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Air Quality RAI AQ-5 Entergy 2015i_WF3 Air Emission Calculations_Ceo 2015-00017
	ML17019A306
Person / Time
Site:	Waterford
Issue date:	02/07/2017
From:	; Entergy Operations
To:	Keegan E; Division of License Renewal
	Elaine Keegan, NRR/DLR, 415-8517
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ML17018A143	List: ML17018A166; ML17018A186; ML17018A205; ML17019A297; ML17019A306; ML17023A266; ML17023A268; ML17024A170; ML17024A193; ML17024A218; ML17024A239; ML17024A247; ML17030A167; ML17030A177; ML17030A187; ML17034A323; ML17034A328; ML17037C948; ML17037C997; ML17037D011; ML17037D017; ML17037D036; ML17037D055; ML17037D108; ML17037D250; ML17037D282; ML17037D290; ML17037D302; ML17037D315; ML17037D321; ML17038A260; ML17038A264; ML17038A273; ML17038A277; ML17038A280;
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Date: April 6, 2015 To:Rodney LeBlanceFrom:Rick Buckley

Subject:

Waterford 3 Air Emission CalculationsCriteria Pollutants, Hazardous Air Pollutants and Greenhouse GasesCEO 2015-00017To support the evaluation of air quality impacts associated with license renewal, thiscalculation package contains the criteria air pollutant emissions associated with thepermitted sources listed in Attachment 1 for the years 2010 through 2014. In addition,this package also contains the calculated direct (combustion sources) and indirect(workforce commuting) greenhouse gas emissions associated with Waterford 3's plantoperation for these same years.Attachment 2 to this calculation package contains an annual emission summary ofcriteria air pollutant emissions for the years 2010 through 2014 of the permitted sourceslisted in Attachment 1. Attachment 2 also lists a criteria air pollutant emission summaryfor each the categorical sources listed below which was utilized to develop the overallannual emission summary.600 Horsepower Stationary Generators >600 Horsepower Stationary Generators <100 MMBTU Portable Diesel Boiler600 Horsepower Portable Diesel GeneratorsEntergy Services, Inc1340 Echelon ParkwayJackson, Mississippi 39213

Portable Gasoline Engines

Diesel Fuel/Lube Oil/Gasoline Tanks Criteria air pollutant emission calculations for combustion sources shown in Attachment 1 were based on calculated annual fuel usage (Attachment

3) utilizing the Environmental Protection Agency's emission factors published in AP-42, Compilation of Air Pollutant Emission Factors. Volatile organic compounds for the diesel fuel oil, lube oil and gasoline tanks listed in Attachment 1 were based on permitted tons per year (0.35) shown on pages 5 and 6 in Waterford 3 Air Permit 2520-00091-00.

Attachment 4 contains an annual greenhouse gas (GHG) emission summary of the combustion sources listed in Attachment 1, and from workforce commuting for the years 2010 through 2014. GHG emissions for combustion sources were calculated based on annual fuel usage from all combustion sources. GHG emissions from workforce commuting were calculated based on data furnished by the United States Census Bureau and the Environmental Protection Agency. Attachment 5 contains the supporting calculations for these sources of GHG emissions.

If you have any questions, please contact me at 601-368-5823.

Rick Buckley Sr. Project Manager, Environmental Permitted Air Emission SourcesEmission PointDescription3-79Emergency Diesel Generator A4-79Emergency Diesel Generator B5-79Fire Water Diesel Pump A6-79Fire Water Diesel Pump B7-79Security Emergency Diesel Generator8-83Emergency Operations Facility Emergency Diesel Generator9-99Dry Cooling Tower Diesel Pump A10-99Dry Cooling Tower Diesel Pump B11-00IT Emergency Diesel Generator19-79Portable Diesel Generator20-00ACCW Wet Cooling Tower A21-00ACCW Wet Cooling Tower B12-79Diesel Fuel Oil Storage Tank (100,000 gallons)13-79Emergency Diesel Generator Fuel Oil Storage Tank A (142,500 gallons)14-79Emergency Diesel Generator Fuel Oil Storage Tank B (142,500 gallons)15-79Lube Oil Batch Tank A (21,200 gallons)16-79Lube Oil Batch Tank B (21,200 gallons)17-79Main Turbine Lube Oil Reservoir (20,900 gallons)18-79Gasoline Fuel Storage Tank (900 gallons)22-02Portable Outage/Maintenance Diesel Engines23-02Portable Outage/Maintenance Gasoline Engines24-03Portable Auxiliary Boiler Annual Air Emissions Inventory Summary, 2010-2014Annual Emissions (tons/year)Year SO x NO x CO PM 10VOCsHAPs2010 0.415.0 3.9 0.7 1.00.012011 0.520.5 5.3 1.0 1.20.022012 1.838.5 9.1 2.2 2.70.042013 0.618.1 4.7 0.8 1.00.032014 0.622.2 5.5 1.2 1.50.02 (Continued)Annual Air Emissions Inventory Summary, 2010-20142010 Annual Emissions (tons/year)

Emission Source SO x NO x CO PM 10VOCsHAPs600 Horsepower Stationary Generators 0.1 0.8 0.2 0.1 0.10.001>600 Horsepower Stationary Generators 0.111.9 3.2 0.4 0.30.01<100 MMBTU Portable Diesel Boiler 0 0 0 0 0 0600 Horsepower Portable Diesel Generators 0.2 2.3 0.5 0.2 0.20.002Portable Gasoline Engines0.0010.010.010.020.0010.00003Diesel Fuel/Lube Oil/Gasoline Tanks(a)0 0 0 00.35 0Total 0.415.0 3.9 0.7 1.00.012011 Annual Emissions (tons/year)

Emission Source SO x NO x CO PM 10VOCsHAPs600 Horsepower Stationary Generators 0.1 0.8 0.2 0.1 0.10.001>600 Horsepower Stationary Generators 0.115.4 4.1 0.5 0.40.01<100 MMBTU Portable Diesel Boiler 0.1 0.6 0.2 0.10.010.005600 Horsepower Portable Diesel Generators 0.2 3.7 0.8 0.3 0.30.003Portable Gasoline Engines0.0010.010.010.020.0010.00003Diesel Fuel/Lube Oil/Gasoline Tanks(a)0 0 0 00.35 0Total 0.520.5 5.3 1.0 1.20.02a. VOC annual emissions based on the permitted tons per year from all tanks shown on Pages 5 and 6 in WF3 Air Permit2520-00091-00. (Continued)Annual Air Emissions Inventory Summary, 2010-20142012 Annual Emissions (tons/year)

Emission Source SO x NO x CO PM 10VOCs HA Ps600 Horsepower Stationary Generators 0.1 1.0 0.2 0.1 0.10.001>600 Horsepower Stationary Generators 0.113.8 3.7 0.4 0.40.01<100 MMBTU Portable Diesel Boiler 0.1 0.7 0.2 0.10.010.005600 Horsepower Portable Diesel Generators 1.523.0 5.0 1.6 1.80.02Portable Gasoline Engines 0 0 0 0 0 0Diesel Fuel/Lube Oil/Gasoline Tanks(a)0 0 0 00.35 0Total 1.838.5 9.1 2.2 2.70.042013 Annual Emissions (tons/year)

Emission Source SO x NO x CO PM 10VOCsHAPs600 Horsepower Stationary Generators 0.1 0.8 0.2 0.1 0.10.001>600 Horsepower Stationary Generators 0.113.9 3.7 0.4 0.40.01<100 MMBTU Portable Diesel Boiler 0.3 2.0 0.5 0.20.030.015600 Horsepower Portable Diesel Generators 0.1 1.4 0.3 0.1 0.10.001Portable Gasoline Engines 0 0 0 0 0 0Diesel Fuel/Lube Oil/Gasoline Tanks(a)0 0 0 00.35 0Total 0.618.1 4.7 0.8 1.00.03a. VOC annual emissions based on the permitted tons per year from all tanks shown on Pages 5 and 6 in WF3 Air Permit2520-00091-00. (Continued)Annual Air Emissions Inventory Summary, 2010-20142014 Annual Emissions (tons/year)

Emission Source SO x NO x CO PM 10VOCsHAPs600 Horsepower Stationary Generators 0.1 2.2 0.5 0.2 0.20.002>600 Horsepower Stationary Generators 0.112.7 3.4 0.4 0.40.01<100 MMBTU Portable Diesel Boiler0.003 0.8 0.2 0.10.010.006600 Horsepower Portable Diesel Generators 0.4 6.5 1.4 0.5 0.50.006Portable Gasoline Engines 0 0 0 0 0 0Diesel Fuel/Lube Oil/Gasoline Tanks(a)0 0 0 00.35 0Total 0.6 22.2 5.5 1.2 1.5 0.0 2a. VOC annual emissions based on the permitted tons per year from all tanks shown on Pages 5 and 6 in WF3 Air Permit2520-00091-00. Annual Air Emissions Inventory Summary, Supporting Calculations1. Emission calculations for the stationary emission points below were based on annualcalculated fuel usage (annual operational run hours x maximum gallons per hour fuelconsumption). Emission Point 3-79: Emergency Diesel Generator A (339 gph) Emission Point 4-79: Emergency Diesel Generator B (339 gph) Emission Point 5-79: Fire Water Diesel Pump A (12 gph) Emission Point 6-79: Fire Water Diesel Pump B (12 gph) Emission Point 7-79: Security Emergency Diesel Generator (16 gph) Emission Point 8-83: EOF Emergency Diesel Generator (18 gph) Emission Point 9-99: Dry Cooling Tower Diesel Pump A (1.2 gph) Emission Point 10-99: Dry Cooling Tower Diesel Pump B (1.2 gph) Emission Point 11-00: IT Emergency Diesel Generator (9.4 gph)Although stationary combustion sources at Waterford 3 are limited as it relates to annualoperational hours based on the operating schedule shown in Air Permit2520-00091-00, thepermit does not impose recordkeeping requirements to track the hours. In 2004, Waterford 3began tracking the operational hours to verify that the values specified in the operatingschedule of the air permit were not exceeded. However based on review of the operationalrun times recorded from 2004 through 2014, this practice did not continue on a consistentbasis after 2008. Therefore with the exception of Emission Points 3-79 (Emergency DieselGenerator A) and 4-79 (Emergency Diesel Generator B), calculated criteria air pollutantemissions based on annual operational run hours and associated calculated fuel usage forthe remaining stationary combustion sources (Emission Points 4-79, 5-79. 6-79, 8-83, 9-99,10-99 and 11-00) should be considered projected annual estimates for certain years. TableA-1 provides additional details regarding the basis for determining annual operational hours.2. With the exceptions noted in Table A-2, emission calculations for the emission points belowwere based on annual fuel usage reports submitted to the LDEQ. Emission Point 22-02: Portable Outage/Maintenance Diesel Engines Emission Point 23-02: Portable Outage/Maintenance Gasoline Engines Emission Point 24-03: Portable Auxiliary Boiler

3. PM 10 emissions from the auxiliary component cooling water wet cooling towers were notincluded in the emissions inventory since water flowing through the towers is filtered water;therefore, PM 10 emissions, if any, would be insignificant.Table A-1 lists operational hours for the emission sources in Item 1 above, while Table A-2 listscalculated fuel usage for these emission sources. Table A-2 also lists fuel usage reported to theLDEQ for the emission sources in Item 2 above. Emission calculations for emission sourceslisted in Items 1 and 2 above are included in this attachment.

Table A-1Operational Hours, 2010 - 2014Emission PointDescription201020112012201320143-79 EDG A69.9 98.7 88.8 91.4 91.94-79 EDG B86.4 103.8 92.8 91.9 74.7 5-79(a)Fire Water Diesel Pump A19.5 19.5 19.5 19.5 12.0 6-79 (b)Fire Water Diesel Pump B13.5 13.5 13.5 13.5 11.0 7-79 (c)Security EDG76.0 76.0 76.0 76.0 386.0 8-83 (d)EOF EDG43.6 43.6 75.8 44.65 44.65 9-99 (e)DCT Diesel Pump A0.15 0.15 0.15 0.15 0.15 10-99 (f)DCT Diesel Pump B0.16 0.16 0.16 0.16 0.16 11-00 (g)IT EDG22.1 22.1 22.1 22.1 1.5a. 2010 -2013 based on 4-year average. December 2013 reading (217.0) minus December 2009reading (139.0).b. 2010 - 2013 based on 2-year historical average. December 2009 reading (35.0) minusDecember 2007 reading (8.0).c. 2010 -2013 based on 4-year average. December 2013 reading (1542.6) minus December 2009reading (1238.5).d. 2010 and 2011 based on 3-year average. December 2011 reading (1032.2) minus December2008 reading (901.3).2013 -2014 based on 2-year average. December 2014 reading (1197.3) minus December 2012reading (1108.0).e. 2010 - 2014 based on 4-year historical average, December 2008 reading (0.7) minusDecember 2004 reading (0.09).f. 2010 - 2014 based on 4-year historical average, December 2008 reading (0.74) minusDecember 2004 reading (0.09).g. 2010 - 2013 based on 5-year average, December 2013 reading (516.6) minus December 2008reading (406.0).

Table A-2Fuel Usage, 2010 - 2014 Emission Source20102011201220132014Stationary Diesels (>600 HP)52,98668,64861,56262,13956,477Stationary Diesels600 HP)2,6052,6053,1852,6247,270Portable Diesel Boiler (<100 MMBTU) 064,46765,280200,94079,815Portable Diesels600 HP)7,46811,97474,5294,50020,902(a)Gasoline Engines110110 0 0 0 (b)a.Assumed that fuel usage was all fuel deliveries made by Jackie Bee in 2014.

b.Value of 7,317 gallons reported in the Annual Air Emissions Report was not associated with EmissionPoint 23-02 (Portable Outage/Maintenance Gasoline Engines).4. For the emission points listed below, permitted volatile organic carbon tons per year from alltanks listed on pages 5 and 6 of Waterford 3 Air Permit 2520-00091-00 was utilized as thedefault value (0.35). Emission Point 12-79: Diesel Fuel Oil Storage Tank (100,000 gallons) Emission Point 13-79: EDG Fuel Oil Storage Tank A (142,500 gallons) Emission Point 14-79: EDG Fuel Oil Storage Tank B (142,500 gallons) Emission Point 15-79: Lube Oil Batch Tank A (21,200 gallons) Emission Point 16-79: Lube Oil Batch Tank B (21,200 gallons) Emission Point 17-79: Main Turbine Lube Oil Reservoir (20,900 gallons) Emission Point 18-79: Gasoline Fuel Storage Tank (900 gallons)

Stationary DieselsAir Emission Calculations(Emission Points 5-79, 6-79, 7-79, 8-83, 9-99, 10-99 and 11-00: 600 Horsepower)(Emission Points 3-79 and 4-79: >600 Horsepower) 2010 Stationary Combustion Sources ( 600 HP)aEnter Fuel Use (gal/yr) b2,605Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 20.29 365 1060.1 NO x4.41 3651,6080.8 CO0.95 365 3460.2 VOC f0.35 365 1280.1 PM 100.31 365 1130.1Hazardous Air PollutantsBenzene0.000933 3650.30.0002Toluene0.000409 3650.10.0001Xylenes0.000285 3650.10.00011,3-Butadiene0.0000391 3650.010.00001Formaldehyde0.00118 3650.40.0002Acetaldehyde0.000767 3650.30.0001Acrolein0.0000925 3650.030.00002Napthalene0.0000848 3650.00.000021.20.001a. Includes Emission Points 5-79, 6-79, 7-79, 8-83, 9-99, 10-99, and 11-00.b. Total combined fuel usage for emission points listed in note a above.c. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yrf. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2010 Stationary Combustion Sources (>600 HP)aEnter Fuel Use (gal/yr) b52,986Enter Fuel Sulfur Content (%)0.02Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 21.017,418 1500.1 NO x3.27,41823,73811.9 CO0.857,4186,3053.2 VOC f0.097,418 6680.3 PM 100.17,418 7420.4Hazardous Air PollutantsBenzene0.0007767,4185.80.003Toluene0.0002817,4182.10.001Xylenes0.0001937,4181.40.001Formaldehyde0.00007897,4180.60.0003Acetaldehyde0.00002527,4180.20.0001Acrolein0.000007887,4180.10.00003Napthalene0.0001307,4181.00.000515.80.01a. Includes Emission Points 3-79 (EDG A) and 4-79 (EDG B).b. Total combined fuel usage for Emission Points 3-79 and 4-79.c. Factors obtained from AP-42 Tables 3.4-1, 3.4-3 and 3.4-4.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr (For SO 2, fuel sulfur content of 0.02 was also included in the formula).f. Emission factor includes methane and nonmethane emissions (see AP-42 ,Table 3.4-1, footnote f).Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2011 Stationary Combustion Sources ( 600 HP)aEnter Fuel Use (gal/yr) b2,605Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 20.29 365 1060.1 NO x4.41 3651,6080.8 CO0.95 365 3460.2 VOC f0.35 365 1280.1 PM 100.31 365 1130.1Hazardous Air PollutantsBenzene0.000933 3650.30.0002Toluene0.000409 3650.10.0001Xylenes0.000285 3650.10.00011,3-Butadiene0.0000391 3650.010.00001Formaldehyde0.00118 3650.40.0002Acetaldehyde0.000767 3650.30.0001Acrolein0.0000925 3650.030.00002Napthalene0.0000848 3650.030.000021.20.001a. Includes Emission Points 5-79, 6-79, 7-79, 8-83, 9-99, 10-99, and 11-00.b. Total combined fuel usage for emission points listed in note a above.c. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr.f. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2011 Stationary Combustion Sources (>600 HP)aEnter Fuel Use (gal/yr) b68,648Enter Fuel Sulfur Content (%)0.02Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 21.019,611 1940.1 NO x3.29,61130,75415.4 CO0.859,6118,1694.1 VOC f0.099,611 8650.4 PM 100.19,611 9610.5Hazardous Air PollutantsBenzene0.0007769,6117.50.004Toluene0.0002819,6112.70.001Xylenes0.0001939,6111.90.001Formaldehyde0.00007899,6110.80.0004Acetaldehyde0.00002529,6110.20.0001Acrolein0.000007889,6110.10.00004Napthalene0.000139,6111.20.00120.50.01a. Includes Emission Points 3-79 (EDG A) and 4-79 (EDG B).b. Total combined fuel usage for Emission Points 3-79 and 4-79.c. Factors obtained from AP-42 Tables 3.4-1, 3.4-3 and 3.4-4.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr (For SO 2, fuel sulfur content of 0.02 was also included in the formula).f. Emission factor includes methane and nonmethane emissions (see AP-42 ,Table 3.4-1, footnote f).Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2012 Stationary Combustion Sources ( 600 HP)aEnter Fuel Use (gal/yr) b3,185Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 20.29 446 1290.1 NO x4.41 4461,9661.0 CO0.95 446 4240.2 VOC f0.35 446 1560.1 PM 100.31 446 1380.1Hazardous Air PollutantsBenzene0.000933 4460.40.0002Toluene0.000409 4460.20.0001Xylenes0.000285 4460.10.00011,3-Butadiene0.0000391 4460.020.00001Formaldehyde0.00118 4460.50.0003Acetaldehyde0.000767 4460.30.0002Acrolein0.0000925 4460.040.00002Napthalene0.0000848 4460.040.000021.40.001a. Includes Emission Points 5-79, 6-79, 7-79, 8-83, 9-99, 10-99, and 11-00.b. Total combined fuel usage for emission points listed in note a above.c. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr.f. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2012 Stationary Combustion Sources (>600 HP)aEnter Fuel Use (gal/yr) b61,562Enter Fuel Sulfur Content (%)0.02Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 21.018,619 1740.1 NO x3.28,61927,58013.8 CO0.858,6197,3263.7 VOC f0.098,619 7760.4 PM 100.18,619 8620.4Hazardous Air PollutantsBenzene0.0007768,6196.70.003Toluene0.0002818,6192.40.001Xylenes0.0001938,6191.70.001Formaldehyde0.00007898,6190.70.0003Acetaldehyde0.00002528,6190.20.0001Acrolein0.000007888,6190.10.00003Napthalene0.000138,6191.10.00118.40.01a. Includes Emission Points 3-79 (EDG A) and 4-79 (EDG B).b. Total combined fuel usage for Emission Points 3-79 and 4-79.c. Factors obtained from AP-42 Tables 3.4-1, 3.4-3 and 3.4-4.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr (For SO 2, fuel sulfur content of 0.02 was also included in the formula).f. Emission factor includes methane and nonmethane emissions (see AP-42 ,Table 3.4-1, footnote f).Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2013 Stationary Combustion Sources ( 600 HP)aEnter Fuel Use (gal/yr) b2,624Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 20.29 367 1070.1 NO x4.41 3671,6200.8 CO0.95 367 3490.2 VOC f0.35 367 1290.1 PM 100.31 367 1140.1Hazardous Air PollutantsBenzene0.000933 3670.30.0002Toluene0.000409 3670.20.0001Xylenes0.000285 3670.10.00011,3-Butadiene0.0000391 3670.010.00001Formaldehyde0.00118 3670.40.0002Acetaldehyde0.000767 3670.30.0001Acrolein0.0000925 3670.030.00002Napthalene0.0000848 3670.030.000021.20.001a. Includes Emission Points 5-79, 6-79, 7-79, 8-83, 9-99, 10-99, and 11-00.b. Total combined fuel usage for emission points listed in note a above.c. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr.f. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2013 Stationary Combustion Sources (>600 HP)aEnter Fuel Use (gal/yr) b62,139Enter Fuel Sulfur Content (%)0.02Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 21.018,699 1760.1 NO x3.28,69927,83813.9 CO0.858,6997,3953.7 VOC f0.098,699 7830.4 PM 100.18,699 8700.4Hazardous Air PollutantsBenzene0.0007768,6996.80.003Toluene0.0002818,6992.40.001Xylenes0.0001938,6991.70.001Formaldehyde0.00007898,6990.70.0003Acetaldehyde0.00002528,6990.20.0001Acrolein0.000007888,6990.10.00003Napthalene0.000138,6991.10.00118.50.01a. Includes Emission Points 3-79 (EDG A) and 4-79 (EDG B).b. Total combined fuel usage for Emission Points 3-79 and 4-79.c. Factors obtained from AP-42 Tables 3.4-1, 3.4-3 and 3.4-4.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr (For SO 2, fuel sulfur content of 0.02 was also included in the formula).f. Emission factor includes methane and nonmethane emissions (see AP-42 ,Table 3.4-1, footnote f).Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2014 Stationary Combustion Sources ( 600 HP)aEnter Fuel Use (gal/yr) b7,270Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 20.291,018 2950.1 NO x4.411,0184,4882.2 CO0.951,018 9670.5 VOC f0.351,018 3560.2 PM 100.311,018 3160.2Hazardous Air PollutantsBenzene0.0009331,0180.90.0005Toluene0.0004091,0180.40.0002Xylenes0.0002851,0180.30.00011,3-Butadiene0.00003911,0180.040.00002Formaldehyde0.001181,0181.20.001Acetaldehyde0.0007671,0180.80.0004Acrolein0.00009251,0180.10.00005Napthalene0.00008481,0180.10.000043.20.002a. Includes Emission Points 5-79, 6-79, 7-79, 8-83, 9-99, 10-99, and 11-00.b. Total combined fuel usage for emission points listed in note a above.c. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr.f. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2014 Stationary Combustion Sources (>600 HP)aEnter Fuel Use (gal/yr) b56,477Enter Fuel Sulfur Content (%)0.02Criteria PollutantsAP-42 Factor(lb/MMBtu) c MMBtu/yr dlbs/yr etons/yr SO 21.017,907 1600.1 NO x3.27,90725,30212.7 CO0.857,9076,7213.4 VOC f0.097,907 7120.4 PM 100.17,907 7910.4Hazardous Air PollutantsBenzene0.0007767,9076.10.003Toluene0.0002817,9072.20.001Xylenes0.0001937,9071.50.0008Formaldehyde0.00007897,9070.60.0003Acetaldehyde0.00002527,9070.20.0001Acrolein0.000007887,9070.10.00003Napthalene0.000137,9071.00.000516.80.01a. Includes Emission Points 3-79 (EDG A) and 4-79 (EDG B).b. Total combined fuel usage for Emission Points 3-79 and 4-79.c. Factors obtained from AP-42 Tables 3.4-1, 3.4-3 and 3.4-4.d. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000e. AP-42 Factor x MMBtu/yr (For SO 2, fuel sulfur content of 0.02 was also included in the formula).f. Emission factor includes methane and nonmethane emissions (see AP-42 ,Table 3.4-1, footnote f).Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year)

Portable Diesel BoilerAir Emission Calculations(Portable Diesel Boiler: <100 MMBTU) 2011 Portable Auxiliary Boiler (Emission Point 2-95)Enter Fuel Use (gals/yr) 64,467 Enter Fuel Sulfur Content (%)

0.02Criteria PollutantsAP-42 Factor(lb/1000 gal) a lbs/yr btons/yr SO 2 142 183 0.1 NO x 20 1,289 0.6 CO 5 322 0.2 PM 10 2 129 0.1 VOC c 0.252 16 0.01Hazardous Air PollutantsBenzene 0.000214 0.01 0.00001Ethylbenzene 0.0000636 0.004 0.000002Formaldehyde 0.0330 2.1 0.001 Napthalene 0.00113 0.1 0.000041,1,1-Trichloroethane 0.000236 0.02 0.00001Toluene 0.00620 0.4 0.0002o-Xylene 0.000109 0.01 0.000004Antimony 0.00525 0.3 0.0002Arsenic 0.00132 0.1 0.00004Beryllium 0.0000278 0.002 0.000001Cadmium 0.000398 0.03 0.00001Chromium 0.000845 0.1 0.00003 Cobalt 0.00602 0.4 0.0002 Lead 0.00151 0.1 0.00005 Manganese 0.00300 0.2 0.0001 Mercury 0.000113 0.01 0.000004Nickel 0.0845 5.4 0.003 Selenium 0.000683 0.04 0.00002 1.0 0.005a. Factors obtained from AP-42 Tables 1.3-1, 1.3-3, 1.3-9 and 1.3-11b. Yearly fuel usage xAP-42 emission factor x 0.001 (For SO 2, the fuel sulfur content of 0.02 was also included in the formula).c. Emission factor includes methane and nonmethane emissions.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year)

Enter Fuel Use (gals/yr) 65,280 Enter Fuel Sulfur Content (%)

0.02Criteria PollutantsAP-42 Factor(lb/1000 gal) a lbs/yr btons/yr SO 2 142 185 0.1 NO x 20 1,306 0.7 CO 5 326 0.2 PM 10 2 131 0.1 VOC c 0.252 16 0.01Hazardous Air PollutantsBenzene 0.000214 0.01 0.00001Ethylbenzene 0.0000636 0.004 0.000002Formaldehyde 0.0330 2.2 0.001 Napthalene 0.00113 0.1 0.000041,1,1-Trichloroethane 0.000236 0.02 0.00001Toluene 0.00620 0.4 0.0002o-Xylene 0.000109 0.0 0.000004Antimony 0.00525 0.3 0.0002Arsenic 0.00132 0.1 0.00004Beryllium 0.0000278 0.002 0.000001Cadmium 0.000398 0.03 0.00001Chromium 0.000845 0.1 0.00003 Cobalt 0.00602 0.4 0.0002 Lead 0.00151 0.1 0.00005 Manganese 0.00300 0.2 0.0001 Mercury 0.000113 0.01 0.000004Nickel 0.0845 5.5 0.003 Selenium 0.000683 0.04 0.00002 1.0 0.005a. Factors obtained from AP-42 Tables 1.3-1, 1.3-3, 1.3-9 and 1.3-11b. Yearly fuel usage xAP-42 emission factor x 0.001 (For SO 2, the fuel sulfur content of 0.02 was also included in the formula).c. Emission factor includes methane and nonmethane emissions.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year)2012 Portable Auxiliary Boiler (Emission Point 2-95)

Enter Fuel Use (gals/yr) 200,940 Enter Fuel Sulfur Content (%)

0.02Criteria PollutantsAP-42 Factor(lb/1000 gal) a lbs/yr btons/yr SO 2 142 571 0.3 NO x 20 4,019 2.0 CO 5 1,005 0.5 PM 10 2 402 0.2 VOC c 0.252 51 0.03Hazardous Air PollutantsBenzene 0.000214 0.04 0.00002Ethylbenzene 0.0000636 0.01 0.00001Formaldehyde 0.0330 6.6 0.003 Napthalene 0.00113 0.2 0.00011,1,1-Trichloroethane 0.000236 0.05 0.00002Toluene 0.00620 1.2 0.001o-Xylene 0.000109 0.02 0.00001Antimony 0.00525 1.1 0.001Arsenic 0.00132 0.3 0.0001Beryllium 0.0000278 0.01 0.000003Cadmium 0.000398 0.1 0.00004Chromium 0.000845 0.2 0.0001 Cobalt 0.00602 1.2 0.001 Lead 0.00151 0.3 0.0002 Manganese 0.00300 0.6 0.0003 Mercury 0.000113 0.02 0.00001Nickel 0.0845 17.0 0.01 Selenium 0.000683 0.1 0.0001 3.0 0.015a. Factors obtained from AP-42 Tables 1.3-1, 1.3-3, 1.3-9 and 1.3-11b. Yearly fuel usage xAP-42 emission factor x 0.001 (For SO 2, the fuel sulfur content of 0.02 was also included in the formula).c. Emission factor includes methane and nonmethane emissions.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year)2013 Portable Auxiliary Boiler (Emission Point 2-95)

Enter Fuel Use (gals/yr) 79,815 Enter Fuel Sulfur Content (%)

0.0005Criteria PollutantsAP-42 Factor(lb/1000 gal) a lbs/yr btons/yr SO 2 142 6 0.003 NO x 20 1,596 0.8 CO 5 399 0.2 PM 10 2 160 0.1 VOC c 0.252 20 0.01Hazardous Air PollutantsBenzene 0.000214 0.02 0.00001Ethylbenzene 0.0000636 0.01 0.000003Formaldehyde 0.0330 2.6 0.001 Napthalene 0.00113 0.1 0.000051,1,1-Trichloroethane 0.000236 0.02 0.00001Toluene 0.00620 0.5 0.0002o-Xylene 0.000109 0.01 0.000004Antimony 0.00525 0.4 0.0002Arsenic 0.00132 0.1 0.0001Beryllium 0.0000278 0.002 0.000001Cadmium 0.000398 0.03 0.00002Chromium 0.000845 0.1 0.00003 Cobalt 0.00602 0.5 0.0002 Lead 0.00151 0.1 0.0001 Manganese 0.00300 0.2 0.0001 Mercury 0.000113 0.01 0.000005Nickel 0.0845 6.7 0.003 Selenium 0.000683 0.1 0.00003 1.1 0.006a. Factors obtained from AP-42 Tables 1.3-1, 1.3-3, 1.3-9 and 1.3-11b. Yearly fuel usage xAP-42 emission factor x 0.001 (For SO 2, the fuel sulfur content of 0.0005 was also included in the formula).c. Emission factor includes methane and nonmethane emissions.Hazardous Air Pollutants (Tons/Year)2014 Portable Auxiliary Boiler (Emission Point 2-95)Criteria Pollutants (Tons/Year)

Portable DieselsAir Emission Calculations(Portable Diesels: 600 Horsepower) 2010 Portable Diesel Engines (Emission Points 19-79 and 22-02)Enter Fuel Use (gal/yr) 7,468Criteria PollutantsAP-42 Factor(lb/MMBtu) aMMBtu/yr b lbs/yr ctons/yr SO 2 0.29 1,046 303 0.2 NO x 4.41 1,046 4,611 2.3 CO 0.95 1,046 993 0.5 VOC d 0.35 1,046 366 0.2 PM 10 0.31 1,046 324 0.2Hazardous Air PollutantsBenzene 0.000933 1,046 1.0 0.0005Toluene 0.000409 1,046 0.4 0.0002Xylenes 0.000285 1,046 0.3 0.0001 1,3-Butadiene 0.0000391 1,046 0.04 0.00002Formaldehyde 0.00118 1,046 1.2 0.001Acetaldehyde 0.000767 1,046 0.8 0.0004Acrolein 0.0000925 1,046 0.1 0.00005 Napthalene 0.0000848 1,046 0.1 0.00004 3.3 0.002a. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.b. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000c. AP-42 Factor x MMBtu/yrd. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2011 Portable Diesel Engines (Emission Points 19-79 and 22-02)Enter Fuel Use (gal/yr) 11,974Criteria PollutantsAP-42 Factor(lb/MMBtu) aMMBtu/yr b lbs/yr ctons/yr SO 2 0.29 1,676 486 0.2 NO x 4.41 1,676 7,393 3.7 CO 0.95 1,676 1,593 0.8 VOC d 0.35 1,676 587 0.3 PM 10 0.31 1,676 520 0.3Hazardous Air PollutantsBenzene 0.000933 1,676 1.6 0.001Toluene 0.000409 1,676 0.7 0.0003Xylenes 0.000285 1,676 0.5 0.0002 1,3-Butadiene 0.0000391 1,676 0.1 0.00003Formaldehyde 0.00118 1,676 2.0 0.001Acetaldehyde 0.000767 1,676 1.3 0.001Acrolein 0.0000925 1,676 0.2 0.0001 Napthalene 0.0000848 1,676 0.1 0.0001 5.3 0.003a. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.b. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000c. AP-42 Factor x MMBtu/yrd. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2012 Portable Diesel Engines (Emission Points 19-79 and 22-02)Enter Fuel Use (gal/yr) 74,529Criteria PollutantsAP-42 Factor(lb/MMBtu) aMMBtu/yr b lbs/yr ctons/yr SO 2 0.29 10,434 3,026 1.5 NO x 4.41 10,434 46,014 23.0 CO 0.95 10,434 9,912 5.0 VOC d 0.35 10,434 3,652 1.8 PM 10 0.31 10,434 3,235 1.6Hazardous Air PollutantsBenzene 0.000933 10,434 9.7 0.005Toluene 0.000409 10,434 4.3 0.002Xylenes 0.000285 10,434 3.0 0.001 1,3-Butadiene 0.0000391 10,434 0.4 0.000Formaldehyde 0.00118 10,434 12.3 0.01Acetaldehyde 0.000767 10,434 8.0 0.004Acrolein 0.0000925 10,434 1.0 0.0005 Napthalene 0.0000848 10,434 0.9 0.000 32.9 0.02a. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.b. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000c. AP-42 Factor x MMBtu/yrd. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2013 Portable Diesel Engines (Emission Points 19-79 and 22-02)Enter Fuel Use (gal/yr) 4,500Criteria PollutantsAP-42 Factor(lb/MMBtu) aMMBtu/yr b lbs/yr ctons/yr SO 2 0.29 630 183 0.1 NO x 4.41 630 2,778 1.4 CO 0.95 630 599 0.3 VOC d 0.35 630 221 0.1 PM 10 0.31 630 195 0.1Hazardous Air PollutantsBenzene 0.000933 630 0.6 0.0003Toluene 0.000409 630 0.3 0.0001Xylenes 0.000285 630 0.2 0.0001 1,3-Butadiene 0.0000391 630 0.02 0.00001Formaldehyde 0.00118 630 0.7 0.0004Acetaldehyde 0.000767 630 0.5 0.0002Acrolein 0.0000925 630 0.1 0.00003 Napthalene 0.0000848 630 0.1 0.00003 2.0 0.001a. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.b. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000c. AP-42 Factor x MMBtu/yrd. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2014 Portable Diesel Engines (Emission Points 19-79 and 22-02)Enter Fuel Use (gal/yr) 20,902Criteria PollutantsAP-42 Factor(lb/MMBtu) aMMBtu/yr b lbs/yr ctons/yr SO 2 0.29 2,926 849 0.4 NO x 4.41 2,926 12,905 6.5 CO 0.95 2,926 2,780 1.4 VOC d 0.35 2,926 1,024 0.5 PM 10 0.31 2,926 907 0.5Hazardous Air PollutantsBenzene 0.000933 2,926 2.7 0.001Toluene 0.000409 2,926 1.2 0.001Xylenes 0.000285 2,926 0.8 0.0004 1,3-Butadiene 0.0000391 2,926 0.1 0.0001Formaldehyde 0.00118 2,926 3.5 0.002Acetaldehyde 0.000767 2,926 2.2 0.001Acrolein 0.0000925 2,926 0.3 0.0001 Napthalene 0.0000848 2,926 0.2 0.0001 9.2 0.006a. Factors obtained from AP-42 Tables 3.3-1 and 3.3-2.b. Yearly fuel usage x 140,000 Btu/gal

÷ 1,000,000c. AP-42 Factor x MMBtu/yrd. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year)

Portable Gasoline EnginesAir Emission Calculations 2010 Portable Outage/Maintenance Gasoline Engines (Emission Point 23-02)Enter Fuel Use (gals/yr) 110Criteria PollutantsAP-42 Factor(lb/MMBtu)a, b MMBtu/yr clbs/yr dTons/Year SO 20.084 141.20.001 NO x1.63 14 230.01 CO0.99 14 140.01 VOC e0.10 141.40.001 PM 102.1 1430.00.02Hazardous Air PollutantsBenzene0.000933 140.010.00001Toluene0.000409 140.010.000003Xylenes0.000285 140.0040.0000021,3-Butadiene0.0000391 140.0010.0000003Formaldehyde0.00118 140.020.00001Acetaldehyde0.000767 140.010.00001Acrolein0.0000925 140.0010.000001Naphthalene0.0000848 140.0010.0000010.040.00003a. Criteria pollutant emission factors obtained from AP-42 Table 3.3-1.b. HAP emission factors obtained from AP-42 Table 3.3-2 since these are the only ones related to gasoline engines based on AP-42 (Gasoline and Industrial Engines).c. Yearly fuel usage x 130,000 Btu/gal

÷ 1,000,000d. Emission Factor x MMBtu/yre. Utilized AP-42 exhaust emission factor.Criteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year) 2011 Portable Outage/Maintenance Gasoline Engines (Emission Point 23-02)Enter Fuel Use (gals/yr) 110Criteria PollutantsAP-42 Factor(lb/MMBtu)a, b MMBtu/yr clbs/yr dTons/Year SO 20.084 141.20.001 NO x1.63 14 230.01 CO0.99 14 140.01 PM 100.10 141.40.001 VOC e2.1 14 300.02Hazardous Air PollutantsBenzene0.000933 140.010.00001Toluene0.000409 140.010.000003Xylenes0.000285 140.0040.0000021,3-Butadiene0.0000391 140.0010.0000003Formaldehyde0.00118 140.020.00001Acetaldehyde0.000767 140.010.00001Acrolein0.0000925 140.0010.000001Naphthalene0.0000848 140.0010.0000010.040.00003a. Criteria pollutant emission factors obtained from AP-42 Table 3.3-1.b. HAP emission factors obtained from AP-42 Table 3.3-2 since these are the only ones related to gasoline engines based on AP-42 (Gasoline and Industrial Engines).c. Yearly fuel usage x 130,000 Btu/gal

÷ 1,000,000d. Emission Factor x MMBtu/yrCriteria Pollutants (Tons/Year)Hazardous Air Pollutants (Tons/Year)

AP-42 Emission Factors <100 MMBTU Portable Diesel Boiler (Tables 1.3-1, 1.3-3, 1.3-9 and 1.3-11)600 Horsepower Portable Diesel Generators (Tables 3.3-1 and 3.3-2) Portable Gasoline Engines (Table 3.3-1 and 3.3-2) >600 Horsepower Stationary Generators (Tables 3.4-1, 3.4-3 and 3.4-4) 5/10 External Combustion Sources 1.3-2Table 1.3-1. CRITERIA POLLUTANT EMISSION FACTORS FOR FUEL OIL COMBUSTION a SO 2 b SO 3 c NO x d CO e Filterable PM f Firing Configuration (SCC)a Emission Factor (lb/10 3 gal)EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal)EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal) EMISSIO N FACTOR RATING Emission Factor (lb/10 3 gal)EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal) EMISSION FACTOR RATING Boilers > 100 Million Btu/hr No. 6 oil fired, normal firing (1-01-004-01), (1-02-004-01), (1-03-004-01) 157S A 5.7S C 47 A 5 A 9.19(S)+3.22 A No. 6 oil fired, normal firing, low NO x burner (1-01-004-01), (1-02-004-01) 157S A 5.7S C 40 B 5 A 9.19(S)+3.22 A No. 6 oil fired, tangential firing, (1-01-004-04) 157S A 5.7S C 32 A 5 A 9.19(S)+3.22 A No. 6 oil fired, tangential firing, low NO x burner (1-01-004-04) 157S A 5.7S C 26 E 5 A 9.19(S)+3.22 A No. 5 oil fired, normal firing (1-01-004-05), (1-02-004-04) 157S A 5.7S C 47 B 5 A 10 B No. 5 oil fired, tangential firing (1-01-004-06) 157S A 5.7S C 32 B 5 A 10 B No. 4 oil fired, normal firing (1-01-005-04), (1-02-005-04) 150S A 5.7S C 47 B 5 A 7 B No. 4 oil fired, tangential firing (1-01-005-05) 150S A 5.7S C 32 B 5 A 7 B No. 2 oil fired (1-01-005-01), (1-02-005-01), (1-03-005-01) 142S h A 5.7S C 24 D 5 A 2 A No.2 oil fired, LNB/FGR, (1-01-005-01), (1-02-005-01), (1-03-005-01) 142S h A 5.7S A 10 D 5 A 2 A Table 1.3-1. (cont.)

1.3-12 EMISSION FACTORS 5/10 SO 2 b SO 3 c NO x d CO e Filterable PM f Firing Configuration (SCC)a Emission Factor (lb/10 3 gal)EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal) EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal) EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal)EMISSIONFACTOR RATING Emission Factor (lb/10 3 gal) EMISSION FACTOR RATING Boilers < 100 Million Btu/hr No. 6 oil fired (1-02-004-02/03) (1-03-004-02/03) 157S A 2S A 55 A 5 A 9.19(S)+3.22 i B No. 5 oil fired (1-03-004-04) 157S A 2S A 55 A 5 A 10 i A No. 4 oil fired (1-03-005-04) 150S A 2S A 20 A 5 A 7 B Distillate oil fired (1-02-005-02/03)

(1-03-005-02/03) 142S A 2S A 20 A 5 A 2 A Residential furnace (A2104004/A2104011) 142S A 2S A 18 A 5 A 0.4 g B a To convert from lb/103 gal to kg/103 L, multiply by 0.120. SCC = Source Classification Code.

b References 1-2,6-9,14,56-60. S indicates that the weight % of sulfur in the oil should be multiplied by the value given. For example, if the fuel is 1% sulfur, then S = 1.

c References 1-2,6-8,16,57-60. S indicates that the weight % of sulfur in the oil should be multiplied by the value given. For example, if the fuel is 1% sulfur, then S = 1.

d References 6-7,15,19,22,56-62. Expressed as NO2. Test results indicate that at least 95% by weight of NOx is NO for all boiler types except residential furnaces, where about 75% is NO. For utility vertical fired boilers use 105 lb/103 gal at full load and normal (>15%) excess air. Nitrogen oxides emissions from residual oil combustion in industrial and commercial boilers are related to fuel nitrogen content, estimated by the following empiri cal relationship: lb NO2 /103 gal = 20.54 + 104.39(N), where N is the weight % of nitrogen in the oil. For example, if the fuel is 1% nitrogen, then N = 1.

e References 6-8,14,17-19,56-61. CO emissions may increase by factors of 10 to 100 if the unit is improperly operated or not well maintained.

f References 6-8,10,13-15,56-60,62-63. Filterable PM is that particulate collected on or prior to the filter of an EPA Method 5 (or equivalent) sampling train. Particulate emission factors for residual oil combustion are, on average, a function of fuel oil sulfur content where S is the weight % of sulfur in oil. For example, if fuel oil is 1% sulfur, then S = 1.

g Based on data from new burner designs. Pre-1970's burner designs may emit filterable PM as high as 3.0 1b/103 gal.

h The SO2 emission factor for both no. 2 oil fired and for no. 2 oil fired with LNB/FGR, is 142S, not 157S. Errata dated April 28, 2000. Section corrected May 2010.

i The PM factors for No.6 and No. 5 fuel were reversed. Errata dated April 28, 2000. Section corrected May 2010.

1.3-14 EMISSION FACTORS 5/10 Table 1.3-3. EMISSION FACTORS FOR TOTAL ORGANIC COMPOUNDS (TOC), METHANE, AND NONMETHANE TOC (NMTOC) FROM UNCONTROLLED FUEL OIL COMBUSTION a EMISSION FACTOR RATING: A Firing Configuration (SCC) TOC b Emission Factor (lb/10 3 gal) Methane b Emission Factor (lb/10 3 gal) NMTOC b Emission Factor (lb/10 3 gal) Utility boilers No. 6 oil fired, normal firing (1-01-004-01) 1.04 0.28 0.76 No. 6 oil fired, tangential firing (1-01-004-04) 1.04 0.28 0.76 No. 5 oil fired, normal firing (1-01-004-05) 1.04 0.28 0.76 No. 5 oil fired, tangential firing (1-01-004-06) 1.04 0.28 0.76 No. 4 oil fired, normal firing (1-01-005-04) 1.04 0.28 0.76 No. 4 oil fired, tangential firing (1-01-005-05) 1.04 0.28 0.76 Industrial boilers No. 6 oil fired (1-02-004-01/02/03) 1.28 1.00 0.28 No. 5 oil fired (1-02-004-04) 1.28 1.00 0.28 Distillate oil fired (1-02-005-01/02/03) 0.252 0.052 0.2 No. 4 oil fired (1-02-005-04) 0.252 0.052 0.2 Commercial/institutional/residential combustors No. 6 oil fired (1-03-004-01/02/03) 1.605 0.475 1.13 No. 5 oil fired (1-03-004-04) 1.605 0.475 1.13 Distillate oil fired (1-03-005-01/02/03) 0.556 0.216 0.34 No. 4 oil fired (1-03-005-04) 0.556 0.216 0.34 Residential furnace (A2104004/A2104011) 2.493 1.78 0.713 a To convert from lb/103 gal to kg/103 L, multiply by 0.12. SCC = Source Classification Code.

b References 29-32. Volatile organic compound emissions can increase by several orders of magnitude if the boiler is improperly operated or is not well maintained.

5/10 External Combustion Sources 1.3-21 Table 1.3-9. EMISSION FACTORS FOR SPECIATED ORGANIC COMPOUNDS FROM FUEL OIL COMBUSTION a Organic Compound Average Emission Factor b (lb/10 3 Gal) EMISSION FACTOR RATING Benzene 2.14E-0 4 C Ethylbenzene 6.36E-05 c E Formaldehyde d 3.30E-0 2 C Naphthalene 1.13E-0 3 C 1,1,1-Trichloroethane 2.36E-0 4 c E Toluene 6.20E-0 3 D o-Xylene 1.09E-0 4 c E Acenaphthene 2.11E-0 5 C Acenaphthylene 2.53E-0 7 D Anthracene 1.22E-06 C Benz(a)anthracene 4.01E-06 C Benzo(b,k)fluoranthene 1.48E-0 6 C Benzo(g,h,i)perylene 2.26E-0 6 C Chrysene 2.38E-0 6 C Dibenzo(a,h) anthracene 1.67E-06 D Fluoranthene 4.84E-0 6 C Fluorene 4.47E-0 6 C Indo(1,2,3-cd)pyrene 2.14E-0 6 C Phenanthrene 1.05E-0 5 C Pyrene 4.25E-0 6 C OCDD 3.10E-09 c E a Data are for residual oil fired boilers, Source Classification Codes (SCCs) 1-01-004-01/04.

b References 64-72. To convert from lb/10 3 gal to kg/10 3 L, multiply by 0.12.

c Based on data from one source test (Reference 67).

d The formaldehyde number presented here is based only on data from utilities using No. 6 oil. The number presented in Table 1.3-7 is based on utility, commercial, and industrial boilers.

Table 1.3-11. EMISSION FACTORS FOR METALS FROM UNCONTROLLED NO. 6 FUEL OIL COMBUSTION a Average Emission Factorb, d (lb/10 3 Gal) EMISSION FACTOR RATING Metal 5.25E-03 c E Antimony Arsenic 1.32E-03 C Barium 2.57E-03 D Beryllium 2.78E-05 C Cadmium 3.98E-04 C Chloride 3.47E-01 D Chromium 8.45E-04 C Chromium VI 2.48E-04 C Cobalt 6.02E-03 D Copper 1.76E-03 C Fluoride 3.73E-02 D Lead 1.51E-03 C Manganese 3.00E-03 C Mercury 1.13E-04 C Molybdenum 7.87E-04 D Nickel 8.45E-02 C Phosphorous 9.46E-03 D Selenium 6.83E-04 C Vanadium 3.18E-02 D Zinc 2.91E-02 D a Data are for residual oil fired boilers, Source Classification Codes (SCCs) 1-01-004-01/04.

b References 64-72. 18 of 19 sources were uncontrolled and 1 source was controlled with low efficiency ESP. To convert from lb/10 3 gal to kg/10 3 L, multiply by 0.12.

c References 29-32,40-44.

d For oil/water mixture, reduce factors in proportion to water content of the fuel (due to dilution). To adjust the listed values for water content, multiply the listed value by 1-decimal fraction of water (ex: For fuel with 9 percent water by volume, multiply by 1-0.9=.91).

5/10 External Combustion Sources 1.3-23 EMISSION FACTORS10/963.3-6Table 3.3-1. EMISSION FACTORS FOR UNCONTROLLED GASOLINEAND DIESEL INDUSTRIAL ENGINES aPollutantGasoline Fuel(SCC 2-02-003-01, 2-03-003-01)Diesel Fuel(SCC 2-02-001-02, 2-03-001-01)EMISSIONFACTORRATINGEmission Factor(lb/hp-hr)(power output)Emission Factor(lb/MMBtu)(fuel input)Emission Factor(lb/hp-hr)(power output)Emission Factor(lb/MMBtu)(fuel input)

NO x 0.0111.630.0314.41D CO6.96 E-03 d 0.99 d6.68 E-030.95D SO x5.91 E-040.0842.05 E-030.29DPM-10 b7.21 E-040.102.20 E-030.31D CO 2 c 1.08 154 1.15 164 BAldehydes 4.85 E-040.074.63 E-040.07D TOC Exhaust 0.0152.102.47 E-030.35D Evaporative6.61 E-040.090.000.00E Crankcase4.85 E-030.694.41 E-050.01E Refueling1.08 E-030.150.000.00E aReferences 2,5-6,9-14. When necessary, an average brake-specific fuel consumption (BSFC) of7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr. To convert from lb/hp-hr to kg/kw-hr, multiply by 0.608. To convert from lb/MMBtu to ng/J, multiply by 430. SCC = SourceClassification Code. TOC = total organic compounds.

bPM-10 = particulate matter less than or equal to 10m aerodynamic diameter. All particulate isassumed to be 1m in size.

cAssumes 99% conversion of carbon in fuel to CO 2 with 87 weight % carbon in diesel, 86 weight %carbon in gasoline, average BSFC of 7,000 Btu/hp-hr, diesel heating value of 19,300 Btu/lb, andgasoline heating value of 20,300 Btu/lb.

dInstead of 0.439 lb/hp-hr (power output) and 62.7 lb/mmBtu (fuel input), the correct emissionsfactors values are 6.96 E-03 lb/hp-hr (power output) and 0.99 lb/mmBtu (fuel input), respectively.This is an editorial correction. March 24, 2009

Table3.4-1.GASEOUSEMISSIONFACTORSFORLARGESTATIONARYDIESELANDALLSTATIONARYDUAL-FUELENGINES a PollutantDieselFuel(SCC2-02-004-01)DualFuel b(SCC2-02-004-02)EmissionFactor (lb/hp-hr)(poweroutput)EmissionFactor (lb/MMBtu)(fuelinput)

EMISSION FACTOR RATINGEmissionFactor (lb/hp-hr)(poweroutput)EmissionFactor (lb/MMBtu)(fuelinput)

EMISSION FACTOR RATING NO x Uncontrolled0.0243.2B0.0182.7 D Controlled 0.013 c 1.9 c BNDND NA CO5.5E-030.85C7.5E-031.16 D SO x d8.09E-03S 1 1.01S 1 B4.06E-04S 1+9.57 E-03S 2 0.05S 1+0.895S 2 B CO 2 e1.16165B0.772110 B PM 0.0007 c 0.1 c BNDND NATOC(asCH 4)7.05E-040.09C5.29E-030.8 D MethaneffE3.97E-030.6 E Nonmethane f f E1.32E-03 0.2 g E aBasedonuncontrolledlevelsforeachfuel,fromReferences2,6-7.Whennecessary,theaverageheatingvalueofdieselwasassumedtobe19,300Btu/lbwithadensityof7.1lb/gallon.Thepoweroutputandfuelinputvalueswereaveragedindependentlyfromeachother, becauseoftheuseofactualbrake-specificfuelconsumption(BSFC)valuesforeachdatapointandoftheuseofdatapossiblysufficientto calculateonly1ofthe2emissionfactors(e.g.,enoughinformationtocalculatelb/MMBtu,butnotlb/hp-hr).Factorsarebasedon averagesacrossallmanufacturersanddutycycles.Theactualemissionsfromaparticularengineormanufacturercouldvaryconsiderably fromtheselevels.Toconvertfromlb/hp-hrtokg/kw-hr,multiplyby0.608.Toconvertfromlb/MMBtutong/J,multiplyby430.SCC=

SourceClassificationCode.

bDualfuelassumes95%naturalgasand5%dieselfuel.

cReferences8-26.ControlledNO xisbyignitiontimingretard.

dAssumesthatallsulfurinthefuelisconvertedtoSO 2.S 1=%sulfurinfueloil;S 2=%sulfurinnaturalgas.Forexample,ifsulfercontentis1.5%,thenS=1.5.eAssumes100%conversionofcarboninfueltoCO 2with87weight%carbonindiesel,70weight%carboninnaturalgas,dual-fuelmixtureof5%dieselwith95%naturalgas,averageBSFCof7,000Btu/hp-hr,dieselheatingvalueof19,300Btu/lb,andnaturalgas heatingvalueof1050Btu/scf.

fBasedondatafrom1engine,TOCisbyweight9%methaneand91%nonmethane.

gAssumesthatnonmethaneorganiccompoundsare25%ofTOCemissionsfromdual-fuelengines.Molecularweightofnonmethanegas streamisassumedtobethatofmethane.10/96StationaryInternalCombustionSources 3.4-5 Table3.4-3.SPECIATEDORGANICCOMPOUNDEMISSIONFACTORSFORLARGEUNCONTROLLEDSTATIONARYDIESELENGINES aEMISSIONFACTORRATING:E PollutantEmissionFactor (lb/MMBtu)(fuelinput)

Benzene b7.76E-04 Toluene b2.81E-04 Xylenes b1.93E-04 Propylene2.79E-03 Formaldehyde b7.89E-05 Acetaldehyde b2.52E-05 Acrolein b7.88E-06 aBasedon1uncontrolleddieselenginefromReference7.SourceClassificationCode2-02-004-01.Notenoughinformationtocalculatetheoutput-specificemissionfactorsof lb/hp-hr.Toconvertfromlb/MMBtutong/J,multiplyby430.

bHazardousairpollutantlistedintheCleanAirAct

.10/96StationaryInternalCombustionSources 3.4-7 Table3.4-4.PAHEMISSIONFACTORSFORLARGEUNCONTROLLEDSTATIONARYDIESELENGINES aEMISSIONFACTORRATING:E PAHEmissionFactor (lb/MMBtu)(fuelinput)

Naphthalene b1.30E-04 Acenaphthylene9.23E-06 Acenaphthene4.68E-06 Fluorene1.28E-05 Phenanthrene4.08E-05 Anthracene1.23E-06 Fluoranthene4.03E-06 Pyrene3.71E-06 Benz(a)anthracene6.22E-07 Chrysene1.53E-06 Benzo(b)fluoranthene1.11E-06 Benzo(k)fluoranthene<2.18E-07 Benzo(a)pyrene<2.57E-07 Indeno(1,2,3-cd)pyrene<4.14E-07 Dibenz(a,h)anthracene<3.46E-07 Benzo(g,h,l)perylene<5.56E-07TOTALPAH<2.12E-04 aBasedon1uncontrolleddieselenginefromReference7.SourceClassificationCode2-02-004-01.Notenoughinformationtocalculatetheoutput-specificemissionfactorsoflb/hp-hr.To convertfromlb/MMBtutong/J,multiplyby430.

bHazardousairpollutantlistedintheCleanAirAct

.EMISSIONFACTORS10/96 3.4-8 Annual Greenhouse Gas Emissions Inventory Summary, 2010 - 2014Metric Tons of Carbon Dioxide Equivalent Emissions, 2010

-2014 YearCombustion SourcesWorkforce CommutingTotal 2010 6472,7223,369 20111,5132,7224,235 20122,0942,7224,816 20132,7662,7225,48 8 20141,6842,7224,406 Annual Greenhouse Gas Inventory Summary, Supporting CalculationsA. Permitted Stationary and Portable Combustion SourcesCarbon dioxide equivalent emissions for the stationary and portable diesels, and portablediesel-fired boiler were calculated annually based on total fuel usage of all emission sourceswithin these categories (see Table A-3). For the portable gasoline engines, carbon dioxideequivalent emissions were calculated based on total fuel usage (see Table A-3). Calculationsare included in this attachment.Table A-3Total Fuel Usage, 2010 - 2014 Emission Source20102011201220132014Stationary Diesels (>600 HP)52,98668,64861,56262,13956,477Stationary Diesels600 HP)2,6052,6053,1852,6247,270Portable Diesel Boiler 064,46765,280200,94079,815Portable Diesels600 HP)7,46811,97474,5294,50020,902(a)Total 63,059147,694204,556270,2 0 3164,464Gasoline Engines110110 0 0 0 (b)Total110110 0 0 0a. Assumed that fuel usage was all fuel deliveries made by Jackie Bee in 2014.

b.Value of 7,317 gallons reported in the Annual Air Emissions Report was not associated withEmission Point 23-02 (Portable Outage/Maintenance Gasoline Engines).B. Workforce TransportBased on statistical information obtained from the U. S. Census Bureau (USCB), 10.5 percentof U.S. residents carpool to work (USCB 2014). As of February 2014, there were 640 full-timeemployees employed at the Waterford 3 (Table 2.5-1 of WF3 Environmental Report), and isbeing assumed that this employment number remained consistent over previous years.Utilizing the USCB 10.5 percent statistic, it is assumed that approximately "67" of theseemployees would car pool (640 x 10.5%) to work every day. Therefore, a value of "573"passenger vehicles per day was utilized, which would be considered conservative since thenumber of employees traveling to the site on weekends would be less than that during thenormal work week of Monday - Friday.Based on information obtained from the Environmental Protection Agency's Greenhouse GasEquivalencies Calculator, the CO 2e/vehicle/year was estimated to be 4.75 metric tons basedon the 2011 average vehicle miles of 11,318 miles per year, and the weighted averagecombined fuel economy of cars and light trucks at 21.4 miles per gallon (EPA 2014a). Based on Table A-1 to Subpart A of 40 CFR Part 98, carbon dioxide has a global warming potential(100-year time horizon) of "1" (EPA 2014a). Therefore, the metric tons of carbon dioxideequivalent (CO 2e) emissions that would have been generated during the years of 2010through 2014 as a result of Waterford 3 employees commuting to and from work would be asfollows:Year CO 2 e metric tons(a)20102,72220112,72220122,72220132,72220142,722a. 573 vehicles x 4.75 metric tons CO 2e/vehicle/year x 1 (GWP)REFERENCESEPA (U.S. Environmental Protection Agency). 2014a. Greenhouse Gas EquivalenciesCalculator, Calculations and Reference Page. Retrieved from<http://www.epa.gov/cleanenergy/energy-resources/refs.html> (accessed April 24, 2014).EPA. 2014b. Table A-1 to Subpart A of 40 CFR Part 98. April 22, 2014.USCB (U.S. Census Bureau). 2014. Random Samplings, Green Stats. Retrieved from<http://blogs.census.gov/2011/04/20/green-stats/> (accessed April 24, 2014).

Stationary and Portable Diesels, and Portable Diesel BoilerCarbon Dioxide Equivalent Emission Calculations 2010 Stationary Diesels, Portable Diesel Boiler and Portable DieselsEnter Fuel Use (gal/yr) 63,059Pollutants Global Warming Potential aEmission Factor (lb/MMBtu) bMMBtu/yr c lbs/yr d CO 2 e metrictons/yr e Carbon Dioxide 1 163.1 8,702 1,419,319 644Nitrous Oxide 298 0.001 8,702 9 1.2 Methane 25 0.007 8,702 61 0.7TOTAL 646a. Based on Table A-1 to Subpart A of 40 CFR Part 98.b. Based on Table 1 of EPA's 2014 GHG Emission Factor Hub for Number 2 diesel fuel oil (http://www.epa.gov/climateleadership/documents/ emission-factors.pdf). Emission factors were converted to lb/MMBtu (see below).