _ _ _

Detector #: 1 Energy(keV)= -0.16+ 0.500*Ch+ 0.00e+00*Ch 2 + 0.O0e+00*ChA3 10/03/2005 /

FWHM(keV) 0.91+ 0.012*En+ 3.98e-04*En42 + .00e+00*EnA3 09/29/2005 -

Where En = Sqrt(Energy in keV)

Eff.=l/[ 6.43e-02*En^-2.76e+00 + 1.76e+02*EnA 7.65e-01] 10/14/2003 CONCENTRATIONs Units: pCi/L

= - = = = --- = = == = = = =======================s==============

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide K-40 8.78E+01 3.14E+01 ---------- ---------- ---------- K-40 CO-57 ---------- ---------- 4.05E+00 1.26E+01 8.48E+00 CO-57 CE-144 ---------- ---------- 2.97E+01 9.28E+01 6.21E+01 CE-144 CE-141 ---------- ---------- 7.24E+00 2.27E+01 1.52E+01 CE-141 RA-226 ---------- ---------- 9.79E+01 3.05E+02 2.05E+02 RA-226 NP-239 ---------- ---------- 1.01E+02 3.21E+02 2.16E+02 NP-239 SE-75 ---------- ---------- 4.47E+00 1.41E+01 9.58E+00 SE-75 CR-51 ---------- ---------- 3.63E+01 1.13E+02 7.74E+01 CR-51 EU-152 ---------- ---------- 1.20E+01 3.75E+01 2.57E+01 EU-152 I-131 ---------- ---------- 5.43E+00 1.72E+01 1.17E+01 I-131 AG-108M ---------- ---------- 3.19E+00 1.03E+01 6.97E+00 AG-108M BE-7 ---------- ---------- 3.12E+01 1.01E+02 6.81E+01 BE-7 RU-103 ---------- ---------- 3.58E+00 1.15E+01 7.90E+00 RU-103 I-133 ---------- ---------- 2.09E+02 6.54E+02 4.55E+02 I-133 CS-134 ---------- ---------- 2.45E+00 8.31E+00 5.70E+00 CS-134 RU-106 ---------- ---------- 3.46E+01 1.14E+02 7.73E+01 RU-106 CS-137 ---------- ---------- 3.86E+00 1.19E+01 8.53E+00 CS-137 MO-99 ---------- ---------- 8.34E+01 2.73E+02 1.88E+02 MO-99 ZR-95 ---------- ---------- 6.08E+00 1.97E+01 1.37E+01 ZR-95 NB-95 ---------- ---------- 3.01E+00 9.37E+00 6.92E+00 NB-95 CO-58 ---------- ---------- 3.76E+00 1.21E+01 8.41E+00 CO-58 MN-54 ---------- ---------- 3.76E+00 1.21E+01 8.39E+00 MN-54 AG-110M ---------- ---------- 4.47E+00 1.46E+01 1.02E+01 AG-110M ACTH-228 ---------- ---------- 1.08E+01 3.63E+01 2.49E+01 ACTH-228 I-132 ---------- ---------- 5.06E+01 1.72E+02 1.16E+02 I-132 ZN-65 ---------- ---------- 5.44E+00 1.77E+01 1.30E+01 ZN-65 FE-59 ---------- ---------- 8.41E+00 2.74E+01 1.99E+01 FE-59

CONCENTRATIONs Units: pCi/L

=====- = = = =========s==e= ===========ce======_sCeJ (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide CO-60 ---------- ---------- 4.51E+00 1.44E+01 1.03E+01 CO-60 BALA-140 ---------- ---------- 5.01E+00 1.68E+01 1.20E+O1 BALA-140 SB-124 ---------- ---------- 8.30E+00 2.82E+01 1.98E+O1 SB-124 TOTAL MEASURED ACTIVITY: 8.78E+01 +- 3.14E+01 pCi/L Results TRANSFERRED to ELMS.

- = = = = == =- == == == = = = = === = === = == = == = == = === =e== =

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: M/W 108 9/29/05 Counting Start: 10/03/2005 10:12:03 Lab ID. . . . . . . . . . . . .20053236 Decay Time. . . . . . . 9.42E+01 Hrs Client ID . . . . . . . . . . IP-05-581 Sampling Stop . . 09/29/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L '

Sample Duration . . . . O.O0E+00 Hrs Yield . . . . . . . . . . . . . 1.0000, Sampling Start. . 09/29/2005 12:00:00 Geometry Code . . . . . . . . . 30OMS0.

Live Time (hr:min:sec). . . 001:00:01 Eff. Calib. Date. . 07/20/2004 12:40:07 Real Time (hr:min:sec). . . 001:00:17 Library File. . . . . . . . .MASTER.LIB

-n _4 REVIEWED BY:__ _

Detector #: 8 /

Energy(keV)= 0.18+ 0.500*Ch+ 0.00e+00*ChA2 + 0.00e+00*ChA3 10/03/2005

  • FWXM(keV) - 0.71+ 0.015*En+ 5.29e-04*EnA2 + 0.OOe+00*EnA3 09/27/2005 '

Where En = Sqrt(Energy in keV)

Eff.=l/[ 1.09e-01*EnA-2.35e+00 + 1.67e+02*En^ 7.66e-01] 07/20/2004 CONCENTRATIONs Units: pCi/L

e == e==

e ==

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

=== = = == =======.======.=========================== == = = = = =

CO-57 --- --- ---------- 2.96E+00 9.38E+00 6.31E+00 CO-57 CE-144 ---------- ---------- 2.26E+01 7.09E+01 4.82E+01 CE-144 CE-141 ---------- ---------- 5.97E+00 1.86E+01 1.27E+01 CE-141 RA-226 ---------- ---------- 7.92E+01 2.51E+02 1.69E+02 RA-226 NP-239 ---------- ---------- 7.20E+01 2.26E+02 1.56E+02 NP-239 SE-75 ---------- ---------- 4.72E+00 1.46E+01 1.02E+01 SE-75 CR-51 ---------- ---------- 2.86E+01 9.14E+01 6.25E+01 CR-51 EU-152 ---------- ---------- 9.iiE+O0 2.95E+01 2.O1E+O1 EU-152 I-131 ---------- ---------- 3.91E+00 1.29E+01 8.75E+00 I-131 AG-108M ---------- ---------- 2.94E+00 9.54E+00 6.55E+00 AG-108M BE-7 ---------- ---------- 2.58E+01 8.33E+01 5.81E+01 BE-7 RU-103 ---------- ---------- 3.62E+00 1.14E+01 8.08E+00 RU-103 I-133 ---------- ---------- 7.12E+01 2.36E+02 1.61E+02 I-133 CS-134 ---------- ---------- 2.09E+00 7.06E+00 5.10E+00 CS-134 RU-106 ---------- ---------- 2.72E+01 9.74E+01 6.37E+01 RU-106 CS-137 ---------- ---------- 3.23E+00 1.06E+01 7.39E+00 CS-137 MO-99 ---------- ---------- 6.44E+01 2.07E+02 1.48E+02 MO-99 ZR-95 ---------- ---------- 4.34E+00 1.49E+01 1.04E+01 ZR-95 NB-95 ---------- ---------- 3.38E+00 1.12E+01 7.75E+00 NB-95 Co-S8 ---------- ---------- 3.97E+00 1.26E+01 8.96E+00 CO-58 MN-54 ---------- ---------- 3.09E+00 1.01E+01 7.17E+00 MN-54 AG-llOM ---------- ---------- 4.09E+00 1.36E+01 9.62E+00 AG-110M ACTH-228 ---------- ---------- 9.86E+00 3.49E+01 2.35E+01 ACTH-228 I-132 ---------- ---------- 2.69E+01 1.04E+02 6.78E+01 I-132 ZN-65 ---------- ---------- 3.86E+00 1.48E+01 1.02E+01 ZN-65 FE-59 ---------- ---------- 9.66E+00 3.17E+01 2.27E+01 FE-59 CO-60 ---------- ---------- 3.21E+00 1.12E+01 7.84E+00 CO-60

CONCENTRATIONs Units: pCi/L

==R===scs==a=== = == = == = ====s========e==============~===-=e=== -

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide S===2==SS=== == = == == = = == S=S=====S= -- == --S= ===S=S==

K-40 ---------- ---------- 2.98E+01 1.20E+02 7.37E+01 K-40 BALA-140 ---------- ---------- 3.84E+00 1.37E+01 9.77E+00 BALA-140 SB-124 ---------- ---------- 9.92E+00 3.33E+01 2.35E+01 SB-124 TOTAL MEASURED ACTIVITY: 0.00E+00 +- 0.00E+00 pCi/L Results TRANSFERRED to ELMS.

- - - - -- s----==m===== == = === = =

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab S=a=l=eDESCR====IPTIN:=====1=0=9929 Sample DESCRIPTION: M/W 109 9/29/05 Counting Start: 10/03/2005 10:13:06 Lab ID. . . . . . . . . . . . .20053237 Decay Time. . . . . . . 9.42E+O1 Hrs Client ID . . . . . . . . . . IP-05-582 Sampling Stop . . 09/29/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L Sample Duration . . . . O.OOE+00 Hrs Yield . . . . . . . . ... . . . 1.0000,.

Sampling Start. . 09/29/2005 12:00:00 Geometry Code . . . . . . . . . 3_OMSO, Live Time (hr:min:sec). . . 001:00:07 Eff. Calib. Date. . 10/28/2003 11:01:26,-

Real Time (hr:min:sec). . . 001:00:09 Library File. . . . . . . . .MASTER.LIBE REVIEWED BY:_ _ _ __ _

Detector #: 3 Energy(keV)= -0.49+ 0.500*Ch+ 0.OOe+00*Ch^2 + 0.OOe+00*ChA3 10/03/2005 FWHM(keV) = 1.03+ -0.021*En+ 1.97e-03*En^2 + -2.09e-05*EnA3 09/27/2005 Where En = Sqrt(Energy in keV)

Eff.=l/[ 9.9le-02*EnA-2.44e+00 + 1.77e+02*EnA 7.80e-011 10/28/2003 CONCENTRATIONs Units: pCi/L

=========== = === == ====== === === em=== = == === - - -= == e==== == == = = =

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide K-40 1.88E+02 3.98E+01 ---------- ---------- ---------- K-40 CO-57 ---------- ---------- 3.18E+00 9.99E+00 6.77E+00 CO-57 CE-144 ---------- ---------- .2.66E+01 8.24E+01 5.63E+01 CE-144 CE-141 ---------- ---------- 5.03E+00 1.66E+01 1.08E+01 CE-141 RA-226 ---------- ---------- 7.67E+01 2.43E+02 1.64E+02 RA-226 NP-239 ---------- ---------- 8.68E+01 2.69E+02 1.86E+02 NP-239 SE-75 ---------- ---------- 4.55E+00 1.45E+01 9.86E+00 SE-75 CR-51 ---------- ---------- 2.81E+01 8.96E+01 6.18E+01 CR-51 EU-152 ---------- ---------- 9.59E+00 3.09E+01 2.12E+01 EU-152 I-131 ---------- ---------- 4.14E+00 1.32E+01 9.23E+00 1-131 AG-108M ---------- ---------- 3.60E+00 1.13E+01 7.91E+00 AG-108M BE-7 ---------- ---------- 3.11E+01 9.81E+01 6.90E+01 BE-7 RU-103 ---------- ---------- 3.64E+00 1.15E+01 8.14E+00 RU-103 I-133 ---------- ---------- 6.62E+01 2.22E+02 1.52E+02 I-133 CS-134 ---------- ---------- 2.03E+00 7.OOE+00 5.02E+00 CS-134 RU-106 ---------- ---------- 4.42E+01 1.39E+02 9.81E+01 RU-106 CS-137 ---------- ---------- 3.74E+00 1.20E+01 8.45E+00 CS-137 MO-99 ---------- ---------- 5.93E+01 1.87E+02 1.39E+02 MO-99 ZR-95 ---------- ---------- 4.57E+00 1.55E+01 l.09E+0l ZR-95 NB-95 ---------- ---------- 3.65E+00 l.19E+01 8.35E+00 NB-95 CO-58 ---------- ---------- 3.38E+00 1.08E+01 7.81E+00 CO-58 MN-54 ---------- ---------- 2.99E+00 1.05E+01 7.02E+00 MN-54 AG-llOM ---------- ---------- 4.51E+00 1.48E+01 1.05E+01 AG-110M ACTH-228 ---------- ---------- 1.30E+01 4.27E+01 3.OOE+O1 ACTH-228 I-132 ---------- ---------- 3.11E+01 1.11E+02 7.70E+01 I-132 ZN-65 ---------- ---------- 1.1OE+01 3.36E+01 2.45E+01 ZN-65 FE-59 ---------- ---------- 7.65E+00 2.58E+01 1.89E+01 FE-59

CONCENTRATIONs Units: pCi/L

=

e~c=eetcee==== = = = --- ===== == = = ===-

= = ======= = -= = = = == = === == == == ~

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide Co-o- ---------- ---------- 3.19E+00 1.06E+01 7.88E+00 CO-60 BALA-140 ---------- ---------- 3.84E+00 1.42E+01 9.90E+00 BALA-140 SB-124 ---------- ---------- 8.12E+00 2.71E+01 2.01E+01 SB-124 TOTAL MEASURED ACTIVITY: 1.88E+02 +- 3.98E+01 pCi/L Results TRANSFERRED to ELMS.

= =e====

==== = === --- = - - - = = -= -- -== ==== = = = ====- === = = === ===x:

SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab

=Sp DSI=PTION: M/W == = = ==9===9=05 Sample DESCRIPTION: M/W 111 9/29/05 Counting Start: 10/03/2005 10:15:04 Lab ID. . . . . . . . . . . . .20053238 Decay Time. . . . . . . 9.43E+01 Hre Client ID . . . . . . . . . . IP-05-583 Sampling Stop . . 09/29/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L '

Sample Duration . . . . O.OOE+00 Ero Yield . . . . . . . . . . . . 1.0000.-

Sampling Start. . 09/29/2005 12:00:00 Geometry Code . . . . . . . . . 3_OMSO.,

Live Time (hr:min:sec). . . 001:12:04 Eff. Calib. Date. . 10/14/2003 12:51:25, Real Time (hr:min:sec). . . 001:12:07 Library File. . . . . . . . .MASTER.LIB.

REVIEWED BY:

Detector #: 4 Energy(keV)= 0.34+ 0.500*Ch+ 0.00e+00*ChA2 + 0.00e+00*Ch^3 10/03/2005 -

FWHM(keV) , 0.62+ 0.018*En+ 3.23e-04*En 2 + 0.OOe+00*EnA3 09/27/2005 Where En = Sqrt(Energy in keV)

Eff.=l/[ 4.84e-02*EnA-3.0le+00 + 2.74e+02*EnA 8.17e-01] 10/14/2003 CONCENTRATIONs Unite: pCi/L

========= ==C = == = == - ==== == -= = -- = === = = C e = ee= = ee~ Z see G (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide R-40 2.49E+02 5.26E+01 ---------- ---------- ---------- K-40 CO-57 ---------- ---------- 3.95E+00 1.24E+01 6.41E+00 CO-57 CE-144 ---------- ---------- *2.81E+01 8.96E+01 6.01E+01 CE-144 CE-141 ---------- ---------- 7.32E+00 2.31E+01 1.56E+01 CE-141 RA-226 ---------- ---------- 1.04E+02 3.32E+02 2.20E+02 RA-226 NP-239 ---------- ---------- 9.33E+01 3.OOE+02 2.01E+02 NP-239 SE-75 ---------- ---------- 5.52E+00 1.77E+01 1.20E+01 SE-75 CR-51 ---------- ---------- 3.65E+01 1.18E+02 7.98E+01 CR-51 EU-152 ---------- ---------- 1.26E+01 4.10E+01 2.77E+01 EU-152 1-131 ---------- ---------- 6.15E+00 1.95E+01 1.35E+01 I-131 AG-108M ---------- ---------- 5.20E+00 1.61E+01 1.13E+01 AG-108M BE-7 ---------- ---------- 2.83E+01 9.68E+01 6.52E+01 BE-7 RU-103 ---------- ---------- 4.05E+00 1.37E+01 9.19E+00 RU-103 I-133 ---------- ---------- 9.80E+01 3.19E+02 2.21E+02 I-133 CS-134 ---------- ---------- 4.17E+00 1.36E+01 9.55E+00 CS-134 RU-106 ---------- ---------- 4.92E+01 1.56E+02 1.10E+02 RU-106 CS-137 ---------- ---------- 4.48E+00 1.49E+01 1.02E+0l CS-137 MO-99 ---------- ---------- 9.32E+01 2.97E+02 2.12E+02 MO-99 ZR-95 ---------- ---------- 5.65E+00 1.98E+01 1.36E+01 ZR-95 NE-95 ---------- ---------- 6.34E+00 1.97E+01 1.40E+01 NB-95 CO-58 ---------- ---------- 4.96E+00 1.54E+01 1.13E+01 CO-58 MN-54 ---------- ---------- 4.56E+00 1.51E+01 1.05E+01 MN-54 AG-lOM ---------- ---------- 6.60E+00 2.26E+01 1.51E+01 AG-110M ACTE-228 ---------- ---------- 1.38E+01 4.73E+01 3.28E+01 ACTH-228 I-132 ---------- ---------- 5.08E+01 1.74E+02 1.21E+02 I-132 ZN-65 ---------- ---------- 6.39E+00 2.20E+01 1.61E+01 ZN-65 FE-59 ---------- ---------- 1.07E+01 3.55E+01 2.60E+01 FE-59

CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide

=t==============C= == = =- =-===-=======S==S============== = == == = =

CO-60 ---------- ---------- 1.81E+00 8.01E+00 5.57E+00 CO-60 BALA-140 ---------- ---------- 5.80E+00 l.99E+01 1.45E+01 BALA-140 SB-124 ---------- ---------- 6.19E+00 2.62E+01 1.75E+01 SB-124 TOTAL MEASURED ACTIVITY: 2.49E+02 +- 5.26E+01 pCi/L Results TRANSFERRED to ELMS.

ATTACHMENT 7.12 PAGE IOF I INDIAN POINT SPECIALS ENVIRONMENTAL LABORATORY SAMPLE <WUBMITTAL FORM WEEK # 49 CLIENT CODE 04 SAMPLE CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA DATETME VOLUME ANALYSIS SAMPLE STATION TYPE CODE (UNITS) TYPE ID NUMBER NUMBER FROM TO 2 c., - , . .- _

IP 05-777 MW-38 RR WA 12/8/5 1 GAL H-3 GSA P 05-778 MW-107 RR WA 121815 1 GAL H GSA IP 05-779 MW-105 RR WA 1218/5 1 GAL H-3 GSA IP 05-780 MW-101 RR WA 121815 1 GAL H-3 GSA IP RR WA .GAL H. GSA IP RR WA I GAL H-3 GSA IPRR WA I GAL H-3 GSA IPRR WA I GAL H-3 GSA REMARKS: INDIAN POINT SPECIALS - MONTHLY DEC I 2Q05 RR = Regular Routine

INDIAN POINT STATION NUCLEAR ENVIRONMENTAL MONITORING NEM-5.101 Rev. 15 ATTACHMENT 7.12 PAGE I OF I INDIAN POINT SPECIALS ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM WEEK # _ 49 CLIENT CODE 04 SAMPLE CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA SAMPLE STATION DATE/TIME VOLUME ANALYSIS TYPE CODE (UNITS)

ID NUMBER NUMBER TYPE FROM TO lll____

IP H-3, GB3 14 WATER METER RR WA

_ _. HOUSE GAL GSA BUCHANAN SEWAGE GAL 1-131 IP 97 TREATMENT PLANT RR SL I liter GSA

__(Recirc Tank 1)  :

BUCHANAN SEWAGE . -

IP 98 TREATMENT PLANT RR SL GAL GSA (Holdup Tank 2)

H-3 IP 99 ALGONQUIN OUTFALL RR WA 3 LITERS GSA IP 100 GYPSUM PLANT H-3 RR WA 3 LITERS

_ ___.____ STREAM GSA IP 102 TRAP ROCK QUARRY H1-3 RR WA 3 LITERS GSA IP 05-775 104 GYPSUM PLANT WELL tes, 0 S060 _ 1 RR WA 121615 3 LITERS H-3 GSA IP 05-776 105 GYPSUM PLANT WELL RR 2oor_061 . WA 12615 3 LITERS H-3 GSA

. 3 . . . I REMARKS: INDIAN POINT SPECIALS - MONTHLY RR = Regular Routine 2 DEC 1 M

INDIAN POINT

SUMMARY

SHEET SAMPLE TYPE: MONITORING WELLS REPORTING UNITS IN: pCi/L WEEK 50 i-SOT.0PE,. . - E'.

Be-7 l_ _ _ _ _ _ _ _ _ i <34.87 0I j 05 OP 0 - 78 P <24.4 - -  : _ _ _ _ _

Mn-54 7.5 <3.76 <2.95 Co-58 7.5 <4.52 <2.64 _

Fe-59 15 <1 0.84 <6.8 Co-60 7.5 <4.43 <3.58 Zn-65 15 <5.02 <3.88 Zr-95 7.5 <5.94 <4.16 Nb-95 7.5 <2.06 <3.2 Ru-103 <3.76 <2.95 Ru-106 <31.15 <28.24 1-131 7.5 <5.75 <3.45 Cs-134 7.5 <4.18 <3.04 Cs-137 9.0 <4.07 <2.97 _

BaILa-140 7.5 <5.63 <4.26 Ce-141 <6.4 <5.02 Ce-144 <27.00 <20.20 Ra-226 136.5+/-78.96 129.5+/-56.62 Ac-228 <16.64 <9.04 GROSS BETA NA NA H-3 3000 <454 <454 GSA Results reported as < are CL values

  • Posted CL's correspond to LLD's listed in TS-5.104 (Rev.5) J CL Values Verified By ' A =t e NOTE: The summary data sheet results have been provided to you to facilitate the review ofinalytical results. These summary sheets have not been independently verified and should not be used for the final reporting of data without a second verification.

INDIAN POINT

SUMMARY

SHEET SAMPLE TYPE: MONITORING WELLS REPORTING UNITS IN: 2CiIL WEEK 50 ISOTOPE MIN.; REQ.

GYPSUM PLANTJ GYS

WELL#1 l WL
PLA..NT Ji M3 i os-I j W M-

-1

__:- ____:-:IP O0 -775 - 6 P _ _  : _ _

Be-7 <33.47 <27.85 <21.35 <37.7 K-40 361.9*46.06 <38.68 119+/-32.56 142.1+/-36.96 Mn-54 7.5 c3.34 <3.41 <2.94 <4.64 Co-58 7.5 <4.18 <3.24 <2.51 <2.78 Fe-59 15 <10.38 <9.42 <8.9 <9.83 Co-60 7.5 <4.02 <2.85 <2.99 <4.11 Zn-65 15 <4.94 <9.35 <3.13 <5.8 Zr-95 7.5 <6.1 <6.51 <4.93 <6.93 Nb-95 7.5 <2.83 <3.36 <3.71 <3.87 Ru-1 03 <4.52 <3.76 <3.62 <4.45 Ru-106 <34.08 <27.32 <32.69 <42.89 1-131 7.5 <5.88 <4.74 <4.1 <6.51 Cs-i34 7.5 <3.83 <2.61 <3.26 <4.98 Cs-137 9.0 <4.17 <3.73 <2.93 <2.55 BaJLa-140 7.5 <6.03 <3.98 <3.37 <5.77 Ce-141 _<_ _ c7.63 <5.28 <4.84 <10.52 Ce-144 <30.50 <18.10 <21.60 <42.10 Ra-226 <99.02 <68.1 <72.56 <136 Ac-228 <13.44 <11.9 <8.64 <15.05 GROSS BETA ___ NA NA NA NA H-3 3000 <454 <454 985 +/-146 <454 GSA Results reported as < are CL values (N

  • Posted CL's correspond to LLD's listed in TS-5.104 (Rev.5)

CL Values Verified By NOTE: The summary data sheet results have been provided to you to facilitate the review analytical results. These summary sheets have not been independently verified and should not be used for the final reporting of data without a second verification.

JAF ENVIRONMENTAL LABORATORY Tritium Activitv Calculation Sample ID GYPSUM PLANT WELL I ELMS #: 20054060 Sample On Date/Time: 12/06/0S a 12:00 Client lD No. IP 05-776 Sample Off Date / Time: 1206/oS a 12:00 Run No. 0549 Sample Count Date: 12/14/05 a 12-:00 Sample Distiled: YES Elaped Time "Caltd8 to on dns 0.02 i~cyfactor: _ .9 Background Gross counts: 913.33 Background count time (minutes) 100 Background Counts, CPM: __9.13 Background DPM 26.19 Critical Level (Ct CPM 0.70 Sample Gross counts: 942 Sample Count Time (minutes) 100 Sample CPM: 9.42 Sample Net CPM: 0.29 Sample DPM: 0.70 sample volume (L) 0.004 D2 Background Counting Efficiency 0.356 CL Ratio= 0.41 LLD value (pCi/) ActtError Ratio= 0.6 Sample Counting Efficiency 0.357 Sample Activity (pCVL) +/-1 sigma 79 136 X (p _6

  • sigma
  • _$

21-1--1 112 -

Comments:

Note; If CL ratio is <1.0 OR Act/Error Ratio is <2.7 than the LLD value Is reported as a 'Less Than" Activitv.

Technician: p ;IZ _ Date: 1g/6/2 Supervisor review: B. Gorman gDae:

print /sign p:\tritium program\tritium activity calc.xit

JAI: ENVIRONMENTAL LAB3ORATORY Tritium Activity Calculation___ __

sampie ID GYPSUM PLANT WELL 2 ELMS

  • 2Q054061 Saminle OnDeft/lTime: 125 eS 12:00 Client 10No. IP 06776 Sample Off D~ate I rime: 1VW0M5 a 12:00 Run No. 05-89 Sample Count Date: 12MV~06 a 12:G00 Sample DfstN led: YES

-lpe tl (countf date to oftf dete- 0.02 Decax Factor. 0.9988 Blackground Gross counts: _913.33 Background count time (minutes) _l00 Background Counts, CPM: 9.13 B~ackground DPM 26.19 Gritical LviC)CPM 0.70 Sarnple Gross counts: 949.33333 Sample Count Time (minutes) _100 Sample CPM: 8.49 Sample Net CPM: _0.36 Sample OPM: 0.98 sample volume 10.004 Background Counting Efficiency 0.356 CL Ratio= 0.5t1 LLD value (CJlAct/Ei lor Ratio= 0.8 ample Counting Efficlency 0.356 Sample Activity (pC!/L) :t1 sigma 110 :t 137 Comments:. I Note: If CL ratio is <1.0 OR Act/Error Ratio is c2.7 than the LLD value Is reported as a "Less Than' Activity, Technician: 67 Date: d f Supervisor review: B. Gorman t? /5t2' b , Date: d4r2C

",~print / sign p:\tntium program~ttium activity calc~xt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation sample ID IPEC MW48 ELMS #: 20054062 Sample On Datea Time: 12108/05 o 12:00 Client to No. IP 05-777 Sample Off Date/Trime: 12/08605 a 12:00 Run No. Os Sample Count Date: 12/14(05 a 12:00 Sample Distilled: YES Elapsed Time Lcont date to off 0.02 Deca Factor: 0.9991

E1 Background Gross counts: 913.33 Background count time (minutes) 100 Background Counts, CPM: 9e.3 Background OPM 26.19 Critical Level C0.70 Sample C tross counts: 1228 mple Count Time (minutes) 100 Smple CPM: 12.28 Sapie Net CPM: 3.15 Sample DPM: 8.74 sameoe volumeato s.004 Backgiround Counting Efficiency 0.356 CL Ratfo= 4.48 LLD value (pC/L c454 Act/Efor Rato 6.7 Sample Counting Efficiency 0.357 Sail civity (pCl1L) t 1 sigma f 8 146 Comments:

pn IDsg Note: If CL ratio Is <1.0 OR ActlError Ratio Is <2.7 than the LLD value is reported as a 'Less Than, Activity, Technician: I; >i-tti te: fZ -4 Da--- -c-0 pnn sign p,

SuperviSOr review: B.;omn, /- ,/S ZS C Dat:/ f7 print / sign p:\tritium programutritium activity calc.xlt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-107 ELMS #- 20054063 Sample On Date/ Time: 12/08/05 a 12:00 Client ID No. IP 05-778 Sample Off Date /Time: 12/08/05 a 12:00 Run No. 0589 Sample Count Date: 12/14105 a 12:00 Sample Distilled. YES Elapsed Time (count dat to off dat)s 0.02 gix Deca Factor: 0.9991 Background Gross counts: 913.33 Background count time (minutes) 100 Background Counts, CPM: 9.13 Background DPM 26.19 Critical Level CL CPM 0,70 Sample Gross counts: 953_33333 Sample Count Time (minutes) 100 Sample CPM: g__3 Sample Net CPM: 0.40 Sample DPM: 1.14 sample volume (L) 0.004 Background Counting Efficiency 0.36 CL Ratlo= 0.57 LLD value (pCi/L) f <454> AcVError Ratio= 0.9~

Sample Counting Efficlency 0.356 Sample Activity (pCVL). +/-1 sigma 128 137 Comments:

Note: If CL ratio is c1.0 OR Act/Error Ratio Is <2.7 than the LLD value is reported as a "Less Than" Activity.

Technician: V\ z 7? Date: , -

pripnt Ss!

Supervisor review: S. Gorman a/t/e: (e/)

print Jsign p:tiritium program\tritum activity calcxt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-15 ELMS #: 20054064 SamPle On Date ITime: 12/08105 a 12:00 Client 1D No. IP 0-779 SampleOffDatelTime: 12108105 a 12:00 RunNo. 05-89 Sample Count Date: 12/141W a 12.00 Sample Distilled: YES Ela sed Time coWn date to off dae yr 0.02 Deca Factor: 0.9991

~ ~

Background Gross counts: 913.33 Background count time (minutes) 100 Background Counts, CPM: 9.13 Background DPM 26.19 Critical Level CL) CPM 0.70 Sample Gross counts: 988.66667 Smple Count Time (minutes) 100 Sample CPM: 9.89 Sample Net CPM: 0.76 Smple DPM: 1.92 sa le volume 0.004 Background Counting Efficiency ,i CLRatio 1.07 LL) value (pCVL) C<454 ) ActError Ratio= 1.6 Sample Counting Efficiency 0.358 Sample Activity (pC!/L)t 1 sigma 216 e 137 Comments:

Note: If CL ratio Is <1.0 OR Act/Error Ratio Is <2.7 than the LLD value Is reported as a 'Less Than" Activity.

Technician: vE Z Date: iZ-I6

,_rpdblt gn Supervisor review: B. Gorman Date:

pnrit /sign p:\tritium program\titium activity calc.xit

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID MW-101 ELMS #: 20054065 Sample On Date / Time: 1210815 a 12:00 Client ID No. IP 05-780 Sample Off Date/ Time: 12108105 a 12:00 Run No. 0589 SamPle Count Date: 12114105 o 12:00 Sample Distilled: YES Elapsed Time (count date to off data) yrS 0.02 Deca Factor: 0.9991 Background Gross counts: 913.33 Background count time (minutes) 100 Background Counts, CPM: 9.13 Background DPM 26.19 Critical Level (CL) CPM0.70 Sample Gross counts: 998.33333 Sample Count Time (minutes) 100 Sample CPM: 9.98 Sample Net CPM: 0.85 Sample DPM: 2.39 sample volume (L 0.004 Background Counting EfficIency 0.356cyt0.2 1 LLD value( CVI. AcError Ratio= 1.9 Sample Counting Efficiency 0.356 Sample Activity (pCIIL) +/-1 sigma 269 139 MON~w?.MI-IM" . ,  ;,..1 ME.,

Comments:

Note: If CL ratio Is <1.0 OR Ac/Error Ratio Is <2.7 than the LLD value Is reported as a 'Less Than" Activity.

Technician: PA& _~)5 _ Date: Iz-~ -1 07ln7 sign Supervisor review: B. Gorman Z, sg3n2z1 print Isign p:\tritium program\tritium activity calc.xlt

Spectrum Storage ID #: 20054060GO.SPC Analyzed by sawyer on 12/1212005 12:43i SEEKER G A M MA A N A.L Y S I S R E S U r T 8 version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: GYPSUM WELL #1 Counting Start: 12/12/2005 10:58:18 Lab ID. . . . . . . . . . . . .20054060 Decay, Time. . . . . . . 1.43E+02 Era Client ID . . . . . . . . . . IP 05-775 Sampling Stop . . 12/06/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 Lv Sample Duration . . . . O.OOE+00 Ers Yield . . . . . . . . 1.0000.r Sampling Start. . 12/06/2005 12:00:00 Geometry Code . .. . . . . . 3_0MSO-Live Time (hr:min:sec). . . 001:40:00 Eff. Calib. Date. . 10/13/2005 13:57:48-Real Time (hr:min:sec). . . 001:40:05 Library File. . . . . . . . .MSTER.LIT' REVIEWED SY: _ __ _

Detector #: 2 Energy(kev). -0.03+ 0.500*Ch+ 0.00e+00*Ch^2 + 0.QOe+00*ChA3 12/12/2005 Vt FWEM(keV) - 1.07+ -0.016*En+ 1.68e-03*En^2 + -1.19e-05*En^3 10/07/2005 Where En - Sqrt(Energy in keV)

Eff.-1/[ 7.08e-02*EnA-2.61e+00 + 1.84e+02*EnA 7.74e-01] 10/13/2005 /

CONCENTRATIONs Units: pCi/L

= n u = urn.

= r u== = nnmr unn~.ne m...,. = urn..,... mu un,..... mmu~nni~irn= un nun uun urn.

(1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide 2-40 3.62E+02 4.61E+01 ---------- ---------- ---------- 2-40 Co-57 ---------- ---------- 3.94E+00 1.19E+01 8.13E+00 Co-57 Ce-144 ---------- ---------- 3.05E+01 9.28E+01 6.29E+01 Ce-144 Ce-141 ------ ---------- 7.63E+00 2.34E+01 1.58E+01 Ce-141 Ra-226 ---------- ---------- 9.90E+01 3.04E+02 2.05E+02 Ra-226 Np-239 ----- --- 1.47E+02 4.60E+02 3.08X+02 Np-239 Se-75 ---------- ---------- 4.53E+00 1.42E+01 9.54E+00 So-75 Cr-51 ---------- ---------- 3.73E+01 1.14E+02 7.83E+01 Cr-51 Eu-152 ---------- ---------- 1.18E+01 3.63E+01 2.49E+01 Eu-152 1-131 ---------- --- 5 .88E+00 1.82E+01 1.25E+01 1-131 Ag-108m ---------- ---------- 3.27E+00 1.01E+01 6.99E+00 Ag-108m Be-7 ---------- ------ 3.35E+01 1.05E+02 7.13E+01 Be-7 Ru-103 ---------- ---------- 4.52E+00 1.39E+01 9.61E+00 Ru-103 1-133 ---------- ---------- 4.59E+02 1.43E+03 9.83E+02 1-133 Cs-134 ---------- ---------- 3.83E+00 1.20E+01 8.27E+00 Cs-134 Ru-106 ---------- ---------- 3.41E+01 1.08E+02 7.422+01 Ru-106 Cs-137 ---------- ---------- 4.17E+00 1.28E+01 8.95E+00 Cs-137 Mo-99 ---------- ---------- 1.10E+02 3.41E+02 2.40E+02 Mo-99 Zr-95 ---------- ---------- 6.10E+00 1.93E+01 1.34E+01 Zr-95 Nb-95 ---------- ---------- 2.83E+00 8.61E+00 6.35E+00 Nb-95 Co-58 ---------- ---------- 4.18E+00 1.30E+01 9.03E+00 Co-58 Xn-54 ---------- ---------- 3.34E+00 1.09E+01 7.35E+00 Mn-54 Ag-lOm -------- -------- 4.67E+00 1.50E+01 1.03E+01 Ag-llOm AcTh-228 ---------- ---------- 1.34E+01 4.51E+01 2.94E+01 AcTh-228 1-132 ---------- ---------- 7.49E+01 2.35E+02 1.64E+02 1-132 Page 006

Spectrum Storage ID #s 20054060G0.$PC Analyzed by sawyer on 12/12/2005 12t43:

CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Lese Than LLD Muclide Conc. +- Uncert. Level Conc. Con¢. Conc. Nuclide Zn-65 --------- 4.94Z+00 1.64E+01 1.15E+01 Zn-65 Fe-59 ---------- ---------- 1.04E+01 3.30E+01 2.31E+01 Fe-59 Co-60 ---------- ---------- 4.02E+00 1.31E+01 8.97E+00 Co-60 BaLa-140 ---------- ---------- 6.03E+00 1.95E+01 1.36E+01 BaLa-140 Sb-124 ---------- ---------- 9.42E+00 3.02E+01 2.13E+01 Sb-124 TOTAL MEASURED ACTIVITY: 3.62E+02 +- 4.61E+01 pCi/L Error in Results Transfer to ELMS.

Page 007

Spectrum Storage ID #s 20054061G0.SPC Analyzed by sawyer on 12/12/2005 13:271 SEEKER G A X X A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: GYPSUM WELL #3 Counting Start: 12/12/2005 10s58:37 Lab ID. . . . . . . . . . . . .20054061 Decay Time. . . . . . . 1.43E+02 Ers Client ID . . . . . . . . . . IP 05-776 Sampling Stop . . 12/06/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L-Sample Duration . . . . 0.00Z+00 Bra Yield . . . . . . . . . . . . . 1.0000/

Sampling Start. . 12/06/2005 12:00:00 Geometry Code . . . . . . . . . 3_-01S0 Live Time (hr:minssec). . . 002:13:20 Eff. Calib. Date. . 10/12/2005 09:18:44, Real Time (hr:minssec). . . 002:13:26 Library File. . . . . . . . .KASTER.LIBJ REVIEWED BY: _ _ _ _- _ _

Detector #: 7 '0/

Energy(keV)m -0.49+ 0.500*Ch+ 0.OOe+00*Ch42 + 0.00e00*ChA3 12/12/2005 FWHM(keV) = 0.63+ 0.017*En+ 5.30e-04*EnA2 + 0.OOe+00*EnA3 09/27/2005 V Where En

  • Sqrt(Energy in keV)

Eff.-l/E 7.48e-02*En^-2.83e+00 + 3.77e+02*EnA 8.82e-01 10/12/2005 J CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide CO-57 --- 2.13E+00 6.81E+00 4.57E+00 CO-57 Ce-144 ---------- ---------- 1.81E+01 5.64E+01 3.85E+01 Ce-144 Ce-141 ---------- ------- 5.28E+00 1.64E+01 1.12E+01 Co-141 Ra-226 ---------- ---------- 6.81E+01 2.181+02 1.45E+02 Ra-226 Np-239 ---------- ---------- 1.18E+02 3.68E+02 2.54E+02 Np-239 So-75 ---------- ---------- 3.44E+00 1.11E+01 7.511+00 Se-75 Cr-51 - --- ^-- 2.51E+01 8.13E+01 5.52E+01 Cr-51 Eu-152 ---------- ---------- 1.07E+01 3.33E+01 2.31E+01 Eu-152 1-131 ---------- ---------- 4.74E+00 1.53E+01 1.05E+01 1-131 Ag-108m ---------- ---------- 2.57E+00 8.33E+00 5.76E+00 Ag-108m Be-7 ---------- ---------- 2.79E+01 8.85E+01 6.19E+01 Be-7 Ru-103 ---------- ---------- 3.76S+00 1.21E+01 8.32E+00 Ru-103 1-133 ---------- ---------- 3.08E+02 1.061+03 7.08E+02 1-133 Cs-134 ---------- ---------- 2.61E+00 8.47E+00 5.98E+00 Cs-134 Ru-106 ---------- ----- 2.73E+01 9.18E+01 6.35E+01 Ru-106 Cs-137 ---------- ---------- 3.73E+00 1.19E+01 8.35+00 Cs-137 Mo-99 ---------- ---------- 1.02E+02 3.42E+02 2.34E+02 Mo-99 Zr-95 ---------- ---------- 6.51E+00 2.08E+01 1.481+01 Zr-95 Nb-95 ---------- ---------- 3.36E+00 1.13E+01 7.731+00 Nb-95 Co-58 ----- ---------- 3.24E+00 1.03E+01 7.49E+00 Co-58 Mn-§4 --------- ------ 3.41E+00 1.12E+01 7.82E+00 Mn-54 Ag-hOrm ---------- ---------- 4.47E+00 1.51E+01 1.04E+01 Ag-llOm AcTh-228 ---------- ---------- 1.19E+01 4.18E+01 2.76E+01 AcTh-228 1-132 ---------- ---------- 7.29E+01 2.39E+02 1.68E+02 1-132 Zn-65 ---------- ---------- 9.35E+00 2.93E+01 2.12E+01 Zn-65 Page 006

Spectrum Storage ID #: 20054061GO.SPC Analyzed by sawyer on 12/12/2005 13:27:

CONCENTRATIONs Units; pCi/L (1.00 Sigma) Critical Less Than LLD Nuclide Cone. +- Uncert. Level Cone. Cone. Cone. Nuclide Fe-59 -- --- 9.42E+00 3.19E+01 2.25E+01 Fe-59 Co-60 ---------- ---------- 2.85E+00 1.03E+01 7.18E+00 Co-60 K-40 ---------- ---------- 3.87E+01 1.49E+02 9.23E+01 R-40 BaLa-140 ---------- ---------- 3.97E+00 1.59E+01 1.05E+01 BaLa-140 Sb-124 ---------- ---------- 1.22E+01 3.95E+01 2.85E+01 Sb-124 TOTAL MEASURED ACTIVITY: O.OOE+00 +- O.OOE+00 pCi/L Error in Results Transfer to ELMS.

Eage 007

Spectrum Storage ID #: 20054062GO.SPC Analyzed by sawyer on 12/12/2005 12s37:

SEERER G A M M A A NA L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Envirowmental Lab Sample DESCRIPTION: MW-38 Counting Start: 12/12/2005 11:11:57 Lab ID. . . . . . . . . . . . .20054062 Decay Time. . . . . . . 9.52E+01 Era Client ID . . . . . . . . . . IP 05-777 Sampling Stop . . 12/08/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 Lf Sample Duration . . . . O.OOE+00 Era Yield . . . . . . . . . . . . . 1.0000' Sampling Start. . 12/08/2005 12:00:00 Geometry Code . . . . . . . . . 3_OMSOG Live Time (hr:min:sec). . . 001:23:20 Eff. Calib. Date. . 09/27/2005 13:14:16f Real Time (hr:min:sec). . . 001:23:22 Library File. . . . . . . . .MASTER.LIV' REVIEWED 8Ys_

Detector #s 3 Eneray(keV)= -0.46+ 0.500*Ch+ 0.00e+00*Ch^2 + 0.O0e+OO*Ch^3 12/12/2005 V FWUM(keV) a 0.84+ 0.011*En+ 4.55e-04*EnA2 + 0.OOe+00*EnA3 09/27/2005 V Where En = Sqrt(Energy in keV)

Eff.=/1[ 7.51e-02*En4-2.55e+00 + 1.76e+02*EnA 7.65e-01 09/27/2005 7 CONCENTRATIONs Units: pCi/L m.= = m m== mum= mmuuummu= mu::sx:m:c. smu mum.....

= e msmmc=a:a~smmma mummmm.. u.mnm= m (1.00 Sigma) Critical Less Than LLD Nuclide Cone. +- Uncert. Level Con¢. Conc. Conc. Nuclide E-40 l.19E+02 3.26E+01 ---------- ---------- ---------- R-40 CO-57 ---- ---------- 2.81E+00 8.67E+00 5.91E+00 CO-57 CE-144 ---------- ---------- 2.16E+01 6.68E+01 4.54E+01 CE-144 CE-141 ---------- ---------- 4.84E+00 1.525401 1.02E+01 CE-141 RA-226 --------- --- 7.26E+01 2.29E+02 1.53E+02 RA-226 NP-239 ---------- - - 6.76E+01 2.17E+02 1.44E+02 NP-239 SE-75 ---------- ---------- 4.35E+00 1.33E+01 9.26E+00 SE-75 CR-51 ---------- --------- 2.36E+01 7.50E+01 5.13E+01 CR-51 EU-152 ---------- ---------- 7.34E+00 2.42E+01 1.61E+01 EU-152 1-131 ---------- ---------- 4.10E+00 1.29E+01 8.90E+00 1-131 AG-108M ---------- ---------- 2.35E+00 7.85E+00 5.21E+00 AG-108M BE-7 ---------- ---------- 2.14E+01 6.84E+01 4.77E+01 BE-7 RU-103 ---------- ---------- 3.62E+00 1.11E+01 7.86E+00 RU-103 1-133 ---------- ---------- 6.32E+01 2.02E+02 1.41E+02 1-133 CS-134 ---------- ---------- 3.26E+00 1.04E+01 7.22E+00 CS-134 RU-106 ---------- ---------- 3.27E+01 1.04E+02 7.23E+01 RU-106 CS-137 ---------- ---------- 2.93E+00 9.42E+00 6.57E+00 CS-137 MO-99 ---------- ---------- 6.72E+01 2.05E+02 1.49E+02 MO-99 ZR-95 ---------- ---------- 4.93E+00 1.62E+01 1.12E+01 ZR-95 NB-95 ---------- ---------- 3.71E+00 1.15E+01 8.19E+00 NB-95 CO-58 ---------- ---------- 2.51E+00 8.11E+00 5.79E+00 CO-58 MN-54 ---------- -- 2.94E+00 9.52E+00 6.64E+00 Ml-54 AG-llOM ---------- ---------- 3.75E+00 1.23E+01 8.59E+00 AG-llOM ACTH-228 ---------- ---------- 8.64E+00 3.08E+01 2.02E+01 ACTE-228 1-132 ---------- ---------- 3.81E+01 1.25E+02 8.69E+01 X-132 Page 006

Spectrum Storage ID 0: 20054062G0.SPC Analyzed by sawyer on 12/12/2005 12:37i CONCENTRATIONs Units: pCi/L (1.00 sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide ZN-65 --- 3.13E+00 1.22E+01 8.13E+00 ZN-65 FE-59 ---- 8.90E+00 2.79E+01 2.04E+01 FE-59 CO-60 ------ - ---- 2.99E+00 1.01E+01 7.06E+00 CO-60 BA-140 ---------- ---------- 3.37E+00 1.21E+01 8.33E+00 BALA-140 SB-124 ------ ---------- 7.12E+00 2.36E+01 1.70E+01 SB-124 TOTAL MEASURED ACTIVITY: 1.19E+02 +- 3.26E+01 pCi/L Results TRANSFERRED to ELKS.

Page 007

SEEKER G A XM A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: MW-107 Counting Start: 12/12/2005 13:59:09 Lab ID. . . . . . . . . . . . .20054063 Decay Time. . . . . . . 9.80E+01 Brs Client ID . . . . . . . . . . IP 05-778 Sampling Stop . . 12/08/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L Sample Duration . . . . O.QOE+00 Brs Yield . . . . . . . . . . . . . l.000O/

Sampling Start. . 12/08/2005 12:00:00 Geometry Code . . . . . 3_OMSO' Live Time (hrsmin:sec). . . 002:00:05 Eff. Calib. Date. . 09/27/2005 09:07:02' Real Time (hr:mintsec). . . 002:00:11 Library File. . . . . . . . .MASTER.LIE/

REVIEWED BY: r -

- Detector #: 1 Energy(keV)m -0.20+ 0.500*Ch+ 0.OOe+00*Ch42 + 0.OOe+OO*Ch^3 12/12/2005 J1 FWEM(keV) a 0.90+ 0.013*En+ 3.85e-04*EnA2 + 0.OOoe+00EnA3 10/07/2005 Where En w Sqrt(ExLergy in keV)

Eff.=1/[ 4.93e-02*En4-2.90e+00 + 1.79e+02*En^ 7.60e-0l1 09/27/2005 J CONCENTRATIONs UnitE: pCi/L mum... mm.-mum...,, m=m..,., emsm .:emuc mum.uumucmm......mumc,_., m-m..e mum mu (1. 00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide E-40 1.42E+02 3.70E+01 ---------- ---------- ---------- K-40 CO-57 ----- ---- 5.77E+00 1.76E+01 1.18E+01 CO-57 CE-144 ---------- ---------- 4.21E+01 1.29E+02 8.59E+01 CE-144 CE-141 ---------- ---------- 1.05E+01 3.21E+01 2.15E+01 CE-141 RA-226 ---------- ---------- 1.36E+02 4.16E+02 2.78E+02 RA-226 NP-239 ---------- ---------- 1.22E+02 3.77E+02 2.52E+02 NP-239 SE-75 ---------- --- 6.50E+00 1.98E+01 1.34E+01 SE-75 CR-51 ---------- ---------- 4.38E+01 1.34E+02 9.05E+01 CR-51 EU-152 ---------- ---------- 1.52E+01 4.70E+0i 3.14E+01 EU-152 X-131 ---------- ---------- 6.51E+00 1.97E+01 1.35E+01 1-131 AG-108S ---------- ---------- 4.45E+00 1.36E+01 9.26E+00 AG-108M BE-7 ---------- ---------- 3.77E+01 1.16E+02 7.89E+01 BE-7 RU-103 ---------- ---------- 4.45E+00 1.38E+01 9.34E+00 RU-103 1-133 ---------- ---------- 1.27E+02 3.90E+02 2.655+02 X-133 CS-134 ---------- ---------- 4.98E+00 1.56E+01 1.04E+01 CS-134 RU-106 ------- ----- 4.29E+01 1.33E+02 9.07E+01 RU-106 CS-137 ---------- ---------- 2.55E+00 8.25E+00 5.59E+00 CS-137 MO-99 ---------- ---------- 9.20E+01 2.84E+02 1.95E+02 30-99 ZR-95 ---------- ---------- 6.93E+00 2.16E+01 1.48E+01 ZR-95 NB-95 ---------- ---------- 3.87E+00 1.16E+01 8.27E+00 NB-95 Co-58 ---- -- 2.78E+00 8.65E+00 6.11E+00 CO-58 NN-54 ---------- ---------- 4.64E+00 1.42E+01 9.81E+00 1N-54 AG-110M ---------- ---------- 6.14E+00 1.91E+01 1.31E+01 AG-110M ACTE-228 ---------- ---------- 1.51E+01 4.81E+01 3.22E+01 ACTE-228 1-132 ---------- ---------- 5.53E+01 1.76E+02 1.18E+02 1-132 ZN-65 ---------- ---------- 5.80E+00 1.88E+01 1.29E+01 ZN-65 FE-59 ---------- ---------- 9.83E+00 3.12E+01 2.15E+01 FE-59

CONCENTRATZONs Units: pCi/L (1.00 sigma) Critical Less Than LLD Ruclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide CO-60 ----- - ---- 4.llE+QO 1.33E+01 8.97E+00 CO-60 BALA-140 ---------- ---------- 5.77E+O0 1.92E+01 1.27E+O1 BALA-140 S0-124 ---------- ---------- 8.13E+00 2.66E+01 1.82E+01 S3-124 TOTAL MEASURED ACTIVITY; 1.42E+02 +- 3.70E+O1 pCi/L Results TRANSFERRED to ELKS.

Spectrum Storage ID #: 20054064G0.SPC Analyzed by sawyer on 12/12/2005 13:54t

  • mum. *uu~ec~wu U. sum e mum mm mu
XS-- -ccacw=em-e-SEEIER G A M M A A N A L Y S I S R X S V L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: KW-105 Counting Start: 12/12/2005 11:52:15 Lab ID. . . . . . . . . . . . .20054064 Decay Time. . . . . . . 9.59E+01 Ers Client ID . . . . . . . . . . IP 05-779 Samling Stop . . 12/08/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L Sample Duration . . . . O.OOE+00 Era Yield . . . . . . . . . . . . . 1.0000k Sampling Start.
  • 12/08/2005 12:00:00 Geometry Code . . . . . . . . . 3_0M SO 1 Live Time (hrsmin:sec). . . ool:56:40 Eff. Calib. Date. . 10/17/2005 14:20:15/

Real Time (hrtmintsec). . . 001%56:43 Library File. . . . . . .. . MASTER.LIB'

+EVIEWED BY:_______________

Detector Energy(keV)m 0.30+ 0.500*Ch+ 0.00e+OCI*ChA2 + 0.O0e+00*ChA3 12/12/2005J FWMM(keV) - 0.73+ 0.003*En+ 9.45e-04*En^2 + -7.44e-06*EnA3 09/27/2005 Where En = Sqrt(Energy in key)

Eff.=-/1 5.91e-02*En^-2.90e+00 + 2.81e+02*En^ 8.17e-01] 10/17/2005 CONCENTRATIONs Units: pCi/L mumem mmmhmmina u mmmmmmm Umum... am.. mu- . mm, umumam. in..e mmumz mum.. in.... m (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Cone. Conc. Nuclide RA-226 1.36E+02 7.90E+01 ---------- ---------- ---------- RA-226 Co-57 ---------- ---------- 3.50E+00 1.09E+01 7.31E+00 Co-57 Ce-144 ---------- ---------- 2.70E+01 8.31E+01 5.64E+01 Ce-144 Ce-141 - -------- 6.40E+00 1.97E+01 1.34E+01 Ce-141 Np-239 ---------- ---------- 9.38E+01 2.88E+02 1.97E+02 Np-239 Se-75 ---------- --- 5.32E+00 1.64E+01 1.12Z*01 Se-75 Cr-S1 ---------- ---------- 3.24E+01 1.02E+02 6.91E+01 Cr-51 Eu-152 ---------- ---------- 1.07E+01 3.39E+01 2.29E+01 Eu-152 1-131 ---------- ---------- 5.75E+00 1.79E+01 1.22E+01 1-131 Ag-lQsm ---------- ---------- 4.34E+00 1.31E+01 9.24E+00 Ag-108m Be-7 ------ --------- 3.49E+01 1.08E+02 7.52E+01 Be-7 Ru-103 ---------- ------ 3.76E+00 1.18E+01 8.20E+00 Ru-103 1-133 ---------- ---------- 8.90E+01 2.83E+02 1.95E+02 1-133 Cs-134 ---------- ---------- 4.18E+00 1.31E+01 9.12E+00 Cs-134 Ru-106 ---------- ---------- 3.11E+01 1.04E+02 7.OOE+01 Ru-106 Cs-137 ---------- ---------- 4.07E+00 1.28E+01 8.91E+00 Cs-137 Mo-99 ---------- ---------- 6.81E+01 2.20E+02 1.53E+02 Mo-99 Zr-95 ---------- ---------- 5.94E+00 1.91E+01 1.34E+01 Zr-95 Nb-95 ---------- ---------- 2.06E+00 6.79E+00 4.98E+00 Nb-95 Co-58 ---------- ---------- 4.52E+00 1.38E+01 9.90E+00 Co-58 Kn-54 ---------- ---------- 3.76E+00 1.22E+01 8.37E+00 Kn-54 Ag-ilbm ---------- ---------- 4.92E+00 1.67E+01 1.11E+01 Ag-110n AcTh-228 ---------- ---------- 1.66E+01 5.30E+01 3.66E+01 AcTh-228 1-132 ---------- ---------- 3.84E+01 1.33E+02 8.90E+01 1-132 Zn-65 __________ __________

5.01E+00 1.70E+01 1.22E+01 Zn-65 Page 006

Spectrum Storage ID #: 20054064GO.SPC Analyzed by sawyer on 12/12/2005 13:54:

CONCENTRATIONs Units:S Ci/L (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Cone. ConC. Conc. Nuclide Fe-59 ---------- ---------- 1.08E+01 3.45E+01 2.46E+01 Fe-59 Co-6Q ---------- ---------- 4.43E+00 1.44E+01 1.01E+01 Co-60 1-40 ---------- ---------- 4.46E+01 1.63E+02 1.02E+02 1-40 Sa&L-140 ---------- ---------- 5.63E+00 1.87E+01 1.31E+01 BaLa-140 Sb-124 ---------- --- 6.20E+00 2.32E+01 1.56E+01 Sb-124 TOTAL MEASURED ACTIVITY: 1.36E+02 +- 7.90E+01 pCi/L Error in Results Transfer to ELMS.

Page 007

Spectrum Storage ID #: 20054065GO.SPC Analyzed by sawyer on 12/12/2005 12:52:

SEEKER G A Y M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: MW-101 Counting Start: 12/12/2005 11:26:l8 Lab ID. . . . . . . . . . . . .20054065 Decay Time. . . . . . . 9.54E+01 Ers Client ID . . . . . . . . . . IP 05-780 Sampling Stop . . 12/08/2005 12:00:00 Sample Size . . . . . . . . 3.OOe+00 Lf Sample Duration . . . . 0.QOE+00 Brs Yield . . . . . . . . . . . . . 1.0000/

Sampling Start. . 12/08/2005 12:OOsOO Geometry Code . . . . . . . . . 3_ONSOr Live Time (hr:min:sec). . . 001:23:20 Eff. Calib. Date. . 10/13/2005 13:05:49' Real Time (hr:min:see). . . 001:23:24 Library File... . . . . . . .XASTER.LIE, REVIEWED BY:__

Detector #s 8 Eneray(keV)= 0.17+ 0.500*Ch+ 0.OOe+00*ChA2 + 0.OOe+00*Ch^3 12/12/2005 /

FWKM(keV) = 0.80+ 0.008*En+ 6.4le-04*En42 + 0.00e+00*EnA3 09/27/2005 Where En = Sqrt(Energy in key)

Eff.ml/[ 2.28e-01*EnA-2.04e+00 + 1.71e+02*EnA 7.76e-01] 10/13/2005 CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Les Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide mam am amaaammamma am am a = mamma mama==wS=e:==

em-eamma =- a m-mmacmama mama am RA-226 1.30E+02 5.6 66E+01 RA-226 K-40 1.20E+02 2.82E+01 __________ -_________

K-40 CO-57 __________ __________

2.48E+00 7.77E+00 5.26E+00 CO-57 CE-144 2.02E+01 6.20E+01 4.26E+01 CE-144 CE-141 5.02E+00 1.57E+01 1.06E+01 CE-141 NP-239 7.53E+01 2 .31E+02 1.59E+02 N1-239 SE-75 3.36E+00 1. 08E+01 7.25E+00 SE-75 CR-51 2.81E+01 8.64E+01 6.03E+01 CR-S1 EU-152 7.76E+00 2.41E+01 1.69E+01 EU-152 1-131 3.45E+00 1.07E+01 7.58E+00 1-131 AG-108SM 2.42E+00 7.92E+00 5.34E+00 AG-108M BE-7 2.44E+01 7.68E+01 5.36E+01 BE-7 RU-103 2.95E+00 9.50E+00 6.50E+00 RU-103 1-133 7.10E+0l 2.25E+02 1.57E+02 1-133 CS-134 3.04E+00 9.69E+00 6.76E+00 CS-134 RU-106 2.82E+01 8.88E+01 6.32E+01 RU-106 CS-137 2.97E+00 9.40E400 6.62E+00 CS-137 MO-99 4.80E+01 1.61E+02 1.1OE+02 MO-99 ZR-95 4.16E+00 1.41E+0l 9.59E+00 ZR-95 NB-95 3.20E+00 1.04E+O1 7.14E+00 NB-95 re- _. a n &-qPAA a - ------ ^

Speotrunm Storage ID #: 20054065G0.SPC Analyzed by saiwyer on 12/12/2005 1252:

CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- uncert. Level Conc. Cone. CoLC. Nuclide ZN-s- ---------- ---------- 3.88Z+00 1.31E+01 9.56E+00 ZN-65 FE-59 ---------- ---------- 6.80m+00 2.29E401 1.61E+01 FE-59 CO-60 -- - 3.58E+00 1.12E+01 8.20E+00 CO-60 BALA-140 ------- --------- 4.26E+00 l.45E+01 1.01E+01 BALhA-140 SB-124 ---------- ---------- 7.34E+00 2.37E+01 1.74E+01 8B-124 TOTAL MEASURED ACTIVITY: 2.49E402 +- 8.48E+01 pCi/L Results TRANSFERED to ELMS.

Page 007

ATTACHMENT 7.6 PAGE1 OFI DRINKING WATER (MONTHLY)

ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM WEEK # 48 CLIENT CODE 04 CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA SAMPLE VOLUME ANALYSIS SAMPLE STATION TYPE CODE DATE (UNITS) TYPE ID NUMBER NUMBER 1-131 IP 07 CAMP FIELD TS WA 2 GSA RESERVOIR _gal GB 1-131 IP 08 CROTON RESERVOIR RR WA 2 GSA

_ _ __ _ _ . gal GB 1-131 IP 85 AMICUS RR WA 2 GSA RESERVOIR gal GB IP 05-750 5THSTREET WELL RR WA 11/30/5 3 GSA NC1 LITERS H3 H-3 IP U3-4 RR WA 1 GSA LITER REMARKS: MONTHLY SAMPLES - DRINKING WATER TS = TECH SPECS RR REGULAR ROUTINE

ATTACHMENT 7.12 PAGEI OFI INDIAN POINT SPECIALS ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM WEEK# 48 CUENT CODE 04 SAMPLE CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA DATEITIME VOLUME ANALYSIS SAMPLE STATION TYPE CODE (UNITS) TYPE ID NUMBER -NUMBER FROM TO H-3,GB IP 14 WATER METER RR WA GAL GSA "OUSE . 1-131 BUCHANAN SEWAGE IP 97 TREATMENT PLANT RR SL lifter GSA

. . (Recire Tank t BUCHANAN SEWAGE IP 98 TREATMENT PLANT RR SLGAL GSA (Holdup Tank 2)GA 7y?11-3 IP 05 44 ALGONQUIN OUTFALL RR WA 11/30/5 3 LITERS GSA 9~9f. 9~ H-3 IP 05-748 GYPSUM PLANT RR WA 11/30/5 3 LITERS GSA

_____STREAM .

2 6705356 H-3 IP 05-749 TRAP ROCK QUARRY RR WA 1113015 3 LITERS GSA IP 104 GYPSUM PLANT WELL RR WA GAL 1-3 GSA GB IP 105 GYPSUM PLANT WELL SPECIAL WA GAL "-3 GSA GB I PARKING LOT .

REMARKS: INDIAN POINT SPECIALS - MONTHLY RR = Regular Routine

INDIAN POINT

SUMMARY

SHEET SAMPLE TYPE: Special Waters REPORTING UNITS IN: pCUL Nov-05 W?.WE - .IJT Moop A L MM R:A 8e-7 <2924 <29.4 <16.93 <27.40 K-40 196.6*45.26 217+/-42.03 95.15+/-27.81 135 +/-31.0 Mn-64 <4.21 <3.13 <2 <2.76 Co-58 <4.33 <2.97 <2.69 <3.40 Fe-59 <9.76 <8.71 <5.43 <8.85 Co-60 (7.5*) <4.54 <3.67 <2.2 <2.59 Zn-65 <10.63 <4.97 c5.56 <3.86 Zr-95 <6.27 <6.77 <3.42 <5,20 Nb-95 <3.7 <3.57 <2.43 <4.40 Ru-103 <3.56 <3.56 <3.24 <3.06 Ru-106 <33.64 <26.42 <26.9 <33.50 1-131 _ <6.51 <5.79 <3.59 <4.92 Cs-134 (7.5*) <3.59 <3.3 <2.99 <2.98 Cs-1S7 (9.0*) <3.38 <327 <2.01 <3.15 Bs/La-140 <4.69 <6.1 <5.01 <4.84 Co-t41 <6.05 <5.74 <3.99 <5.68 Ce-44 <21.50 <20.20 <15.60 <21.30 Ra-226 <78.33 <71.26 159.6+/-50.33 <76.60 Ac-228 <13.71 <12.39 <10.55 <9.35 GROSS BETA NA NA NA NA H-3 -_ <464 <464 <464 <464 Results reported as < are CL values

  • Posted CL's correspond to LLD's listed In TS-5.104 (RevJ6)

CL Values Verified a NOTE: The summary data sheet results have been provided to you to facilitate the review of analytical results. These summary sheets have not been Independently verified and should not be used for the fInal reporting of data without a second verification.

Spectrum Storage ID #s 20053959G0.SPC Analyzed by sayer oa 12/0612005 12:52s:

S3XER G A Y Y A A NA L Y 8 I 8 R E8 V L TS Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab muwu Ummuuuu ummuma m..-mmm.." s".mu.. mamumm.. um.., . m.m... m.mum m.USinUm.".

Sample DESCRIPTION: ALGONQUIN OUTFALL Counting Starts 12/06/2005 11:09s12 Lab ID. . . . . . . . . . . . .20053959/

Decay Tie. . . . . . . 1.43Z+02 Hrs Client ID . . . . . . . . . . IT 05-747k Sampling Stop . . 11/30/2005 12:00sOOk Sample Size . . . . . . . . 3.00+OO L Sample Duration . . . . 0.00Z+00 Era Yield . . . . . . . . . . . . . 1.0000 Sampling Start. . 11/30/2005 12sOOsOO Geometry Code . . . . 3_0YSO0 Live Time (hrtamintse). . . 00123s20 3ff. Calib. Dat. .\10/17/2003 14:20:15' Real Time (hrsmin:sec). . . 001:23s22 Library File. . . . . .MABTZR.LI9" RVIED BY:_ _

Detector #t 4 Energy(kaV)w 0.30+ 0.500*Ch+ 0.00-+OO*ChA2 + 0.OO+0O*ChA3 12/06/2005 FWU(keV) - 0.73+ 0.003*Zn+ 9.45e-04*ZnA2 + -7.44e-06G*nA3 09/27/2005 Where En n Sqrt(Emergy in keV)

Eff.-lIC 5.91e-02*EnA-2.90*+00 + 2.81-+02*knA 8.17*-Oll 1017/2005 CONCENTRATION* Unitst pCi/L

.m.m.mmn.m.m m.mmm.m.mn.m m.mm.m m.m ... mm........ .......................m........ --..-m----

(1.00 Sigma) Critical Loes Than LLD Nuclide Cone. +- Uncert. Level Cone. Cone. Cone. Nuclide

  • .Um-"----.mfinmi..m.iU.Um.u.m.u..m.um...mu.mummmuubmmuumuU" n - -

3-40 1.973+02 4.533X+01 ---------- ---------- ---------- 3-40 CO-57 ---------- ---------- 2.87X+00 9.253+00 6.193+00 CO-57 CE-144 ---------- ---------- 2.153+01 6.803+01 4.653+01 C3-144 CE-141 ---------- ---------- 6.05S+00 1.90Z301 1.293401 C3-141 RA-226 ---------- ---------- 7.833+01 2.50Z402 1.68Z+02 RA-226 3P-239 ---------- ---------- 1.41X+02 4.453+02 3.06X+02 31-239 83-75 ----- --- 4.59-+00 1.453+01 1.003+01 53-75 CR-S1 ---------- ---------- 2.873+01 9.393+01 6.39X+01 CR-51 EU-152 ---------- ---------- 1.01Z+01 3.25X+01 2.253X01 ZV-152 X-131 ---------- ---------- 6.513+00 2.053+01 1.433+01 1-131 AO-108Y ---------- ---------- 2.373+00 8.353+00 5.513+00 AG-108l B3-7 ---------- ---------- 2.923+01 9.573+01 6.633+01 33-7 RU-103 ---------- ---------- 3.563+00 1.213401 8.123+00 RU-103 I-133 ---------- ---------- 3.213+02 1.123+03 7.563+02 X-133 CS-134 ---------- ---------- 3.593+00 1.183+01 8.25S+00 CS-134 RU-106 ---------- ---------- 3.36Z+01 1.103+02 7.813+01 RU-106 C8-137 ---------- ---------- 3.383+00 1.10Z+01 7.843+00 I8-137 30-99 ---------- ---------- 1.133+02 3.723+02 2.643+02 30-99 ZR-95 ---------- ---------- 6.273+00 2.123+01 1.463+01 ZR-95 33-95 ---------- ---------- 3.703+00 1.25X+01 8.653+00 -D-95 CO-58 ---------- ---------- 4.333+00 1.383+01 9.90Z+00 CO-58 M3-54 ------ - ---------- 4.213+00 1.333+01 9.633+00 M3-54 AG-lIOw ---------- --- 5.653+00 1.853+01 1.303+01 AG-LION ACTE-228 ---------- ---------- 1.373+01 4.623+01 3.203+01 ACTE-228 X-132 ---------- ---------- 6.953+01 2.25Z+02 1.65Z+02 1-132 Page 006

Spectrum Storage ID *: 20053959G0.SPC Analyzed by mayor on 12/06/2005 12t52::

CO"CITaXIONs Unitst pCi/L (1.00 Sigma) Critical Loon Than LLD Nuclide Cone. +- Uncert. Level Cone. Cone. Cone. Ruclid.

33-65 ---------- ---------- 1.06x+01 3.24X+01 2.431+01 ZN-65 11-59 ---------- ---------- 9.763+00 3.39X+01 2.38x+01 11-59 CO-60 ---------- ---------- 4.533+00 1.323+01 1.083+01 CO-60 BALA-140 ---------- ---------- .691+00 1.71x+01 1.23x+01 ZALA-140 SB-124 ---------- ---------- 6.883+00 2.77x+01 1.84x+01 8B-124 TOTAL IMBUMRD kCTIVmTYs 1.97Z402 +- 4.531+01 pCi/L Xesults TRANSrzRRED to zLMs.

lag* 007

Spectrum Storage ID #: 20053960G0.SPC Analyzed by sayer on 12/06/2005 14:55:04 SEEKER G A M M A A N A L Y S I S R E S U L T S Version 2.3.0 Entergy Nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTION: gypsum plant stream Counting Start: 12/06/2005 11:09:51 Lab ID. . . . . . . . . . . . .20053960 Decay Time. . . . . . . 1.43E+02 Hrs Client ID . . . . . . . . . . IP 05-748 Sampling Stop . . 11/30/2005 12:00:00 Sample Size . . . . . . . . 3.00e+00 L/'

Sample Duration . . . . O.OOE+00 Hrs Yield . . . . . . . . . . . . . 1.0000' Sampling Start. . 11/30/2005 12:00:00 Geometry Code . . . . . . . . .3-OMSO' Live Time (hr:min:sec). . . 002:46:40 Eff. Calib. Date. . 10/12/2005 09:18:44/

Real Time (hr:min:sec). . . 002:46:43 Library File. . . . . . . . .MASTER.LIB' REVIEWED B:

Detector #: 7 Energy(keV)= -0.50+ 0.500*Ch+ 0.00e+00*Ch +0 3 12/06/2005 V FWHM(keV) = 0.63+ 0.017*En+ 5.30e-04*En^2 + 0.00e+00*En^3 09/27/2005 /

Where En = Sqrt(Energy in keV)

Eff.=l/1 7.48e-02*En^-2.83e+00 + 3.77e+02*En^ 8.82e-01] 10/12/2005 CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide K-40 2.17E+02 4.20E+01 ----------- ---------- ---------- K-40 Co-57 ---------- ---------- 2.67E+00 8.24E+00 5.59E+00 Co-57 Ce-144 ---------- ---------- 2.02E+01 6.17E+01 4.23E+01 Ce-144 Ce-141 ---------- ---------- 5.74E+00 1.77E+01 1.20E+01 Ce-141 Ra-226 ---------- ---------- 7.13E+01 2.28E+02 1.50E+02 Ra-226 Np-239 ---------- ---------- 1.20E+02 3.73E+02 2.55E+02 Np-239 Se-75 ---------- ---------- 3.96E+00 1.24E+01 8.43E+00 Se-75 Cr-51 ---------- ---------- 3.OOE+01 9.56E+01 6.39E+01 Cr-51 Eu-152 ---------- ---------- 1.l1E+01 3.38E+01 2.35E+01 Eu-152 I-131 ---------- ---------- 5.79E+00 1.8OE+0l 1.24E+0l 1-131 Ag-108m ---------- ---------- 2.73E+00 8.59E+00 5.95E+00 Ag-108m Be-7 ---------- ---------- 2.94E+01 9.08E+01 6.38E+01 Be-7 Ru-103 ---------- ---------- 3.56E+00 1.12E+01 7.76E+00 Ru-103 1-133 ---------- ---------- 3.48E+02 1.13E+03 7.71E+02 1-133 Cs-134 ---------- ---------- 3.30E+00 1.02E+01 7.22E+00 Cs-134 Ru-106 ---------- ---------- 2.64E+01 8.77E+01 5.99E+01 Ru-106 Cs-137 ---------- ---------- 3.27E+00 1.07E+01 7.25E+00 Cs-137 1o-99 ---------- ---------- l.1lE+02 3.57E+02 2.46E+02 Mo-99 Zr-95 ---------- ---------- 6.77E+00 2.12E+01 1.49E+01 Zr-95 Nb-95 ---------- ---------- 3.57Ei00 1.18E+01 7.95E+00 Nb-95 Co-58 ---------- ---------- 2.97E+00 9.96E+O0 6.75E+00 Co-58 Mn-54 ------- - --------- 3.13E+00 1.03E+01 7.05E+00 Mn-54 Ag-ll0m ---------- ---------- 5.61E+00 1.78E+01 1.24E+01 Ag-lOrm AcTh-228 ---------- ---------- 1.24E+01 4.14E+01 2.78E+01 AcTh-228 I-132 ---------- ---------- 6.59E+01 2.23E+02 1.49E+02 I-132 Zn-65 ---------- ---------- 4.97E+00 1.62E+01 1.20E+01 Zn-65 Page 006

Spectrum Storage ID #: 20053960G0.SPC Analyzed by sayer on 12/06/2005 14:55:04 CONCENTRATIONs Units: pCi/L (1.00 Sigma) Critical Less Than LLD Nuclide Conc. +- Uncert. Level Conc. Conc. Conc. Nuclide Fe-59 ---------- ---------- 8.71E+00 3.01E+01 2.03E+01 Fe-59 Co-60 ---------- ---------- 3.67E+00 1.23E+01 8.53E+00 Co-60 BaLa-140 ---------- ---------- 6.10E+00 1.98E+01 1.42E+01 BaLa-140 Sb-124 ---------- ---------- 6.93E+00 2.43E+01 1.70E+01 Sb-124 TOTAL MEASURED ACTIVITY: 2.17E+02 +- 4.20E+01 pCi/L Error in Results Transfer to ELMS.

Page 007

Spectrum Storage ID #: 200335361GO.SPC Analyzed by sayer on 12/06/2005 13:06s:

SEEKER GA M M A A N A L Y B I 8 R E S U L T 8 Verion 2.3.0 Entergy nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTIONs TRAP ROCK QUARRY Counting Starts 12/06/2005 1l10Os54 Lab ID.20053961 Decay Time .1.433+02 Nrs Client ID .IP 05-749 apwling Stoip . 11130/2005 12:00s00 Sample Sie. 3.OO..0OO L' Sample Duration . . . . 0.03+OO Brs Yield .1.0000' Sampling Start . 11/30/2005 12:00sOO Geometry Code. 3_080S Live Time (hxriinssec). . . 001:23:20 3ff. Calib. Date. 10/13/2005 13:05s:94 Real Time (hrzminsec). . . 001:23:22 Library File.. ASTR.LXB, RIVIZ3ED BYS Detector #s 6 Enorgy(keV)- 0.17+ 0.SOO*Ch+ 0.00-+00*ChA2 + 0.OOe+00*Ch^3 12/06/2005 /

MWEN(k*V) - 0.00+ 0.008*En+ 6.41-e04*3nA2 + 0.00+OO*EnA3 09/27/2005 >

Where En - Sqrt(ZrLeroy in koV)

Eff.-1/E 2.28*-01*EnA-2.04*+00 + 1.71*+02*En^ 7.76C-011 10/13/2005 CONCENTRATIONs Unites pCi/L (1.00 Sigma) Critical Loss Than LLD Nuclide Cone. +- Uncert. Level Cone. Cone. Cone. Euclid.

....... muumamumu...mu -u mmu .. uims-ium uunmnm a ua mim RP-226 1.60Z+02 S.03Z+01 __________ __________ RA-226 K-40 9.52Z+01 2.78Z+01 K-40 CO-57 __________ ________ __

2.28Z300 7.123+00 4.843+00 CO-57 CE-144 __________ __ _ ___ ___

1.56x+01 4.923+01 3.341+01 CE-144 CE-141 __________ __________

3.983+00 1.273+01 8.541+00 C3-14 NP-239 __________ __________

1.163+02 3.593+02 2.483+02 NP-239 53-75 _ _ _ ____ _ _ _ __ _ _ ___

3. OlI+00 9.07X+00 6.56z+00 53-75 CR-51 ___ _______ __________

2.283+01 7.20E+01 4.97E+01 CR-S1 EU-152 __________ __________

6.773+00 2.163+01 1.493+01 EU-152 I-131 __________ _____ _____

3.593+00 1. 143+01 7.983+00 I-131 AG-108b ___ _______

2.353+00 7.52E+00 5.193+00 AG-10sN B3-7 __________

1.693+01 5.753+01 3.883+01 Z3-7 RU-103 ____ ______ __________

3.243+00 9.913+00 7.10E+00 RU-103 I-133 _______ ___ ___ _______

2.543+02 8.413+02 5. 80+02 I-133 C8-134 __________ __________

2.993+00 9.483+00 6.663+00 C8-13S RU-106 _________ _ ______ ____

2.693+01 8.923+01 6.053+01 RU-106 C8-137 __________ _ _________

2.013+00 6.923+00 4.683+00 CS-137 30-99 __________ __________

7.283+01 2.473+02 1.69Z+02 YO-99 ZR-95 _ __ _ ____ _ _________

3.423+00 1.213+01 8.13t+00 ZR-95 33-95 __ ________ __ ______ _

2.243X+00 8.223+00 5.633+00 3B-95 CO-58 __________ __________

2.693+00 8.65+00 6.133+00 Co-so 33-54 __________ ____ ______

2.003+00 7.173+00 4.731+00 M3-54 AG-10 __________

3.29E+00 1. 093+01 7.643+00 AG-1103 ACTN-228 __________ ______ ____

1.063+01 3.42Z+01 2.393+01 ACTE-228 I-132 __________ _______ ___

5.133+01 1.663+02 1.183+02 $-132 Page 006

Spactum Storage ID At 2005396100.8SPC Analyxed by sayer on 12/06/2005 13sO6:;

COXCENTRATION. Units: pCL/L (1.00 Sigma) Critical Less Than LLD Nualide Cone. +- Unoert. Level Cono. Cone. Cone. Nuclide ueuuumuummmummma.-.me....mi.m.mi.m..in...mn....--- - -.s... -

ZN-65 ---------- -------- S.5f6+00 1.793+01 1.293+01 ZN-65 7Z-59 ---------- ---------- 5.43x+00 1.99X+01 1.343401 rz-s9 CO-60 ---------- ---------- 2.191+00 7.80x+00 5.43X+00 CO-60 DAL&-140 ---------- --------- 5.011+00 1.62X+01 1.103+01 DALA-140 0B-124 ---------- ---------- 7.021+00 2.251+01 1.683+01 83-124 TOTAL NsASURRD ACTZVITYt 2..53+02 +- 7.81Z+01 pCiIL Results TRANSPERRID to XLMS.

laog 007

Speotrum Storage ID #s 20053962GO.SPC Analyzed by sayer on 12/06/2005 13:153; SEEKER Q A X A A N A L Y S I S R E S8 L 8 Version 2.3.0 Entergy nuclear Northeast James A. Fitzpatrick Environmental Lab Sample DESCRIPTXION 5TH STREET WELL Counting Starts 12/06/2005 11:22s08 Lab ID. . . . . . . . . . . . .20053962 Decay Time. . . . . . . 1.43E+02 Ers Client ID . . . . . . . . . . IP 05-750" Sampling Stop . . 11/30/2005 12:00sO0 sample size . . . . . . . . 3.00-+00 L Sample Duration . . . . 0.00+00 Ers Yield . . . . . . . . . . . . . 1.0000-Sampling Start. . 11/30/2005 12:00:00 Geometry Code . . . . . . . . . 3_01150 Live Time (hrzuinssec). . . 001s23s20 Eff. Calib. Date. . 09/27/2005 13:14:16' Real Time (hrtmintsec). . . 001t23s22 Library rile. . . . . . . . .MASTER.LIB REVIEWED __

Detector 8s 3 Znergy(kaV)- -0.46+ 0.500*Ch+ 0.00e+00*ChA2 + 0.OOe+00*ChA3 12/06/2005VI FWHM(keV) a 0.84+ 0.011*Zn+ 4.55o-04*3nA2 + 0.OOe+OO*ZnA3 09/27/2005 V Where En - 8qrt(Znergy in keV)

Nff.M-l/ 7.51--02*EnA-2.5-e+00 + 1.76e+02*EnA 7.65*-Oil 09/27/2005.'

CONCETR&TIOIs Unitas pCi/L (1.00 sigma) Critical Less Than LLD Nuaclde Cona. +- Uncert. Level Cone. Cone. Conc. Nuclide X-40 1.353+02 3.103+01 ---------- ---------- ---------- s-40 CO-57 ---------- -- 2.701+00 8.451+00 5.70E+00 CO-57 CE-144 ---------- ---------- 2.133+01 6.6S3+01 4.493+01 C3-144 C-141 ----------

- ---------- 5.68X+00 1.771+01 1.193+01 CE-l41 RA-226 ---------- ---------- 7.66Z+01 2.403+02 1.613+02 RA-226 3P-239 ----

-__ -------- 1.36Z+02 4.193+02 2.883+02 NP-239 92-7 ----------- --------- 3.99M400 Z.27Z+01 6.5&+00 SE-75 CR-51 ----------- --------- 2.57Z+01 8.123+01 5.573+01 CR-51 EU-152 ---------- ---------- 8.713+00 2.743+01 1.89Z+01 3U-152 1-131 ---------- ---------- 4.923+00 1.543+01 1.071+01 1-131 AG-108l ---------- ---------- 2.433+00 7.931+00 5.373+00 AO-108Y B1-7 ---------- ---------- 2.741+01 8.59x+01 5.983+01 8E-7 RU-103 ---------- ---------- 3.06X+00 1.00X+01 6.77Z+00 RU-103 1-133 ---------- ---------- 3.463+02 1.09Z+03 7.662+02 I-133 CS-134 ---------- ---------- 2.983+00 9.583+00 6.663+00 CS-134 RU-106 ---------- ---------- 3.35+01 1.063+02 7.393+01 RU-106 C8-137 ---------- ---------- 3.15X+00 9.683+00 6.99X+00 C8-137 10-99 ---------- ---------- 9.653+01 3.123+02 2.17E+02 30-99 ZR-95 ---------- ---------- 5.20E+00 1.633+01 1.173+01 ZR-95 R1-95 ----- -------- 4----

  • .403+00 1.361+01 9.59Z+00 13-95 C0-S8 ---------- ---------- 3.40Z+00 1.083+01 7.593+00 CO-SS M-54 ---------- ---------- 2.76Z+00 8.903+00 6.293+00 1W-54 AG-lIO ---------- ---------- 4.113+00 1.343+01 9.313+00 AG-110l ACTE-228 ---------- ---- 9.353+00 3.063+01 2.163+01 ACTH-228 I-132 ---------- ---------- 5.491+01 1.76Z+02 1.263+02 X-132 Pago 006

Spectrum Storage ID At 2005396200.BPC Analyxed by sayer on 12/06/2005 13si5sg CONCZUTRATIONo Units: pCi/L (1.00 Sigma) Critical Less Than LLD Muclide Cona. +- Uncert. Level Cona. Cone. Conm. Nuclid.

.uuuMMMM............... ............................ U--

^

ZN-65 __________ ---------- _

3.00z+uu . en _.^<

10.4,11UL 9.59X+00 ZN-6S 13-59 ---------- 8.853+00 2.82x+01 2.063+01 '3-59 CO-60 ---------- 2.593+00 8.99X+00 6.263+00 CO-60 BALA-14 0 __ _ _ _ _ _ _

4.84X+00 1.623+01 1.153+01 DAA-140 83-124 _ ---------- 5.13Z+00 1.92x+01 1.313+01 S-124 TOTAL KZLSURED ACTXVI! Iys 1.35X+02 +- 3.10x+01 PCi/L Results TRANSFERRED to ELKS.

lage 007

ATTACHMENT 7.12 PAGE1 OFI INDIAN POINT SPECIALS ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM WEEK# 48 CUENT CODE -9 SAMPLE CLIENT SAMPUNG SAMPLE LOCATION SAMPLE MEDIA DATEMPE VOLUME ANALYSIS SAMPLE STATION TYPE CODE (UNITS) TYPE ID NUMBER NUMBER FROM TO IP 14 WATER METER _-3, GB RR WA GAL GSA

_ _ _ _ _ _ _ _ _ _H O USE _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1-131 BUCHANAN SEWAGE IP 97 TREATMENTPLANT RR SL I ,e GSA

_(Rc Tank1) -

BUCHANANSEWAGE IP 98 TREATMENT PLANT RR SL GAL GSA (Holdup Tank 2)

IP 05-748 ALGONQUIN OUTFALL RR WA 11130/5 3LUTERS GSA IP 05-748 GYPSUM PLANT RR WA 11/0/ 3 LITERS GSA 2 voso396 }/ STREAM IP 05-749 TRAP ROCK QUARRY RR WA 11150 3 LITERS GSA IP 104 GYPSUM PLANT WELL RR WA GAL H-3 GSA GB IP 105 GYPSUM PLANT WELL SPECIAL WA GAL KH- GSA GB PARKING LOT _ -

REMARKS: INDIAN POINT SPECIALS- MONTHLY RR = Regular Routine

ATTACHMENT 7.6 PAGE 1 OF 1 DRINKING WATER (MONTHLY)

ENVIRONMENTAL LABORATORY SAMPLE SUBMITTAL FORM t

WEEK # 48 CLIENTCODE CD CLIENT SAMPLING SAMPLE LOCATION SAMPLE MEDIA SAMPLE SAMPLE VOLUME ANALYSIS STATION TYPE CODE DATE (UNITS) 1D NUMBER NUMBER TYPE Ip 07 1-131 CAMP FIELD TS WA 2 GSA RESERVOIR gal GB IP 08 CROTON RESERVOIR 1131 RR WA 2 GSA

______ galGo__ GB IP 85 AMICUS RR WA RESERVOIR 2 GSA gal GB IP 05-750 l h STREET WELL RR WA 13 GSA LITERS H3 H9-3 IP U3-4 RR WA L GSA LITER REMARKS: MONTHLY SAMPLES - DRINIONG WATER TS a TECH SPECS RR.= REGULAR ROUtINE

TRITIUM PROGRAM Tritium Analysis Sample Run ID Sheet Run No. 05-87 Plant Eff. El Environmental El Other El Sample Count Date 12/6/2005 Background Count Time(min.) 100 Background (CPM) 9.46 Background Counting Elf. 0.354 Background (DPM) 26.73 3-5 QC STD 3/1412002 12:00 NA E3050 100 36.25 75.28 0.355 10457 f 264 5-1 ALGONQUIN OUTFALL 11/30/2005 12:00 20053959 IP-05-747 100 9.65 0.57 0.354 <464 5-2 GYPSUM PLANT STREAM 11/30/2005 12:00 20053960 IP-0748 100 9.61 0.52 0.353 c464 5-3 TRAP ROCK QUARRY 11/30/2005 12:00 20053961 IP-05-749 100 9.20 -1.07 0.359 <464 5-4 5TH STREET WELL 11130/2005 12:00 2005962 IP-05-750 100 9.29 -0.65 0.356 <464

=- m _ - -

Page _ of Completed By: Date:

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID GYPSUM PLANT STREAM ELMS 0: 20059690 Sample On Date I Time: t1J3iUDS 0 12.00 Client ID No. IP.0S-748 SampleOff Date/Time: 11J5 0 12:00 RuniNo. 05487 Sample Count Date: 121J6J05 o 12:00 Sampie Distilled: I YES Eapsed Tnme (count dai to aof dd) wrs 0.02 Decay Factor: 0.9991 Background Gross counts: 945.89 Background count time (minutes) 100 Background Counts, CPM: 9.46 Background DPM 26.73 Critica Level (CL) CPM 0.72 Sample Gross counts: 961 Sample Count Time (minutes) 100 Sample CPM: 9.61 Sample Net CPM: 0.15 Sample DPM: 0.52 evolum L 0.004 Background Counting Efficiency 0.5 CL Ratlo= 0.21 LLD value (CIL <464 Act/Error Ratlo= OA Sample Counting Efficiency 0.353 Sample Activity (pCK)

  • 1 sigma 59 t 140 Comments:

Note: f CL ratio Is d.0 OR Act1irror Ratio Is <2.7 %anUwh= value Is reported as a"Less Thanr Activty Technician: J Da:

Supervisor review: S._Gorman _ ___ __Date: /-?/A prit /sign p:\trlfurn program\riium acbivity calc.xt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID ALGONQUIN OUTFALL ELMS # 20053959 Sample On Date/Time: 11t30/05 0 12:00 Client ID No. IP-05-747 Sample Off DateITime: 11130A)5 a 12:00 Run No. 0587 Sample Count Date: 1215 a 12:00 Sample Distilled: YES Elapsed Time (oun date to off daft) 0.02 Decay Factor: 0.9991 Background Gross counts: 945.89 Background count time (minutes) 100 Background Counts, CPM: 9A6 Background DPM 26.73 Critical LevelCPM 0.72 Sample Gross counts: 965.33333 Sample Count Time (minutes) 100 Sample CPM: 9.65 Sample Net CPM: 0.19 Sample DPM: 0.57 sample volume (L) 0.004 Background Counting Efficiency 0.354 CL Ration 0.27 LLD value (CIL <464 ActlEffor Ratlo= 0.5 Sample Countng Efciency 0.354 Sample Activity(pCi/L) *t1sigma 64- t 139 Comments:

Note: I CL ratlo Is <l.0 :U rror Ratlo lc2.7 t n th3LLD value Is reported as a "Loss Than Activ.

Technician: _ 1k) i RIE-tQ Date: 81 Supervisor review: B. Gornman 3 p Date: 6 print Isign p:\bfftum program\trilum actfvity calc.xlt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID TRAP ROCK QUARRY ELMS #: 20053961 Sample On Date/Time: 11/30/05 o 12:00 CUent ID No. IP-05-749 SampleOlfDate/Time: 1113005 o 12:00 Run No. 05-87 Sample Count Date: 12)/5 0 12.00 Sample Distilled: YES Eia Time count ddt to on date 0.02 Decay Factor 0.9991 Background Gross counts: 945.89 Background count time (minutes) 100 Background Counts, CPM: 9.4U Background DPM 26.73 Critical LevelCL) CPM 0.72 Sample Gross counts: 920.33333 Sample Count Time (minutes) 100 Sample CPM: 9.20 Sample Net CPM: -0.26 Sample DPM: -1.07 saFmpl volume L 0.004 Background Counting Effliclency 0.354 CL Ratio= -0.36 LLD value CUL <464 ActlError Ratio= -0.9 Sample Counting Efficiency 0.359 Sampl Activity (pCUL) t l sigma m -121 136 Comments:

Note: i CL ratio Is <1.0 OR A c Ratio Is <2.7 n the 4D lue Is re rted as a 'Less Than" Aervty.

Technician: , E {4e/

1J print,*sn Supervisor review: B. Gorman . Date:

print / sIgn p:wbtium program\lritium actvity calc.xdt

JAF ENVIRONMENTAL LABORATORY Tritium Activity Calculation Sample ID 5TH STREET WELL ELMS 6: 20053962 Sample On Date/Tlme 111S305, a 12:00 Cllent lD No. IP-54Z780 ple Off Date / Time: 1113MM=5 o 12:00 Run No. 05487 Sample Count Date: 12106M5 o 12:00 Sample Distilled: YES Elas Time count dde to otr dat) We 0.02 Decay Factor: 0.9991 Background Gross counts: 945.89 Background count time (minutes) 100 Background Counts, CPM: 9_44 Background DPM 26.73 CrItIcal Level CL CPM 0.72 Sample Gross counts: 029.33333 Sample Count Time (mInutes) 100 Sample CPM 9.29 Sample Net CPM -0.17 Sample DPM: -0.65 sample volume (L) 0.004 Background CountIng Efficiency -) CL Ratlo= -0.23 LLD value pCVL <464 Act/Error Ratio= -0.5 Sape Counting Efficlency 0.356 sa~eActilvi + WC/Lima -73 t 137

_Rro _______-

Comments.

Note: nf CL ratio Is <1 OOR Aqror Ratio Is <2.71thanlhe I$D value Is reported as a 'Less Than' Activity.

Technician: Date:d SupervIsor review: B. Gorn Date:

punt /sign p:\triltum program\tritlum actvity calc xlt

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