ML043560248
| ML043560248 | |
| Person / Time | |
|---|---|
| Site: | Catawba  |
| Issue date: | 12/15/2004 |
| From: | Peed C Duke Power Co |
| To: | Foster B Office of Nuclear Reactor Regulation, State of SC, Dept of Health & Environmental Control |
| References | |
| 7099 3400 0008 2838 1497, SC0004278 | |
| Download: ML043560248 (116) | |
Text
Duke PowerCatawba Duke Power Nuclear Station P yPower. 4800 Concord Road A bD,E-V.1vv York, SC 29745 (803) 831-3000 December 15, 2004 South Carolina Department of Health and Environmental Control ATTN: Betty Lou Foster NPDES Administration Section Bureau of Water 2600 Bull Street Columbia, SC 29201
Subject:
Catawba Nuclear Station NPDES Permit #SC0004278 Renewal Application Certified: 7099 3400 0008 2838 1497
Dear Ms. Foster:
Attached please find a completed NPDES permit renewal application consisting of the following documents:
- Forn I - General Infonnation (With Quad Map)
- Supplemental Information for NPDES Pennit
- Fonn 2C - Application for Permit to Discharge Wastewater (Existing Facility)
- Forn 2E - Facilities Which Do Not Discharge Process Wastewater
- Summary of Requested NPDES Pennit Changes
- Sludge Disposal Supplement for NPDES and ND Permit Applications Please note 3 16(a) demonstration data was submitted with the March 1997 permit application. Additional data is not being submitted with this pennit application; however we request a continued 316(a) variance and renewal of the current thermal limits.
Also, the NOI for storm water is on file with SCDHEC and is not being included with this application. Should you have questions regarding this application, please contact Margot Rott at (803) 831-3180.
Sincerely, Cheryl Peed, Manager CNS Environment, Health & Safety cc: USNRC Document Control Desk (Docket # 50-413 & 50-414)
E.F. Guthrie, NRC Senior Resident Inspector S.E. Peters, NRC Project Manager (CNS)
Please print or type in the unshaded areas only (filln areas are spaced for elite type, I.e.. 12 charactersinch). For Approved. OMB No. 2040-0086. Approval expires 5-31-92 FORMI--
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IL'POLLTANT I ,.A CARACTERSTICS -and for~the leial authorizationunder Which IuIN:I MU I 'OmpleleAturru.n.I %t to aelermine wieluer you reem 0 aunuil any permit upplicauon torms to uie t-A. IT you answer 7yes .- o any questions, you must submit this form and the supplemental from listed In the parenthesis following the question.)Mark 'X' In the box In the third column If the supplemental form Is attached.lIf you answer "not to each question, you need not submit any of these forms., You may answer "no"f your activity Is excluded from permit requirements; see Section C of the Instructions. See also, Section D of the instructions for definitions of bold-faced terms. .-S
",;. ' ' _ MSARSPEC
_ SPECIFIC QUESTIO S
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,NO ';,YES-. ____YE FORM . *-.--. ~ YS N.*O NO ATC-E M ATTCAD A. ;Is this faclity a publicly owned treatment works B. Does or- will this facility, (either existing or.
which results in a discharge to waters of the. [clJd.,-a concentrated- -animal
-U.S.?(FORMA) . feeding operation: or aquatic Wanimal production facility which results In a discharge 16 17 .18 : towatersoftheU.S.?(FORM2B) : --. -. -j 121 C. Is!. this .facility which. currently results in T. D. Is this proposal facility (other than those described 1. T discharges to waters 'ofthe U.S.. other than El In A or B above) which will result In a discharge those described In A or B above? (FORM 2C) 22 23 24 to waters of the U.S.? (FORM 2D) 25 26 27 E. Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes? (FORM 3) i a f municipal effluent below the lowermost stratum containing, within one quarter mile of the well 5 1 [
.4 I" bore, underground sources of drinking water?
_ _ _ _ _ _ _ _ _ _ _ 28__ *W29 30 ) T 31RM 32_3 G. Do you or will you Inject at this facility any H. Do you or will you inject at thisfalityfluids for produced water other fluids which are brought to special processes such as mining of sufer by the the surface In connection with conventional oil or natural gas production. Inject fluids used for
[ 0 [] Frasch process, solution mining of minerals. In situ combustion of fossilfuel orrecoveryof 0 1 enhanced recovery of oil or natural gas, or Inject geothermal energy? (FORM 4) fluids for storage . of liquid, hydrocarbons?
(FORM 4) '_* . -- 34 35 36 37 38 39 I. Is this facility a .proposed stationary source J. Is this facility a proposed stationary source which Is one of the 28 Industrial categories listed which is NOT one of the 28 industrial categories In the Instructions and which will potentially emit 100 tons per year of any air pollutant regulated El 09 ED listed In the Instructions and which will potentially emit 250 tons per year of any air pollutant LJ ESI 0 under the Clean Air Act and may affect or be regulated under the Clean Air Act and may affect _
located In an attainment area? (FORM5 42 or be located In an attainment are? (FORM 5)
-i 40 41 43 44 45 111. NAME OF FACILITY _ _
4+ SKIP lCatawba Nuclear Station 15 6-29 30 69 IV. FACILITY CONTACT
- - . A. NAME & TITLE (last, first & title) - B. PHONE (area code & no.
r' Peed, Cheryl EHS Manager 803 831 3361 15 1 16 45 46 48 _ 49 51 _ 52 .55 V. FACILITY MAILING ADDRESS
.A. STREET OR P.O. BOX C 4800 Concord Road 15 l 16 45 B. CITY OR TOWN C. STATE D. ZIP CODE c YorkS I 29745 15 16 40 1 41 42 l 47 51 VI. FACILITY LOCATION T
. A. STREET, ROUTE NO. OR OTHER SPECIFIC IDENTIFIER X C Highway 274
- 5U 15 16 45 B. COUNTY NAME York 46 70 C. CITY OR TOWN D. STATE E. ZIP CODE F. COUNTY CODE C Newport SC 29745 15 l 16 40 41 42 47 51 52 54 I CONTINUED ON REVERSEIZ ,s, EPA FORMI 3510-1 (8-90) II
CONTINUED FROM THE FRONT Vii: SIC CODES (4-digit, in order of priority)_1M A. FIRST B. SECOND r; c 4911 (specify) 7 (specify) 7 16 .7 Electric Services 15 1615 16 19~
C. THIRD - - D.-FOURTH c (specify) (specify) 7 i t 7 16 15 17 I 15 16 19-Vill. OPERATOR INFORMATION A.NAME -- , B. Is the name listed In Item*
C Duke Energy Corporation (see attachment for listof owners) VII-;Aalso theowner?,
18 11955 .;YES.~
C.STATUS OF OPERATOR (Enter the appropriate letter Into the answer box; if !Other, specif) . D.PHONE (area code &no.)
F = FEDERAL M= PUBLIC (other than federal or state) P (specify) c _803 831 t 3361 S=STATE 0 =OTHER (specify) 3M I 831 336 P= PRIVATE'.' 56 1159 I1--218 F 12225 229 '
E. STREET OR P0 BOX 422 Church Street .... '
26 --
F.CITY OR TOWN G. STATE H.ZIP CODE I. INDIAN LA C Charlotte NC 28242 -Isthe facility located on Indian lands?
15 16 40 1 42 42 1 47 5 -
X. EXISTING ENVIRONMENTAL PERMITS A. NPDES (Discharges to Surface Water) D. PSD (Air Emissions from Proposed Sources) . -
C T I SC0004278 T a 9 INj P 15 16 17 18 la30 15 16 117118 .30:
B. UIC (Underground Injection of Fluids - E. OTHER (sci (Specify)
C T . 463303-1601 Landfill 15 1 6 1? 1IIS30 8 is 15 16 1?17 10 30 C. RCRA (Hazardous Wastes) E. OTHER (specify) (Specify)
C SSCDO70619796 Cl T 8 2440-0070 Air Permit 15 16 1 18 30 15 1 16 17 18a 30 Xi. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed Intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs, rivers and other surface water bodies in the map area. See instructions for precise requirements.
XII. NATURE OF BUSINESS (provide brief desci Nuclear fuel steam electric generation facility XIII. CERTIFICATION (see instructions)
I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.
A. NAME & OFFICIAL TITLE (type or print) B. SIGNATURE v . C. DATE SIGNED Dhiaa Jamil, Vice President 11(1 Catawba Nuclear Station COMMENTS FOR OFFICIAL USE ONLY EPA FORM 3510-1 (S-90)
Duke Power Company Catawba Nuclear Station NPDES Permit Renewal Catawba Owners 0 North Carolina Municipal Power Agency Number One 0 North Carolina Electric Membership Corporation S Piedmont Municipal Power Agency S Duke Energy Corporation S Saluda River Electric Cooperative, Inc.
Catawba Nuclear Station NPDES Pernit SC0004278 Catawba Owners 12/1/2004 Permit Renewal Application Page I of I I
UNITED STATES . b5 ; --- LAKE WYLI E QUADRANGLE
)EPARTMENT OF THE INTERIOR : SOUTH CAROLIF IA-NORTH CAROLINA GEOLOGICAL SURVEY g 7.5 MINUTE SE RIES (TOPOGRAPHIC)
-S
/ SE/4 CLOV ER 15' QUADRANGLE
- S gj ! J t N I'@ *. t-, t, '. '.'N j's 1.
- ON SCALE 1:24 000 I
I- 0 1 MILE 1000 0 1000 2000 3000 4000 5000 6000 7000 FEET 1 MIL I
I1* .5 0 I KILOMETRE I II UTMGRID AND1996 MAGNETICNORTH DECtJAnTON ATCENTER OFSHEET' CONTOUR INTERVAC 10 FEET NATIONAL GEODETIC VERTICAL DATUM OF 1929 I
SOUTH CAROLINA DEPARTMENT OF HEALTH AND ENVIRONMENTAL CONTROL BUREAU OF WATER (803) 8984300 LOCATION SUPPLEMENT FOR ND AND NPDES PERMIT APPLICATIONS I. Date: 12/1/2004 II. Name of Facility: Catawba Nuclear Station III. NPDES or ND Number: SC0004278 IV. If the facility is not owned by a city or towh, please answer the following question. Is the plant or discharge point/application site(s) located within the corporate limits of a city or town?
Yes, Name of city or town:
X No.
V. If the address on the application is not a specific location, please give a short description of the plant location. Example: Plant is located at the interchange of Interstate 26 and U.S. Highway #1.
The address is: Catawba~Nuclear Station 4800 Concord Road York, SC 29745 Concord Road is located off of Highway 274 approximately 2 miles south of the intersection of Highways 55, 49, and 274.
VI. For NPDES permits, please give a description of the location of each discharge point into the receiving stream using some landmark as a reference point, i.e., bridge, stream, road junction, the plant itself, etc. Example: Discharge #001 is into Johnny Creek approximately 300 feet directly behind the plant. Discharge #002 is into Doris Creek 150 feet downstream from U.S. Highway #30 bridge.
Outfalls #001, 002, and 003 discharge into the Big Allison Creek arm of Lake Wylie, approximately 1500 feet north of the Concord Road Bridge that crosses Big Allison Creek.
Lookingnorth from the bridge the discharge points for Outfall 001 and 003 are visible. From the facility site, the discharge points are located immediately south of the perimeter fencing.
Outfalls #004 and 005 are internal to Outfall #001.
Catawba Nuclear Station NPDES Permit SC0004278 Location Supplement Revised 12/1/2004 Penmit Renewal Application Page I of I I
VII. Please submit a copy of a U.S. Geological Survey 7 /2 minute quad sheet (or a 15 minute quad if a 7 l/2 quad is not available for the area) with the discharge point(s) identified. The entire quad sheet need not be submitted. An 8 '/2 by 11 inch photocopy of the applicable portion of the map is sufficient. The quad sheet name must be provided on the copy submitted to the Department. USGS Maps are available at the SC Department of Natural Resources/Map and Information Center, 2221 Devine Street, Suite 222, Columbia, SC 29205. Telephone #: (803) 734-9108 The 7.5 minute Lake Wylie Quadrangle, South Carolina - North Carolina, SE/4 Clover 15' Quadrangle map is attached.
Catawba Nuclear Station NPDES Permit SC0004278 Location Supplement Revised 12/1/2004 Penmit Renewal Application Page 1 of I I
UNITED STATES LAKE WYLIE QUADRANGLE
)EPARTMENT OF THE INTERIOR SOUTH CAROLINA-NORTH CAROLINA G'EOLOGICAL SURVEY 7.5 MINUTE SERIES (TOPOGRAPHIC)
SE/4 CLOVER 15' QUADRANOLE r/S,,,
I N 4 -A' l.IA :~V-
- ~
m IN 0 1 MILE 0-02' 1000 0 1000 2000 3000 4000 5000 6000 7000 FEET 1 MIL
- l. .5 0 1 KILOMETRE i
.:I I
CONTOUR INTERVAL 10 FEET I11 AND 1996 MAGNETIC NORTH UTMGRID ;
ATCENTER Of SHEET NATIONAL GEODETIC VERTICAL DATUM OF 1929 DECLINATION
CATAWBA NUCLEAR STATION NPDE.S PERMIT #SC0004278 RENEWAL APPLICATION 12/01/2004 l
- 1. General Station Description
- 2. Station Intakes 2.1. Low Pressure Service Water Intake Structure 2.2. Nuclear Service Water System Intake Structure
- 3. Outfall 001 3.1. Inputs 3.1.1. Low Pressure Service Water 3.1.2. Liquid Radioactive Waste - Internal Outfall 004 3.1.3. Cooling Tower Blowdown - Internal Outfall 005 3.1.4. Nuclear Service Water 3.2. Flows 3.3. Chemicals & Characteristics of Discharge
- 4. Outfall 002 4.1. Description of Discharge 4.1.1. Service Building Sump 4.1.2. Water Treatment Room 4.1.3. Diesel Generator Room Sumps 4.1.4. Turbine Building Sumps 4.1.5. Auxiliary Building Floor Drain Sumps 4.1.6. Diesel Generator Catchment Sumps 4.1.7. Step-up Transformers Base Drainage Sumps 4.1.8. Sulfuric Acid Tank Containment Drainage Sump 4.1.9. Yard Drain Collection System Sumps Catawba Nuclear Station NPDES Permit SC0004278 Table of Contents Revised 12/7/2004 iPennit Renewal Application Page lof 3
4.1.10. Miscellaneous 4.2. Flows 4.3. Chemicals & Characteristics of Discharge 4.4. Treatment 4.4.1. Initial Holdup Pond 4.4.2. Settling Ponds A & B
- 5. Outfall 003 5.1. Description of Discharge 5.2. Flows 5.3. Chemicals & Characteristics of Discharge 5.4. Treatment
- 6. Outfall 004
- 7. Outfall 005
- 8. Miscellaneous Operations 8.1. Fire Protection System 8.2. Drinking Water System 8.3. Cooling Tower Drainage 8.4. Miscellaneous System and Component Cleanings 8.4.1. Mechanical Cleanings 8.4.2. Chemical Cleanings 8.5 Storm Water Discharges 8.6 Dye Use Catawba Nuclear Station NPDES Permit SC0004278 Table of Contents Revised 12/7/2004 Permit Renewal Application Page 2of 3
- 9. Other Environmental Permits 9.1. Landfill 9.2. Air Pennit 9.3. RCRA Hazardous Waste 9.4. Underground Storage Tank Permits 9.5. Asbestos 9.6 Laboratory Certification
- 10. Hazardous Substances 10.1. Hazardous and Toxic Substances, Table 2C-3 10.2 Hazardous Substances Under 40 CFR 117 and CERCLA
- 11. Thermal 316(a) and Impingement/Entrainment 316(b) Demonstrations
- 12. Site Layout/Drawing 12.1. General Site Layout and Identification of Outfall Locations Catawba Nuclear Station NPDES Permit SC0004278 Table of Contents Revised 12/7/2004 Permit Renewal Application Page 3of 3 I I
1.0 General Station Description The Catawba Nuclear Station is a two unit nuclear fission steam electric generating station. It is owned by Duke Energy Corporation, North Carolina Electric Membership Corporation, North Carolina Municipal Power Agency Number #1, Piedmont Municipal Power Agency, and the Saluda River Electric Cooperative, Inc. The facility is operated by Duke Power Company.
Each unit is a four loop pressurized water reactor. Reactof fuel is sintered uranium oxide pellets with zirconium alloy cladding. Reactor heat from each unit is absorbed by the reactor coolant system and produces steam in four steam generators sufficient to drive a turbine generator unit with a design gross electrical rating of 1205 megawatts.
In 2005 Catawba will be testing mixed oxide fuel, or MOX (a mixture of uranium oxide and plutonium oxide), by inserting 4 of these MOX fuel assemblies into one of the units along with 189 uranium oxide assemblies. MOX fuel is a result of the US/Soviet agreement to reduce nuclear arsenals. Catawba and McGuire Nuclear Stations were selected by the DOE to test and use MOX fuel. This change will not affect wastewater discharges.
The nuclear reaction is controlled by control rods and chemical neutron absorption. Boric acid is used as a chemical neutron absorber and to provide borated water for safety injection. During reactor operation, changes are made in the reactor coolant boron concentration.
A diagram of water use and discharges indicating average flow rates for individual waste streams of Catawba Nuclear Station is attached. Actual flow through individual systems may vary significantly depending on operating needs and meteorological conditions. The following is a brief description of the major water systems, inputs, and discharges.
The station has five permitted outfalls, three of which discharge directly into Lake Wylie. Outfall 001 discharges the Low Pressure Service Water System, Outfall 002 discharges the Conventional Wastewater Treatment System, and Outfall 003 discharges the Sanitary Wastewater System. Outfall 004 is an internal outfall discharging low level radioactive effluents through Outfall 001. Outfall 005 is also an internal outfall discharging cooling tower blowdown through Outfall 001.
In 2005 Catawba will be routing sanitary wastewater to York County. Once the tie-in is complete, discharges from this outfall will cease and the outfall will no longer be needed.
Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page I of 22'
2.0 Station Intakes There are two intake structures to withdraw raw water from Lake Wylie, one for the Low Pressure Service Water System and one for the Nuclear Service Water System. Lake water enters each intake structure through trash racks that remove large debris. The Low Pressure Service Water Intake also has traveling screens, which remove smaller debris.
2.1 Low Pressure Service Water Intake Structure There are a total of six pumps on the Low Pressure Service Water intake structure. Three are for the Low Pressure Service Water System and three are for the Fire Protection System. Each Low Pressure Service Water pump is in a separate bay equipped with a trash rack and traveling screen.
The trash racks and traveling screens remove trash and prevent debris from entering the pumps.
Accumulated trash is cleaned from the' racks by hand and from the screens by a backwash system. The intake screens can be backwashed manually or automatically, or as frequently as the differential pressure alarms on each pump bay indicate the need. Each screen is backwashed every ten hours for approximately 10 minutes per screen. The water is returned to Lake Wylie at the intake bay. The trash and debris collected from the racks and screens arc disposed in a permitted landfill. No chemicals are used in the backwash operation.
The three Low Pressure Service Water pumps are separated by precast concrete wall panels that form pump wells. Each pump withdraws water from its well and discharges to a common header. After leaving the common header, flow is divided into two main headers, A and B. Both headers are in service during normal operations.
Upon entering both headers A and B, flow passes through strainers designed to remove still finer debris from the lake water. These strainers backwash automatically based upon either a set time interval or increase in differential pressure. This backwash water passes through each strainer and drains back to the lake in the vicinity it was originally withdrawn.
2.2 Nuclear Servicc Water System Intake Structure The Nuclear Service Water Systerii is a oncc-through cooling water system. This system supplies cooling water to various heat loads in the Auxiliary and- Reactor Buildings other than the steam side of the station.
It is served by two bodies of water - Lake Wylie and the Standby Nuclear Service Wat6r Pond - but only one pump structure. The intake in each Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page 2 of 22 I 4
water body is completely submerged approximately 30 feet below the surface of the water. The Standby Nuclear Service Water Pond and the pump structure are seismically designed with sufficient water to bring the station to a cold shutdown in case of the loss of Lake. Wylie Dam. The level of the pond is maintained via an overflow pipe to the lake and pumping capability from the lake. Water from either the pond or the lake is piped to the nuclear service water pump structure. The pump structure consists of two 330,000 gallon pits that serve to provide suction to the pumps. There are two pumps per pit. In normal Nuclear Service Water System operation, pump suction is from Lake Wylie. Pump suction can be switched to the Standby Nuclear Service Water Pond.
Additionally, during testing required by the Nuclear Regulatory Commission, the Nuclear Service Water system is aligned to discharge to the Standby Nuclear Service Water Pond rather than Outfall 001. When discharge is aligned in this manner, the pump suction can be either from the lake or the pond.
In order to maintain the temperature of the Standby Nuclear Service Water Pond within limits imposed by the Nuclear Regulatory Commission, cooler water from Lake Wylie is periodically pumped to the pond. This is dependent on current weather conditions, and the amount of time in such alignment will vary.
The typical temperature change of the water removed from and returned to the Standby Nuclear Service Water Pond is 2 OF. The temperature change would be greater if alignment to the pond should occur during the process of shutdown. The discharge line to the pond splits and discharges flow to separate points of the pond to assure that temperatures throughout the pond remain uniform.
Periodically to ensure operability, the nuclear service water pump bearing oil cooler and the motor cooler are cleaned to remove silt and sediment deposits which restrict pump cooling water flow. Approximately fifty gallons of cleaning solution are injected into the bearing cooling water flowv path for each pump. A soda ash (Na 2 CO3 ) solution is used for rinsing the pump bearings. The cleaning solutions are captured in drums and are used as treatment chemicals in the conventional treatment ponds. This cleaning is not considered a chemical metal cleaning because it does not attack the base metal of the piping.
3.0 Outfall 001 3.1 Inputs Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Ayplication Page 3 of 22
Outfall 001 discharges subsurface through a concrete structure directly into the Big Allison Creek arm of Lake Wylie and is comprised of the:
Low Pressure Service Water System Liquid Radioactive Waste Outfall 004 Cooling Tower Blowdown Outfall 005 Nuclear Service Water System.
A detailed description of each input follows.
3.1.1 Low Pressure Service Watcr The Low Pressure Service Water System supplies water from Lake Wylie for cooling of various "secondary" plant systems, makeup water to the main condenser recirculating cooling water system, and makeup water for the filtered water and demineralized water systems. This system also receives discharges from the Nuclear Service Water System, Liquid Radioactive Waste System (Outfall 004), and Cooling Tower Blowdown (Outfall 005).
3.1.2 Liquid Radioactive Waste - Internal Outfall 004 Outfall 004 discharges flow from the liquid radioactive waste system. This flow combines with plant once through cooling water before discharging through Outfall 001.
The Liquid Radioactive Waste System collects waste from radioactively contaminated system drainage, floor and equipment drains, laundry waste, and ventilation unit drains. All waste meets Nuclear Regulatory Commission (NRC) requirements (10 CFR Part 20 and 10 CFR Part 50) prior to release, with the type of processing dependant on the type of waste. The maximum discharge rate from radioactive waste is 250 gpm. Chemicals that may be present in the liquid radioactive waste system include among others:
boric acid borax dispersants ammonia sodium nitrite lithium hydroxide ethylene glycol tolytriazole (TTA) sodium molybdate detergents hypobromous acid hydrazine carbohydrazide hypochlorite hydrogen peroxide antifoam 3-methoxypropylamine dimethylamine (DMA)
(MPA)
Catawba Nuclear Station NPDES Pennit SC0004278 Narrative Description
- Revised 12/7/2004 Penmit Renewal Application Page 4 of 22 I
pump bearing cleaning laboratory chemicals surfactants chemicals polyelectrolytes commercial cleaning products degreasers sodium bicarbonate sodium hydroxide sodium metasilicate mercaptobenzothiazole (MBT) trisodium phosphate microbiocides, including isothiazolone, gluteraldehyde, and dibromo nitriloproprionamide (DBNPA)
Coagulant sulfuric acid Additionally, non-contaminated sumps can become contaminated with radioactivity. When this occurs, the liquid is pumped to the Liquid Radioactive Waste System for treatment. The decision on the method of treatment depends on the amount of waste needing treatment and the quality qf the water being treated. Chemicals listed as being in the Turbine Building Sump (in Section 4.0, titled Outfall 002) could then be in the radioactive waste system (Outfall 004). Solids or concentrated radioactive by-product generated in the treatment process are disposed of in a State and Nuclear Regulatory Commission licensed low level radioactive waste disposal facility.
3.1.3 Cooling Tower BlowdoWn - Intcrnal Outfall 005 The Condenser Circulating Water System provides the heat sink for the main condenser and the feedwater pump turbine condensers. This is a closed loop cooling system containing 7.5 million gallons of service water per unit.
After passing through condensers, the warm water is pumped to the top of the cooling towers. This water is distributed uniformly across the top of the cooling towers (three per unit) and cascades by gravity to the floor of each cooling tower. Falling water cascades over fill material which breaks the water into droplets.
Fans on the top of the towers pull ambient air in from the sides and past the falling water. From the floor of the cooling tower, water flows by gravity back to the condenser.
Due to the concentrating effect of evaporation, a blowdown rate of approximately 5000 gallons per minute is maintained per unit.
Bfovwdown rates can be higher or lower depending upon system water quality. The Low Pressure Service Water system provides makeup to maintain the system volume.
Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page 5 of 22 I
Sodium hypochlorite and sodium bromide are added to the cooling towers periodically to provide an oxidizing biocide to control biological growth. If necessary, sulfuric acid is added to lower pH.
A polyacrylate dispersant may be added to minimize solids deposition from the lakewater.
Normal oxidant additions range from every other day to once per week based on seasonal conditions. During biocidal treatment, the blowdown line to Outfall 001 is secured. During those times when blowdown is necessary to prevent scaling and control algae growth, if chlorine concentrations exceed discharge specifications, sodium sulfite or sodium nitrite can be added to the cooling towers in stoichiometric proportions for dechlorination.
Periodically, sections of the Nuclear Service Water system which are kept in wet lay-up are drained to the condenser circulating water system. Water in these sections contain corrosion inhibitors and chemicals to control pH. These chemicals are discharged at concentrations that would not exhibit toxicity.
The cooling tower blowdown is aligned to the Low Pressure Service Water and discharges through internal Outfall 005 then to Lake Wylie through Outfall 001. During unit outages, part or all of the Condenser Circulating Water System can be drained to Outfall 001 and/or the Conventional Wastewater Treatment System, Outfall 002, through the Turbine Building sump.
3.1.4 Nuclear Service Water The Nuclear Service Water System is a once-through plant cooling water system. This system supplies cooling wvater to various heat loads in the Auxiliary and Reactor Buildings other than the steam side of the station. It is served by two bodies of water - Lake Wylie and the Standby Nuclear Service Water Pond - but only one pump structure.
As a result of microbiological growth, and siltation, chemical treatment is necessary. Polyacrylate dispersant is added to the system to control silt deposition. The discharge of the polyacrylate solution is maintained well below the No Observable Effect Concentration. Sodium hypochlorite or hypobromus acid are biocides added to the system control biological fouling and corrosion. The total residual chlorine concentration at Outfall 001 will vary over the discharge period, but the average daily discharge concentration is less than the pcnnit limit of 0.019 mg/l. The Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page 6 of 22
/
station performs a time-weighted average calculation to determine chlorine concentration for each 24-hour period as follows (example calculation):
Sample I = 0 mg/i Sample 2 = 0.127 mg/i Sample 3 = 0.124 mg/I Sample 4 = 0.081 mg/i Sample5 =0 TRC is discharged for no more than 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br />. During TRC discharge, samples are pulled every 20 minutes. During the remaining 22 hours2.546296e-4 days <br />0.00611 hours <br />3.637566e-5 weeks <br />8.371e-6 months <br />, TRC is 0 mg/L. There are 72 20-minute periods in a day.
0.127 + 0.124 + 0.081 = 0.332 mg/I 0.332 mg/l - 72 sample periods = 0.0046 mg/l daily average, which is less than the daily limit of 0.019 mr/l If similar additions are made 30 days per month, the monthly average would be 0.0046 mg/I, which is less than the monthly average of 0.11 mg/L.
In 2005 Catawba will add a dechlorination system using sodium bisulfite to the once through cooling water system prior to discharge at Outfall 001. This will allow higher biocide concentrations to be maintained in the system for better biofouling treatment. A construction permit will be submitted prior to installation of this system. After the dechlorination system is in place, chlorination/dechlorination may also be used to treat for Asiatic clams. Asiatic clam treatment will require continuous chlorination/dechlorination for approximately 21 days twice a year during spawning season.
The closed cooling system for the containment building can be automatically discharged through Outfall 001 if all power is lost to the system chiller unit. The automatic release will only occur during a loss of power to the system, which is a very infrequent event. The concentrations of layup chemicals within the. system are maintained such that no toxicity is exhibited at the Outfall.
These products used for wet lay-up and biological control in the safety related Nuclear Service Water System can be discharged to the Standby Nuclear Service Water Pond during required'system testing. Also, low concentrations of these products' may be Catawba Nuclear Station NPDES Pennit SC0004278 Narrative Description Revised 12/8/2004 Permit Renewal Application Page 7 of 22
discharged to the pond if the discharge path to Lake Wylie automatically swaps the discharge to the pond. However, product biodegradation and system demand would minimize the discharge concentration.
3.2 Flows 5 Year Average 5 Year Maximum (mgd) (mgd)
Low Pressure Service Water and Nuclear Service Water 56.49 91.53 Liquid Radioactive Waste 0.02 0.04 Cooling Tower Blowdown 12.12 14.4 Total Flow Outfall 001 68.65 105.97 3.3 Chemicals & Charactcristics Of Discharge This Outfall consists primarily of once-through cooling water from Lake Wylie. This stream is used primarily as cooling water for plant equipment and as such discharges some degree of a heat load to Lake Wylie. Because of this, the temperature is continuously monitored by in line instruments which input to the Operator Aid Computer. The temperature change as well as total flow are also measured in this manner. The computer is programmed to provide the operators an alarm when the delta temperature begins to approach the permitted limit. This allows the operators time to adjust plant operations to maintain the discharge temperature within the permit limits. At times when the temperature and flow monitoring devices are out of service for calibration or the computer is down, temperatures are measured once per day and flows are estimated at least once per day.
Additionally, temperature may be taken from the Nuclear Service Water System header, which is similar to normal intake water temperature..
4.0 Outfall 002 4.1 Description of Discharge Outfall 002 discharges flow from the Conventional Wastewater Treatment System through a parshall flume into the Big Allison Creek arm of Lake Wylie. This system consists of the following:
I Initial Holdup Pond Concrete 300,000 gallons 2 Settling Ponds Earthen 5,000,000 gals each I Final Holdup Pond Earthen 1.5 million gallons Catawba Nuclear Station NPDES Pcmnit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page 8 of 22 I
I1
Normally, inputs are received in the Initial Holdup Pond which provides a surge-dampening function to the settling ponds and also allows heavy solids to settle for periodic removal. Solids removed from the Initital Holdup Pond are dewatered and disposed in a licensed landfill. Inputs can bypass the Initial Holdup Pond and be directed to the in-service settling pond or Final Holdup Pond if necessary.
From the Initial Holdup Pond flow is directed to the in-service settling pond where chemical treatment, mixing, and aeration take place. Sulfuric acid and sodium hydroxide are added for pH control. Coagulants can also be added to facilitate the settling of small particles. Infrequently, it may be necessary to oxidize persistent chemicals with the use of hypochlorite (sodium or calcium) or hydrogen peroxide. Additionally, a defoamer may need to be added to the system to prevent foaming at the discharge.
The settling ponds are discharged directly to Lake Wylie via Outfall 002.
Treatment in the WC System is on a batch basis. Maximum discharge flowrate is 1760 gpm. Recirculation capability is available for recirculation intra- or inter-basin.
The WC System receives inputs directly from the service building sump, turbine building sumps, diesel generator catchment sumps, step-up transformer base drainage sumps, sulfuric acid tank containment drainage sump, Yard Drain Collection System Sumps, and rainwater from various sources.
4.1.1 Service Building Sump The service building sump receives inputs from the water treatment room and reverse osmosis unit, diesel generator room sumps, and the service building floor drains. The sump has an approximate holding volume of 26,500 gallons and two pumps, each with a capacity of 1350 gpm. Normal alignment is to the Conventional Wastewater Treatment System directly, but can be through the turbine building sump.
The service building floor drains receive miscellaneous leakage and drainage. Chemical inputs include among others:
hydrazine trisodium phosphate ammonia sodium molybdate sodium hydroxide sulfuric acid cationic polyelectrolytes alum ..- ethylene glycol antifoam tolytriazole (TTA) 3-methoxypropylamine
__(MPA)
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I I
commercial cleaning products laboratory chemicals citric acid hydrogen peroxide oils coagualants hypochlorite anti-scaling agents sulfamic acid dispersants microbiocides, including surfactants isothiazolone, gluteraldehyde, and dibromo nitriloproprionamide (DBNPA) boric acid dimethylamine (DMA) carbohydrazide borax mercaptobenzothiazole (MBT) sodium nitrite bead resin carbon 4.1.2 Watcr Treatment Room The Water Treatment Room produces filtered water and demineralized water. All chemicals used, all leakage and drainage, and all wastes produced go directly to the service building sump.
Filtered water is made by taking lake water, adding a coagulant, filtering up through one of two gravel-to-sand beds and chlorinating to approximately 1.5 mg/l FAC. The beds are flushed on pressure buildup with high velocity lake water.
Approximately semi-annually, or when necessary, each bed is cleaned with approximlately 200 gallons of hydrogen peroxide and a surfactant.
Demineralized water is made by passing filtered water through a carbon bed, a reverse osmosis unit, a regenerative resin bed, and a polishing ion exchange bed. There arc two carbon beds, one reverse osmosis unit, and two regenerative resin beds, and 2 polishing ion exchange beds.
Several times each year the reverse osmosis membranes are cleaned with a combination of acids, bases, and polymeric cleaning solutions. To regenerate the resin, sulfuric acid and sodium hydroxide are flushed through the bed. Each regeneration takes approximately 98 gallons of 93% sulfuric acid and 330 gallons of 50% sodium hydroxide. Regeneration occurs approximately once a month. The amounts qf required acid and caustic will vary as dictated by operational requirements.
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4.1.3 Diesel Generator Room Sumps The diesel generator room sumps receive inputs from leakage or draining the diesel generator engine cooling water system. Each of the four sumps has a volume of approximately 470 gallons and two pumps, each with a capacity of 50 gallons per minute.
The diesel generator engine cooling water systems have a volume of 2240 gallons each. The systems are treated ivith a mixture of sodium molybdate, borax (sodium tetraborate), and sodium mercaptobenzothiazole (MBT). To control bacteria, an approved biocide is added.
For incidental oil spills, an oil coalescing unit is installed between the diesel sumps and the service building sump.
4.1.4 Turbine Building Sumps The turbine building sumps receive inputs from steam generator wet lay-up chemicals, secondary system drainage, cooling tower drainage, auxiliary building floor drain sumps, and the turbine building floor drains. Each of two sumps has an approximate capacity of 12,000 gallons and three pumps, each with a capacity of 1350 gallons per minute. Normal alignment is directly to the Conventional Wastewvater Treatment System. However, hose connections on the discharge of the pumps allow rerouting to other sumps for unusual circumstances. Chemicals that may be present include among others:
hydrazine trisodium phosphate ammonia sodium bromide sodium hydroxide sulfuric acid cationic polyelectrolytes alum ethylene glycol borax tolytriazole (TTA) sodium molybdate commercial cleaning products laboratory chemicals citric acid hydrogen peroxide oils coagualants hypochlorite anti-scaling agents sulfamic acid dispersants mercaptobenzothiazole (MBT) surfactants boric acid dimethylamine (DMA) carbohydrazide 3-methoxypropylamine powdered or bead resin sodium nitrite (MPA) antifoam Microbiocides, including sulfuric acid isothiazolone, gluteraldehyde, and dibromo nitriloproprionamide (DBNPA)
Catawba Nuclear Station NPDES Pernit SC0004278 Narrative Description Revised 12/7/2004 Penmit Renewal Application Page II of 22 I
4.1.5 Auxiliary Building Floor Drain Sumps Auxiliary building floor drain sumps can be diverted to the turbine building sumps. Each sump has an approximate capacity of 500 gallons and two pumps, each with a capacity of 50 gallons per minute. Inputs consist of equipment drainage, air handling unit condensate, sample line purge, floor wash water and lab drains.
Chemicals that may be present include among others:
boric acid borax nitrate ammonia sodium molybdate lithium hydroxide ethylene glycol tolytriazole (TTA) sodium bromide sodium bicarbonate dispersant hydrazine carbohydrazide chlorine or hypochlorite hydrogen peroxide industrial cleaning products 3-MPA, or DMA trisodium phosphate pump bearing cleaning laboratory chemicals surfactants chemicals polyclectrolytes biocides degreasers sodium metasilicate sodium hydroxide phosphate detergents defoamer 4.1.6 Diesel Gcnerator Catchment Sumps The diesel generator catchment sumps receive inputs from the fuel oil unloading pads, Containment Mechanical Equipment Building sumps, contaminated drum storage area sump, hydrogen/oxygen generator, Standby Shutdown Facility, hazardous waste storage building floor drain, and rainwater. The Unit 2 sump pumps to the Unit I sump with each sump having two pumps.
Each pump has a capacity of 250/ 10 gpm, Unit 1 and 2, respectively. Unit 1 sump consists of two separate volumes - one to receive all flow and the other to house the pumps. A partial concrete wall separates the volumes, allowing flow under the wall only, which minimizes oil from getting to the pump suction.
Additional chemical inputs include ethylene glycol from the Standby Shutdown Facility cooling system and residual biocide in the fuel oil. During unit outages, borated ice may be transferred to the diesel generator pad and allowed to melt into this sump.
4.1.7 Stcp-up Transformer Base Drainage Sumps Tile step-up transformer base drainage sumps receive rainwater and oil leakage from the curbed bases under the main step-up, Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page 12 of 22
auxiliary step-up, and auxiliary electric boiler transformers, and water from floor drains in the adjacent high-rise office building.
Each sump consists of two separate volumes, one to receive all flow and the other to house the pumps. A partial concrete wall separates the volumes, allowing flow under the wall only, which should minimize the possibility of oil getting to the suction of the pumps.
The capacity of the oil holdup section is -12,716 gallons.The capacity of the water pump section is 6,358 gallons. Each sump has two pumps with a capacity of 800 gpm each.
4.1.8 Sulfuric Acid Tank Containment Drainagc Sump The sulfuric acid tank containment drainage sump receives inputs from rainwater, laboratory drains, industrial strength cleaning chemicals, and drainage from the sulfuric acid and dispersant tank coritainments..The approximate holding capacity is 225 gallons with pump capacity of 35 gpm.
4.1.9 Yard Drain Collection System Sumps Yard Drain Collection System sumps receive input from the yard drains. Three 10,000 gallon sumps are available for spills or rainfalls less than 10,000 gallons. The sumps can pump to the initial or final holdup ponds. By design, rainfalls greater than 10,000 gallons will overflow directly to Lake Wylie. Actuation, testing, or flushing of the chlorinated fire protection system in the yard could overflow a sump.
The groundwater drainage system from the plant discharges to the yard drains. Additionally, the site switchyard contains two oil trap tanks. Rainfall collected from the switchyard flows through these tanks. These tanks will contain any oil spilled or leaked in the switchyard. Oil removed from these tanks would be disposed of separately as used oil.
The Yard Drain Collection System Sumps are also used to collect wastewater from cleaning outdoor air conditioning coils. This work involves spraying a coil cleaner onto the exterior surface of the air conditioning coils then rinsing the coils off with a garden hose. The wastewater is collected in the Yard Drain Collection Systern. nd pumped to the Conventional Wastewater Treatment System. BMPs are in place to ensure this does not occur during periods bf rain.
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-p
4.1.10 Miscellaneous There are approximately 25 to 30 closed cooling systems within the station. The largest system has a volume of approximately 44,000 gallons. The main portions of these systems are constructed of carbon steel, with some of the systems having copper/nickel heat exchangers. Corrosion inhibitors consisting of carbohydrazide, glycol, sodium molybdate, borax, tolytriazole (1TA) are added for corrosion control. Organic biocide and dispersant are added to control biofouling.
4.2 Flows The settling ponds discharge directly to Lake Wylie via Outfall 002.
Maximum discharge flowrates is 1760 gallons per minute. Recirculation capability is available for recirculation intra- or inter-basin.
Flows are measured at Outfall 002 for each discharge from the treatment system. The following flows are from the previous five years of operation.
5 Year Average Design Maximum 5 Year (MGD) (MGD) Maximum (MGD)
Total Flow Outfall 002 1.55 2.88 2.48 4.3 Chemicals & Characteristics of Discharge The expected chemical inputs to this Outfall are described above. The discharge is controlled and treated to yield a very low impact release to Lake Wylie. All chemical constituents are released as limited by the NPDES permit and such that they do not exhibit toxicity in the discharge.
4.4 Treatment Treatment in the WC System is on a batch basis.
4.4.1 Initial Holdup Pond The Initial Holdup Pond allows heavy solids to settle for periodic removal and allows neutralization of wastes.
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4.4.2 Settling Ponds A &B From the Initial Holdup Pond flow is directed to the in-service settling pond where chemical treatment, mixing, and aeration take place. Sulfuric acid and sodium hydroxide may be added for pH control. Coagulants can also be added to facilitate the settling of small particles. Infrequently, it may be necessary to oxidize persistent chemicals, with the use of hypochlorite (sodium or calcium) or hydrogen peroxide. A defoamer may be added to prevent foaming at the discharge.
- 5. Outfall 003 During 2005, Catawba Nuclear Station will undertake construction activities to tie the site's sanitary wastewater discharge to York County. The tie-in is expected to complete in the first quarter of 2005. Once complete, the sewage treatment system will be closed and discharges from this outfall will cease.
5.1 Description of Discharge Outfall 003 discharges flow from the Sanitary Waste Treatment System into the Big Allison Creek arm of Lake Wylie. The sewage treatment system consists of a 1.28 million gallon aeration basin that is divided into four sections and a 0.525 million gallon effluent polishing basin.
5.2 Flows Discharge from Outfall 003 is continuous. The following flows are from the previous five years of operation. Design flow is 0.080 MGD. During periods of heavy rainfall, the design flow may be exceeded.
5 Year Average 5 Year Maximum (MGD) (MGD)
Total Flow Outfall 003 0.02 0.112 5.3 Chemicals & Characteristics of Discharge The Sanitary Waste Treatment System receives raw sewage from Catawba Nuclear Station, the Catawba Training Center, sink drains, shower drains, and drinking water fountains. Soaps and industrial cleaning supplies are expected inputs to this system. This system also receives flow from the oil/water separator and drains located at the on-site transportation garage..
The grease trap located at the site cafeteria also flows to this treatment system.
Catawvba Nuclear Station NPDES Pennit SC0004278 Narrative Description Revised 12/7/2004 Pennit Renewal Application Page 15 of 22
Small amounts of photographic waste (developer and rinse) are disposed of in the WT system. The components of these substances include:
l acetic acid l potassium sulfite otassium hydroxide hydroquinone -phenyl pyrazolidinone lutaraldehyde bisulfite When it becomes necessary to remove sludge from the system, it will either be tanked to a municipal sewage treatment system or dewatered and disposed in the site's pennitted landfill.
5.4 Treatment Inputs to the sewage treatment system initially pass through a comminutor which cuts and shreds large solids into smaller particles. From the comminutor, the waste passes through a bar screen then enters the aeration lagoon where the sewage is decomposed by aerobic bacteria.
Settleable solids and excessive activated sludge collect in the bottom of the lagoon where they undergo further reduction.
Aeration is provided by blowers/compressors. Under normal alignment, waste from the fourth cell enters the effluent polishing basin. When necessary, the effluent polishing basin can be bypassed and flow can be directly discharged to Lake Wylie through Outfall 003 if quality is accept-able. The effluent polishing basin is also aerated by blowers which reduce suspended solids, nitrogen, and phosphorous levels. Soda ash or citric acid solutions are added to the system as necessary for pH control.
The effluent flows through a parshall flume to record discharge flow.
After the parshall flume, flow passes through a tablet chlorinator and a chlorine contact chamber. The flow then enters a tablet dechlorinator system and a dechlorinator contact chamber before being discharged to Lake Wylie. The chlorinator system is not used unless necessary to meet the fecal coliform limits imposed by the permit.
6.0 Outfall 004 This Outfall is described with Outfall 001 (See Section 3.1.2) since it is an internal outfall which discharges to Lake Wylie through Outfall 001.
7.0 Outfall 005 This Outfall is described with Outfall 001 (Sec Section 3.1.3) since it is an internal outfall which discharges to Lake Wylie through Outfall 001.
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8.0 Miscellaneous Operations 8.1 Fire Protection System Water supply for fire protection is provided by three full capacity (250 gpm) fire pumps. In addition, two 25 gpm and one 200 gpm jockey pump (supplied by the Filtered Water System) are provided to prevent frequent starting of the main fire pumps to maintain pressure in the yard mains. If system needs cannot be met with the jockey pumps, the main fire pumps start in sequence as the pressure in the yard mains drop.
The system is chlorinated periodically to prevent the survival and growth of Corbicula clams within the system. Alternate chemicals to chlorine are being evaluated as a chlorine replacement. If it is determined that a chemical other than chlorine shall be used, the system will be operated in such a way to prevent the discharge of toxic quantities of the chemical to receiving waters. Prior to implementing use, appropriate permission will be obtained.
8.2 Drinking Water System Potable water is supplied to the station by York County. A municipal drinking water connection to the site occurred in 1993.
Periodically, when new lines are disinfected or repairs are made to existing lines, the lines are flushed as required by the State drinking water regulations. Where possible, these discharges will be routed to a treatment system or flushed across the ground to eliminate any chlorine before reaching the lake.
8.3 Cooling Tower Drainage The Condenser Circulating Cooling system (which includes the cooling towers) is initially drained through permitted Outfalls 005 and 001 for system maintenance. Any in-leakage of lake water during the maintenance activity is pumped into the yard drain system which discharges directly to Lake Wylie.
8.4 Miscellaneous System and Component Cleanings 8.4.1 Mechanical Cleanings Heat exchanger and cooling water pipes are periodically cleaned mechanically with brushes, rods, high pressure water, hydrolasing, and other physical means. No chemicals are used during these Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Permit Renewal Application Page 17 of 22 I
cleanings, solids are trapped or filtered at the source, and the water flow typically discharges to various station sumps described above.
8.4.2 Chemical Cleanings Systems may need to be cleaned periodically because of scaling or plugging. Other components will be cleaned as necessary for various fouling problems. Solutions utilized will be standard chemical cleaning methodologies. Chemicals'utilized by these methodologies, alone or in combination, include the following:
Alkaline Boilout Solutions non-ionic surfactants cationic surfactants sodium hydroxide anionic surfactants trisodium phosphate sodium metasilicate soda ash monosodium phosphate sodium bicarbonate disodium phosphate Acid Solutions & Additives hydrochloric acid sulfuric acid phosphoric acid formnic acidhydroxyacetic, acid sulfamic acid citric acid nitric acid oxalic acid ammonium bifluoride thiourea EDTA Compounds and IIEDTA pH adjusted tetra-ammonium EDTA di-ammonium EDTA tetra-ammonium EDTA Hydroxyethylenediamine tetra-sodium EDTA triacetic acid
_Miscellaneous Compounds sodium chloride chlorine (hypochlorite) potassium permanganate aqua ammonia ammonium persulfate sodium nitrite antifoam sodium sulfite corrosion inhibitors (e.g.,
phosphates, borax-nitrite, silicates, etc.)
organic biocides chlorothene The spent solvents from these cleanings will be treated in the Conventional Waste System or the Radioactive Waste System. The acid/alkaline compounds will be neutralized; the other compounds will be mixed, oxidized, and/or precipitated as necessary for treatment.
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8.5 Storm Water Discharges The Yard Drain Collection System collects storm water drainage from the powerhouse yard drains. This system consists of 10,000 gallon collection sumps for each of the three (3) containment areas. The powerhouse yard drains connect to the collection sumps via a passive intercept/trap system.
Spills and minor volumes from rain storms will flow into the sumps, while significant rainfall flows will still be discharged directly to Lake Wylie and the Standby Nuclear Service Water Pond. Storrn water is pumped from the sumps to the Conventional Wastewater Treatment System. The pumps continue to operate until the sump is emptied. A rainfall of approximately 0.016 inches in one hour will fill the sumps. Allowing significant rain water flow to continue to discharge to the Standby Pond and Lake Wylie will prevent overloading of the WC System.
Areas outside the powerhouse yard are not connected to the Yard drain Collection System and drain directly to Lake Wylie or the Standby Nuclear Service Water Pond. These areas include the cooling tower yard, wastewater treatment yard, construction laydown area northwest of the powerhouse, areas bordering the Standby Nuclear Service Water Pond, the Security Practice Range, Recreation Area, and permitted industrial waste landfill # IWP 463303-1601.
Storm Water discharges are regulated under the State General Permit for Stormnwater Discharges Associated with Industrial Activity, Permit
- SCR000000. The storm water outfall at the permitted landfill is considered to be the worst case storm water discharge for the site and is the only storm water point monitored.
8.6 Dyc Use Periodically fluorescent dye may be injected/added to one of the plant systems in order to identify leaks in buried pipe. Biodegradable dyes are used for this purpose. Water with dye will be discharged via Outfall 001 or 002.
9.0 Other Environmental Permits 9.1 Landfill Permit #463303-1601 issued by South Carolina Department of Health and Environmental Control.
Catawba Nuclear Station NPDES Pennit SC0004278 Narrative Description Revised 12/7/2004 Permit Reneval Application Page 19 of 22
9.2 Air Permit Permit #2440-0070 issued by South Carolina Department of Health and Environmental Control.
9.3 RCRA Hazardous Wastc EPA ID #SCD070619796 9.4 Underground Storage Tank Permits Site Identification numbers 09242 and 09244 issued by South Carolina Department of Health and Environmental Control.
9.5 Asbestos Permit #8044 issued by South Carolina Department of Health and Environmental Control.
9.6 Laboratory Certification Certification #46003 issued to Catawvba Nuclear Station by South Carolina Department of Health and Environmental Control. Certification includes the following paramenters: Hydrogen ion concentration (pH), dissolved oxygen, non-filterable residue (TSS), residual chlorine (TRC), and temperature.
Off-site laboratories that perfonm analyses for Catawba include:
Duke Power Company Laboratory Services, #99005 EIT Environmental, #23104 Pace Analytical, #99006 Texidyne, 39107 10.0 Hazardous Substances 10.1 Hazardous and Toxic Substances , Table 2c-3 At Catawba Nuclear Station the projected concentration level and potential for toxic and hazardous substances being in a discharge is very low. With reference to Item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in a discharge are as follows:
a.. Formaldehyde - is present in the laboratory. in the pH buffers, turbidity standards, and reference electrode filling solutions. It Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description
-Revised 12/7/2004 Pennit Renewal Application Page 20 of 22
potentially can be discharged via Outfalls 002 and 004 in very small concentrations.
- b. Dicamba - is a herbicide that is 2.82 percent of the product. The product is diluted prior to application. Dicamba could be present in Outfall 002 and storm water in very low concentrations.
- c. Monoethylamine is used in the laboratory in the sodium analyzer reagent in order to adjust the pH. It potentially could be in Outfall 002 but at very low concentrations.
- d. Asbestos - can potentially be present in Outfalls 001, 002, 003, and 004 due to removal of asbestos materials. If present it will be at very low concentrations.
- e. Other - During the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain Very low levels of a susbstanrce found in Table 2c-3. It is not anticipated that these products will impact toxicity at Outfalls 001 and 002 since their concentrations are extremely low.
10.2 Hazardous Substances Under 40 CFR 117 and CERCLA The following are hazardous substances located at Catawba Nuclear Station that could be released in the event of a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117.12(a)(2), 302, and 355. This list is being provided in order to qualify for the reportablity exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA).
The values below represent the maximum quantities on site, which could be released at one time. They do not reflect quantities that are discharged through typical use. The spill reportability exemption is requested for the substances identified below.
Substance Quantity (Gal) Source Discharge sodium hypochlorite 5,400 Cooling Tower Treatment Outfall 002, 005 sodium hydroxide 1,500 Water Treatment Outfall 002, 005 sodium hydroxide 5,000 Demin Regen., Water Treatment, Outfall 002, 005 hydrazine 340 Water Treatment Outfall 002, 004 sulfuric acid 30,000 Cooling Tower Treatment, Water Outfall 002, 005
.. _ Treatment, Demin Regen sodium hypochlorite . . 550 Nuclear Service Water Treatment Outfall 001 Catawba Nuclear Station NPDES Permit SC0004278 Narrative Description Revised 12/7/2004 Pennit Renewal Application Page 21 of 22 I-
11.0 Thermal 316(a) and Impingement/Entrainment 316(b) Demonstrations During the initial operation of Catawba Nuclear Station (CNS), studies were conducted to address potential thermal and impingement/entrainment concerns, as required by the licensing of CNS. These studies indicated that operation of CNS had no adverse impact to the balanced indigenous aquatic communtiy of Lake Wylie. The 316(a) demonstration report submitted to SCDHEC in March 1997 continues to demonstrate no adverse impact to the water quality and the aquatic community of Lake Wylie, as no operational changes have occurred or are planned. Duke Power requests a continued 316(a) variance and renewal of the current thermal limits.
In conjunction with the rulemaking process for the new Phase II 316(b) rule pertaining to fish impingement and entrainment, Duke Power and other South Carolina electric utility representatives met to discuss compliance requirements and responsibilities with SCDHEC in July 2004. A follow-up meeting has been scheduled for January 2005 per SCDHEC's request. Although the new Phase II 316(b) rule for existing facilities is currently being litigated, submittal of required information is being prepared for SCDHEC review.
12.0 Site Layout/Drawving 12.1 General Site Layout and Identification of Outfall Locations Catawba Nuclear Station NPDES Penrnit SC0004278 Narrative Description Revised 12/7/2004 Pennit Renewal Application Page 22 of 22 I'
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- - - - - - M.1 1 2 ... . I .... ...
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' :EPA ID Number (Copy from Item ofFormt ) form Aprved-P!ease type'orpnt 1I te n ded ar y *
- SC04278 l ;' V0. pl's
-Form '¢- *- *Y
- t ir. rf - .S. ENVIRONMENTAL PROTECTION AGENCY .
, r ; 'APPLICATION 4 FOR PERMIT TO DISCHARGE WASTEWATER ! ;
' . "EXISTING MANUFACTURING".OMERIAMINING AND SILVICUTLRALhOPERA M ONS
- 0 Consolidated
-; CNPDESi Permits Progt rm -
I. Outfall Location:-:'
3/4Forths outfal'i istthe latitude and longitude, and narme of tie reivnggater(s) .;..
- ; ' ' . ; 2;
-'.-.Out1'all-t^: *: d '`-W:Latitude Longltude : -;I4:
.. :Recetng Water (name) '.' '
NubIitV -- De -Mm -nSec -- Deg -Min -~-Sec-*~.**>.. ...
002 35 03 05 81 04 10 Lake Wylie 004 35 03 05 81 04 10 Lake Wylie via Outfall 001 005 35 03 05 81 04 10 Lake Wylie via Outfall 001 II. Flows; Sources of Pollution, and Treatment Technologies A.-, .,For each outfall, provide a description of (1)all operations contributing wastewater to the effluent, Including process wastewater. sanitary
-wastewater icooling'water, and 'stormwater runoff;'(2) the average flow contributed by each operation; and (3)the treatment received by the wastewater. Continue on additional sheets if necessary.;-
B. . For each outfall, provide a description of (1)all operations contributing wastewater to the effluent, Including process wastewater, sanitary wastewater, cooling water, and stormwater runoff; (2)the average flow contributed by each operation; and (3) the treatment received by the wastewater. 'Continue on additional sheets if necessary.-
1.Outfall 2. Operations Cont ibuting Flow 3. Treatment Number . a. OPERATION (list) b. AVERAGE FLOW' a. DESCRIPTION b. LIST CODES FROM TABLE 2C-1 002 Processl Wastewater and 1.55 mgd Grit removal, 1-M Storm Water mixing, sedimentation, 1-Q chemical 1-U oxidation, 2-B chemical precipitation, 2-C neutralization, 2-K discharge to surface water 4-A 004 Radioactive Wastewater .020 mgd Mixing, 1-U multimedia 1-Q filtration, chemical 2-B oxidation, coagulation, 2-D ion exchange, 2-J discharge to 4-A surface water 005 Cooling Tower Blowdown 12.12 mgd Discharge to 4-A surface water EPA FORM 3510-2C (Rev. 2-85) Page 1 of 4 CONTINUED ON REVERSE
/
^ CONTINUED FROM THE FRONT C. Exceptforstor nnffleaks;orspills.,are any of the discharges described In Items Il-Aor B Intermittentorseasonal? - r,-; -i.
. I"{YESc , fiete hef --inrtbl~e e ;
- 0-'0 -NO_0j6f ,flo ---ow qotoSection:j :::) :-;: . * ,..._
- 3. FREQUENCY '^ , -4. FLOW - * - - !,__
- 1. OUTFALL 2. OPERATION(s) DAYS b. MONTHS a. FLOW RATE b.VTOTAL VOLUME. AOa.
NUMBER CONTRIBUTING FLOW 1PER WEEK PER YEAR (in mgd) ' (specify with unitsC. DUR-,
(ls).oeage (ist) -
(pct verage)
- (specify..
1.LONG TERM AVERAGE 2. MAXIMUM
-DAILY
'. LONGTERM AG*2. MAXIMUM
- -,AVERAGE DAILY ATION das.
002 water filter, 3 12 1.55 2.88 1.6e6 gal 2.9 e6 150 equipment gal drainage, plant sumps, cooling system drains, storm water containment, system flush for maintenance 004 radioactive 2 12 0.02 0.04 2e4 gal 4e4 gal 100 system maintenance, laundry operation, decontamination operations, floor drains, various sumps _
005 cooling tower 4 12 12.12 14.4 12.1e6 14.4e6 250 blowdown gal gal III. PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility?
N YES (complete Item l/l-8) 0 NO (go to Section IV)
B. Are the limitations In the applicable effluent guideline expressed in terms of production (or other measure of operation)?
- YES (complete Item 1iI! - NO (go to Section lt .
C. It you answered -yes- to Item hi1-s. list the quantity which represents an actual measurement of your level of production, expressed In the terms and units used in the aDlicable effluent guideline, and indicate the affected outfalls.
- 1. AVERAGE DAILY PRODUCTION 2. AFFECTED OUTFALLS
- a. QUANTITY PER DAY b. UNITS OF MEASURE c. OPERATION. PRODUCT. MATERIAL. ETC. (list ouffalt numbers)
W
__specfiy)_
N A_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
.4- 4
.4- .4- t 4- + _____________
4- 4 4- .4- &
.4- .4- _____________
4- 4- 4 IV. IMPROVEMENTS I l E EPA FORM 3510-2C (Rev. 2-85) Page 2 of 4 CONTINUED ON PAGE 3
1 A.t Are you now required by any Federal, State, or local authority to meet any Implementation schedule for the constructon, upgrading, or,--;
.operaton'ofwastewater treatment equipment or pr'cesor.yothe n the disrgs desbed I
,-' $this ti 1spai abo~n? lsnlude;,,i butjJs"iotlimited to, term o *d-if
.scheduleiltter7s.ipul'abons, courtorders. hd grantorloan cond-itf: 2.'I> 2 ;; 22.: ,'
'!<,,:2 E S'(cmiethth tble) <¢Ys :
eoi'tig' OUFLLS ~N- :. ~ ~ -
1.IETFCTOOFCNIIN "2AFFECTED OUT 1.IDENTFICATON OF CONDITION. A 3. **..
BRIEF
.A..,AT.,NAL:
-- DESCRIPTION OF PROJECT :>..:-
i COMPUANCE
. DATE AGREEMENT. ETC. . , No, b. SOURCE OF.DISC-ARGE .S. i ... ' . a REQ- b.PRO-
.,____________ ,,UIRED* . JECTED N/A =__ __ __
B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may zffect your discharges)you now have underway or which you plan. Indicate whether each program is row underway or planned.
and indicate your actu'al or planned schedules for construction. 1'- . . : .- -, , : , -. - :.
, - MARK X IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAM IS ATTACHED EPA FORM 3510-2C (Rev. 2-85) Page 2 of 4 CONTINUED ON PAGE 3 I
EPA ID Number (Copy from Item I of Form 1)
CONTINUED FROM PAGE 2 I SC0004278 I V.-'INTAKE'AND EFFLUENT:CHARACTERISTICS =
A, BQ& C: y,;See Instructions before proceeding -Complete one set of tables or each outfall -Annotate the outfall number Inthe space provided.,%;t
':.* ; NOTE: !Table' V-A. V-B.nd V-C areIncluded on separ r V-1through V-9. :
atesheetsnurbe as 7' -'-"2 D: Use the space below t list any of the pollutants listed InTables 2c-3 of the Instructions, which you know or have reason to believe Isdischarged or ' '
may be'discharged Prom any outfall. Forjevery pollutant you list, briefly describe the reasons you believe It to be present and report any analytical,
-..datain your possession.t'T . ' .. ' . . ' X . e 7 my
- -.;;1.
- POLLUTANT-i.; . SOURCE-i:.
.2
!?:t : '--1.1POLLUTANT * ~-.-;i. 2.SOURCE For identification of substances, see the attached supplemental, Section 10.
VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Isany pollutant listed inItem V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? -
' YES {list all such pollutants below) - NO (qo to Item VI-B)
EPA FORM 3510-2C (Rev. 2-85) Page 3 of 4 CONTINUED ON REVERSE I I
I CON~TINUED FROM THE FRONT TOXICITY TESTING DAA _llBIOLOGICAL
.Do you haeayloMdeo esnt eiv htaybological test for acute or.chronic toxicity has been made'on any of your discharges or ona receing water In relation to our discharge within the !ast 3 years?> .; . l ;;.: 2 ' ; , * :-.' - .; ; i
-YES fidentiy the test(s) and descietheirpuros O goi C} NO (qotdSectioriV ii)
Outfalls 001 and 002 are subject to quarterly Ceriodaphnia dubla 7-day chronic testing under NPDES permit SC0004278. These tests were performed quarterly pursuant to the current NPDES permit. Results indicate that the discharge of Outfalls 001 and 002 is not toxic.
Toxicity testing has been performed by:
ETT Environmental, Inc.
4 Craftsman Ct.
Greer, SC 29650 (864) 877-6942 Vill. CONTRACT ANALYSIS INFORMATION Were any of the analyses reported In Item V performed by a contract laboratory or consulting firm?
3 YES (list the name, address, and telephone number of, and pollutants 0 NO (go to Section DO analyzed by, each such laboratory or firm below)
C. TELEPHONE D. POLLUTANTS ANALYZED A. NAME B. ADDRESS (area code & no.) (list)
Duke Energy Analytical 13339 Hagers Ferry Rd (704) 875-5209 'All except as noted Laboratory #99005 Huntersville, NC 28078 below Catawba Nuclear 4800 Concord Rd (803) 831-3370 pH, chlorine, TSS Station #46003 York, SC 29745 Texidyne 915 West Main St. (864) 639-6207 BOD, CBOD
- 39107 Central, SC 29630 General Engineering 2040 Savage Rd (843) 556-8171 Outfall 004 - all Laboratories, LLC Charleston, SC 29414 analyses and mercury
- 10120 on Outfall 002 Pace Analytical 9800 Kincey Avenue, Suite 100 (704) 875-9092 color, cyanide, sulfide,
- 99006 Huntersville, NC 28078 phenolics, surfactants, semivolatiles, BOD, sulfite, bromide Florida Radiochemistry 5456 Hoffner Rd, (407) 382-7733 total radium, radium Services, Inc. #12709 226 IX. CERTIFICATION _ __ _ _
EPA FORM 3510-2C (Rev. 2-85) Page 4 of 4
I crtify under penalty of law that this document and aof attachments were prepared under my direction or supervision In accordance with asystemrn
' designedtoassuie thatq-1lifedpersonniepropvrtygatherganld elnfy iitiqsibdmfhed.: ased oni n iy'bftth t haate er or er ns
-who manage the tystm orthose sns thI epes bae knowledge end bel;ieftrue, ccurate, and complete.. 7 amsIware that there sre sign1 tp forsumittg (alse Information e giossibllity offin 'and iirlsdnment fr knowing violations.t:*-i:-
I *-.i;~)ii;i tdSt~dyiiir!e~n~~it2iji;-t; j A. NAME & OFFICIAL TITLE (type or print) B. PHONE NO. (area code & no.)
Dhiaa M. Jamil, Vice president Catawba Nuclear Station (803) 831-4251 C. SIGNATURE _ D. DATE SIGNED
/, -Il- ot EPA FORM 3510-2C (Rev. 2-85) Page 4 of 4
SNSWP 600 001 16,500 Lake COND. POLISH LAKE Wylie DEMIN. FLOOR WYLIE DRAINS STEAM GEN.
BLOWDOWN 60,350 l MISC. SUMP- CONVENTIONAL WASTEWATER. OUTFALL TREATMENT I 002 50 FILTER FLUSH
-- DEMIN BACKWASH Potable Water 15 15 (Off-Site OUTFALL 003 Supply)
SNSWP CATAWBA NUCLEAR STATION NOTE: ALL FLOWS ARE IN GPM WATER FLOW SCHEMATIC FOR AVERAGE CONDITIONS
At PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D. NUMBER (copy from Item 1 of Form 1) this information on separate sheets (use the same format) instead of completing these pages.
SEE INSTRUCTIONS SC0004278 OUTFALL NO.
V. INTAKE AND EFFLUNT CHARACTERISTICS (continued from page 3 of Form 2-C) 002 PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.
- 2. EFFLUENT 3. UNITS 4. INTAKE (optional)
- 1. POLLUTANT a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (if available) (if available) d. NO. OF a. Concen. b.Mass b. NO. OF (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentrabon (2) Mass ANALYSES tration (t) Conc ntration (2) Mass ANALYSES Biochemical Oxygen 6.7 138.7 3.4 44.0 14 mg/ Lb/Day bDt.scat Oxygen 30.4 629.1 1 mg/I lb/Day aema(COO) .
Total Organic 5.58 115.5 I mg/I lb/Day
- bn (roc)
. Total Suspended 18.2 376.7 7.4 95.7 14 mg/I lb/Day So (ds __SS)
. Ammonia (asN) 1 20.7 1 mg/ lb/Day
'.Flow VALUE VALUE VALUE 138 MGD X VALUE 2.48 1.55
- Tomperstwu VALUE VALUE VALUE 36 VALUE winter) 19.5 14.2 DEGREES CELSIUS .
r.mTonvrate VALUE VALUE VALUE 31 VALUE ssnwmer) 29.4 24.8 DEGREES CELSIUS
- pH MINIMUM MINIMUM MAXIMUM. 54 6.s__ _ ___ 7.8 I.4 _ _ STANDARD UNITS PART B - Mark WXin column 2a for each pollutant you know or have reason to believe is present. Mark X in column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant For other pollutants for which you mark column 2a, you must provide quantitatve data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements.
- 1. POLLUTANT 2.MARK X 2. EFFLUENT 3. UNITS 4. INTAKE (optional)
AND CAS NO. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE ifava"t) aopr..b.ab- (f avaiLable) _(if avaable) d.NO. OF a. Concenr 5. Mass b.NO. OF sent sent (1)Concentration(2)Mass (1)Concentralion(2)Mass 11)Concentration(2)Mass ANALYSES ration ) Concentration (2)Mass ANALYSES
.Bromide X 1.31 27.1 1 mgA lIb/Day 24959-67-9)
,.Chline. X 10 l0 0 0 17 mg/I lb/Day ot l Residual cow X 75 1 Std. Units X 1Fecal X Colonies X Coldfomn _ _ _ ______ /1100 ml l _ _ _
.Ftround X 0.13 2.7 1 mg/I lb/Day 16984-484) 1 ________ 1 1 1 1 Ntrate_ X l 0.29 6.0 1 mg/I lb/Day 44tnt (as N) tn e ( s N)_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ __ _ __ _ __ __ __ _ __ _ __ _ _ _____ ____ _______________A..
EPA MIT% 35101942C (eV. d-00) PAGEV 1 CONTINUE ON PAGE V 2
1OUTFALL NUMBER EPALD. NUMBER (copy (copy from item II of fromItem of P04101)
Form 1) OUTFALLSNUmCER -1 ITEM V-B CONTINUED FROM FRONT SC004278 002
- 1. POLLUTANT 2. MARKX 3. EFFLUENT 3. UNITS 4. INTAKE (optional)
AND CAS NO. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE available) &pre- .-ab (if available) (ifavailable) 4. NO. OF a.Concen- b. Mass D.NO. OF sent sent (1) Concentratbon (2) Mass /1)coentraton 12)Mass (1) Corsentrauon (2) Mass ANALYSES urauon (1) toncentration (2) Mass ANALYSES p htrogen.
TowlOrgaro A 0.87 18.0 mg/ tblDay is N) nL_d WA Zi4s A 5 103.5 4 5 6r4.7 14 mg/I lb/Day AsP).Total A 0.05 1.0 1 mg/I l/Day 77A3-.4-)
_ Rad~icbnvify __ _ _ _ _ _ _ _
row _ 8.04E-01 1 pCi/I x o A 3.670+00 1 pCi/
rowe A_ 0.6 1 pCI x 4)R 4iurn
- 26. Totw) A 0.4 1 pCia X AsS04) A 70.5 1459.0 1 mg/ lb/Day t
14808-7-8) su A < 0.05 < 1.0 1 mg/i lbDray ss03) A ' 2 41.4 1 mg/I lb/Day 14265-45-3)
A < 0.1 ' 2.1 1 mg/I lb/Day Total A 0.0897 1.9 1 mg/I lD/Day
[7429-90-5)
Irow A 0.025 0.5 1 mg/l lb1Day 7440-39-3) rol A 0.367 7.6 I1 mg/I lbDay (744042-8) _
otw) A < 0.001 0.0 1 mg/I lb/Day 7441041 w)
- iro-n To-W 7439-89-6) A 0.233 4.8 0.138 1.8 10 mg/I lb/Day.
1Magnesuln.
role A 3.276 67.8 1 mg/ lb/Day 7439-95-4) row A 0.338 7.0 1 mg/i lb/Day 7439-98-7)
- v. Manganes.
row A 0.035 0.7 1 mg/I lb/Day 743 t9 S)_ _ _ _ __ _ __ _ __ _ _ _ _ _
v.TA TotS 7440-31-5) A < 0.05 < 1.0 1 mgI lbDay Cidarvu.
ow) A < 0.01 < 0.2 1 mg/I lb/Day
/4 ( - 2 0 __ _ _ _ _ _ __ _ _ _ _ _ __ _ _ _ _ _ __ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ __4_ _ _ _ _ __ _ _ _ _ _ _ __ _ _ _ _ ____ _ _ _ _ _
tFPA FOMI 401V-4LC (KOW.2h0) FAULV-2 CONTINUE UN PAUL V 3
. -. 0 I". It I
a OUTFALL FLOW= 2.48 mod I INTAKE FLOW= mad I b OUTFALL FLOW= mod 1 c OUTFALL FLOWs= t55 mgd EPAI.D. NUMBER (copy from Item I or Form1) OUTFALL NUMBER I CONTINUED FROM PAGE 3 OF FORM 2-C I SC0004278 002 PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark 'X" in column 2-a for all such GCIMS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries.
nonprocess wastewater outfalls, and nonrequired GCIMS fractions), mark 'X' in column 2-b for each pollutant you know or have reason to believe is present. Mark OX-in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one arqalysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2, 4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. *-
- 1. POLLUTANT 2. MARK":X 3.EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. ore-[pe- ab a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (davarob) quar- (i avilben (i amble) (if *vaiable) / d* NO. OF a. Concert-bbd. . Mass d.NO. OF d (1)concentration (2)Mass (1)Concentration (2)Mass (1)Concentration 2)Mass ANALYSES tration (1)Concntrahon (2)Mass ANALYSES METALS. CYANIDE. AND TOTAL PHENOLS 1M.Antimony. _ - 3 0 06I T 7 Total(7440-380)
UM.Anew15Tote)a--l ~T ~ Fl F 7440-38-2) _
W., (wm^ 0 U5 01 9u b Day Tota)(7440.41-7) 4U. caim.inw^ - 0T.5~~ ~
total (7440-43-9)
W. Coromun- - _ 0F 1 -3uV I 1003ay rotal(7440 4743) 3MCopper. Total X - 0 < WZ 0.1Z 10T mgTr-F IbD7y 7440-50-8)I UM.Lead,Total - 2 004 I UgA lbDFay 7439412.1)
M Momrty, Total -.- - X 3 -ay 7438-974)
M. Ncke. TotWa - - 70 Z 04 _ 1 U5-y 7440-02-0) 10 Selwrsim 6 - Ib/Day UP/F Total (7782.48-2) 11M Silver.jota) r - - 7 r I gli bua F 7440.22-4) _ __0 __00_u______
12M. Thorn, Th&Day - 0- - 0 0 07l eota)(7440.28.0) l3 a Z tc.Tota) _ 0 - W _ 5 l F (74 .40464) _ _ _ _ _ _ _ _
14M.Cyange. - - M Tota(57.12-5) _
15M.Phonols, 0.- 8 1.1 mg/T liuay otal UIUAIN
.3.7.8 Ttro" l Il F6UCRbLtitUL13 inoo(o17o P l401) NOT DETECTED EPWA. form . - 2c(Rev.
331
_ 35110-2C olio _v._2455)) PA. _GE _NUE COATIN PA. AE tPA PAGE V-3 CONTINUE ON PAGE V-4
- 1 EPA I.D. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 SCO004278 002
- 1. POLLUTANT 2. MARK *X 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. a.re. b.pr cab. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE C. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE 4av.aabJ) quir- sent sent (i available) (if available) (if available) d. NO. OF a. Concen- b. Mass d. NO. OF ed ( 1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass ANALYSES tration (1) Concentration (2) Mass ANALYSES GCIMS FRACTION -VOLATILE COMPOUNDS IV. AnX _ 2 0.04 1 U ttVFay 107.024) .
A -. 2 0.4-1 1 /Uay 107.13-1)
IV.64WI. WFAT 1D 1-43-2) X = _ _2__OU-1__ ___
IV.ai (Chior-My Eaw X ug/l lb/Day 5421) pv. &o~nidron - - . 7 a 0.4191 T tt~a
- 75. c52 __________
Broata23 X ' 2 < 0.04 1 ug ItVDay 7v -n r n < 00 1 U9Wva 108.90.7) _ _ _ _ __ _ _ _ _
pV.Ciro-tt X ' 2 < 0.04 . 1 Ugh lbDay C124-4.8-I) .______________
v.C~roeIMM 5.00.3)
< Z T ~ -.. ~ * - T ug4- ~Vte IlV. 2Chhod awlnvelwt mm X < 2 ' 0.04 1 Ug/ lb/Day 110-7548) ___ ____
12V.Ct> -
U an. X h 2 < 0.04 1 ugA lb/Day 75-274) 13V.2sCh o-
.laE.
X 2 ' 0.04 1 ug/ lb/Day ps 51-) __ _ _ _ __ _ _ _ _
I V. 1C1-oco0- X T-2 0.04 Tvma*7 1
- a. (753).-3)
IS5V.1.2l o2 r0.04 X -ugi iivuay . ,.
tn (107.82) l16V. i*.ossara AT- z <1.
- < 0.4u ~ F awien (78-5.4_
82 10CV4T
,IZV. IaXhwo R <2g X 20-
.4 1bDay1ugl tvay 1542-7546)
EPAFor 19V. 35.10.20o Eattldzn (Iv 4)PG X - ] 7 <
Zr- . *2 -Iu tV~a7l CNIU NPG ~
- 10. D41o4) . _________ _______
0oV. MethW X < 5- 0.10 T 1gt t~7 diane (7443-9)
(10.874&3)
EPA Fosm3510-2C (Rev.2-U) PACE V-4 CONTINUE ON PAGE V-5
0 1:o1 EPA I.D. NUM5FR {copy from Item I of Form 1) OUTFALL NLIWER CONTINUED FROM PAGE Vv4 I SC0004278 1 002 1.POLLUTANT 2.MUARKW* 3.EFFLUENT 4.UNITS S.INTAKE (optional) lAND CAS NO. b.p. >.PF a.; MAXIMUM DAILY VALUE ......... b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (iava"W) su4.
nt uent (if iivadb>Nf) vaib (d ayiajble) d. NO. OF a. Concen- b. Mass d. NO. OF
- d (l) Concenuraton 1(2) Mass (1)concentrabon l (2) mass (i) cnetration l (2) Wss ANALYSES tration 5llCocentratin (2\ Mass$ ANALYSES lGC/MS FRACTION - VOILATILE COIMPOUNDS (continued)
Z2V.M oUryi A a < 0.041uglwa p(75-09-2) 23 .11,2,2-TerU - __..
p ane X < 2 < 0.04 1 ugA1 IblDay
$2V.Tirat~o- X _ < Z < 0,041 Ugl IVa etyC (127-184). _.
S.To# aw0041w/1 Wa p08-83)_
p6.12-Tra 566-)X 2 < 0.04 1 ugA ID/Day 7V. l.l,l-T _ _
phun X < 2 < 0.04 1 ug/l bDay X < 2 < 0.04 1 ug/l IblDay L2V. T io~o X .4 .1 ug/1 Ib/Day. .
(yn7M1-6)_:
p hX < 2 < 0.04 1 ug/l IbtDay.
tv.-J X 2 < 0 4a 1 ugl 754-04)
(iod Nl:#btiKAt; IUN - Altll,,e~JUMV INUb.
nd(120432) l l I I pK2,4-0maty- l l - 10 0.21 1 U/ -Ib/Dayl nsol(534-52-1) gZ24"v~ d l 10 < . 91 IVay.
44,10 heno 10 I-g I~a I.i pdS947 1A 1 1 1 _n j*X0-1P0 X r 10 <c 0.21 i ugn1 Ibmay p8062) .
rare renn sews {rev. He) rAllt VW0 CONTviNrUt N rA1,t1 V-
.1 0 1, EPA I.D. NUMBER (copy from Item I o Form 1) 1OUTFAL NUMBtER UUN I WdUt1 PXUM tAtzibt: V.a I bU;UUU4zaB I UU;1
- 1. POLLUTANT 2. MARK":X" _ 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. lare p[eb.
.. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE C.LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (i availabe) Jqwrsent sn (if available) (if available) (d available) d. NO. OF a. Concen- b. Mass d. NO. OF d (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2)Mass ANALYSES tration (1) Concentration (2) Mass ANALYSES GC/MS FRACTION - BASE NEUTRAL COMPOUNDS I lAcenap1swee A - - c - 10 0.ZI T1 D 83-32-9)
ZS.AcWhm A 1 0 o 0.211 glbDa B. Amnepf1ityne - - f T
- r1u Z1 ay 120 7)
- B.Bnn _ - 510 u9/ Ibly.
92417-5 _ _ _ __ _ _ _ _
SB. Beo (a)
X < 10 c 0.21 1 Ugl lb/Day Sonz (a) = 10 0.Z 1 Iy _ - a (50.324) _ _ _ _ _ _ _ _ _ _ _ _ _I__ _ _ _
8.3.443reno-IB.3,48 X _ 10 < 0.21 1 u911 Ib/Day 205-99-2) . . _
i 8.nzo (W) -_ 10 < 0.1
- rybne (191.24-2)
- 08. Beruzo (ti) kuoranone X < 10 ' 0.21 1 ug/ lb/Day 20708-9)
- 08. Boa(2-C..,
)l ulane n X 10 - 0.21 1 ug/I Ib/Day 111<-91-I) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _.,__
- dsIhyEthr X < 10 0.21
- 1 u9/A lb/Day i28.8B (2 WA EUer X ' 10 < 0.21 1 Ug/I lb/Day 1080.1) _
13B,sis (2-ErI
)Pe)
Phawat X - 10 < 0.21 1 ug9/ Ib/Day 11741-7) 148.44kono-Ptwnfl X < 10 .c 0.21 1 Ug') lb/Day Ethe t(101-53) 15B. E 10 X 02 1 u/ Day at Ihd(8548.-7) _ _ _ _ _ _ _ _ _
I SB.2-Ch h X < 10 ' 0.21 1 ugAl bDay 91-58_7) 178. 4-Q5Wo-PsFen-l X - 10 < 0.21 1 ugA IblDay the(7005-72.3) I 21o01.9) 10 _ 0.21_ I ugA Way nu X < 10 < 0.21 1 ug/l lb/Day 53-70.3) _ _ _ _ _ _ _ _
I08.
1,2 oro- _ 10 < 0.21 IbDIa 1 -9/r nzn (95-50I ) _ .
ane (5i41.731) __ __ __ _ _ __
10___ _ _ _ _v__zf _ _ _ _ __ _ _ __ _ _ __ _ _ = __ __ _ugIb/Day rare rang 1wsw to s. owl -6 WN I INUC UN relic v {
ta-
.1 r
IEPA CO.NUMBER (copy tram1 Items1 of Form I) 1 OUTFALL NUMBE5R WUN I INUtU PIKUM IAUt V-b I bLWUL14L2It I uuz
- 1. POLLUTANT 2. MARK X I 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. s.. a.p- cao- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE avaable) qwra. f ovable) ilant (f ava/lable) (i available) d. NO. OF a. Concen- b. Mass d. NO. OF d3 _ (1)cocontnton T (2) Mass () oncentrations (2) Mass (1) Concentration (2) Mass ANALYSES tration (1)Concentration (2) Mass ANALYSES GCIMS FRACTION BASE/NEUTRAL COMPOUNDS (continued)
Z28,1.4-14o x - 0 -lo 0 2T ur- ItDa.
4nzen (10 6-7)
- 38. 3.3-Os~oo X < 20 < 0.41 1 ugh Ib/Day 91.94-1) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
14B.Dwtlryl X 4 10 < 0.21 1 ugI lb/Day 84-6&2)
Z5B.Ossthy_
Pnt X < 10 < 0.21 1 ugh/ lb/Day 131-11.3) to X c 2 ' 0.04 1 ug/ lb/Day 54-74-2)
- 78. 2,4-*r 1 0.20 - l ( u9/ r I1ay olww (121-14-2) o~usrw(608-20.2) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
Z9.1D X x _ 10 < 0.21 1 ug/i b/Day
'117840) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
("uAlo X ' 20 - 0.41 1 ug/l lb/Day
) 122-6&7)
- 18. Fkw1Ul o X 10 0.Z1 T U9/ 1/y.
- 8. Fxwto A 1 - < 0 Z 1-u9U -Ib/ Day 68.73.7 _ __ _ _
33B.HoXao- - < U 10 I b/D a y 0enzen (118-74-1)
Mo.Noah.
ob X < 10 I 0.21 1 ug) Ib/Day (87-3)
X ' 10 - 0.21 1 UGh lb/Day 77-47-4) _ _ _ _ _
38B.HoAa10*- AX -10 0.Z1 I UT1 Uay thsne(87.72-1) 37B. h0800 1,2.3-cd) Pyrone X < 10 . 0.21 1 ug/I lb/Day (t93-39-5) las ~worne - -u 21705 78-5O-1) _ _ _ _ _ _ _
98O. Naphhono -i r 0.2f t g u iiDay 91-20-3) ____ ___1__ ___
8e.Nitrsotoain 10 0-21 T1 ugi i ay 98-95-3) 418.N4*10-t X ' 10 c 0.21 1 ug) Ib/Day e62-7s-9) . _ _ _ _ _ _ _ _ _ _ _
X _ 10 < 0.21 ug lb/Day W1 82144-A.E V-7
__7 COTUEO PAG V-EPA E FWM 512 (Rev. Z2W) erne31.20(o. 2-0 PACE CONTINUE ON PAGE V 8
- 1 I
EPA I.D. NUMBER (copy from Item of1 Form 1) QUTFALLNUMBER CONTINUED FROM PAGE V-7 I SC004278 002 1.POLLUTANT 2. MARK', I_ 3. EFFLUENT __4. UNITS 1 5. INTAKE (optional)
AND CASNO. . b.c a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG: VALUE (if availab.) d.NO.OF a. Concen- b. Mass r d. NO. OF enit (.1 avi e) (if available)
( av ailbe r I (1) Con r. bton l (2) Mass (1) Con uabon l (2) Mass I (1) Concentraton 1 (2) Mass ANALYSES I tration (1)Concantraton (2)Mass ANALYSES GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (continued) ohs-a1 - X 0O 0.21 1 ugtl lblDay 863U-6)
"4a. Ptnarl _vw- 1- 0.21 Iay u/
[129.000) X_ _.t__ gA X I)Da 148.1.2,4-Tn--
oov, an. X 10 0.21 1 I1 Day 120.812-1) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
IP.AWMb -g - -- M a.
3090-02) A _____Ib/Day 2P.aBHC _ A.
X U9/1 O33tbow~s"^nhc-- -. U9/ /a IP.b 31849tamm-atic
- 9) - A-u__b1Day (31;9464) _________ _________ - u g I_________
WP. "AN-BIC - - -
57-74-9) X u9_1 Iblay 7P. 4,4'4DOT A = g U9/ Day 50.29-3) _ _ _ _ _ _ _ _
3P.4.4-'O- Xu/ -- u-_- Way 72 ) _ _ _ _ _ _ __ _ _ _ _ _ _
toP. 0DoD* ug/l W 7ay 60-571) = _ _ __1 Way =
ttPuntan ug/ WVDay~
115-29_7) __________y _
IZP.betaEndosuktan A- -ur-g -iM~-y
'11 -29.7) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _
t3P.aEn U9g/l 1031.074) 14P.EWM _ bDay 72-20.8) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
tSP. Endn _ -
We"rd LJ9A 7421-93-4) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
756p4448) ___ ___ X_ _ __ _ =____ =
E ur r-a-.. ste s.- Ha r^bc is wa l uric we rose v w
.9
, I EPA l.D. NUMBER (copy fromItem 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 I SC0004278 I 002
- 1. POLLUTANT 2. MARK XX' 3. EFFLUENT __ _ 4. UNITS 5. INTAKE (optional)
AND CAS NO. a..- D.pro-cab- J a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE aivaaba) IQu an sent (i aaable) (if available) (4 aaIabte) d. NO.OF a. Concen- b. Mass d. NO. OF ld (1)Concntration (2) Mass (1)Concantraton (2) Mass (1 concentraon (2) Mass ANALYSES tration () Concentraon (2) Mass ANALYSES GC/MS FRACTION PESTICIDES (continued) 17P.hFptacNor X ugAl IbiDay 102457.3) 16P.Pca 1242 A ugZ WiDay 534B9-21-9) ________
9P. F 1254 .Aay X ug/
1109769.1)
OP.PC8-1221 X _ ug/l ID/Day 11104-28.2) _
2P. PC31232 A 91 Wa 11141.1805) . .
P. PC8-124B - X ay 2672-2"-8) 20 -PCB- ug 1 Ih/Day 2P. PCIB-1010 U9/ Ilay 12674-11-2) 2s.Toxh A ug / Wi/Day 8B001452) __________
Era e-refm Q zSI. gnaw t.oo) InAt, VW rr X*Xw emv. =<a) P-AGErV 9
9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA LD. NUMBER (copy from Item 1 of Form 1) this information on separate sheets (use the same format) instead of completing these pages.
SEE INSTRUCTIONS P SC0004278 OUTFALL NO.
V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) 004 PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.
- 2. EFFLUENT 3. UNITS 4. INTAKE (optional)
- 1. POLLUTANT a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE C.LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE
. (davailable) (d available) d. NO. OF a. Concen- D.Mass b. NO. OF (1)Concentration (2)Mass (1)Concentralion 1(2)Mass (1)Concentrulion (2)UMass ANALYSES fation (1)Concentration (2)Mass ANALYSES a Bochemical Oxygen 64.9 10.3 < 33.5 Ic 5.3 2 mg/I lbDay Demzd (BOD)
.Chem" Oxygen 193 30.6 . < 98.9 - 15.7 2 mg/ lb/Day Dem cond (COD)I Total Organic 71.7 11.4 37.1 5.9 2 mgAi lb/Day
- arbon (TOC) _
t Totat Suspended 12 1.9 6 - 1.0 2 mg/ lbtDay Solids (TSS)
.Ammonr (asN) 0.71 0.1 0.45 0.1 2 mgA lb/Day F.low VALUE VALUE VALUE MGD X VALUE 0.019 159
. Teeraiture VALUE VALUE VALUE VALUE winter) DEGREES CELSIUS r Teaperatre VALUE VALUE VALUE VALUE S_ _ __r_) IDEGREES CELSIUS 6.4 9.2 159 STANDARD UNITS PART B - Mark X in column 2a for each pollutant you know or have reason to believe is present. Mark WXin column 2b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which Is limited either directly or indirectly but expressly in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements.
- 1. POLLUTANT 2.MAF 'x. 2. EFFLUENT 3. UNITS 4. INTAKE (optional)
ND CAS NO. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE if available) apre- bab (i available) _ ( available) d. NO. OF a. Corncen b.Mass b. NO. OF Samt sit (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES atibon (1)Concentration (2)Mass ANALYSES
.Bomide X 16 2.5 9.1 1.4 2 mg/I lbtDay 2495947-9) _ _ _ _ _ _
c.chlorie, mg/I lb/Day TotalResidual I I_ _
c_co X 20 l12.5 2 Std. Units tFera X ColorIes
- 01dorm . ____ _/1100 ml nae X _ 0.56 0.1 mg/I lb/Day 1in984(48) __ I_ _ _ . I itrite (as N) =_ =_ _ _ __ _ _ _ _ _ _ _ _ __ _ _ _ _ __ _ __ _ __ _ __ _ __ _ __
EPA Form EPA ^norm F^ 3S10-2C Ra.2.........)...
ID1~2 (Rev. 2-45)
PA V.1.
PAGEV 1 r D-r U/rlulNul IN PAub V-.i CONTIINUE ON PAGE V-2
an /s It from Ibm l of Form 1)
NUMBER EFA LO(copy 1oU7FALL NUMBER 1 004
'I SC0004278 EPA I.D. NUMBER (copy from 1t.0n1o1formi 1) OUTFL NUMBER ITEM V-B CONTINUED FROM FRONT I SC0004278 I 004 I
- 3. UNITS 4. INTAKE (optional)
- 2. MARK X
- 3. EFFLUENT a. LONG TERM AVG. VALUE 1.POLLUTANT _ _
- c. LONG TERM AVG. VALUE B. NO. OF
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE d. NO. OF S.Conc an. b. Mass AND CAS NO. f Id availabe) fif avadable)
(1) CoCnentraon (2) Mass ANALYSES a.pro- bab (2) Mass tAaEo ldavai abb) ci)concentrauen (2) Mass (1 1)ConcCntrason MA*NALYSES sent sent (
1)Concentraton 2) Mass n rogen.
0.3 2 mgm (b /Day 2.18 A_ 3.34 0.5 Tow Organic c _15 2.4 2 mg/l lb/Day hl. ase An 25 4.0 1.67 0.3 2 m g3 ib/Day A 1.99 0.3
.asP) Total .
2 PCci X
- 4.03 A 6 8.07 4 rot.
2 pC2 X 6.894 t03 rowi A 1.31+04 2 pcinx X
- 1.765 row A 4 1.979 2 pCiZ( X
.c 0.68_
Totla 8.6 A 0.909 Sulfate m gI .
lb/Day 3.4 0.5 2 A 6.64 1.1
. s 4)Af 0.1 2 mg/I lb/Day
' 0.41 '
A XsS) 0.072 0.0 2 Mg lb/Day 2.5 _0.4 A 3 0.5 (S O53)
A mg/I b/Day 0.0 2 mg /i lb/Day
- 0.05 __________
A 0.068 0.0 ________
ToW l (74nur0n-5) 0.0 2 mgI lb/Day 0.009 A 0.017 0.0 (7a9) 61.8 2 mgni lb/Day 390 A 779 123.5 ToW 3.2 2 mgn lb/Day
< 20 4 A ' 20 ' 3.2 a Io 0.2 2 mg/I lb/Day 1.21 A 2.38 0.4
- 7439-8 94) 0.89 0.1 2 mg/ lb/Day r1ow A 1.75 0.3 0.6 2 mga lbDay
< 3.5 _
A 6.97 1.1 row Mang~anese. mg/I lb/Day 0.026 0.0 2 A 0.048 0.0 rowa 0.0 2 mg / lb/Day
. 0.005 c A 0.005 0.0 (7440-31-5) 0.00. 2 mg/I WDay
.oa A 0.001 EPA ~ssl 0.0 339-Z _ (Re. 283) AGEV-2CONTINUE ON PAGE V-3 EA Fonn 3510-2r. (Rev. 2-115) PAGE V-2 CONTINUE ON PAGE V-3
A.
'U, It a OUTFALL FLOW = 0.019 mga I INTAKE FLOW = mo l d b ,OUTFALL FLOW = mgd l C[OUTFALL FLOW = 0.019 modl EPA I.D. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C SC0004278 004 PART C- If you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X' in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outfalls, and nonrequired GC/MS fractions), mark AXE in column 2-b for each pollutant you know or have reason to believe is present. Mark "X" in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2, 4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details aind reniiireminfts
- 1. POLLUTANT 2. MARK _ _ _ _ 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
A6ND CAS NO. a tr- cab-b.p- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE a LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE if avalable) qvr.tl S srn1 (if available) (d avalable) if anabta) d. NO. OF a. Concen- b. Mass d. NO. OF
_d (1) concantraion (2) Mass (1) Concentralion (2) Mass (1) Corcentration (2) Mass ANALYSES tration (1)concentraiion (2) Mass ANALYSES METALS, CYANIDE. AND TOTAL PHENOLS 1U. Aunony, < ---- 0 < 5 < ug/l Duaa-y-rota) (7440.36-0)
Az~ 5 o -- U000 5 W2ugly_
t744038-2) 3a.Bery-^ < 0 00 7 0W2 u9A1 LD/Ua7y Total(7440-41-7)
IM. cauw - 1.o o~w < C(Kelf-e-00 PAGE V-4 CONTINUE ON PAGE V 5
I EPA ID. NUMBER (copy fromRem I of Form 1) jOUTFALL NUMBER CONTINUED FROM PAGE V-4 I SC0004278 1 004
- 1. POLLUTANT 12. MARK "X" 3. EFFLUENT ' 4. UNITS 5. INTAKE (optional)
AND CAS NO. ar bpre- c.Ab- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE 1dvaable)l quw- sent lard (if avaiable) (if available) (It avadable) d. NO. OF a. Concen- b. Mass d. NO. OF ld (1)Concinuraton 1(2)Mass (1) ConcnntraOn (2)Mass (1 Concentraton (2) Mass ANALYSES tration (1) Concentration (2) Mass ANALYSES GCIMS FRACTION -VOLATILE COMPOUNDS (continued) _
2V. fMethyse"e- -~
.(75-9-2) X _ ____Iba 23V.1,,2,2-Tatrt-79345 X ugl lb/Day 24V. Ter U _ ui/x/Day f127-1-4) 1tfibn __X X 25V.TouflOn o91Iblay 10-848-3) _ __ ___X_
iftyiw X ugh lb/Day 15 0-5) 794-S X ug/ lb/Day 28V,1,1,2-Tn-_
3V1.1.2-Tn-29V. T-6Stan.
n c__ X __ __o_ __X_.______Ibla U9/1 lb/Day 31V. Tndrlo. _ X * - IDa than. X ug/l lb/Day fft fdn (7 9 01-4) __ _ _ _ _ _ _ _ _ _.
- (75-01-4) 5-9-5 4) _ ___
IV.2,4i n -> X loro~ l tan of -Ug-- U91r- - -*Ib~aVy 2.D4-Oas..oro- - IDay pnd(120-83-2) _
9a~
53-57-8) = = ______Iblay _________
2.4-mthyl- - u gI lb/Day n)(105-67-9) _ _ _ _ _ _ _ _
A 4.84o IblDay Uy sol(534-52-1) U . 9 / 1I b l ay 2.4-0"ntro- - - aFy -
nol (51-28-5) 8- 5-5 ) _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _
A4-Nitopflenoi - - _ 1~ a~
1 PbCO- n d Ug/l D/Day 100-95-2)
I1A.
108- 2, 902) T - .r
, ... . uglb/Day EPA Fonn 45110-Z (Kell. 3-11) PAGF VS -CONTlNqE_ ON PAGEFV-6
It
-- C--- .....
...e__......l.
ELAW. NUMdERt ECOpyIrOMRIes 1 Faot 1) OUTPALL NUMBEK
(.UN IINUtU I'KUM VAUt V-D btUUU4;110 I UU4
- 1. POLLUTANT 2. MARK wX 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. b-.Dcja. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE Navailable) qvi sent sent (if available) (if available) (if available) d. NO.OF a. Concen- b. Mass d. NO. OF d () Concentratn (2) Mass (1) Concentration (2) Mass () Concentration (2) Mass ANALYSES trationl () Concentration (2)Mass ANALYSES GCIMS FRACTION - BASE NE UTRAL COMPOUNDS 1a.Acenrpftliene X ug- Ib/Day 83-32-9) _____ ___
ZB. Acenaphtp A ug lay 20&8964) iB. Angwaceon - - XbiDay 120.12.7) _ _ _ _ _ _ _
9B2-7.5) _ X .4 ug/l Iblay B.Buo J(a)
Ug4 Ib/Day StS55-3)_ _ _ _
B.Beno (a) - X ugil 1ID/D rne(50-32-8)
B. 3,4-bento -
a05.9. ug/l Ib/Day 205.99.2) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
B.sotwi (Wu), X --- Ibay eryan. (191-24-2) .
8B.Bauo() - -
'207)anthen ug/l lb/Day 207.08-9) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
- 10. Bie (2.choo - -
hlL)j SUsaN uh Ib/Day 1111.191.1) _ _ _ _ _ _ _
I1B.Bil2.Ci--o- - -
A 8ywl ug/l lb/Day a8. a(2-0 I11144-4) 12B.s (24CtBorwsi -
phe Ethel ugA lb/Day 138. Bi (2.4 - -_
Philh7le ug/l lb/Day 1117-8117) 108-6(0-1) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
148. 4-Brmo
- iiny) Phanyl ugh lb/Day sa.Butoyl nX ug-l Ibl-ay ato(85-68.7) _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
t9B.2-COl b -
thlee(1 00155-3) _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ug/l IbtDay -Ni 91.5a-7) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
- 11. 4-Cbtlol--
nlPhenyl ugA lb/Day t-(7005-72-3) 18.Clrysene - - biua 218-01-9) _ _ _ _ _ _ _ _ _ _ _ _ _ _
ugh) lb/Day Z8. 1,2-t sIh-_ a ug/l eane (95-50-1)
- 18. 1.3-ct- t. X u/ IlDay nzn (541.73-1) _ _ .
EDcFr 314~c lRv2S PC rows as 2NcU 5 Dl. v .{
Gro rw-- st-. n WN I INUC VN r^>c
.1 0
EPA I.D. NUMBER (copy from Item I of Form 1) _OUTFALL NUMBER LuU/ I lvUru I-KUM IAur-V-ts I ~ b1UUU4Z/b 1 UU4
- 1. POLLUTANT 2. MARKX" 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. a.fe. o.pri cao. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE if available) quir- sant sent (d available) (if available) (d available) d. NO.OF a. Concen- b. Mass d. NO. OF d _ (1) ConAnt ofn (2) Mass (1) Ctoncantalion (2) Mtss (1) Concentration (2) Mass ANALYSES tration 1) Concentration 12)Mass ANALYSES GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (continued) 228 1.4-Cilro X .o ugjI W en.n(106848.7)
Z38.3.3-Dictior-Anz X ug/l Ib/Day 91-94.1) _ _ _ _ _ _ _ _ _ _ _ _ _ _ i__
Z48. Otethy blhalate X ugh tt/Day 84-68-2) z58. o"Imaosl 28Bi2.to X ugA ItvDay 131611-3) .
868.Dm.N-Bult4 hf9lslat- X Ug9 lb/Day 8474-2) 178.2.4.Dwi.ro. - U WDua osuen. (121.14-2) olsian (608-20-2) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
298. F4-)4 A u I H La. ri u9g Ib/Day 117-84.0) .
48.1.2-HDpfse)b/Da )- X. . ug/l Iblay IS. a Ah - ugn lb/Day unvn.)(12246-7) .
- 18. FXAo~noan X .7 WDa
- 28. I'Lorena -j aUP 818-73-7) _ _ . .
388. IOeacnloroX ug/)
an.-9 (118.74.1) 2110Napht'em ug/ Ib/Day 87-28-3)
B. haachfo-3
= - --
poaentodi- ug/1 lb/Day 861.
h~Aa&QhoC- - .... (9 A thtan.(67.72.1) _______
- 78. flOofo4 - -
1.2.3-cd) PyTne ug/l lbDay 193-39-5) ___.______._ _______ r_.__ ..
- 38. Isopfsorona A U7I1A 78.58.1)
B277S79) 198. Naphittialene -g - -suaI 91-20-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
108.fivotiobanan - x-.- A,- bv 98.95-3) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
18o.N-Nato--
ugh lb/Day
- 28. "nsNtosd. - -
1ro64aman ugh) lb/Day EPA Form 3310-9Q (Kov. 2453) PAGE V 7 CONTINUE ON PAGE V-8
I It EPA I.D. NUMBER(copy fromnItem I of Form1) IOUTFAL NUMBER CONTINUED FROM PAGE V.7 SC0004278 1 004
- 3. EFFLUENT 4 4. UNITS 5. INTAKE (optional)
I. POLLUTANT 2. MARKX _ _
- b. MAXIMUM 30 DAY VALUE a LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE 0NDCAS NO. r. pro.
- b. a. MAXIMUM DAILY VALUE
- d. NO.OF a. Concen- b. Mass d. NO. OF snt (if avai (f available) (if available) idavailable) quir.
ANALYSES ti on tra 1)Concntraton (2) Mass ANALYSES
- 2) s1) Concentriaion (2) Mass II) Concentration (2) Mass a d1)nconcera n GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (continued) _ _ _ _
48N-Nit.o- -_
ug/I IblDay 88-04) .__ _
2FA I
,t12SOpyre _.0u90.0)a 9 -
.1,2 .4-Tn- -
U Eug/A lb/Day lIU/
7F *1)DIa
[30IP. Alton 9.02)
Il~a 319-44)
_________________91
.ug/l i/a l
lll l X g l -E1aDy lp. b*WaBl1C - - sHC g 315-4 5-7) _ __X____u__
ug/l IbD P. guwimnaB-I X l .41 ug/) _______1_ _Ivay 57-74-9) _________ ~ ~ ~
'P. 4.4X-DOT ug/l _7FI O 50-29-3)
-=;l g I ug/l - v a P. 4,4.OQE -I
[1P. c~w firE wa # l l X U-/ =
1P.4.W.OX 72.5".)
-*Day 7 I 1E7oa-l lop. Dsetim -
60-57.1) _ _ _ _ _ _ _
12P.beia-Endosultan ~- Up 1115.29.7) _ _ _ _ _ _ _
13P.Enososulan -
Ugh Slate (1031.07-8) 14P.Endon
- L?- --
I7 E_________a_____y__
(72-20-8) 15P. En"n --.
_ _ C421N93-4) PA_ V-9 Up 1wwa 116P.
F76-448) i-eplaC~ro, _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
-- __ %Wv. d) Wo WN I INUt WN FAL.11 V-W
0 . , ,
EPA I.D. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 I SC0004278 004
- 1. POLLUTANT 2. MARKW __ 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. a.. tipr CAS a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE dfa*ailfa e) - lent snt (if vailabtie) (if avatlable) (if available) d. NO. OF a. Concen- b. Mass d. NO. OF ed 11) Concentratin (2) Mass (1) Concentratiort (2) Mass (1) concentration (2) Mass ANALYSES tration (1)concentration (2) Mass ANALYSES GC/MS FRACTION
- PESTICIDES (continued) 17P.hoptaor - X 1024-573) lbrDay 18P.P08-1242 __ _ - u t way 53469-21-9)
I9P. PCs-1254 - -u ay 111097491)
WP. PC.11221 X u- Eay ivI 5 11104-28-2)
FIP. s1Pt 232 -u A 7r I D7ay 11141.16-5) .
MP. Pc8-1248 AU t 3P. P,8-1260 - u-/r I-liay 4P. PC8-1016 _gA W7a -y 12674.11.2) tiP. To aptin/7 a 80 1 3 - )_ _ _ __ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ __ _ _ _ _ _ _ __3_ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _
EPA Form 3s10-2c (Rev. 2.85) PAGE V-9
yt I -1 it I1 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D. NUMBER (copy from Item 1 of Form 1) this information on separate sheets (use the same format) instead of completing these pages.
SEE INSTRUCTIONS I SC0004278 OUTFALL NO.
INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) 005 PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.
2.EFFLUENT 3.UNITS 4. INTAKE (optional)
- 1. POLLUTANT a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (d available) . ifavailable) 4 . NO. OF a.Cotn 5.Mass b.NO.OF
(_1_)
Concajliaon (2) Mass (1)Concentration (2) Mass 11)
Concentrabon (2) Mass ANALYSES trabon (1) Concentraljon (2) Mass ANALYSES
. Siochenmcal Oxygen 3 360.5 1 mgAI lb/Day 1emand 5BO0) I a Cheical Oxygen 30.7 3689.2 1 mgol lb/Day (TadCOO)
TdtalSuapenoed 4 480.7 1 m9A lb/Day Solits (TSS)
. Ammonia (as N) 0.08 9.6 1 mg/ lb/Day Flowa VALUE VALUE VALUE MGD X VALUE 14.4 10.91 52
. Temperature VALUE VALUE VALUE VALUE winter) 26.5 18.5 29 DEGREES CELSIUS Temperature VALUE VALUE VALUE VALUE summer) 27.2 24.4 22 DEGREES CELSIUS
,. pH IMINIMUM 71MAXIMUM 87MINIMUM MAXIMUM 0 SADRUNT
___ ____7.7__ 8.7__ _ _ __ _ __ _ 50 STA N DA RD UN ITS_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
PART B - Mark X in column 2a for each pollutant you know or have reason to believe is present. Mark X in column 2b for each poll tant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each outfall. See the instructions for additional details and requirements.
- 1. POLLUTANT 2.MARKCW _ 2. EFFLUENT 3. UNITS 4. INTAKE (optional)
AND CAS NO. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE d available) a pre- bab- (d available) (d available) d. NO. OF a. Concen. 5. Mass b. NO. OF sent snt (1)Conentrabon (2) Mass (1) Concrntation (2) Mass (1)Concemnution (2) Mass ANALYSES tration (1) Concentrastion (2) Mass ANALYSES
. Bromide X 2.97 356.9 1 m/I lb/Day 24959-67-9) l l l l
.Chlorine. C X 0.05 l 6.0 l 0.05 lC 6.0 50 m91/ IbDay statResidual
- Color X Std. ULnts X LFaca X Colories X c:io lor _m _ /100 ml l
. Flounda X 0.32 38.5 1 mgI lb/Day 16984488)
.Nitratea X 1.09 131.0 1 mgI lb/Day tite (as N)_ l _ ll
~
xF % o f n .
con ron- 45>g i.. alr dR
{V.
. aO OJ
&-"J In lr b VI1 PAGEt V-1 IQ TI
. U UN PA. v-CONTINUEFON PAGE V 2
.1
.4. f art scan § K K risen EPAI.D. NUM5ER (copy from Item 1 of Form 1)
ITEM V-B CONTINUED FROM FRONT I SC0004278 1I 005U"'r I
- 1. POLLUTANT 2. MAFK- 3. EFFLUENT 3. UNITS 4. INTAKE (optional)
AND CAS NO. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE idavailable) a.pr- b.ab (if available) (f available) id.NO. OF a. ConcAn- 0.Mass b. NO. OF sent sent (I) Concentration (2) Mass mi Concentration (2) Mass (1) Concentration (2)Mass ANALYSES trabon (1) Concentration (2) Mass ANALYSES TaO) OaA. mg/n lb/Day as N)__ _ _ _ _ _ _ __ _ _ _ _ _ _
erase A - 5 - 6b00.8 mg/- Day
.Phosphorous asP)7Total A 0.03 3.6 mg/ Ib/Day 7723.14-0) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _
Radoactvity eta) A__ . . -=U .pci X x_
Tow A pCin x x 2otal pCIl X XA Z2, Total APC/IA X x Si
&.tale__ _ _ _ _ _ _
as 604) A 30.99 3724.0 mg/l 10Day 14808.7941) as S) A 4 0.05 < 6.0 mg/I lb/Day as 503) A _ 2 < 240.3 mg/I Lb/Day 14265-45-3) . .
mg/A 1/Day ota)l A mg/I 1/Day
~7429i-90.5)__ _ _ _ _ _ _ _
Tot a mg/I lb/Day 7440-39.3) roal A mg/l lb/Day 7440-4248) eota A mg/I i/Day (743995-4) ..
7439494) A mgA 1b/Day Total A mg/l lb/Day 7439-95-4)
(ta 1 A mg/l 10Day 74398-7) rtow _ mg/I I/Day 7439.96-5) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
74,40-311.51 mg/I 10/Day eota) A mg/I 10/Day 1440.32.8) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
EPA Fotm 3310-2C (Rev. 2-55) PAGEV-2 CONTINUE ON PAGE V-3
- 1 a OUTFALL FLOW = 14.4 mod I NTAKE FLOW= mrgd b OUTFALL FLOW= mgdI c OUTFALL FLOWz 10.91 mgdI EPA I.D. NUMBER (copy fromItem 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C SC0004278 005 PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark 'X' in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outfalls, and nonrequired GC/MS fractions), mark "X" in column 2-b for each pollutant you know or have reason to believe is present. Mark 'X" in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile, 2, 4 dinitrophenol, or 2-methyl-4. 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. I
- 1. POLLUTANT 2. MARK X' l 3. EFFLUENT 4. UNITS 5. INTAKE (optional) l AND CAS NO. .- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE itavaDab) qi. leant lnl(af av le) (d *vadabM) (ifavalIabta) d. NO.OF a. Concen- b. Mass d.NO.OF dl (1) Concentration (2) Mass (1)concentraton (2) Mass (1)Concentration (2) Mass ANALYSES tration (1)Concentration (2) Mass ANALYSES ETALS, CYANIDE. AND TOTAL PHENOLS __I 1M Antimony, _ug1I/ay roI (7440-36-0) X i AnrnI, Total ug/l 7440.38-20 X __ _ l__
otaI(7440 41-7) X _
XCa_ ugx- I /May otal(7440-43-9) X ate)(7440.47-3) X _ _ _ _ _ _ _ _
Copp(., ToWtmgAl LV1ay rM.Lead. Total _2 W)Dlay 7439-92-1) X Mercwy, TotWl _ _ Xula 7439,-9746) X__ _ _ _ _ _ _
W.Nic."Toud W g11 744040240) X _________
iot . Selenium. ughlADay Tot (7782-49-2) X 1M. Sives 7Total-1D/7a W 7440-22-4) X a2 Thankmgl -- a Tot (7440-28-0) X
- 13. Zmic,Tot L7F mal aDay 744046-6) X 14t. Cyade., -2 1v 7ay etas (57-125) X ______
U11JAIN 2.3,7.8 Tatra 1 I I i3 E FDRESULTS wXlorodibF, P x NOT DETECTED (1764401 6) sDOxin I lP 1-C(e. 4)PG _om . ONIU NPG -
EPA Fofm 3510-2C (Rev. 245) CONTINUE ON PAGE V-4 V-3 PAGE
- 1 EPA I.D. NUMBER (copy from Item 1 of Form 1) ' OUTFALL NUMBER CONTINUED FROM PAGE V-3 I SC0004278 005
- 1. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. a.re- b.re cab- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE C.LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE ifavaitabbe) quir- sent sent (if available) (if available) (if available) d. NO. OF a. Concen- b. Mass d. NO. OF ed (1) Concentration (2) Mass (1)Concentration (2) Mass (1) Concentration (2) Mass ANALYSES tration (1) Concentration (2) Mass ANALYSES GC/MS FRACTION - VOLATILE COMPOUNDS 107.0241) X l -____Ivy_
- V.Acrywvwtnt - I -- gA~ -
107.13-1) X ____g/l_____._
71-43-2) X
,V. Ba(Chborc.
ts21)Erw X ug/ lb/Day X 5 4 2 - M8- ) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
V. Barnstorm 57 - a 75-25-2) X ._ug) _Iv _a V.Cabon rtrachwwe X ug/l lbDay wX-23-5) ug/l Way 1V.Ctlhorobenzeneo . WA 10840.7) X ug/lbva V.Corod-rr t an.eum X ugA lb/Day 124-48-1) X . u9___Way W6.C*kmwuw ug 70ay 75-00-3) X 10V.2uChlnoO-tW4vi 4EEaw X ug lWl/Day 1 1 0 -7 "- )_ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _
s7-4)) X W74. 3 - x_'ifo__-
x~rm ane X Ugh lb/Day 75-27-4) _ _ _ _ _ __ _ _ _ _
W3.DQdvoro-alan.ogu X ugh blbDay 7 5 -5 1-8) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
thlan. (75-34-3) X _ _ _ _ _
Isv. 1.2-ODchhoo- IgA - U~a-fthne (107-08-2) X _____
thylen. (75-35-4) X __ _ _ ___ _ _ _ _
Cww (75847-5) X __ _ _ _ __ _ _ _ _ __ _ _ _ _
Z;7 topylne (542-75-6)
X U - wbua 100-41-4) X_ _ _ _ _
V.Methyl UP - IE)Da7 (74 a) X _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
(74487.3) X ._ __ _
EPA Form 3510-2C (Rev. 2-0) CONTINUE ON PAGE V 5 PAGE V-4
I1 EPA1.0.NUMBER (copy from t1m 1 of Form 1) _OUTFAUL NUMUER CONTINUED FROM PAGE V-4 I SC0004278 I 005
- 1. POLLUTANT 2. MARK X7 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. are- Spr- lt,cap. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE 4 avadble) rn nt (if awadable) (r avadiable) (davadable) d. NO. OF a. Concen- b. Mass d. NO. OF d (1) Cono-nhratn ( s)Concntr Own (2) Mass (1)Concnunton (2) Mass ANALYSES tration (1) Conoentral-on (2) Mass ANALYSES GC/MS FRACTION VOLATILE COMPOUNDS (continued) .
22V.movwM) u4M1 Ib/Day 0(75.2) X 23V.l1,2I24TuFra.
OW) X ugJI Ib/Day Whyen(127.18-4) X 108-88.3) X
=_u9)_ila
-7 - w-26V.1,2-Tnwm.
I cborost X ugA Itbiay 15-0-5) _
2V. 1.1.1.Tn-tha0,ene X ugA lb/Day 30V. T2Ta-2SV. TVW).
4 n r_ X _ _ _u _a Ug/l
/lI_ lb/Day Tnchxl- x9
.(780149 )
- 31. . X Ugh lb/Day Chbnd75 4)-4) _ . . _
(.Mb M-HAUi 1tU- At.UJ tSUNU.
l 2-CN"o~ , o - - X _/DUay 2.44No - - I ug/ Iblay (12083.2) l 2,4-Dmthyn* - - Mu/vbDay not(105 467.9) X l_ __l U_______
4,6-DvotroO- - A -- ~ ay Wso(534-521) l X lu9/1
_ _ Ib/Day 2.4Omdro- - -ua yD not_(51-28-5) l _ _ _
24Nuop andf - - u9/ IVDay 8875-5) _ _ _ _ _ _ _.
C4-n 1rv -1 I* I n DI soot (59-407)
I I-X I u-/ Iblay-not p h (874 8.5) _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
1108.95-2) 8T6 lX _ = ugA IblDay =
I A. 2,4.6-Tn-14" p" Ug9/ lb/Day 8806-2) _ _
..t A D- .=- OOt^..'"^ N P '"-
tryCD-CrFee %n " -w1>2
,v-a tabs. -G) 5J 245) MAGEV-2 WONTINUEUON PAULE V45
.5 EPA I.0. NUMBER (copy from Item i of Form l)
_OUTFAU.NUMBER UUN I INUtU IKUM FAUM V-b I hLX;UUU14Z/tS I Uuu
- 1. POLLUTANT 2. MARKrX 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. are b.p- Ca a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE d avaie) qu. s (if available) (it available) (d available) d. NO.OF a. Concen- b. Mass . d. NO. OF d (1) Conralion (2) Mass (1) Concentraion (2) Mass (I) Concentration (2) Muss ANALYSES tration (1) Concentration (2) Mass ANALYSES GCIMS FRACTION - BASE NEUTRAL COMPOUNDS ._
18.Acenaptanen - - 1--v ua 83-32-9) 2t. Acena ene - U Ib/Da 208-984) 3B..Anuitracen WgDay 120.12-7)
'4=. Iblaey ugA 92 .817-5) _ _ _ _ _ _ _ _ _
BE.Betol) (a rcene u/g Wb/Day 56-55-3)
- 5, enwo (a) UgA "no (50-324)
F8.3.4-Bonzo iurnueeugh lb/Day 205-92) 3a.Benzao NI .
arytne (191 24-2) is. Benwo) . -
-kaorandhwn ug/I lb/Day 207-089) 108. IN&(2-Chor-u9w1 Metlaie ugII Ib/Day
'111-91-1) 11a. W(2-Ctloro .
athiy)Eror ugh Wb/Day 111-44-4) 12B.Bi(2-Chloro.so-Etr
)EB ug/ Ib/Day 10840.1) 13B. Bi (2-Egr 2 l - X 1
ob) Ptlstvalte ug9 Ib/Day 11741I7) 148.4-Br - .
- )tnyl Fb nyl U9/ lbDay th r(101-553) 15*. S"yl Eyl) - X .Ib/Day 168.2-CXoro- .
h , Ug/ lb/Day 91-58-7) 178. 4.Chboo-tryl bny ug9 btDay 7OM (7005-72-3) _
s8s. Crsens - - IDay 218.01.9) 9B.tmzo( X-lb/Day 53-70°3) X lb/Day n oon. (9 5-5 0.1 ) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _
lB. 1 ,i--W - -/ . iuay tI A eQm INCY.a-6se 11ayL (%*V.
runtA "3W46r n F M ... N Is fi V -I EVA rACE; V-0 CONTIINUE ON PAGE V-f
I' EPA l I.D.NUMBER (copy fromIem 1 of Form1) 1OUTFALLNUMBER UUN I INUtU IKUM VAUt V-b I bU;UUU4Z/t I UU0 1 1
- 1. POLLUTANT 2. MARK X 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. *.- . a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE C.LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE davaDbe) quit-
- sot (divaiabl) (ifavailable) (if available) d.NO. OF a. Concen- b. Mass d.NO. OF
_ I (1) CtntanirationI (2)Mass (1) Concentraion (2) Mass (1) Concentration (2) Mass ANALYSES tration (1) Coiicntratbon (2) Mass ANALYSES GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (continued) 2B. 1,4-hcoro- - A U9/ 'DDay nzone(106-46.7) 38.3.3-OXch4 .
X Ug9 lb/Day 248.Q.bsi 84-662) 311:446-2 X _ _ _ _ _ _ _ _ U9/1 WbDay 268.Dimstli.
10ut t11-)X x ug/l uigf lb/Day lb/Day 131.11.3) _ _ _ _ _ _ _ _
- 68. Dm-N-Bulyl to X ugA ib/Day i34-74-2) 27B.2.4A-Dora _g X . 91 ay olsen. (121-14-2) _ _
88B.2.6-Oqoduro- - - -7U-oluan (606-20-2) U9_1 __lay
- 98. OD-NOy -
' ^to ug) lb/Day 4B. 1,2- wnyl- - .
iydrazin ( Azo ug lb/Day ownue)
(122-66-7) 318.Flipovahgto - - ~ua-18.Fitorw U9/j 8 73-7) X ___l_____
i38.
NoisncNi_.oro- Ug/l tbl~ay n one (1i18.74-1) _ _ _ _ _
2lX t . ugfl lb/Day 87.68.3)
B. iebchloro nbpnadione Ug/1 lb/Day 77-47-4)
B6. NozA&wol8- Y.u4 ILa than.(67-72-1) X _9A t_/Day 178.Warno X 1.2.3-cd) Py~rne Ugl lb/Day 193-39.5) _
B. )Xisw - _ ugA 1i7viy 7 8.59.1) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
l98.Napihumier - -r u9 i/ay 91-20-3) iO8.NaB.__. - A U-A 118.N-Nilh-c-wdwylamno Ug/I lb/Day G2.75-9) ___ _ U9/_
- 28. o.od- * .X G214A-.n Ug) lb/Day 62.. 4 7 _ _ _ _ _ _ _s ew_.............. _ _w__ n. . . . . . _
EP-A fQ(m 351U-iI6 JKOV.W26) PAGEV-7 CONTINUE ON PAGE V48
.1 I
EPA ID. NUMBER (copy from IhemI of Fofrm1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 SC0004278 1 005 5 - ------ S
- 1. POLLUTANT 1 2. MARKX 3. I 1 2. MARK Xw D D- a . s - , 4. UNITS 5. INTAKE (optional)
AND CAS NO.
v j ffi *
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE
& . - o o b.p.- tci.A ffi
- a. LONG TERM AVG. VALUE d Savmisff) sent sentl (Ofavalable)
(1) Comentration l (2) Mats 1 I (l) ConcAntraon (f avalable)
I (2) Mass (ift Va4abl)
(1) Concentration (2) Mass
- 8. NO. OF ANALYSES I
- a. Concen-tration
- b. Mass I d.ANO.AOF GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (continued) .. . . _._.__ __
438. N-Nr0- U-A WIDay
~883046) _ _ _ __ _ _ _ _
so1dpteyln 448. PfatlWVer - __h q 51A .
U9/1bDay 458 PT .U7r -M0-y
'129-00-0) _ U___Way 468.1,2,4-Tn. - -
lsoorobenzons UgA lb/ay
'120d82.1)
ULLMb I- KA(; I IUN -tPEbST _ _
IP.Ajdn - U7r- Dwa7
'30"Z02) )blay u 9 / 1_
2P, EEsaBIC - X- *921 IlDay (P.b7ta-Oc - A ug- Way 7P.4,4'DT -_A *'bDay 3 92-58 i~i.
4.4-OOE
- 9) -u-tAI = = ____U _ __ay _ 1WDa (72-54-8) - l_ T _ __ _ _ u lop. Qerow" - -g7 y 60.57-1) _ ug/ _ _ l I b/Day I1P.allpho-Endosutf an - -g7 IWDay 1P. boEls osutaln - _ __ _ _ A__
[115-29-7) X _ _______/Da 13P.Endosutan - -
Sulfate Ugh)
(1031-07d8)
I*P. Endon (72-20d8) __________
=
A X _ __ _b/Da_
~1D U9/ 7 Abehtyde ugh)
(7421143-4) __ _ __ _ _ __ _ __ _ __ _ _ __ _ _ __ _a__ _ __ _y__ _ __ _ _
16P. hoptachl-(78-44-)a_) _ _ ug/l A
... A _o~
51.20e. 2.85 PAG =8 CONlT.ID/Ua ON.PA_ V-B....__
EPA form 3310-2G (Roy. 245) PAGE V4 CONTINUE ON PAGE V 9
I EPAI.D. NUMBER (copy from Item of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 I ~ SC0004278 I 005 I. POLLUTANT 2. MARK "X 3. EFFLUENT 4. UNITS 5. INTAKE (optional)
AND CAS NO. .S Dp a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (d vSW&") quir. sntvont (f available) (if anaiable) (df aiIabI.) d NO OF a. Concen- b. Mass d. NO. OF ad1) I onmcenruhbon (2) Mass (1) Coxne nuiton (2) Manss (1) toncentration (2) Mass ANALYSES tration (1)Concentraion (2) Mass ANALYSES GC/MS FRACTION - PESTICIDES (continued) .
17P. fr1puQ-9sh A dUg _I/Day 1024457.3) _ _ _ _ _ _ _
53469-21-9) _ X Utl I__ay
_P. PC4-=1254 -== li =
1107-'9.1) __la U9/)
OPPCB.1221 U9/1 IWUay 1)104.28-2) _ _ _ _ _ _ _
IP. PCS-1232 A V*gI*-1AI 11141.18-5)
P.PC8-1248 x7_ ~I ug/_ ~ ~~wuay_
-2.72-294) W ay 3P. PTo.1260 -ul
)bDay
,1(800101 . _a 126 74 .11-2) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
P.Toan.
8001,35. 2
- -F I A I _ __ _ __ _
- I 7 tEPA Form 3510-2C (Rev. 285) PAt;E V-9
p..
EPA IDNumber (Copy from Item I of Form 1) : ."orm Approved , .-..**ne Pleastype or prin In the unshaded ar nly. SC0004278 F orm - ....... ..t >.*.......,.--
'!' ' 'A'"
..,tt-.wt_
NPDE S EPA 'LFacilities Which Do Not Discharge Process Wastewater
- 1. Receiving Water For this outfall, list the latitude and longitude, and name of the receiving water(s).l : .. .. :.;,;..
Outfall I Latitude on gitude Receiving Water (name)
Number (list) M n-a Sec Deg I Min .o :'SecI 001 35 3 5 81 4 10 ILake Wylie 11.Discharge Date (If a new discharger, the date you expect to begin discharging)
NWA Ill. Tye of Waste A. Check the box(es) Indicatng the general type(s) of wastes discharged. . -i-- Other Nonprocess CI Sanitary Wastes ' RestaurantorCafeteria'Wastes Noncontact Cooling Water [] Wastewater (identify)-
B. If any cooling water additives are used, list them here. Briefly describe their composition if this Information is available.
- A polyacrylate solution is added to the Nuclear Service Water System (once-through cooling) to control silt deposition. The concentration at the plant discharge is below the NOEC.
- An oxidizing biocide, Stabrex (stabilized hypobromous acid) or sodium hypochlorite, is also added to this system to control biofouling and under-deposit corrosion. The concentration at plant discharge is within the permit limits.
IV.Effluent Characteristics A. Existing Sources - Provide measurements for the parameters listed in the left-hand column below, unless waived by the permitting authority (see Instructions).
B. New Dischargers - Provide estimates for the parameters listed In the left-hand column below, unless waived by the permitting authority.
Instead of the number of measurements taken, provide the source of estimated values (see Instructions).
(1) (2) (3) (4)
Pollutant or Maximum Average Daily Number of Source of Parameter Daily Value Value (last year) Measurements Estimate (including units) rincgde units) Taken (if new Mass Concentration Mass Concentration (last year) discharger)
Biochemical Oxygen 2,451 lb/day 3.0 mg/i 1,701 lb/day 3.0 mg/I 1 Demand (BOD)
Total Suspended Solids (TSS) 8,170 Ib/day 10 mg/I 5,686 lb/day 10 mg/l 1 Fecal Coliform (if believed present or if sanitary waste Is discharged)
Total Residual Chlorine (if 5.72 lb/day 0.0070 mg/I 0 lb/day 0 mg/I 779 chlorine Is used)
Oil and Grease <4,089 <5.0 mg/I < 2,846 <5.0 mg/I I Iblday Iblday
- Chemical oxygen demand <16,356 <20.0 mg/I < 11,382 <20.0 mg/I 1 (COD) lb/day lb/day
'Total organic carbon (TOC) 3,238 lb/day 3.96 mg/I <2,254 3.96 mg/I I
__ __ __ __ __ _ __ __ __ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ lb /d ay_ _ _ _ _ _ _ _ _ _ _ _
Ammonia (as N) 40.9 lb/day .05 mg/I 28.4 lb/day .05 mg/I 1 Discharge Flow Value 98 MGD 68.2 MGD 365 pH (give range) Value 6.8 61 Temperature (Winter) 23.8 17.1 °C 181 Temperature (Summer) 33.1 0C 29.1 °C 184
'if noncontact cooling water is discharged EPA Form 3510-2E (9-86) Page 2 of 2 I
I
V. Expect for leaks or spills, will the discharge described In this form be intermittent or seasonal? - .
If yes, briefy describe the frequency of flow and duration.. - : _ . - , :l: ; Y No l . t * -.
VI. Treatment Syter Describe briefi an treatment stem s used or to be used Treatment system to be used:
In order to more effectively control biofouling and corrosion, sodium hypochlorite andlor hypobromous acid concentrations will be increased in 2005. Prior to Increasing biocide concentration, a chemical addition system will be added to the once through cooling system to inject sodium bisulfite, which will neutralize the biocide prior to discharge, thus meeting current discharge limits.
VII. Other Information (Optional lI Use the space below to expand upon any of the above questions or to bring to the attention of the reviewer any other Information you feel should be considered In establishing permit limitations. Attach additional Sheets, If necessary.
VilI. Certificationi I certify underpenalty of law that this document and all attachments were prepared under my direction or supervision In accordance with i:
a system designated to assure that qualified personnel properly gather and evaluate the Information submitted. Based on my Inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Information, the Information submitted Is to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false Information, including the possibility of fine and Imprisonment for knowing violations.
A. Name of Official Title B. Phone No. (area code & no.]
Dhiaa Jamil, Vice PresidentCatawba NuclearStation (803) 831-4251 C. Signature D. Date Signed
\~~ . /,7o 5(e-/wy EPA Form 3510-2E (9-86) Page 2 of
EPA ID Number (Copy from Itemform Approved Please type or prnt In the'un d areas only ',Approva, expires 7-3 -88 ;.. -;
2E NPDES i PAe ,Facilities Whicht ---Discharge Process lDoNot -i Wastewater..
I. Receiving Water
- For this outfall, list the latitude and longitude, and name of the receiving waterns) . .; . . .*. .;... . -
Outfall:
.. . . titudeo ^ : tude -, Receiving Water (name) i Number (list) Deg . Sec , -1 Min - -."Sec 003 35 3 5 81 1 4 10 Lake Wylie II. Discharge Date (If a new discharger, the date you expect to begin discharging)
NA IlI. Type of Waste A. Check the box(es) Indicating the general type(s) of wastes discharged. . . .-. . .Other Nonprocess Sanitary Wastes i Restaurant or Cafeteria Wastes U Noncontact Cooling Water -J Wastewater (identify)
B. If any cooling water additives are used, list them here. Briefly describe their composition if this Information is available.
IV. Effluent Characteristics A. Existing Sources - Provide measurements for the parameters listed in the left-hand column below, unless waived by the permitting authority (see instructions).
B. New Dischargers - Provide estimates for the parameters listed In the left-hand column below, unless waived by the permitting authority.
Instead of the number of measurements taken, provide the source of estimated values (see instructions).
(1) (2) {3 r) (4)
Pollutant or Maximum Average Daily Number of Source of Parameter Daily Value Value (last year) Measurements Estimate (including units) incude units) Taken (if new Mass Concentration Mass Concentration (last year) discharger)
Carbonaceous Biochemical 8.8 lbs/day 9.4 mg/I 0.85 lbs/day 4.6 mg/I 13 Oxygen Demand (CBOD)
Total Suspended Solids (TSS) 23.7 lbs/day 25.4 mg/I 2.6 lbs/day 14.1 mg/I 13 Fecal Coliform (ifbelieved/100 ml 44.2/100 ml 19 present or if sanitaty waste Is discharged)
Total Residual Chlorine (if 0.28 lbs/day 0.3 mg/I 0.03 lbs/day <0.1 3 chlorine is used)
Oil and Grease <4.7 lbs/day < 5.0 mg/I <0.9 lbs/day <5 mg/I i
'Chemical oxygen demand (COD)
Ammonia (as N) 3.22 lbs/day 3.44 mg/I 0.63 lbs/day 3.44 mg/I I Discharge Flow Value 0.112 MGD 0.022 MGD 365 pH (give range) Value 8.0 6.2 51 Temperature (Winter) -- - 18.4 c 12.4 °C 29 Temperature (Summer) 27.3 24.3 25
'If noncontact cooling water is discharged EPA Form 3510-2E (9-86) Page 2 of I
V. Expect for leaks or spills, will the discharge described In this form be Intermittent or seasonal? - :
If yes, beflydescribethefretuency of flow and duration.'. ,i :, : Li Yes No VI. Treatment Syter (Descrbebriefl an treatment stem s used or t be use A
VII. Other Information Optional)
Use the space below to expand upon any of the above questions or to bring to the attention of the reviewer any other Information you feel should be considered In establishing permit limitations. Attach additional Sheets If necessary.
Sanitary wastewater will be re-routed to York County during the first half of 2005. This outfall will be eliminated after the tie-in.
Vill. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision In accordance with a system designated to assure that qualified personnel properly gather and evaluate the Information submitted. Based on my Inquiry of the person or persons who manage the system, or those -persons directly responsible for gathering the Information, the Information submitted Is to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false Information, Including the possibility of fine and Imprisonment for knowing violations.
A. Name of Official Title . B. Phone No. (area code & no.)
Dhiaa Jamil, Vice President Catawba Nuclear Station (803) 831-4251 C. Signature D. Date Signed I I l// f/ Y_
EPA Form 3510-2E (9-86) Page 2 of 2 I
Duke Energy Corporation Catawba Nuclear Station NPDES Permit Rcnewal Summary of Requested NPDES Changes Outfall 001 1.1 Delete nitrite monitoring requirements. Sodium nitrite is no longer used as the corrosion inhibitor in closed cooling systems. The-station switched to sodium molybdate during 2002. Sodium nitrite is a component of ethylene glycol, which is used in some plant cooling systems, however the concentration of sodium nitrite in glycol is extremely low and would not be detectable in wastewater systems.
1.2 Delete the monitoring requirement for total recoverable copper. The majority of copper in the discharge is the result of copper from intake water being "cycled up" in the cooling towers. The contribution from the
- plant is very small. Toxicity testing at this outfall has shown that the copper concentration is not adversely affecting the receiving water.
- 2. Outfall 002 2.1 Delete nitrite monitoring requirements for the same reason as in 1.1 above.
- 3. Outfall 003 3.1 This Outfall will no longer be used after 2005. Provisions for this should be made in the next permit.
- 4. Part Ill. A. - Other Requirements 4.1 Delete III.A.23 requirement based on the reasoning in 1.2 above.
Catawba Nuclear Station NPDES Permit SC0004278 Pennit Changes Requested 12/1/2004 Permit Renewal Application Page I of I I
l C taO 0 PROTLCT TIgSft, South (Croina Deputwect f Heahlh and i sFrocmubl Coobrot BUREAU OF WATER SLUDGE DISPOSAL SUPPLEMENT FOR NPDES AND ND PERMIT APPLICATIONS Facility Name: (!C oiJ k Alar S Ale 6al Permit Number: SCOO aq C (4 a2b (leave blank for a new facility) or NDOO Please check your proposed or current sludge disposal procedure:
- 1. Existing Eacilities:
X Lagoon or other facility with no routine sludge disposal. Please attach a letter that addresses the approximate schedule for sludge removal and address the anticipated disposal method (note that the proposed sludge disposal method must be approved by the Department prior to initiation).
Sludge disposal at another wastewater treatment facility. Attached is a recent letter of acceptance dated . This letter must include the NPDES or ND number of the treatment facility accepting the sludge for disposal. If no previous SCDHEC approval has been granted on the disposal method, then please include a detailed report on the existing sludge disposal method. See the attached requirements for Sludge Disposal Report A. If a previous SCDHEC approval has been granted, then include a recent analysis that shows the non-hazardous nature of the sludge or a signed statement that the sludge characteristics have not changes since the last analysis.
a Sludge disposal at a landfill. If the landfill is SWAIP (special waste) approved, an recent acceptance letter from the landfill is acceptable. If the landfill is not SWAIP approved, attached is SCDHEC Solid and Hazardous Waste approval dated , or other SCDHEC approval dated . If no previous approval has been granted on the disposal method, then please include a detailed report on the existing sludge disposal method. See the attached requirements for Sludge Disposal Report B.
Sludge disposal by Beneficial Use of Sludge. Attached is SCDHEC approval letter or program approval dated . If no previous approval has been granted on the disposal method, then please include a detailed report on the existing sludge disposal method. See the attached requirements for Sludge Disposal Report C.
fl. Proposed Facilities:
Lagoon or other facility with no routine sludge disposal. Please attach a letter that addresses the approximate schedule for sludge removal and address the anticipated disposal method (note that the proposed sludge disposal method must be approved by the Department prior to initiation).
Sludge disposal at another wastewater treatment facility. Please include a detailed report on the proposed sludge disposal method. See the attached requirements for Sludge Disposal Report A.
Sludge disposal at a landfill. Please include a detailed report on the proposed sludge disposal method. See
'the attached requirements for Sludge Disposal Report B.
Sludge disposal by Beneficial Use. Please include a detailed report on the proposed sludge disposal method.
See the attached requirements for Sludge Disposal Report C.
Send this form and the appropriate disposal report (if applicable) with your NPDES or ND permit application.
ALSO SEE ATTACHED INSTRUCTIONS July 1. 1998
/
Duke Energy Corporation Catawba Nuclear Station NPDES Permit Renewal Sludge Disposal At A Landfill: Sludge Disposal Report B A. Sludge Generator
- 1. Name - Duke Energy Corporation, Catawba Nuclear Station
- 2. Address - 4800 Concord Road, York, SC 29745
- 3. Phone Number- 803-831-3000 4 Countye- York
- 5. NPDES Permit Number - SC0004278
- 6. Plant capacity (MIGD)
Conventional Waste System = Design Maximum of 2.88 MGD Sanitary Waste System = Design Base of 0.080 MGD
- 7. Amount of sludge generated per year (dry weight tons)
Conventional Waste System = Varies with facility operation - average of 9000 pounds per year.
Sanitary Waste System = 0
- 8. Size, description, and location of sludge storage Conventional Waste System - Sludge is not stored. When accumulated sludge within the system reaches a volume that requires processing, that portion of the system is isolated and the sludge removed. The removed sludge may require drying or processing to remove free water prior to disposal in the landfill.
Immediately after processing or drying, the sludge is placed in the permitted landfill.
Sanitary Waste System - Sludge is not stored. When the system is shut down in 2005, the accumulated sludge will be dried or processed to remove free water prior to disposal in the landfill. Immediately after processing or drying, the sludge will be placed in the pcrmitted landfill.
Catawvba Nuclear Station NPDES Permit SC0004278 Sludge Report B 12/1/2004 Page l of3 I
- 9. Amount of stockpiled sludge and sludge age As stated above, sludge is not stored or stockpiled. Sludge depth is monitored in the treatment systems. When the accumulated sludge warrants, it is/will be disposed in the permitted landfill immediately upon completion of drying or processing to remove the water.
- 10. Description of sludge treatment (sludge must be stabilized). Process to Significantly Reduce Pathogens (PSRP), if any. Process to Further Reduce Pathogens (PFRP), if any.
The Sanitary Waste Treatment System does not produce large amounts of sludge due to the process used for treatment. As approved in our Sludge Management Plan, which was submitted to SCDHEC on December 12, 1992, Catawba will seek approval for the proper treatment and disposal of this sludge after the Sanitary Waste Treatment System is closed in 2005.
- 11. Current method of sludge disposal The SCDHEC approved Sludge Management Plan is attached. This plan was required by the NPDES permit issued on September 15, 1992. The plan describes the routine sludge generation for the facility and the disposal methods. The permitted site landfill, IWP - 463303 - 1601 (formerly IWP - 192), is approved to accept the routine sludge generated at the facility (copy attached).
- 12. Letter of acceptance from an official of the landfill accepting the sludge for disposal Approval has been sought and obtained from SCDHEC to dispose of sludge in the pcnnitted site landfill. Catawba Nuclear Station has no arrangements with any other landfill to accept sludge generated at the facility.
- 13. Amount of sludge transported, reported in dry tons per year Sludge removal from the Conventional Wastewater Treatment System occurs every 4 to 5 years. The sludge is dewatered on site and transported to the site landfill. The average dry weight of the sludge is 42,000 pounds.
The domestic wastewater lagoon has never required sludge removal. Sludge accumulates in the bottom of the 10 feet deep cells and decomposes anaerobically. It is estimated that the accumulated sludge would be -35,000 pounds, dry weight.
Catawba Nuclear Station NPDES Permit SC0004278 Sludge Report B 12/1/2004 Page 2 of 3 I
- 14. Estimated percent solids and total liquid volume A vendor using a SCDHEC approved water removal process presses sludge from the Conventional Waste System. The final waste product is subjected to the Paint Filter Test to ensure acceptable levels of free liquid prior to burial in the permitted landfill. This same process will be used for disposal of sludge from the Sanitary Waste Treatment System.
B. Sludge Analysis Information I. TLCP toxicity results with acceptable ignitability, corrosivity, and reactivity lab report or rational to demonstrate the non-hazardous nature of the sludge.
For existing facilities, a statement that no change in sludge constituents has occurred since the last EP or TCLP toxicity test and provide a copy of the latest test results.
For the Conventional Wastewater Treatment System, there has been no change in the sludge constituents since the last TCLP that was conducted during September 1995 (results attached).
For the Sanitary Waste Treatment System TCLP testing was performed in 1991 and determined to be non-hazardous. (results attached).
- 2. Name, address, and phone number of the certified lab conducting the analysis General Engineering Laboratories PO Box 30712 Charleston, SC 29417 (803)556-8171 Duke Power Analytical Laboratory Services 13339 Hagers Ferry Rd.
Huntersville, NC 28078 (704) 875-5038
- 3. Other compounds required by NPDES or ND permit or present in effluent to treatment plant All chemical constituents are identified in the application narrative section attached to Form I and in the analysis results documented in Form 2C.
Catawba Nuclear Station NPDES Permit SC0004278 Sludge Report B 12/1 /2004 Page 3 of 3 I
Duke Energy Corporation Catawba Nuclear Station NPDES Permit Renewal Sludge Disposal At A Landfill: Sludge Disposal Report B Attachment 1 Sludge Management Plan Catawba Nuclear Station NPDES Permit SC0004278 Sludge Report B 12/1/2004 Attachment I I
Duke Power Company GenerationServices Department 13339 Hagers Fery Road lluntersoille. NC28078-7929 DUKE POWER December 17, 1992 To: Mr. Robert Knauss
-Enforcement Division Bureau of Water Pollution Control South Carolina Department of Health and Environmental Control 2600 Bull Street
- Columbia, SC 29201
Subject:
- Catawba Nuclear Station NPDES Permit No. SC0004278 Waste Water Treatment Systems Sludge Management Plan File: CN-702.13
Dear-Mr. Knauss:
As required by Part III Item 10 page -29 of 31 of the subject NPDES permit, attached is the sludge management plan for Catawba Nuclear Station's NPDES waste water treatment facilities. If there are any changes to this plan Duke Power Company will notify you.
Please advise (704) 875-5970 -if you have any questions or need additional information.
Sincerely, Robert R. Wylie, Engineer Environmental Division Duke Power Company cc: Timothy Eleazer - DHEC Columbia Office Al Williams - DHEC Catawba District Cheryl Peed - Catawba Nuclear Station-
, Page I-of 2 CATAWBA NUCLEAR STATION SLUDGE MANAGEMENT PLAN INTRODUCTION This plan identifies the various.sludges, mud and oils that are removed from NPDES treatment systems and are required. to be disposed of by rules and regulations of the Bureau of Solid and Hazardous Waste Management. At Catawba Nuclear Station sludge and/or mud is removed from the conventional waste water treatment system, the cooling towers and miscellaneous sumps. Sludge may eventually be remove from the domestic sewage treatment system at which time appropriate DHEC approvals will be requested and the removal will occur in accordance with DHEC rules and regulations.
Chemical metal cleaning sludge is presently not generated at Catawba Nuclear Station.
CONVENTIONAL WASTE WATER TREATMENT SYSTEM Approximately every eighteen months dewatered sludge is removed from the conventional waste water treatment system. This sludge is dewatered by a vendor and disposed of in the on-site landfill in accordance with the vendor's construction permit and the landfill's permit (4IWP-192), -respectively'. Additionally if the sludge is determined to have measurable levels of radionuclides that are due to the facility's operation , then approval is also obtained from the DHEC Bureau of Radiological Health prior to the disposal operation.
COOLING TOWER SYSTEM During refueling outages the cooling tower system is dewatered and mud is normally needed to be removed. This occurs .approximately every fourteen months for ea:ch of the two units. This mud is primarily removed from distribution flumes.. The disposal is conducted in accordance with the special conditions as outlined in the landfill permit (#IWP-192).
YARD DRAINAGE COLLECTION SYSTEM The yard drainage collection system periodically needs sand and mud to be removed. This material is removed by use of a vacuum truck and placed upland in areas that will minimize any runoff to Lake Wylie.
MISCELLANEOUS The potential exists for sludge to accumulate in various sum&s at the site. This sludge may periodically need to be removed to prevent its buildup or if a special maintenance activity such as coating of the walls is. to occur. Prior to the sludge being disposed of it will be characterized either by knowledge or analytically and then as appropriate approval for its disposal will be sought.
I
Page 2 of 2 OIL COLLECTION
- An oil coalescing unit is utilized to aid in preventing oil from entering the service building sump. The oil that is collected in the oil coalescing unit's collection tank is drained and sent off-site for fuel usage. If oil does reach a treatment system is it is removed with oil absorbent material and disposed of as approved by DHEC.
Duke Energy Corporation Catawba Nuclear Station NPDES Permit Renewal Sludge Disposal At A Landfill - Sludge Disposal Report B Attachment 2 Site Landfill Permit Catawba Nuclear Station NPDES Penrit SC0004278 Sludge Report B 12/1/2004 Attachment 2 s; J
/ I South Carolina -, ' Cor sti:on. Douglas E. Bryant I
DIIEC Department of Heatth and Envronmental Controf Boad: Richard E. Jabbour. DO9S, Chaiman Robert J. Slriptng. J., VWce Ctialman Sandra J. Motander. Secretary William E.Applegate. li.
John H Burriss Tony Graham, Jr, MD John B.Pate. MO 2600 Bull Street Columbia. SC 29201 Promoting Healthi, Prowteing Me Environment OFFICE OF ENVIRONMENTAL QUALITY CONTROL BUREAU OF SOLID AND HAZARDOUS WASTE MANAGEMENT INDUSTRIAL WASTE PERMIT IWP-192 Date of Reissue:November 1. 1993 Effective Date:December 1. 1993 Permission is hereby granted to:
Name of Facility: Duke Power Company Address: P.O. Box 1007 Charlotte, NC 28201-1007 supervisor: Chuck Denny Phone: (803) 831-3676 for the operation of an on-site industrial waste landfill located approximately seven (7) miles north of the city of Rock Hill on Road 11132.
This permit is issued pursuant to Sections 44-96-10 et sea.,
48-1-10 et seg. and 44-1-140 (11) of the 1976 South Carolina Code of Laws, as amended, and South Carolina Rule(s) and Regulation(s)
R. 61-70, including the Permitting Protocol approved by the SC DHEC Board on March 11, 1993. The authority granted hereunder is subject to the requirements of the aforementioned laws and regulations and the attached conditions.
William W. Culler, P.E., Director Division of Solid Waste Management Bureau of Solid and Hazardous Waste Management This permit is non-transferable and is the property of the Bureau of Solid and Hazardous Waste Management and must be surrendered on demand.
If the permit is appealed, the effective date of the permit will be revised as necessary. Any, request for review or appeal of this permit must be served in person or by mail within fifteen (15) days of the date of issuance, on:
.The Board of Health and Environmental Control Office of the Commissioner 2600 Bull Street Columbia, South Carolina 29201 81 3 (803) 734-4880
¶J ,ecyckdpver
Catawba Nuclear Station Landfill IWP-192 A. General IWP Permit Conditions
- 1. The Permittee shall adhere to the approved design plans and specifications and operational plan, revised on June 27, 1988 and with revisions dated September 24, 1991, unless permit conditions state otherwise.
- 2. This permit is limited to the disposal of the following waste(s): inert construction debris, paper; cans, wood, plastic, dunnage, conventional industrial wastewater treatment sludge, cooling tower sludge, sanitary wastewater treatment sludge, asbestos material, non-hazardous oil and hydraulic oil materials spilled, such as rags, soil and absorbent, sandblasting material, alumina, non-radioactive carbon, slightly radioactive carbon, exhausted KG resin, boric acid, borax; acid, caustic and glycol spill clean-up materials; silica gel, powdered anion hydroxide resin, and powdered cation ammonia resin.
- 3. It is the Permittee's responsibility to ensure that no other waste is disposed at this site. If the Permittee determines the need to dispose of any waste other than that listed in permit condition two (2), prior written approval must be obtained from the Bureau of Solid and Hazardous Waste Management. Each request shall be made in writing to the attention of: Manager, Waste Assessment Section, cc:
Director, Solid Waste Management.
- 4. All waste shall be covered daily with a minimum of six (6) inches of clean soil with the exception of sandblasting material and cooling tower sludge. Cooling tower sludge shall be covered at a minimum of once a week.
- 5. Should a disposal area become inundated or have measurable water contained, steps must be taken to remove this water before continuing disposal of waste.
- 6. This permit will be subject to an environmental compliance review at least once every 5 years.
November 1, 1993 Page 1 of 8 I
B. Groundwater Permit Conditions
- 1) GROUNDWATER DETECTION MONITORING SYSTEM The Permittee shall maintain a groundwater detection monitor-ing system consisting of a sufficient number of wells, installed at appropriate locations and depths to yield representative groundwater. samples from the hydrologic units underlying the site.
.a) Monitoring well(s) shall be maintain hydraulically upgradient from the waste management area with numbers, locations, and depths sufficient to yield groundwater samples that are representative of background groundwater quality in the uppermost aquifer, and not affected by the facility.
eb) Monitoring wells shall be maintain hydraulically downgradient from the waste management area with numbers, locations, and depths .sufficient to promptly detect any statistically significant degradation of groundwater quality in the uppermost aquifer.
.c) The monitoring system shall be continuously maintained in such a manner as to yield samples representative of the quality of groundwater immediately upgradient and downgradient of the waste management area.
.d) The Permittee shall construct monitoring wells and maintain monitoring well integrity in accordance with R.61-71 and the well construction specifications in the permit application. In addition, each monitoring well shall be properly labeled with a permanent identification plate constructed of a durable material secured to the well casing or surface pad where it is readily visible.
.e) The Permittee shall maintain groundwater monitoring wells designated MW-1A, MW-2, MW-3, and MW-4. If the Permittee determines or is notified by the Department that the groundwater monitoring system no longer satisfies the minimum requirements for the number, location, construction, or integrity of wells, pursuant to permit condition 1, (e.g., structurally damaged wells, dry wells, wells no longer upgradient or downgradient, etc.)
the Permittee shall:
- i) Notify the Department in writing within seven (7) days of evaluating data, but no later than sixty 60 days after collecting groundwater monitoring data, that the monitoring system no longer satisfies permit conditions; November 1, 1993 Page 2 of 8 -
I
- ii) Submit to the Department in writing a complete proposal to upgrade the monitoring well network within thirty (30) days of notification from the Department, but no later than ninety (90) days after collecting groundwater monitoring data; and
'iii) Complete installation of additional well(s) necessary to achieve compliance with permit conditions within 60 days of receiving approval from the Department.
- 2) ROUTINE GROUNDWATER MONITORING The Permittee shall perform routine monitoring of groundwater quality and elevation conditions to determine if waste disposal activities are affecting groundwater quality at the waste management area.
a) The Permittee shall perform groundwater monitoring according to the constituents in attachment I for all wells that are determined to be components of the groundwater network and any other well(s) deemed necessary by the facility or the Department to uphold the intent of this permit. The permittee shall ensure that groundwater monitoring is conducted semi-annually in accordance with the schedule presented in section 6a of these permit conditions.
.b) The Permittee must determine during each sampling event the elevation of the groundwater surface in each well.
Elevations must be determined on the same day that samples are collected.
vc) The Permittee shall collect, preserve, and analyze groundwater samples pursuant to a revised sampling and analysis plan to be submitted within 90 days of issuance of .this permit and any subsequent modifications required by the Department.
- 3) DATA EVALUATION The Permittee shall evaluate all groundwater quality and water level elevation data to determine if the waste management area is impacting groundwater.
a) The Permittee must submit a plan for statistically evaluating groundwater quality data generated by the facility. In addition, the plan should be capable of determining if a statistically significant impact to groundwater has already occurred. This plan must be submitted within 90 days of issuance of this permit.
November 1, 1993 Page 3 of 8 I
b) The Permittee should ensure that the groundwater flow rate and direction are evaluated by a qualified groundwater professional each time samples are collected.
This evaluation should be used to determine whether the groundwater monitoring requirements under permit condition 1 continue to be met. A summation of the results of this semi-annual evaluation must be supplied in the annual report specified in permit condition 6b.
- 44) ASSESSMENT OF GROUNDWATER IMPACT
.a) If statistical evaluation of the monitoring data indicates that a statistically significant change in groundwater quality has occurred, and said significant change has not been or currently is not being addressed through a condition of this permit, the Permittee shall, ii) Notify the Department within seven (7) days of making the initial determination that a significant trend or significant difference over background exists.
'ii) Submit to the Department within thirty (30) days of notification, a preliminary report which addresses the potential for detrimental impact to human health and the environment as a result of the statistically significant change. The report should indicate whether additional assessment and\or corrective actions are warranted.
'b) If routine monitoring indicates ;that a constituent exceeds the standards established in R.61-68 (Water Classifications and Standards System), and said exceedance is not currently being addressed through a condition of this permit, the Permittee shall,
- i) Notify the Department in writing within seven (7) days of making that determination.
ii) Immediately resample the monitoring well(s) in question to determine the validity of the data, and submit the results no later than sixty (60) days after the date of the resampling event.
c) If a statistically significant change indicates that further assessment is warranted, as outlined in section a) of this permit condition, or an exceedance of a standard or the detection of an attachment I parameter with no standard above background concentrations is--
confirmed, the Permittee shall, November 1, 1993 Page 4 of 8
- i) Submit to the Department within ninety (go) days of verification of possible groundwater impact, a plan prepared by a qualified groundwater professional, to conduct a groundwater quality assessment.
eii) Within ninety (90) days of approval of the assessment plan, initiate the first phase of the plan; submit a preliminary report identifying the source, migration rate, extent, and severity of the contaminant plume; and. submit a plan for any additional assessment work required.
.iii) Upon completion of the approved groundwater quality assessment, submit a report which details the findings of the groundwater quality assessment and makes recommendations toward further assessment and\or corrective action.
.5) CORRECTIVE ACTION Upon completion of the groundwater quality assessment and verification of groundwater contamination, the Permittee must submit a corrective action plan to address groundwater quality.
.a) The Permittee must submit a plan for corrective action based on the findings of the groundwater quality assessment.
eb) The Permittee must implement the corrective action plan within 90 days of approval by the Department.
Additionally, the Permittee must establish and implement a groundwater monitoring program to demonstrate the effectiveness of the corrective action program.
.c) The Permittee must continue corrective action measures to the extent necessary to ensure that the groundwater standards are not exceeded for a period of at least three consecutive years.
id) The Permittee must submit semi-annually to the Department a report which discusses the effectiveness of the corrective action program.
.e) If the Permittee or the SCDHEC determines that the corrective action program no longer satisfies- the requirements of permit condition 5, the Permittee shall within 90 days of that determination submit a proposal to make appropriate changes to the program.
November 1, 1993 Page 5 of 8 I
- 6) REPORTING
- a) The Permittee shall analyze groundwater samples for the constituents in Attachment I and submit these groundwater data on a semi-annual basis in accordance with the following schedule:
Sampling Period Submittal Due Date October-December groundwater data January 15 April-June annual report with-- July 15 groundwater data s.b) The Permittee shall submit an annual report signed by a qualified groundwater professional summarizing the semi-annual determinations of groundwater flow direction and rate as required by permit condition 3b. The annual report shall be submitted in accordance with the submittal schedule presented in Permit condition- 6a. The annual report shall also include the groundwater monitoring data for both semi-annual monitoring events from the previous year and the semi-annual statistical analysis that has been performed on these data. In addition, the report shall make a determination as to whether the monitoring well network continues to meet requirements of Permit Condition 1.
C) The established background values and the data collected by the implementation of the groundwater monitoring program as specified by this Permit shall be submitted to the SCDHEC, Bureau of Solid and Hazardous Waste Management, Division of Hydrogeology, Solid Waste Section and to the Regional Hydrologist in the Catawba District Environmental Quality Control Office in Lancaster S.C..
November 1, 1993 Page 6 of 8 I
C. Closure/Post Closure Care Permit Conditions
- 1. The Permittee is responsible for submitting a closure plan within ninety (90) days of reissuance of this permit, which outlines the activities necessary to close the landfill in a manner that minimizes the release of contaminants.
Final cover must be applied during the closure period to any surface which represents the final grade of the landfill. Testing of the in-place compacted clayey cover material is required and a South Carolina Professional Engineer must.certify that the required permeability has been achieved. The type of vegetation selected to be placed on the closed out areas needs to be documented for its erosion control properties. Final cover shall be placed over,-any completed section of the fill within one hundred eighty (180) days following the final placement of solid waste within that portion.
- 2. The Permittee is responsible for submitting a detailed Post Closure Care Plan, within ninety (90) days of reissuance of this permit, which outlines the activities necessary to maintain a properly closed out landfill. Post Closure Cdre; shall be conducted for a period of thirty (30) years unless a variance is applied for and obtained by the Permittee.
The Permittee is responsible for inspecting and maintaining an adequate cap, gas monitoring and drainage system for the Post Closure Care Period. This plan shall provide a schedule indicating ,when the cap, gas monitoring and drainage system will be inspected, a discussion about how each will be inspected, and a contingency plan that discusses what action will be taken if failure occurs at any one system.
- 3. The Permittee is responsible for submitting a detailed Post Closure Care Plan within ninety (90) days of reissuance of this permit, which outlines the activities to be performed to ensure that an adequate groundwater monitoring system is in place at the time of closure for post closure monitoring of the waste management area. Post Closure Care shall be conducted for a period of thirty (30) years unless a variance is applied for and obtained by the Permittee.
The Permittee is responsible, for inspecting and maintaining an adequate groundwater monitoring system for the Post Closure Care Period. This plan needs to describe in detail the activities to be performed to..
ensure that an adequate groundwater monitoring system is November 1, 1993 Page 7 of 8
I-in place at the time of closure for post-closure monitoring of the waste management area. This plan shall specify the wells to be monitored, and the parameters to be monitored.
D. Special Permit Conditions
- 1. The future renewal of this permit will be contingent upon the receipt of updated analysis on all appropriate waste streams.
If any change occurs in any of Duke. Power's waste generating processes within the duration of this permit, Duke Power Company must notify the Catawba EQC District Solid Waste manager Immediately.
- 2. Duke Power Company is granted approval to receive asbestos-containing waste materials, and shall comply with the requirements of National Emissions Standards for Hazardous Air Pollutants (NESHAP), 40 CFR 61.154; AND no waste containing or contaminated by friable asbestos materials shall be accepted for disposal without prior written approval of the Bureau of Air Quality Control, Department of Health and Environmental Control, 2600 Bull Street, Columbia, SC 29201.
- 3. Approval must be granted by the Department's Division of Radioactive Waste management for the disposal of any low level radioactive waste.
- 4. A minimum buffer zone of five (5) feet must be maintained between the seasonal high water table and/or bedrock and any waste considered radiologically contaminated.
- 5. Duke Power Company is responsible for routine maintenance of the drainage ditch if the buildup of siltation or debris deposits has occurred, i.e. yearly.
- 6. sludges listed in General Permit Condition 2 must pass the Paint Filter Liquids Test prior to disposal in the landfill.
- 7. Spill clean-up materials listed in General Permit Condition two (2) must be contained, neutralized and solidified prior to disposal in separate areas of the landfill.
November 1, 1993 .
Page 8 of 8
I-ATTACHMENT 1 Frequencv Parameter Semi-Annually .pH (field & lab) std.units;
-specific conductance (field umhos/cm);
xtotal organic carbon mg/i;
-water level tenth/feet; chloride mg/l;
- sulfate mg/l;
-total nitrate (N) mg/i; Gamma Spectroscopy.
tritium /
Annually .arsenic ug/i;
- barium ug/l;
-cadmium ug/l;
-chromium ug/l;
-lead ug/l;
-mercury ug/l;
- selenium ug/l;
.silver ug/l I
Duke Energy Corporation Catawba Nuclear Station NPDES Permit Renewal Sludge Disposal At A Landfill - Sludge Disposal Report B Attachment 3 TCLP Results For Conventional Wastewater Treatment System Catawba Nuclear Station NPDES Permit SC0004278 Sludge Report B 12/1/2004 - Attachment 3 I
1; 1 4;6 IV y -
GENERAL ENGINEERING LABORATORIES Lbwc&r CatUtcatfow row C5 Afeeting tozJad 's needls weithit vision for toniorrow.
STATIE GEL EPI FL E*715GE7294 E97472=745S NC 233 SC 10120 105t2 TN 02934
- .rnyr A nr", dY1; A XT A r YCITC1 VA 0015t Client: Duke Power 1339.Hlagers Ferry Road Huntersville, Nordi Carolina 28078
Contact:
Ms. Penny Frankin cc:DUPO00191 ReportDatc: September29,1995 Page lof 3 Sample ID :34714 Lab ID :9509269-01 Matrix : TCLP Date Collected : 09/12/95 Date Received : 09/14195 Priority : Routine Collector : Client Parameter Qualifier Result Units Method Analyst Date Time Batch vYilstnle nr*nnlcs TCLP Volatile Conzpounds -11 items 1,1-Dichloroethylene < a).0700 mg/l EPA 8240 RMIB 09(20,95 1656 72924 1,2-Dichloroethane < a).0500 mg/l EPA 8240 1.4-Dichlorobenzne < 0.750 mgll EPA 8240 2-Butanone < 20.0 mg/l EPA 8240 Benzene < ).0500 mg/l EPA 8240 CarbonTetrachloride < C).0500 mgAl EPA 8240 Chlorobenzene < 10.0 mg/l EPA 8240 Chloroforn < 0.600 mg/l EPA 8240 Tetradiloroethylene < C).0700 mgll EPA 8240 Trichloroethylene < C).0500 mg/I EPA 8240 Vinyl chloride < ).0200 mg/l EPA 8240 Extractable Organics TCLP Add Co*~wunds -5 ites 2,4,5-Trichlorophenol < 40.0 mg/l EPA 8270 {NM 09/21195 1123 72874 2,4,6-Trichlorophenol < 0.200 mgE EPA 8270 Pentachlorophenol < 10.0 mg/ EPA 8270 Mp-Cresol < 20.0 mg/I EPA 8270 o-Cresol < 20.0 mg/1 EPA 8270 TCLP BiselNeutralCompowtds - 6 items 2,4-Dinitrotoluene < 0.130 mgA EPA 8270 l1exachlorobenzene < 0.130 mg/ EPA 8270 Wexachlorobutadiene < 0.100 mg/ EPA 8270
- 1exachloroethane < 0300 mgn EPA 8270 Nitrobenzene < 0.200 mg/I EPA 8270 Pytidine < 0.500 mg/l EPA 8270 TCLP Iferbcides -2 itdnis 2,4,5-TI 0.100 mg/l EPA 8150 modified, JU 09(25,95 1353 72903 2,4-D < 1.00 mg/l EPA 8150 modified TCLP Pesticides- 6 items PO Box 30712 -Ciarleston. SC 29417 (803) 556-8171
- Fax (803) 766-1178 *9509269.01*
! ,i t.i.q.l-l¢.tolge
- s-
.C1t2-t GENERAL ENGINEERING LABORATORIES Afeetittg todav-s ieeds wihlz a v'isioinfor tolinorrowt: LsboIWty CIIcWaar STAIE GEL Ef I:L Et/7156i/294 E&7472/745S NC 233 SC 10120 1052 TN 02934 CERTIFICATE OF ANALYSIS VA tbl, 00151 non-Q Clicnt Duke Power 1339 H1agers Pcrry Road Ilutersville, North Carolina 28078 Contac Ms. Penny Franklin cc: DUPO00191 ReportDatc: September29.1995 Page 2of3 Sample ID :34714 Parameter Qualifier Result . Units Method Analyst Date Time Batch Cilordane 0.0125 mgtl EPA 8080 MAA 091221)5 0914 72902 Endrin 0.00300 mg/I EPA 8080 MAA 09o22/95 0914 72902 Heptachlor & Ilep. Epoxide 0.000800 mg/l EPA 8080 Mcthoxyclior 1.00 mg/i EPA 8080 Toxaphene 0.0500 mg/l EPA 8080 gaamma-BHC 0.0400 mgll EPA 8080 Metals Analysis Silver 0500 mg/I EPA 6010A ISS . 09/21J95 1323 72926 Arscnic 0.500 mg/l EPA 6010A Barium 10.0 MZg EPA 6010A Cadmium 0.100 mg/l EPA 6010A Ciromium 0o500 mg/i EPA 6010A Lead 0.500 mg/l EPA 6010A Selenium 0300 mg/l EPA 6010A Mercury 0.0200 mgll EPA7471 BBJ 09/22/95 1129 72921 The following prep procedures were performed:
GCIMS Acid Compounds EPA 3500s3520 MBB 09119195 2300 72874 GC/MS Base/Ncutrsl Compounds EPA3500s3520 MBB 0919,95 2300 72874 Herbicides EPA8150 hIM 09(20*95 1545 72903 Pesticides EPA 350013520 J11M 09/20,95 1540 72902 ICP EPA 3005 FGD 092N,95 1800 72926 Mercury EPA 7470 KILM 09f20595 1600 72921 TCLP Extraction - Senivolatiles EPA 1311 JL 0911895 2045 72772 TCLP Extraction - Volafiles EPA 1311 nL 09/18,95 2230 72773 TCLP Prep for Metals EPA 1311 IL 09/18/95 2045 72774 P 0 Box 30712 , Charleston. SC 29417 - (803) 556-8171
- Fax (803) 766-1178*9509269o01
- _ 41* %z5 t¢v
t -.
GENERAL ENGINEERING LABORATORIES EAWCorSOiy Cerallr n Meeting todays Iteeds ivith a visionfor tontorrow.
rATE GL EDi n ES7156IS7294 ES7472174S5 ro ovI" sH{C 233
- 10120 10512
- 11q( 02934 CERTIFICATE OF ANALYSIS VA 00151 Clicnt: Duke Power 1339 lIlagers Ferry Road iuntcrsvllle, North Carolina 28078 Contactr Ms. Penny Frakln cc: DUPO0191 Report Date: Septembcr29.1995 Page 3 of 3 SamplecD :34714 rarameter Qualifier Result . Units Method Analyst Date Time Batch This data report has been prepared and reviewed in accordance with General Engineering Laboratories standard operating procedures. Please direct any qucstio, to your Project Managr4ob 9(1 556-8171.
P0 Box 30712 tCharklston. SC 29417 *(803) 556-8171 *Fax (803) 766-117R*95s926901*
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CHAIN OF CU! STODY RECORD Form 35226 (R6-9V' ;
OUKE POWER COMPANY Laboratory Services I XND' MNS Bldg. # 7405 (MG03A1) 13339 Ha ers Ferrv Road A REEQUEST FORM
- 04 ; I Huntersvie NC 28078 LS CLIENT 6ONTACT/PHONE':
CLIENPt: WI)Lb(, 4>Lul< Irn rS~
krrJ\L &MIT94)
ANALYSES REQUESTED by bottle type-MUST NOTE PRESERVATIVE'"
Project Name': Wr w .A Po -uzS S-r-rtw PoitaW Results to/Phone': ry4i,15
-;LFit 9n -S5 3 ,4 4 r g (may note special DL or Method)"
Address and/or PROFS': LAW (J4n5 D Qth. Y6tt yb* .c Matrix (type of samples)/QC Level': I z Iq5 SAM No.: .3 '31 I T I - -
Collected using Sample Description sampling Instructions ,U L 9J FRAC Number or .
.7 I ID'° Date TIme Name I.!
)' = D4-7q Tribl lPolAvt 4 1-l/2/f J^ oct!1h~i_<
Sample Preserved 0 Yes 0No, Total# of samples":
Name: _____I__-_ __=
Delivered by"4: Delivered by: Delivered by: - Tunaround Reques Date/Time: Date/Time: te/Tme: 0 Routing (3weeks)
_ _ _ __ _q__ ) /-0 'Rush (2 weeks)
Received by: Received by: ARceived by: n O Emergency Rush J Li0 Date Results Requested Comments":
- See Inst. .ions on back of form.
11%A1*k1& - -v .- I C =Ioo DinL O _ C.-klnt C(nnv
Duke Energy Corporation Catawba Nuclear Station NPDES Permit Renewal Sludge Disposal At A Landfill - Sludge Disposal Report B Attachment 4 TCLP Results For Sanitary Waste Treatment System Catawba Nuclear Station NPDES Pennit SC0004278 Sludge Report B 12/1/2004 AttachnientA4
! I
TO: WILLIE DA'VIS & GARY SAIN STATION: CATAWBA NUCLEAR SThTION\I
SUBJECT:
WT CELLS "A" &"B" SLUnGE CHEM. SCI.#: 9107120 PL.-EASE FIND ATTACHED. ANtALYSIS RESULTS FOR SAMLES SUBMITTED TO CHEMICAL SCIENCES. IF YOU HAVE Ar'-Y QUESTIONS, PLEASE CONTACT ME OR VIOLA 'f-.T BURLESON 875-544F OPR 975-5206. PLEASE REf-ERENCE CI'f1. SCi. t WHEN, 7OJ UIR I IG ABOUT PESULTS.
D1ENNIS 'J. HAIRSTON BY VIOLA BJURLESON Q.s
' W- ... ' .
I I
I IfA2'ARltU! W.ASI I SAnIIP r. LSIJL TS APPL I ED 3C I ENCE CEINTrR STATION CATAWBA NUCLEAR STATION SAMPLE I.D.: lT CELL "A" SLUDGE - 1'3641C CHM. SCI. V: 9107120--02 NOTE: Adjusted Results have been corrected by the fol]low'ing equation:
ADJUSTED RESULT = Result (from instrumrint)
Matrix Spil:e Recove-ry 100 %
ANALYSIS I RESULT lADJUSTED RESULT I LIMIT I AG: I <0.05 mg/I I 0.11 mg/] I 5.C. inc*.
I 1A: 1 0.50 m/1 I C0.50 mg/I 1 100 rlc./ I CD: 0.02 rig / I 1 0.02 mg/, I ' .I ;m. /
CR: I <0.05 mg./I 1 0.05 mg/I 1 5.0 mgJI I PE: I <0., I I I 0. 1 1 rgo/I I 5.C m -1 I AS: I 0:.0033: mg I 0.0056 mm/1 I 5.') ma/i !
- SE: ! .O1 mg/I 1 0.0173 mG.I I . n i ANlALYSIS I RES 1T I LIMIT HG: I 0.011i g/I I °.2 rg/
- ASI: I N!R 1.' NO IMI T I BTU: i I'lR p BTU'bl NO LIMIT T.5 . I T: :*.; E I f. i
-.* : ,! trt rt I
IiAARDOUS WASTIE SAMPLE R[:3ULTS APPLIED SCIENCE CFNTER STATION CATAWBA NUCLEAR STATION SAMPLE I.D.: WT CELL "B" SLUDGE - $436409 CHM. SCI. 4: 9107120-01 NOTE: Adjusted Results have been corrected by the following equation:
ADJUSTED RESULT Result (from instrumenst)
Matrix Spil:e Recov.rery 1 C00 *,/
ANALYSIS I RESULT IADJUSTED RESULT I LIMIT AG: 1 <0.05 mg/I I 0.11 maI/ 1 5.0 m.a I BA: I 1.25 mg/l 1 1.25 mg/I I 100 mg/I I CD: I 0.01 pla/l I 0.01 mg / I I 1.0 mQ/1 CR: I <0.05 mg/l 1 0.05 ma/l 1 5.0 mgfI I PD: I <0.1 mg/i I 0.11 ma/l 1 5.Q mg'I I AS: 1 0.0033 ma/l I 0C.0053 mg.' I 5.0 m.' ' I SE: ' 0.01 mg/i 1 0.0173 ma2. 1 ; .Q :1 ANALYSIS i RESULT i LIMIT
- I <0 .0 1 mg I 1 0.2 ma/i' I ASH: I N/R *' I tN0 ' IIMT STU: N/R STU/lb( NO 1LIMIT TOT. r :O NO LIITr LT.
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DUKE POWER COMPANY CHAIN OF CUSTODY RECORD Form 35226 (R2-91) 'J Production Envrtal Servis Appldbd Science Center (MG03A)
AND 1t3I HZro Fe"r Road Huntersv NC 28078 ANALYSIS REQUEST FORM `
PES CUEN CONTACT/GROUP/PHONE.: bi ^ /.S. 5 Il ANALYSES REQUESTEI ) by bottle type-MUST NOTE PRESERVATIVE 12 (mayynote special DL or Method)13
'CUENTP. A.,)
4.:: 4 Prject Nanme: CoQ " &AI ROSultsto/Phote4: 0;1;S Qv., I (o v G;irs Address and/or PROFS5: -
Matrix (type of sawnpes)/QC Level SLU &C P1:
Date results requested": -
SAM No. CHEMPLT *Sample Description Collection" with Number or dash' 9 ID' 0 Date ITlme Name
_eeie by Reeie by __= Reeie__by:
Preservation by: Teotal# of sames'6: __
Delivered y$ Delivwed bi. Delivered by: Delivered by: Delivered by:
DateTme: 1131wAA Date/Timne Date/Time: Date/Time: Date/Time:
Received by: Received by Comments": C Vtc, 1 !5,;-,^145 +o pt.-S9tf _. TC.4-P M 9TA LSn pH ,'%; W+;/
VeAd%-, L'-146 - -- 7CrLp- o0R'J4:scC- (Vok4t5e d-SVQHiui <) P4se+ d;.s 7$e/Hrtbtc;4e i I
- See Instructions on back of form.
White: canary, pink - PES files. Goldenrod - Returned to Client after signatures. /0 /o%7CLp Lztm-r5 FoiR c7,qT(5
SEMIVOLATILE METHOD TCLP REPORTED (BIAS CORRECTED) RESULTS DATE SAMPLED :07/10/91 DATE RECEIVED :07/13/91
- TCLP STARTED :07/15/91 (TCLP ROTATION STARTED)
DATE EXTRACTED:07/18/91 DATE ANALYZED :07/20/91 COMPUCHEM SAMPLE # 431356 - MS # 431357 CLIENT I.D. # 910 712801 MSD# 431368 FILE NAME :GH031356A07 DILUTION FACTOR 5*
COMPUCHEM DIL-ADJ COMPUCHEM REGULATORY COMPOUND REPORTING CC REPORT REPORTING LEVEL AMOUNT LIMITS LIMITS (MG/L) (MG/L) (MG/L) (MG/L)
PYRIDINE BRL 0. 050 2.5 6.0 1,4-DICHLOROBENZENE BRL 0.050 3.75 7.5 2-METHYLPHENOL (O-CRESOL) 8RL 0.050 100. 200.
3-METHYLPHENOL (M-CRESOL) x BRL 0.050 100. 200.
4-METHYLPHENOL (P-CRESOL) x BRL 0. 050 100. 200.
HEXACHLOROETHANE BRL 0.050 1.5 ,.0 NITROBENZENE BRL 0. 050 1.00 2.0 HEXACHLOROBUTADOIENE BRL 0.050 0.25 0.5 2,4,6-TRICHLOROPHENOL BRL 0.050 1.0 2.0 2 ,4,5-TRICHLOROPHENOL BRL 0.050 200. 400.
2,4-DINITROTOLUENE BRL 0. 050 0.065 0.13 HEXACHLOROBENZENE BRL 0.050 0.065 0.13 PENTACHLOROPHENOL GRL 0.250 50.00 100.
TOTAL CRESOLS BRL 0.050 100. 200.
- = Refer to CompuChem's 'Plan and Policies".
X = Indistinguishable Isoriers BRL = Below Reporting Limits DIL-ADJ CC REPORT LIMITS=Dilution-Adjusted CompuChem Reporting Limits
= Method Detection Limits X Dilution Factor I I
SEMIVOLATILE METHOD TCLP REPORTED (BIAS CORRECTED) RESULTS DATE SAMPLED :07/10/91 DATE RECEIVED :07/13/91 TCLP STARTED :07/15/91 (TCLP ROTATION .STARTED)
DATE EXTRACTED:07/18/91 DATE ANALYZED :07/20/91 COMPUCHEM SAMPLE ' 431361 MS X 431357 CLIENT I.O. # 910712802 MSD# 431358 FILE NAME : GH031361A07 DILUTION FACTOR : 5
- COMPUCHEM DIL-ADJ COMPUCHEM REGULATORY COMPOUND REPORTING CC REPORT REPORTING LEVEL AMOUNT LIMITS LIMITS (MG/L) (MG/L) (tMG/L) (MG/L)
PYRIDINE BRL 0. 050 2.5 5.0 1,4-DICHLOROBENZEWE BRL 0.050 3.75 7.5 2-METHYLPHENOL (O-CRESOL) BRL 0. 050 100. 200.
3-METHYLPHENOL (M-CRESOL) x 8RL 0. 050 100. 200.
4-METHYLPHENOL (P-CRESOL) X BRL 0.058 100. 200.
HEXACHLOROETHANE BRL 0. 50 I .5 3.0 NITROPENZENE 8RL 0.850 1.00 2.0 HEXACHLOROBUTADIENE BRL 0. 050 0.25 0.5 2,4,6-TRICHLOROPHENOL BRL 0.Q50 1.0 2.0 2.4,5-TRICHLOROPHENOL BRL 0. 50 200. 400.
2,4-DINITROTOLUENE BRL 0.050 0.065 0. 13 HEXACHLOROBENZENE BRL 0.050 0.065 0.13 PENTACHLOROPHENOL BRL 0.250 5s. 00 100.
TOTAL CRESOLS BRL -0.050 100. 200.
- = Refer to CompuChem's 'Plan and Policies".
X = Indistinguishable Isoners BRL = Below Reporting Limits
-OIL-ADJ CC REPORT LIMITS=Dilution-Adjusted CompuChem Reporting Limits
= Method Detection Limits X Dilution Factor I
VOLATILE METHOD TCLP ZHE REPORTED ;EiA- CORRECTED) RESLULTS DATE fiMFPLED :'7/I0.9I 5ATE RECEIVED :7/13/91 DA-E TCLP/-HE :7/ 16,91 (TCLP ROTATION STAR.TED)
DATE ANALYZED :7f/1/91 COMPIJCHEM SAMPLE # 431I34 MS# 431345 CLIENT I.O. 910.12B01 MSD# 431346 SAMPLE FILE NAME : CN031 34aA03 DILUTION FACTOR : 5 4 COMP UCHEM OIL-ADJ COMPUCHEM REGULATORY COMPOUND REPORTING3 CC REPORT REPORTING LEVEL AMOUNT LIMITS LIMITS (M6/L) (M6/L) {MG/L) (MG/-L)
VINYL CHLORIDE 8RL 0.050 0. 10 I 1-DICHLOROETHENE BRL 0.025 0.35 0. 7 2-BUTANONE BRL 0. 050 100. 200.
CHLOR FOPR BRL 0.025 3.00 6.00 CARBON TETRACHLORIDE BRL 0.025 0.25 0.50 BENZ ENE BRL 0.025 0.25 0. S0 1 ,2-DICHLOROETHANE BRL 0.025 0 .2 5 0.RE TRICHLOROETHENE BRL 0.025 0. 25 0.50 TETRACHLOROETHENE BRL 0..025 0.35 0.70 CHLOROB ENZENE PRL 0.025 50.0 100.
BRL = Below Reporting Limits
= Refer to CompuCherm's "Plen and Policies .
DIL-fiOJ CC REPORT LIMITS-Dilution-Adjusted CompuChem Reporting Limit5
= Method Detection Limits X Dilution Factor I
VOLATILE METHOD TCLP / ZHE REPORTED tBIAS CORRECTED' RESULTS DATE SAMPLED : 7.0I9.1g DATE RECEIVED :7/1 /SI DATE TCLP/7HE :. 16/91 *TCLP RPTATION 3TAPTED) -
DATE ANALYZED :7.1'1 19I COMPUCHEM SAMPLE t 431354 MS# 431345 CLIENT I.D. 4 910712802 MSDt 431346 SAMPLE FILE NAME : CN0317 A5403 DILUTION FACTOR : 5. 4 COMP UCHEM DIL-ADJ COMPUCHEM REGULATORY
' COMPOUND REPORTI QG CC REPORT REPORTING LEVEL AMOUNT LIMITS LIMITS (MG/L) (M5/L) (MG/L) (M5/L)
VINYL CHLORIDE eRL 0. 050 0..10 0.20 IJl-DICHLOROETHENE BRL 0.02S 0.35 0.70 2-BUTANONE BRL 0. 050 100. 200.
CHLOROFORM BRL 0.025 3.00 CARBON TETRACHLORIDE BRL 0.025 0.25 0.50 BENZ ENE 6RL- 0.025 0.25 0.50 1,2-DICHLOROETHANE BRL- 0.025 0.Z5 0.50 TRICHLOROETHENE BRL 0.025 0.25 0.50 TETRACHLOROETHEN4E 6RL 0.025 0.35 0.70 CHLOROBENZEENE BRL 0.025 50.0 100.
ERL = Below Reporting Linits
- - Refer to CompuChem's 'Plan end Policies".
OIL-ADJ CC REPORT LIMITS-Dilution-Adjusted ConpuChem Reporting Limits
= Method Detection L:mits ;". Dilution Factor I
PESTICIDE METHOD TCLP REPORTED (BIAS CORRECTED) RESULTS DATE SAMPLED 07/10/91 DATE RECEIVED 07/13/91 DATE LEACHED 07/15/91 (TCLP ROTATION STARTED)
DATE EXTRACTED: 07/18/91 DATE ANALYZED : 07/19/91 COMPUCHEM SAMPLE # 431363 .MS# 431364 CLIENT I. D. 4 910712801 MSD# 431365 COMPUCHEM COMPUCHEM REGULATORY COMPOUND REPORTING REPORTING LEVEL AMOUNT LIMIT (MG/L) (MG/L) (MG/L)
HEPTACHLOR BRL 0.004 0.008 HEPTACHLOR EPOXIDE BRL 0.004 0.008 TOXAPHENE BRL 0.250 0.500 GAMMA-BHC (LINDANE) BRL 0.200 0.400 CHLORDANE BRL 0.015 0.030 ENDRIN 0 BRL 0.010 0.020 P,P'-METHOXYCHLOR
- BRL 5.000 10.00 BRL = Below Reporting Limits i = Not Spiked in Associated MS and MSD
= Average % Recovery of Heptachlor Is Used to Adjust the Results I
PESTICIDE METHOD TCLP REPORTED (BIAS CORRECTED) RESULTS DATE SAMPLED : 7/10/91 DATE.RECEIVED : 7/13/91 DATE LEACHED : 7/15/91 (TCLP ROTATION STARTED)
DATE EXTRACTED: 7/18/91 DATE ANALYZED : 7/19/91 COMPUCHEM SAMPLE I 431368 HSI 431364 CLIENT I. D. I 910712802 MSDI 431365 COMPUCHEM COMPUCHEM REGULATORY COMPOUND REPORTING REPORTING LEVEL AMOUNT LIMIT (MG/L) -(MG/L) 4 (MG/L)
HEPTACHLOR BRL 0.004 0.008 HEPTACHLOR EPOXIDE BRL 0.004 0.008 TOXAPHENE BRL 0.250 0.500 GAMMA-BHC (LINDANE) BRL 0.200 0.400 CHLORDANE
- BRL 0.015 0.030 ENDRIN
- BRL 0.010 0.020 P,P'-METHOXYCHLOR
- BRL 5.000 10.00 BRL = Below Reporting Limits
- = Not Spiked in Associated MS and MSD
= Average % Recovery of Heptachlor Is Used to Adjust the Resulf 5 I7, Jl
HEFRBICIDE METHOD TCLP PEPORTED !EIAiS CCORRECTED; RESULTS DATE SAMPLED :07,10;9i C.ATE RECEIVED :07113in1 DATE LEACHED :07;15;S; (TCLF ROTATION STARTEDX oATE EXTRACTED:072J2/91 DA TE ANALYZED :07/;4/91 COMPUCHEM SAMFLE ;F 431370 no4 431371 CLIENT I.O. #q10712801 MEDv 431372 COMPUJCHEM COMFUCHEM REGULATORY COMPOUND R.EPORT ING REPORTING LEVEL AMOLUNT LIMIT (MG.LL) (MGiL' (MG/L)
,- _ -GPL. 5.00 10.0 2, ,S-TP 'G-TLVEkJN) BRL e. we 1 .00 GFL = Sel1:u Peporting Limits I
- HERBICIDE METHOD TCLP REPORTED (BIAS CORRECTED) RESULTS -
GATE SAMPLED :07::0:91 DATE RECEIVED :07 :3'1i91 DATE LEACHED :07115/91 (TCLP ROTATION SThRTED;!
DATE EYTRACTED:07/2,:Sl SATE hN.LY7ED :07/24/91 COMPUCHEM -. AMPLE I 431375 MS# 431371 CLIENT I.D. 4910712S02
- MSDI 431372 COMPUCHEM OIOMPUCHEM REGULATORY COMPOUNJD REPORTING REPORTING LEVEL AMOUNT LIMIT tMG/L) (MG/L) (MG/L)
^,.-3 2.L 5.00 10.0
_,4,5-TF vSILV'EX) ERL 0.50 1.00 ERL = Below Repcrting Limitss
INORGANIC CASE
SUMMARY
NARRATIVE CASE # 50012 SDG # 235879 CONTRACT # 788 The indicated Sample Delivery Group (SDG) consisting of two (2) soil samples was received on July 13, 1991, intact and in good condition, but without Chain of Custody (COC) Records. The samples were analyzed, in accordance with EPA CLP Statement of Work (SOW) 7/88, for cyanide only.
The following customer IDs are associated with this SDG: 910712801, 910712802 All calibration verification solutions (ICV & CCV) and blanks (ICB, CCB) associated with this data were confirmed to be within EPA CLP allowable limits.
The sample preparation procedure verifications (LCSS & PBS) were found to be within acceptable ranges. The sample preparation phase of analysis was initiated within the contract required holding times. Due to catastrophic instrument failure, the instrumental phase of the analysis could not be completed until several days later. This event should have no impact upon the usability or validity of the data associated with these samples due to the fact that the distilled samples are quite stable in the absorber tube solution and do not degrade readily. This incident is also described in the enclosed Laboratory Notice.
The sample matrix spike, CCN 431396 (910712801S) was found-to be outside CLP control limits for the requested analyte. The reported concentrations for the analyte are flagged with an "N" on all associated Form 1 and on Form Sa.
An "N" indicates a matrix-related interference in the sample preparation procedure &/or analysis for the flagged analyte. This is normally the consequence of a relatively high anionic interference content in the sample or (for some sediments) an inconsistent sample matrix relative to that analyte.
CLP control limits for matrix spike recoveries are set at 75% to 125% of the analyte quantity added unless original sample concentrations exceed the true values of these "spikes" by a factor of four or more; in this case effected analytes are not flagged even if recoveries fall outside percentage recovery control limits.
A post-distillation spike for cyanide analysis is required if unsatisfactory recoveries are observed for matrix spike samples. The result of this spike are presented on Form-Sb.
Satisfactory recovery of an analyte in a post-preparation spike of this type implies interference by the required preparation procedure or in the sample matrix itself. Lack of uniformity for an analyte in sediments will also result in satisfactory recovery of post-digestion spikes after failure in the related matrix spike.
The sample matrix duplicate, CCN - 431398 (910712801D) was inside control limits for the requested analyte.
'CLP control limits for duplicate determinations are +/- 20% Relative Pe~rcent Difference (RPD) for-concentrations greater than or equal to five times the CRDL in both the original and duplicate samples, and +/- the CRDL for concentrations less than five times the CRDL. The RPD is not calculated if both the original and duplicate values fall below the IDL.
Release of the data contained in this hard copy data package has been authorized by the laboratory Manager or his designee, as verified by- the following signature.
/g~er Hrick norg' c Division Manager August 28, 1991 Note: This report is paginated for reference and accountability.
I
I LABORATORY NOTICE In accordance with the USEPA 7/88 Statement of Work '
(SOW) analytical samples must be anal-yzed for cyanide within a 12 day holding time. The preparation phase of the analysis was completed within this time frame. But due-to an instrument problem that required service and parts, the instrumental phase of the analysis could not be completed until later. All other analytical and QC samples are in I control. Therefore, the data is being reported with reference to this qualifying notice.
Bryce M. Holmes Chemist II Inorganics 07-24-1991 QA Approval #2635 Janet G. Livingston QA Specialist III
.S I INORGqNI6 CRSE 235S7.9- L .. _ - ,
U.S. EPA - CLP CLIENT SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET I I j* 910712801 I Lab Name: COMPUCHEM-LABOEATORIES Contract: 788 .I I Lab Code: COMPU Case No.: 50012 SAS No.: SDG No.: 235879 Matrix (soil/water): SOIL Lab Sample ID: 431395 Level (low/med): LOW Date Received: 07/13/91
% Solids: 10.0 Concentration Units (ug/L or mg/kg dry weight): MG/KG I..I I *1- I-ICAS No. I Analyte IConcentrationiCI Q IM 7429-90-5 Aluminum HNR 7440-_6-0 Antimony - NR 744-38-Z Arsenic _ _ NR 7440-39-3 Barium _ NR 7440-41-7 Beryllium _ NR.
7440 Cadmium _ _HR 7440-70-2 Calcium _ _HR 7440-47-3 Chromium _ _NR 7440-48-4 Cobalt = NR 7440-50-8 Copper _ NR 7 89 Iron _ _NR 7439-92-1 Lead _ _ _ NR 7439-95-4 Magnesium _ NR 7439-96-5 Manganese = NR 7439-97-6 Mercury _ NR
-7RTWf02-0 Nickel _NR 7440-09-7 Potassium _ NR 778Z-49-2 Selenium _NR 7440-22-4 Silver _ NR 7440-23-5 Sodium __ NR_;
7440-8-0 Thallium _ NR 7440-62-Z Vanadium _ NR 7440-66-6 Zinc _ NR .
_Cyanide 5.0 U N AS Color Before: BLACK Clarity Before: Texture: FINE Color After: COLORLESS Clarity After: Artifacts:
Comments:
FORM 1.04 - PAGE 1 FORM I - IN 7/88 I INiORGPNIC CPSE 2 35 97
U.S. EPA - CLP CLIENT SAMPLE NO.
INORGANIC ANALYSIS DATA SHEET I 910712802 1 Lab Name: COMPUCHEM LABORATORIES Contract: 788-I . I Lab Code: COMPU Case No.: 50012 SAS No.: SDG No.: 235879 Matrix (soil/water): SOIL Lab Sample ID: 431402 Level (low/med): LOW Date Received: 07/13/91
% Solids:. 15.0 Concentration Units (ug/L or mg/kg dry weight): MG/KG CAS No. I Analyte IConcentrationlCI Q jM I 7429-90-5 lAluminum l NRl 7440-36-0 Antimony __N 7440-38-Z Arsenic NRR 7440 Barium _ NR 74T40-1-7 Beryllium_ NR .
7440_43-9 Cadmium NRR 7440- Calcium NR 7440-47-3 Chromium NR 74 Cobalt _NR 7440-50-8 Copper _ NR
. iron _ NR 7439-92-1 Lead NR__HR 7439-95-4 Magnesium . _ HR 749 Manganese = NR 97-6 MercurY= NR 7440-_02-0 Nickel NR 7440-09-7 Potassium __. NR
- 77Z-49-2 Selenium HNR 7440-22-4 Silver _ NR 7440-23-5 Sodium . _ HR 7440-Z8-0 Talium = NR 7440-6Z-2 Vanadium I NR 7440-66-6 z-n _
Cyanide 3.3 U N AS Color Before: BLACK Clarity Before: Texture: FINE.
Color After: COLORLESS Clarity After: Artifacts:
Comments:
FORM 1.04 - PAGE 2 FORM I -IN 7/88 IHNORGfNIC CPSE 25.5879 ,,-
1 :