ML993630306: Difference between revisions

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{{Adams
#REDIRECT [[PLA-5142, Susquehanna Steam Electric Station NRC Notification of NPDES Permit Renewal Application]]
| number = ML993630306
| issue date = 12/21/1999
| title = Susquehanna Steam Electric Station NRC Notification of NPDES Permit Renewal Application
| author name = Byram R G
| author affiliation = PP&L, Inc
| addressee name =
| addressee affiliation = NRC/OCIO/IMD/RMB
| docket = 05000387, 05000388
| license number = NPF-014, NPF-022
| contact person =
| case reference number = -RFPFR, PLA-5142
| document type = Letter
| page count = 395
}}
 
=Text=
{{#Wiki_filter:Robert G. Byram Senior Vice President Generation and Chief Nuclear Officer Tel. 610.774.7502 Fax 610.774.5019 E-mail: rgbyram@papl.com PP&L, Inc. Two North Ninth Street Allentown, PA 18101-1179 Tel. 610.774.5151 http://www.ýol-inc.com/
\ I i j PP'.>T 41, ) ,1111, T IAt DEC 2 1 1999 U. S. Nuclear Regulatory Commission Attn.: Document Control Center Mail Station OP 1-17 Washington, D. C. 20555 SUSQUEHANNA STEAM ELECTRIC STATION NRC NOTIFICATION OF NPDES PERMIT RENEWAL APPLICATION PLA-51 42 Docket Nos. 50-387 and 50-388 The purpose of this letter is to submit the Susquehanna Steam Electric Station NPDES permit renewal application to the NRC in accordance with Section 3.2 of the Environmental Protection Plan. Please contact Mr. R. D. Kichline at (610) 774-7705, if there are any questions concerning the renewal application.
Sincerely, Attachment cc: NRC Region I Mr. S. L. Hansell, NRC Sr. Resident Inspector, SSES Mr. V. Nerses, NRC Sr. Project Manager ?D( A .cC- o ooC)53'/PLA-5142 SUSQUEHANNA STEAM ELECTRIC STATION NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) RENEWAL PERMIT APPLICATION PERMIT NO. PA 0047325 PP&L, INC. DECEMBER 6,1999 Jerome S. Fields IL a A; Sr. Environmental Scientist
-Nuclear p PP&L, Inc. Two North Ninth Street Allentown, PA 18101-1179 TM Tel. 610.774.7889 Fax 610.774.7205 jsfields@papl.com December 6, 1999 Mr. Paul M. Swerdon Chief Permits Section Water Management Program Pennsylvania Department of Environmental Protection 2 Public Square Wilkes-Barre, PA 18711-0790 SUSQUEHANNA STEAM ELECTRIC STATION APPLICATION-NPDES RENEWAL PERMIT PA-0047325 CCN 741326 FILE R9-8A PLE-21639
 
==Dear Mr. Swerdon:==
PP&L, Inc. is submitting a NPDES renewal permit application for the Susquehanna Steam Electric Station (SES), Salem Township, Luzeme County, PA. The present NPDES permit no. PA-0047325 expires on June 21, 2000. Included for Pennsylvania Department of Environmental Protection review are; 1) three copies of the application (one notarized), 2) an application fee of $500.00, payable to the Commonwealth of Pennsylvania, and 3) copies of letters with certified mail receipts notifying Salem Township and Luzeme County of this renewal permit application.
If you have any questions please call me at (610) 774-7889.
Sincerely, 'Jerome S. Fields, REM Sr. Environmental Scientist
-Nuclear Enclosure 99140.doc(lmc)
Jerome S. Fields I Sr. Environmental Scientist
-Nuclear ' t & PP&L, Inc. _V__ Two North Ninth Street .MR-Allentown, PA 18101-1179 m ,L Tel. 610.774.7889 Fax 610.774.7205 I U jsfields@papl.com ma September 3, 1999 Mr. Eugene Klein, Chief Clerk Luzeme County Courthouse 200 North River Street Wilkes-Barre, PA 18711 SUSQUEHANNA STEAM ELECTRIC STATION NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT RENEWAL: PA 0047325 CCN 741326 FILE R9-8A PLE- 21516
 
==Dear Mr. Klein:==
In accordance with Act No. 14, P.L. 834, this letter is to notify you that PP&L, Inc. will submit a renewal National Pollutant Discharge Elimination System Permit application during the fourth quarter of 1999 to the Pennsylvania Department of Environmental Protection for the Susquehanna Steam Electric Station (SES). The Susquehanna SES is a two-unit nuclear station with a generating capacity of 1,150 megawatts per unit, located in Salem Township, Luzeme County, Pennsylvania.
If you have any questions concerning this permit renewal application, please call me. Sincerely
// Senior Environmental Scientist-Nuclear Certified Mail No. Z 232 731 657 Copy to: Ms. I. Hopkins, EPA Region III Mr. P. M. Swerdon, PaDEP Jerome S. Fields Sr. Environmental Scientist
-Nuclear PP&L, Inc. Two North Ninth Street Allentown, PA 18101-1179 Tel. 610.774.7889 Fax 610.774.7205 jsfields@papl.com September 3, 1999 Ms. Judith Boudman Secretary, Salem Township Salem Township Municipal Building 400 Luzerne Avenue Berwick, PA 18603 SUSQUEHANNA STEAM ELECTRIC STATION NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT RENEWAL: PA 0047325 CCN 741326 FILE R9-8A PLE- 21517
 
==Dear Ms. Boudman:==
In accordance with Act No. 14, P.L. 834, this letter is to notify you that PP&L, Inc. will submit a renewal National Pollutant Discharge Elimination System Permit application during the fourth quarter of 1999 to the Pennsylvania Department of Environmental Protection for the Susquehanna Steam Electric Station (SES). The Susquehanna SES is a two-unit nuclear station with a generating capacity of 1, 150 megawatts per unit, located in Salem Township, Luzerne County, Pennsylvania.
If you have any questions concerning this permit renewal application, please call me. Sincerely, ,J.rome S. Fields Senior Environmental Scientist-Nuclear Certified Mail No. Z 232 731 656 Copy to: Ms. I. Hopkins, EPA Region III Mr. P. M. Swerdon, PaDEP C SSENDER: I also wish to receive the follow" o c Complete items I and/or 2 for additional services.
ing services (for an extra fee): C Complete iems 3, 4a, and 4b. o Print your name and address on the reverse of this form so that we can return this .card to you. I. PAddressees Address 0". 0 Attach this form to the front of the masipiecs, or on the back if space does not "W permit.  .= 0 Write 'Retum Receipt Requested'on the mailpeec below the article number. 0 The Returnecept will show to whom the article was delvered and the date O delivered.
""_ ___ 3. Article Addressed to: 4a. Article Number & P-s. 2.32. I.3 E- 4b. Service Type It..-- S ' Registered R:,Certified ,- '.. /. , 0 Express Mail E Insured / 0 Return Receipt for Merchandise El COD 5Received By. Name) B. Addressee's Address (Only if requested and M ~J3ýJ fee is paid) 5 6. .Siqrature (Afidress~,~
Aget) PS t6rm 381 1S,6ecember 1994 102595-99-8-0223 Domestic Retum Receipt SENDER: nConmplete items 1 and/or 2 for additlonal services.
I also wish to receive the i ,CompleteArs 3,4a, and 4b. following services (for an Ia Print your narme and address on the reverse of ttiss form slo that we can return this extra fee): card to you.  *Aftach tis form to the front of the mallpiece, or on the back it space does not 1.A Addressee's Address pernt. Write'Retum Receipt Requested'on the mallpiece below the article number. 2. 3 Restricted Delivery The Return Receipt wil s~how to whom the article was delivered and the date delivered.
Consult postmaster for fee. -_ 3. Article Addressed to: 4a. Article Number Mr ~ ki~ ~ i I~r -. Z Z3Z r-731 (.-4b. Service Type 0 Exrs al0IsrdRegistered S~ Certified " " -" 9 ...I 0 Express Mail [3 Insured -S S.0 Retum ReceiptforMrlmhand5
[ 0 C0OD 7 7aU IP ?,t " S ,,, " Addressee's Address (Ony frequesed and fee is paid) 6. Signature: (Addressee or Agent) , F -..381, De. mbr1.4 02-,97-,079 Domstcetun ecip C=.  £o 3 U Ps Form 3811, December 1994 10259.597-B-179 Domestic Retum Receipt U 3. E nfl a.÷I 0130-PM-DPCO001 Rev 10/30/1998 FORM COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION PERMIT APPLICATION
-- GENERAL INFORMATION Before completing this form, read the step-by-step instructions provided in this Permit Application Package. This version of the General Information Form (GIF) must be completed and returned with any program-specific application.
SECTION A. PROJECT INFORMATION Project Name SUSQUEHANNA STEAM ELECTRIC STATION Project Description The Susquehanna Steam Electric Stations consists of two boiling water reactors, each with a net electrical generating capacity of approximately 1,150 megawatts.
The station owned by PP&L, Inc. (90%) and Allegheny Electric Cooperative Inc. (10%) is located on a 1,700 acre site in Salem Township, Luzeme County. Water is withdrawn from both the Susquehanna River and ground water for cooling, domestic, and station uses. PP&L, Inc. operates this station.
Time Schedules Project Milestone (Optional)
NA Will your project involve the disturbance of any primary agricultural lands? If "yes", indicate the alternatives to this disturbance considered and the reasons they were not deemed feasible.
Z No Alternative Considered Reason Not Feasible 0 Yes 1. 2. 3. Will your project require any Commonwealth funds or Commonwealth-administered federal funds? If "yes", indicate the type, amount, and source of these funds. Z No Type Amount Source F- Yes 1. $ 2. $ 3. $ Page 5 W Printed on Recycled Paper 0130-PM-DPCOOOI Rev 10/30/1998 SECTION B. APPLICANT INFORMATION DEP Client ID# Applicant Type / Code PACOR Corporation/PA Organization Name or Registered Fictitious Name Employer ID# (EIN) Dun & Bradstreet ID# PP&L, Inc. 23-0959590 00-790-9427 Individual Last Name First Name MI Suffix SSN Additional Individual Last Name First Name MI Suffix SSN Mailing Address Line 1 Mailing Address Line 2 PP&L, Inc. 2 N. 9th Street (GENA93) Address Last Line -City State ZIP+4 Country Allentown PA 18101-1179 USA Applicant Contact Last Name First Name MI Suffix Phone Ext Fields Jerome S (610)774-7889 Applicant Contact Title Email FAX Sr. Env. Scientist-Nuclear jsfields@papl.com (610)774-7205 SECTION C. SITE INFORMATION Estimated Number of Applicant Employees to be Present at Site [] 1-4 E] 5-9 [] 10-19 20-49 0 50-99 Ej 100-249 250-499 E 500+ DEP Site ID# Site Name Susquehanna Steam Electric Station Site Location Line I Site Location Line 2 Salem Township, Luzeme County Site Location Last Line -City State ZIP+4 EPA ID# Berwick PA 18603-0467 PAD 000765883 Detailed Written Directions to Site Five miles north of Berwick, PA on US Route 11 or four miles south of Shickshinny, PA on US Route 11. Description of Site Two unit nuclear generating station County Name Municipality City Boro Twp State Luzerne Salem [] E] Z PA County Name Municipality City Boro Twp State El El Dl Site Contact Last Name First Name MI Suffix Phone Ext Castleberry Gary W (570)542-3970 Site Contact Title FAX Effluents Management-Supervisor (570)542-1857 Site Contact Firm Email PP&L, Inc. gwcastleberry@papl.com Mailing Address Line 1 Mailing Address Line 2 Susquehanna SES P.O. Box 467 Mailing Address Last Line -City State ZIP+4 Berwick PA 18603-0467 Applicant to Site Relationship If "Other" -Explain OWNOP Owner/Operator SIC Codes (Two-Digit Codes -List All That Apply) (Optional:
4-Digit Code) 49 4911 P Printed on Recycled Paper Page 6 0130-PM-DPCOOOI Rev 10/30/1998 SECTION D. PERMIT COORDINATION ANSWER DEP QUESTION Use Yes No Additional Information Due to "Yes" Response 1.1 Will the project involve construction activity that El Z Total Disturbed Acreage: 4x66 disturbs five or more acres of land? If "Yes", specify total disturbed acreage.
Note: If more than 10 acres are disturbed, it is the applicant's responsibility to also notify the PA Historical and Museum Commission, PO Box 1026, Harrisburg, PA 17108-1026, Telephone (717) 787-3362.
1.2 Is a stormwater collection and discharge system EL Z 4x66 proposed for this project? 1.3 Will any work associated with this project take E] Z Stream: 4x66 place within 50 feet of a stream, waterway, or Waterway:
wetland; or is located in a FEMA delineated Wetland: floodway?
If "Yes", identify the stream, waterway, or wetland.
1.4 Does the project involve dredging or construction Z [ Li Dredging 4x66 of any structure or placement of fill that Li Bridge or Culvert Construction encroaches on a stream, floodplain, or wetland? If Li Pier Construction "Yes", check the appropriate item(s). Li Outfall Pipe Construction E] Other: 2.1 Will the project involve discharge of industrial E] Z (Discuss in Section A, Project Description.)
4x62 wastewater or stormwater to a dry swale, surface water, ground water or an existing sanitary sewer system or storm water system? If "Yes", discuss in Project Description.
2.2 Will the project involve the construction and El Z 4x62 operation of industrial waste treatment facilities?
2.3 Will the project involve construction of sewage E] Z Est Prop Flow (gal/day):
4x62 treatment facilities, sanitary sewers, or sewage pumping stations?
If "Yes", indicate estimated (Discuss in Section A, Project Description.)
proposed flow (gal/day).
Also, discuss the sanitary sewer pipe sizes and the number of pumping stations/treatment facilities/
name of downstream sewage facilities in the Project Description, where applicable.
3.1 Will land be subdivided for this project? El Z_ 4x61 3.2 Will the proposed generate sewage? L] Z Est Flow (gal/day):
4x61 If "Yes", indicate estimated flow (gal/day).
Persons Served: If "Yes", indicate number of persons to be served. Treated by: Li On-Site Soils System If "Yes", attach Act 537 approval letter. L] On-Site Treatment Plant If "Yes", sewage will be treated by (check L] Conveyed to Off-Site Trmt Pit appropriate item/box).
3.3 If sewage planning was submitted and approved, Proj Name/Code:
4x61 indicate project name or code. 4.1 Does the project involve construction of a dam? If ZII Dam: 3140 "Yes", identify the dam. 4.2 Will the project interfere with the flow from, or ] Z Dam: 3140 otherwise impact, a dam? If "Yes", identify the dam.P Printed on Recycled Paper Page 7 0130-PM-DPCOOOI Rev 10/30/1998 SECTION D. PERMIT COORDINATTON (eontinuepd)
ANSWER DEP QUESTION Use Yes No Additional Information Due to "Yes" Response_
5.1 Will the project involve operations, excluding
[ Type Amount 4x71 during the construction period, that produce air emissions (i.e., NOX, VOC, etc.)? If "Yes", identify the type and amounts of emissions.
6.1 Is an on-site drinking water supply (well), other Z [ Persons Served: 4x81 than individual house wells, proposed for your Emp/Guests:
project? If "Yes", indicate total number of people Connections:
served and/or the total number of connections Sub-Facilities:
served, if applicable.
And check all proposed sub- n Distribution Sys E] Source facilities.
E] Entry Point F] Storage Fac E] Water Trmt Pit [ Pump Sta [:] Transmission Main 6.2 If purchasing your water in bulk, excluding during Z [ Provider:
4x81 the construction period, name the provider.
Also, Emp/Guests:
indicate the daily number of employes or guests served. 6.3 If to be served by public water supply, indicate El [ Supplier:
4x81 name of supplier and attach letter from supplier stating that it will serve the project.
6.4 Will this project involve a new or increased Stream: 4x81 drinking water withdrawal from a stream or other water body? If "Yes", provide name of stream. 7.1 Will the construction or operation of this project El Type Amount Means 4x32 involve treatment, storage, reuse, or disposal of El Treated waste? If "Yes", indicate what type, (i.e., El Stored hazardous, municipal, residual, infectious
& Fl Reused chemotherapeutic) and how much. What are the [ Disposed proposed means of treatment, storage, reuse and disposal?
8.1 Will your project involve the removal of coal, E] E 48yl minerals, etc. as part of any earth disturbance activities?
9.1 Will your project involve operations within Zl API#: 4z41 200 feet of an oil or gas well? If "Yes", indicate Oil and Gas AiPI#. 10.1 Does your project involve installation of any of the 3930 following?
If "Yes", list Substance
& Capacity; may need a Storage Tank Site Specific Installation Permit. Substance
"* A field constructed underground storage tank? 11 Z "* An aboveground storage tank greater than Fl Z 21,000 gallons capacity?
"* A tank greater than 1,100 gallons which will El Z contain a highly hazardous substance?
"* A storage tank at a new facility?
El __P Printed on Recycled Paper Page 8 0130-PM-DPCO001 Rev 10/3011998 SECTION E. FACILITY INFORMATION Application Type [] New 0 Renewal [] Modification F1 Transfer [ Other Modification of Existing Facility Yes No 1. Will this project modify an existing facility, system, or activity?
[] E 2. Will this project involve an addition to an existing facility, system, or activity?
[] ED If "Yes" check all relevant facility types and provide DEP facility identification numbers below. FACILITY TYPE DEP FAC ID# FACILITY TYPE DEP FAC ID# F1 Air Emission Source [] Public Water Supply System L1 Hazardous Waste Facility F_1 Water Resource (withdrawal point) E) Municipal or Residential Waste Facility F_1 Oil & Gas Location El Mining Operation O_ oil & Gas Location / Coal Pillars _ _ Dam_[] Radiation Protection Facility [] Water Obstruction or Encroachment
[] Other [] Water Pollution Control Facility [:] Other Latitude DEG 41 MIN 5 SEC 30 Lniue DG 76 MIN 8 S 45 S: ~SECITON F. ' CONSUTANT FOR Last Name First Name Nu Suffix Title Consulting Firm Mailing Address Line 1 Mailing Address Line 2 Address Last Line -City State ZIP+4 Country Email Phone Ext FAX SECTION G., CERTIFICATION I certify that I have the authority to submit this Permit Application on behalf of the applicant named herein and that the information provided in this Application is true and correct to the best of my knowledge and information.
Signature Date Type or Print Name Robert F. Saunders, VP -Nuclear Site Operations Page 9 V Printed on Recycled Paper 0130-PM-DPCO001 Rev 1013011998 CBEC:als COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION PERMIT APPLICATION
-GENERAL INFORMATION
....... .................................
ECKIST Please check the following list to make sure that you have included all the required information.
Place a checkmark next to each item completed and/or provided.
Failure to provide all of the requested information will delay the processing of the application and may result in the application being placed on hold with no action, or will be considered withdrawn and the application file closed.  ...... ...........
a C ec k / Ilcu d [] 1. ATTACHMENTS.
The completion of the GIF may require the submission of some or all of the following.
Where appropriate, include the appropriate attachment(s) with the completed GIF. El a) Section A -Additional information attached -Lengthy Project Description El b) Section A -Additional information attached -Lengthy Time Schedules
[] c) Section C -Copy attached -7.5 Minute Topographic Map (with drawn outline of site) El d) Section C -Additional information attached -Lengthy Detailed Written Directions to Site El e) Section D, Question 3.2 -Copy attached -Act 537 Approval Letter El f) Section D, Question 6.3 -Copy attached -Public Water Supplier's Agreement Letter to Serve the Project El 2. CONTACTS MADE. According to information provided in Section D. Permit Coordination, the appropriate Regional/District Office has been contacted.
El a) Question Series 1 -If Yes -Local County Conservation District Office or Regional Soils & Waterways Section El b) Question Series 2 -If Yes -Regional Water Quality Permitting Section El c) Question Series 3 -If Yes -Regional Water Quality Planning Section E] d) Question Series 4 -If Yes -Central Office Dam Safety Division El e) Question Series 5 -If Yes -Regional Air Quality Program El f) Question Series 6 -If Yes -Regional Water Supply Section and Community Health Office El g) Question Series 7 -If Yes -Regional Waste Management Program El h) Question Series 8 -If Yes -District Mining Permitting Section E i) Question Series 9 -If Yes -Regional Oil & Gas Program El j) Question Series 10 -if Yes -Division of Storage Tanks, Central Office El 3. BEFORE YOU DIG -CONTACT. Pennsylvania One Call System at 1-800-242-1776. 
[] 4. APPLICATION MAILED. Permit application has been completed and properly signed according to instructions and type codes; and will be mailed to the appropriate DEP office. Page 1 C Printed on Recycled Paper LATITUDE 41 0 04'00"to41°06'00" LONGITUDE 760 11 15" to 760 06' 15" FIGURE 4-1 TOPOGRAPHIC MAP SUSQUEHANNA SES F ------ I i-ý t ------ I F ------ i 3600-PM-WQ0008 Rev 7197 COMMONWEALTH OF PENNSYLVANIA Project No. DEPARTMENT OF ENVIRONMENTAL RESOURCES WATER MANAGEMENT PROGRAM NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) Application for NPDES Permit New and Existing Industrial Dischargers SECTION A. APPLICANT IDENTIFIER Applicant Name PP&L, INC. 2 N. 9TH STREET ALLENTOWN, PA 18101-1179 SECTION B. GENERAL INFORMATION
: 1. SIC Codes Corresponding SIC Description 1st 4 9 1 1 ELECTRIC SERVICES 2nd 3rd 4th 2. General Description and Nature of Business Generation of electricity.
The Susquehanna Steam Electric Station is a nuclear power station with two Boiling Water Reactors with an electrical generating capacity of approximately 1,150 Mwe per reactor. 
: 3. List all NPDES and Part II Water Quality Management Permits presently held for this facility 1. NPDES permit no. PA 0047325, June 22, 1995 2. Water Quality permit no. 4085411, October 7, 1985 Water Quality permit no. 4076203, May 25, 1977 000001 0047325 NPDES Number PA 3600-PM-WQO0008 Rev 7197 SECTION B -(continued)
: 4. Attach Topographic Map. See instructions.
SEE FIGURES 4-1,4-2, AND 4-3 5. Outfall Location:
For each outfall, list the latitude and longitude of its location to the nearest second and the name of the receiving water. Where available, the receiving stream width and depth should also be provided using actual measurements or topographic map and navigational charts.Low Flow FINAL LATITUDE LONGITUDE RECEIVING WATER Stream OUTFALL NUMBER (Name) Ft. Ft.  (list) 1.DEG 2.MIN. 3.SEC. 1 DEG. 2MIN. 3.SEC. Width Depth. 070 41 5 15 76 8 45 Lake Took-a-while 160 3 071 41 5 30 76 8 45 Susquehanna River 1000 13 072 41 5 30 76 8 45 Lake Took-a-while 160 3 073 41 5 30 76 8 45 Lake Took-a-while 160 3 074 41 5 30 76 8 45 Lake Took-a-while 160 3 075 41 5 30 76 8 30 Lake Took-a-while 160 3 079 41 5 30 76 8 30 Susquehanna River 1000 10 080 41 "5 30 76 8 30 Lake Took-a-while 160 3 River Intake 41 5 15 76 8 00 071 at River 41 5 00 76 8 00 079 at River 41 5 15 76 8 00 6. Preparedness, Prevention, and Contingency (PPC) Planning Does the facility have a PPC plan which has been reviewed and approved by the Department?
LI Yes See note below E] No (attach 2 copies for review and approval)Date of Approval Does the facility have any other related plans, such as a Pollution Incident Prevention (PIP) Plan or a Spill Prevention Control and Counter Measure (SPCC) Plan? Included with Best Management Practices in PPC Plan.Z Yes E] No If yes, identify and indicate date(s) approved by the Department or EPA. PPC Plan was previously submitted to the PaDEP with the last NPDES permit renewal application on July 15, 1994 (letter PLE-1 7914). At this time it is being updated and 2 copies will be forwarded to the PaDEP by June 1, 2000.O00o00;-2-0047325 NPDES Number PA LATITUDE 41 0 04 00" to 410 06' 00" LONGITUDE 760 11' 15" to 76 06' 15" FIGURE 4-1 TOPOGRAPHIC MAP SUSQUEHANNA SES 000003 F i I
'12 1 MILE FIGURE 4-2 SPRINGS USED FOR WATER SUPPLY WITHI 1 MILE OF THE STATIO,, SUSQUEHANNA SES 000004 NOTE: NUMBERS INDICATE APPROXIMATE LOCATION OF WELLS SIMILE FIGURE 4-3 WATER WELLS WITHIN 1 MILE OF STATION SUSQUEHANNA SES 000005 SECTION B -(continued)
: 7. Line Drawing. See instructions Susquehanna River@ Chemical Addition Notes: Data averaged over years 1996, 1997 and 1998 were used to determine river water withdrawal, consumptive use, and blowdown back to the river. Outfalls 077 and 078 have not been included in this line drawing or permit renewal application since they do not discharge to the stormdrains. 000006 NPDES Number PA 0047325 3620-PM-WQ0008 Rev. 7197 0047325 3600.PM-WQOOO8 Rev 7197 NPDES Number PA SECTION B -(continued)
: 8. Site Plan and Stormwater Runoff -Use space below or an attachment.
See instructions.
Complete this part for outfalls discharging process, non-contact cooling or sanitary wastewater in combination with stormwater.
The Department strongly recommends the separation of stormwater and other wastewaters.
However, if this is impossible, complete this part. Section C must be completed for the other wastewater contribution.
Complete Section D for the stormwater contribution.
If the stormwater can be separated, complete Section D for the stormwater outfall, and Section C for any other wastewater outfalls.
See Figure 8-1 000007 NPDES Number PA 3600.PM-WQ0008 Rev 7/97 8-1 O MAJOR DRAINAGE AREAS AND FLOWPATHS SUSQUEHANNA SES G0 LIST OF CODES FOR FIGURE 8-1 SITE PLAN AND STORMWATER RUNOFF NORTH DRAINAGE AREA 2N -Discharge of Storm Drain near North Gatehouse Parking Lot 3N -Effluent from Peach Stand Pond (Outfall 075) 4N -Influent to Lake Took-a-while 5 -Effluent from Lake Took-a-while CENTRAL DRAINAGE AREA 1 C -Waste Accumulation Area 2C -Influent to C-1 Pond 3C -Effluent from C-1 Pond (Outfall 080) 4C -Influent to Lake Took-a-while 5 -Effluent from Lake Took-a-while SOUTH DRAINAGE AREA 1S -Acid and Chlorine Building (no longer stores acid or chlorine) 2S -Influent to S-2 Pond 3S -Effluent from S-2 Pond (Outfall 070) 4S -Influent to Lake Took-a-while 5 -Effluent from Lake Took-a-while codesS-1 .doc 00O009 3600-PM-WQO0008 Rev 7197 SECTION B -(continued)
: 9. New Source Determination Referring to the instructions for this question, indicate when "construction" (as defined by EPA) and discharge began for the facilities causing each discharge?
If "construction" has not begun, state when it will begin. Do not complete this table for outfalls which only discharge sanitary wastewater or stormwater runoff (unless considered "process wastewater" under an EPA effluent guideline regulation).
Date "Construction" Began* N/A Date "Discharge Began-Facilities Causing Discharge Outfall(s)
* If "construction" began on different dates for facilities which contribute to the same outfall, list these dates separately (use additional sheets if necessary). 
** If not yet discharging, indicate date on which discharge is expected to begin.-5-0047325 NPDES Number PA 3600-PM-WQO0008 Rev 7/97 SECTION C -DATA REQUIREMENTS FOR PROCESS, NCCW, AND SANITARY WASTEWATER DISCHARGES I. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES Treatment Treatment Method for Handling and Disposal Handling Outfall Treatment Unit Description Unit Code Unit Design of Solid or Liquid Residue and Number (list in sequence) (see Flow Rate Resulting from Treatment Disposal Table 1) 106 gal/day (list in sequence)
Code 070 4-A Discharge to Surface Water Sedimentation (settling)
Discharge to Surface Water Sedimentation (settling)
Disinfection (chlorine)
Dechlorination (other) (optional)
Disinfection (other) (optional)
Neutralization Diatomaceous Earth Filtration Ion Exchange Neutralization Evaporation (optional)
Microstraining Neutralization Sedimentation (settling)
Oil and Grease Removal Discharge to Surface Water via Storm Drains Oil and Grease Removal Discharge to Surface Rain dependent Rain dependent 20 20 1-U 4-A 1-U 2-F 2-E 2-H 2-K 1-C 2-J 2-K 1-F 1-N 2-K 1-U 4-H 4-A 4-H 4-A N/A N/A Landfill or Land Application N/A NIA N/A N/A Radioactive waste landfill Radioactive waste landfill N/A Radioactive waste landfill Radioactive waste landfill N/A Landfill or Land Application Recycle; Sale N/A Recycle; Sale N/A-6-4000011 071 171 (internal) 371 (internal) 571 (internal) 072 073 20 20 20 20 0.28 0.28 0.28 0.28 0.002 0.04 0.023 0.023 0.018 0.018 5-Q 5-P 5-Q 5-Q 5-Q 5-Q 5-Q 5-P 4-C; 4-E 4-C; 4-E.0047325 I v I NPDES Number PA N/A 3600-PM-WQ0008 Rev 7/97 SECTION C -DATA REQUIREMENTS FOR PROCESS, NCCW, AND SANITARY WASTEWATER DISCHARGES I. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES Treatment Treatment Method for Handling and Disposal Handling Outfall Treatment Unit Description Unit Code Unit Design of Solid or Liquid Residue and Number (list in sequence) (see Flow Rate Resulting from Treatment Disposal Table 1) 106 gallday (list in sequence)
Code 074 Oil & Grease Removal Discharge to Surface Water via Storm Drains Discharge to Surface Water via Storm Drains Sedimentation (settling)
Grinding (comminutors)
Screening Equalization Pre-aeration Activated Sludge Neutralization Disinfection (chlorine)
Dechlorination (other) Disinfection (other) Discharge to Surface Water Discharge to Surface Water Via Storm Drains Sedimentation (settling) 0.018 0.018 4-H 4-H 4-A 1-U 1-L 1-T 1-Y 3-E 3-A 2-K 2-F 2-E 2-H 4-A 4-A 1-U Recycle; sale N/A N/A N/A N/A Incineration; Landfill N/A N/A Belt filtration; Aerobic Digestion Incineration; Landfill N/A N/A N/A N/A N/A N/A N/A 5-0; 5-Q 5-C; 5-A 5-0; 5-Q 000012-6-Rain Dependent Rain Dependent 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 Rain Dependent Rain Dependent 075 .079 080__________
I 0047325 NPDES Number PA 4-C; 4-E ADDITIONAL INFORMATION FOR SECTION C-1 ADDITIONAL OUTFALL DESCRIPTIONS 070 -The S-2 Pond, located on the South side of the Susquehanna SES site, is a storm water runoff outfall (SWRO). This SWRO outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may also contain small amounts of chlorine, which will dissipate upon mixing with storm water in the pond, before the discharge reaches Lake Took-a-while.
Due to the similarity of this outfall and Outfalls 075 and 080, only Outfall 075 was sampled for this NPDES permit application.
In addition, options are being reviewed to dry Cooling Tower sediment onsite. Dried sediment may be used as a coproduct or for beneficial uses to control site erosion and/or support warm season grasses on PP&L lands in the vicinity of the Susquehanna SES. Runoff from the sediment may enter this or the SWROs, however, this additional runoff will be negligible compared to present site runoff volume. 071 -Cooling Tower Blowdown includes input from the Unit 1 and Unit 2 Cooling Towers, internal discharges, and Emergency Spray Pond (Spray Pond) overflow, and other miscellaneous water. The Cooling Towers and Spray Pond contain river water used for cooling station main condensers and heat exchangers.
Spray Pond discharge is based on pond level, and is dependent on make-up to the pond and rainfall.
Assuming an estimated Spray Pond discharge of 250 gpm (0.36 MGD) and an average two-unit Cooling Tower discharge of 7,639 gpm (1 1-MGD), then the pond discharge adds only an additional 3.27% to the station blowdown.
This amount however, is not captured in the blowdown flow recorders located upstream of the Spray Pond. Therefore, PP&L requests a daily Estimated Flow and not Recording Instrumentation for Outfall 071. We will continue to provide recorded readings from blowdown excluding the additional 250 gpm from the Spray Pond. Turbulence and river debris in the blowdown line downstream of the Spray Pond discharge have made flow recorders inoperable.
Evaporative losses in the Cooling Towers generally result in the cooling water being cycled 3 to 5 times the concentration of river water. Cooling Tower Basins each contain approximately 7 million gallons of water and the Spray Pond 25 million gallons.
In order to reduce fouling and corrosion in the Service Water and Circulating Water Systems, PP&L utilizes a chemical treatment program. Chemicals included in present and proposed treatment are listed in Section C, IV, "Information and Analysis of Effluent Quality for Other Potentially Toxic Pollutants" in this permit renewal application.
OOG-13 By definition closed cooling systems are not routinely discharged to the environment.
When maintenance is performed on these systems, batch discharges are directed to the Cooling Tower Basins (Outfall 071) or the Sewage Treatment Plant (Outfall 079). Treatment of Emergency Diesel Generator Jacket Cooling Water (DGJCW) for corrosion and biofouling control continues to be problematic.
Treatment chemicals used have included Isothiazolin, Glutaraldehyde, and a combination of Sodium Molybdate, Sodium Nitrite, and Methylbenzotriazole.
Therefore, PP&L is evaluating the use Sodium Chromate as a possible treatment options and is including it in this NPDES permit renewal application.
Leakage from DGJCW systems discharges to the Service and Administrative Building sump, Outfall 072. Target concentration of chromate in the DGJCW systems will be between 150 and 250 mg/l. Assuming a worst-case scenario, leakage of 10% from any of the systems A -D (71 gallons each) at any one time or from system E (150 gallons) into Outfall 072 (2-10,000 gallon sumps) the chromate concentration in the sump discharge should be between 1.8 and 3.75 mg/l. By definition closed cooling systems are not routinely discharged to the environment.
When maintenance is performed on these system, batch discharges can be treated or directed to the Cooling Tower basins (Outfall 071), Sewage Treatment Plant (Outfall 079), or other storm water outfall with PaDEP concurrence.
The following Table 1, Closed Cooling Systems lists station systems.
TABLE I CLOSED COOLING SYSTEMS SYSTEM SYSTEMS NO. OF SYSTEMS VOLUME (gal) Units 1 & 2 Reactor Building 2 4,300 Closed Cooling Water Units 1 & 2 Turbine Building 2 1,150 Closed Cooling Water Units 1 & 2 Common Gaseous 3 3,100 Radwaste Recombiner Closed Cooling Water Units 1 & 2 Reactor Building 2 4,750 Chilled Water Units 1 & 2 Turbine Building 2 6,200 000014 Chilled Water Control Structure Chilled Water 1 1,200 Radwaste Building 1 860 Chilled Water A-D Emergency Diesel 4 710 Generator Jacket Cooling Water E Emergency Diesel Generator 1 1,500 Jacket Cooling Water INTERNAL OUTFALLS 171 -Liquid Radwaste discharge includes leakage and wastewater from the radiologically controlled area and also potentially from other sources of water in the Condensate Storage Tank bermed areas (former Outfalls 077 & 078) and mop water from outside the radiologically controlled area. Prior to combining with Outfall 071, this wastewater is passed through various treatment processes to reduce the concentration of radioactive materials.
Approximately 90% of liquid radwaste are treated by one of two processes:
filtration followed by ion-exchange demineralization, or ion exchange demineralization followed by microstraining.
Less than 10% of liquid radwaste is from the laundry drainage system, which receives wastewater from equipment washdown stations and personnel decontamination facilities in the radiologically controlled area. PP&L-supplied clothing is sent to an outside contractor for cleaning.
Miscellaneous wastes discharged through this system also include service water leakage, mop water from cleaning, and leakage from various pumps and valves. This water passes through microstraining filters prior to sampling the discharge.
271 -Waste Filter Bypass was previously eliminated from this NPDES permit since it is no longer in operation.
371 -Neutralization Basin internal discharge includes inputs from the demineralizer rinse water and chemical waste inputs from Circulating Water Pumphouse Building equipment and floor drains. There are two basins each with a capacity of approximately 20,000 gallons. The basins are used alternately and the contents are air sparged, recirculated, and samples prior to being directed to the suction side of the circulating water pumps.O00015 471 -Waste Filter was previously eliminated from this NPDES permit because it is no longer in operation.
571 -Circulating Water Pumphouse Building sump receives leakage from the Circulating Water System that includes circulating water, seal water, and also equipment and floor drains. The three remaining internal outfalls 171, 371, and 571 discharge into the Susquehanna River through Outfall 071. 072 -The Service and Administration (S&A) Building Low Volume Waste Sump receives inputs from the diesel generator oil unloading areas and building floor drain sumps, the emergency start-up transformer bermed areas, and the S&A Building Oil Storage Room floor drains. The sump contains two cells, each with approximately 10,000-gallon capacity.
An oil and grease separator is'provided to remove any fuel or transformer fluid leakage. DGJCW leakage may enter this sump. If Sodium Chromate should be used as a corrosion inhibitor in this system some leakage into this sump may occur. It is estimated that the chromate concentration would be no greater than 3.75 mg/I. 073 -Unit 1 Turbine Building Low Volume Waste Sump collects storm water drainage from the transformer, turbine lube oil, and oil circuit breaker bermed areas. This sump has two cells of approximately 8,700 gallons each; however, discharges are usually about 8,100 gallons. The storm water collected in this sump passes through an oil and grease separator prior to discharge.
074 -Unit 2 Turbine Building Low Volume Waste sump is similar to Outfall 073, only this Outfall 074 collects storm water from the Unit 2 side of the site. Because of the similarity between these outfalls only Outfall 073 was sampled for this NPDES permit renewal application.
075 -The Peach Stand Pond is a SWRO through which runoff from the station facilities and North side of the site flow into this pond. This outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may contain small amounts of chlorine, which will dissipate upon mixing with storm water before entering Lake Took-a-while.
Discharge from this outfall goes into Lake Took-a-while located east of US Route 11. Because this outfall and Outfalls 070 and 080 are similar, only this outfall was sampled for this NPDES permit renewal application.
077 -Unit 1 Condensate Storage Tank bermed area stormwater is discharged through Outfall 071, Cooling Tower Blowdown.
Since there have been no discharges to the storm drains from this outfall, PP&L has decided not to include it in this NPDES permit renewal application.
000016 078 -Unit 2 Condensate Storage Tank bermed area runoff like Outfall 077 is discharged Outfall 071, therefore, PP&L has also decided not to include this stormwater outfall in this NPDES permit renewal application.
079 -The Sewage Treatment Plant (STP) is designed to treat 80,000 gallons per day of sanitary wastes from the collection system onsite and from pump stations at the Training Center, Riverlands Recreation Area, Environmental Lab, West Building, and Vehicle Maintenance Garage. Sanitary wastes may contain small amounts of cleaning agents, and other chemicals.
Material Safety Data Sheets for these chemicals recommend treatment at STPs prior to discharge (Susquehanna River). 080 -The C-1 Pond is a SWRO outfall located in the central drainage area just East of the station's protected area. This outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may contain small amounts of chlorine, which will dissipate upon mixing with storm water before entering Lake Took-a-while.
Since this outfall is similar to Outfall 070 and 075 it was not sampled. Sample data are provided from Outfall 075 in this application.
000017 3600-PM-WQO008 Rev 7/97 SECTION C -(continued)
I1. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 070 (S-2 Pond) 1. Process Wastewater
: a. Describe process and type of wastewater N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti y Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: __ hrs/day; __ day, During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; __ days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater:
N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quantity Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: __ hrs/day; __ day,, During which months? For continuous discharges report: The avera discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate/wk; __ days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 000018-7-0047325 NPDES Number PA SECTION C -(continued)
: 11. SOURCES OF WASTEWATER FOR OUTFALL 070 2. Other Wastewater Contributing to this Outfall (Description)
See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day; days/wk;days/yr;During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum d discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate 3. Total Process. Miscellaneous Non-Contact Coolinq, and Sanitary Wastewater
: a. Source(s):
Runoff from paved roads, roof drains.__ hrs/day; _ days/wk;days/yr;months/yr During which months? Rain dependent.
For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The Iona-term average discharge rate The maximum daily discharge rate-8-MGD MGD MGD 000019 months/yr MGD MGD MGD CYCLES/DAY MIN. GPM b. Discharge Occurs: 0047325 3600-PM-WQ0008 Rev 7197 NPDES Number PA 3600-PM-WQOOO8 Rev 7197 SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL (continued) 070 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
Drainage Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2 X 0.623 Gallons 4.7 X 5.55 x 10 5  Yd 2 X 5.61 = 1.46 x 10 7  Gallons X Acres X 27.152 Gallons II1. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application
[] YES Z NO 00002C-9-0047325 NPIDES Number PA SECTION C -(continued)
I1. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 071 1. Process Wastewater
: a. Describe process and type of wastewater:
: b. Applicable EPA Effluent Limitation Guideline:
40 CFR: 423 Category/Subcategory Steam Electric Power c. Maximum Monthly Production Rate: Quanti Units of Measure 1.65 x 10' mwh(net)Of Product (or raw material used) Electricity Month When Representative Production Occurs March 1998 Days/Month Production Occurs 31 d. Discharge Occurs: 24 hrs/day; 7 days/wk; 365 days/yr; During which months? For continuous discharges report: The averae discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate 12 months/yr 7.93 MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater~
N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day,, During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term averaae discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; I days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 100O;ZI-7-0047325 3600-PM-WQ0008 Rev 7/97 NPDES Number PA 3600-PM-WQO0008 Rev 7197 SECTION C -(continued)
SOURCES OF WASTEWATER FOR OUTFALL 071 Other Wastewater Contributing to this Outfall (Description) -See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day; days/wk; days/yr; months/yr During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate CYCLES/DAY MIN. GPM 3. Total Process. Miscellaneous Non-Contact Cooling. and Sanitary Wastewater Internal discharges:
Outfalls 171-Liquid Radwaste; 371-Neutralization Basis; 571-Circulating Water a. Source(s):
Pumphouse Bldg. Sump.b. Discharge Occurs: hrs/day;days/wk;days/yr;During which months? 12 For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: (1998) The long-term average discharge rate The maximum daily discharge rate N/A MGD 171 0.014 371 0.017 571 0.054 0.073 0.019 0.069 MGD MGD-8-000022 II. 2.MGD MGD MGD months/yr 0047325 NPDES Number PA 3600.PM-WQOOO8 Rev 7197 NPDES Number PA 0047325 SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL (continued) 071 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2 X 0.623 Gallons X Yd 2 X 5.61 Gallons 4.7 X 8 Acres X 27.152 = 1,021 Gallons (Emergency Spray Pond) III. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application
[] YES Z NO O00023-9-0047325 3600-PM-WQOOOB Rev 7t97 NPDES Number PA 3600-PM-WQO0008 Rev 7/97 NPDES Number PA SECTION C -(continued)
SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 072 Process Wastewater (Service and a. Describe process and type of wastewater:
N/A kdmin. Bldg. Low Volume Waste Sump)b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quantity Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day. During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk;" __ days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quantit Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ days/wk; _ days/yr; During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate_ _ months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 000024 7 I1. 1.0047325 SECTION C -(continued) 1I. SOURCES OF WASTEWATER FOR OUTFALL 072 2. Other Wastewater Contributing to this Out-fall (Description)
See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day;days/wk; days/yr;During which months? For continuous discharges report: The averae discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate MGD MGD MGD CYCLES/DAY MIN. GPM 3. Total Process. Miscellaneous Non-Contact Cooling, and Sanitary Wastewater
: a. Source(s):
: b. Discharge Occurs: 1 hrs/day;-days/wk;33 days/yr;12 monthslyr (1998)During which months?For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate N/A MGD 0.011 MGD 0.020 MGD 000025-8-months/yr 0047325 3600-PM-WQ0008 Rev 7/97 NPDES Number PA 3600-PM-WQO0008 Rev 7197 SECTION C -(continued)
I1. SOURCES OF WASTEWATER FOR OUTFALL (continued) 072 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
N/A Drainage Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2 X 0.623 = Gallons X Yd 2 X 5.61 = Gallons X Acres X 27.152 = Gallons III. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application D YES E NO-9-0047325 NPDES Number PA SECTION C -(continued)
SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 073 Process Wastewater (Unil a. Describe process and type of wastewater:
N/A t I Turbine Bldg. Low Volume Waste Sump)b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day,, During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; -days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quantity Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day, During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; I days/yr months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 0 0O&7 I1. 1.-7-0047325 3600-PM-WO0008 Rev 7197 NPDES Number PA 3600-PM-WQO0008 Rev 7/97 NPDES Number PA SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL 073 2. Other Wastewater Contributing to this Outfall (Description) -See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day;days/wk;___ .days/yr;During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate MGD MGD MGD CYCLES/DAY MIN. GPM 3. Total Process. Miscellaneous Non-Contact Cooling, and Sanitary Wastewater
: a. Source(s):
Miscellaneous wastewater
-transformer area and parking area runoff.b. Discharge Occurs: 1 hrs/day;-days/wk;18 days/yr;12 months/yr (1998)During which months? Can occur in all months; depejndent on parking lot area runoff.For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate N/A MGD 0.011 MGD 0.030 MGD O00o0- S months/yr-8-0047325 3600-PM-WQ0008 Rev 7197 SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL (continued) 073 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
NIA Drainaae Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2  X 0.623 Gallons X Yd 2 X 5.61 Gallons X Acres X 27.152 Gallons III. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application
[] YES Z NO"000029-9-0047325 NPDES Number PA 3600-PM-WQO0008 Rev 7197 SECTION C -(continued)
SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 074 Process Wastewater (Uni a. Describe process and type of wastewater N/A t 2 Turbine Bldg., Low Volume Waste Sump)b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day,, During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s[wk;_ days/yr,_ months/yr MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ days/wk; _ days/yr; During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 00003C Ii. 1.-7-0047325 NPDES Number PA SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL 074 2. Other Wastewater Contributina to this Outfall (Description)
See No. 3 below. a. Source(s):
NPDES Number PA b. Discharge Occurs: hrs/day;days/wk; days/yr;During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term averaae discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 3. Total Process. Miscellaneous Non-Contact Cooling, and Sanitary Wastewater
: a. Source(s):
Miscellaneous wastewater
-transformer area, parking area runoff.b. Discharge Occurs: 1 hrs/day;-days/wk;21 days/yr;12 months/yr (1998)During which months? Can occur in all months, dependent on parking area runoff For continuous discharges report: The averae discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The Iong-term average discharge rate The maximum daily discharge rate N/A MGD 0.013 MGD 0.024 MGD-8-0047325 3600-PM-WQOOOS Rev 7/97 3600-PM-WQOOO8 Rev 7197 SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL (continued) 074 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
N/A Drainage Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2 X 0.623 Gallons X Yd 2 X 5.61 = Gallons X Acres X 27.152 = Gallons III. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application E]YES Z NO 000032-9-0047325 NPDES Number PA 3600-PM-WQ0008 Rev 7197 SECTION C -(continued)
I1. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 075 1. Process Wastewater
: a. Describe process and type of wastewater:
N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: ' hrs/day; _ day.During which months? For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The Iona-term averaae discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; _ days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater:
N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day,, During which months? For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate swk; I days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 000033-7-0047325 NPDES Number PA 3600-PM-WQOOO8 Rev 7197 SECTION C -(continued)
SOURCES OF WASTEWATER FOR OUTFALL 075 Other Wastewater Contributing to this Outfall (Description)
See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day; days/wk;days/yr;During which months? For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate MGD MGD MGD For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate CYCLES/DAY MIN. GPM 3. Total Process, Miscellaneous Non-Contact Coolina. and Sanitary Wastewater
: a. Source(s):
Runoff from paved roads, roof drains; discharges from Outfalls 072, 073, and 074.b. Discharge Occurs: hrs/day;days/wk;days/yr;months/yr During which months? Rain dependent.
For continuous discharges report: The averaae discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate MGD MGD MGD-8-II. 2.months/yr 0000211 0047325 NPDES Number PA 3600-PM-WQOOO8 Rev 7197 SECTION C -(continued)
I1. SOURCES OF WASTEWATER FOR OUTFALL (continued) 075 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
Drainage Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2  X 0.623 Gallons 4.7 X 7.25 x 10 5  Yd 2 X 5.61 = 1.92 x 10 7  Gallons X Acres X 27.152 Gallons II1. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application
[] YES E NO 000035-9-0047325 NPDES Number PA 3600-PM-WQ0008 Rev 7197 SECTION C -(continued)
II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 079 1. Process Wastewater
: a. Describe process and type of wastewater N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: CategorylSubcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)(Sewage Treatment Plant)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: __ hrs/day; __ day. During which months? For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The lona-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; __ days/yr, months/yr MGD MGD MGD CYCLES/DAY MIN. GPM Process Wastewater
: a. Describe process and type of wastewater:
N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: .Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs hrs/day; __ days/wk; __ days/yr; __ months/yr During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate MGD MGD MGD CYCLES/DAY MIN. GPM 0100 03 G d. Discharge Occurs:-7-0047325 NPDES Number PA 3600-PM-WQO0008 Rev 7197 SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL 079 2. Other Wastewater Contributinq to this Outfall (Description)
See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day;days/wk; days/yr;During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate months/yr MGD MGD MGD For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate CYCLES/DAY MIN. GPM 3. Total Process. Miscellaneous Non-Contact Cooling, and Sanitary Wastewater
: a. Source(s):
Sanitary Wastes b. Discharge Occurs: 24 hrs/day; 7 days/wk; 365 days/yr 12 months/yr During which months? All months For continuous discharges report: The averag discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate 0.022 MGD* N/A MGD MGD*Average discharge rate from March 1998, month of highest electrical production in 1998.000037 0047325 NPDES Number PA 3600-PM-WQ0008 Rev 7/97 NPDES Number PA SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL (continued) 079 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other wastewaters.
N/A Drainage Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2 X 0.623 = Gallons X Yd 2 X 5.61 = Gallons X Acres X 27.152 = Gallons IIl. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application
[] YES Z NO 000038-9-0047325 SECTION C -(continued)
II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALL NUMBER 080 1. Process Wastewater
: a. Describe process and type of wastewater: (C-1 Pond)N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quantitv Units of Measure Of Product (or raw material used1 Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: -hrs/day; -days/wk; During which months? For continuous discharges report: The averao discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term averaoe discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate Process Wastewater
: a. Describe process and type of wastewater:
-days/yr;months/yr MGD MGD MGD CYCLES/DAY MIN. GPM N/A b. Applicable EPA Effluent Limitation Guideline:
40 CFR: Category/Subcategory
: c. Maximum Monthly Production Rate: Quanti Units of Measure Of Product (or raw material used)Month When Representative Production Occurs Days/Month Production Occurs d. Discharge Occurs: _ hrs/day; _ day= During which months? For continuous discharges report: The averae discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge rate s/wk; _ days/yr;000039-7-months/yr MGD MGD MGD CYCLES/DAY MIN. GPM 0047325-- 3600-PM-WQ0008 Rev 7/97 NPIDES Number PA 3600-PM-WQOOO8 Rev 7197 NPDES Number PA 0047325 SECTION C -(continued)
II. SOURCES OF WASTEWATER FOR OUTFALL 080 2. Other Wastewater Contributinq to this Outfall (Description)
See No. 3 below. a. Source(s):
: b. Discharge Occurs: hrs/day; days/wk;days/yr; months/yr During which months? For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate MGD MGD MGD For batch discharges report: No. of decant cycles Length of each decant cycle Average decant discharge flow rate CYCLES/DAY MIN. GPM 3. Total Process. Miscellaneous Non-Contact Cooling, and Sanitary Wastewater
: a. Source(s):
Runoff from paved roads, roof drains.hrs/day; _ days/wk; _ days/yr;months/yr During which months? Rain dependent.
For continuous discharges report: The average discharge rate associated with the month of maximum production.
For intermittent or seasonal discharges report: The long-term average discharge rate The maximum daily discharge rate-8-MGD MGD MGD 000040 b. Discharge Occurs: (Description)
See No. 3 below. a. Source(s):
0047325 3600-PM-WQ0008 Rev 7197 NPDES Number PA 3600-PM-WQO0008 Rev 7197 SECTION C- (continued)
II. SOURCES OF WASTEWATER FOR OUTFALL (continued) 080 4. Stormwater Runoff (Only if in combination with any of the above wastewaters.
If outfall consists of only stormwater, complete Section D) otherwise complete Section D for the stormwater contribution and Section C for contributions from other Wastewaters.
Drainage Area Conversion Rainfall (inches) Size Units Factor Volume Units X Ft 2 X 0.623 Gallons 4.7 X 1.6 x 10' Yd 2 X 5.61 = 4.2 x 10' Gallons X Acres X 27.152 Gallons III. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data Use the space below (attach additional sheets if necessary) to provide any of the optional site-specific information discussed in Appendix 2.  (The Analyses Results Table should be used to report intake water quality, upstream background or ambient water quality, and parameter specific coefficient of effluent variability.
Space is provided at the top of the table to provide description of sampling points used.)Optional Toxics Data is attached to Application
[] YES Z NO 000041-9-0047325 NPDES Number PA 3600-PM-WQOOO8 Rev 7197 NPDES Number PA 0047325 SECTION C -(continued)
Ill. REQUIRED AND OPTIONAL ANALYSES 2. Summary of Reauired Analyses Worksheet**** ALL DISCHARGERS SUBMIT THIS WORKSHEET WITH YOUR APPLICATION
....Discharge Contains (see Pollutants or Pollutant Required No. Outfall Instructions for Section C, Part 11) GW Storm- Groupings which must be of Sample Number Process Sanitary Misc. Cleanup water Sampled for and Analyzed Events Waste NCCW Waste Waste (see C.I11) Groups 1,2,3,4,5,7,8 Total Kjeldahl River Intake _ Nitrogen (TKN) 070 X See Note 1 071 X Groups 1,2,3,4,5,7,8, TKN 3 072 x 2C,3C,4C,5C,7C,12C,16C,5M, 072_ X 18M,23M 073 X 2C,3C,4C,5C,7C,12C,16C 1 074 X See Note 2 075 x 1 C,2C,4C,6C,7C,8C,9C,1 1C,1 2C, 1 075 X 14C,16C,18CTKN 1C,4C,6C,9C,11 C,12C,14C,17C, 079 X 18C,19C,6M,7M,1 3M,8V,1 1V,12V 080 X See Note 1 Notes: 1) Outfalls 070, 075 and 080 are similar 2) Outfalls 073 and 074 are similar * *.* SUBMIT THIS TABLE WITH YOUR APPLICATION
....3600-PM-WQOOO8 Rev 7197 0047325 NPDES Number PA-10-000042 REQUIRED AND OPTIONAL ANALYSES SECTION C. III -NOTES SAMPLING LOCATIONS
: 1. SUSQUEHANNA RIVER INTAKE 2. OUTFALL 071, COOLING TOWER BLOWDOWN 3. OUTFALL 072, SERVICE AND ADMINISTRATION BUILDING LOW VOLUME WASTE SUMP 4. OUTFALL 073, UNIT 1 TURBINE BUILDING LOW VOLUME SUMP 5. OUTFALL 075, PEACH STAND POND STORMWATER RUNOFF 6. OUTFALL 079, SEWAGE TREATMENT PLANT Note: Since Outfall Outfalls 077 and 078, Unit I and 2 Condensate Storage Tank Areas have never discharged stormwater to the storm drains and can not since the discharge pipes have been flanged shut, PP&L requests elimination of these two outfalls from the NPDES renewal permit.000043 SUSQUEHANNA RIVER INTAKE NOTES 1. Memo from Analytical Laboratory Services Inc. (ALSI) listing exceptions to detection limits. 2. ALSI Cyanide procedures (2) 3. Teledyne Brown Engineering Environmental Services radiological procedures (3) 4. Other Notes: 15C, Fluoride One sample analyzed by Standard Methods Ed. 18 -4500 and two samples analyzed by EPA method No. 300.0. 16C, Nitrate-Nitrite One sample analyzed by EPA method No. 353.2 and two samples by 300.0. 19C, Sulfate One sample analyzed by EPA Method No. 375.4 (detection limit 3,000 ug/I) and two samples by 300.0 (detection limit 500 ug/I). 21C, Sulfite EPA method No. 377.1 used for all three samples, however, one sample had a detection level of 4,000 ug/I while the other samples had a detection level of 2,000 ug/l. Reasons for higher detection levels for this parameter and some other NPDES analyses may be attributed to natural interference.
5M, Chromium (Hexavalent)
Even though the same analytical method was used (Standard Methods -3500D) three different detection levels were used. They were 20, 40, and 10 ug/l respectively.
8M, Mercury (Total) Detection level of one sample was 0.5 and the other two samples 0.2 ug/l. 15M, Phenols -(Total) Two had a detection level of 10 and one 5 ug/l. 16M, Aluminum (Total) One sample had a detection level of 150 and the other two 100 ug/l. 21M, Iron (Dissolved)
Two of the three samples had a detection level of 60 and the third 30 ug/l. 22M, Magnesium (Total) All three samples had a detection level of 50 ug/l. The magnesium concentrations were very high however, between 4,730 and 11,000 ug/l.000044 05/14/1399 1@:30 7179441430 ANALYTICAL LABS PAGE @2 Ana~I ~I~lyica-LaI~iboratory Memo fri Jerry Fields Frum Sue Baer Dew May 14, 1999 Re! NPDE$ Laboratory RepottS Following are the completed NPDES reports from the cooling tower blowdown (sample #129815).
river intake (sample #129811), and outfall 072(sample
#130621) locations.
Please note, the following ALSI reporting limits do not meet the recommended NPDES limits on these samples: Analysis ALSI Reporting Limit Analysis
* Acroelin 20 ugA Volafile Organics by GOiMS
* Mercury 0.5 ug0 Total Metals by ICP S AiJurninum 150 ugfl Total Metals by ICP 0 Magnesium 50 ug!A Total Metals by ICP a Zinc 10 ughI Total Metals by ICP 0 Dissolved Iron 60 ughl Dissolved Metals 9 Phenols 10 ugi. Phenol!
* Sulfate* 3000 ug/Il Sulfate a Cr+6 20 ug Hexavalent Chromium In some cases, this is no an issue if the sample result is above the reporting limit. Also, I will be forwarding you a copy of our standard operating procedure (SOP) for free cyanide.
Currently, this SOP is under revision and I thought I would wait and send you the most updated copy*Due to new instrumentation at the laboratory, the sulfate and mercury reporting limits will meet NPDES reporting limits for Me second and third samples.
* Page 1 000045 NOV 2 2 1999 Method: 09-CNDIS 1`, ;iR0,&3ENTAL SERVICI Revision:
3 Date: September 28, 1998 Page: 1 of 16 Document Title: Total Cyanide and Weak Dissociable Cyanide by MIDI DistillationDocument Control Number: Organization Title: Address: P16-o-: ANALYTICAL LABORATORY SERVICES, INC. (ALSI)34 Dogwood Lane Middletown, PA 17057 (717) 9-4--5541 Approved by: M. Magniess,'
Assurance Manager Dave Lane', Technical DirectorThis document is the properry of Anaiytical Laboratory Services.
Inc. ht may be used by she recipient only for she purposefor which it was transmitted.
It is submitted in confidence and its disclosure to you is sot intended to constitute public disclosure or authorization for disclosure to other parties. It may not be copied or communicated without the written consent of Analytical Laboratory Services.
Inc.UNiCONTROLLED COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 2 of 16 TABLE OF CONTENTS 1 Scope and Application
................................................................
3 2 Summ ary of M ethod .....................................................................
3 3 Interferences
.................................................................................
3 4 Safety ............................................................................................
4 5 Apparatus and M aterials ..............................................................
5 6 Reagents .......................................................................................
5 7 Glassware Cleaning .....................................................................
9 8 Quality Control ............................................................................
9 9 Sample Collection, Preservation and Handling ..........................
10 10 Procedure
..................................................................................
10 11 Calculations
................................................
14 12 Reporting Results .......................................................................
14 SOP Concurrence Form ..............................................................
16 This document is the propert ofAnalytical Laboratory Services.
Inc. It may be uted by the recipient only/or the purposejbr which it was transmitted.
It is submitted it: confidence and its disclosure to you is aot intended to constitute public disclosure or authorization for disclosure to other parties. It may not be copted or communicated without the written consent ofAnalyficnl.Laboratory Services.
Inc. 000047 UNCONTi OLL10 COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 3 of 16 Scope and Application 1.1 The purpose of this procedure is to convert cyanide ion and complex cyanides to hydrocyanic acid by reduction in the MIDI distillation system with sulfuric acid in the presence of magnesium ions for the determination of total cyanide. The distillation of weak acid dissociable cyanide is also described in this procedure.
1.2 This standard operating procedure is adapted from Standard Methods 18t' Edition 4500-CN C, Determination of Total Cyanide, 4500CN I, Weak Acid Dissociable Cyanide, EPA Methods 335.2 and 335.4, Cyanide, Total and SW-846 Method 9010B Rev. 2 December 1996, Total and Amenable Cyanide: Distillation, and Midi-Dist Instruction Manual. 2 Summary of Method 2.1 The MIDI distillation system is used to release hydrocyanic acid from the sample and to absorb it into a scrubber of sodium hydroxide solution.
This absorbing solution is then tested for the presence of cyanide ion. 3 Interferences NOTE: The interferences described in this section relate only to the distillations performed for TOTAL cyanide analysis.
If weak and dissociable cyanides are to be distilled, refer to the procedure section for guidance on interferences. 
 
===3.1 Known===
interferences for this method are aldehydes, nitrate-nitrite, and oxidizing agents such as chlorine, thiocyanate, thiosulfate, and sulfide. Some interferences are minimized by the use of a distillation system. Verifications of the treatment of these interferences is accomplished by analyzing laboratory fortified sample matrices.
3.2 Lead acetate paper is used to test for sulfides since they interfere with the colorimetric procedure.
If sulfides are present, the sample is treated with an excess of bismuth nitrate solution. (Note: An alternate treatment with cadmium carbonate may be used when analyzing samples by EPA Method 335.4.) 3.3 Sulfamic acid is used to treat all samples for the presence of nitrates and nitrites. 
 
===3.4 Thiocyanate===
 
is reported to be an interference at high levels although levels as high This document is thi propery of ,4nalytical Daboratot Services, Inc. I may be used by the recipient onlyfor the purpose for which it was transmitted.
It is submitted in conjidence and its disclosure to you is not intended to constitute public disclosure or authorization for disclosure to other paties. It may nor be copied or communicated without the written consent ofAnalytical Laboratory Services.
Inc.0000418 UiUNTROLLED COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 4 of 16 as 1 Omg/L do not interfere. 
 
===3.5 Fatty===
Acids, surfactants and detergents cause problems with foaming in the distillation process. These samples are to be handled with predistillation dilutions.
If foaming remains a problem, acidify the sample with acetic acid (1.6 M) to pH 6.0 to 7.0. CAUTION: THIS PROCEDURE CAN PRODUCE LETHAL GAS. PERFORM THIS PROCEDURE IN A FUME HOOD. Extract the sample with iso-octane, hexane or chloroform (preference in order named) with a solvent volume equal to 20% of the sample volume. One extraction is usually adequate to reduce the compounds below the interference level. Avoid multiple extractions or a long contact time at low pH in order to keep the loss of HCN at a minimum.
When the extraction is completed, immediately raise the pH of the sample to pH >12, using a 50% NaOH solution. 
 
===3.6 Other===
methods for removing interferences may be employed provided that they do not adversely affect the performance of the method. Before using a method other than those stated above, approval must be given by the laboratory manager and the client, and a method blank and Laboratory Control Sample (LCS) must be prepared using this method. 4 Safety 4.1 The toxicity or carcinogenicity of each reagent used in this method has not been precisely defined. Each chemical should be handled as if it were a health hazard. 4.2 Each analyst should become familiar with the reagents used by referencing the Material Safety Data Sheet for each reagent. In doing so, the analyst will become familiar with the appropriate safety precautions for each reagent.
4.3 The following chemicals have the potential to be toxic or hazardous
 
====4.3.1 Sulfuric====
Acid 4.3.2 Potassium Cyanide 4.4 Because of the toxicity of hydrogen cyanide (HCN), all distillation equipment must be fitted with final traps or performed under a hood. 4.5 Analysts must wear a fully-buttoned lab coat, safety glasses and PVC gloves at all times during the analysis.
This document is the property ofAnaiytical Laboratory Sertices, Inc. It may be used by the recipient only for the purpose for which it was troasmisted.
It is submitted in contfidence and its disclosure to you is not iotesded to constitute public disclosure or authoritation for disciosure to other parties. It may not be copied or communicated without the written consent of Analytical Laboroy Se-ices. Inc.000049 Method: Revision:
Date: Page: UNICONITROLhII COW'r 09-CNDIS 3 September 28, 1998 5 of 16 5 Apparatus and Materials 5.1 MTDI-Distillation Syatem -This apparatus contains heating blocks, reflux flasks and absorbing flasks with connections for 10 samples. 
 
===5.2 Vacuum===
Pump equipped with trap. 5.3 Assorted Class A volumetric flasks and Class A volumetric pipets. 5.4 Calibrated pH meter 5.5 Balance, capable of weighing O.Olg 5.6 Lead Acetate Paper -(purchased from VWR #60792-009 or equivalent). 
 
===5.7 Graduated===
 
cylinders, various sizes 5.8 Ultrasonic cleaner 5.9 Autoclave 5.10 Boiling Chips -Chemware PTFE boiling stones or equivalent..
5.11 Aluminum foil 6 Reagents 6.1 All reagents are prepared from reagent grade chemicals All c ---rec-orded-in-the-r-eagents-logbook. 
 
===6.2 Reagent===
Water -Reagent water is water in which an interferant is not observed at the analyte of interest.
For this purpose, ALSI uses a deionization system which provides analyte-free, >16.0 megohm-cm deionized water on demand. All references to water in the method refer to reagent water unless otherwise specified. 
 
===6.3 Sodium===
Hydroxide (NaOH) -reagent grade or equivalent..
000050 This documcnt istheproperty of Analytical Laboratory Scraicco, Inc. It may be ued by the recipient onlyfor the purposefor which it was transmitted.
Irta submitted in confidence and its disclosure to you is not intended to constitute public disclosure or authorization for disclosure to other parties. It may not be copied or communicated without the written consent o/Analytical Laboratory Serices, Inc.
Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 6 of 16 6.4 Sodium Hydroxide Absorbing Solution (0.25 N) -Dissolve 10.0 g of sodium hydroxide pellets in deionized water and dilute to 1 liter in a Class A volumetric flask. 6.5 Magnesium Chloride (MgCI 2.6H 2 0) -reagent grade or equivalent. 
 
===6.6 Magnesium===
 
Chloride Solution (51%) (WN) -Dissolve 510 g MgC1 2 .6H,0 in deionized water and dilute to 1 liter. 6.7 Sulfuric Acid, conc (H2SO 4) -Baker Ultra-Analyzed or equivalent. 
 
===6.8 Sulfuric===
Acid (50%) (V/V) -Using a graduated cylinder, slowly add 500 ml of concentrated H 2 S0 4 to 500 ml of deionized water in a glass flask or beaker. CAUTION: glassware will be hot. Use of a cold water bath is recommended to cool the flask while the solution is being prepared. 
 
===6.9 Sulfamic===
Acid -reagent grade or equivalent.
6.10 Sulfamic acid (4%) -Dissolve 40 g of sulfamic acid in deionized water and dilute to 1 liter in a Class A volumetric flask. 6.11 Bismuth Nitrate (Bi(NO 3)3.5 H 2 0) -reagent grade or equivalent.
6.11.1 Bismuth Nitrate Solution -Dissolve 30 g of Bi(NO 3)3  5 H 2 0 in approximately 100 ml of deionized water. Using a graduated cylinder, add 250 ml glacial acetic acid. Stir throughout the addition until dissolved.
Dilute to 1 liter. 6.12 Glacial Acetic Acid -J.T. Baker Ultra-Analyzed or equivalent.
6-.-3-Cyamide-Stock-Sol ion-(-r000-mgitT)
--PREP R IN A iFUME- HO-OD7--AVOID CONTACT WITH ACIDS, KCN IS HIGHLY TOXIC. Dissolve 2.0 g Potassium hydroxide (KOH) and 2.51 g potassium cyanide (KCN) in deionized water and dilute to 900 ml in a volumetric flask. Standardize with 0.0192 N AgNO 3 following the procedure listed below. Then, remove 500 ml and dilute to the appropriate volume such that the resulting solution is 1000 mg/l. Prepare fresh weekly or restandardize weekly. 6.13.1 Pipet 20.0 ml of the stock solution to an Erlenmeyer flask. Add approximately 0.5 ml (5 drops) of the rhodanine indicator.
Th7is document is the property ofAidlyrical Laboratory Services, Inc. It may be used by the recipient only for the purpose for which it was tranemitted.
It is submitted in confidence and its disclosure to you is not itendcd to coiistiatte public disclosure or authorization for disclosure to otier partie. It mnt ot be copied or communicated without she written consenmm f Anarytical Laborazory Services.
Inc.000051 HKCON H 1BBLE B' Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 7 of 16 6.13.2 Titrate with standard 0.0192 N silver nitrate to the first change in color from yellow to brownish-pink.
The titration must be performed slowly with constant stirring.
6.13.3 Titrate a water blank using the same amount of sodium hydroxide and indicator as in the standard.
6.13.4 Calculate concentration of CN in mg/L in the 900 ml of cyanide solution as follows: mg/lCN = (A- B) x 1000 C Where: A = ml of AgNO 3 for titration of standard.
B = lm of AgNO 3 for titration of blank. C -ml of standard titrated.
6.13.5 Calculate the volume of water to add to 500 ml of the Cyanide Stock Solution prepared in section 6.13 to achieve 1000 mg/i cyanide. Use the following equation.
Vol. of Water to Add = (500 ml x Conc. of CN from step above) -500 to 500 ml Std. 1000 mg/l 6.13.6 Accurately measure out 500 ml of the Cyanide Stock Solution.
To it, add the volume of additional water calculated above. The concentration of the Cyanide Stock Solution is now 1000 mg/I.  -So-lion to verify that it is now 1000 mg/i following the instructions in section 6.13.1 through 6.13.4. The acceptable range for the cyanide concentration is +/2%, or 980 to 1020 mg/i. If the concentration is out of this range, fresh standard must be prepared.
The solution must be prepared fresh weekly or restandardized weekly. All standardizatiuon records should be maintained in the standards notebook.
6.14 Cyanide Spike Solution (5 mg/i) -In a 1000 ml volumetric flask, dilute 5.0 ml of stock standard (6.13) with 0.25 N NaOH. Dilute to mark and mix well. Prepare This document is thc propeary ofAnalytical Laboratory Services.
Inc. It may be used by the recipicatt only for the purpose for which it was transmitted.
It is submitted in confidence and its disclosure to you is not _ intended to constitutc public disclosure or authorisation for disclosure to other patics. It may not be copied or communicated without the written consen toftAnalytical Laboratory.Services.
lite.000052 HUMMED TU1 COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 8 of 16 this solution daily. To spike a water sample, add 1.0 ml of the 5 mg/i Cyanide Spike Soloution to 50 ml of sample to achieve a 0.1 mg/i spike. 6.15 Low Range Laboratory Control Sample (LCS) (0.05 mg/L) -Using a 1 ml Class A pipet, pipet I ml of the Cyanide Spike Solution (6.14) into a 100 ml volumetric flask Dilute to volume with 0.25 N NaOH and invert to mix. This will give the 0.05 mg/i solution required.
Prepare this solution daily. 6.16 High Range Laboratory Control Sample (LCS) (0.400 mg/L) -Using an 8 ml Class A pipet, pipet 8 ml of the Cyanide Spike Solution (6.14) into a 100 ml volumetric flask Dilute to volume with 0.25 N NaOH and invert to mix. This will give the 0.400 mg/i solution required.
Prepare this solution daily. 6.17 Reporting Limit Standard (RLS) (0.005 mg/L) Using a Class A volumetric pipet, pipet 5 mL of the Cyanide Spike Solution (6.14) into a Class A 50mL volumetric flask. Dilute to volume with 0.25 N NaOH and invert to mix. This forms a 0.5 mg/L solution.
Using a lmL Class A pipet, pipet lmL of the 0.5 mg/L solution into a Class A 1 00mL volumetric flask. Dilute to volume with 0.25N NaOH and invert to mix. Distill 50mL of this solution to form the 0.005 mg/L RLS. 6.18 Sodium Acetate Trihydrate
-NaC 2 H 3 O, .3H 2 0, reagent grade or equivalent.
6.19 Acetate Buffer -Dissolve 410g sodium acetate trihydrate in 500 mL of reagent water. Add glacial acetic acid to yield a solution pH of 4.5. Verify pH with a calibrated pH meter. 6.20 Zinc Acetate, Zn(C 2 H 3 0 2) H20, reagent grade or equivalent.
6.21 Zinc Acetate Solution (100g/L) Dissolve 120g zinc acetate in 500mL reagent water in a Class A , 1000mL volumetric flask. Dilute to volume with reagent waterand-invertto-mix.
6.22 Methyl Red Indicator 6.23 Ascorbic Acid -reagent grade or equivalent.
6.24 DPD Total Chiorine Reagent Powder Pillows -Purchased from HACH, cat.#14076-99 or equivalent.
000053 This document is the property ofAnalyticaf Laboratory Services.
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Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 9 of 16 7 Glassware Cleaning 7.1 Cleaning of Volumetric Glassware.
7.1.1 This glassware is cleaned in accordance to the policies set forth in the glassware cleaning Standard Operating Procedure. 
 
===7.2 Cleaning===
of the distillation unit. 7.2.1 All glass parts are to be cleaned by washing with hot tap water and a brush, rinsed with 10% sulfuric acid and finally rinsed with deionized water. All tubing is to be washed using hot tap water. 7.2.2 If the absorber flit becomes stained or clogged from samples (especially soils) they may be soaked in conc. HCI for 20 minutes in an ultrasonic cleaner. Aqua-Regia may be used if the flit becomes completely clogged.
Rinse thoroughly with deionized water after using acids to clean the flits. 7.2.3 The glassware may be autoclaved as an additional cleaning step after tubing and plastic fittings are removed. This is not normally needed and should be used only in the case of extremely contaminated glassware.
7.2.4 When not in use, the MIDI glassware must be labeled as either "Clean" or "Dirty". If it is not properly labeled (including date and technician), the unit must be presumed to be dirty. 7.2.5 Record all maintenance in the MIDI logbook.
8 Quality Control 8-t- --Dilutions-of spiki-g- solTtion (6.14), and Reporting Limit Standard (RLS) are to be prepared fresh daily. All other non-cyanide containing reagents remain stable for 180 days. 8.2 A method blank sample consisting of DI water is to be distilled with each batch of samples and repeated every 20 samples.
8.3 The analyst should alternate between the use of a low-range LCS (0.05 mg/l) and a high range LCS (0.400 mg/1) on successive batches. If only one batch is being distilled in a day, then both the low range and high range LCS must be distilled This document is thcpropcrty ofAnalytical Laboratory Services, Inc. It may be used by the recipient ondy for the purpose for which it was transmitted.
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Inc.000054 UNCONTROLLED COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 10 of 16 with that batch. 8.4 A sample Matrix Spike (MS) is to be distilled at a frequency of one per 10 samples. Add lmL of the 5.0 mg/l Cyanide Spike Solution to all samples requiring a matrix spike. Matrix Spike Duplicates (MSD) are to be distilled at a frequency of 1 per 20 samples.
8.5 A Reporting Limit Standard (RLS) should be distilled and analyzed once a month. 8.6 Sections 8.1 through 8.5 describe the required quality control for total cyanide distillation.
Those samples requiring weak and dissociable cyanide distillation require a method blank and High Range LCS per batch as well as a matrix spike every 10 samples. Spike volumes and concentrations for total and weak and dissociable cyanides are the same. 9 Sample Collection, Preservation and Handling 9.1 Aqueous samples are placed in clean plastic bottles and preserved with sodium hydroxide to a pH greater than 12 at the time of sampling. 
 
===9.2 Samples===
are kept at 1-4.4°C until the time of distillation.
After distillation, the absorbing solution is then kept at 1-4.4°C until the time of analysis. 
 
===9.3 Samples===
known or suspected of containing oxidizing agents such as chlorine are to be tested with DPD powder (10.2.2).
A blue color indicates the need for treatment by ascorbic acid. Add ascorbic acid, a few crystals at a time until a drop of sample produces no color change. Then add an additional 0.6 g of ascorbic acid per liter of sample. 10 Procedure 10.1 Weak and Dissociable Cyanide Distillation.
10.1.1 For samples requiring the distillation and analysis of weak and dissociable cyanide, proceed to section 10.1.2. For those samples requiring total cyanide distillation and analysis, proceed to section 10.2. 10.1.2 Transfer 5OmL of sample or the appropriate standard solution to a clean reflux flask using a Class A volumetric pipet or Class A graduated cylinder.
Add 2-3 teflon boiling stones to the flask. Th is document is ehe property of Analytical Laboratory Services.
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Inc.000055 UNCONTROLLID CO'P Method: 09-CNDIS Revision:
3 Date: September 28, 1.998 Page: 11 of 16 10.1.3 Follow instructions in 10.4 through 10.14, then proceed to Section 10.1.4. 10.1.4 Add 2mL of acetate buffer and 2mL of zinc acetate solution to the air inlet tube. 10.1.5 Add 1 drop of methyl red indicator to the air inlet tube and rinse tube with 2-5 mL reagent water. 10.1.6 The methyl red indicator should turn pink in the reflux flask if the pH is within the range specified in the method (4.5-6.0).
If a pink color does not persist for colorless samples, add 10% acetic acid drop-wise until a pink color persists.
For colored samples, the red indicator may not be visible.
Do not add acetic acid to colored samples. Note in the distillation logbook if a sample is colored and the methyl red indicator is not visible.
10.1.7 Once the distillation system is set, cover the reflux flask with aluminum foil. This will reduce the photo-decomposition of some metal-cyanide complexes by ultraviolet light. 10.1.8 Proceed to section 10.22 10.2 Transfer samples to a clean reflux flask. 10.2.1 For aqueous samples, test for the presence of sulfides using lead-acetate paper, by placing a drop of sample on the test paper. A change in color of the paper denotes the presence of sulfides.
Treat a 50 ml portion of the sample containing sulfides with the bismuth nitrate solution (6.13) until there is no presence of sulfides.
Transfer the treated sample to the reflux __ --flask.-(Note-that-the-line-on-the-reflux-flask-is-50-m-i)-Add-2-to-3-b-oilin-g chips to the flask. Document check in the logbook.
10.2.2 For aqueous samples, test for the presence of chlorine using DPD total chlorine reagent powder pillows. Place 5mL of sample into a test tube and add powder pillow. The development of a pink color indicates the presence of chlorine.
Add ascorbic acid, 10 crystals, to another 5 mL of sample. Recheck for chlorine.
Repeat until no pink color forms. Add 10 times the amount of ascorbic acid used in 5mL of sample to the volume of sample to be analyzed (50 mL). Document check in the logbook.
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3 Date: September 28, 1998 Page: 12 of 16 10.2.3 For solid samples, transfer a significant amount of sample to a plastic weigh dish. Using a stainless steel spatula, mix the sample until homogenous.
Weigh approximately 1.Og of the mixed sample into the reflux flask. Dilute to the 50 ml line with deionized water. Add 2 to 3 boiling chips to the flask. 10.3 If a sample needs to be spiked, add 1.0 ml of the Cyanide Spike Solution (6.14) to 50 ml of sample to achieve a 0.1 mg/l spike. 10.4 Place the filled reflux flask into the rack containing the heating block. 10.5 Add 50 ml of 0.25 N NaOH into the absorber flask (note that the line on the absorbing flask is 50 ml), and place opposite the reflux flask. Make sure that both the reflux and the absorber flasks are clearly marked with the sample number. 10.6 Place a reflux impinger into the reflux flask. Make sure that the inlet tube is facing forward. This position will have the hose connections at the rear of the distillation apparatus.
10.7 Place an absorber impinger into the absorbing flask. There are two hoses coming from the absorbing impinger.
One joins at the top and the other joins perpendicular to the impinger.
The perpendicular hose should be facing the front of the distillation apparatus.
10.8 Make sure that all of the hoses are connected properly.
The hose from the reflux impinger connects to the hose from the top of the absorbing impinger.
The hose from the front of the absorber impinger is connected to the valve on the front of the MIDI. 1 0-9---Plaee-a-cotd-fmger-condenserinto-th-e-reflux impinger and check to make sure that all connections are tight. 10.10 Repeat steps 10.3 through 10.8 for each sample to be run working from left to right in the heating block. 10.11 Turn off each vacuum valve by tightening the knobs on the front of the distillation apparatus.
10.12 Make sure that the vacuum pump and trap are installed properly.
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Inc.00oo57 UNCONTROLLED COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 13 of 16 10.13 Turn cooling water on to a flow rate of 6 gallons per hour (GPH) for each sample being distilled.
Note on the flow meter that there are two scales, one for GPH and one for number of samples. Again make sure that all water connections are made properly and that the tubes are not pinched to insure proper condensing of the sample and to keep the water lines from rupturing.
10.14 Turn on the vacuum and, using the knobs at the front of the distillation unit, adjust the vacuum in each sample to a rate of three bubbles per second in the reflux flask. 10.15 Allow the vacuum to draw for 5 minutes.
10.16 Add 10 ml of 4% sulfamic acid solution to the inlet tube of each sample with a Class A volumetric pipet. 10.17 Allow the vacuum to draw for 5 minutes.
10.18 Add 5 ml of 50% (v/v) H 2 S0 4 to the inlet tube of each sample with a Class A volumetric pipet. 10.19 Allow the vacuum to draw for 5 minutes.
10.20 Add 2 ml of 51% magnesium chloride solution to the inlet tube of each sample using a Class A volumetric pipet. If excessive foaming occurs a fresh aliquot of the sample must be diluted, and the entire procedure (starting at 10.1) is performed on the diluted sample. 10.21 Rinse the inlet tube with a minimal amount of DI water. 1-2-2-uTirn-the distillation-unit -on-by-pushinrg-the-re-d-rocker-switch-i-ti-l-it ights. 10.23 Set the timer for 105 minutes. Additional lights on the top of the distillation unit will glow. The green light is the timer light and the amber light is to indicate when the heating block is heating. This setting allows for 15 minutes of heating time to achieve temperature and 90 minutes of reflux time. 10.24 After the timer has counted down to zero, the heating block will be turned off automatically.
This dacumeat is the property ofAnalytical Laboratory Services, Inc. It may be used by the recipient onlyffor the purpose for which it was transmitted.
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Inc.000058 UNCONTROILID COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 14 of 16 10.25 Let the unit cool for an additional 15 minutes with the vacuum and cooling water on. After cooling, shut off the vacuum and cooling water. 10.26 Remove the absorber impinger from the flask. Check that none of the receiving solution was lost or that none of the solution from the reflux flask was transferred during distillation to the absorber flask. This can be done by making sure that there is still 50 ml of receiving solution in the absorber flask. Disconnect the tubing and place the absorbing solution into a 125 ml amber bottle. Label with appropriate information and refrigerate at 1-4.4°C until analysis.
Repeat this step for each sample distilled on the unit. 11 Calculations 11.1 Not applicable.
12 Reporting Results 12.1 In the "Daily Functions" menu of the LIM system select #6 "Preps Performed" entry. 12.2 Enter Test -(WC2) 12.3 Batch # -The batch # and the COC # assigned to the reagent blank are the same six characters.
The reagent blanks are sequentially numbered in the wet chemistry log book with the 2 letter prefix CN followed by 4 digits; i.e., CNOOO1. To assign a reagent blank a COC # and subsequently the distillation batch # in the Preps Performed Entry Menu of the LIMS, consult the wet chemistry log book and locate the last blank for the WC2 distillation.
Name the batch # the following number preceded by the CN prefix. The low or high range LCS will be labeled with-the-samg -n'umbe- thh-ik~ f-itwi1 be preceeded by an "17', i.e., LCN0001.
12.4 Enter the date the distillation was started.
12.5 Enter the technician's initials responsible for finishing the prep. 12.6 Enter the initial and final volumes previously recorded in the wet chemistry logbook.
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-.000059 UNCONTROLED COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 15 of 16 12.7 Select B from the bottom of the screen to create a reagent blank in the LIMS once all of the preparatory factors have been entered.
12.7.1 Enter the appropriate final and initial volumes in ml (or grams for soils) for the reagent blank. 12.8 Review the labeling on bottles, the entries in the log book and the entries in the LIMS to verify that all entries match.OOOOGO This document is the properry ofAnaiytcal Laboratory Services.
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UINCONTROLLED COPY Method: 09-CNDIS Revision:
3 Date: September 28, 1998 Page: 16 of 16 SOP Concurrence Form for the Distribution and Revision of Standard Operating Procedures I have read, understood, and concurred with the Standard Operating Procedure (SOP) described above and will perform this procedure as it is written in the SOP.Print Name Signature Date This document is the property ofAnalytical Laboratory Services, Inc. It may be used by the recipient only for the purpose for which it was rransrmitted.
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Inc.0000G13 Method: Revision:
Date: Page Document Title: Total Cyanide, Automatic Spectrophotometric Document Control Number: UNCONTROL[[
COPY Organization Title: Address: Phone: Approved by: ANALYTICAL LABORATORY SERVICES, INC. (ALSI) 34 Dogwood Lane Middletown, PA 17057 (717) 944-5541 Susan M. Magnes, Quality Assurance Manager David W. A e Technical Director O000062 04-CN 4 October 1 of 24 This document i' the property ofAnalytical Laboratory Sereices.
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UNCONTROLU[D WGPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 2 of 24 TABLE OF CONTENTS 1 Scope and Application
................................................................
3 2 Summary of Method ................................
3 3 Interferences
.....................................
3 4 Safety ..........................................
4 5 Apparatus and Materials
.............................
5 6 Reagents .......................................................................................
5 7 Instrument Calibration
..............................
8 8 Quality Control ...........................................................................
10 9 Sample Collection, Preservation and Handling ..........................
12 10 Procedure
.....................................................................................
12 11--aCale-uldt-ibns
........ ... .....................................................................
1-4 12 Reporting Results .......................................................................
14 APPEND IX A ............................................................................
15 SOP Concurrence Form ..............................................................
32 Th en documet is he propey ofAnolytical Laboraorty Services.
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Inc. 000063 U NCONTBOLLED OP Method: 04-CN Revision:
4 Date: October 9, 1999 Page 3 of 24 Scope and Application 1.1 This method is adapted from the U.S. EPA Method 335.4, "Determination of Total Cyanide by Semi-Automated Colorimetry", Method 335.3, "Cyanide, Total", and SW-846 Method 9012, "Total and Amnmenable Cyanide." This method also references information found in Lachat's Quikchem method number 10-204 00-1-A. The current method detection limit can be found in the current year's method detection limit laboratory notebook.
1.2 This method is restricted for use by or under the supervision of analysts trained on the use of the Lachat. However, the trays may be loaded by analysts who are trained on this part of the analysis.
1.3 This method covers the determination of cyanide in drinking, ground, surface, and saline waters, domestic and industrial wastes, and soils and solids. 2 Summary of Method 2.1 Total cyanide from alkaline distillates is converted to cyanogen chloride, CNCI, by reaction with chloramine-T at pH less than 8. The CNCl then forms a red-blue dye by reacting with pyridine-barbituric acid reagent. The color is read at 570 nm. 2.2 Reduced volume versions of this method that use the same reagents and molar ratios are acceptable provided they meet the quality control and performance requirements stated in this method. 2.3 Limited performance-based method modifications may be acceptable provided they are fully documented and meet or exceed requirements expressed in Sect. 8.0, Quality Control.
3 Interferences
 
===3.1 Several===
interferences are encountered with this method. Some of the known interferences are sulfides, thiocyanate, thiosulfate, sulfide, aldehydes, nitrate nitrite, and oxidizing agents, such as chlorine.
Multiple interferences may require the analysis of a series of laboratory fortified sample matrices (LFM) to verify the suitability of the chosen treatment.
For total cyanide most interferences are eliminated by the distillation procedure.
This document is the property ofAnalytical Laboratory Services, htc. It may be used by the recipient only for the purposefor uhich it was transmitted It is submitted in confidence and its disclosure toyou is no! intevnded to constitute public disclosure or authorization for disclosure to other parties. It may not be copied or communicated without the written consent ofAnalytical Laboratory Ser'ices.
Inc.O0000W U ONTROLL[O COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 4 of 24 3.2 Sulfides adversely affect the colorimetric procedure.
Sulfides are tested for by using lead acetate paper. If sulfides are present, the sample is treated with 50 ml of bismuth nitrate solution after the air flow is set and prior to the addition of the sulfuric acid in the distillation procedure. 
 
===3.3 Nitrates===
and/or nitrites are also a potential interference.
All samples are treated with sulfamic acid in the distillation procedure to remove this interference. 
 
===3.4 Other===
compatible procedures for the removal or suppression of interferences may be employed provided they do not adversely affect the overall performance of the method. New procedures may not be implemented without the permission of the section leader and a Laboratory manager. 
 
===3.5 Method===
interferences may be caused by contaminants in the reagent water, reagents, glassware, and other sample processing apparatus that bias analyte response.
4 Safety 4.1 The toxicity or carcinogenicity of each reagent used in this method has not been fully established.
Each chemical should be regarded as a potential health hazard and exposure should be as low as reasonably achievable.
Cautions are included for known extremely hazardous materials or procedures.
4.2 Each analyst should become familiar with the reagents used by reference the Material Safety Data Sheets (MSDS) for each reagent. In doing so, the analyst will become familiar with the appropriate precautions for each reagent.
4.3 The laboratory also operates under a formal safety plan. 4.4 The following chemicals have the potential to be highly toxic or hazardous, consult MSDS: 4.4.1 Hydrochloric acid 4.4.2 Silver nitrate 4.4.3 Potassium cyanide 4.4.4 Sulfuric acid 4.5 Because of the toxicity of evolved hydrogen cyanide (HCN), distillation should be This document is the property of Analytical Laboratory Services, Inc. It may be used by the recipient only for the purposefor which it was transmitted.
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Inc. 0000G5 Method: 04-CN UNCONTROLLED COPY Revision:
4 Date: October 9, 1999 Page 5 of 24 performed in a well vented hood. 4.6 Analysts must wear a buttoned lab coat, safety glasses, and PVC gloves at all times during the analysis.
5 Apparatus and Materials
 
===5.1 Balance===
-Analytical, capable of accurately weighing to the nearest 0.0001 g. The current balance being used is the Mettler AG245 purchased through VWR catalog no 11274-666. 
 
===5.2 Glassware===
 
-Class A volumetric flasks and pipets as required.
5.3 Midi reflux distillation apparatus including boiling flask, condenser, and absorber purchased from Andrews Glass Co. or equivalent. 
 
===5.4 Heating===
mantel or heating block as required. 
 
===5.5 Automated===
 
continuous flow analysis equipment designed to deliver and react sample and reagents in the required ratios. A Lachat QuikChem AE system with an XYZ sampler and autodistillation capabilities is currently in use. It consists of a sampling device, a multi-channel pump, a reaction unit or manifold, a colorimetric detector, a data recording device and a heating unit. 5.6 Disposable culture tubes -Purchased from VWR catalog no. 60825-571 or equivalent. 
 
===5.7 Transfer===
pipets -Purchased from VWR catalog no. 14670-103 or equivalent.
5.&8 --Vacuum-pump_
 
===5.9 Sonicator===
 
6 Reagents 6.1 Reagent Water -Reagent wateris water in which an interferant is not observed at the analyte of interest.
For this purpose, ALSI uses a Filson Water Purification System which provides analyte-free, greater than 16 megohm-cm, DI water on demand. This document is the property of .4nalytical Laboratory Services, Inc. It may be used by the recipient only for the purpose for which it was transmitted.
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Method: 04..CN UNCONTROLLED COPY Revision:
4 Date: October 9, 1999 Page 6 of 24 6.2 Degassing with helium. To prevent bubble formation, degas all solutions, except the standards, with helium. Use He at 140 kPa (20 lb/in 2) through a helium degassing tube (Lachat Part #50100). Bubble He vigorously through the solution for one minute. Zero grade helium is purchased from MG Industries.
Alternatively, degassing may be performed by sonication and vacuum. 6.3 Sodium hydroxide (NaOH) -pellets, purchased from VWR catalog no. JT3722-7 or equivalent. 
 
===6.4 Reagent===
1, Carrier, 0.25 N Sodium Hydroxide
-By Volume: In a 1-L volumetric flask, dissolve 10.0 g sodium hydroxide (NaOH) in approximately 800 ml water. When the pellets are completely dissolved, dilute to the mark and invert three times to mix. This solution is good for six (6) months. 6.5 Potassium phosphate, monobasic, anhydrous (KH 2 PO 4) -Purchased from VWR catalog no. JT 3246-1 or equivalent. 
 
===6.6 Reagent===
2, Phosphate Buffer, 0.71 M -By Volume: in a i-L volumetric flask, dissolve 97 g potassium phosphate in approximately 800 ml water. Dilute to the mark and invert three times to mix. This solution is good for six (6) months. 6.7 Chloramine-T
-Purchased from VWR catalog no. JTE494-6 or equivalent. 
 
===6.8 Reagent===
3, Chloramine-T
-By Volume: To a 500-ml volumetric flask, add about 250 ml water. Then add 2.0 g chloramine-T.
Dilute to the mark and invert three times to mix. PREPARE FRESH DAILY. 6.9 Pyridine -Purchased from VWR catalog no. JT3348.11 or equivalent.
6.10 Barbituric acid -Purchased from Aldrich catalog no. 18,569-8 or equivalent.
6.11 Hydrochloric acid, conc. (HC1) -Purchased from VWR catalog no. JT9535-33 or equivalent.
6.12 Reagent 4, Pyridine Barbituric Acid Reagent -By Volume: IN THE FUMfE HOOD, place 15.0 g barbituric acid in a 1-L beaker and add 100.0 ml water, rinsing down the sides of the beaker to wet the barbituric acid. Add 75 ml pyridine (CH 5 N) with stirring and mix until the barbituric acid dissolves.
Add 15 ml concentrated This docwuent is the propery ofAnalytical Laboratory Ser'ices, inc. It may be uwed by the recipient only for the purpocefor which it was transmitted.
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It may not be copied or communicated without the written consent of.Analytical Laboratory Services, Inc. 000067 Method: 04-CN UNCONTROLLED Crn'_ Revision:
4 Date: October 9, 1999 Page 7 of 24 hydrochloric acid (12 M HCl) and mix. Transfer to a 1-L volumetric flask, dilute to the mark, and invert three times to mix. This solution is good for six (6) months. 6.13 Potassium Cyanide (KCN) -Purchased from VWR catalog no. EM-PX1435-1 or JT3080-4 or equivalent.
6.14 Potassium Hydroxide (KOH) -Purchased from VWR catalog no. JT3140-11 or equivalent.
6.15 Silver Nitrate Solution (AgNO 3)(0.0192 N) -Purchased from Baxter catalog no. 6910 or equivalent.
6.16 Indicator
-paradimethylaminobenzalrhodanine, purchased from Baxter catalog no. 2560 or equivalent.
6.17 Cyanide Stock Solution (1000 mg/L) -PREPARE IN A FUME HOOD, AVOID CONTACT WITH ACIDS, KCN IS HIGHLY TOXIC. Dissolve 2.0 g potassium hydroxide (5KOH) and 2.51 g potassium cyanide (KCN) in 900 ml of deionized water. Standardize with 0.0192 N AgNO 3 following the procedure listed below. Then, remove 500 mL and dilute to the appropriate volume such that the resulting solution is 1000 mg/L. Prepare fresh weekly or restandardize weekly. 6.17.1 Pipet 20.0 mL of the stock solution to an Erlenmeyer flask. Add approximately 0.5 mL (5 drops) of the rhodanine indicator.
6.17.2 Titrate with standard 0.0192 N silver nitrate to the first change in color from yellow to brownish-pink.
The titration must be performed slowly with constant stirring.
6.17.3 Titrate a DI water blank using the same amount of sodium hydroxide and indicator as used in the titration of the standard.
6.17.4 Calculate concentration of CN in mg/L in the 900 mL of cyanide solution as follows: CN (mg/L) = (A-B) x 1000 C where: 77Tis document is the property ofAnalytical Laboratory Services, Inc. It may be used by the recipint only for the purpnse for which it was transmitted.
It is submitted in confulence and its disclosure to you is not intaended o constitute public disclosure or authorization for disclosure to other pories. It may not be copied orcommunicated without the written consent ofAnalytical Laboratory Services, Inc. 00006S UNCONTROLLE COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 8 of 24 A = ml of AgN0 3 for titration of standard.
B = ml of AgNO 3 for titration of blank. C = ml of standard titrated.
6.17.5 Calculate the volume of water to add to 500 mL of the Cyanide Stock Solution prepared in Section 6.17 to achieve 1000mg/L cyanide. Use the following equation.
Vol. of Water to add to 500 mL Std. = (500 mL x Conc. of CN from step above) -500 1000 mg/L 6.17.6 Accurately measure out 500 mL of the Cyanide Stock Solution.
To it, add the volume of additional water calculated above. The concentration of the Cyanide Stock Solution is now 1000 mg/L. 6.17.7 Titrate a 20.0 mL portion of the 1000 mL Cyanide Stock Solution to verify that it is now 1000 mg/L following the instructions in Section 6.18.1 through 6.18.4. The acceptable range for the cyanide concentration is +/2%, or 980 to 1020 mg/L. If the concentration is out of this concentration range, fresh standard must be prepared.
The solution must be prepared fresh weekly or re-standardized weekly. All standardization records should be maintained in the standards logbook.
6.18 Working Calibration Standard (5 mg/L) and Cyanide Spike Solution (5 mg/L) -In a 1000 ml volumetric flask, dilute 5.0 ml of Cyanide Stock Solution (6.17) with 0.25 N NaOH. Dilute to mark and mix well. This must be made up daily. One mL of this solution is added to 50 mL of sample to yield a 0.10 mg/L spike. 6.19 Stock Calibration Verification Standard (1000 mg/L) -Prepare and standardize in the same manner as the Cyanide Stock Solution except a different lot of KCN must be used.-Standardize-as-in-6.7-.-1-dhrough 6.1-7-.4.-Label as-Stock CVS.-T-his----
solution must be prepared fresh weekly or re-standardized weekly. 6.20 Working Calibration Verification Standard (5 mg/L) -Prepare a 5 mg/L working standard from the Stock CVS in the same manner as the Working Calibration Standard (6.18) was prepared.
Label as Working CVS. This must be made up daily. 7 Instrument Calibration
 
===7.1 Refer===
to the Lachat protocol and maintenance document Section 1.0, Changing of This document is the property ofAnalylical Laboratory Services.
Inc. It may be used by the recipient onlyfor the purposefor which it was transmitted.
It is submitted in confidence and its disclosure to you is not intended to constautepublic disclosure or authorization for disclosure to other panics. It may not be copied ar conmmunicated without the written consent ofAnalytical Laboratory Services, Inc. 0000G9 UNCONTROLLED COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 9 of 24 the Manifold; Section 2.0, Running of the Lachat; and Section 3.0, Calibration.
The method to be downloaded for this analysis is cyanides.
This protocol contains the pertinent information needed to calibrate the instrument and to determine if the calibration is valid. 7.1.7 The R values should be 0.9950 or above for the chords of the curve being used for the samples.
7.1.8 The PIF (peak integrity factor) must be > 0.75 for detectable samples. 
 
===7.2 Prepare===
a series of six (6) standards as described starting in 7.2.1, and a reagent blank by pipetting suitable volumes of Working Calibration Standard solution (6.18) into volumetric flasks for daily calibration.
These standards should be diluted with 0.25 N NaOH (6.4). The carrier that is being used to dilute the standards should be the same carrier that is being used on the Lachat manifold.
NOTE: All standard dilutions must be recorded in the standards logbook located in the wet chemistry area on the bookshelf with the other laboratory notebooks.
Also the dilution scheme outlined below is only to give an example of the sample dilutions.
The amounts may be changed proportionally depending on the amount needed and also on available glassware.
7.2.1 A set of six (6) Working Standards is made from the 5.0 mg/L Working Calibration Stock Standard (6.18). These are: 0.500 0.250 0.100 0.050 0.010 0.005 mgCN/L 7.2.2 First, prepare the 0.5 mg/L standard by diluting 20.0 mL of the 5.0 mg/L Working Calibration Standard (6.18) to 200mL with 0.25 N NaOH (6.4) in a 200 mL volumetric flask. 7.2.3 Prepare the other five calibration standards by diluting the following volumes of the 0.5 mg/L standard to 100mL with 0.25 N NaOH (6.4) in IOOmL volumetric flasks. ML of 0.5 mg/L Standard Concentration Diluted to 100 mL mra,/ 1 0.005 4 0.020 10 0.050 This document is the property ofAnalytical Laboratory Seroices, Inc. It may be usel by the recipient onlyfor the purpose for which it was transmitted.
It is submitted in confidence and its disclosure to you is not intended to constitute public disclosure or authorization for disclosure to other paries. it may not be copied or communicated without the written consent of Analytical Laboratory Services.
Inc. 00007C UNCONTHOLLIO COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 10 of 24 20 0.10 50 0.25 7.2.4 The reagent blank consists of only Reagent 1 -0.25 N NaOH. Do not use DI water. 7.3 After the calibration has been established, it must be verified by the analysis of a 0.1 mg/L Initial Calibration Verification Std (ICVS). If measurements exceed +/10% of the true value, the problem must be investigated and corrected prior to the analysis of any samples. The analysis may have to be terminated and the instrument recalibrated.
The new calibration must be verified before continuing analysis.
7.3.1 ICVS (0.1 mg/L) -Using a Class A pipet, dilute 2.0 mL of 5 mg/L Working Calibration Verification Standard (6.20) with Reagent 1 -0.25 N NaOH (6.4) in a 100 mL volumetric flask. Invert three times to mix. 8 Quality Control 8.1 A method blank must be prepared and analyzed with each distillation batch. The method blank must be less than 2xMDL or less than 5% of the sample concentration.
If the method blank is not within acceptable limits, all samples with a detectable result in the batch must be re-distilled or reported with a qualifying comment.
8.2 A nondistilled Continuing Calibration Standard (7.3.1) and a Calibration Blank (7.2.4) must be run at the beginning of the analysis, after every ten samples and at the end of the run to verify the calibration curve. Analysis of the calibration blank is to verify that the instrument is free from contamination at +/- the reporting limit.-_The-concentration-of theCCS-must-be-within-1-0% of the-true-value.-If-the_
concentration is not within +/- 10%, the source of the problem must be identified and corrected before proceeding with the on-going analysis.
Once the problem has been corrected, re-analyze samples following the last acceptable CCS. For more information on ways to change the frequency of the Continuing Calibration Standards and blanks in the Lachat software, consult the information screens in the software under the windows entitled:
tray definition and submit, data quality management, auto qc set scheduling, qc set definition, and help for dqm. 8.3 The distilled Laboratory Control Sample (LCS) checks the efficiency of the This document is the prope' ofAnalytical Laboratory Services, Inc. It maybe sed by the recipient on ly for the puqposefor which it was transmitted.
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Inc. 000071 UNCONTROLLED COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 11 of 24 distillation procedure as well as the entire analytical procedure.
The analyst should alternate between the use of a low-range LCS (0.05 mg/L) and a high range LCS (0.400 mg/L) on successive distillation batches. If only one batch of samples is analyzed in a day, a high and low LCS must be analyzed in that batch. The LCS must have a recovery within +/- 10% of the true value, or within calculated control limits, whichever is tighter. If the LCS fails, the cause of the failure must be investigated and corrected before proceeding with the on-going analysis.
After corrected, all samples in that batch must be redistilled.
If samples are outside of the holding times, consult a laboratory supervisor or manager. 
 
===8.4 Sample===
matrix spikes must be prepared and analyzed at a frequency of one every ten drinking water samples, or one in every 20 other samples. For water samples, add 1.0 mL of the 5 mg/L Cyanide Spike Solution to 50 mL of sample to achieve a 0.1 mg/L spike. Recoveries must be within the established control limits that are based on historical matrix spike recovery data. In the absence of calculated control limits, the percent recovery must be within +/- 10% of the true value. If the recovery limits fall outside of acceptable range, but the LCS recovery is within acceptable limits, the recovery problem is judged to be sample matrix related.
The result should be reported with a qualifying comment. If the LCS also fails, the problem is judged to be system related, and the batch must be re-distilled. 
 
===8.5 Matrix===
Spike Duplicates (MSD) must be run at a rate of one every 10 samples.
Duplicates must have an RPD within the established control limits that are based on historical RPD data. In the absence of calculated control limits, the RPD must be less than 20%. If the duplicate is not acceptable, it must be redistilled.
If the sample cannot be redistilled and rerun before a holding time violation will occur, consult the supervisor or a laboratory manager. 
-8.6- --.A-Quality-Control Check Standard-should-be performed on-a quarterly basis._ The QC Check Standard should be a blind standard from a commercial source such as Environmental Resource Associates or other commercial supplier.
The recovery must be within the acceptable range provided by the supplier.
If the standard is not within these limits, the source of the problem must be identified and corrected before proceeding with further analysis.
8.7 A Reporting Limit Standard (RLS) must be distilled and analyzed at a rate of one every month. Recoveries must be within the established control limits that are based on historical recovery data. In the absence of calculated control limits, the This document is the property of Analyfical Laboratory Services, Inc. It may be used by the recipient only for the purpose for which it was transmitted.
It is submitted in confidence and its disclosure to you is not jnteded to constitute public disclosure or auzhorization for disclosure to othterparties.
It may not be copied or communicated without the witten con=et of Analytical Laboratory Servictt , Inc.000072 UNCONTROLLED COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 12 of 24 recovery must be within +/-RLS. If the recovery is not acceptable, consult the supervisor or a laboratory manager.
8.8 The absorbance and wavelength of the 510nm filter used for the analysis is validated on an annual basis. This is done by an external vendor, and documentation is kept on file. 8.9 Samples reading a high negative absorbance must be re-analyzed to determine if the high negative absorbance is due to an instrument problem or the sample matrix itself. If the matrix is determined to be the cause of the problem, report the result with a qualifying comment on the Lab Report. 9 Sample Collection, Preservation and Handling 9.1 Samples should be collected in plastic or glass bottles. All bottles must be thoroughly cleaned and rinsed with reagent water. The volume collected should be sufficient to insure a representative sample, allow for replicate analysis (if required), and minimize waste disposal. 
 
===9.2 Samples===
must be preserved with sodium hydroxide to a pH>12 and cooled to 1 4.4°C at the time of collection. 
 
===9.3 Samples===
should be analyzed as soon as possible after collection.
If storage is required, preserved samples are maintained at 1-4.4°C and may be held for up to 14 days. 9.4 The color reaction is pH sensitive.
Therefore, distillates or preserved samples and standards should be carefully matched with respect to NaOH concentration.
Samples for analysis on the Lachat must be in a 0.25M NaOH receiving solution ---------because-the-carrier-on-the-Lachat-is-0.25M NaOH.-Any-other-NaOH-molarity-w-ill give inconsistent results when analyzed on the Lachat. 10 Procedure 10.1 Calibrate the system daily as described in Section 7. 10.2 After an acceptable calibration is performed and the CVS has been checked and verified, samples may be run. Samples must be distilled before running. See the Prep Department SOP for cyanide distillation.
This document is the property of Analytical Laboratory Services.
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Inc. 000073 UNCONTROLLED COPY Method: 04-CN Revision:
4 Date: October 9, 1999 Page 13 of 24 10.3 Each sample tube should be filled V/2 to 3/4 full with sample. 10.5 Sample numbers must be entered before sample submission.
See Section 4 of the Lachat protocol and maintenance document for more information.
Samples should be submitted under the sample submit screen in the Lachat. The only time a dilution factor should appear as part of the sample submit screen is when there was a manual dilution performed.
The operator category should contain the name of both the person who is performing the analysis as well as the name of the one who is filling the trays if they differ. 10.6 Any dilutions made should be done using the carrier solution which is the 0.25 M NaOH solution (6.4). This includes standards and sample dilutions.
10.7 The following is a list of criteria that is specific for the cyanide analysis.
Also included with this method is a packet of the screens printed from the cyanide method definition program. Any change in these screens should be documented with the Lachat data. See Appendix A. 10.7.1 Sample throughput:
80 samples/h; 40 s/sample Pump speed: 35 Cycle period: 50 s Inject to start of peak period: 23 s Inject to end of peak period: 61 s 10.7.2 QuickChem AE Settings:
Parameter, Data Window: Top Scale Response:
0.50 abs ___ ____Bottom_
Sca~le Response -0.05 Segment/Boundaries:
A -500 ug CN/L C -50 ug CN/L D -10 ug CN/L E -5 ug CN/L F -0 ug CN/L Results/Approval, Reports: This document is the property ofAnalytical Laboratory Services, hic. It may be used by the recipient only for the purposefor which it was transmitted.
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Inc. 000074 UNCONTROLLED COP"? Method: 04-CN Revision:
4 Date: October 9, 1999 Page 14 of 24 In the default RDF, change: Set Default Chord 0 to Set Default Chord 3 (Peak should be centered in chord 3.) This change must be made to both the sample and the calibration RDFs. This change may be saved but when updated software is installed the trays must be changed from chord 0 back to chord 3. 10.4 Allow 15 minutes for heating unit to warm up to 600 C. 11 Calculations 11.1 The concentration of cyanide in pg/l will be shown directly on the runtime report. Calculations are determined by a graph of absorbance versus concentration.
If the data meet the criteria outlined in this document, then those results can be reported in the computer system to two significant figures.
11.2 The only time a sample needs to be multiplied by a dilution factor is when a manual dilution was performed.
11.3 To determine amenable cyanide, use the following calculation:
Amenable Cyanide = Total Cyanide (mg/L) -Cyanide in Chlorinated Sample (mg/L) If the Amenable cyanide is a negative concentration using this calculation, the comment on the lab report using the standard verbiage "ACN".  ----12--Reporting Results_ 12.1 Report results in mg/l to three significant figures.
12.2 Duplicates, spikes, and the internal QC samples all need to be reported under the QA screen when entering results.
12.3 If a sample is below the current reporting limit, then the sample should be reported as ND (non-detectable).
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Inc. 000075 04-CN 4 October 9, 1999 15 of 24 APPENDIX A Defig--- TiS Oi~es *ein ' Teeifa ala.~ iSs.ttalTsn ,alae~ S... ....M O CStl. P.r-O a c- -1a ..el ....... a0 channeI 5etecatar Si~~aas ,* he t o tStart 0oP-alsP-td.
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Date: Page This document is the property of.Analytical Laboratory Inc. It may be used by the recipient only for the purposc for which it was transmitted.
It is submitted in confidence and its disclosure lo you is not intended to constitute public disclosure or authorizationfor disclosure to other parnics. It may not be copied or communicated without the written consent ofAnalytical Laboratory Serviccs, Inc. 00007G UNC[ONTROLLED CVnY UNCONTROLLED COPY 04-CN 4 October 9, 1999 16 of 24 Define carne.cner f ur ic-eo--bal¢e~acnrn,.tey.d~r
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Date: Page APPENDIX A*.1 t Oyanide 6 inactive 'i7 i t -c h ~Ij h......of This document is he property of Analytical Laboratoy Se,-ices.
Inc. It msay be used by the recipient onlyfor the purpose for which it was transmitted.
Is is submitted in confidence and its disclosure to you is not intended to constitute public disclosure or authorization for disclosure to other parties. It may not be copied or communicated without the wriuten consent of.Analytical Laborazroy Seryices Inc. 000077 UNCONTROLLED COP"F 04-CN 4 October 9, 1999 17 of 24 APPENDIX A DeO she the o'der standards ill Ib run -n a lI ratson -ho. D. F-ti-oCnN,, Fle .... ipto 0an~e Stda- Tieing O~tt.at.
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Date: Page This document is the property ofAnolytical Laboratory Services.
hic. It may be used by the recipient only for the puwposefor which it woas transmitted It is submitted in Confidence and its disclosure to you is not intended to constitute public disclosure or authorimotion for disclosure to other parties. It may not be copied or communicated without the written consent ofAnalytical Laboratory Services.
Inc. 00007S UNCONTR[L[D COPY 04-CN 4 October 9, 1999 18 of 24 t5'fjne fi, P Sob aSptq Ti- S 011P MS Ti *.Meethod D.ftniticn
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Date: Page APPENDIX A This document is the property ofAnalytical Laboratory Services, Inc. It may be used by the recipient only for the purpose for which it was transmitted.
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Date: Page APPENDIX A This document is the property ofAnalynical Laboratory Services.
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Date: Page APPENDIX A This document is the property ofAnalytical Laboratory Services.
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inc. 000083 Method: Revision:
Date: Page UNCT OTROULLI tWY 04-CN 4 October 9, 1999 23 of 24 APPENDIX A D.5in SS. U nt Signai O'os$ing iiiii ~ ~ ~ -- --1 ....s....... ... ... ...: In.o S Sana a .B.d t.auan r g. S inat n P.itnn M c$S .-laneos S1- ... S1- 0 ...... .. S..........
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Se... Sns ttt:O iii: :::: ,( .....t.....i. .This document is the property ofAnalytical Laboratory Services.
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It is submitted in confidence and its disclosure to you is noa intended to constitute public disclosure or authorization for disclosure to other parties. It may not be copied or communicated without thc written consent 0f/Analytical Laboratory Services.
Inc. O00004 Method: Revision:
Date: Page 04-CN UNCONTROLL[O COPY 04-CN 4 October 9, 1999 24 of 24 SOP Concurrence Form for the Distribution and Revision of Standard Operating Procedures I have read, understood, and concurred with the Standard Operating Procedure (SOP) described above and will perform this procedure as it is written in the SOP.Print Name Signature Date This document is tihe property of Analytical Laboratory Scetices.
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1t is submitted in confidence and its disclosure to you is not intended to constitute public disclosure or authorization for disclosure to other parties. It may not be copied or communicated without the written consent ofAnalyticul Laboratory Services, Inc. 000085
' OlTELEDYNE BROWN ENGINEERING Page 1 of 8 ENVIRONMENTAL SERVICES PRO-032-0 1 DETERMINATION OF GROSS ALPHA AND/OR GROSS BETA ACTIVITY IN WATER SAMPLES
 
==1.0 INTRODUCTION==
 
This procedure is used to measure the overall radioactivity of water samples without identifying the radioactive species present. No chemical separation techniques are involved.
One liter of the sample is acidified with nitric acid, then evaporated on a hot plate. Different volumes may be used if the sample has a significant salt content or if unusual sensitivity is desired. If requested by the customer, the sample is filtered through No. 54 filter paper before evaporation, removing particles greater than 30 microns in size. Other filter media may be used in order to comply with a client's specifications.
After evaporation in a beaker, the sample is rinsed into a 2-inch diameter stainless steel planchet which is stamped with a concentric ring pattern to distribute residue evenly. Final evaporation to dryness takes place under heat lamps. Samples which appear to be hygroscopic are dried again under heat lamps just prior to counting.
Residue mass is determined by weighing the planchet before and after mounting the sample. The planchet is counted for alpha and/or beta activity on an automatic proportional counter. Results are calculated using empirical Approved by Approved By Manager Manager Issue or Effective Environmental Quality Revision Pages Prepared By Date Analysis Assurance Reissue 8 03/20/96 .eter 7 D. Martin J. Guenther 0000S;
' ahTELEDYNE BROWN ENGINEERING Page 2 of 8 ENVIRONMENTAL SERVICES PRO-032-01 self-absorption curves which allow for the change in effective counting effi ciency caused by the residue mass. 2.0 DETECTION CAPABILITY Detection capability depends upon sample volume actually represented on the planchet, background and efficiency of the counting instrument, and upon self-absorption of alpha and beta particles by the mounted sample. Because the radioactive species are not identified, no decay corrections are made and the reported activity refers to the counting time. Minimum detectable level (MDL) for water samples is nominally
 
===1.6 picoCuries===
 
per liter. for gross beta at the 4.66 sigma level, assuming that 1 liter of sample is used and that 1/2 gram of sample residue is mounted on the planchet.
These figures are based upon a nominal counting time of 50 minutes and upon representative values of counting efficiency and background of 0.2 and 1.2 cpm, respectively.
The MDL for gross alpha activity is nominally
 
===2.3 picoCuries===
 
per liter at the 4.66 sigma level also assuming that 1 liter of sample is used and that 1/2 gram of sample residue is mounted on the planchet.
These figures are based upon a nominal 200 minute counting time and upon a representative efficiency of 0.02 and a background of 0.1 cpm. The MDL becomes significantly lower as the mount weight decreases because of reduced self-absorption.
At a zero mount weight, the 4.66 sigma MDL for gross beta is 0.9 picoCuries per liter and the MDL for gross alpha is 0.3 picoCuries per liter. These values reflect a beta counting efficiency of 0.38 and an alpha counting efficiency of 0.18. Different counting intervals may be used to obtain the desired detection limits.0000S7
 
BROWN ENGINEERING Page 3 of 8 ENVIRONMENTAL SERVICES PRO-032-01
 
===3.0 SAMPLE===
SELECTION PROCEDURE (a) Using the Sample Receipt Form or Work List with the Teledyne sample number, locate the sample (or sample group) in the Sample Receiving and Storage Room and transport them to the Alpha/Beta Laboratory.  (b) Begin filling out the Radiochemical Work Sheet -Gross Beta/Gross Alpha, entering the customer name, the sample numbers in nu merical order, the desired analyses (alpha and/or beta), sample collection dates, the sample preparation date and the initials of the analyst.  (c) Make an entry in the Alpha/Beta Laboratory Data Book showing customer name, sample numbers, sample type, collection dates and desired analyses. 
 
===4.0 SAMPLE===
PREPARATION PROCEDURES This section describes how water samples are filtered (if required), then evaporated.
The residue of each sample is dried on a 2-inch stainless steel planchet which is stamped with a concentric ring pattern.  (a) Choose a clean beaker sized to contain the sample aliquot. Mark it with the Teledyne sample number.  (b) Shake the sample container to distribute any particulate matter evenly. Decant the desired aliquot into a clean graduated cylinder, then transfer it to the numbered beaker.  (c) If filtration is requested by the customer, obtain another beaker of the same size and write the sample number on it. Place a glass funnel in a funnel rack over the empty beaker. Fold a 18.5 cm di ameter No. 54 filter paper disk into quarters and place it in the mouth of the funnel. Gravity filter the sample from its original beaker into the identically numbered beaker. Rinse the original beaker and the filter paper with deionized water from a wash bottle. Different filter media may be used in order to comply with a client's specifications.  (d) Add approximately 5 ml concentrated HNO 3 to the sample from a dropping bottle. Place the beaker on a hot plate under the hood in the Alpha-Beta Laboratory and set the hot plate for high surface temperature.
0000S8
* 7" TELEDYNE BROWN ENGINEERING Page 4 of 8 ENVIRONMENTAL SERVICES PRO-032-01 (e) Evaporate the sample gently to dryness. Take care to reduce hot plate temperature as the sample volume decreases in order to avoid loss by spattering from the beaker. Remove from the hot plate.  (f) Prepare a 2-inch stainless steel concentric ring planchet for each water sample by first wiping it clean with a Kimwipe. Write sam ple number, customer name, and desired analyses (alpha and/or beta) on a gummed label and stick to back of planchet.  (g) Take the labeled group of planchets to the Radiochemistry Counting Room on a sample tray and weigh each on the analytical balance. Record this tare weight in the Alpha-Beta Laboratory Data Book beside the sample number. Return the tray of tared planchets to the Alpha-Beta Laboratory.  (h) Wet the interior sides and bottom of the sample beaker with a fine steam of 2M HN0 3 from a wash bottle. Using a rubber policeman mounted on a glass stirring rod, police the interior of the beaker thoroughly to bring any adhering material into suspension in the liquid. Transfer the solution from each sample beaker to its correspondingly numbered planchet.
Repeatedly wash the beaker with small amounts of 2M HN0 3 from a wash bottle and collect the washings in the planchet.
NOTE: If a film of sample residue remains in the beaker, rinse with ethanol from a wash bottle. Use the policeman to remove the residue, then transfer it to the planchet.  (i) Place the filled planchets in the sample tray under heat lamps in the Light Hood. Add a few drops of 0.1% laboratory aerosol to each planchet.
Evaporate to dryness. Remove and allow to cool. If any residue is found on the outside edge of a planchet, scrape it off with a spatula and return it into the planchet.  (j) Take sample tray to the analytical balance within 1/2 hour after removing from the Light Hood. Weigh each planchet and record final weight next to the corresponding tare weight in the Alpha Beta Laboratory Data Book.  (k) Subtract the tare weight from the final weight for each sample and record this mount weight on the Radiochemical Work Sheet and in the Data Book. Submit the Radiochemical Work Sheet and the tray of finished planchets to the Radiochemistry Counting Room for radioassay.
0000S9
* A1L TELEDYNE BROWN ENGINEERING Page 5 of 8 ENVIRONMENTAL SERVICES PRO-032-01
 
===5.0 SAMPLE===
COUNTING PROCEDURE Before carrying out the steps below, inspect the residue in the planchets.
If these residues appear to have gained moisture from the air, place the tray of planchets under heat lamps and dry again.  (a) Verify that the sample tray containing a group of sample planchets contains the same sample numbers as the accompanying Radiochemical Work Sheet -Gross Beta/Gross Alpha.  (b) Write counting sequence numbers on the work sheet following the order that the sample numbers appear on the sheet. Begin with the number 1 if starting a new sample counting group; oth erwise use the number which follows the last sequence number assigned.  (c) Remove the sample planchets from the tray in sequence number order, verifying in each case that the sample number on the back of the planchet matches the sequence number. Transfer each to a plastic planchet holder and then to the selected counter in se quence number order.  (d) Write the counting start date and the number of the automatic proportional counter on the work sheet.  (e) Load a counting blank, an alpha check source and a beta check source with each counting group. Set the counting interval and initiate the counting sequence.
Counts are normally set for 50 minutes but the intervals can be modified to obtain desired sensitivity.  (f) After all samples in the group have been counted, copy the printed counts and counting interval for each sample onto the Radiochemical Work Sheet in the space provided.  (g) Unload the sample planchets from the holders and store in the rack for processed alpha and beta samples. 
 
===6.0 CALCULATION===
 
OF THE SAMPLE ACTIVITY OR OF THE MDL (a) Sample activity and the 2-sigma counting uncertainty are calculated as follows: 000090 AMTELEDYNE BROWN ENGINEERING Page 6 of 8 ENVIRONMENTAL SERVICES PRO-032-01 Net pCi = Unit volume N/At- 0 2.22(v)(.)
net activity 2- (N/At + 0)/At _+ 2.22 (v) (e)counting uncertainty N= total counts from sample (counts)At = counting time for sample (nin) P = background rate of counter (cpm) 2.22 = Um pCi v = volume of sample analyzed = efficiency of the counter (b) Establishing and reporting activities that are equal to the detection limit: or less than If the net activity N/At --) is equal to or is less than a designated multiple of the background counting uncertainty, the activity is below the limits of detection and is called "less than" (L.T.) or "minimum detectable level (MDL). The L.T. value can be specified by stating only the counting uncer tainty at a predetermined multiple (am) of the one sigma statis tics. A sigma multiple (am) of 4. 36 is used for calculation of the L.T. values unless the customer requests another value such as 2.83.thus L.T.am2v)) 2.22(v) (e)000091 where:
, AO TELEDYNE BROWN ENGINEERING Page 7 of 8 ENVIRONMENTAL SERVICES PRO-032-O 1 7.0 CALIBRATION OF EQUIPMENT FOR GROSS ALPHA. GROSS BETA ANALYSES Automatic proportional counters are used for measurement of gross alpha and gross beta analyses for all sample media. The preparation of each sample type has been described in separate procedures.
The final "mounting" is in a 2-inch steel planchet which is positioned in the counting instrument.
Alpha and beta standards are also prepared and measured in 2 inch planchets.
Alpha standards are prepared by diluting EPA Am-241 or Th-230 standard solutions (traceable to NIST1 and by evaporating measured aliquots in planchets.
The efficiency of the instrument is then determined by dividing the cpm measured by the dpm value. Routine measurements of check sources are plotted on control charts as described in PRO-032-27.
The absorption (called self-absorption) of alphas by the sample mass in the planchet (thus reducing the count rate) is determined as follows: A known activity of Am-241 or Th-230 is evaporated with varying amounts of Na2CO3 salt. This salt has been shown to have the same self-absorption properties as finely divided silt. Residue weights between 0 and 1.5 grams are distributed in 2-inch planchets.
From the radiometric determinations a curve is constructed with the apparent instrument efficiency monotonically decreasing with increasing "mount weight". An algebraic expression of this curve is stored in a computer and is referenced during data reduction to yield the counting efficiency corresponding to the measured mount weight. Determinations of beta counting efficiencies and self-absorption curves are similar to the methods used for alpha. Beta standards are prepared by diluting EPA Cs-137 standard solutions (traceable to NIST). Measured 000092
"
BROWN ENGINEERING Page 8 of 8 ENVIRONMENTAL SERVICES PRO-032-01 aliquots of these solutions are evaporated in planchets to prepare standards in the same geometry used for counting samples. Self-absorption curves are prepared by evaporating standard solutions with varying weights of Na2C03 salts. Beta check sources are counted routinely and the results are plotted on control charts as described in PRO-032-027.
000093 Fax:2016645586 Sep 29 '99 9:37 P.02 "l"TELEDYNE PRO-032-81 ISOTOPES Page 1 of 6 DETERMINATION OF TOTAL RADIUM IN WATER SAMPLES
 
==1.0 INTRODUCTION==
 
This procedure presents a radiometric method for determining total radium activity (alpha) in water samples. Stable barium carrier is added to the sample and radium is co-precipitated with barium sulfate. The precipitate is collected and mounted on a millipore filter. The precipitate mass is determined by weighing the filter before and after mounting the sample. The filter, mounted in a planchet, is counted on an automatic proportional counter. Results are calculated using an empirical self absorption curve which allows for the change in effective alpha counting efficiency caused by the precipitate mass. The calculation includes a factor to compensate for activity attributed to alpha emitting daughters of Ra-226 which are re establishing secular equilibrium during the time period between the pre cipitation and the midcount time. This procedure is based on Method 900.1 of the Environmental Protection Agency, described in EPA-600/4-80-032, August 1980. 2.0 DETECTION CAPABILITY Detection capability depends upon sample size, chemical yield, the counting interval, the ingrowth factor for alpha daughters of Ra-226, and the efficiency and background of the counting instrument.
The MDL for total radium activity (alpha) is nominally
 
===0.5 picocurie===
 
per liter at the 4.66 sigma Issue and Effective Approved Revision Pages Prepared By Date Date By Draft 4 J. D. Martin 10/17/83 07/01/83 .. Martn Revision 6 H. 01/05/84 01/05/84 000094 Fax:2016645586 Sep 29 '99 PRO-032-81 AWrTELEDYNE Page 2 of 6 ISOTOPES level (0.3 pCi/f at the 2.83 sigma level). The MDL is based on a 50-minute counting time, a chemical yield of 0.90, an ingrowth factor of 1.5, a sam ple volume of 1i, a detector background of 0.15 cpm and efficiency of 0.16 for precipitate mass of 0.03 gram. 3.0 SAMPLE SELECTION PROCEDURE (a) Using the Sample Receipt Form with the Teledyne Isotopes sample number, locate the sample (or sample group) in the Sample Receiving Storage Room and transport them to the Alpha-Beta Laboratory.  (b) Begin filling out the Radiochemical Work Sheet, entering the customer name, the sample number, total radium (as the analysis), sample collection date, the sample preparation date and the initials of the analyst.  (c) Make an entry in the Laboratory Data Book showing customer name, sample numbers, sample type, collection dates and desired analysis. 
 
===4.0 CHEMICAL===
SEPARATION PROCEDURES (a) Write the Teledyne Isotopes sample number on a 2-liter beaker. Shake the sample container and decant into the beaker, filling to the 1 liter mark.  (b) Adjust pH to 3 with HNO 3 as follows: Using a dropping bottle, add conc HNO 3 to the sample while stirring with a clean glass rod. Withdraw the rod periodically and touch to pH paper. Continue until a pH 3 color indication is obtained.  (c) Allow beaker to stand approximately 10 minutes to settle any particulate matter.  (d) Gravity filter the sample through a 18.5 cm diameter fiberglass filter which is folded in quarters and inserted in the mouth of a glass funnel. Receive the filtrate in another 2-liter beaker which is marked with the sample number.  (e) Using a volumetric pipet, add 2.00 ml standardized Ba carrier to the filtered sample (nominally 18 mg Ba/ml). Stir with a glass rod.  (f) Place the filtered sample beaker (now containing Ba carrier) on a hotplate and bring to near boiling.  (g) Using a disposable pipet, add 3 ml K2so4 reagent (nominally 60 mgK 2 SO 4/ml) to the sample. Stir with a glass rod. Record the date and time of this addition in the laboratory data book.000095 9:37 P. 03 Fax:2016645586 Sep 29 '99 PRO-032-81 IWTELEDYNE Page 3 of 6 ISOTOPES (h) Allow the sample beaker to remain on the hotplate another 30 minutes (at a temperature slightly below the boiling point). A fine white BaSO 4 precipitate should form and fall to the bottom of the beaker. Remove beaker from the hotplate and allow to cool. 5.0 MOUNTING THE PRECIPITATE (a) Prepare a new 2-inch stainless steel planchet for each sample by first wiping it clean with a kimwipe. Write customer name, sample number, and analysis (TOT Ra) on a gummed label and stick to the back of the planchet.  (b) Place a 0.45 um millipore filter in each labeled planchet.
Weigh each (including its filter) on an analytical balance and record this tare weight beside the sample number in the Laboratory Data Book.  (c) Set up a vacuum filter (millipore) apparatus for each sample by inserting a fritted glass filter holder in a 1-liter sidearm flask. Taking the samples in numerical order, place the millipore filter on the vacuum apparatus, add the specially designed funnel and fix in place with a clamp.  (d) Vacuum filter the sample into the correspondingly numbered millipore apparatus.
Filtration is fastest if the precipitate is allowed to remain at the bottom of the beaker and is filtered last.  (e) In the last phases of filtration, rinse the sample beaker with deionized water from a wash bottle and add this rinse to the funnel. Do not use a methanol rinse.  (f) Disconnect the vacuum apparatus.
Remove the filter gently with a spatula and transfer it to its planchet (observing the numerical order of samples).  (g) Place planchets (containing their filters with precipitates) in a fiber tray in a hot air oven (100"C), or under heat lamps, to dry.  (h) Take the tray containing dried samples to the analytical balance.
Weigh each planchet and record final weight next to the correspond ing tare weight in the Laboratory Data Book.  (i) Subtract the tare weight from the final weight and record this mount weight in Laboratory Data Book and on the Radiochemical Work Sheet. Divide mount weight by the carrier standardization value (written on the Ba carrier flask) to obtain chemical yield. Record yield on the Radiochemical Work Sheet and in Laboratory Data Book.  (j) Complete the entries on the Radiochemical Work Sheet, adding the sample aliquot used and the date and time of K 2 SO 4 addition.
Submit the Radiochemical Work Sheet and the tray of finished 000096 9 :3? P. 04 Fax:2016645586 Sep 29 '99"IWTELEDYNE PRO-032-81 MSOOPES Page 4 of 6 planchets to the Radiochemistry Counting Room for radioassay. 
 
===6.0 SAMPLE===
COUNTING PROCEDURE (a) Verify that the sample tray containing a group of sample planchets contains the same sample numbers as the accompanying Radiochemical Work Sheets.  (b) Write counting sequence numbers on the work sheets following the order that the sample numbers appear on the sheet. Begin with the number 1 if starting a new sample counting group; otherwise use the number which follows the last sequence number assigned.  (c) Remove the sample planchets from the tray in sequence number order, verifying in each case that the sample number on the back of the planchet matches the sequence number. Transfer each to a plastic planchet holder and then to the counting cassette in sequence number order.  (d) Write the counting start date and time, and the number of the automatic proportional counter on the first work sheet.  (e) Load the cassette into the counter and set the counting mode for alpha. Set the counting interval for 50 minutes unless a different interval is specified for greater sensitivity.  (f) After all samples in the group have been counted, copy the printed counts and counting interval for each sample onto the Radiochemical Work Sheet in the space provided.
Also record the count date and time for each sample (certain automatic proportional counters print the count start time; others do not, requiring a summation of counting intervals from the first sample count).  (g) Unload the sample planchets from the holders and store in the rack for processed alpha and beta samples. 
 
===7.0 CALCULATION===
 
OF THE SAMPLE ACTIVITY OR OF THE MDL (a) Sample activity and the 2 sigma counting error are calculated as follows;000097 9:38 P. 05 Fax:2016645586 Sep 29 '99 ISOTOPES PRO-032-81 Page 5 of 6 7.0 CALCULATION OF THE SAMPLE ACTIVITY OR OF THE MDL (a) Sample activity and the 2 sigma counting error are calculated as follows: Net pCi unit volume N-B 2.22(v)tp)(i) net activi ty 2 N +B +/- ( t 2 TZZ"llV) counting error where: N = total counts from sample (counts) At= counting time for sample (min) B = background rate of counter for alpha (cpm) 2.22 = v = volume of sample analyzed c = efficiency of the counter for Ra-226 alpha, determined empirical ly as a function of precipitate mass. p = Radium-226 alpha ingrowth factor: p = 1 + 3(l-e-'t)
S= decay constant of Rn-222, 0.007551 hr" 1 t = elapsed time (hrs) from the time of BaSO 4 separation to the mid-point of the counting period.  (b) Establishing and reporting activities that are equal to or less than the detection limit: If the net activity -2 p is equal to or is less than a designated multiple of the background counting error, the activity is 00009S 9:38 P. 06 Sep 29 '99 PRO-032-81 Page 6 of 6 below the limits of detection and is called "less than" (L.T.) or "minimum detectable level" (MDL). The L.T. value can be specified by stating only the counting error at a predetermined multiple (am) of the one sigma sta tistics. A sigma multiple (am) of 4.66 is used for calculation of the L.T. values unless the customer requests another value such as 2.83. thus L.T. = 2.22 (v)(p)(C)000099 Fax:2016645586 9:38 P. 07 Fax:2016645586 Sep 29 '99 TLEDn& BROWN ENGINEERING Page 1 of 4 ENVIRONMENTAL SERVICES PRO-022-65 DETERMINATION OF RA-226 IN WATER
 
==1.0 INTRODUCTION==
 
The procedure describes the method of determining Ra-226 in water samples by the emanation technique.
Radon-222 is equilibrated with the parent radionuclide.
Ra-226, and then transferred through a closed system to an evacuated one-liter alpha chamber. The Rn-222 and daughters activi ties are measured in successive counting periods. 
 
===2.0 DETECTION===
 
CAPABILITY The minimum detectable level (MDL) for water samples is nominally 0.2 pCi/liter for Ra-226 at the 4.66 sigma confidence level. This figure is based upon a sample volume of 0.4 liter, a counting time of 1000 minutes, and upon representative values of counting efficiency (for Rn-222 and two alpha emitting daughters) and background of 2.00 and 2.3 cpm, respectively. 
 
===3.0 SAMPLE===
SELECTION PROCEDURE (a) Using the Sample Receipt Form with the Teledyne Brown Engineering
-Environmental Services sample number, locate the sample or sample group in the appropriate storage area. Transport the sample(s) to the Gas Analysis Laboratory.  (b) Select a flask for use. Write the following information on a tag and attach to the flask: customer name, Teledyne #, volume of sam ple, flask ID, and date and time of sample preparation for the Approved By Manager Issue or Effective Technical Quality Revision Pages Prepared By Date Approval Assurance Reissue 4 01/10/97 "/J. D. Martin H. W. Jeter J. Guenther 000100 9:31 P. 02 Fax:2016645586 Sep 29 '99 T EIDY BROWN ENGINEERING Page 2 of 4 ENVIRONMENTAL SERVICES PRO-022-65 Ra-226 determination. 
 
===4.0 SAMPLE===
PREPARATION PROCEDURES (a) Transfer 0.4 liter of water to the labeled emanation flask and close the flask from the atmosphere through the tapered. ground seal. Different volumes of sample may be used in order to obtain differ ent minimum detection levels and depending on the availability of sample volume. It may be necessary to apply a small quantity of vacuum grease to the tapered surface.  (b) Connect the inner tube of the flask to the helium supply and pass helium through the flask for a minimum of five minutes. The bubbling purges radon from the sample.  (c) Close the valve between the helium cylinder and the flask.  (d) Close the two stopcocks on the emanation flask.  (e) Set flask aside for approximately two weeks to permit the Rn-222 activity to equilibrate with the Ra-226, if any. in the water. 5.0 DETECTOR LOADING After approximately two weeks, proceed with the following steps.  (a) Attach the outer tube of the flask to an evacuated 1 liter volume alpha counting chamber through the gas handling system.  (b) Attach the inner tube of the flask to the helium supply.  (c) Open the stopcock on the flask which will permit Rn-222 (and any residual helium) to pass into the 1 liter counting chamber.  (d) Slowly open the stopcock first and then the valve to the helium supply. The helium will flow through the flask and into the 1 liter counting chamber. Monitor the pressure on the vacuum gauge.  (e) When the pressure reaches one atmosphere (760 mm Hg), close all valves.000i01 9::31 P. 03 Fax:2016645586 Sep 29 '99 AWTELEDYNE BROWN ENGINEERING , ENVIRONMENTAL SERVICES Page 3 of 4 PRO-022-65
 
===6.0 SAMPLE===
COUNTING (a) Push the RESET button on the scaler and push the START button. Record the start time.  (b) Record Count at approximately 60 minute intervals until ingrowth of Rn-222 daughters is complete as indicated by a maximum count. If activity is indicated by the count, recount the following day for 60 minutes to verify the presence of Rn-222 by the decay. 7.0 STANDARDS AND CONTROL OF COUNTERS A Ra-226 standard which is NIST traceable, is counted in the same manner. as described above once per month in each counter.
The efficiency of the combined radon extraction from the sample and the nuclear counting is determined with the standard. 
 
===8.0 CALCULATION===
 
OF RA-226 ACTIVITY The Ra-226 activity is determined from the Rn-222 activity as follows: Net pCi unit volume N (e2,t 2) 2.22 (v) (e) (I -e Ati)_+2.22(M (e) (1 -e Ati)net activity counting error N = total counts from sample (counts) At = counting time for sample (min) P = background rate of counter (cpm)2.22 pCi v = volume of sample analyzed E = efficiency of the counter 000102 where: 9:352 P. 04 Fax:2016645586 Sep 29 '99 AmEIZDYNE BROWN ENGINEERING Page 4 of 4 ENVIRONMENTAL SERVICES PRO-022-65 I -e -Xtl) = determines the "ingrowth" of Rn-222 from Ra-226 during the time lapse of ti t = the time lapse of the first helium purge to the second helium purge = the decay constant for Rn-222 e=t2 the correction for Rn-222 decay from the mid count time to the time it was transferred to the counting chamber.
t 2  = the time lapse from transfer to chamber to mid count time Establishing and reporting activities that are equal to or less than the detection limit: If the net activity is equal to or is less than a specified multiple of the back ground counting error, the activity is below the limits of detection and is called "less than" (L.T.) or -minimum detectable level" (MDL). The L.T. value can be specified by stating only the counting error at a prede termined multiple (amn) of the one sigma statistics.
A sigma multiple (0m) of 4.66 is used for calculation of the L.T. values unless the customer requests another value such as 2.83. thus L.T. =t 2.22 (v) (F) (1 -e -Xti)000103 9:32 P. 05 Fax:2016645586 Sep 29 '99 DETERMINATION OF RA-226 IN SOIL INTRODUCTION The initial-preparation of a soil sample for Ra-226 determination by the emanation technique is to transfer one gram of dry soil into a labeled emanation flask. To that are added 10 ml of 6N HC1 and 340 ml of distilled water. Close the flask from the atmosphere through the tapered, ground seal. Proceed with step 4.0 (b) of PRO-022-65.
000104 9:"32 P. 06 601K 813 I I I I I I 3600-PM-WQOOO8 Rev 7/97 NPDES Number PA 0047325 SECTION C -(continued)
Ill. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) n Outfall Number Z Intake Sampling Results -Optional (Specify Source Susquehanna River LI Upstream Background Sample Results -Optional (Specify Location of Sample ] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for Information presented, see Instructions for Section C, Part II 2.a. 2.b. 2.c. 2.d.Maximum Daily Value -Report the highes daily value or daily average from the last year of data. Report both mass and concentration.
Maximum' 30-Day Value -Determine the average of all daily Values during each calendar month and report the highest average.
Long Term Average Value -The average of all values within the last year and report both mass and concentration.
Minimum of three sampling events required for process wastewater discharges and a minimum of one sampling event for all other discharges, treatment facility influent and intake water.-11 -2. LEVEL PRESENT 3. UNITS 4. 1. POLUTANTCoefficient
: 1. POLLUTANT
: a. Maximum Daily Value b. Maximum 30-Day Value c. Long-Term Avge. Value Cofficient GROUP I -___ (if aailable (if avail ble) d. a. b. of Effluent GR UP1 ifavilbl) ifavilbl)No.
of Concentration Mass Variability (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass Analyses (CV) 1C Biochemical Oxygen 4 N/A 2.67 N/A 3 mg/I N/A Chemical Oxygen DemandD 2C COD <15 N/A <15 N/A 3 mg/I N/A 3C Total Organic Carbon, 2.8 N/A 2.67 N/A 3 mg/I N/A Total Suspended Solids, 4C TSS 10 N/A <7 N/A 3 mg/_ N/A 5C Total Dissolved Solids, 281 N/A 188.33 N/A 3 mg/I N/A 6C Ammonia as N <0.10 N/A <0.10 N/A 3 mg/I N/A 7C Oil and Grease <2 N/A <2 N/A 3 mg/I N/A 8C Bromide <2 N/A <1 N/A 3 mg/I N/A 9C Chlorine, Total Residual 0.06 N/A <0.043 N/A 3 mg/I N/A Temperature 3 3v1 (&deg;C) (&deg;C) (&deg;C) 10C winter Value Value Value 1 _ ___ _________
Temperature 23.3 summer Value Value Value 2 (OC) (&deg;C) (&deg;C) 7.47 7.84 3 standard standard 12Cinimum Maximum units unitspH) ) ) )
3600-PM-WQO0008 Rev 7/97 NPDES Number PA 0047325 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results Fj Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [] Outfall Number [ Intake Sampling Results -Optional (Specify Source Susquehanna River E Upstream Background Sample Results -Optional (Specify Location of Sample [] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept- 1. 2. 3. Level Present 4. Units 5 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA Coefficient normally present in this discharge, check the appropriate DetoBp2 iec- Level Method a. Max Daily Value b. Average of Analyses bC. of block or describe another reason. Gru l ion Usd Nme umber Effluent __ Ine-- _ Level d Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other ou 2 vl (ig/I) Used tration Mass tratlon Mass Analysis tration Mass (CV) Material factured Stored mediate Prduct Water (Explain) meodiate OrdctW therEpan 13C Color 1 110.2 40 N/A 28.33 N/A 3 c.U. N/A 14C Fecal Coliform 9222D 90 N/A 28.62 N/A 3 #/100ml N/A 15C Fluoride 100 50 300.0 170 N/A <110 N/A 3 Pg/I N/A 16C Nitrate-Nitrite 50 300.0 850 N/A 593.3 N/A 3 Pg/I N/A __(as N) I__ I__ I__ I 17C Nitrogen, Total 1,000 Calc <1,000 N/A <1,000 N/A 3 pg/I N/A Organic (as N) I I _ 18C Phosphorus 100 365. <100 N/A <100 N/A 3 Pg/I N/A (as P), Total I 0 3 1 0 N/ <0 NA 3/ 19C Sulfate (as S0 4) 1,000 500 300.0 62,500 N/A 37,367 N/A 3 Pig/I N/A 20C Sulfide (as S) 1,000 1,000 3761 <1,000 N/A <1,000 N/A 3 p~g/I N/A 210C Sulfite (as SO 3) 2,000 2,000 377.1 <4,000 N/A <2,667 N/A 3 pg/I N/A 21C Sulfateants 0)200 200 371 <,0 / 267 NA 3 Pg/I N/ 22C Surfactants 25 25 5540c 39 N/A 35.67 N/A 3 pg/I N/A ___(MBAS)
____ _______ ___ ___ ___ ______ Total Kjeldahl-1,000 351.4 <1,000 N/A <1,000 N/A 3 pg/I N/A -Nitrogen 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.I I I I I I I I) ) ) )
I I I I i I I I I I I I i 3600-PM-WQO0008 Rev 7/97 NPDES SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) E Outfall Number [ Intake Sampling Results -Optional (Specify Source Susquehanna River [] Upstream Background Sample Results -Optional (Specify Location of Sample F] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 F] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Pollutant Group 2 ,ccept 1. able Detection Detec-I Level (continued)
Level I loll)Used (Wig/I)2. EPA Method Number Used Concen tration Mass 3. Level Present 4. Units 5.I i t 1 ' 1 'npffie-n Concen tration Mass Alsr~s^f n~ll~ I C.of Analysik Concen tration Mass 1M Antimony, Total 200 10 200.7 <10 N/A <10 N/A 3 1ig/i N/A 2M Arsenic, Total 50 3 200.7 <3 N/A <3 N/A 3 "tig/l N/A 3M Beryllium, Total 5 2 200.7 <2 N/A <2 N/A 3 jig/I N/A 4M Cadmium, Total 5 1 200.7 <1 N/A <1 N/A 3 Pjg/I N/A 5M Chromium, 50 3 200.7 <3 N/A <3 N/A 3 lig/I N/A Total _ _ 5M Chromium, 10 10 3500D <40 N/A <23.33 N/A 3 Pg/I N/A Hexavalent 6M Copper, Total 20 10 200.7 <10 N/A <10 N/A 3 jig/I N/A 7M Lead, Total 100 3 200.7 <3 N/A <3 N/A 3 jig/I N/A 8M Mercury, Total 0.2 0.2 245.1 <0.5 N/A <0.3 N/A 3 jig/I N/A 9M Nickel, Total 40 20 200.7 <20 N/A <20 N/A 3 jig/I N/A 10M Selenium, Total 75 10 200.7 <10 N/A <10 N/A 3 jig/I N/A 11M Silver, Total 10 1 200.7 <1 N/A <1 N/A 3 jig/I N/A 12M Thallium, Total 100 10 200.7 <10 N/A <10 N/A 3 Pjg/I N/A 13M Zinc, Total 5 10 200.7 10 N/A <10 N/A 3 jig/I N/A 14M Cyanide, Total 20 5 335.3 8 N/A <6 N/A 3 jig/I N/A 14M Cyanide, Free 5 5 45001 <5 N/A <5 N/A 3 pjg/I N/A of Effluent Variability Number PA 0047325 6. If you have any reason to expect the pollutant to be normally present in this discharge, check the appropriate block or describe another reason.Raw I Manu- I Inter- St- Ita-e Other Mteriallfactu ored mediates y- IIntake rdr,,,,-, Product Water I(Explain 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. S3.a Maximum Daily Value -Report the highg. daily value or daily average value from the last year of data. Report both mass and concentration.
S3.b, Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
c3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
S Make copies of this table and check appropriate box. It is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses C or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-13--- Y t-I at. Miax DaJilly vatluet v. ,-ra,=p n, ,-,=y... 1Numbe^ IA^u fl^lh* tion 3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
NPDES Number PA 0047325 III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results El Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [ Outfall Number [ Intake Sampling Results -Optional (Specify Source Susquehanna River [ Upstream Background Sample Results -Optional (Specify Location of Sample El Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 [ New Discharge (Describe basis for information presented, see Instructions for Section C, Part II) )Accept. 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA Coefficiern normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses C .of block or describe another reason. Go 2 bloc Number Effluent -o- -ther-s o 2ed) Level. Used Number Concen- Concen- of Concen- Variability Raw Manu- S edInter- Intake Other (continue(d)
W/I /I) Used tration Mass tration Mass Analysis tration Mass (CV) Material factued red Product Product Water (Explain) 15M Phenols, Total 5 10 420.2 <10 N/A <10 N/A 3 pg/I N/A 16M Aluminum, Total 100 150 200.7 <150 N/A <76.7 N/A 3 Plg/I N/A 17M Barium, Total 100 10 200.7 40 N/A 33.33 N/A 3 Pg/I N/A 18M Boron, Total 100 50 200.7 <50 N/A <50 N/A 3 pg/I N/A 19M Cobalt, Total 50 3 200.7 <3 N/A <3 N/A 3 Rg/I N/A 20M Iron, Total 30 30 200.7 570 N/A 370 N/A 3 Pg/I N/A 21M Iron, Dissolved 30 60 200.7 <60 N/A <50 N/A 3 Pg/I N/A 22M Magnesium, 30 50 200.7 11,000 N/A 7,077 N/A 3 jig/I N/A Total I I I 23M Molybdenum, 100 10 200.7 <10 N/A <10 N/A 3 l.g/I N/A _ Total 24M Manganese, 10 3 200.7 110 N/A 96 N/A 3 pg/I N/A Total I I I I III 25M Tin, Total 800 10 200.7 <10 N/A <10 N/A 3 ig/I N/A 26M ITitanium, Total 400 10 200.7 <10 N/A <10 N/A 3 jig/I N/A 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the bigh.s daily value or daily average value from the last year of data. Report both mass and concentration.
C 3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.
* It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.i I -I I I I I I I I I I I II I I I I { 3600-PM-WQO0008 Rev 7/97 NPDES SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) LI Outfall Number [ Intake Sampling Results -Optional (Specify Susquehanna River LI Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325) )Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -Coefficieni normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses c. of block or describe another reason. Group 3 _ion Used Number Ndumber Effluent -n -rso Volatile Organics Level Used Number Concen- Concen- of Concen- Variability Raw Manu- Ite By- Intake Other VoatlWOgag/I)
Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate Prod lai .I CV)Product prduct Water (Explain) 1V Acrolein 10 20 624 <20 N/A <20 N/A 3 jig/I N/A 2V Acrylonitrille 10 10 624 <10 N/A <10 N/A 3 Pjg/I N/A 3V Benzene 10 1 624 <1 N/A <1 N/A 3 Pjg/I N/A 5V Bromoform 10 1 624 <1 N/A <1 N/A 3 jig/I N/A 6v Carbon 10 1 624 <1 N/A <1 N/A 3 Pjg/I N/A TetrachlorideII 7V Chlorobenzene 10 1 624 <1 N/A <1 N/A 3 lig/i N/A 8v Chlorodibromo-10 1 624 <1 N/A <1 N/A 3 jig/I N/A methane 9V Chloroethane 10 2 624 <2 N/A <2 N/A 3 jig/I N/A 2-Chloroethylvinyl 10V Ether 10 5 624 <5 N/A <5 N/A 3 jig/I N/A 11V Chloroform 10 1 624 <1 N/A <1 N/A 3 Pjg/I N/A Dichlorobromo 12V methane 10 1 624 <1 N/A <1 N/A 3 jig/I N/A 14V 1,1-Dichloroethane 10 1 624 <1 N/A <1 N/A 3 Pjg/I N/A 15V 1,2-Dichloroethane 10 2 624 <2 N/A <2 N/A 3 jig/I N/A 16V 1e1-Dichloro-10 1 624 <1 N/A <1 N/A 3 jig/i N/A ethylene______________________________
1,2-Dichloro 17V propane 10 2 624 <2 N/A <2 N/A 3 jig/I N/A 1,3-DicIhIoro 18V propylene 10 2 624 <2 N/A <2 N/A 3 jig/I N/A 19V Ethylbenzene 10 1 624 <1 N/A <1 N/A 3 Pjg/I N/A 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box. It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-15-I I I I I 3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
Ill. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results NPDES Number PA 0047325 Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) El Outfall Number Z Intake Sampling Results -Optional (Specify Source Susquehanna River Ej Upstream Background Sample Results -Optional (Specify Location of Sample [] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 El New Discharge (Describe basis for information presented, see Instructions for Section C, Part II) )Accept 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA Coefficiar, normally present in this discharge, check the appropriate Group 3 D Level Method a. MaxDal Value b. Average fAl of block or describe another reason, et e Dv .l V nalvsesof bclr -resn- Wo p 3 't.Number Effluentner Volatile Organics Leeonl Used Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other (continued) (el/l 1) tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored medit uct Water (Explain) 20V Methyl Bromide 10 3 624 <3 N/A <3 N/A 3 lg/I N/A 21V Methyl Chloride 10 2 624 <2 N/A <2 N/A 3 Pg/I N/A 22V Methylene 10 3 624 <3 N/A <3 N/A 3 gull N/A Chloride 23V 1,1,2,2-Tetra-10 1 624 <1 N/A <1 N/A 3 Pg/I N/A I chloroethane 24V Tetrachloro-10 1 624 <1 N/A <1 N/A 3 vg/I N/A ethylene 25V Toluene 10 1 624 <1 N/A <1 N/A 3 jig/I N/A 26V 1,2-Trans-Di-10 1 624 <1 N/A <1 N/A 3 jig/I N/A chloroethylene
_ __ I 27V 1,1,1-Trichloro-10 1 624 <1 N/A <1 N/A 3 pjg/I N/A ethane I I 28V 1,1,2-Trichloro-10 2 624 <2 N/A <2 N/A 3 ig/I N/A ethane 29V Trichloro-10 1 624 <1 N/A <1 N/A 3 ig/I N/A ethylene 31V Vinyl Chloride 10 2 624 <2 N/A <2 N/A 3 jig/I N/A 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the hihest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-I I I I I I I I I I I I I I 3600-PM-WQO008 Rev 7/97 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results NPDES Number PA 0047325 EI Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) L] Outfall Number Z Intake Sampling Results -Optional (Specify Source Susquehanna River 0 Upstream Background Sample Results -Optional (Specify Location of Sample F] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II)Pollutant Accept 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection EPA -Coefficleni normally present In this discharge, check the appropriate Group 4 Detec- Level Method a. Max Daily Value b. Average f Analyses Nmc.bei of block or describe another reason. Acid-Fraction tion Used Number Effluent Inter- B I tion 44ed Used Concen- Concen- of Concen- Variability Raw Manu- By- Intake Organics -tration Mass traton Mass Analysis tration Mass (CV) Material factured Stored mediate Oter -/ -I ___ Product Product Water (Explain) 1A 2-Chlorophenol 10 10 625 <10 N/A <10 N/A 3 Ag/I N/A 2A 2,4-Dichloro-10 10 625 <10 N/A <10 N/A 3 1ig/1 N/A phenol 3A 2,4-Dimethyl-10 10 625 <10 N/A <10 N/A 3 lag/I N/A phenol 4A 4,6-Dinitro-o-10 10 625 <10 N/A <10 N/A 3 9g/I N/A Cresol I I I I 5A 2,4-Dinitro-50 15 625 <15 N/A <15 N/A 3 lig/I N/A phenol I I I 6A 2-Nitrophenol 10 10 625 <10 N/A <10 N/A 3 ugkl N/A 7A 4-Nitrophenol 50 10 625 <10 N/A <10 N/A 3 gg/I N/A 8A P-Chloro-m-10 10 625 <10 N/A <10 N/A 3 itg/I N/A Cresol I I I 9A Pentachloro-50 25 625 <25 N/A <25 N/A 3 lag/I N/A phenol 10A Phenol 10 10 625 <10 N/A <10 N/A 3 Vg/I N/A A 2,4,6-Trichloro-10 10 625 <10 N/A <10 N/A 3 Pg/I N/A 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility Influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It Is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3600-PM-WQ0008 Rev 7/97 NPDES SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results L] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) F] Outfall Number [ Intake Sampling Results -Optional (Specify Source Susquehanna River [] Upstream Background Sample Results -Optional (Specify Location of Sample [J Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325) ) )Pollutant Accept 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection EPA Coefficlenr normally present In this discharge, check the appropriate Group 5 Level Method a. Max Daily Value b. Average of Analyses c. of block or descbe another reason. Base-Neutr tion Number Effluent In ter Fraction Level- Used Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other Organics / tration Mass tration Mass Analysis tration Mass (CV) Materiai factured Stored I Product Water (Explain) 1B Acenaphthene 10 3 625 <3 N/A <3 N/A 3 pg/I N/A 2B Acenaphthylene 10 3 625 <3 N/A <3 N/A 3 pg/I N/A 3B Anthracene 10 2 625 <2 N/A <2 N/A 3 plg/I N/A 4B Benzidine 50 20 625 <20 N/A <20 N/A 3 pg/I N/A 5B Benzo (a) 10 2 625 <2 N/A <2 N/A 3 plg/I N/A Anthracene I 6B Benzo (a) Pyrene 10 2 625 <2 N/A <2 N/A 3 pag/I N/A 7B 3,4-Benzo-10 2 625 <2 N/A <2 N/A 3 pg/I N/A fluoranthene 8B Benzo (ghi) 10 2 625 <2 N/A <2 N/A 3 plg/I N/A Pervlene 9B Benzo (k) 10 5 625 <5 N/A <5 N/A 3 pg/I N/A Fluoranthene 10B Bis (2-Chloro-10 3 625 <3 N/A <3 N/A 3 pg/I N/A 10_ ethoxy) Methane 11B Bis (2-Chloro-10 3 625 <3 N/A <3 N/A 3 pg/I N/A 11B ethyl) Ether I _ 12B Bis (2-Chloro-10 2 625 <2 N/A <2 N/A 3 pg/I N/A ___ isooronvi)
Ether________________
13B Bis (2-Ethyl-10 2 625 <2 N/A <2 N/A 3 pg/I N/A 1 3 B h e x V ) P h t h a la te I I I _ 14B 4-Bromophenyl 10 3 625 <3 N/A <3 N/A 3 pIg/I N/A Phenyl Ether 1 1 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
c3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
Make copies of this table and check appropriate box.  ** It is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-i I I [ I I I I I I I I I I I I I I I I 3600-PM-WQOOO8 Rev 7/97 NPDE' SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results LI Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) LI Outfall Number Z Intake Sampling Results -Optional (Specify Source Susquehanna River nI Upstream Background Sample Results -Optional (Specify Location of Sample L] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II ,Number PA 0047325 Pollutant Accept 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection EPA I Coefficleni normally present in this discharge, check the appropriate Group 5 Detec- Level Method a. Max Daily Value b. Averae of Analyses .of block or describe another reason. Base-Neutral tion Used Number .ob Effluent -_ o Inter BraseNetron Usedvumbe Concen- Concen- of Concen- Variabi~lity MRaw Manru- meinter By- Intake Other Fraction Leve' 4-(g/I) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored Pediate Product Water (Explain) 15B Butyl Benzyl 10 5 625 <5 N/A <5 N/A 3 pg/I N/A 16B_ Phthalate 1 52 < N5 /A__/ 16B 2-Chloronaphthalene 10 5 625 <5 N/A <5 N/A 3 pg/I N/A 184-Chlorophenyl 10 5 625 <5 N/A <5 N/A 3 p~g/I N/A __7B Phenyl Ether _____ _____________
18B Chrysene 10 2 625 <2 N/A <2 N/A 3 pg/l N/A 9B Dibenzo (a, h) 10 2 625 <2 N/A <2 N/A 3 Pg/I N/A SAnthracene 1 20B 1,2-Dichlorobenzene 10 5 625 <5 N/A <5 N/A 3 pg/I N/A 21B 1,3-Dichlorobenzene 10 5 625 <5 N/A <5 N/A 3 pg/I N/A 22B 1,4-Dichlorobenzene 10 5 625 <5 N/A <5 N/A 3 lug/I N/A 23B 3.3'-Dichloro-50 5 625 <5 N/A <5 N/A 3 Ag/I N/A benzidine I 24B Diethyl Phthalate 20 10 625 <10 N/A <10 N/A 3 pg/I N/A 25B Dimethyl Phthalate 20 10 625 <10 N/A <10 N/A 3 pg/I N/A 26B Di-N-Butyl 20 5 625 <5 N/A <5 N/A 3 pg/I N/A 2 Phthalate 27B 2,4-Dinitrotoluene 10 2 625 <2 N/A <2 N/A 3 pg/I N/A 28B 2,6-Dinitrotoluene 10 1 2 625 <2 N/A <2 N/A 3 [Ig/I N/A 29B Di-N-Octyl Phthalate 20 5 625 <5 N/A <5 N/A 3 pg/I N/A 30B 1,2-Diphenylhydra-10 5 625 <5 N/A <5 N/A 3 pvg/I N/A _ Azobenzene) , If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.  "=&#xfd;.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
w3"b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration. 
-3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.-19-)
3600-PM-WQOOO8 Rev 7/97 NPDES SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E[ Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [] Outfall Number [ Intake Sampling Results -Optional (Specify Source Susquehanna River [ Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Pollutant Group 5 Base-Neutral Fraction Organics Accept. able Detec tion Level (4g/I)1. Detection Level Used (pg/I)2.  "EPA Method Number Used 3. Level Present 4. Units 5.p y-q-y-q ...-.-u...,..-..
: a. Max Daily Value b. Average of Analyses Concen tration Mass Concen tration Mass C.of Analysl., Concen tration Mass 31B Fluoranthene 10 2 625 <2 N/A <2 N/A 3 pgI N/A 32B Fluorene 10 3 625 <3 N/A <3 N/A 3 pg/I N/A Hexachloro-10 2 625 <2 N/A <2 N/A 3 pg/I N/A 33B benzene 34B Hexachloro-10 5 625 <5 N/A <5 N/A 3 pjg/I N/A butadiene 35B Hexachloro-10 10 625 <10 N/A <10 N/A 3 Pg/I N/A cyclopentadiene 36B Hexachloro-10 5 625 <5 N/A <5 N/A 3 pg/I N/A ethane I 37B Indeno (1,2,3-cd) 10 2 625 <2 N/A <2 N/A 3 pIg/I N/A Pyrene 38B Isophorone 10 3 625 <3 N/A <3 N/A 3 Ag/I N/A 39B Naphthalene 10 3 625 <3 N/A <3 N/A 3 pg/I N/A 40B Nitrobenzene 10 3 625 <3 N/A <3 N/A 3 pjg/I N/A 41B N-Nitrosodi-20 3 625 <3 N/A <3 N/A 3 pg/I N/A '- methylamine 42B N-Nitrosodi-N-20 3 625 <3 N/A <3 N/A 3 pg/I N/A Proovlamine I 43B N-Nitrosodi-20 3 625 <3 N/A <3 N/A 3 Pg/I N/A phenvlamine 44B Phenanthrene 10 3 625 <3 N/A <3 N/A 3 pg/I N/A 45B Pyrene 10 2 625 <2 N/A <2 N/A 3 pfg/I N/A 46B 1,2,4-Trlchloro-10 10 625 <10 N/A <10 N/A 3 pg/I N/A benzene I I _ I I I of Effluent Variability
: 6. If you have any reason to expect the pollutant to be normally present In this discharge, check the appropriate block or describe another reason.Raw Manu- Inter- B Intake Other rita fc e Stored mediate t I,, a,,,t Product Water IExplain 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.  (=3.a Maximum Daily Value -Report the hihest daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
03:c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
3.c Make copies of this table and check appropriate box. S ** It Is In the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses kA or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.Number PA 0047325! I I I I I I I I I 1 c fr. nR r. Rn* IMI imrllm) ) ) )
I I I I I I I I 3600-PM-WQ0008 Rev 7197 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NIA NPDES Number PA 0047325[] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) rU Outfall Number Z Intake Sampling Results -Optional (Specify Source Susquehanna River LI Upstream Background Sample Results -Optional (Specify Location of Sample El Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 [] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA Coefficienr normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses ube of block or describe another reason. Group 6 lion Used Number Concen- of Effluent -nuer Pesticides Level** Concen- Concen- of Concen- Variability Raw Mnu- ediater- By- Intake Other Petcie (jig/I) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored uct roduct Water (Explain)
IP Aldrin 10 2P Alpha BHC 10 3P Beta BHC 10 4P Gamma BHC 10 5P Delta BHC 10 6P Chlordane 10 7P 4,4'-DDT 10 8P 4,4'-DDE 10 9P 4,4'-DDD 10 10P Dieldrin 10 11P Alpha-Endosulfan 10 12P Beta-Endosulfan
'10 13P Endosulfan 10 Sulfate 14P Endrin 10 15P Endrin Aldehyde 10 16P Heptachlor 10 17P Heptachlor 10 Epoxide 10 25P Toxaphene 10 Dioxin: 2, 3, 7, 26P 8-Tetrachloro dibenzo-P Dioxin 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the hihest daily value or daily average value from the last year of data. Report both mass and concentration.
S3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
0 3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
O
* Make copies of this table and check appropriate box.  &#xfd;a ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses A or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit. CAJ-21-) ) ) )
3600-PM-WQOOOB Rev 7/97 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NPDES Number PA 0047325[] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) F] Outfall Number [ Intake Sampling Results -Optional (Specify Source Susquehanna River E Upstream Background Sample Results -Optional (Specify Location of Sample fl Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept. 1.* 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant abe Detection EPA Coefficien normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses c. of block or describe another reason. Gru in Usd Nme umber Effluentt
-Inter-Group 7 tion Used Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other 0i) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate 18P PCB-1242 20 0.2 608 <0.2 N/A <0.2 N/A 3 ttg/I N/A 19P PCB-1254 20 0.2 608 <0.2 N/A <0.2 N/A 3 pgli N/A 20P PCB-1221 20 0.2 608 <0.2 N/A <0.2 N/A 3 pg/I N/A 21P PCB-1232 20 0.2 608 <0.2 N/A <0.2 N/A 3 pg/l N/A 22P PCB-1248 20 0.2 608 <0.2 N/A <0.2 N/A 3 pg/I N/A 23P PCB-1260 20 0.2 608 <0.2 N/A <0.2 N/A 3 lug/I N/A 24P PCB-1016 20 0.2 608 <0.2 N/A <0.2 N/A 3 Pg/I N/A 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-l I I I I I I) ) ) )
I I I 3600-PM-WQO0008 Rev 7/97 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results 3. 3.a 3.b 3.c NPDES Number PA 0047325 LI Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) n] Outfall Number Z Intake Sampling Results -Optional (Specify Source Susquehanna River Ej Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.16 F] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept- 1. 2. 3. Level Present 4. Units 5, 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA --Coefficlen normally present in this discharge, check the appropriate Detec- Level Method a. Max Da!iV Value b. Average of Analyses c. of block or describe another reason. Group 8 tion Used Number I ubrEfun- nter R io ty Level8- Concen- Concen- of Concen- Variability Raw Manu- Se By- Intake Other Radioactiv L) (g/) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured S reded Prodiate ( P)_____ (V aeilfcue t re d uc Pouct Water (Explain)
IR Radioactivity:
Not Avail- Note 1 <2 N/A <2 N/A 3 pCi/I N/A (1) Alpha, able Total 2R (2) Beta, Total Note 1 <4 N/A <3 N/A pCi/I N/A 3R (3) Radium, Total Note 1 <3 N/A <2 N/A pCi/I N/A 4R (4) Radium 226, Total3 Note 1 0.72 N/A 0.58 N/A pCi/I N/A If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. Maximum Daily Value -Report the hihest daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, Intake water and background.
Make copies of this table and check appropriate box. It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.Note I- Procedures used are from Teledyne Brown Engineering are attached.
J.J-23 -) ) ) )
OUTFALL 071 COOLING TOWER BLOWDOWN NOTES 1. Cooling Tower Blowdown, Ouffall 071 samples were collected over three 24-hour periods between March and June 1999. One set of samples was collected during an unscheduled one-unit outage in March. Blowdown flows were 5.568 MGD during this outage and 11,952 MGD and 13,068 MGD respectively for the other two sampling events. Sample results for parameters having the highest concentrations in the March sample are listed under Maximum Daily Value for both concentration and mass. It is possible that the Maximum Daily Value for mass for this sample could be lower than the average mass value (lbs./day) of all three samples since the daily discharge in March was less than one half of the discharge for the other two sampling events. 2. See comments on Susquehanna River Intake parameters for 15C, 16C, 19C, 21C, 5M, 16M, 21 M, and 22M.000118 3600-PM-WQOOO8 Rev 7197 0047325 NPDES Number PA SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results U Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [ Outfall Number 071, Cooling Tower Blowdown Flows= 5.568MGD, 11.952MGD, & 13.068MGD El Intake Sampling Results -Optional (Specify Source U Upstream Background Sample Results -Optional (Specify Location of Sample U Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 2.a. 2.b. 2.c. 2.d.Maximum Daily Value -Report the highes daily value or daily average from the last year of data. Report both mass and concentration.
Maximum 30-Day Value -Determine the average of all daily values during each calendar month and report the highest average.
Long Term Average Value -The average of all values within the last year and report both mass and concentration.
Minimum of three sampling events required for process wastewater discharges and a minimum of one sampling event for all other discharges, treatment facility influent and intake water.-11-)2. LEVEL PRESENT 3. UNITS 4. 1. POLLUTANT
: a. Maximum Daily Value b. Maximum 30-Day Value c. Long-Term Avge. Value Coefficient GROUP 1 (if_ avalable) (if available)
: d. a. b. of Effluent No. of Concentration Mass Variability (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass Analyses (CV) Biochemical Oxygen 1C Demand, BOD 7 325.06 6 492.46 3 mg/I lbs/d Chemical Oxygen Demand, 2C COD 40 3987.19 31 2670.70 3 mg/I Ibs/d Total Organic Carbon, 3C TOC 8.7 404.00 8.53 723.19 3 mg/I lbs/d Total Suspended Solids, 4C TSS 53 5283.02 32.61 2916.26 3 mg/I Ibs/d Total Dissolved Solids, 5C TDS 1440 156941.45 765.33 74615.11 3 mg/I Ibs/d 6C Ammonia as N <0.1 <10.90 <0.1 <8.50 3 mg/I Ibs/d 7C Oil and Grease <2 <217.97 <2 <170.07 3 mg/I Ibs/d 8C Bromide <2 <92.87 <1.37 <104.77 3 mg/I lbs/d 9C Chlorine, Total Residual <0.05 <5.45 <0.05 <4.25 3 mg/I Ibs/d Temperature 25 Value 25 1 (&deg;C) (&deg;C) (&deg;C) 10C winter vauValue Value" Temperature 25 21.75 2(C o)(c 11C summer Value Value Value 2 (OC) (OC) (OC) 12C pH 8.6 877 3 standard standard C H Minimum Mimum units units 3600-PM-WQO0008 Rev 7/97 SECTION C -(continued)
NPDES Number PA III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 071, Cooling Tower Blowdown E] Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample U Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II A. .a. Mx D~lyVaIIA b Averanc of An-[ __a I C.Concen-I IAccept-1 I I I ..,m11 6. If you have any reason to expect the pollutant to be normally present in this discharge, check the appropriate block or describe another reason.able Detec tion Level..  (aa/l1 ass.._ ass "'aysi" tration Mass 13C Color 110.2 30 N/A 26.67 N/A 3 c.u. N/A 14C Fecal Coliform 9222D 24 N/A 8.67 N/A 3 #/100ml N/A 15C Fluoride 100 50 300.0 330 35.97 243.33 22.09 3 ,g/I Ibs/d 16C Nitrate-Nitrite (as N) 300.0 2340 108.66 1940 157.96 3 pg/I lbs/d 17C Nitrogen, Total Organic (as N) Calculation 1510 150.52 <666.67 <101.98 3 Pg/I _bs/d 18C Phosphorus (as P), Total 365.1 850 84.73 603.33 52.49 3 Pg/I Ibs/d 19C Sulfate (as SO 4) 1,000 500 300.0 215,000 23432,23 122033.3 11908.41 3 gg/I lbs/d 20C Sulfide (as S) 1,000 1,000 376.1 3000 299.04 <1666.67 <151.49 3 pg/I lbs/d 21C Sulfite (as S0 3) 2,000 2,000 377.1 <4000 <398.72 <2666.67 <236.52 3 pg/I Ibs/d 220 Surfactants 25 25 5540C 83 8.27 54 4.90 3 pg/I lbs/d Total Kjeldahl-1,000 351.4 1,200 119.62 <1,067 90.73 3 pg/I lbs/d trtNit og Nitrogen 1____ 1____ ______of Concen-Concen-luoenicient of Effluent 3. If other data is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It Is In the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.* 19 -I I I r r I 1 0047325 Pollutant Group 2 Detection Level Used (pg/I)EPA Method Number Used) )I I I I I o.. Level P'resent 4. Units tJ, a. Max Dailv I I 3600-PM-WQ0008 Rev 7/97 NPDE: SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results [] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 071, Cooling Tower Blowdown LI Intake Sampling Results -Optional (Specify Source [ Upstream Background Sample Results -Optional (Specify Location of Sample [] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 Ej New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325 3. If other data is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highst daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility Influent, Intake water and background.
Make copies of this table and check appropriate box. It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-13-Accept- 1. 2. 3. Level Present 4. Units Pollutant able 5. 6. If you have any reason to expect.the pollutant to be Det e- Detection EPA -Coefficien normally present in this discharge, check the appropriate Group 2 tec- Level Method a. Max Daily Value b. Average of Analyses c. of block or describe another reason. GropNumber Effluent contnued)
Level* Used Number Concen- Concen- of Concen- Variability Raw Manu- Inter ((tg/l(g)
Used traion Mass traton Mass Analysis tration Mass (CV) Material factued Stored mediate By- Intake Other _ M r Ma V rProduct Product Water (Explain)
IM Antimony, Total 200 10 200.7 <10 <1.09 <10 <0.85 3 pgl/ lbs/d 2M Arsenic, Total 50 3 200.7 <3 <0.33 <3 <0.26 3 Pg/I lbs/d 3M Beryllium, Total 5 2 200.7 <2 <0.22 <2 <0.17 3 pg/I lbs/d 4M Cadmium, Total 5 1 200.7 <2 <0.22 <2 <0.17 3 pg/I Ibs/d 5M Chromium, 50 3 200.7 <3 <0.33 <3 <0.26 3 Total IPg/I Ibs/d 5M Chromium, 10 10 3500D <20 <2.18 < 16.67 <1.55 3 I Hexavalent Igl__bs/d 6M Copper, Total 20 10 200.7 20 2.18 16.67 1.55 3 pg/I lbs/d 7M Lead, Total 100 3 200.7 4 0.19 <3.33 <0.27 3 pg/I Ibs/d 8M Mercury, Total 0.2 0.5 245.1 <0.5 <0.023 <0.3 <0.022 1 p3g/I lbs/d 9M Nickel, Total 40 20 200.7 <20 <2.18 <20 <1.70 3 pg/I Ibs/d 10M Selenium, Total 75 10 200.7 <10 <1.09 <10 <0.85 3 iag/I lbs/d 11M Silver, Total 10 1 200.7 <1 <0.12 <1 <0.09 3 plg/I Ibs/d 12M Thallium, Total 100 10 200.7 <10 <1.09 <10 <0.85 3 pg/I Ibs/d 13M Zinc, Total 5 10 200.7 20 1.99 16.67 1.34 3 pg/I Ibs/d 14M Cyanide, Total 20 5 335.3 <5 <0.54 <5 <0.42 3 pg/I lbs/d 14M Cyanide, Free 5 5 45001 <5 <0.54 <5 <0.42 3 Pg/I Ibs/d) ) )I 3600-PM-WQ0008 Rev 7197 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results [] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [ Outfall Number 071, Cooling Tower Blowdown E Intake Sampling Results -Optional (Specify Source E] Upstream Background Sample Results -Optional (Specify Location of Sample nI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 Ej New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the hahest daily value or daily average value from the last year of'data. Report both mass and concentration. 
(=3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration. 
(=3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box. C *It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.I I I I I I I I I Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -Coefficien normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses of block or describe another reason. tion Number Effluent In (continu Level.. Used Number Concen- Concen- of Concen- Variability Raw Manu- eBy- Intake Other ( (.g/l) -Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stoed IeProduct Water (Explain) 15M Phenols, Total 5 10 420.2 <10 1.0 <10 <0.85 3 Pg/I lbs/d 16M Aluminum, Total 100 150 200.7 700 32.51 353.33 59.53 3 plg/l lbs/d 17M Barium, Total 100 10 200.7 10 1.09 10 0.85 3 p&#xfd;g/I Ibs/d 18M Boron, Total 100 20 200.7 150 16.35 <90 <12.76 3 pIg/I lbs/d 19M Cobalt, Total 50 3 200.7 <3 <0.33 <3 <0.26 3 pg/I Ibs/d 20M Iron, Total 30 30 200.7 1960 91.02 1486.67 166.67 3 pg/I Ibs/d 21M Iron, Dissolved 30 60 200.7 300 13.93 186.67 25.51 3 pg/I lbs/d 22M Magnesium, 30 50 200.7 37,000 4,033 22,333 3,146 3 plg/I Ibs/d Total 23M Molybdenum, 100 10 200.7 36 3.92 <18.67 <3.06 3 pg/I lbs/d Total 24M Manganese, 10 3 200.7 230 25.07 187.33 19.56 3 pg/I lbs/d Total 25M Tin, Total 800 10 200.7 10 1.09 <10 <0.85 3 pg/I lbs/d 26M Titanium, Total 400 10 200.7 <10 <1.09 <10 <0.85 3 plg/I Ibs/d) ) ) \/
I I I 1 I I 3600-PM-WQ0008 Rev 7/97 NPDES SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 071, Cooling Tower Blowdown U Intake Sampling Results -Optional (Specify [ Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 1] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325) ) )Accept 1. 2. 3. Level Present 4. Units 5 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -5 aeayrao oepc h oltn ob lDetec tCoefflclent normally present in this discharge, check the appropriate Group 3 Detec- Level Method a. Max Daily Value b. Average of Analyses 0. of block or describe another reason. ton Used of Numbeb Effluent a nterr Volatile Organics Level" Used Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other (g/ (pg/I) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate S~~L!)- ----P-od- _ t Product Water (Explain) 1V Acrolein 10 20 624 <20 <2.18 <20 <1.70 3 ./I Ibs/d 2V Acrylonitrille 10 10 624 <10 <1.09 <10 <0.85 3 /~g/1 lbs/d 3V Benzene 10 1 624 <1 <0.12 <1 <0.09 3 pg/I lbs/d 5V Bromoform 10 1 624 <1 <0.12 <1 <0.09 3 pgll Ibs/d 6v Carbon 10 1 <1 <0.12 <1 <0.09 3 Tetrachloride
/1 624 < < lbs/d 7V Chlorobenzene
: 10. 1 624 <1 <0.12 <1 <0.09 3 Pll Ibs/d 8V Chlorodibromo-10 1 624 <1 <0.12 <1 <0.09 3metsndIM____
9V Chloroethane 10 2 624 <2 <0.22 <2 <0.17 3 I sd l/I bs/d 10V Tunloroethylvinyl 10 5 624 <5 <0.54 <5 <0.42 3 Ag/I I _bs/d 11V Chloroform 10 1 624 <1 <0.12 <1 <0.09 3 lsg/I Ibs/d 12V Dichlorobromo-10 1 624 <1 <0.12 <1 <0.09 3 l _____ methane pl b/ 14V 1,1-Dichloroethane 10 1 624 <1 <0.12 <1 <0.09 3 pg/I Ibs/d 15V 1,2-Dichloroethane 10 2 624 <2 <0.22 <2 <0.17 3 Ibg/I dbs/d 16V ethylene 10 1 624 <1 <0.12 <1 <0.09 3 l Ibs/d 17V ,2aDichloro 10 2 624 <2 <0.22 <2 <0.17 3 .g/I Ibs/d 1,3-DIchlIorO 18V propylene 10 2 624 <2 <0.22 <2 <0.17 3 .g/I lIbs/d 19V Ethylbenzene 10 1 624 <1 <0.12 <1 <0.09 3 lbs/d <1 ~ ~ <0._ _ _ _1<.0 g/ b/ If ~ nfhnrs y.nf, Ia** .OO 114 Lkm 1~ ~ MAOI AIUWIiYU ~Ui eemn i,.o iao, o *vo j -~l c~t=t .1, ei paCst.yea!
UI Udata ma;'y be used~ to uetermine
,3a, JD, ,3c, and 5. 3.a Maximum Daily Value -Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility Influent, intake water and background.
Make copies of this table and check appropriate box. It is In the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements In the finalNPDES permit.-15-q 3600-PM-WQOOO8 Rev 7/97 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES NPDES Number PA 0047325 3. Analyses Results LI Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 071, Cooling Tower Blowdown [ Intake Sampling Results -Optional (Specify Source [ Upstream Background Sample Results -Optional (SpecifyLocation of Sample E] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 0 New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It is In the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses 0 or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.I I I I I I I I t Accept. 1. 2. 3. Level Present 4. Units Pollutan t able 5. 6. If you have any reason to expect the pollutant to be P u t e Detection EPA .Coefficlent normally present in this discharge, check the appropriate Group 3 Detec- Level Method a. Max Daely Value b. Average of Analyses of block or describe another reason. Gton U Number Effluent Inter Volatile Organics LevelNumber Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other (continued) (g/ ) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate -Pgo --Product Product Water (Explain) 20V Methyl Bromide 10 3 624 <3 <0.33 <3 <0.26 3 ulg/I Ibs/d 21V Methyl Chloride 10 3 624 <3 <0.33 <3 <0.26 3 ug/I Ibs/d 22V Methylene 10 2 624 <2 <0.22 <2 <0.17 3 lag/I Ibs/d Chloride 23V 1,1,2,2-Tetra-10 1 624 <1 <0.12 <1 <0.09 3 jig/I lbs/d chloroethane I 24V Tetrachloro-10 1 324 < 1 <0.12 < 1 <0.09 3 ug/l Ibs/d ethylene 25V Toluene 10 1 624 <1 <0.12 <1 <0.09 3 ug/I Ibs/d 26V 1,2-Trans-Di-10 1 624 <1 <0.12 <1 <0.09 3 Aull Ibs/d chloroethylene I 27V 1,1,1-Trichloro-10 1 624 <1 <0.12 <1 <0.09 3 pg/I Ibs/d ethane 28V 1,1,2-Trichloro-10 2 624 <2 <0.22 <2 <0.17 3 pig/I lbs/d ethane ethylene 31V Vinyl Chloride 10 2 624 <2 <0.22 <2 <0.17 3 pg/i lbs/d) ) )I i I i I i I " -" I 3600-PM-WQOOO8 Rev 7/97 NPDEc SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results [ Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [ Outfall Number [ Intake Sampling Results -Optional (Specify Source 071, Cooling Tower Blowdown El Upstream Background Sample Results -Optional (Specify Location of Sample [ Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 [ New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325) )Pollutant Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection-EPA -Coefficien normally present in this discharge, check the appropriate Group 4 Detec- Level Method a. Max Daily Value b. Average of Analyses C. of block or describe another reason. tion Number Effluent Inter Acid-Fraction Level-N Concen- Concen- of Concen- Variability R Manu- t ediate By- Intake Other Organics (lg/I) (ig/I) Used tration Mass tration Mass Analysis tration Mass (CV) Materia factured -r d Product Water (Explain) 1A 2-Chlorophenol 10 10 625 <10 <1.09 <10 <0.85 3 pg/I Ibs/d 2A 2,4-Dichloro-10 10 625 <10 <1.09 <10 <0.85 3 pg/I Ibs/d phenol 3A 2,4-Dimethyl-10 10 625 <10 <1.09 <10 <0.85 3 pg/I lbs/d ___ henol_________________
4A 4,6-Dinitro-o-10 10 625 <10 <1.09 <10 <0.85 3 Pg/I Ibs/d Cresol 5A 2,4-Dinitro-50 15 625 <15 <1.63 <15 <1.27 3 plg/I Ibs/d phenol 6A 2-Nltrophenol 10 10 625 <10 <1.09 <10 <0.85 3 pg/I Ibs/d 7A 4-Nitrophenol 50 10 625 <10 <1.09 <10 <0.85 3 pjg/I lbs/d 8A P-Chloro-m-10 10 625 <10 <1.09 <10 <0.85 3 pg/I lbs/d Cresol 9A Pentachloro-50 25 625 <25 <2.72 <25 <2.12 3 plg/I lbs/d phenol 10A Phenol 10 10 625 <10 <1.09 <10 <0.85 3 pg/I lbs/d ,,A 2,4,6-Trichloro-10 10 625 <10 <1.09 <10 <0.85 3 pjg/I Ibs/d Sphenol-_
I_ ---3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, Intake water and background.
* Make copies of this table and check appropriate box. I** t Is In the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses o or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3600-PM-WQ0008 Rev 7/97 NPDE, SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) Z Outfall Number 071, Cooling Twoer Blowdown F1 Intake Sampling Results -Optional (Specify Source [] Upstream Background Sample Results -Optional (Specify Location of Sample E] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 n New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325 Pollutant Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection EPA --Coefficient normally present in this discharge, check the appropriate Group 5 Detec- Level Method a. Max Daily Value b. Average of Analyses .of block or descrbe another reason. Base-Neutral tion Number Effluent Inter Fraction Level- Ue N Concenoncen-of Concen- Variability Raw ManI- B Intake Other Organics 441g/I) (I.g/I) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stared mediate Product Water (Explain) 18 Acenaphthene 10 3 625 <3 <0.33 <3 <0.26 3 jig/I lbs/d 2B Acenaphthylene 10 3 625 <3 <0.33 <3 <0.26 3 Pg/I lbs/d 3B Anthracene 10 2 625 <2 <0.22 <2 <0.17 3 Pg/I Ibs/d 4B Benzidine 50 20 625 <20 <2.18 <20 <1.70 3 jig/I Ibs/d 5B Benzo (a) 10 2 625 <2 <0.22 <2 <0.17 3 Anthracene Pg/I Ibs/d 6B Benzo (a) Pyrene 10 2 625 <2 <0.22 <2 <0.17 3 jig/I lbs/d 71 3,4-Benzo-10 2 625 <2 <0.22 <2 <0.17 3 fluoranthene
__g/I Ibs/d 8B Benzo (ghi) 10 2 625 <2 <0.22 <2 <0.17 3 jg/I lbs/d Pervlene _g/IIbs/d 98 Benzo (k) 10 5 625 <5 <0.54 <5 <0.42 3 jig/I lbs/t Fluoranthene I ._____ 10B ethoxy) Methaneloro-10 3 625 <3 <0.33 <3 <0.26 3 Pjg/I lbs/d 118 Bis (2-Chloro-10 3 625 <3 <0.33 <3 <0.26 3 jig/I Ibs/d 11B ethy/) Ether __g/_ Ibsd 128 Bis (2-Chloro-10 2 625 <2 <0.22 <2 <0.17 3 jg/I lbs/t 12B isopropy/)
Ether __g/I Ibs/d 13B Bis (2-Ethyl-10 2 625 <2 <0.22 <2 <0.17 3 /d 13 h hexy/) Phthalate pg/I Ibs/d 14B 4-Bromophenyl 10 3 625 <3 <0.33 <3 <0.26 3 jig/I lbs/d _ Phenyl Ether ___ I I _ 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, Intake water and background.
* Make copies of this table and check appropriate box.  ** It Is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.AI I) ) ) )I I i, I I I I I I( I I I I 3600-PM-WQ0008 Rev 7/97 NPDES SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [ Outfall Number 071, Cooling Tower Blowdown [ Intake Sampling Results -Optional (Specify Source fl Upstream Background Sample Results -Optional (Specify Location of Sample E] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 [] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325) )Pollutant Accept- 1. 2. 3. Level Present 4. Units 5, 6. If you have any reason to expect the pollutant to be able Detection EPA Coefficlen normally present in this discharge, check the appropriate Group 5 Detec- Level Method a. Max Daily Value .b. Average of Analyses of block or descbe another reason. r 1 6 ~~~~NumcberEfl et .I er Base-Neutral tion Used Numbeo Efuent bo or dsi a nother ra-son. Fraction Level** Concen- ConcConcen-oncen- Variability Raw Manu- By- Intake Organics 440 (lgI) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate -4g/ ----Product Product Water (Explain) 15B Butyl Benzyl 10 5 625 <5 <0.54 <5 <0.42 3 gI Ibsld 16B__ Phthalate 1 5 6<5 04 5 02 3 g/I Ibs/d 16B 2-Chloronaphthatene 10 5 625 <5 <0.54 <5 <0.42 3 pgI lbs/d 4-Chlorophenyl 10 5 625 <5 <0.54 <5 <0.42 3 gI b/ 17B Phenyl Ether _g/I Ibs/d 18B Chrysene 10 2 625 <2 <0.22 <2 <0.17 3 g/I Ibs/d Dibenzo (a, h) 10 2 625 <2 <0.22 <2 <0.17 3 19B Anthracene .Ig/I Ibs/d 20B 1,2-Dichlorobenzene 10 5 625 <5 <0.54 <5 <0.42 3 Ibs/d 21B 1,3-Dichorobenzene 10 5 625 <5 <0.54 <5 <0.42 3 pg/I Ibs/d 22B 1,4-Dichlorobenzene 10 5 625 <5 <0.54 <5 <0.42 3 lg/I bs/d 23B 3.3'-Dichloro-50 5 625 <5 <0.54 <5 <0.42 3 benzidine .g/5 Ibs/d 24B Diethyl Phthalate 20 10 625 <10 <1.09 <10 <0.85 3 g ubs/d 25B Dimethyl Phthalate 20 10 625 <10 <1.09 <10 <0.85 3 Pg/I lbs/d Di-N-Butyl 20 5 625 <5 <0.54 <5 <0.42 3 268 Phthalate
_g/_I Ibs/d 27B 2,4-Dinitrotoluene 10 2 625 <2 <0.22 <2 <0.17 3 4g/I lbs/d 28B 2,6-Dinitrotoluene 10 2 625 <2 <0.22 <2 <0.17 3 pg/I Ibs/d 29B Di-N-Octyl Phthalate 20 5 625 <5 <0.54 <5 <0.42 3 Pg/I lbs/d 30B 1z2-Diphenylhydra-10 5 625 <5 <0.54 <5 <0.42 3 pg/I Ibs/d zine (as______
_____________________
______ _______________
'Azovenzene)
: 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box.  ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results El Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) [ Outfall Number 071, Cooling Tower Blowdown E] Intake Sampling Results -Optional (Specify Source El Upstream Background Sample Results -Optional (Specify Location of Sample El Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 [] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325 Pollutant Accept. 1. 2. 3. Level Present 4 Units 5 6 If you have any reason to expect the pollutant to be able Detection EPA Coefficient normally present In this discharge, check the appropriate Deeto P __c___________________
of block or describe another reason. Group 5 Detec- Level Method a. Max Daly Value b. Average of Analyses o bumbe* Eu --reason. Base-Neutral tion Usedmumee EffluentIer Fraction Levelt- Concen- Concen- of Concen- Variability Raw Manu- m Intake Other Organics (i.g/I ) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Prod t Product Water (Explain) 31B Fluoranthene 10 2 625 <2 <0.22 <2 <0.17 3 ljg/I Ibs/d 32B Fluorene 10 3 625 <3 <0.33 <3 <0.26 3 lug/I Ibs/d 33B Hexachloro-10 2 625 <2 <0.22 <2 <0.17 3 Pg/I lbs/d benzene 34B Hexachloro-10 5 625 <5 <0.54 <5 <0.42 3 pg/i Ibs/d butadiene g/ Ibd 35B Hexachloro-10 10 625 <10 <1.09 <10 <0.85 3 cvclopentadiene 10g/I Ibs/d 36B Hexachloro-10 5 625 <5 <0.54 <5 <0.42 3 Pgi Ibs/d ethane __g/IIbs/d 37B Indeno (1,2,3-cd) 10 2 625 <2 <0.22 <2 <0.17 3 pg/I Ibs/d Pyrene __g/IIs/d 38B Isophorone 10 3 625 <3 <0.33 <3 <0.26 3 Fg/I Ibs/d 39B Naphthalene 10 3 625 <3 <0.33 <3 <0.26 3 P*g/I Ibs/d 40B Nitrobenzene 10 3 625 <3 <0.33 <3 <0.26 3 pg/I lbs/d 41B N-Nitrosodl-20 3 625 <3 <0.33 <3 <0.26 3 pg/I lbs/d methylamine g/ Ib/ 42B N-Nitrosodi-N-20 3 625 <3 <0.33 <3 <0.26 3 pg/I lbs/d Propylamine
_ _g/I_ _bs/d 43B N-Nitrosodi-20 3 625 <3 <0.33 <3 <0.26 3 pg/I lbs/d p Dhenylamine Ig/I__bs/d 44B Phenanthrene 10 3 625 <3 <0.33 <3 <0.26 3 pg/I lbs/d 45B Pyrene 10 2 625 <2 <0.22 <2 <0.17 3 lag/I lbs/d 46B 1,2,4-Trichloro-10 5 625 <5 <0.54 <5 <0.42 3 pg/I lbs/d benzene II/I Ibs/ I I I I I I 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
0 3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
S3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
Make copies of this table and check appropriate box. It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.I I -I I I I I I I I I) ) ) )1 1 1 I I I I I I I I 3600-PM-WQOOO8 Rev 7/97 NPDES Number PA 0047325 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NIA -- Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) Z Outfall Number 071, Cooling Tower Blowdown El Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample [ Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II)Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -Coefficienl normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses c. of block or describe another reason. Group 6_ _ _ ~Number Effluent -n-e Group 6 lion Used Number Cncn- Concen- of Concen- VariabilityRr Pesticides Level** Raw Manu- By- Intake Other Pestici(dieg/I)
Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate /I Product Product Water (Explain)
IP Aldrin 10 0 2P Alpha BHC 10 3P Beta BHC 10 4P Gamma BHC 10 5P Delta BHC 10 6P Chlordane 10 7P 4,4'-DDT 10 8P 4,4'-DDE 10 9P 4,4'-DDD 10 l0P Dieldrin 10 11P Alpha-Endosulfan 10 12P Beta-Endosulfan 10 13P Endosulfan 10 Sulfate 10 14P Endrin 10 15P Endrin Aldehyde 10 16P Heptachlor 10 17P Heptachlor 10 Epoxide 10 25P Toxaphene 10 Dioxin: 2, 3, 7, 26P 8-Tetrachloro dibenzo-P Dioxin 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
0 3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration. 3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, Intake water and background.
Make copies of this table and check appropriate box.  ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3600-PM-WQOOO0 Rev 7/97 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NPDES Number PA 0047325 Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 071, Cooling Tower Blowdown E] Intake Sampling Results -Optional (Specify Source [] Upstream Background Sample Results -Optional (Specify Location of Sample E] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 F1 New Discharge (Describe basis for information presented, see Instructions for Section C, Part II__) )Accept. 1. 2. 3. Level Present 4, Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA ' Coefficient normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Averane of Analyses c. of block or describe another reason. GroupD7 lion Usd NmeN~umber Effluent ---Inter?- --Grou Level- Used Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other (p./I) (g/) Use tration Mass tration Mass Analysis tration Mass (CV) Material factured St Product Product Water (Explain) 18P PCB-1242 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 jg/I lbs/d 19P PCB-1254 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 pg/I lbs/d 20P PCB-1221 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 pg/I Ibs/d 21P PCB-1232 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 pg/I Ibs/d 22P PCB-1248 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 pg/I Ibs/d 23P PCB-1 260 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 pg/I lbs/d 24P PCB-1016 20 0.2 608 <0.2 <0.022 <0.2 <0.016 3 Pjg/I lbs/d 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the hihest daily value or dally average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
Make copies of this table and check appropriate box. It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit. C I I _- -I I I I I I I i I)I I I I I I I I 3600-PM-WQOOO8 Rev 7/97 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NPDES Number PA 0047325 F] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) 0 Outfall Number 071, Cooling Tower Blowdown E] Intake Sampling Results -Optional (Specify Source [] Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 3. 3.a 3.b 3.c Accept- 1 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA .Coefficient normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses c. of block or describe another reason. Group 8 tion Used Number Number Effluent Inter Radioactivity Ledel- Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other WW(/I) W/1) Use tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate Product Water (Explain) 1R Radioactivity:
Not Avail- Note 1 <5 EQ N/A <3 EQ N/A 3 pCi/I N/A (1) Alpha, able Total 2R (2) Beta, Total Note 1 7.2 EQ N/A <3.3 EQ N/A 3 pCi/I N/A 3R (3) Radium, Total Note 1 <3 EQ N/A <2.3 EQ N/A 3 pCi/I N/A 4R (4) Radium 226, Total Note 1 1.7 EQ N/A <7.7 E-11 N/A 3 pCi/I N/A If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
Make copies of this table and check appropriate box. It Is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.Note I -Procedures used are from Teledyne Brown Engineering.
Procedures precede Intake sampling results.-23 -) ) ) )
OUTFALL 072, SERVICE AND ADMINISTRATION BUILDING LOW VOLUME SUMP NOTES No comments 000132 I I I I I I 3600-PM-WQOOO8 Rev 7/97 NPDES Number PA 0047325 SECTION C -(continued)
Ill. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results [] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 072, Service and Administration Building Low Volume Waste Sump Flow=0.01MGD El Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 2.a. 2.b. 2.c. 2.d.) ) ) )Maximum Daily Value -Report the hJghes daily value or daily average from the last year of data. Report both mass and concentration, Maximum 30-Day Value -Determine the average of all daily values during each calendar month and report the highest average.
Long Term Average Value -The average of all values within the last year and report both mass and concentration.
Minimum of three sampling events required for process wastewater discharges and a minimum of one sampling event for all other discharges, treatment facility influent and intake water.-11 -2. LEVEL PRESENT 3. UNITS 4. 1. POLLUTANT
: a. Maximum Daily Value b. Maximum 30-Day Value c. Long-Term Avge. Value Coefficient GROUP I a._____ Maximum_ Dalaue(faailabl) (if available)
: d. a. b. of Effluent GRO P (f aaiabe) ifavilale .No. of Concentration Mass Variability (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass Analyses (CV) Biochemical Oxygen 1C Demand, BOD Chemical Oxygen Demand, 2C COD <15 <1.25 <15 <1.25 1 mg/I lbs/d Total Organic Carbon, 3C TOC 2.5 0.21 2.5 0.21 1 mg/I Ibs/d 4C Total Suspended Solids, 5 0.42 5 0.42 1 mg/I lbs/d Total Dissolved Solids, 5C TDS 210 17.51 210 17.51 1 mg/I lbs/d 6C Ammonia as N 7C Oil and Grease <2 <0.17 <2 <0.17 1 mg/I lbs/d 8C Bromide 9C Chlorine, Total Residual Temperature l0C winter Value Value Value (&deg;C) (OC) (&deg;C) Temperature IIC summer Value Value Value (&deg;C) (&deg;C) (&deg;C) 12C pH Minimum Maximum units units 3600-PM-WQ0008 Rev 7197 SECTION C -(continued)
II1. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyes Results NPDES Number PA 0047325 R Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) Z Outfall Number 072, Service and Administrative Building Low Volume Waste Sump F] Intake Sampling Results -Optional (Specify Source [:] Upstream Background Sample Results -Optional (Specify Location of Sample [] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 [] New Discharge (Describe basis for Information presented, see Instructions for Section C, Part II)Accept. 1 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection EPA Coefficient normally present in this discharge, check the appropriate Pollutant LDetec-.
tion Level Method a. Max Daily Value b. Average of Analyses Nub of block or describe another reason. Level Used Number Concen- Varabity Raw Manu- Intake Other Levgel- Used-o Vrablt Stored mediarte ~- Itk (__g/I)_ Use tratlon Mass tration Mass Analysis tration Mass (CV) Material factured product Product Water (Explain) 13C Color 14C Fecal Coliform 15C Fluoride 100 16C Nitrate-Nitrite 100 353.2 390 32.53 390 32.53 1 &#xfd;.gll lbs/d (as N) 17C Nitrogen, Total Organic (as N) 18C Phosphorus
_ (as P), Total 19C Sulfate (as S0 4) 1,000 20C Sulfide (as S) 1,000 21C Sulfite (as S0 3) 2,000 22C Surfactants 25 I (MBAS) I 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the hiahest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box. It Is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.1 1 "^- I I I I I I I I I i I I I I I 3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
Ill. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results El Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 072, Service and Administration Building Low Volume Waste Sump LI Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 3. 3.a 3.b 03.c NPDES Number PA Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA Coefficient normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average .f Analyses cb of block or describe another reason. NumbeoUsed Number Cc Cnen- of Effluent Inter- By- Intake other Cencen- Concen- of Concen- Variability Raw Manu- mediate (cntnud Usdl*tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored Product By-d IntakeWOthr 1M Antimony, Total 200 2M Arsenic, Total 50 3M Beryllium, Total 5 4M Cadmium, Total 5 5m Chromium, 50 5 200.7 <5 <0.42 <5 <0.42 1 pg/I Ibs/d Total I 5M Chromium, 10 10 3500D <10 <0.83 <10 <0.83 1 pg/I lbs/d Hexavalent I 6M Copper, Total 20 7M Lead, Total 100 8M Mercury, Total 0.2 9M Nickel, Total 40 10M Selenium, Total 75 11M Silver, Total 10 12M Thallium, Total 100 13M Zinc, Total 5 14M Cyanide, Total 20 14M Cyanide, Free 5 If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
Make copies of this table and check appropriate box. It is In the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-13-0047325) 3600-PM-WQOOO8 Rev 7/97 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results NPDES Number PA 0047325[] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 072, Service and Administration Building Low Volume Waste Sump [J Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 F] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept. 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA Coefficient normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Averae fAnalyses
-of block or describe another reason. Group 2 tion Levd Numethod a.NMumber al Effluent --A (continued)
Level USed NumberU Concen- Concen- Of Concen- Variability Raw Manu- ate B Intake Other Pel t 5d tration Mass tration Mass Analysis tratlon Mass (CV) Material factured StoredP t Product Water (Explain) 15M Phenols, Total 5 16M Aluminum, Total 100 17M Barium, Total 100 18M Boron, Total 100 50 200.7 60 5.00 60 5.00 1 pgl/ lbs/d 19M Cobalt, Total 50 20M Iron, Total 30 21M Iron, Dissolved 30 22M Magnesium, 30 Total 23M Molybdenum, 100 10 200.7 12 1.00 12 1.00 1 pIgl/ lbs/d Total 24M Manganese, 10 Total 25M Tin, Total 800 26M Titanium, Total 400 3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highest daily value or daily average value from the last year of data, Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility Influent, Intake water and background.  .C, Make copies of this table and check appropriate box.  ** It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.  -J ! ! I [ I t I) ) ) )
OUTFALL 073, UNIT 1 TURBINE BUILDING LOW VOLUME SUMP NOTES A sample was collected from Outfall 073 and not Outfall 074, Unit 2 Turbine Building Sump since their discharges are similar.000137 NPDES Number PA 0047325 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 073, Unit I Turbine Building Low Volume Sump Flow=0.0081 MGD E Intake Sampling Results -Optional (Specify Source E] Upstream Background Sample Results -Optional (Specify Location of Sample []Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 2.a. 2.b. 2.c. 2.d.Maximum Daily Value -Report the hig.hes daily value or daily average from the last year of data. Report both mass and concentration.
Maximum 30-Day Value -Determine the average of all daily values during each calendar month and report the highest average.
Long Term Average Value -The average of all values within the last year and report both mass and concentration.
Minimum of three sampling events required for process wastewater discharges and a minimum of one sampling event for all other discharges, treatment facility influent and intake water.I I I I I I I I) ) )2. LEVEL PRESENT 3. UNITS 4 1. POLLUTANT
: a. Maximum Daily Value b. Maximum 30-Day Value c. Long-Term Avge. Value Coefficient GROUP 1 ___(if_ av~al labj) (if available)
: d. a. b. of Effluent No. of Concentration Mass Variability (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass Analyses (CV) Biochemical Oxygen 1C Demand, BOD Chemical Oxygen Demand, 2C COD 41 2.77 41 2.77 1 mg/I lbs/d Total Organic Carbon, 3C TOC 7.6 0.51 7.6 0.51 1 mg/I Ibs/d 4C Total Suspended Solids, <5 <0.34 <5 <0.34 1 mg/I lbs/d 4C TSS Total Dissolved Solids, 5C TDS 711 48.03 711 48.03 1 mg/I lbs/d 6C Ammonia as N 7C Oil and Grease <2 <0.14 <2 <0.14 1 mg/I lbs/d 8C Bromide 9C Chlorine, Total Residual Temperature 10C winter Value Value Value (0C) (0C) (0c) Temperature 11C summer Value Value Value (0C) (Oc) (0C) 120 pH 7.60 7.87 4 standard standard I I Minimum Maximum units units 3600-PM-WQOOOB Rev 7/97 I I 1 3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NPDES Number PA 0047325 Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A 10) [ Outfall Number 073, Unit I Turbine Building Low Volume Sump E Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample [ Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 [ New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 3. 3.a 3.b 3.c Accept- 1. 2. 3. Level Present 4. Units S. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -Coefficient normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses c. of block or describe another reason. Gru in Ue ubrINumber Effluent Inter- By Inke Otr Group 2 tion Used Number Concen- Concen- of Concen- Variability Raw Manu- mediate By Intake LeveW* Variabilitynaysi W/I) W/0 Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Sto Product Product Water (Explan) 13C Color 14C Fecal Coliform 15C Fluoride 100 16C Nitrate-Nitrite 0.10 353.2 170 0.01 170 0.01 1 pg/I lbs/d (as N) 17C Nitrogen, Total Organic (as N) 18C Phosphorus (as P), Total I 19C Sulfate (as S0 4) 1,000 20C Sulfide (as S) 1,000 21C Sulfite (as S0 3) 2,000 22C Surfactants 25 (MBAS)If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. Maximum Daily Value -Report the highos daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility Influent, intake water and background.
Make copies of this table and check appropriate box. It is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.-12-) ) ) )
OUTFALL 075 PEACH STAND POND NOTES A sample was collected from Outfall 075 representing all three stormwater outfalls.
The other outfalls are Outfall 070, S-2 Sedimentation Pond and Outfall 080, C-1 Pond.000140 NPDES Number PA 0047325 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results F1 Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 075, Peach Stand Pond Stormwater Runoff Flow=0.279417MGD E] Intake Sampling Results -Optional (Specify Source F1 Upstream Background Sample Results -Optional (Specify Location of Sample F1 Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 LI New Discharge (Describe basis for information presented, see Instructions for Section C, Part II 2. LEVEL PRESENT 3. UNITS 4. 1. POLLUTANT
: a. Maximum Daily Value b. Maximum 30-Day Value c. Long-Term Avge. Value Coefficient GROUP 1 xmm i u (if available) (if.. available
: d. a. b. of Eff luent No. of Concentration Mass Variability (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass Analyses (CV) Biochemical Oxygen 4 9.32 4 9.32 1g/I Ibs/d 1C Demand, BOD SChemical Oxygen Demand, <2 <4.66 <2 <4.66 1ig/I Ibs/d 2C COD Total Organic Carbon, 3C TOC Total Suspended Solids, 1 233 4C TSS <1 <2.33 1 Vg/l lbs/d Total Dissolved Solids, 5C TDS 6C Ammonia as N 0.12 0.28 0.12 0.28 1 lbs/d 7C Oil and Grease <2 <4.66 <2 <4.66 1 Pgg/I Ibs/d 8C Bromide 9C Chlorine, Total Residual 0 0 0 1 PIg/I Ibs/d Temperature 1 (&deg;C) (&deg;C) (OC) 100 winter Value Value Value 1(0 0)(0 110Temperature 15 Value 15 1 (_C) (&deg;C) (&deg;c) summer Value Value 12C p77standard standard 7.67 7.I 7 1 units units 120 pH Minimum Maximum j ______ untuis Maximum Daily Value -Report the highes daily value or daily average from the last year of data. Report both mass and concentration.
Maximum 30-Day Value -Determine the average of all daily values during each calendar month and report the highest average.
Long Term Average Value -The average of all values within the last year and report both mass and concentration.
Minimum of three sampling events required for process wastewater discharges and a minimum of one sampling event for all other discharges, treatment facility influent and intake water.-11 -a. b. dc .d.I I I I 3600.PM-WQ0008 Rev 7/97) ) ) )
3600-PM-WQO0008 Rev 7/97 SECTION C -(continued)
IIl. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results NPDES Number PA 0047325 r] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 075, Peach Stand Pond Stormwater Runoff Flow=0o.279417MGD
[ Intake Sampling Results -Optional (Specify Source LI Upstream Background Sample Results -Optional (Specify Location of Sample LI Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 E] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutan able Detection EPA -Coefficieni normally present in this discharge, check the appropriate t Detec- Level Method a. Max DaIly Value b. Average of Analyses cb of block or describe another reason. Gru 2UedrNumber Effluent nter Group 2 Leve Used Number Concen- Concen- of Concen- Variability Raw Manu- By- Intake Other (g/lI) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored mediate ________ Product Product Water (Explain) 13C Color 14C Fecal Coliform 9222D 1,700 N/A 1,700 N/A 1 #/100ml N/A 15C Fluoride 100 16C Nitrate-Nitrite 500 300.0 1,150 2.67 1,150 2.67 1 pg/I lbs/d (as N) 17C Nitrogen, Total Organic (as N) 18C Phosphorus 100 365.1 <100 <0.23 <100 <0.23 1 pig/I lbs/d (as P), Total 19C Sulfate (as SO 4) 1,000 20C Sulfide (as S) 1,000 21C Sulfite (as S0 3) 2,000 22C Surfactants 25 (MBAS) Total Kjeldahl-1,000 351.4 <1,000 <2.33 <1,000 <2.33 1 pg/I lbs/d -_1_ Nitrogen I I I I I 1 11 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box. O* It is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses O or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.  [ [LII!I t I I I ! [) ) ) )
OUTFALL 079 SEWAGE TREATMENT PLANT NOTES No comments 000143 3600-PM-WQOOO8 Rev 7197 NPDES Number PA 0047325 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES 3. Analyses Results El Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) [ Outfall Number 079, Sewage Treatment Plant Flow=0.01718MGD
[] Intake Sampling Results -Optional (Specify Source El Upstream Background Sample Results -Optional (Specify Location of Sample El Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A.10 E] New Discharge (Describe basis for Information presented, see Instructions for Section C, Part II 2.a. 2.b. 2.c. 2.d.) )Maximum Daily Value -Report the highes daily value or daily average from the last year of data. Report both mass and concentration.
Maximum 30-Day Value -Determine the average of all daily values during each calendar month and report the highest average.
Long Term Average Value -The average of all values within the last year and report both mass and concentration.
Minimum of three sampling events required for process wastewater discharges and a minimum of one sampling event for all other discharges, treatment facility influent and intake water.II -II 1 1 1 1 1 1 2. LEVEL PRESENT 3. UNITS 4. 1. POLLUTANT
: a. Maximum Daily Value b. Maximum 30-Day Value c. Long-Term Avge. Value d Coefficient GROUP 1 (i vilbe (if available)
: d. a. b. of Effluent No. of Concentration Mass Variability (1) Concentration (2) Mass (1) Concentration (2) Mass (1) Concentration (2) Mass Analyses (CV) Biochemical Oxygen IC Demand, BOD 11 1.58 11 1.58 1mg/I bs/d Chemical Oxygen Demand, 2C COD Total Organic Carbon, 3C TOC Total Suspended Solids, 4C TSS 7 1.00 7 1.00 1 mg/I Ibs/d Total Dissolved Solids, 5C TDS 6C Ammonia as N 25 3.58 25 3.58 1 mg/I Ibs/d 7C Oil and Grease 8C Bromide 9C Chlorine, Total Residual 0.02 0.003 0.003 0.0005 14 mg/I lbs/d Temperature 10C winter Value Value Value (OC) (&deg;C) (&deg;C) Temperature 23 Value 21.75 6 (0 C) (&deg;0) (00) summer Value Value I 2C pH 7.40 standard standard _C pH 1Minimum Maximum units units S I I t I NPDES Number PA 3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*0047325 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A. 10) Z Outfall Number 079, Sewage Treatment Plant F- Intake Sampling Results -Optional (Specify Source El Upstream Background Sample Results -Optional (Specify Location of Sample El Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 [] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Accept- 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be able Detection EPA -Coefficient normally present in this discharge, check the appropriate Polutant Detec- Level Method a. Max Daily Value b. Average of Analyses c of block or describe another reason. Levl 2Number Effluent Group 2 Ltion Used Number Concen- Concen- of Concen- Variability Raw Menu- to mediate By- Intake Orher Level' (g/I) Used n te Product Water Explain) (4g/0 tration Mass tration Mass Analysis tration Mass (CV) Material factured StredProductP 13C Color 14C Fecal Coliform 9222D 11 N/A 11 N/A I #/100ml N/A 15C Fluoride 100 16C Nitrate-Nitrite 100 353.2 4,790 0.69 4,790 0.69 1 pg/I lbs/d (as N) I 17C Nitrogen, Total 1,000 Calculation 3,100 0.44 3,100 0.44 1 plg/I lbs/d Organic (as N) I I 18C Phosphorus 100 365.1 9,760 1.40 9,760 1.40 1 pg/I lbs/d _ (as P), Total I 19C Sulfate (as SO 4) 1,000 3,000 375.4 105,000 15.04 105,000 15.04 1 pg/I lbs/d 20C Sulfide (as S) 1,000 21C Sulfite (as S0 3) 2,0001 22C Surfactants 25 (MBAS) 000 351.4 28,100 _ 4.03 1 _____ Total Kjeldahl-1,000 351.4 28,100 4.03 28,100 4.03 1 pg/I lbs/d -Nitrogen I -I I _ 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the hahest daily value or daily average value from the last year of data. Report both mass and concentration.
3 b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
3.0 A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
* Make copies of this table and check appropriate box. N-- ** It is In the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.  ) ) ) )
3600-PM-WQO0008 Rev 7/97 NPDEc SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 079, Sewage Treatment Plant [- Intake Sampling Results -Optional (Specify Source L] Upstream Background Sample Results -Optional (Specify Location of Sample F] Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 [] New Discharge (Describe basis for information presented, see Instructions for Section C, Part II iNumber PA 0047325) ) )Accept- 1 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -Coefficlent normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Average of Analyses c- of block or describe another reason. Group 2 tion Used NumberNumber Effluent Inte (continued)
Levelu U NUe Concen- Concen- of Concen- Variability Raw Manu- mediate Y. Intake Other (oln e W Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stored Product Product Water (Explain) 1M Antimony, Total 200 2M Arsenic, Total 50 3M Beryllium, Total 5 4M Cadmium, Total 5 5M Chromium, 50 Total 5M Chromium, 10 Hexavalent 6M Copper, Total 20 10 200.7 10 0.0014 10 0.0014 1 jug/I 7M Lead, Total 100 6 200.7 <6 <0.0009 <6 <0.0009 1 gig/I 8M Mercury, Total 0.2 9M Nickel, Total 40 10M Selenium, Total 75 11M Silver, Total 10 12M Thallium, Total 100 13M Zinc, Total 5 20 200.7 70 0.01 70 0.01 1 Pg/I 14M Cyanide, Total 20 14M Cyanide, Free 5 3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
03.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
S3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, Intake water and background.
Make copies of this table and check appropriate box. It is in the applicant's interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.I I I I I I I "^ I 3600-PM-WQ0008 Rev 7197 NPDES SECTION C -(continued)
III. REQUIRED AND OPTIONAL ANALYSES*
: 3. Analyses Results E] Outfall Sampling Results (Locate Sampling Point on Line Drawing Required by Question A.10) Z Outfall Number 079, Sewage Treatment Plant [] Intake Sampling Results -Optional (Specify E] Upstream Background Sample Results -Optional (Specify Location of Sample El Treatment Facility Influent Sampling Results (Locate Sampling Point on Line Drawing required by Question A. 10 [ New Discharge (Describe basis for information presented, see Instructions for Section C, Part II Number PA 0047325 Accept 1. 2. 3. Level Present 4. Units 5. 6. If you have any reason to expect the pollutant to be Pollutant able Detection EPA -Coefficient normally present in this discharge, check the appropriate Detec- Level Method a. Max Daily Value b. Averane of Analyses ub of block or describe another reason. Group 3 tion Used Number Efletnter Nme Effluent -___ ______ Volatile Organics Level Used Number Concen- of Concen- Variability Raw Manu- So dIntake -Other V t r/Ioi (jig/I) Used tration Mass tration Mass Analysis tration Mass (CV) Material factured Stor mediate Pd ProductY Water (Explain) 1V Acrolein 10 2V Acrylonitrille 10 3V Benzene 10 5V Bromoform 10 6v Carbon 10 Tetrachloride 1 7V Chlorobenzene 10 8v Chlorodibromo-10 1 624 <1 <0.0001 <1 <0.0001 1 pjg/I lbs/d ___methane______________
9V Chloroethane 10 2-Chtoroetihylvinyl 10 10V Ether 1 11V Chloroform 10 1 624 <1 <0.0001 <1 <0.0001 1 jig/I lbs/d 12V Dichlorobromo-10 1 624 <1 <0.0001 <1 <0.0001 1 jig/I lbs/d _ methane 14V 1,1-Dichloroethane 10 15V 1,2-Dlchloroethane 10 1,1-Dichloro-10 16V ethylene 10 17V 1,2-Dichloro-10 1Vpropane 10_ ____ ___ ____ ____-- ---___ 1 ,3-Dichloro 18V propylene 10 19V Ethylbenzene 10 3. It otner data is availaDle (ie., UMR aata, etc.), me past year of oata may oe used to aetermire 3a, c, andu a. 3.a Maximum Daily Value -Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b Average of Analyses -Determine the average of all samples taken within the past year. Report both mass and concentration.
_3.c A minimum of three Sampling Events required for process wastewater discharges, and a minimum of one Sampling Event for all other discharges, treatment facility influent, intake water and background.
Make copies of this table and check appropriate box.  ** It is in the applicant's Interest to achieve a level of detection at least equal to (or preferably more sensitive than) those listed. This will minimize uncertainty and therefore the need for additional analyses or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.  ,Q-15-) ) ) )A 3620-PM-WQOOO8 Rev. 7/97 SECTION C (continued)
NPDES Number PA 0047325 IV. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLY TOXICS POLLUTANTS
: 1. Information on Chemical Additives Known or Expected to be Present in the Discharge (Notes 2-11 attached)(Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)
Chemical Average & Lowest Whole Whole substance or Manufacturer Maximum CONCENTRATION Possible product product Outfall compound USAGE Analytical 96 Hr LC50 48 Hr LC50 Trade Names or Name and Address RATE Detection (mg/l) and (mg/i) and Specific Ingredients (2) lbs/day In-System Effluent Units Level (pg/I) species 1) species"-'
ii 071 Acrylic Acid Sulfonated Acrylic Calgon Corp. Avg. 950 2,400 1 2,400 i Pg/I 1,500 Rainbow Trout Daphnia Magna Acid Copolymer Dispersant, P.O. Box 1346 Max 2,000 (4,900 mg/I) (2,800 mg/I) 32.125 Pittsburgh, PA 15230 1346 (180,000 Ibs./yr) 071 Hydroxy ethylidene disphosponic Avg. 750 4,000 4,000 pg/I 83 Rainbow Trout Daphnia Magna acid (HEDP), 32.127 Max 1,500 (368 mg/I) (527 mg/I) (90,000 Ibs./yr) 071 Solution of Quaternary Alkyl Avg. 800 10,600 100 j Pg/I 100 pg/I Bluegill Sunfish Daphnia Magna Ammonium Compound Max 1,200 j (0.32-0.59 mg/I) (0.094 mg/I) Molluscide and General Biocide, (10,000 32.126 Ibs./yr.)
071 Sodium Bromide, 32.114 Avg. 500 3,300 3,300 Pg/I 125 Rainbow Trout ) Daphnia Magna (0.23 mg/I) (0.71 mg/i) Max 1,000 071/072 Magnesium Nitrate and 5-chloro-BetzDearborn Inc. See Note 4 --- I--- --- Rainbow Trout Daphnia Magna 2-methyl-4-isothiazolin-1, 32.53 4636 Somerton Road (8.7 mg/I) (2.9 mg/I) Trevose, PA 19057 Calgon Corp I 071/072 Glutaraldehyde 40%-70%, 32.70 P.O. Box 1346 See Note 5 --- --- Flathead Minnow Daphnia Magna Pittsburgh, PA 15230- (12 mg/I) (12 mg/I) 1346 _(1) If LC50 Data for whole product is not available, data for the individual active ingredients may be provided. II I I I I I I I I 0 I 3620-PM-WQ0008 Rev. 7/97 SECTION C (continued)
I I I I I i I I I I I I NPDES Number PA 0047325 IV. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLY TOXICS POLLUTANTS
: 1. Information on Chemical Additives Known or Exoected to be Present in the Discharae (Notes 2-11 attached)(Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)
Chemical Average & Lowest Whole Whole substance or Manufacturer Maximum CONCENTRATION Possible product product Outfall compound USAGE Analytical 96 Hr LC50 48 Hr LC50 Trade Names or Name and Address RATE Detection (mg/I) and (mg/I) and Specific Ingredients lbs/day In-System Effluent Units Level (jig/I) species0) species")
071 Proprietary Descaling Agent Betz
 
==Dearborn,==
Inc. See Note 6 -.. 4636 Somerton Rd . Trevose, PA 19053 Calgon Corp. 071 Bentonite Clay Slurry, 32.128 P.O. Box 1346 Avg -1,400 0 8,000 jig/I 100 Pittsburgh, PA 15230- Max- 4,000 1346 (8,000 lbs./yr) 071 Alkyl Dimethyl Benzyl Betz
 
==Dearborn,==
Inc. Avg -770 15,000 1 <200 Pg/I 200 Fathead Minnow Daphnia Magna Ammonium Chloride (ADBAC) 4636 Somerton Rd (2.9 mg/I) (0.2 mg/I) and Dodecyl Guanidine Trevose, PA 19053 Max -10,000 I Hydrochloride (DGH), 32.69 Manley-Regan 071/079 Sodium Hypochlorite, 15%, Chemicals Avg -5,000 33,000 33,000 i gg/I 400 Ceriodaphnia 32.63 532 East Emaus Street Dubia P.O. Box 280 Max -10,000 (1.23 mg/I) Middletown, PA 17057 071 Rotenone, 32.15 AgroEvo Environmental See Note 7 --Health 95 Chestnut Ridge Rd Montvale, NJ 07645 071 Fluridone, 32.46 SePro See Note7 --- --11550 N. Meridian Carmel IN 46032 (1) If LC50 Data for whole product Is not available, data for the individual active ingredients may be provided.
I1. Information on Chemical Additives Known or Expec;ted to be Present in the Discharge (Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)
Chemical Average & Lowest Whole Whole substance or Manufacturer Maximum CONCENTRATION Possible product product Outfall compound USAGE Analytical 96 Hr LC50 48 Hr LC50 Trade Names or Name and Address RATE Detection (mgll) and (mg/l) and Specific Ingredients lbslday In-System Effluent Units Level (lgll1) species(,)
species0t) 071/079 Sodium Bisulfite, 32.113 Allied Corp. Avg -183 0 500 I.Ig/I 125 Mosquito Fish Mosquito Fish Chemical Sector (240 rag/1) (240 rag/I) P. 0. Box 1139R Max -400 Morristown NJ 07960 Sheephead Fathead Minnow 071 Sod iu mdich loro-S-triazinetrirone Calgon Corp. Avg. -70 200-500 <200 1 g/I so Minnow (0.7 rag/I) and Sodium Bromide, 32.115 P.O. Box 1346 (3.42 mg/I) Pittsburgh PA 15230- Max -300 1 3 4 6 (A s ,: ro e a v a ila b le c h lo rin e ) 071 Sulfuric Acid, 32.57 Allied Corp. (&#xfd;&#xfd;435,000
--- ---------P.O. Box 2064R Ibs./yr.)
Morristown, NJ 07960 071 2-(Tert-butylamino)-4-Chloro FMC Corp, Process (13,800 tbs. 67,000 2,200 igg/I Rainbow Trout Daphnia Magna (Ethylamino)-s-Triazine; Additives Division twice a year) (3.8) rag/I) (39 rag/I) Terbuthylazine(Algicide) 1735 Market Street Philadelphia, PA 19103 071 2-phosphono-1,2,4-Bayer Corp. Product (864 tbs. 4,000 131 V~g/I ----Rainbow Trout butanetricarboxylic acid aqueous Safety & Reg. Affairs four times a (5,300 rag/1) solution (corrosion inhibitor) 100 Bayer Road year) Pittsburgh, PA 15205 9741 071 Depositrol PY5206 Betz
 
==Dearborn,==
Inc. Avg. -96 32,000 1,140 tag/I 12,000 Fathead Minnow Daphnia Magna 4636 Somerton Road lbs./day (1,680 mg/1) (1,635 rag/I) Trevose, PA 19053 Max. -385 Ibs./day S (1) If LC50 Data for whole product is not available, data for the individual active ingredients mybeprvd.
S~-24-3620-PM-WQ0008 Rev. 7/97 NPDES Number PA 0047325 (Notes 2-11 attached)I I I I I I I I I SECTION C (continued)
IV. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLY TOXICS POLLUTANTS 360P -Q0dS v7/9- I iI !I i I I I I I 3620-1m-vM-QOOd8 e.79 SECTION C (continued)
NPDES Number PA 0047325 IV. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLY TOXICS POLLUTANTS
: 1. Information on Chemical Additives Known or Expected to be Present in the Discharge (Notes 2-11 attached) (Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information)
Chemical Average & Lowest Whole Whole substance or Manufacturer Maximum CONCENTRATION Possible product product Outfall compound USAGE Analytical 96 Hr LC5O0 48 Hr LC50 Trade Names or Name and Address RATE Detection (mg/I) and (mgll) and Specific Ingredients Ibslday In-System Effluent Units Level (pigll) speciesM 1) species0')
072 Sodium Chromate Mallinckrodt Baker Inc. See Note 8 --- .--- . 222 Red School Lane Phillipsburg, NJ 08865 071/072/079 Miscellaneous Various See Note 9 --- --- --- ---(1) If LC50 Data for whole product is not available, data for the individual active ingredients may be provided. v1 SECTION C-IV NOTES Note (2) Equivalent chemicals from other suppliers may be purchased.
Product concentrations may change; however, the concentration of active ingredients discharged should remain about the same. Approval numbers are included for those chemicals listed in the Susquehanna Approved Materials Manual. Other chemicals will be approved prior to their use onsite. Note (3) Toxicity of hypobromous acid is expressed as bromine.
Note (4) Approximately 25 gallons/year of this biocide is injected into the closed system cooling water to a maximum average effluent concentration of 330 mg/I of product or 5.0 mg/I as active isothiazolin.
Occasionally these systems are drained to the Cooling Tower basin. This product would not be expected to be detected in the Cooling Tower blowdown.
Note (5) Glutaraldehyde is added to closed cooling water systems to maintain microbiological control. A maximum concentration of 300 mg/I active or 600 mg/I product is used. Occasionally these systems are drained to the Cooling Tower blowdown.
This product would not be expected to be detected in the Cooling Tower blowdown.
Note (6) The Cooling Tower blowdown is isolated when this descaling agent is used in Circulating Water System (4,000 gal/treatment).
Treatment has been very infrequent.
Note (7) Rotenone and Fluridone are products used in the Emergency Spray Pond that has been permitted for use by the Pa Fish and Boat Commission and the PaDEP. The Emergency Spray Pond is treated when needed with 1,000 lbs. of Rotenone to a level of 5 mg/I; however, it is detoxified with potassium permanganate at a rate equal to this concentration prior to discharge and, therefore, is not expected to be present in Outfall 071. Also, 32 lbs. of Fluridone will be applied as necessary to an area of 8/10 surface acre along the pond's edge. Note (8) Sodium Chromate may be used as a corrosion inhibitor and biocide in the Emergency Diesel Generator Jacket Water (DGJW) Systems.
Sodium Chromate addition of 4 lbs. to 710 gallons each of diesels A through D and 7.5 lbs. to 1480 gallons for the larger E diesel's DGJW system. Then systems will maintain a concentration of less than 500 mg/I as Chromate.
If there is any leakage from these systems it would enter the Service and Administration Building sump (2-10,000 gallons lbs.), Outfall 072. This sump is manually discharged for 10,000 gallons 000152 at any given time. Assuming leakage of 20 gallons into a 10,000 gallon sump, the effluent concentration is estimated to be < 1.0 mg/I. This product will not be used unless other treatment strategies are unsuccessful at protecting the Emergency Diesel Generators from corrosion and biocide fouling.
Note (9) Miscellaneous chemicals used in very small quantities for cleaning surfaces, cooling coils, decontamination of floors, walls, and equipment, cleaning agents, liquid dye for flow tests, laboratory reagents and standards, etc. The following are some of these chemicals:
000153 Chemical/SAMM
# Est. gal/yr.Coil Rite, C-10.384 Acti-Klean, C-10.326 By-Pas, E-10.11 Organic Orange, E-10.35 Citirikleen, E-10.29 MSA/Cleaner/Sanitizer II, E-10.8 Rhodamine WT Dye, 32.68 Spartan SD-20, C-1 0.167 Touch It Up, E-10.4 601-Nami-Lo, C-10.74 Powerline PPL10, 32.90 Cobratec TT-50-S, 32.87 Yellow/Green liquid dye, 32.42 Clarifloc C-9490 polymer, 32.109 Nalco 9905, 32.81 Ethylene Glycol mixture, 16.20 Iron Oxalate, 32.129 Polyfloc CP1160, 32.130 Polyfloc AP1 100, 32.131 Propylene Glycol Mixture, 16.36 EPA 2000 WCI-140, B-10.27 Trisodium Phosphate, A-20.24 Sodium Hydroxide, 32.59 a a 220 110 a 288, b a a a a 50 a a 10-15, c 220, c d 500 lbs./yr.
20 lbs./yr.
20 lbs./yr.
a, d a a 500"Key a. Not available b. Ounces c. Flocculent aid used infrequently for dewatering sludge d. Present in equipment onsite and has potential for entering storm drains. Preventative maintenance and analysis of replacement chemicals such as Propylene Glycol will minimize any adverse impacts to the environment.
Some of these chemicals may be discharged to the Cooling Tower Basins/ Blowdown, Sewage Treatment Plant, or storm drains in accordance with their Material Safety Data Sheet recommendations.
jsf/99123.doc(Imc) 000154 Assigned to: ????FOR INFORMATION ONLY S. ............. 'Expires On: \??PCL461 P.O. Box 134I *1k ~ Pittsburgh, PA 15230-1I4 F C D ft a t, t 0 Phore-(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: PCL.401 CHEMICAL DESCRIPTION:
Aqueous solution of anlonrc copolymer PRODUCT CLASS: Water treatment MSOS CODE: 0544.08-09-96 Section 2. INFORMATION ON INGREDIENTS CAS % by Qh~jalblmeNurnbe Weight SH &E~L ACQIH TLV"No hIgredients listed In this section' This product is not considered to be hazardous according to the criterla of the U.S. Federal OSMA tazard Communication Standard (29 CFR 1910.1200) wnd Is not a contloiled product under WHMIS in Canada.Section 3. HAZARDS IDENTIFICATION
******~****t*
,*****x* = EMERGENCY OVERVIEW ****************"****
This product poses ittlo or no Immediate health hazard. PRIMARY ROUTES OF ENTRY: None TARCIET ORGAN10i Nmn# MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Unknown POTENTIAL HEALTH EFFECTS: EYE CONTACT: This product would not be expected to produce Irryttion upon cohtact with the eye. SKIN CONTACT: The product Is not expected to cause akin rritation upon contact. Data Indicate that this produot wilt not produce an alerglo skin reaction or be absorbed t"rough the skin In harmful amounts.
INGESTION:
This product would be regarded es practically non-toxic If swallowed.
INHALATION:
This product Is not expected to present an Inhat~on hazard.MSDS Code: 0544-0809-96 Issue Date: 10/30/9M Conftiued on Page2 000155 Assigned to: ???? FOR INFORMATION ONLY Expires On: PCL-401 SUBOHRONIC, CHRONIC: No eaplicable Inrormation was found concerning any potential health effect* resulting from subchronlc or chronic exposure to the pmducl. CARCINOGENICITY:
NTP: *No Ingredients Hated in this section* IARC *No ingredients listed In this section' OSHA: "-No ingredlents listed In this sectWn' Section 4. FIRST AID MEASURES EYE CONTACT: Not expected to require flint aid measures.
However, follow good Industrial hygiene prmctloes end, in case of contict, flush eyes wlih plnty of water. SKIN CONTACT: Not expected to require first old measures.
However, follow good Industriai hygiene practIces end, In case of contact, wash affected skin arbas thoroughly with soap and water. INGESTION:
Not an expected route of overexposure, It do not Induce vomIling.
Cal a pysiolan.
This product would be expected to be practically non-toxic by Ingestion.
INHALATION:
Not an expected route of overeoxpoure, Section 5. FIRE-FIGHTING MEASURES FLASH POINT: 200'F This product i1 not by definition a "flammable liquid* or a 'combustible lquid'. LOWER FLAMMABLE LIMIT! Not available UPPER FLAMMABLE UMIT: Not available AUTO-IGNITION TEMPERATURE:
Not available EXTINGUISHING MEDIA:. Use-exigulshing media approprIate for the eurTounding fire. FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when lighting any chemical ftire. A self-contained breathing apparatus and protective clothing are essential FIRE & EXPLOSION HAZARDS!'
Product emits toxic gases under fire condtions.
DECOMPOSITION PRODUCTS:
Thermal decompoelIton or combustion may produce carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides. NFPA RATINGS: Health 0 Flammability
= 1 Reactivity
= 0 Special Hazard -None Hazasd raUng sI.al: 0.MInbla 1-SlIght 2-=Modarata 4-8evem MSDS Codem 0544-08-09-96 Page 2 Issue Date: 10W f96 Continued on Page 3 00015G -
Assigned to: ????3!.Is-w PCL-401 Section G. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR'SPILLED:
Wearirg appropriate personal protective.
equIpment, contain split. colect onto inert absorbent and place Into suitable container.
Spiled product may make floor alIppery:, spils should be clesned up Immedlately to prevent falls. Section 7. HANDLING AND STORAGE HANDLING:
As part of good Industrial nd personal hygiene end safety procedure, avoid alt unnecessary exposure 16 the product and ensure prompt removal from eyes, skn and dothIng.
Wash thoroughly -after hwndling.
Keep container closed when not In use; STORAGE: No specific Informatlon.
ScII'on 8. EXPOSURE CONTROLS i PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
Chemical splash goggles recommended as a good Industrial hygiene pracltce; SKIN. PROTECTION:
No speoial reKufremen'" rESPIRATORY PROTECTION:
None required.
ENGINEERING QONTROLS:
No specific recommendationS.
Section 9i PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: Not avallable SOLUBILITY IN WATER: Complete VAPOR PRESSURE:
Similarto water SPECIFIC GRAVITY: 1.18 -1.20 @ 25C "VAPOR DENSITY (a&r-1): Similar to water pH: 4.2 -5.0 0 25*0 %VOLATILE BY WEIGHT: -.66 (water) FREEZING POINT: 25F "APPEARANCE AND ODOR: Clear, colorless to pale yellow, slightly viscous lquld. Section 10. STABILITY AND.REACTIWITY CHEMICAL STABILrTY; Stable HAZARDOUS POLYMERIZATION:
Will not occur CONDITIONS TO AVOID:. No speclfli nformatior.
iag L MSDS Code: 0544-08-09-96 Issue Date: 10130/96 Page 4 Continued on Page 4 00015,7 FOR INFORMATION ONLY Expires On:\? .... ......,, r-1,p~
Assigned to: ????F-T--FOR INFORMATION ONLY PCL..401 Expires On: -g, INCOMPAT11BLITY:
Strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion may produce carbon monoxide.
oarbon dioxldf, nitrogen oxides, and sulfur oxides. Seotilon 11. TOXICOLOGICAL INFORMATION ON PRODUCT: Product Oral Leoi (rat): i. 5 gtig troduct Dermal LODo (rabbit);
> 2 /kg Eye Irritation:
The product produced no Iritation when Instlted In ralbbt eyes (unwashed).
Sdn Irhdtilor:
The primary skin Irritation Index (rabbits)
Is 0.09/8. Section 12. ECOLOGICAL INFORMATION ON PRODUCT, Environmt1ral date: TOC: 128,000 ppm COD: .10,00 Ppm SOD: %< 5,000 ppm ON ING(REDIENTS:
Qhmkcal*NarD_
Aaua$C Tb2=ft Data. Anionic cqpolymer 48 hr LOC0 (Daphnla magne), 2,600 ppm 06 hr LCr (btuaonl sunftah):
> 10,000 ppm e6 hr LCw (rainbow trout): 4.900 ppm Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would not be cons"kWeI a RCRA Hazardous Waste. DISPOSAL, Dispose of In accordance vdth local, state and federal regulations.
Section U4. TRANSPORT INFORMATION., DOT CLASSIFICATION:
CasaDivilvon, Not restricted Proper Shipping Name: Not applicable
*LabeI: None Peolong Group: Not applicable ID Number Not applicable Section 16. REGULATORY INFORMATION OSHA Hazard Coimmunicaion Status: Nonhazardous
-MSDS Code: 0544-08-09-98 Issue Date:. 10/30lr Page 4 ContInued on Page 6 000158 -i Assigned to: ????FOR INFORMATION ONLY?iz'.I 4 PCL-401 TSCA. The Ingredlents of this product- are listed on the Toxic Subsatances Control Act (TSCA) Chemical Substances Inventory.
CERCLA reportable qvantfty of EPA hazardous substances in product, rvhe mmgl Nam No higredlents of this product have CERCLA reportable quantities.
Product Ro.: Not applicable (Notify EPA of product splitg exoeeing tiis amount) SARA TITLE 111. Sacton 302 Extremiely Hazardous suIbstaflcew cheica IEbe08 'Ther are no SARA 302 Exdraem* Hazardous Substances In 1his product, Secton 311 ind 312 Health andPftyalcmI Heamd*t Immediate Delayed Fire -Pressure Reactivity
[no) [no] [iol [no0010 Sacton 313 Toxic &#xfd;Chemicals:
Y y Might Therwe re no reportable SARA O313Toxl Chemicals In this product Section IS. OTHIER INFORMATION HMIS RATNOS: Health-0 Flamnmablity
-I Personal Protective Equipment
=A Reactivity
-0 Hazard Moa~n scale: 04&llmal 1-Slight 2W4Odt6MI 3-Soj0iue 4wSeysre MSDS REVISION
 
==SUMMARY==
: Supersedes MSDS Issued on OOt2/'3. T1he MSDS has been changed in Section S. whIl.hL. 6L ~ lroation and 60om~tebaL L0rth h~fGin as.4 bILOV64 tO b6 0GUICOCZI L BEOf MO. dbt& hereao, IAAO CW"RdiAY:OK1 jAY-W 50 ARRMYW WMYI ViKRP'IV 14XUM' M.5 DIRCL.AMN ALL, Ujiif.i'M1 M~W W1m.1X2 I'I{RWI.
PREPAR1ED 13Y: P.4. Maloney MSDS Code' 0-O08-0a960 Issue Date: 110MOSQ 0001159 Expires On:. V? (9-Pago 6 Last Pop NSDS Fax-on-Depand Systlm I PCL-57 I P.O. Box 1346 Z Pittsburgh, PA 15230-1346
' W W=C.a f A TS aC=IP Phone-(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: PCL-57 CHEMICAL DESCRIPTION:
Aqueous solution of organic phosphonate PRODUCT CLASS: Water treatment MSDS CODE: 0658-06-20-95 Section 2. INFORMATION ON INGREDIENTS CAS % by Chemical Name Number Weight OSHA PEL ACGIH TLV 1-Hydroxyethylidene-1,1-diphosphonic acid 2809-21-4 60 None established None established (HEDP) Phosphorous acid 13598-36-2 3 None established None established Section 3. HAZARDS IDENTIFICATION
* ******** ************
EMERGENCY OVERVIEW *******************
DANGER! May cause severe eye damage. May cause skin and respiratory tract irritation.
May be harmful if swallowed.  ***** ******* *** ***** ,***********
l** * ~***** ***** *** ** PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation, ingestion TARGET ORGANS: Eye, skin, blood, bone, mucous membranes MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
May aggravate anemia POTENTIAL HEALTH EFFECTS: EYE CONTACT: This product may cause irreversible eye damage upon contact depending on the length of exposure, solution concentration and first aid measures.
MSDS Code: 0658-06-20-95 Page 1 Issue Date: 09/12/95 Continued on Page2 2 Haoember 19, 1997 "SDS Fax'On-Demand System I PCL-57 I SKIN CONTACT: Exposure to this product may cause moderate to severe irritation of the skin. This product is not expected to be absorbed through the skin in harmful amounts or to produce an allergic skin reaction.
INGESTION:
The low pH of the product would indicate that it may produce severe irritation or bums to the mouth, throat, esophagus, and stomach if swallowed.
INHALATION:
This product is not expected to present an inhalation hazard unless mists or vapors are generated.
Breathing mist of HEDP may be irritating to the mucous membranes of the respiratory tract. SUBCHRONIC, CHRONIC: Some blood effects have been produced by HEDP in chronic feeding studies with rats. A product containing 60% HEDP was administered to beagle dogs at dietary concentrations of 1,000, 3,000, or 10,000 ppm for 90 days with no adverse hematologic.
biochemical or histopathologic effects.
Numerous publications in the scientific literature discuss the effects of HEDP related to bone resorption in tissue and cell culture, and in animals. The effects of HEDP related to bone mineralization, calcium absorption, and metabolism of calcium and phosphate have also been evaluated.
CARCINOGEN ICITY: NTP: *No ingredients listed in this section* IARC: *No ingredients listed in this section* OSHA: *No ingredients listed in this section* Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid immediately.
SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Seek medical aid immediately.
Wash clothing before reuse. INGESTION:
If swallowed, do NOT induce vomiting.
Give large quantities of water. Seek medical aid immediately.
Never give anything by mouth to an unconscious person. INHALATION:
If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Seek medical aid. Section 5. FIRE-FIGHTING MEASURES FLASH POINT: > 200"F (TCC) This product is not by definition a "flammable liquid" or a "combustible liquid".
LOWER FLAMMABLE LIMIT: Not available UPPER FLAMMABLE UMIT: Not available AUTO-IGNITION TEMPERATURE:
Not available MSDS Code: 0658-06-20-95 Issue Date: 09112/95 Page 2 Continued on Page 3 0001631 November 14, 1997 HSDS Fax-On-Demand System I PCL-57 I EXTINGUISHING MEDIA: Use extinguishing media appropriate for the surrounding fire. FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective clothing are essential.
Use water to keep fire-exposed containers cool. FIRE & EXPLOSION HAZARDS: Product emits toxic gases under fire conditions.
DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide, phosphines, and phosphorus oxides.NFPA RATINGS: Health = 3 Flammability
= 1 Reactivity
= 0 Special Hazard = None Hazard rating scale: 0-Minimal 1 -Slight 2-Moderate 3-Serious 4-Severe Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent and place into suitable container.
Spilled product may be neutralized carefully with weak caustic solutions or sodium carbonate.
Neutralization releases large amounts of heat. Section 7. HANDLING AND STORAGE HANDLING:
Do not get in eyes. Avoid contact with skin and clothing.
Avoid breathing vapor or mist. Use with adequate ventilation.
Wash thoroughly after handling.
Keep container dosed when not in use. STORAGE: Do not store near incompatible materials.
Store in a cool, dry, well-ventilated location.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
Chemical splash goggles and face shield SKIN PROTECTION:
Chemical resistant gloves and protective clothing RESPIRATORY PROTECTION:
If airborne concentrations become irritating, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
ENGINEERING CONTROLS:
Use local exhaust ventilation at elevated temperatures or if mists are generated.
WORK PRACTICES:
Eye wash station and safety shower should be accessible in the immediate area of use. Avoid using in confined spaces.MSDS Code: 0658-06-20-95 Issue Date: 09/12/95 Page 3 Continued on Paae 4 0001 November 14, 1337 SDS Fax-On-Demand SysteN I PCL-57 UNSATISFACTORY MATERIALS OF CONSTRUCTION:
Product is corrosive to mild steel. Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOIUNG POINT: 226"F (108"C) SOLUBILi VAPOR PRESSURE:
Similar to water SPECIFIC VAPOR DENSITY (air=1): Similar to water pH: < 2 %VOLATILE BY WEIGHT: -37 (water) FREEZIN( APPEARANCE AND ODOR: Clear, pale yellow liquid with no odor. Section 10. STABILITY AND REACTIVITY TY IN WATER: Complete GRAVITY: 1.41 -1.47 @ 25"C (1% active solution)
G POINT: F (25-C)CHEMICAL STABILITY:
Stable HAZARDOUS POLYMERIZATION:
Will not occur CONDITIONS TO AVOID: Temperatures greater than 200'C (392"F). At this temperature, product can form flammable phosphine gas. INCOMPATIBIUTY:
Strong oxidizers and bases DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide, phosphines, and phosphorus oxides. Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT: See the following information on ingredients.
ON INGREDIENTS:
Oral LDso Dermal LDso Inhalation LCso Chemical Name (rat) (rabbit) (rat) 1 -Hydroxyethylidene-1,1 -diphosphonic acid 2400 mg/kg (60% >7940 mg/kg (60% Not available
"(HEDP) soln) soin) Phosphorous acid 1895 mg/kg Not available Not available Section 12. ECOLOGICAL INFORMATION ON PRODUCT: Environmental data: Prolonged exposure of terrestrial or aquatic environments to acidic conditions can be expected to produce adverse effects by releasing toxic cations, e.g., metals.MSDS Code: 0658-06-20-95 Issue Date: 09/12/95 Page 4 Continued on Page 5 OO0O61, November 14, 1997 NS5S Fax'On'Demand System I PCL-57 I ON INGREDIENTS:
Chemical Name Aquatic Toxicity Data 1-Hydroxyethylidene-1
,1-diphosphonic acid 48 hr LCs 0 (Daphnia magna): 527 ppm 96 hr LC 5 0 (rainbow trout): 368 ppm 96 hr LCso (bluegill sunfish):
868 ppm Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would be considered a RCRA Hazardous Waste based on the characteristic of corrosivity.
The EPA Hazardous Waste Number is D002. DISPOSAL Dispose of in accordance with local, state and federal regulations.
Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:
Class/Division:
8 Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (contains 1 -Hydroxyethylidene-1,1 -diphosphonic acid) Label: Corrosive Packing Group: III ID Number. UN 3265 Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA: The ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory.
CERCLA reportable quantity of EPA hazardous substances in product: Chemical Name RQ No ingredients of this product have CERCLA reportable quantities.
Product RQ: Not applicable (Notify EPA of product spills exceeding this amount.) SARA TITLE Ill: Section 302 Extremely Hazardous Substances:
Chemical Name CAS # RQ TPQ There are no SARA 302 Extremely Hazardous Substances in this product.
Section 311 and 312 Health and Physical Hazards: Immediate Delayed Fire Pressure Reactivity
[yes] [nol [no] [no] [no] MSDS Code: 0658-06-20-95 Page 5 Issue Date: 09/12/95 Continued on Page 60001 .4 November 14, 1337 NSD3 Fox-On'Demand System I PCL-57 I Section 313 Toxic Chemicals:
Chemical Name CAS # %by Weight There are no reportable SARA 313 Toxic Chemicals in this product.
Section 16. OTHER INFORMATION HMIS RATINGS: Health = 3 Flammability
= 1 Reactivity
= 0 Personal Protective Equipment
= X (to be specified by user depending on use conditions)
Hazard rating scale: 0-Minimal 1 -Slight 2-Moderate 3-Serious 4-Severe -MSDS REVISION
 
==SUMMARY==
: Supersedes MSDS issued on 2/14/95. The MSDS has been changed in Section 14. W'hile this information and xecormendations set foxth herein axe believed to be accurate as of the date hereof, CALLGON HAIMS NO WARRANTY w;ITH RESPECT HFETO AMND DISCLAIMS ALL LIABILITY FRON! RELIANCE THEREON.
PREPARED BY: P.J. Maloney MSDS Code: 0658-06-20-95 Issue Date: 09/12/95 Page 6 Last Page 00065D November 14, 1887 Assigned to: ???? 1I505 Fax-On-Demand Syskte FOR INFORMATION ONLY Expires On: '"'.H-130M P.O. Box 1346 dflh [ Pittsburgh, PA 15230-1346
= F8 .slow Phone-(412)44--8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: H-110M CHEMICAL DESCRIPTION:
Solution of quatemary alkyl ammonium compound PRODUCT CLASS: Mollusciade MSDS CODE: 0B75-02-08-95 Section 2. INFORMATION ON INGREDIENTS CAS % by Chemical Name Number Weight OSHA PEL ACGIH TLV Dldecyldimethylammonium chloride 7173-51-5 50 None established None established Ethanol 64-17-5 10 TWA 1000 ppm, TWA 1000 ppm, 1900 mg/m 3  1880 mg/m 3 Section 3. HAZARDS IDENTIFICATION
*. .....* * *. ....* * .....E M E R G E N C Y O V E R V IE W ...* ..* * * *
* DANGER! May cause severe eye and skin damage. May be harmful id swallowed.
May cause respiratory tract irritation.
Flammable/CombustIble liquid and vapor. PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation, ingestion TARGET ORGANS: Eye. skin, mucous membranes, central nervous system MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
No data available.
POTENTIAL HEALTH EFFECTS: EYE CONTACT: This product may cause severe irritation and damage upon contact with the eye.MSDS Code: 0B75-02-08-95 issue Date: 03/18/96 agejfT q Continued on Page 2 I 0001f;G Nlove *6b r 14 'Q 2 1JI.I I!
Expires On: \??Assigned to: ???? FOR INFORMATION ONLY AS0S FA. x-O-Dn-snd Systom H"vOebor Ii, 1537 H-130M SKIN CONTACT: Direct or prolonged contact with this product can cause severe skin Irritation and possibly skin bums. Data Indicate that this product will not be absorbed through the skin in harmful amounts and will not cause an allergic skin reaction.
INGESTION:
if swallowed, this product would be expected to cause immediate burning pain In the mouth. throat, and abdomen, severe swelling of the larynx, skeletal muscle paralysis affecting the ability to breathe, circulatory shock, convulsions.
INHALATION:
Solvent vapors or mist of product can cause irritation of mucous membranes 4i Inhaled.
Exposure to ethanol concentrations of over 1000 ppm may cause headache, Irritation of the eyes, nose and throat, and, if long continued, drowsiness and fatigue, loss of appetite and Inability to concentrate.
SUBCHRONIC, CHRONIC: This product was found to be not teratogenic in rats treated with 10-50 mglkg on days 6 to 15 gestation, not mutagenic in Ames Salmonella test with or without metabolic activation, and not clastogenic in Chinese hamster ovary cells with or without metabolic activation.
There was no evidence of chromosomal damage in the bone marrow of rats treated with 600 mg/kg. CARCINOGENICITY:
NTP: *No ingredients listed In this section* IARC: .No ingredients listed in this section* OSHA: *No ingredients listed In this section* Section 4. FIRST AID MEASURES EYE CONTACT: in case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid immediately.
SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Seek medical aid immediately.
Wash clothing before reuse. INGESTION:
If swallowed, give large amounts of water to dilute the toxicant.
If immediately available, demulcents such as milk, vegetable oil or egg whites can be given. Do NOT induce vomiting as it is likely to cause considerable mucosal damage. If vomiting does occur, give fluids again. Get medical attention immediately.
NOTE TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, as well as oxygen and measures to support breathing manually or mechanically, may be needed. If persistent, convulsions may be controlled by the cautious intravenous injection of a short-acting barbiturate drug. INHALATION:
If Inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Seek medical aid. MSDS Code: 0B75-02-08-95 g2aPe.e.2 Issue Date: 03/18/96 Continuedofo-Paoe 3
FOR INFORMATION ONLY floveatbor 111P. 1257' __J H-130M Section 5. FIRE-FIGHTING MEASURES FLASH POINT: 1 09F (Setaflash)
This product is a fire hazard.LOWER FLAMMABLE LIMIT: Not available AUTO-IGNITION TEMPERATURE:
Not available EXTINGUISHING MEDIA-UPPER FLAMMABLE UMIT: Not available Use dry chemical, "alcohol" loam, carbon dioxide, or water spray.FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when lighting any chemical fire. A self-contained breathing apparatus and protective clothing are essential.
Use water to keep fire-exposed containers cool. FIRE & EXPLOSION HAZARDS: Product emits toxic gases under fire conditions.
Heated solvent vapors can travel to an ignition source and flash back. DECOMPOSITION PRODUCTS:
Thermal decomposition may produce carbon monoxide, carbon dioxide, organic materials, hydrogen chloride, amines, and nitrogen oxides.NFPA RATINGS: Health -3 Flammability
-2 Reactivity
= 0 Special Hazard = None SHazard rating scale: 0-Minimal 1 -Slight 2-Moderate 3-Serious 4-Severe Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition.
Ventilate area of spill. Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent and place into suitable container.
Do not allow to contaminate sewers and waterways.
Spilled product may make floor slippery-, spills should be cleaned up immediately to prevent falls. Section 7. HANDLING AND STORAGE HANDUNG: STORAGE: It is a violation of Federal law to use this product in a manner inconsistent with its Labeling.
Do not get in eyes, on skin or clothing.
Avoid breathing vapor or mist. Use with adequate ventilation.
Wash thoroughly after handling.
Keep container dosed when not in use. Keep away from heat and flame. Do not contaminate water, food, or feed by storage.
Maximum storage temperature:
140"F MSDS Code: 0B75-02-08-95 Issue Date: 03/18/96 Continge d1o Pq--ContinuedI on Page 4 UU014bN Assigned to: ???? r43'VVn'U*mnar tlygtta Expires On:
Assigned to: ???? FOR INFORMATION ONLY Expires On: \?? nI:t t 2'Un'Uenand 5ajLwtgm NovenbO H-130M Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
Chemical splash goggles and face shield SKIN PROTECTION:
Chemitcal resistant gloves and protective clothing RESPIRATORY PROTECTION:
If airborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
ENGINEERING CONTROLS:
Use local and/or general exhaust ventilation to maintain airbome concentrations below exposure limits. WORK PRACTICES:
Eye wash station and salety shower should be accessible in the Immediate area of use. Section 9. PHYSICAL AND CHEMICAL PROPERTIES -BOIUNG POINT: Not available SOLUBILITY IN WATER: Complete VAPOR PRESSURE:
Not available SPECIFIC GRAVITY: 0-93 @ 25"C VAPOR DENSITY (air-i): Not available pH: 7.0 -8.0 (1% solution)
%VOLATILE BY WEIGHT: 50 FREEZING POINT: Not available APPEARANCE AND ODOR: Colorless to pale yellow, slightly viscous liquid with alcohol odor. Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY:
Stable HAZARDOUS POLYMERIZATION:
Will not occur CONDITIONS TO AVOID: Do not use this product In conjunction with soap or any anionic wetting agent. INCOMPATIBILITY:
Strong oxidizers and reducers DECOMPOSITION PRODUCTS:
Thermal decomposition may produce carbon monoxide, carbon dioxide, organic materials, hydrogen chloride, amines, and nitrogen oxides. MSDS Code: 0B75-02-08-95 Lgl-W 2 Issue Date: 03(18/96 Continued on Page 5 000169 Assigned to: ???? -o#. ^ verl n Vil a  FOR INFORMATION ONLY Expires On: ?I H-13OM Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT: Product Dermal LDso (rabbit):
4300 mg/kg (based on 80% active) Eye Irritation:
Instillation of 0.1 ml to the eye with or without washing resulted In extreme Irritation that did not dear by day 7, post-dose.
Skin irritation:
Application of 0.5 ml to abraded and non-abraded skin resulted in severe redness and swelling, as well as scabbing and blanching of the skin that did not dear by day 7, post-dose.
Skin sensitization:
In a dermal sensitization study of didecytdimethylarnmonium chloride conducted in guinea pigs, there was no evidence of photoallergy or contact sensitization.
Toxicological data on chronic effects: For didecyidimethylammonium chloride: -Dermal subchronlc toxicity (90 day -rat): no systemic toxicity observed.  -Reproductive effects (2 generation rat study): treatment at or below the level which produces mild toxic effects shows no reproductive effects.  -Oral chronic toxicity (dog -1 year): no target organ effects.  -Pharrnacokinetics (dog): this material does not accumulate in body tissues.
ON INGREDIENTS:
Chemical Name Didecyldim ethylammonium chloride Ethanol Oral LD50 .(rat) 84 mglkg 7060 mg/kg Dermal LD50 (rabbitj Not available LDL 20 g/kg Inhalation LCso (rat) Not available 20000 ppmn10H Section 12. ECOLOGICAL INFORMATION ON PRODUCT: Environmental data: This product is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, ooeans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPD ES) permit and the permitting authority has been notified in writing prior-to discharge.
Do not di'.sc-har effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority.
For guidance contact your State Water Board or Regional Office of the EPA. Semi Continuous Activated Sludge Test: 91 -97%ON INGREDIENTS:
Chemical Name Didecyldimethylarnnmonium chloride Aquatic Toxicity Data 48 hr EC 5 0 (Daphnia magna): 0.094 ppm 96 hr LC 5 0 (mysid shrimp): 0.069 ppm 96 hr LCso (bluegill sunfish):
0.32-0.59 ppm 96 hr LCs 0 (rainbow trout): 1.1 ppm 96 hr LCs0 (coho salmon): 1.0 ppm MSDS Code: 0B75-02-08-95 Issue Date: 03/18/96 a5 Continued on Page 6 UUU~LI FOR INFORMATION ONLY NaoW0ber IV 1137 H-130M Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would be onnsldered a RCRA Hazardous Waste based on the characteristic of Ignitabilty.
The EPA Hazardous Waste Number is 0001. DISPOSAL-Pesticide wastes are acutely hazardous.
Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:
Class/Division:
8 Proper Shipping Name: Corrosive liquid, flammable, n.o.s. (contains Didecyldimethylammonium chiloide and Ethanol) Label: Corrosive, Flammable liquid Packing Group: It ID Number UN 2920 Section 15. REGULATORY INFORMATION OSSHA Hazard Communication Status: Hazardous TSCA: Pesticides are exempted by TSCA (the Toxic Substances Control Act), under Section 3(2)(a)ii, from the provisions of the Act. CERCLA reportable quantity of EPA hazardous substances in product: Chemical Name RQ No ingredients of this product have CERCLA reportable quantities.
Not applicable (Notify EPA of product spills exceeding this amo~unt.).
SARA TITLE 111: Section 302 Extremely Hazardous Substances:
Chemical Name CAS # RQ There are no SARA 302 Extremely Hazardous Substances in this product.Section 311 and 312 Health and Physical Hazards: Immediate Delayed Iyes] Inol Fire 1yesi Pressure (nol TPQ Reactivity
[no]Section 313 Toxic Chemicals:
Chemical Name CAS # There are no reportable SARA 313 Toxic Chemicals in this product.% by Welaht MSDS Code: 0B75-02-08-95 Issue Date: O31 8196 Continued on Page 7 000171 Product RQ: Assigned to: ???? 115.tij4K-tx-On-Q&Md
$V*Eam-Expires On: X??
Assigned to: ????Expires On: '?FOR INFORMATION ONLY H-130M Section 16. OTHER INFORMATION HMIS RATINGS: Health -3 Flammablity
-2 Reactivity
-0 Personal Protective Equipment
-X (to be specified by user depending on use conditions)
Hazard rating scale: 0-Minimal 1-Slight 2-Moderate 3-Senous 4-Severn MSDS REVISION
 
==SUMMARY==
: Supersedes MSDS issued on 2"4/94. The MSDS has changed in Sections 11 and 14. Zlle rb!5 intfzration and recccmnendation.
set forth herein are belleved to be ccurette as cf the -dat beereof. CAI'):, .P.T0-4O 11>Es --. RPyrr 7 i RESPECT HE y AMD DIS CLU.IS AL.L IL ZALITY T'. I MZN CE T[-:EO. PREPARED BY: P.J. Maloney MSUDS Code: 0B75-02-O8-95 Issue Date: 03/18196 L~agt 7 117 0O0172, 000172-1 I I Assigned to: ???? *I.J-4d iflafO ax-nvaaa4scWD FOR INFORMATION ONLY ftevomber 2 4 =H-940 Expires On: k?? imILP.O. Box 1346 Pittsburgh, PA 15230-134W Phone-(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: H-940 CHEMICAL DESCRIPTION:
Aqueous solution of alkali metal halide PRODUCT CLASS: Biocide MSDS CODE: 0A48-11-04-93 Section 2. INFORMATION ON. INGREDIENTS CAS %by Chemical Name Number W. h OSHA PEL ACGIH Sodium bromide 764715-6 40 None established None established Section 3,. HAZARDS IDENTIFICATION
** *************~****
EMERGENCYOVERVIEW
*t.*,.********
** ***** **WARNING! May cause eye and skin Irritation.
PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation of mist TARGET ORGANS: Eye, skin MEDICAL CONDrITONS AGGRAVATED BY EXPOSURE:
Pre-existing skin disorders.
POTENTIAL HEALTH EFFECTS: EYE CONTACT: This product may produce Irritation upon contact with the eye. SKIN CONTACT: This solution was found to be non-irritating .to the skin in animal tests. It is not expected to be absorbed in harmful amounts. Prolonged or repeated skin exposure may result in skin irritation and dermatitis.
Failure to decontaminate could result in superficial bums. INGESTION:
This product would be regarded as practically non-toxic If swallowed.
Excessive ingestion of sodium bromide may produce rashes, depression, emaciation and, in severe cases, psychosis and mental deterioration.
MSDS Code: 0A48-11-04-93 Issue Date: 09/12196 Page 1 Continued on Pane 2 000173 Assigned to: ???? FOR INFORMATION ONLY Expires On: 1" I H-940 *INHALATION:
This product would not be expected to be an inhalation hazard unless the product Is misted or sprayed. Bromide rashes may occur when bromide inhalaion is prolonged.
The systemic effects of bromide ion are chiefly mental: drlowsiness, irritability; vertigo, confusion, hallucinations.
SUBCHRONIC, CHRONIC: A three-generation reproduction study in rats fed 4800 mg/kg of solid sodium bromide showed a decrease In fertility.
Other animal tests with sodium bromide produced adverse reproductive effects.
The physiological effects of sodium bromide are attributable to the bromide Ion. Metabolically, bromide has a biologic half-life of about 12 days. Is not Incorporated into fat or blood proteins, and none Is extractable from plasma or hemolyzed blood cells by ether. Nor does the bromide ion interfere with thyroid activity even at large daily doses for extended periods of time. CARCINOGEN ICITY: NTP: *No ingredients listed In this sectiont IARC: *No ingredients listed in this section* OSHA: "No ingredients listed In this section* Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid. SKIN CONTACT: In case of contact, flush skin with plenty of water. Remove contaminated clothing.
Seek medical aid if Irritation persists.
Wash clothing before reuse. INGESTION:
Not an expected.mute of overexposure.
if swallowed, do not induce vomiting.
Call a physician.
This product would be expected to be practically non-toxic by Ingestion.
INHALATION:
Not an expected route of overexposure.
However, if exposure by inhalation is suspected.
remove to fresh air. Aid in breathing if necessary and seek medical aid if symptoms occur. Section 5. FIRE-FIGHTING MEASURES FLASH POINT:. None LOWER FLAMMABLE UMIT: Not applicable UPPER FLAMMABLE LIMIT: Not applicable AUTO-IGNITION TEMPERATURE:
Not applicable EXTINGUISHING MEDIA: This material does not burn. If exposed to fire from another source, use suitable fire extinguishing agent for that fire. FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective clothing are essential.
FIRE & EXPLOSION HAZARDS: Product emits toxic gases under fire conditions.
MSDS Code: 0A48-11-04-93 Page 2 Issue Date: 09/12Z96 Continued on Page 3 000174-Assigned to: ???? FOR INFORMATION ONLY Expires On: 1?? DECOMPOSITION PRODUCTS:
In tires fueled by other material, hydrogen bromide or bromine may be released.
NFPA RATINGS: Health = 2 Flammability
-0 Reacty -0 'Special Hazard = None Hazard ratuig scale: 0-Minimal 1 -Slight 2-Moderate 3-Serious 4-Severe Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent and place Into suitable container.
Section 7. HANDLING AND STORAGE HANDDUNG:
It Is a violation of Federal law to use this product in a manner Inconsistent with its labeling.
Avoid contact with eyes, skin and clothing.
Avoid breathing mist. Use with adequate ventilation.
Wash thoroughly alter handling.
Keep container closed when not in use. STORAGE: St6re in a cool, dry, well-ventilated location.
The recommended minimum storage temperature is (&deg;F (-1 7.8"C). Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
Chemical splash goggles SKIN PROTECTION:
Chemical resistant gloves RESPIRATORY PROTECTION:
When misting may occur-In the work area, use a NIOSH approved respirator In accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
ENGINEERING CONTROLS:
Use local exhaust ventilation where mist or spray may be generated.
WORK PRACTICES&
An eye wash station should be accessible in the immediate area of use. Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOIUNG POINT: 217 -21gF (103 -104-C) SOLUBILITY IN WATER: Complete VAPOR PRESSURE:
Similar to water SPECIFIC GRAVITY: 1.43 0 25"C VAPOR DENSITY (air=1): Simllar to water pH: 5.5- 9.0 0 25*C %VOLATILE BY WEIGHT: 60 (water) FREEZING POINT: -10"F (-23.3*C)
MSDS Code: 0A48-11-04-93 Page 3 Issue Date: 09112/96 Continued on Page 4 000175 Assigned to: ???? .iju'a r axuvn.uemand. FOR INFORMATION ONLY November 1,QL I. H-940 APPEARANCE AND ODOR: Clear, colorless to pale yellow liquid with no odor. Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY:
Stable CONDITIONS TO AVOID: Overheating.
HAZARDOUS POLYMERIZATION:
Will. not occur INCOMPATIBILITY:
Product is incompatible with strong oxidizers and acids and Is mildly corrosive to aluminum.
Sodium bromide is rapidly attacked by bromine trifluoride.
DECOMPOSITION PRODUCTS:
In fires fueled by other material, hydrogen bromide or bromine may be released.
Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT: Product Oral LDso (rat): > 5000 mglkg Product Dermal LDso (rabbit):
> 2000 mcIkg Section 12. ECOLOGICAL INFORMATION ON PRODUCT: Aquatic toxicity data: The product is an aqueous sodium bromide solution.
This data is not on the product as is, but rather on the activated product which is hypobrornous acid. Values presented are for hypobromous acid expressed as bromine.
48 hr LCso (Daphnla magna): 0.7i ppm 96 hr LCs 0 (bluegill sunfish):
0.52 ppm 96 hr LCso (rainbow.trout)!
0.23 ppm Environmental data: Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge.
Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority.
For guidance contact your State Water Board or Regional Office of the EPA. Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would not be considered a RCRA Hazardous Waste. DISPOSAL-Dispose of in accordance with local, state and federal regulations.
Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:
Class/Division:
Not restricted Proper Shipping Name: Not applicable MSDS Code: 0A48-11-04-93 Issue Date: 09112/96 Page 4 Continued on Page 5 000176 Expires On: pq&#xfd;4 06&#xfd;->
Assigned to: ???? FOR INFORMATION ONLY Expires On: \?? '97> I ~ ~H-90 _ _ _ Label: None Packing Group: Not applicable ID Number: Not applicable Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA: Pesticides are exempted by TSCA (the Toxic Substances Control Act), under Section 3(2)(a)ii, from the provisions of the Act. CERCLA reportable quantity of EPA hazardous substances in product: Chemical Name RQ No ingredients of this product have CERCLA reportable quantities.
Product RQ: Not applicable (Notify EPA of product spills exceeding this amount.) SARA TITLE IIl: Section 302 Extremely Hazardous Substances:
Chemical Name CAS # RQ TPQ There are no SARA 302 Extremely Hazardous Substances In this product.
Section 311 and 312 Health and Physical Hazards: Immediate Detayed Fire Pressure Reactivity
[yes) [yes] [no] [no] [no] Section 313 Toxic Chemicals:
Chemical Name CAS # % by Weight There are no reportable SARA 313 Toxic Chemicals in this product.
Section 16. OTHER INFORMATION HMIS RATINGS: Health = 2* Flammability
-0 Reactivity  Personal Protective Equipment
= X (to be specified by user depending on use conditions)
*Them are potential chronic health effects to consider.
Hazard ratkig scale: 0-Minimal 1 -Slight 2-Moderate 3-Serious 4-Severe MSDS REVISION
 
==SUMMARY==
: Supersedes MSDS issued on 08/19194.
The MSDS has been changed in Sections 7,9, and 12.  ?-2.1e ui.& inFozoat:icc and xecccndations set toztbL bezein' are believed to be *ccux*ae as of the dat- hezeof, CORPOERATION tKA=E NO WIRRANY WITH EESPECT HERETO AMi DI5CLAIUS ALL. W;.BXITY FROM RM~ZMZCE THMEREN.
PREPARED BY: P.J. Maloney MSDS Code. 0A48-11-04-93 Page 5 Issue Date: 09/12/96 Last Page UO(17 BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 08-APR-1999 PRINTED DATE: 08-APR-1999
: 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SLIMICIDE C-68 PRODUCT APPLICATION AREA: WATER-BASED MICROBIAL CONTROL AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CHEMICAL NAME 10377-60-3 26172-55-4 MAGNESIUM NITRATE Oxidizer; irritant (eyes and skin) 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE Corrosive; toxic (by ingestion and skin absorption) sensitizer (skin)No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
PAGE 1 CONTINUED 000178 32, 3 CAS#
PRODUCT NAME: SLIMICIDE C-68 EFFECTIVE DATE: 08-APR-1999
: 7) HANDLING AND STORAGE HANDLING:
Contains an oxidizer.
Avoid all contact with reducing agents, oils, greases, organics and acids. Corrosive to skin and/or eyes. STORAGE: Keep containers closed when not in use. Store between 20-10OF for no more than 6 months. Store upright in original vented containers.
Product evolves C02 slowly. Store samples in plastic bottles due to pressure build-up. 
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME MAGNESIUM NITRATE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED MISC: Note-mfg.
sugg. exp. limit:0.1 mg/m3 TWA;0.3mg/m3 STEL total isothiazoline).
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with organic vapor/acid gas cartridges and dust/mist prefilters.
SKIN PROTECTION:
gauntlet-type butyl gloves, chemical resistant apron-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield CONTINUED PAGE 4 000179 PRODUCT NAME : SLIMICIDE C-68 EFFECTIVE DATE: 08-APR-1999
: 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Gray. (70F,21C)
Freeze Point (F) 28 Freeze Point (C) -2 Viscosity(cps 70F,21C) Odor Appearance Physical State Flash Point P-M(C pH As Is (approx.)
Evaporation Rate (Ether=1)1.033 8 C)Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Slight Light Yellow To Green Liquid > 200F > 93C 3.0 < 1.00 NA = not applicable ND = not determined
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"1B 13 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: Teratology
: Dermal LD50 RABBIT: NOTE -Estimated value Skin Sensitization HUMAN: Non-Ames Mutagenicity
:>5,000 mg/kg NEGATIVE >2,000 mg/kg POSITIVE NEGATIVE CONTINUED-18.0 < 1.00 100.0 0001S0 PAGE 5 EFFECTIVE DATE: 08-APR-1999 PRODUCT NAME : SLIMICIDE C-68 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50: 8.7 mg/L No Effect Level: 6.5 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay Mortality was observed in lowest concentration tested. Test concentrations were analytically verified.
LC50: 2.9 mg/L 10% Mortality:
.6 mg/L Bluegill Sunfish 96 Hour Static Acute Bioassay LC50: 12.1 mg/L No Effect Level: 6.5 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: 6.6 mg/L No Effect Level: 2.5 mg/L Rainbow Trout 14 Day Chronic Bioassay LC50: 4.6 mg/L No Effect Level: 3.3 mg/L Fathead Minnow 36 Day Early Life Stage Test Lowest Effect Level: 4 mg/L No Effect Level: 1.3 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay LC50: 20 mg/L No Effect Level: BIODEGRADATION COD (mg/gm): TOC (mg/gm): BOD-5 (mg/gm): BOD-28 (mg/gm): 12 mg/L 17 Calculated 6 Calculated 0 Calculated 0 Calculated PAGE 6 CONTINUED 0001$I PRODUCT NAME : SLIMICIDE C-68 EFFECTIVE DATE: 08-APR-1999
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material. 
: 14) TRANSPORT INFORMATION DOT HAZARD: Corrosive to skin UN / NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 15) REGULATORY INFORMATION TSCA: This is an EPA registered biocide and is exempt from TSCA inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER: 3876- 143 FOOD AND DRUG ADMINISTRATION:
21 CFR 176.300 & 176.170 (slimicides and as a preservative)
When used in this specified application, all ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a)(4).
USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS: SEC.G5,G7 SARA SECTION 312 HAZARD CLASS: Immediate(acute);
Delayed (Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
CAS# CHEMICAL NAME 10377-60-3 MAGNESIUM NITRATE CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds PAGE 7 RANGE 2.0-5.0%CONTINUED 001S; PRODUCT NAME: SLIMICIDE C-68 EFFECTIVE DATE: 08-APR-1999 MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds
: 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health Fire Reactivity Special (1) Protective Equipment 3 1 0 CORR D Serious Hazard Slight Hazard Minimal Hazard DOT corrosive Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG MSDS status: EFFECTIVE DATE 22-AUG-1995 12-MAR-1996 21-JUN-1996 28-SEP-1996 02-SEP-1997 01-MAY-1998 08-APR-1999 REVISIONS TO SECTION: REVISED FORMAT ;EDIT:9 15 3,5,14 12 15;EDIT:9
;EDIT:9 SUPERCEDES
** NEW ** 22-AUG-1995 12-MAR-1996 21-JUN-1996 28-SEP-1996 02-SEP-1997 01-MAY-1998 PAGE 8 O001,93 Assigned to: ???? FOR INFORMATION ONLY SW' F.- 610 889 4736 Eafterit Power Groul p* 70 H-550I Expires On: ' 1- 7 _Adfk QP.O. Box 1W4 "P" ibUrgh, PA 15230-1341 AIF n Phone-(412)94-8M00 CHIEMTRECo 1"-80o-424-9300 MATERIAL SAFETY DATA SHEET Section .1. PRODUCT IDENTIFICATION PRODUCT NAME: "-550 CHEMICAL DESCRIPTION:
Glutaraldehyde, 50% aqueous solution PRODUCT CLASS: Biocide MISDS CODE- 613&5-0-29-6 Section 2. INFORMATION ON INGREDIENTS CAS % by ..reinal Name Weight OSHA PEL ACGIH TLV Glutaraldehyde 11 1-3o-e 50 None established Ceiring 0.2 ppm, 0.82 mg/rn 3 Section 3. HAZARDS DENTIFICATI ON * ****************.~~~
EMERGENCY OVERVIEW *** ************** . Clear, coloriess liquid with sherp odor. DANGER! May cause severe eye and skin damage. Harm-fuf if inha'ed.
May be fatal if swallowed, Harmful if absorbed through skin. Prolonged
'or frequently repeated skin contact may cause allergic reactions in some indMvduals.
Causes asthmatio signs and sylTnoms in hyPer-reactive individuals.
PRIMARY ROUTES OF ENTRY: Eye and skin contact inhalation, skin absorption, ingestion TARGET ORGANS: Eye, skin, mucous membranes MEDICAL COND$TIONS AGGRAVATED BY EXPOSURE-Skin contact may aggravate an existing dermatitis.
Inhalation of material may aggravate asthrna and inhlarnmatory or fibrotic pulmonary disease.
MSDS Code- (B&85-01-29-96 i s u e D ra t e : 1 0 0 6 C o n t i n u eaPg e 1 IssueDate 10/6(97Coltinued on Page 2 0001J4 -
Assigned to: ???? FOR INFORMATION ONLY Expires On: k. A 610 $69 4736 Eastern Power Gr'oup 'a0o0A 06 7 i .~H-55o0 POTENTIAL HEALTH EFFECTS: EYE CONTACT: Liquid wdIl cause a severe and persistent cornunctivtis.
seen as excess redness ani mar*ed swelling of the conrPijiva with profuse discharge.
Severe comeal injury may develop, which could permanently impair vision if promt first-aid and medical treatment are not obtained.
Vapor will cause stinging sensations in the eye unth excess tear production, blinking, and possibly a slght excess redness of the conjunctiva.
SKiN CONTACT: Brief contact with the product will cause itching With mild to moderate loc6a redness and Possiy swelling.
Prolonged contact may result hi pain, severe redness and swellrmg, with ulceration, tissue destruction, and possibly bleeding into the inflamed area. Glutaraldehyde may be absorbed through intact skin. Therefore.
prokonged or widespre a contact with the product may result in the absorption of potentially harmful amounfts of materia and may affect the central nervous system producing headache, dizziness, and dullness.
This product may cause allergic contact dermatitis in a small portion of indiMduals.
Sensitfzation reactions usually result from contact with the liquid, but occasionally there may be a reaction to giutaraldehyde vapor. INGESTION:
Swallowing this product may cause moderate to marked irritation and possibly chemical burns of the mouth, throat, esophagus, end stomach, with discomfort or pain in the moUth, throat, chest, and abdomen, nausea, vomiting, diarrhea, dizziness, faintness, doowsiness, weakness, thirst, circulatory shock, collapse, and coma. INHALATION:
Product vapor is irritating to the respiratory tract. causing stinging sensations in the nose and throat, discharge from the nose, possibly bleeding from the nose, coughing, chest discomfort and tightness, difficulty with breathing, and headache.
Severe exposure may cause central nervous system depression with dizziness and drowsiness.
The odor thmrshold of giutaraidehyde is 0.04 ppm whereas the irritation threshold is 0.3 ppm. If vapors are concentl-ted enough to be irritating, the "fV is probably being exceeded.
Inhalation of product can cause signs and symptoms of an asthmatic atac3< in hyper-roact1ve i=4'nz4Jdua!s.
SUBCHRONIC, CHRONIC: Repeated skin contact may cause a cumulative dermatitis.
CARCINOGENICITY:
NWP: 'No ingredients Wted in this section' IARC: No ingredients listed in this section* OSHA: "Na.ingredients fisted In this section.
Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Do not remove contact lenses, if worn. Seek medical aid immedatela.
SKI N CONTACT: In case'of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Seek medical aid irnmedlazely.
Wash clothing before rouse. MWDS Code: 0885-01-29-96 Issue Date: 10/06/97 Continued on Page 3 0001S5\??
Assigned to: ???? FOR INFORMATION ONLY Expires On: '? 18:67 FAX 610 as 76 ?6 EAStern Power Group roic' H-550 INGESTION:
DO NOT INDUCE VOMITNG. Do not give anything to drink. Seek medical advice with urgency. Note to Physician:
Aspiration may cause lung damage. Probable mucosal damage may contraindicate the use of gastric lavage. INHALATION:
if inhaled, remove to fresh air. If not breathing, give arificial respiraton.
If breathing is difficult, give oxygen. Seek medical aid. Section 5. FIRE-FIGHTING MEASURES FLASH POINT: None Non-flammabte (aqueous solution):
After water evaporates, remaining Maftal wall bum. LOWER FLAMMABLE LIMIT: Not determined UPPER FLAMMABLE LIMIT: Not derermlned AUTO-IGNITION TEMPERATURE:
Not available EXTINGUISHING MEDIA: Use alcohol-type or alI-purpose-type foam, applied by manufacturers recommended techniques for large fires. Use carbon dioxide or dry chemical media for small fires. FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A Self-contained breathing apparatus and protective clothing are essential.
FIRE & EXPLOSION HAZARDS: No unusual hazards.
DECOMPOSMTON PRODUCTS:
Thermal decomposition or combustion may produce carbon dioxide and carbon monoxide.
N1.PA Health= 3 : am -r , a U- -Reac,. Hlaza-'d =None H.azTd -radng scale: omMirnimal 1 =Snght 2=M'oderata 3=Seoius 4=Sevarke Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERFAL IS RELEASED OR SPILLED: Wear suitable protective equipment Toxic to fish: avoid discharge to natural waters. Very low concentrations (5 ppm or less of glutaraldehyde) can be degraeds in a biological treatment system. Thus, small spills can be flushed with large quantities of water. Large quantities or "slugs can be harmful to the treatment system. Thus, large spills should be collected for diSposal.
It may also be possible to spilled material by careful appliation of aqueous sodium hydroxide or dibasic ammonium phosphate solution.
Depending on conditions, considerable heat and fumes can be liberated by the decontamination reaction.
M $SO, Code: 01385-011-29-96 p g Issue Date: I 0106(7 Continued ort Page 4 0001SG-Assigned to: ???? FOR INFORMATION ONLY ""+/- s -I-A 610 869 4736 12 3 , 1 0 astern Power Group H-550 Section 7. HANDLING AND sTORAGE HANDLING:
It is a violation of Federaj law to use this product in a manner inconsistent with its labeling.
Do not get in eyes, on skin or clothing.
Avoid breathing vapor.  'Use with adequate ventilation.
Wash thoroughly after handing. Keep container closed when not in use. Remove conlaminated clothing and wash before reuse. Discard contaminated leather articles such as shoes and belt. STORAGE: Glutaraldehtyde solutions can be stored and handled in pItyethylen, stainless steel, or reinforced epoxy-plastic equipment.
For shor storage times (up to about 1 month), temperatures of up to 100'F (38 'C) can be tolerated but the preferred maximum storage temperature is about 807F (27 ".C). Section 8. EXPOSURE CONTROLS I PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION-:
Chemical splash goggles and face shield SKIN PROTECTION:
Chemical resistant gloves and protective clothing (Recommended glove materials include rubber, nitnie (NER), buyfl, and polyethylene.)
RESPIRATORY PROTECTION:
If airbome concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
CONTHOLS:
GOR-o.J ('rech5aiza!)
room verafla:Pon is eetd :o e Sas!ecorv
~i :nis rna.'.eia; is kept in covered equipment or it the soluttion is highly diiute-J.
However, if vacors are strong enough to irritate the nose or eyes, the exposure limits are probably being exceeded and speciaJ ventilation may be required.
WORK PRACTICES:
Eye wash station and safety shower should be accessible in the immediate area of use. SATISFACTORY MATERIALS OF CONSTRUCTION:
Stainless steel types 304 and 316. Nickel, Polyethylene, and Fiberglass-reinforced plastics:
Polyester (e.g., Atlab 382) and Vinylester (e.g., Derakane 411 or 470). Recommended gasket materials:
Silicone, Teflon, Kalrez. or GrafoiL UNSATISFACTORY MATERIALS OF CONSTRUCTION:
Gluraraldehyde solutions are incompatible with many commonly used Materials of construction such as carbon steel, iron, aluminum, tin, zinc, copper and monel. iUned steel containers are not recommended for bulk storage, since pinholes could cause product contamination.
Rubber linings are also unsuitable because of swelling.
Do not use Viton. Section 9. PHYSICAL AND CHEMICAL PROPERTIES Expires On: k??BOILING POINT: 214.217 (101.2"C) 0 760 mnHg VAPOR PRESSURE-15.0 mmHg a 20"C SOLUSIOTY IN WATER Complete SPECIFIC GRAVITY: 1.127- 1.133 @ 20120"C MADS Code: 0188501-29-96 Issue Date: 10/06(97 e Page 4 Continued an Page S 0001S7 Assigned to: ???? FOR INFORMATION ONLY (9/./9 -19:59 FAX 610 869 4736 Eastern Power Group 76 5 VAPOR DENSITY (air=i): 1.05 %VOLATILE BY WEIGHT: Expires On: "? Q006fo1jT pH: 3.1 5 @ 25"C Not available FREEZING POINT: -6"F (-21'0)APPEARANCE AND ODOR: Clear, colorless liquid with sharp odor. VISCOSITY:
2f cps @ 20"C Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY; Stable HAZARDOUS POLYMERIZATTON:
Will not occur CONDITIONS TO AVOID: Avoid high temperature and evaporetion of water. Although polymerization may Occur, it is not hazardous.
INCOMPATIBILrTY:
Alkalies catalyze an aldol-type condensation reaction, which is exotheruc
.,but not expected to be violent DECOMPOSITION PRODUCTS:
Thermal decomposition or corribustioi may produce carbon dioxide and Carbon monoxide.
Section 11 TOXICOLOGICAL INFORMATION ON PRODUCT: Toxicologieal data on Inhalation effects: An NTP inhalation study indicatod that gtutaraldehvde exoosure in rats and mice resulted in a spectrum of necmtic, inflammatory, and reqenerative lesions in the u.ner re pi.-ato.r-v -rrz Th -csrrve-j : eh-fc, levi fo, re.piatcy,, es5ons Per b:!,as ,n. The stay, no'v.ever, did not detect any no-ooserved-adverse-effect level for mice. lnf;ammathon was found in the frontal nassl passage of tne mouse at concenrraion as low as 62-5 ppb. Toxicological data on chronic effects Studies in humans have shown that is neither phototoxic nor a photosensitizer.
Subchronfc drln"dn water studies in rats, mice and dogs using concenlrations up to 1000 ppm showed no evidence for any target organ toxicity-in vitro studies for genotoxicity using a variety of assays have given results varying from no activity to weakly positive; however, all In vivo studies for genotoxicity have been uniformly negative.
Several developmentaJ toxicity studies have demonstrated that at maternally nontoxic doses, glutaraidehyde does not produce fetotoxic, embryotox[c or teratogenic effects. In a chronic (2-year) continuous drinking water combined chronic tkwity-oncogenicity study using Fischer 344 rats, there was no evidence for non-oncogenic target organ toxicity.
The only possible oncogenicity-related finding was an increase in the incidence of large granular cell lymphocytic leukemia in female, but not male, rats. The pattern of the response suggests that it does not represent direct chemical carcinogenic activity but, rather, a modifying influence on the expression of this spontaneous and commonly occurring neoplasm in the FPscher 344 rat ON INGREDJENTS:
Chemiady Name Glutaraldehyde Oral LD 134 mg/kg Dermal LPSO 2550 mgkg (25% soen)Inhalation LCMo (rat) 480 rngtms/4H MSDS Codet. O985-01-29-g6 Issue Date: 10106197 Continued on PWg 6 00(s8_
Assigned to: ????
wi ZO:O0 FAX 6..0 8S9 4736 FOR INFORMATION ONLY Eastern Power Group H-5I Section 12. ECOLOGICAL INFORMATION ON PRODUCT: Environmental data: This product is toxic to fish. Do not discharge effluent containin this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a National Polluant Discharge Eflmination System (NPDES) pernmi and bhe permtting authority has been notified in wdrn prior to discharg.
Do not discharge erffuent this product to sewer systems without previously notifying the local sewage treatment plant authodrY.
For guidance contact your State Water Board or Regioal Office of the EPA. Modified Test for Ready Biodegradion.:
79.7% DOC ON INGREDIENTS: .eMicaI Name Glutaraldehyde (50% active soulrlon)AgyaWic Toxicfty Date 96 hr LCs0 (bluegll sunfish):
22 ppm 96 hr (rainbow trout): 24 ppm 48 hr LCs (Daphnia):
12 ppm 96 hr LCso (fathead minnow): 12 ppm 96 hr LC 5 s> (sheepshead minnow): 64 ppm 96 hr LC 5 0 (mysid shrimp): 14 ppm Q -.- , .. ---,4 J 13.I L-. U1-SAL. w U DERII A'TIONS RCRA STATUS: Discarded ,roduc-t, as sold, not be considered a RCRA Waste. D:SPSAL: Pesticide was:es are acutoly k'azarclous.
frnpr.opoe disposal of excess pesticioe, spray mixTure, cr risate is a vioiation ot Federal law. If Mese wastes cannot be disposed of by use according to latel instructions.
contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION: assf/Dvision:
8 Proper Shipping NamL- Corrosive liquid, acidic, organic, n.c-s. (contains Glutarakdhde)
Label: Corrosive Packing Group: It ID Number' UN 3265 Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA: The ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory.
MSDS Code: 0B85-01-29-96 issue Date: 10/06/97 Continued on Page 7 0001S9 Expires On: X??"-50 I Assigned to: ???? FOR INFORMATION ONLY Expires On: 3/39 IE200 U61 8476Eastern Power Group JOV6 CERCI.A reportable Quantity of EPA hazardous substances in product ChernkmLNamp RO NO ingrelifents of this product have MIRCLA reportable quantities.
Product R0. Not applieabe (NOtify EPA Of Product wpills exceeding this amount) SARA TITLE Ill Section 302 Extremely Hazrdous Suabstances Chemical Name CA R Q.Q There are no SARA 302 ExtremetY HaZardous Substnces in ithis product.
section SI11 and 312 HeAfth and Physical Kazrdsv.
Imrnediiale Delayed Fire Pressure ReactIvty
[e)[Yes] [no) [no] [nol Section 313 Toxic Chemicals:
Chemical Name- GAS 0 Then' ale n0 reportable SARA 313 Toxic Chemicals In this Product.
Section 16. OTHER INFORMATION WM!S RA-riNGS:
Hpei Irh = 'Ffarnrnab~if-y
= 0 Reaccivitv C) Pe-s,-r'~
af z"j Eq;iamen = X '!o Iae -arxfied r-e -nTh &;s= ccooiors&#xfd;
'There are potential chronic health effects to coosider.
Hazard rabhg scale OMirirma!
)=r 2=Atodoraia 3--Serous 4=Savcre MSOS REVISION
 
==SUMMARY==
: Supersedes MSDS issued on 0-9/25/97.
The MISDS has been changed in Section 2. w~iae a-is izrozuatiou ao reco=A~dat:ozx set crctt.. hee are kbeli.eved to te a~c--rte as of thxe dare baieof, CALGOm ~ce"oRA=-M A NCez~ WAc PNT Wa-1-V =SPEC- Krrs v 2ME~ ARD :SCAjjs~ M.1, ;AB7Z:i::
msoir, .1ZLZANCE CNERM, PREPARED BY: R.J. Maloney MVSDS Code, 0B8&!01-29.96 Page 7 Issue Date: 10106(97 Last Page 000190-BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 25-FEB-1997 PRINTED DATE: 25-FEB-1997
: 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : BETZ 860 PRODUCT APPLICATION AREA: WATER-BASED DEPOSIT CONTROL AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME TRADE SECRET INGREDIENT(E195);TSRN 125438 -5118P Irritant (eyes) TRADE SECRET INGREDIENT(122);;TSRN 125438 -5214P Potential irritant (eyes) TRADE SECRET INGREDIENT(222);TSRN 125438 -5238P Oxidizer; corrosive; pulmonary damage; dental erosion No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
PAGE 1 CONTINUED 000191-PRODUCT NAME: BETZ 860 EFFECTIVE DATE: 25-FEB-1997
: 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING May cause slight irritation to the skin. Severe irritant to the eyes. Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract. DOT hazard: Corrosive to steel Emergency Response Guide #154 Odor: Acid; Appearance:
Yellow To Dark Brown, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight irritation to the skin. ACUTE EYE EFFECTS: Severe irritant to the eyes. ACUTE RESPIRATORY EFFECTS: Primary route of exposure;Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract. INGESTION EFFECTS: May cause slight gastrointestinal irritation.
TARGET ORGANS: Prolonged or repeated exposures may cause primary irritant dermatitis and/or toxicity to the lung. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Inhalation may cause irritation of the respiratory tract. Skin contact may cause itching and/or redness.CONTINUED 0009r*3,>PAGE 2 PRODUCT NAME : BETZ 860 EFFECTIVE DATE: 25-FEB-1997
: 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F P-M(CC) MISCELLANEOUS:
Corrosive to steel UN3264;Emergency Response Guide #154 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill.
PAGE 3 CONTINUED 0001.93 PRODUCT NAME : BETZ 860 EFFECTIVE DATE: 25-FEB-1997
: 7) HANDLING AND STORAGE HANDLING:
Contains an oxidizer.
Avoid all contact with reducing agents, oils, greases, organics and acids. STORAGE: Keep containers closed when not in use. Use approved containers only. Store in cool, well-vented area. Contact with metals may release flammable hydrogen gas. 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME TRADE SECRET INGREDIENT(E 195);TSRN 125438 -5118P PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED TRADE SECRET INGREDIENT(122);;TSRN 125438 -5214P PEL (OSHA): NUISANCE DUST TLV (ACGIH): 5 MG/M3 MISC: Note: manufacturer's recommended exposure limit: 10 mg/m3. TRADE SECRET INGREDIENT(222);TSRN 125438 -5238P PEL (OSHA): 5 MG/M3(IOMG/M3-STEL)
TLV (ACGIH): 5 MG/M3(10MG/M3-STEL)
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
An air-supplying respirator (positive pressure full facepiece) may be needed for this product.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles PAGE 4 CONTINUED 00019 4 PRODUCT NAME : BETZ 860 EFFECTIVE DATE: 25-FEB-1997
: 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F) Freeze Point (F) Viscosity (cps 70F)1.098 26.00 ND Odor Appearance Physical State Flash Point (F) pH As Is (approx.)
Evaporation Rate (Ether=l)Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water)Acid Yellow Liquid > 200 1.4 < 1.00 S18.0 < 1.00 100.0 To Dark Brown P-M (CC)NA = not applicable ND = not determined
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with organics or alkaline materials.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "D11 Di 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: >2,000 mg/kg NOTE -Estimated value Dermal LD50 RABBIT: >2,000 mg/kg NOTE -Estimated value Inhalation LC50 RAT: >2,000 ppm/hr NOTE -Estimated value 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY No Data Available.
BIODEGRADATION COD (mg/gm): 443 TOC (mg/gm): 203 BOD-5 (mg/gm): 381 BOD-28 (mg/gm): 505 CONTINUED 000.195 PAGE 5 PRODUCT NAME : BETZ 860 EFFECTIVE DATE: 25-FEB-1997
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is D002 = Corrosive(pH, steel). Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material. 
: 14) TRANSPORT INFORMATION DOT HAZARD: Corrosive to steel UN / NA NUMBER: UN3264 DOT EMERGENCY RESPONSE GUIDE #: 154 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): 9,111 gallons due to (122);5,466 gallons due to (222); SARA SECTION 312 HAZARD CLASS: Immediate(acute);Delayed (Chronic)
SARA SECTION 302 CHEMICALS:
CAS# CHEMICAL NAME TRADE SECRET(222)
--INORGANIC ACID SARA SECTION 313 CHEMICALS:
CAS#CHEMICAL NAME TRADE SECRET(222)
--INORGANIC ACID RANGE 2.0-5.0%CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds CONTINUED 0001196 PAGE 6 PRODUCT NAME : BETZ 860 EFFECTIVE DATE: 25-FEB-1997
: 16) OTHER INFORMATION CODE TRANSLATION Health Fire Reactivity Special (1) Protective Equipment 2 1 0 CORR B Moderate Hazard Slight Hazard Minimal Hazard DOT corrosive Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE MSDS status: 22-AUG-1995 28-SEP-1996 25-FEB-1997 REVISIONS TO SECTION: REVISED FORMAT 3,5,14 12 SUPERCEDES
** NEW ** 22-AUG-1995 28-SEP-1996-PAGE 7 00(019:7 NFPA/HMIS FOR INFORMATION ONLY Coagulant Aid 35 P.O. Box 1346 Pittsburgh.
PA 15230-1346 Phone-(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: Coagulant Aid 35 CHEMICAL DESCRIPTION:
Bentonite, a colloldal clay (aluminum silicate) that consists primarily of montmnorillonite PRODUCT CLASS: Water treatment MSDS CODE: 0378-04-25-95 Section 2. INFORMATION ON INGREDIENTS CAS % by Chemical Name Number Weight OSHA PEL ACQG,-I 11 V Silica, crystalline, quartz, respirable dust 14808-60-7
< 2 TWA 0.1 mg!m3 TWA 0. 1 mrg/rn" Section 3. HAZARDS IDENTIFICATION"EMERGENCY OVERVIEW*&#xfd;* *** -* r * ** w -*WARNING! May cause respiratory tract and eye irritation.
Prolonged inhalation of product dust may cause lung injury or disease.
Causes slippery surfaces when wet. PRIMARY ROUTES OF ENTRY: Inhalation, eye contact TARGET ORGANS: Lung, eye MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Pre-existing chronic lung conditions such as, but not limited to, bronchitis, emphysema, and asthma. POTENTIAL HEALTH EFFECTS: EYE CONTACT: This product is expected to cause eye irrtation due to mechanical action. SKIN CONTACT: The product is not expected to cause skin irritation upon contact. No data is available to suggest that this product may produce an allergic skin reaction or be absorbed through the skin in harnmful amounts.MtSU Code: 037&0-4-25-95 Issue Date: 11/07/95 Continue ;onPage 2 000198 a Assigned to: ????Expires On: I-'I ON, IWWV' Assigned to: ???? FOR INFORMATION ONLY Expires On: \?? r a)c-vt-Uemana "bIJSgtI floolmOel' T Coagulant Aid 35 __ INGESTION:
This product would be expected to be practically non-toxic by ingestion.
INHALATION:
Exposure to high dust concentrations may produce irritation to the nose, throat, and respiratory tract. Inhalation of large amounts of dust of this product may produce shortness of breath and reduced pulmonary function.
* SUBCHRONIC, CHRONIC: Inhalation of dusts of this product over a prolonged period of time may produce lung injury or disease like silicosis.
Silicosis is a chronic disease characterized by the formation of scattered sirzca-containing nodules of scar tissue In the lungs. Silicosis usually begins with symptoms of coughing, breathing difficulty, wheezing, and repeated, non-specific chest illnesses.
Impairment of pulmonary function may be progressive.
This product contains a srnall amount of free crystalline silica which upon prolonged inhalation has exhibited evidence of carcinogenictty.
CARCINOGENICITY:
NTP: Respirable crystalline silica is a NTP anticipated carcinogen (6th Annual Report. 1991). IARC: Respirable crystalline silica is an IARC probable human carcinogen (Group 2A); human evidence-limited.
animal evidence-sufficient.
OSHA: No ingredients listed. Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water. Seek medical a;d if irritation persists.
SKIN CONTACT: Not expected to require first aid measures.
INGESTION:
Not an expected route of overexposure.
INHALATION:
If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give "oxygen. Seek medical aid. Section 5. FIRE-FIGHTING MEASURES FLASH POINT: Not applicable Product is noncombustible.
LOWER FLAMMABLE LIMIT: Not applicable UPPER FLAMMABLE LIMIT: Not applicable AUTO-IGNITION TEMPERATURE:
Not applicable EXTINGUISHING MEDIA: Use extinguishing media appropriate for the surrounding fire. FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective clothing are essential.
MSDS Code: 0378-04-25-95 c'a'9'e-2:
Issue dale: 11/07195 Continued on Page 3 000199 Assigned to: ???? nwa. t4a-sn-eamO  FOR INFORMATION ONLY "tov-wbse ZU, I Coagulant Aid 35 -FIRE & EXPLOSION HAZARDS: No unusual hazards.
DECOMPOSITION PRODUCTS:
None NFPA RATINGS: Health = I Flammability
-0 Reativity 0 Hazard rating scale: 0-Minimal 1-Slight 2-Moderate 3-Seious 4-Severe Special Hazard = None Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wearing appropriate persona) protective equipment, vacuum i0 possible to avoid generating airborne dust, and place into a suitable container.
Avoid using water as the product will become slippery when wet..7 L A111,gm-.
.flMINULIL-i AF b l UHAGE HANDUNG: Avoid breathing dust. Avoid contact with eyes. Use with adequate ventilation.
Wash thoroughly after handling.
Keep container dosed when not in use. STORAGE: No specific information.
Section 8. EXPOSURE CONTROLS/
PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYEIFACE PROTECTION:
Chemical splash goggles SKIN PROTECTION:
No special requirement.
RESPIRATORY PROTECTION:
If airborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR.1910.134).
ENGINEERING CONTROLS:
Use IocaJ andtor general exhaust ventilation to maintain airborne ooncentrations below exposure limits. WORK PRACTICES.
Ensure all equipment is properly grounded to prevent static electricity discharge.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOIUNG POINT: Not applicable VAPOR PRESSURE:
Not applicab4e VAPOR DENSITY (air-l)):
Not applicable SOLUBILITY IN WATER: Negligible SPECIFIC GRAVITY: 1.2 (1% aqueous suspension) pH: 8-5 -10.5 (5% suspension)
Issue Date: 11107/95 ued on P-e 4 Expires On: '-?00OZ0I AA0MC' Assigned to: ????FOR INFORMATION ONLY Coagulant Aid 35%VOLATILE BY WEIGHT: Not applicable FREEZING POINT: APPEARANCE AND ODOR: Pale gray to buff powder or granules, odorless.
Section 10. STABILITY AND REACTIVITY Not applicable CHEMICAL STABILITY:
Stable HAZARDOUS POLYMERIZATION:
Will not occur CONDITmONS TO AVOID: No specific information.
INCOMPATIBILITY:
No significant incompatibirdies known DECOMPOSITION PRODUCTS:
None Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT: No information available on the formulated product.
ON INGREDIENTS:
Oral LDso Dermal LDSO Inhalation LCso Chemical Name (rat) 'rabbit) (rat) Silica, crystafline, quartz. respirable dust Not available Not available LC. (human): Section 12. ECOLOGICAL INFORMATION ON PRODUCT: No information available on the formulated product.
Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would not be considered a RCRA Hazardous Waste. DISPOSAU Dispose of in accordance with local, state and federal regulations.
Section 14. TRANSPORT iNFORMATION DOT CLASSIFICATION:
Class/Division:
Not restricted Proper Shipping Name: Not applicable Label: None Packing Group: Not applicable ID Number: Not applicable MSDS Code: 0378-04-25-95 Issue Date: 11107/95 Continued on Page 5 Expires On: \??I Assigned to: ???? FOR INFORMATION ONLY Expires On: ;flaD -ftx-900and
~suten mvembr eb.~1t I Coagulant Aid 35 Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA* The Ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory.
CERCLA reportable quantity of EPA hazardous substances in product Chemical Name R. No Ingredients of this product have CERCLA reportable quantities.
Product RQ: Not applicable (Notify EPA of product spills exceeding this amount.) "SARA TITLE 11. Section 302 Extremely Hazardous Substances:
Chemical Name CAS # RO TPQ There are no SARA 302 Extremely Hazardous Substances in this product.
Section 311 and 312 Health and Physical Hazards: Immediate Delayed Fire Pressure Reacthr-y, [yes! [yes] [no] [no! [no] d o,. 313 To xc C' ca s Chemical Name GAS * % by Weicht There are no reportable SARA 313 Toxic Chemicals in this product.
Section 16. OTHER INFORMATION HM IS RATINGS: Health = 1" Flammability 0 Reactivity
= 0 Personal Protective Equipment
-X (to be specified by user depending on use conditions)
*There are potential chronic health effects to consider.
Hazard rating scate: 0-Minimal 1-Sllght 2-Moderae 3-Serious 4-Severe MSDS REVISION
 
==SUMMARY==
: Supersedes MSDS issued on 10(28/92_
The MSDS has been changed in Sections 3 and 8. le 'hLs Intor-zmatjc-awbd zr 'o:h hexcin aze bele.Led to be ac.uzare as of rhe duse hexeom, CA-LGOW1 HO.TZN~AIcE NO WAL.RRJ.r7
--TR RESPZCr HEREO AWD DXSCL.AUIZ ALL UALrn 1TW.Mort REIMANCE THErEON.
PREPARED BY: P.J. Maloney MSDS Code: 0378-04-25-95 Issue Date: 11/07/95 Last Page 00020oooko BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 12-JUN-1998 PRINTED DATE: 23-OCT-1998(ol 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: BETZ CLAM-TROL CT-1 PRODUCT APPLICATION AREA: COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CHEMICAL NAME 107-21-1 68424-85-1 67-63-0 13590-97-1 64-17-5 ETHYLENE GLYCOL Liver, kidney and blood toxin; CNS depressant; animal teratogen (at high oral doses) (C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE Corrosive (eyes and skin);toxic (by ingestion)
ISOPROPYL ALCOHOL (IPA) Flammable liquid; chronic overexposure may cause liver and kidney toxicity DODECYLGUANIDINE HYDROCHLORIDE (DGH) Corrosive ETHYL ALCOHOL (ETHANOL)
Flammable liquid; irritant (eyes); potential and kidney toxin; may cause CNS depression liver 111-46-6 ETHANOL, 2,2'-OXYBIS Toxic (by ingestion);
liver and kidney toxin; CNS depressant 000PEC IDO 3 CAS#CONTINUED PAGE 1 PRODUCT NAME: BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998 HAZARDOUS INGREDIENTS (continued):
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
PAGE 2 CONTINUED 000204 PRODUCT NAME: BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER Corrosive to skin. Corrosive to the eyes. Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract. DOT hazard: Corrosive to skin, flammable Emergency Response Guide #29 Odor: Mild; Appearance:
Colorless To Light Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; Corrosive to skin. ACUTE EYE EFFECTS: Corrosive to the eyes. ACUTE RESPIRATORY EFFECTS: Primary route of exposure;Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract. INGESTION EFFECTS: May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse.
Possible death when ingested in very large doses. TARGET ORGANS: Prolonged or repeated exposures may cause CNS depression, tissue necrosis, and/or toxicity to the liver, kidney, and reproductive system. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Inhalation of vapors/mists/aerosols may cause eye, nose, throat and lung irritation.
Skin contact may cause severe irritation or burns.  -PAGE 3 CONTINUED 0 0~)
PRODUCT NAME : BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 4) FIRST AID MEASURES SKIN CONTACT: Remove clothing.
Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid treatment.
Immediately contact a physician.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: 116F 47C SETA(CC) MISCELLANEOUS:
Corrosive to skin, flammable UN2920;Emergency Response Guide #29 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Remove ignition sources. Flush area with water. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -Dispose of in approved pesticide facility or according to label instructions.
PAGE 4 CONTINUED O0Ok 00 PRODUCT NAME : BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 7) HANDLING AND STORAGE HANDLING:
Combustible.
Do not use around sparks or flames. Bond containers during filling or discharge when performed at temperatures at or above the product flash point. STORAGE: Keep containers closed when not in use. Do not store at elevated temperatures.
Keep away from flame or sparks. 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME ETHYLENE GLYCOL PEL (OSHA): 50 PPM-C TLV (ACGIH): 100 PPM-C (Cl 2-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ISOPROPYL ALCOHOL (IPA) PEL (OSHA): 400 PPM(500PPM-STEL)
TLV (ACGIH): 400 PPM(50OPPM-STEL)
DODECYLGUANIDINE HYDROCHLORIDE (DGH) PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ETHYL ALCOHOL (ETHANOL)
PEL (OSHA): 1,000 PPM TLV (ACGIH): 1,000 PPM ETHANOL,2,2'-OXYBIS PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED MISC: Note-AIHA WEEL of 50 ppm for aerosol and vapor has been established.
PAGE 5 CONTINUED 0 0 "1 PRODUCT NAME: BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with organic vapor cartridges and dust/mist prefilters.
SKIN PROTECTION:
gauntlet-type neoprene gloves, chemical resistant apron-Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Gray. (70F,21C) 1.022 Vapor Pressure (mmHG) 23.0 Freeze Point (F) < -30 Vapor Density (air=1) > 1.00 Freeze Point (C) < -34 Viscosity(cps 70F,21C) 23 % Solubility (water) 100.0 Odor Mild Appearance Colorless To Light Yellow Physical State Liquid Flash Point SETA(CC) 116F 46C pH As Is (approx.)
 
===3.6 Evaporation===
 
Rate (Ether=1)
< 1.00 NA = not applicable ND = not determined
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "iFB" PAGE 6 CONTINUED 000,?8 PRODUCT NAME : BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: 3,270 mg/kg Dermal LD50 RABBIT: >2,000 mg/kg Skin Irritation Score RABBIT: 5.13 Eye Irritation Score RABBIT: 103 NOTE -Max unwashed (day 14); max washed value:101 (day 14) 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Flow-Thru Bioassay LC50: 8.1 mg/L No Effect Level: 6.5 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay LC50: 2.9 mg/L No Effect Level: 2.1 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay LC50: .2 mg/L No Effect Level: .135 mg/L Ceriodaphnia 48 Hour Fiow-Thru Bioassay LC50: .14mg/L No Effect Level: .05 mg/L Mysid Shrimp 96 Hour Flow-Thru Bioassay LC50: .34 mg/L No Effect Level: .1 mg/L BIODEGRADATION COD (mg/gm): 1155 Calculated TOC (mg/gm): 278 Calculated BOD-5 (mg/gm): 24 Calculated BOD-28 (mg/gm): 254 Calculated 0 0 ID9 CONTINUED PAGE 7 PRODUCT NAME : BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is D001 = Ignitable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.14) TRANSPORT INFORMATION DOT HAZARD: UN / NA NUMBER: DOT EMERGENCY RESPONSE GUIDE #: Corrosive to skin, flammable UN2920 15) REGULATORY INFORMATION TSCA: CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): 2,05,9 gallons due to ETHYLENE GLYCOL; FOOD AND DRUG ADMINISTRATION:
21 CFR 176.300 (slimicides for wet end use) When used in this specified application, all ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a)(4).
SARA SECTION 312 HAZARD CLASS: Immediate(acute);
Delayed(Chronic);
Fire SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
CAS# CHEMICAL NAME 107-21-1 ETHYLENE GLYCOL CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds RANGE 21.0-30.0%
MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds CONTINUED O000-AO PAGE 8 PRODUCT NAME: BETZ CLAM-TROL CT-1 EFFECTIVE DATE: 12-JUN-1998
: 16) OTHER INFORMATION CODE TRANSLATION Health Fire Reactivity Special (1) Protective Equipment 3 2 0 CORR D Serious Hazard Moderate Hazard Minimal Hazard DOT corrosive Goggles,Face Shield, Gloves,Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG MSDS status: EFFECTIVE DATE 29-OCT-1997 01-MAY-1998 15-MAY-1998 12-JUN-1998 REVISIONS TO SECTION: 8,15;EDIT:9 2 2,8,15 SUPERCEDES
** NEW ** 29-OCT-1997 01-MAY-1998 15-MAY-1998 PAGE 9 000 _I 1 NFPA/HMIS Assianed to: ?fl? FOR INFORMATION ONLY EprsO:'SODIUM WYPOC1LOpxfE SOLUTION-.- I 12V Sepwmbaq, 19.9g-] -Product ansi Cemaapt 7 d'ntifea~pn MANITfACnURER'S NAME: EMERGENCY TELEPHONE NUMERS ADDRESS: DATE OF REVISION:
2 -Coaposjif fo4ffpafionptp TRADE NAME: Conwonent:
oOJdL'm n yp. ocasorihe Solution, CONTAINS:
Sodium Hydroxide Chlorine (Available)
Water CAS NUMBERh 1310-73-2 7782-50-5 7732-18-5 MANLEY-REGAM CEM AcCAI&S DIVISION OF E+E (US) INC. 800-424-9300 (Chemtrec) 24 hours a day, 7 days a week 532 EAST EMAUS STREET P.O. BOX 280 MIDDLETOWN, PA 17057 800-283-0326 September 19, 1998 SODIM MTOCI.ILORIT,, 15% CL/VOL CASlyumber:
PERCENTAGE:
0.g to 2.4 Approx. 10 Approx. 89.0 7681-52-9 P2L'Thv -SOURcE PEt 8hr 2mg/rm(3)
OSHA TLV Shr Ceiling ACGIR OSHIA (PEt) TWA -0.5 ppm STEL -I ppm ACGIR (TLN) TWA -0.5 ppm STEL -I ppm Synonyms/Common Names; Chemical Formula: DOT Proe Shipping Name: DOT Haird ClAss: DOT I Number DOT Pacldng Group: DOT Hazardous Substanee:
DOT Marine Pollutant Additional Description Requirement Chlorine Bleach, Soda Bleach, Liquid Chlorine NaOC1 HypochIorite Solutions UN1791 RQ 1 00# (Sodium Hypochlorfra)
NIA N/k Page 1 of S ,1- * -/ R flt I I .JGrTu r Vfl I i
* ri,' -r- 4%--.O X Assianed to: ????Expires On: I Assigned to: ???? FOR INFORMATION ONLY Expires On: W?? Jae. &3 Boiling Point Freezing Point Vapor Pressure: (@760 mm Hg) Weight % 10 12 Temperature Deg F 48U2 60.8 68.0 89.6 118.4 Deop2oses aboye 110 Deg C (230 Det.F) FreeziUg Point Deg F 7 -3'minR 8 3.7 8.0 12.1 31.1 1000M PSIA 0.071 0.15 0.23 0.60 1.93 Appmximately 1.19 100%Specific Gravity Solubility in I.hO pH Appc-ance'Odor-(HO) = 1) (By Weight)9-12 Colorless to light yelow-green liquid with chlorine like odor.4-uind Firse Aid EYES: SKIN: INRIALAT]ON:
IN'GESTION:
Immediately flush eyes with flowing water for at least 15 minutes. Washing eyes within one (1) minute is essential to achieve maximum effectiveness.
SEEK MEDICAL A7TT"TION3LVAyTjZy Skin contact may cause severe iritation.
Flush tboroughly with cool water under shower while removing co*ntinted clotding and shoes. Discard non-rubber shoes. Wash clothing before ;euse. Continue to flush until medical attention arrives.
SEEK MEDICAL A Y. Remove to fresh air. If breathing is dificult, have a qualified person administer ox-ygen If respiration stops, give mouth-bto-.nouth resuscitation, GET VM4 E 1TEMA;rCL A TTEZIV2oN.
Never gi1vec any-thinzg
*by m o"u~th to .an unconscious person. If Pwallo'wed,,DO NOT 12DUCE I'OMITETG.
Give large quantities of milic. If these are not available, give large quantifes of water. If vomiting occrs spotaneously keep airmay clear and give more milk or water. Avoid vomiting, lavage or acidic antidotes.
GET MEDI CAL A7TENTION MMEDLAF.-TO PYSIC IAN: Sodium Hypoehloryte Is an alkaline corrosive.
For exposure by Ingestion do not use emesfs, lavage or acidic anfidotes.
Dilute Immediately by giving mikm, nelted Ice cream, beaten egg white, starch paste or antacids such as milk of magnesia, alumnium hydroxide gel or magnesium trislicate gel. Avoid sodurm bicarbonate because of carbon dioxide release. Sodium thiosulfate solution may prove beneficial by reduzcing unreacted materiaL S 'd 2P c~ J~." ICS "S'~S- -............-
00 Assigned to: ???? FOR INFORMATION ONLY Exoires On: ? MINALATION; SKIN: EYE CONTACT: INGESTION:
FUres and FYeTro,-._
oPage 3 of5 Inhalation ofhypochioru add fumes may cause severe respiratory tract iniaon and pulmona-y edema. Skin conact may cause severe irritation and bums. Eye contact may cause severe rtation, bums and/or co'rosion.
Ingestion may cause pain and inflammation of the mouth and digestive syste,,, burns and perforaton of the eophagus or stomach vomiting, circulatory collapse, confusjon delirium and coma.EFFECTS OF OVEREXPOSUm:
Corrosive and strongly irritatin&#xfd;g to the eyes, skin, and respiratory tract. Inhalation Of fumes may cause pulmonary edema, Ingestion may cause burns to the mouth and digestive tract and abdominal distress.
No Data.f -Fire a dn.Finsiozt_ POQL-T (rest niehod) ; AUTOIGNITION TEMPERATUE:
FLAMMAB2LITY LIMJTS IN AIR: LEL: N/A Non-FlammabLe None None UEL: N/A EXTINGUISHMIG MEDIA: Use water spray, fog, foam, dry chemical, or carbon dioxide or agents suitable for materials in surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES:
Avoid fumes from spiled or exposed liquid, dilute copiously, ventilate and be preared to use respiratoiy protection if needed. Use self-conained breathing apparatus and fill protective equpment Acid contamination wi produce very irritating fumes similar to chlorine.
UNUSUAL FIRE AND EXPLOSION HAZARD: Product decomposcs when heated and may cause contaners to rupture or explode. Vigorous reaction is possible with organic matexials or oxidizing agents and may result in fire. CONDITONS CONTRMBUTING TO INSTAB1ILIY:
Strong oxidlzer, stability decreases with concentr&-on, heat, light, decrease in pH and contaminadon by metals. INCOMPATIBILITY Avoid coutamini a with heavy metals, reducing agcats, rther, ammonia, and acids. MAZARDOUS DECOMPOSITION PRODUCTS:
Acid fumes. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:
Material is not known to polymeriz P d &#xfd;-PG IO 3.rL I-PM J I "n- t-
* i. r*-T-
* OOOVi4 ACUTE: CHRONIC: Assigned to: ????FOR INFORMATION ONLY Expires On:?!
FOR INFORMATION ONLY Page 4 of 5 vE Tumfol REQU mM- provide good genera room ventilation plus local exhaust at points of emission.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY; NIOSH/MSHA pproved respirator, following mactw=-s rec= enjs sbould be used as a PeautionalY measwr where airborne contminants may ocur. EYE: Wear chemical saety goggles plus full face shield to protect against splashing when approprifat.
GLOVES: Wear impervious gloves such as rubber, neoprene or vinyl. OTHBR CLOTAING AND EQUIPMIT\:
Wear imperious protective clothing including gloves, apron or raia suit and boots to avoid bodily contactL wash facility and emergency shawer should be in close proxidmit.
2.- and Storae AND STORAG3E PRECAUTfONS:
Do not store adjacent to chemicals that may react if spfllape occurs, Comply with DOT regulations when ShipDed. If closed bo i :-dccmp,&#xfd;scm n&#xfd;ucs @naLn~y au=.' &#xa3;3 ecarb'tcns cids,j_ oxy de r de&#xa2;Posit'oz).
ZDc Cot Z,'AX or coen:&inzt with hyd-'ocabons, acids, alccohc1's Or cther_ " DO INOT REUSE CONTAIN-ERS:
Product residues may remain in containers.
All labeled precautions must be observed.
Dispose ofcontainer in a manner meetin government regulations.
PRODUCT DISPOSAL:
Product should be completely removed from containers.
Material that cannot be used or chemica4ly reprocessed should be disposed of in a manner meeting government regulations.
10O- Envfronnze~a; Procedwsec.
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Do not allow spilled materiaI to enter sewers or streams. Flush with water to dilute as much as possible and pump into polyethylene Contalners for disposal.
Avoid heat and contamination with acid materials.
Do not use combustible materials such as sawdust to absorb Sodium Hypochlorite Solution.
WASTE DISPOSAL METHOD: Reduce with agents such as bisulfites or ferrnus salt solutions.
Some heat will be produced.
Keep on alkaline side and dilute with copious amount of watr. Main end-product is salt wae=t Comply with all applicble governmental regulations.
TOXICOLOGY DATA; The toxicity and corrosivity of Sodium Hypochtorite is a fuiction of concentration.
lndustrial grades of higher concentrations than household bleach are more toxic and Corrosive, Aquatic Toxicity Raft: 96 hr. LC5O Ceriodaphnia dubla: 1.23 ppm Pimephales promelas:
1.19 ppm Sodium Hypocorite
@ 12.5% (Rat, Oral LDS0) Test Result 5.0 g/kg Sodium
@ 5.25% (Ran Oral LD50) Test Result 13.0 g&kg Sd '9E 0 5 Expires On: \??Assigned to: ????
to: ???? FOR INFORMATION ONLY Expires On: ? Page s as Tlis blend does not contain any substances subject to the Planning Quantity CTPQ) requireme=
of SectioM 313 of the act, CONTAINER DISPOSAL:
Dispose in a licensed fadiliD-, Recommed crushjg or other means to prevet unauthorized reuse. NSF LIMITS: NSF Maximum Drlng Water Use Concentration, 100 mg/L as Sodi= HypocRloxte.
The finished dr!ink* water should be monitored for disinfecteon by-produVts in accordance with state and U.S. ,P.A. regulations and guidelines.
Levels of chlorjte ion nd chlorate ion should not eaceed 10 ppb, USDA APPROVAL:
This product is acceptable as a sanitizer for all surfaces not always requiring a rinse in official establishments operating under the Federal meat, poultry, shell eggn and egg products inspection programs.
Section 311 of The Clean Water Act lists this product as a hazardous substance which, if discharged to l teT, may ; eqf re immediate response to mjtga:e ..., Malcdjai is contained on a composite list as required under 101 (24) of CERCLA Sodium Hypocbiorite Solution is regulated by the USEPA under the Federal Insecticide, Fungicide and Rodenticide Acid (FTFRA) as a pesticide product.
DISCLAIMER:
The information and recommendations are offered for the user's conaideration and examination, and it Is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer relabels this product4 legal counsel should be consulted to insure proper health, safety and other necessary information Is lcluded on the comtainer.
Manley-Regan Chemicals provides no warranties, either expressed or implied, and assumes no responsibility for the accmucy or completeness of the data contained herein. The above information complies with the OSHA's hazard communication standard 29CFR1910.1200, The standard must be consulted for speeffic requirement.
9'd 27'W8k1 W--u- WH971N A CCC0 0T AgrEvoo Material Safety Data Sheet Page: 1 of 8 Issue Date: 07/28/98 A company of Hoechst and Schering, Berlin ./ "Supersedes:
02/14/96 NUSYN-NOXFISHW FISH TOXICANT SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION AgrEvo Environmental Health Chestnut Ridge Road Montvale, NJ 07645 COMPANY CONTACT: Regulatory Department TELEPHONE NUMBER: (800)438-5837 EMERGENCY TELEPHONE NUMBER (800)477-0650 PRODUCT NAME: NUSYN-NOXFISH FISH TOXICANT PRODUCT CODE: B467413 CHEMICAL NAME: Mixture; a.l 's, rotenone and piperonyl butoxide EPA REGISTRY NUMBER: 432-550 MSDS IDENTIFICATION CODE/NUMBER:
B467413 Nusyn-Noxfish is a registered trademark of AgrEvo Environmental Health, Inc. PRODUCT DESCRIPTION:
Nusyn-Noxfish Fish Toxicant is a restricted use pesticide to be used in fisheries management for the eradication of fish from lakes, ponds, reservoirs and streams.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS CONCENTRAT ION INGREDIENT NAME EXPOSURE LIMITS PERCENT BY WEIGHT Rotenone ACGIH TLV-TUA 5 mg/m3 = 2.5 CAS NUMBER: 83-79-4 OSHA PEL-TWA 5 mg/m3 Piperonyt Butoxide, technical None established
= 2.5 CAS NUMBER: 51-03-6 Other associated resins None established
= 5 Other ingredients, including:
= 90 Aromatic petroleum solvent 100 ppm (Manufacturer recommended)
< 85 CAS NUMBER: 64742-94-5 SECTION 3. HAZARDS IDENTIFICATION
*****************************
EM4ERG]ENCY OVERVIEW
* A clear to brown liquid with a mild odor.
* Fatal if inhaled.
* May be fatal ff swallowed.
Harmful if absorbed through skin.
* Causes substantial but temporary eye injury.
* Causes skin irritation.
* Combustible mixture.
* This pesticide is extremely toxic to fish. POTENTIAL HEALTH EFFECTS (01 ?117 Page: 2 of 8 Issue Date: 07/28/98 Supersedes:
02/14/96 NUSYN-NOXFISHi FISH TOXICANT SECTION 3. HAZARDS IDENTIFICATION
-Continued PRIMARY ROUTE(S) OF ENTRY Inhalation, ingestion, skin and eye contact.
EYES 'Ca-'uses substantial but temporary eye injury. SKIN -Causes skin irritation.
INGESTION May be fatal if swallowed.
INHALATION Fatal ff inhaled.
SECTION 4. FIRST AID MEASURES EYES 7T7 W-eyelids open and flush with a steady, gentle stream of water for 15 minutes. Get medical attention.
SKIN Wasi, with plenty of soap and water. Get medical attention.
INGESTION Promptly drink a large quantity of milk, egg white, gelatin, solution or if these are not available, large quantities of water. Avoid alcohol. Do not induce vomiting.
Call a physician or Poison Control Center. INHALATION Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth to mouth. Get medical attention.
NOTE TO PHYSICIAN This product is highly toxic when spray mist is inhaled, moderately toxic by the oral route and slightly toxic by the dermal route. This product causes substantial but reversible eye irritation.
Initial treatment is removal of exposure by washing, emesis or lavage and is followed by symptomatic and supportive care. SECTION 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES FLASH POINT: 115 0 F 465C TCC FIRE AND EXPLOSION HAZARDS Keep away from sources of ignition.
EXTINGUISHING MEDIA Fog, foam, carbon dioxide or dry chemical.
FIRE FIGHTING INSTRUCTIONS As i any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH approved (or equivalent) and full protective gear. Keep upwind. Isolate hazard area. Avoid inhalation of smoke and fumes. Use water or foam to reduce fumes. Do not touch spilled material.
If possible, move containers from area. Extinguish only if flow can be stopped. Use flooding amounts of water as a fog. Cool containers with flooding amounts of water from as far a distance as possible.
Avoid breathing vapors. FLAMMABILITY CLASSIFICA TION/RA TING:
Page: 3 of 8 Issue Date: 07/28/98 Supersedes:
02114/96 NUSYN-NOXFISHW FISH TOXICANT SECTION 5. FIRE FIGHTING MEASURES -Continued NFPA/OSHA Class: // NFPA Rating (Fire): 2 SECTION 6. ACCIDENTAL RELEASE MEASURES GENERAL AND DISPOSAL Use proper protective equipment to minimize personal exposure (see Section 8). Take all necessary action to prevent and to remedy the adverse effect of the spill. Ensure that the disposal is in compliance with all Federal, State/Provincial, and local regulations (See Section 13 for applicable RCRA Number). Refer to Section 15 for applicable Reportable Quantity (RQ) and other regulatory requirements.
LAND SPILL OR LEAK Small Spills: Absorb liquid with an inert absorbent material such as granular clay, saw dust, or pet litter. Sweep up carefully while avoiding . the formation of a dust cloud. Place in an approved chemical waste container for disposal.
Rinse spill area with small amount of soapy water. Contain and absorb the rinsate with inert absorbents and place into the same disposal container.
Area can be washed with water to remove the last trace residue. Do not allow water to contaminate water supplies or sewers. Large Spills: Eliminate all ignition sources. Stop leak if you can do so without coming into contact with spilled material.
Dike far ahead of liquid spill for later disposal.
All equipment used to clean up spill should be grounded.
Prevent entry into waterways, sewers, basements or confined areas. Inform appropriate authorities immediately if contamination occurs. Contact AgrEvo for further assistance if necessary.
SECTION 7. HANDLING AND STORAGE HANDLING PRECAUTIONS Z Do not breathe spray mist.
* Do not get in eyes, on skin or on clothing.
* Do not use near heat or open flame. STORAGE PRECAUTIONS
"* Do not store near heat or open flame.  "* Do not contaminate water, food or feed by storage. 
"* Store only in original containers, in a dry place inaccessible to children and pets. Nusyn-Noxfish will not solidify nor show any separation at temperatures down to 401F and is stable for a minimum of one year when stored in sealed drums at 70 OF. WORK/HYGIENIC PRACTICES
"* Wash thoroughly with soap and water after handling and before eating, drinking or using tobacco. 
"* Remove contaminated clothing and wash before reuse. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION MANUFA CTURING. FORMULA TION AND OTHER NON-A GRICUL TURAL USES ENGINEERING CONTROLS Control airborne concentrations below the appropriate exposure guideline (see Section 2 for applicable OSHAIA CGIH Exposure Limits). Local exhaust ventilation may be necessary.
EYE/FACE PROTECTION Wear safety glasses, splash goggles or face shield.000 9 Page: 4 of 8 Issue Date: 07/28/98 Supersedes:
02/14/96 NUSYN-NOXFISit FISH TOXICANT SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
-Continued SKIN PROTECTION Wear chemical-resistant gloves (Neoprene, Nitrile, PVC) and other protective clothing to avoid skin contact.
RESPIRA TORY PROTECTION Ensure good ventilation.
If not adequate, use a chemical cartridge-type respirator approved by the National Institute of Occupational Health and Safety. GENERAL PROTECTION Eye wash facility and safety shower should be available.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Clear, brown liquid. ODOR 707I--odor.
BASIC PHYSICAL PROPERTIES PHYSICAL STA TE: Liquid pH: Not available VAPOR PRESSURE:
Not available VAPOR DENSITY (AIR= 1): Not available EVAPORATION RATE (BUTYL ACETATE = 1): Not available SPECIFIC GRA WTY OR DENSITY (G/ML): Not available PACKING (BULK) DENSITY (LB/GAL):
8.25 BOILING POINT/RANGE:
200 0 C MEL TING/FREEZING POINT RANGE: Not available SOLUBILITY (IN WATER): Miscible SOLUBILITY IN SOL VENTS/OIL (SPECIFIED):
Not available DUST EXPLOSION SEVERITY DATA: Not applicable MINIMUM IGNITION ENERGY (MJ): Not available MINIMUM EXPLOSION CONCENTRA TION (MEC): Not available LIMITED OXYGEN CONCENTRA TION (LOC): Not available SECTION 10. STABILITY AND REACTIVITY STABILITY:
Stable CONDITIONS TO AVOID (STABILITY)
None. INCOMPATIBLE MATERIALS Strong oxidizing and strong reducing agents. HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide and carbon dioxide.
CONDITIONS TO AVOID (POLYMERIZATION)
A void excessive heat and ignition sources.
HAZARDOUS POLYMERIZATION:
Will not occur.0002 20 Page: 5 of 8 Issue Date: 07/28/98 Supersedes:
02/14/96 NUSYN-NOXFISIH FISH TOXICANT SECTION 11. TOXICOLOGICAL INFORMATION ACUTE STUDIES THE FOLLOW/Nb DATA WERE DEVELOPED WITH: Nusyn-Noxfish Fish Toxicant.
EYE EFFECTS (Rabbit) Moderately irritating SKIN EFFECTS Irritation (Rabbit):
Moderately irritating Absorption (Rabbit):
LD50 > 2020 mg/kg (slightly toxic) Sensitization (Guinea Pig): non-sensitizing ACUTE ORAL EFFECTS Oral LD50 (Rat, female): 147 mg/kg (moderately toxic) Oral LD50 (Rat, male): 704 mg/kg (slightly toxic) Oral LD50 (Rat, overall):
561 mg/kg (slightly toxic) ACUTE INHALATION EFFECTS 4-Hour LC50 (Rat, female): .041 mg/I (highly toxic) 4-Hour LC50 (Rat, male): .059 mg/I (moderately toxic) 4-Hour LC5O (Rat, overall):
.049 mg/I (highly toxic) NOTE: The severity classifications listed above are those of AgrEvo, and, particularly for eye irritation, may not always coincide with EPA-mandated Precautionary Statements.
THE FOLLOWING DATA WERE DEVELOPED WITH: rotenone and piperonyl butoxide, the active ingredients CHRONIC (CANCER INFORMATION)
Rotenone was not carcinogenic when tested in rats and mice. A statistically significant increase in the number of benign liver tumors appeared in mice fed piperonyl butoxide technical at doses which far exceed any anticipated daily human intake. Independent and industry toxicological experts who have reviewed the data agree that the findings of the study do not indicate a health risk to human beings. CARCINOGENICITY:
NTP: No IARC: No OSHA: No TERATOGENICITY (BIRTH DEFECTS) Rotenone was not teratogenic or fetotoxic when tested in rats and mice. REPRODUCTIVE EFFECTS Rotenone had no adverse effects on reproduction when tested over two successive generations in rats. MUTAGENICITY (GENETIC EFFECTS) Rotenone was not mutagenic nor clastogenic when tested in the Ames Test, Yeast Test, Mouse Lymphoma Test, Mouse Micronucleus Test, Chromosome Aberration Test and the Mitotic Recombination Test in Yeast. SECTION 12. ECOLOGICAL INFORMATION ENVIRONMENTAL PRECAUTIONS:
This pesticide is extremely toxic to fish. Fish kills are expected at recommended rates. Consult your State Fish and Game Agency before applying this product to public waters to determine if a permit is needed for such an application.
Do not contaminate untreated water when disposing of equipment washwaters.
000 ??i Page: 6 of 8 Issue Date: 07/28/98 Supersedes:
02/14/96 NUSYN-NOXFISif FISH TOXICANT SECTION 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by disposal.
Pesticide Disposal : Pesticide wastes are acutely hazardous.
Improper disposal of excess pesticide, spray mixture or rinsate is a violation of federal law. If these wastes cannot be disposed of by use according to the label instructions contact your state pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
Container Disposal:
Triple rinse (or equivalent).
Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities.
RCRA INFORMATION RCRA HAZARDOUS WASTE INGREDIENTS:
None SECTION 14. TRANSPORT INFORMATION PROPER SHIPPING NAME: Pesticides, liquid, toxic, flammable, n.o.s.  (Rotenone, petroleum distillate)
HAZARD CLASS: 6. 1, PG I SUBSIDIARY HAZARD CLASS: 3 DOT IDENTIFICATION NUMBER: UN2903 DOT SHIPPING LABEL: Poison and/or Toxic NOTE: For transport purposes (49 CFR Part 173. 132), the calculated 1-Hour LC5O (Rat, overall) is: .196 mg/I SECTION 15. REGULATORY INFORMATION U.S. FEDERAL REGULATORY INFORMATION EPA Registration Number: 432-550 TSCA Inventory:
registered pesticide, exempt from TSCA SARA TITLE /li NOTIFICA TION AND INFORMA TION Section 302 (EHS) ingredients:
None Section 304 (CERCLA & EHS) ingredients (RQ): None Section 313 ingredients:
None SARA TITLE IIl NOTIFICATIONS AND INFORMATION SARA TITLE III -HAZARD CLASSES: Acute Health Hazard -'Yes" Chronic Health Hazard -'No' Fire Hazard -'Yes' Sudden Release of Pressure Hazard -"No' Reactivity Hazard -"No" SARA TITLE III -SECTION 313 SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372: CAS NUMBER INGREDIENT NAME PERCENT BY WEIGHT 5 1-03-6 Piperonyl Butoxide, technical
= 2.5 This information must be included on all MSDSs that are copied and distributed for this material.REGULATED INGREDIENTS Page: 7 of 8 Issue Date: 07/28/98 Supersedes:
02114/96 NUSYN-NOXFISHW FISH TOXICANT SECTION 15. REGULATORY INFORMATION
-Continued REGULATED INGREDIENTS
-Continued INGREDIENT:
Rotenone CAS NUMBER: 83-79-4 PERCENT BY WEIGHT: = 2.5 Regulations:
Illinois Toxic Substance Massachusetts Hazardous Substance New Jersey Special Health Hazardous Substance New Jersey Workplace Hazardous Substance Pennsylvania Workplace Hazardous Substance INGREDIENT:
Piperonyl Butoxide, technical CAS NUMBER: 51-03-6 PERCENT BY WEIGHT: = 2.5 Regulations:
SARA Section 313 Toxic Chemical U.S. STATE REGULATORY INFORMATION CALIFORNIA (Proposition 65): This product does not contain any chemical which is known to the State of California to cause cancer or birth defects or other reproductive harm. CANADIAN REGULATORY INFORMATION CPC NUMBER: None WHMIS Classification for Control Product Regulations (CPR): Registered pesticide under US FIFRA regulations; exempt from CPR classification.
The MSDS contains all CPR required hazard-related information.
WHMIS HAZARD RATING: See HMIS rating (Section 16) SECTION 16. OTHER INFORMATION HMIS HAZARD RATING -HEAL TH: 3 High -FIRE: 2 Moderate -REACTIVITY:
0 Negligible
-PROTECTION:
H NFPA HAZARD RATING -HEALTH: 3 High -FIRE: 2 Moderate -REACTIVITY:
0 Negligible
-SPECIAL: MSDS IDENTIFICATION CODE/NUMBER:
B467413 PREPARED BY: Regulatory PHONE: (800)438-5837 SUPERCEDES MSDS DATED: 02114/96 DATE AND TIME OF PRINTING:
07/28/98 11:23:44 MSDS Revision Indicators:
Revisions made in Section 1 (added trademarks and product description), Section 2 (added Other ingredient statement), Section 3 (Emergency Overview), Section 5 (chanqed Flash Point and Fire Fighting Procedures and added Flammability Classification/Rating), Section 7 (changed text under each heading), Section 8 (changed text under each heading), Section 9 (Basic Physical Properties), Section 11 (changed the eye, skin irritation toxicity data, added to the acute oral and inhalation toxicity data, chronic toxicity data, added where the data was developed from and what animal was used in the study), Section 12 (Environmental Precautions), Section 13 (Disposal Considerations), Section 14 (changed DOT 00(Z3 Page: 8 of 8 Issue Date: 07/28/98 Supersedes:
02/14/96 NUSYN-NOXFISit FISH TOXICANT SECTION 16. OTHER INFORMATION
-Continued Shipping Label and added 1-Hour LC50) Section 15 (added Regulatory Information) and Section 16 (added HMIS Protection Code and Disclaimer).
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES This information is provided in good faith but without express or implied warranty.
Buyer assumes all responsibility for safety and use not in accordance with label instructions.
Matra Saet Dat Sheet ISePRGl SONAR* SRP Herbicide 3 .'1 (.Emergency Phone: 317-580-8282 General Phone: 1-317-580-8282 EPA Reg. Number: 67690-3 Effective Date: August 25, 1994 SePRO Corporation
-Carmel, IN 1 -Methyl-3-phenyl-5-(3-(trifluoromethyl)phenyl) 4(1 H)-pyridinone (Fluridone)
CAS# 059756-60-4
.................
5% Other Ingredients
..................................................
95% This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200).
In addition, other substances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard.
BOILING POINT: Not applicable VAP. PRESS: Not applicable VAP. DENSITY: Not applicable SOL. IN WATER: Insoluble, but disintegrates in water SP. GRAVITY: Not applicable APPEARANCE:
Dark gray to dark brown pellet ODOR: Faint musty odor pH: (aqueous 50/50) 3.5 FLASH POINT: Not applicable METHOD USED: Not applicable FLAMMABLE LIMITS: LFL: Not applicable UFL: Not applicable AUTO-IGNITION TEMPERATURE:
No ignition up to 1382 0 F, 750 0 C EXTINGUISHING MEDIA: Use water, C02 or dry chemicals.
FIRE AND EXPLOSION HAZARDS: Will emit toxic vapors as it burns. FIRE-FIGHTING EQUIPMENT:
Wear full protective clothing and use self-contained breathing apparatus.
STABILITY: (CONDITIONS TO AVOID) None known INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) None known "Trademark of SePRO Corporation HAZARDOUS DECOMPOSITION PRODUCTS:
Will emit toxic vapors as it burns. HAZARDOUS POLYMERIZATION:
Does not occur. 5.EVRNETL AND DISOSA ENVIRONMENTAL DATA: Follow use directions carefully so as to minimize adverse effects on nontar get organisms.
IN ORDER TO AVOID IMPACT ON THREATENED OR ENDANGERED AQUATIC PLANT OR ANIMAL SPECIES, USERS MUST CONSULT THEIR STATE FISH AND GAME AGENCY OR THE U.S. FISH AND WILDLIFE SERVICE BEFORE MAK ING APPLICATIONS.
Do not contaminate water by cleaning of equipment or disposal of wastes. Trees and shrubs growing in water treated with SONAR may be injured. Do not apply in tidewater or brackish water. Do not apply in lakes, ponds, or other bodies of water where crayfish farming is performed.
ACTION TO TAKE FOR SPILLS: Contain and sweep up material of small spills and dispose as waste. Large spills report to CHEMTREC and SePRO Corporation for assistance.
Prevent runoff. DISPOSAL METHOD: Do not contaminate water, food or feed by storage or disposal.
Wastes resulting from the use of this product may be disposed of at an approved waste disposal facility in accordance with applicable regulations.
ACUTE EXPOSURE (SONAR SRP) Eyes -Rabbit, irritant Skin -Rabbit, 2000 mg/kg, no deaths or toxicity, nonir ritant Inhalation
-This formulation is not considered to be an inhalation hazard due to pelleted nature of material Ingestion
-Rat, 500 mg/kg, no deaths or toxicity Sensitization
-This formulation was not tested. Fluridone technical is not a contact sensitizer in guinea pigs. CHRONIC EXPOSURE (Flurdone Technical)
The fol lowing effects were reported in chronic, teratogenic, and reproductive toxicity studies in laboratory animals where experimental dosage levels and durations of exposure were far in excess of those likely to occur in humans. Chronic Toxicity -Decreased survival in lifetime feed ing study. Increased liver enzyme activity, liver weight, liver cell size, and microscopic liver cell changes.1 0 0'1 6) 5-MaeralSaet Dat Sheet-ISePRn!SONAR* SRP Herbicide Emergency Phone: 317-580-8282 General Phone: 1-317-580-8282 EPA Reg. Number: 67690-3 Effective Date: August 25, 1994 SePRO Corporation
-Carmel, IN Increased kidney weights, and microscopic kidney cell changes. Increased serum enzyme levels. Teratology
& Reproduction
-Not teratogenic.
Fetal deaths at maternally toxic doses. No effects on repro ductive performance.
Mutagenicity
-Not mutagenic in either bacterial or mammalian cells. Carcinogenicity
-Not listed as a carcinogen or poten tial carcinogen by IARC, NCI/NTP, OSHA, or ACGIH. Not considered to be carcinogenic in lifetime feeding studies.
SIGNS AND SYMPTOMS OF EXPOSURE:
There are no reports of significant exposure to SONAR SRP. In two reports of children swimming in water treated with SONAR, no symptoms developed.
PRIMARY ROUTES OF ENTRY: Skin and inhalation.
EYES: Flush eyes with plenty of water and call a physician if irritation develops.
SKIN: Wash exposed areas with plenty of soap and water. Wash all contaminated clothing before reuse. Call a physician if irritation develops.
INGESTION:
Do not induce vomiting.
Call a physician or Poison Control Center. If available, administer acti vated charcoal (6-8 heaping teaspoonfuls) with a large quantity of water. Do not give anything by mouth to an unconscious person. Immediately transport to a med ical care facility and see a physician.
INHALATION:
If discomfort occurs, move individual to fresh air. If breathing difficulty occurs, get medical attention.
If not breathing, provide cardiopulmonary resuscitation assistance and get medical attention immediately.
MEDICAL CONDITIONS GENERALLY AGGRAVAT ED BY EXPOSURE:
No information available.
EXPOSURE GUIDELINE(S):
PEL and TLV not estab lished. VENTILATION:
Good general ventilation should be sufficient for most conditions.
RESPIRATORY PROTECTION:
No respiratory protec tion should be needed when used in accordance with label instructions.
SKIN PROTECTION:
No precautions other than nor mal work clothing should be needed. EYE PROTECTION:
Use safety glasses.
SPECIAL PRECAUTIONS TO BE TAKEN IN HAN DLING AND STORAGE: Keep out of reach of chil dren. Harmful if swallowed, absorbed through skin, or if inhaled. Avoid breathing of dust or contact with skin, eyes, or clothing.
Wash thoroughly with soap and water after handling.
Wash exposed clothing before reuse. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA 704) (4=Extreme; 3=High; 2=Moderate; 1 =Slight; O=Insignificant)
Health: 2 Flammability:
1 Reactivity:
0 SHIPPING REQUIREMENTS DOT Hazard Class: Not regulated.
MSDS STATUS: Revised 1/92, Section 8 (Not meant to be all-inclusive-selected regulations represented).
NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ from one loca tion to another;, it is the buyer's responsibility to ensure that its activities comply with federal, state or provincial, and local laws. The following specific information is made for the purpose of com plying with numerous federal, state or provincial, and local laws and regulations.
See MSD Sheet for health and safety information.
SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title Ill) and is considered, under applica ble definitions, to meet the following categories:
An immediate health hazard The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult SePRO Corporation For Further Information.
2 Form No. A-73-Mq:92CO1) 04-12-1995 04:51PM FROM Eastern Technologies Inc. TO 81774?830 P.02 SODIUM BISULFITE SOLUTION I .GEEA INFR ATO I-..-.........
: r.
* NRC SODIUM BISULF!rE SOLUTION 32; /13 S(C.A.S. NO. Q ALLIED PRODUCT CODE 7631 5 CHEMICAt.
1UAMC ANDJR SYNONYM Sodium bisulfite.
aqueous solution F~ORiMULA MOLECULAR wVEI *HT 38% NaHSO 3 in witer 104.06 1 D CORPO TION ADDRESS (No.. STREET. CITY, STATE AND ZIP CODEI ALLIEDCRPR1TO CHEMICAL SECT R PO. Box I139R Morristown.
NJ. 0?960 C&#xfd;ONTACT PHONE NUMBERt LAST ISSUE DATE JURENT ISSUE DATE Director, Product 4fety (201) 455-4157 June. 1980 j May, 1985 EMERGENCY PHONJE NUMBER Eves: Immediatel flush with plenty of water, continuing for at least 15 minutes. (201) 455-2000 Get medical atten on. Skin: Promptly flush with plenty of soap and water. Inhalation-Promptly remove to fresh air. Ingestion:
If consc ous, give plenty of water or milk. Induce vomiting by touching finger to back of throat. Ge medical attention.
HEAL11H INHALATION I Inhalation of mist sy irritate respiratory tract. INGESTION May irritate gastroijtestinal tract. Very large doses cause violent colic, diarrhea, depression, and death. -Reference (b). May cause severe allergic reaction is some asthmatics.
SKIN Repeated or prolon ed contact with product may cause irritation EYES Solution contact wIll irritate the eyes. Long untreated exposures may cause burns. PERMISSIBLE CONCENT.IATION:
AIR BIOLOGICAL (SEE SECTIONJO TLV: 5 mg/cu.m. I None UNUSUAL CHRONIC TO) ICITY "None known 0.U-7-3 1 111 04-12-1995 04:51PM FROM Eastern Technologies Inc. TO HAADS(oI-'
817747830 P.03 F.IRE AND EXPLOSIOIE FLASH POINT 1 OC AUTO IGNITION OC FLAMMABLE LIMITS IN AIR (% ',Y VOL-) Not flammable TEMPERATURE QOPE1 CUP ElCLOS-DCUP Not applicable LOWER -Not applicable UPPER UNUSUAL FIRE AND EXPL(,SION HAZARDS See Hazardous Deco position Products, Section G. F:IRE EXTINGUISHING AGE1 TS RECOMMENOED N.A. FIRE EXTINGUISHING AGENTS TO AVOID N-A. SPECIAL FIRE FIGHTING PTECAUTIONS Wear self-contained b~eathing apparatus approved by NIOSH. VENTILATION I Sufficient to eliminate mists and reduce S02 levels below TLV. Packaging, unloading and open processing areas should be equipped with mechanical exhaust system.E.I PlEC] IVE EQUIPM=ENT RESPIRATORY PROTECTIC N Where required, use a NIOSH-approved respirator for mist, and/or sulfur dioxide gas, as conditions indicate.
Some exposures may require N IOSH -approved self-contained breathing apparatus or supplied-air respirator.
EYES AND FACE Wear hard hat (or otter head covering) and chemical safety goggles. Do not wear contact lenses.[4ANDS. ARMS. AND BODY Wear impervious glovIls and full work-clothing, including acid resistant apron, long-sleeved shirt and trousers.
OTHER CLOTHING AND EvIPMENT Eye-wash facility.I NORMAL HANDLING i Avoid contact with s~in, eyes, clothing.
Avoid breathing mist and/or SO 2 vapors. Use normal personal hygiene and housekeeping.
Keep away from acid& or heat.STORAGE I Cool, well-ventilated ppace away from acids and oxidizing agents.  (Releases sulfur dioxide gas slowly at ambient temperatures-see odor, Section F-) I SPILL OR LEAK (ALWAYS fVEAR PERSONAL PROTECTIVE EQUIPMENT
-SECTION -) Dilute small spills c&#xfd;utiously with water. Neutralize residue with aikali such as soda ash. lime or limestone.
Sulfur dioxide and carbon dioxide rqay be released during neutralization.
SPECIAL: PRECAuT3ONSfPF4OCEDURES1 LABEL INSTRUCTIONS SIGNAL WORD -WARN INGI 04-12-1995 04:52PM FROM Eastern Technologies Inc.*. PflflPRUIT&*a T*-1-nrv 817747830 P. 04 MATERIAL IS tAT NORM4L CONDITIONM
: APPEARANCE AND ODORO I Yellow liquid W LIQUID [0 OLID O GAS Pungent sulfur dioxide gas odor SPECIFIC GRAVITY VAPOR DENSITY BOILING POINT 104 -oC I-2o-1) [AIR 1) r "1.37 N.A. MELTiNG*POINt[
'NDO CN SOLUBIUTY IN WATER "" VAPOR PRESSURE % by WeItl 4nm H9 a% 200C) 2 IPSIGIO] 00% 4.3-4.5 est. 32 EVAPORAJION RATE " VOLATILES BY VOLUME lButVI ^elf= -t) Cr (scr IQ I -(At 200C) NA. STABILITY " CONDITIONS TO AVOrID Temperatures at or near boiling (104 0 C) cause evolution of toxic -UNSTABLE M STABLE and corrosive sulfur dioxide. (Sulfur dioxide also will evolve slowly at ambient temperatures.)
INCOMPATIBMLITY IMAT4 IALSTO AVOID) Oxidizers:
cause str ng exothermic reaction.
Acids: yield sulfur cfoxide gas. which is toxic and corrosive.
HAZARDOUS DECOMPOSIuTION PRoDUCTS Sulfur dioxide gas: see above comments.
Sodium sulfide maylbe formed after dried solution residues are heated. This is an explosive hazard and s$rongly alkaline in contact with water. j HAZiARDOUS POLYMERIZATION CONDITIONS TO AVOID El MAY OCCUR C WILL NOT OCCUR N-A. MATERIAL OR COMPONENT/CJA.S.
# WT.% HAZARD DATA (SEE SECT. .) NOT APPLICABLE Q!l: TO-4af 411&#xfd;1 04-12-1995 04:52PM FROM Eastern Technologies Inc. TO ENVIROMENTA L l K.ADTOA INF =None 006. _0--*- 0 . 1J EST ,-- ]ON -LLIE C1qPO .:.1O' PR VID S N V&#xfd;A RAN IES FiHE EX R &#xfd;S O M LE &#xfd;rj SNE OK .t(',111 DEGRADABILITY AQUATIC TOXICITY OCTAMOL/WATER PARTITION COEFFICIENT Aquatic toxicity:
l 7 ND 240 ppm/24o 48, 96 hr/mosquito fish/TLm/fresh water-Reference (b) (100% basis) I EP&#xfd;AHAZADU STANCE (0% ass SCE N ATTER IF SO. REPORTABLE QUANTITY:
5000 4OCFR tC.E AN W&#xfd;ATE R ACT, CT 0 100% Basis) __ iYES No 116-117 WASTE DISPOSAL MET DOS (DISPOSER MUST COMPLY WITH FEDERAL. STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS) Neutralize with alkali and flus6 to sewer with plenty of water if permitted by applicable disposal regulations.
Good ventilation is required during neutralization because of the release of SO 2 gas. Oxidation to sodium sulfate solution is required prior to disposal.
This ma' be done by adding a slight excess of dilute hydrogen peroxide carefully and with stirring.
Neutralized or oxidized waste rlay have to be disposed of by an approved contractor.
RCRA STATUS OF UNUSED MATERIAL IF DISCARDED.
HAZARDOUS WASTE NUMBER: IIF APPLICABLE 4 Not a "hazardous waste". 0261 PERM!SSISLE CONCENTRATION REFERENCES (1) "Threshold Limit Values for Chemical Substances".
ACG IH, 1984/85.REGULATORY STANDARDS 0. .CASFCAIN orsv I ' 7 I DOT ID No.: NA 2693 FDA regulations a~ply to food use and NF grades (21 CFR). Food use in meats or in food recognized as a source of vitamin B1 is prohibited CFR 132-3766).
GENERAL I (a) ACGIH, Docurmentation of 'the Threshold Limit Values, 4th Ed., 1981, Am. Conf. of Governmental Industrial Hygienists, Cincinnati 45202-a review for this material with 4 references.  (b) Coast Guard C)iRIS system form covering Sodium Bisulfite and Metabisulfite, "-SBS. October, 1978.p=I 81??74"83 P.0 0 {.0T.T CLASSIFICATION-Corrosive S49CFR 173 None I Towerbrom 960 1&#xfd;r OFPjl 0 O R P Z3 R A T i NP.O. Box 1346 Pittsburgh, PA 15230-1346 Phone--(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: Towerbrom 960 CHEMICAL DESCRIPTION:
This product is a mixture of Sodium dichloro-s-triazinetrione and Sodium bromide.
When dissolved in water, the mixture produces the disinfectant hypobromous acid. PRODUCT CLASS: Microbiocide MSDS CODE: 0B79-10-04-93 Section 2. INFORMATION ON INGREDIENTS Chemical Name Sodium dichloro-s-triazinetrione Sodium bromide CAS Number 2893-78-9 7647-15-6% by Weight OSHA PEL 89 None established 7 None established ACGIH TLV TWA 0.5 mg/m 3 , STEL 1.5 mg/m3 (supplier recommendation)
None established Product ingredient, Sodium dichloro-s-triazinetrione, is also referred to as Sodium dichloroisocyanurate.
Product contains 57% available chlorine.
Product provides 128% available bromine with continued use in accordance with the directions for use. Section 3. HAZARDS IDENTIFICATION
* * ** *****************
EMERGENCY OVERVIEW *********************
DANGER! May cause severe eye and skin damage. May be harmful if swallowed.
May cause respiratory tract irritation.
STRONG OXIDIZING AGENT. WILL BURN WITH THE EVOLUTION OF CHLORINE AND EQUALLY TOXIC GASES. Contact with water slowly liberates irritating and hazardous chlorine containing gases. Decomposes at 460-480&deg;F with release of harmful gases. PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation, ingestion l-ag MSDS Code: 0B79-10-04-93 Issue Date: 01/31/96 Page "1 Continued on Page 2 0002~'- 1,1 I Towerbrom 960 TARGET ORGANS: Eye, skin, respiratory tract, gastrointestinal tract MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
No data available.
POTENTIAL HEALTH EFFECTS: EYE CONTACT: This product may cause severe irritation and damage upon contact with the eye. SKIN CONTACT: This product may be irritating and damaging to the skin upon contact. In dry form, the product is not appreciably irritating to dry skin. However, on contact with moisture, sodium dichloro-s-triazinetrione readily hydrolyzes to form hypochlorous acid which may cause tissue damage. This product is not expected to be absorbed through the skin in harmful amounts or to cause an allergic skin reaction.
INGESTION:
Ingestion of this product may result in burning of mouth, throat and esophagus, abdominal distress and severe irritation, possible corrosion of the digestive tract. Prolonged ingestion of large amounts may cause adverse central nervous system effects including:
headache, irritability, muscle incoordination and dizziness.
INHALATION:
Inhalation of sodium dichloro-s-triazinetrione dust has been reported to produce nose, throat, and respiratory tract irritation and in some individuals bronchospasm may result. Chlorine gas from decomposition of the product has been reported to cause burning of the nose and mouth and irritation of the lining of the respiratory tract with coughing, a choking sensation, chest pain, vomiting, nausea, headache, dizziness and fainting.
The onset of severe respiratory symptoms following exposure to chlorine, including pulmonary edema and pneumonitis, may be delayed.
SUBCHRONIC, CHRONIC: Exposure to large amounts may cause damage to the liver and kidney. Due to sodium bromide content, prolonged ingestion of large amounts may cause adverse central nervous system effects.
CARCINOGENICITY:
NTP: *No ingredients listed in this section* IARC: *No ingredients listed in this section* OSHA: *No ingredients listed in this section* Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid immediately.
SKIN CONTACT: In case of contact, immediately brush off excess product and flush with plenty of soap and water. Remove contaminated clothing.
Seek medical aid immediately.
Wash clothing before reuse. INGESTION:
If swallowed, do NOT induce vomiting.
Give large quantities of water. Seek medical aid immediately.
Never give anything by mouth to an unconscious person. NOTE TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage. MSDS Code: 0B79-10-04-93 Page 2 Issue Date: 01/31/96 Continued on Page 3 00? 7?
I Towerbrom 960 1 INHALATION:
If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Seek medical aid. Section 5. FIRE-FIGHTING MEASURES FLASH POINT: Not applicable This product is not, by definition, flammable or combustible, however, it is an oxidizing and chlorinating agent. If heated by an outside source to temperatures above 240&deg;C (464&deg;F), it will undergo vigorous self-sustaining decomposition with the evolution of heat and dense noxious gases. In addition, when in contact with another combustible material, this product will increase the burning rate of the combustible material.
When ignited, it will burn with the evolution of noxious chlorine containing gases.LOWER FLAMMABLE LIMIT: Not applicable UPPER FLAMMABLE LIMIT: Not applicable AUTO-IGNITION TEMPERATURE:
Not available EXTINGUISHING MEDIA: Use water spray to cool containers exposed to fire and massive quantities of water to dilute material involved in a fire or spilled from containers.
Do not use ABC or other dry chemical fire extinguishers since there is the potential for a violent reaction.
FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective clothing are essential.
Chlorine containing gases with traces of phosgene can be liberated at temperatures in excess of 400F. Using a 10% solution of sodium carbonate, thoroughly decontaminate fire fighting equipment including all fire fighting wearing apparel after the incident.
FIRE & EXPLOSION HAZARDS: Nitrogen trichloride can be generated slowly by the reaction of small quantities of water with a high concentration of this product. Nitrogen trichloride can present an explosion hazard. Immediately after a fire has been extinguished, check for wet or damp material.
Any spilled material from burned or broken containers should be assumed to be contaminated.
Neutralize to a non-oxidizing material for safe disposal.
Do not attempt to re-close broken containers, even for movement to the disposal area. They should be left open to disperse any nitrogen trichloride that may form. Bulging containers require extreme care. Contact the fire department.
DECOMPOSITION PRODUCTS:
Chlorine (released in presence of moisture) and other chlorine containing compounds.
Hypobromous acid, hypochlorous acid, and cyanuric acid (released when dissolved in water). Thermal decomposition or combustion may produce oxides of nitrogen, disodium oxide, bromine, and traces of phosgene.NFPA RATINGS: Health = 3 Flammability
= 1 Reactivity
= 2 Special Hazard = Oxidizer Hazard rating scale: O=Minimal 1--Slight 2=Moderate 3=Serious 4=Severe MSDS Code: 0B79-10-04-93 Issue Date: 01/31/96 Page 3 Page 3 Continued on Page 4 0WOA73 I Towerbrom 960 1 Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled material.
Any spillage should be cleaned up as soon as possible.
DO NOT add water to spilled material.
Using clean, dedicated equipment, sweep and scoop all spilled material, contaminated soil, and other contaminated material and place into clean, dry containers for disposal.
DO NOT. use floor sweeping compounds to clean up spills. DO NOT close drums containing wet or damp material.
They should be left open to disperse any nitrogen trichloride that may form. DO NOT transport wet or damp material.
Keep product out of sewers, water sheds and water systems. DO NOT contaminate water, food, or feed by storage or disposal.
Report any release of this product if it could cause harm to people or the environment, or if the State requires a more stringent reporting threshold.
If this product spill gets into the ground or surface water or is involved in a fire, toxic gases are released; therefore, the spill should be reported.Section 7.HANDLING:
STORAGE: HANDLING AND STORAGE It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Do not get in eyes, on skin or clothing.
Avoid breathing dust or fume. Use with adequate ventilation.
Wash thoroughly after handling.
Keep container closed when not in use. Keep from contact with clothing and other combustible materials.
Remove and wash contaminated clothing promptly.
Never add water to product. Always add product to large quantities of water. Use clean, dry utensils.
DO NOT add this product to any dispensing device containing remnants of any other product. Such use may cause a violent reaction leading to fire or explosion.
Contamination with moisture, organic matter, or other chemicals may start a chemical reaction with generation of heat, liberation of hazardous gases, and possible fire and explosion.
Store in a cool, dry, well-ventilated place away from flammable liquids, combustible materials, and oxidizable materials.
Store in original container and in a dry area where temperatures do not exceed 125&deg;F (52"C) for 24 hours. Keep container tightly closed. DO NOT allow water to get into container and keep off wet floors. Do not contaminate water, food or feed by storage or disposal.Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
Chemical splash goggles and face shield SKIN PROTECTION:
Chemical resistant gloves and protective clothing RESPIRATORY PROTECTION:
If airborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
ENGINEERING CONTROLS:
Use local and/or general exhaust ventilation to maintain airborne concentrations below exposure limits. WORK PRACTICES:
Eye wash station and safety shower should be accessible in the immediate area of use.MSDS Code: 0B79-10-04-93 Issue Date: 01/31/96 Page 4 Continued on Page 5 Towerbrom 960 1 Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: Not applicable SOLUBILITY IN WATER: 10 g/100 g @ 25&deg;C VAPOR PRESSURE:
Not available SPECIFIC GRAVITY: Not applicable VAPOR DENSITY (air=1): Not available pH: 6.0 -7.0 (1% solution @ 25C) %VOLATILE BY WEIGHT: Nil FREEZING POINT: 240 -250&deg;C APPEARANCE AND ODOR: White crystalline granules with a slight bromine odor. Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY:
Stable HAZARDOUS POLYMERIZATION:
Will not occur CONDITIONS TO AVOID: Overheating.
INCOMPATIBILITY:
Avoid contact with water on concentrated material in the container.
Also avoid contact with easily oxidizable organic material; ammonia, urea, or similar nitrogen containing compounds; inorganic reducing compounds; floor sweeping compounds; calcium hypochlorite; alkalis.
DECOMPOSITION PRODUCTS:
Chlorine (released in presence of moisture) and other chlorine containing compounds.
Hypobromous acid, hypochlorous acid, and cyanuric acid (released when dissolved in water). Thermal decomposition or combustion may produce oxides of nitrogen, disodium oxide, bromine, and traces of phosgene.MSDS Code: 0B79-10-04-93 Issue Date: 01/31/96 Page 5 Continued on Page 6 OOC&#xfd;e75 I Towerbrom 960 Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT: Product Oral LD 5 0 (rat): 1350 mg/kg (similar formulation)
Product Dermal LD 5 o (rabbit):
> 5000 mg/kg (similar formulation)
Toxicological data on oral effects: Following repeated exposure (8-weeks) to sodium dichloro-s-triazinetrione in their drinking water, rats demonstrated decreases in body weight gain, and drinking water consumption and changes in urine composition at dose levels of 4000 and 8000 ppm which produced some deaths. In a 90-day feeding study with rats, the two highest dose levels of 6000 and 12,000 ppm caused increases of the relative kidney and liver weights.
No birth defects were noted in rats given sodium dichloro-s-triazinetrione orally during the pregnancy, even at amounts which produced adverse effects on the mothers.
Toxic effects reported following ingestion of large single doses of bromide include stomach irritation, nausea, vomiting, and lethargy.
Repeated ingestion of sodium bromide produces sedation and central nervous system (CNS) depression with possible effects such as headache, irritability, vertigo, memory loss, muscular incoordination, increased action of the reflexes, decreased appetite, hallucinations, acne-like rash, stupor and coma. Following repeated exposures (4-12 weeks) to sodium bromide in their feed, signs of muscular incoordination and depressed grooming, changes in body weight and behavior, and endocrine (hormone) system effects were reported in laboratory animals. Reduced fertility and viability of offspring were noted in rats fed sodium bromide for three successive generations.
These effects on the ability of rats to reproduce were reported to be reversible upon withdrawal of the bromide. Results of another study suggest that learning ability was reduced in offspring of rats given sodium bromide during pregnancy.
Toxicological data on inhalation effects: Signs of eye and nose irritation and changes in body weight, liver weight and blood cell composition were noted following repeated inhalation (4-weeks) of sodium dichloro-s-triazinetrione dust by rats. Section 12. ECOLOGICAL INFORMATION ON PRODUCT: Aquatic toxicity data: 48 hr LC 5 o (mysid shrimp): 3.54 ppm 96 hr LC 5 o (sheepshead minnow): 3.42 ppm 48 hr LC 5 0 (Daphnia magna): 2.5 ppm 48 hr LC 5 0 (fathead minnow): 0.7 ppm Environmental hazards: This product is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge.
Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority.
For guidance contact your State Water Board or Regional Office of the EPA. MSDS Code: 0B79-10-04-93 Page 6 Issue Date: 01/31/96 Continued on Page 7 00 0. G Towerbrom 960 1 ON INGREDIENTS:
Chemical Name Sodium dichloroisocyanurate Aquatic Toxicity Data 96 hr LC 5 o (rainbow trout): 0.37 ppm 96 hr LC 5 0 (bluegill sunfish):
0.43 ppm Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would be considered a RCRA Hazardous Waste based on the characteristics of ignitability and reactivity.
The EPA Hazardous Waste Numbers are D001 and D003. DISPOSAL:
Pesticide wastes are acutely hazardous.
Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:
Class/Division:
 
===5.1 Proper===
Shipping Name: Dichloroisocyanuric acid salts, mixture Label: Oxidizer Packing Group: II ID Number: UN 2465 Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA: Pesticides are exempted by TSCA (the Toxic Substances Control Act), under Section 3(2)(a)ii, from the provisions of the Act. CERCLA reportable quantity of EPA hazardous substances in product: Chemical Name RQ No ingredients of this product have CERCLA reportable quantities.
This product has not been assigned an RQ; however, releases may be reportable.(Notify EPA of product spills exceeding this amount.)SARA TITLE I1: Section 302 Extremely Hazardous Substances:
Chemical Name CAS # RQ There are no SARA 302 Extremely Hazardous Substances in this product.Section 311 and 312 Health and Physical Hazards: Immediate Delayed [yes] [yes]Fire [yes]Pressure [no]MSDS Code: 0B79-10-04-93 Issue Date: 01/31/96 Page 7 Page 7 Continued on Page 8 0 00 7 Product RQ: TPQ Reactivity
[yes]
Towerbrom 960 Section 313 Toxic Chemicals:
Chemical Name CAS # There are no reportable SARA 313 Toxic Chemicals in this product.% by Weight Section 16. OTHER INFORMATION HMIS RATINGS: Health = 3* Flammability
= 1 Reactivity
= 2 Personal Protective Equipment
= X (to be specified by user depending on use conditions)
*There are potential chronic health effects to consider.
Hazard rating scale: O=Minimal 1 =Slight 2=Moderate 3=Serious 4=Severe MSDS REVISION
 
==SUMMARY==
: Supersedes MSDS issued on 10/26/95.
The MSDS has been changed in Section 5. While this information and recommendations set forth herein are believed to be accurate as of the date hereof, CALGON CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON.
PREPARED BY: P.J. Maloney MSDS Code: 0B79-10-04-93 Issue Date: 01/31/96 Page 8 Last Page 000 O(.
FOR INKORMATION ONLYExieOn
?material Safety Data Sheet Gyernum Publishifig Corporation 1145 Catalyn Sueet Schencrady, MY 12303-1936 USA (518) 377-8855--aw 37--6-7 SULFURIC ACMDV r Revision C issue&- obaer 1g I6 Revised: February 1986 son%= MW01 13354 Ld1.34 Va cies %@a340-C CAlO 100OcaO Mlel PobNt. des C We a-34 ca3 10A Water olubility
-. Complete Miscibl vapor pramsuns, Mg I@ 100*P --d (93.19% H SO 4); Deg. Dasume -66 (93.19% H2SO 4) -ensity of H 2 S0 4 Is often reported in degrees Daumni Be). Fxmula Is Dc-US (144ftp for liquids heavier die ~fj AMp3e anceu da Ciatr. colorless bygsoscoplic, oily liq.Mid~ wi c odor. MMstsegea thand I mWs3 are easily recognizable.
Those at S wern U distinctly objectionable.-SECE7ION
: 4. FIRE AND EXPLO)SION DAA .:.WER UPPER Flash Point u4 Method Atigtion Ten. Flamabilit Limits in Air Nowe- NoafbmArnnbie_
NA KA NA NA vet ira qg in Wen maylum caise byia coontat Atn materials.
Small fis may be smodsered wIlt mailble dry chemical.
Cool exudror of scoveg iniks of H1SQ 4 %Mwow ID avoid ruptare Vf eposed b ame aome add nim 9E othe liqud in the seM1 Mie scid, especially whndiluted with waher. cm react with -Je&a sD lbaute fnammabl bydrages gSm. Swufuic acdd *ibO mlP vIaon D a fir wes, at coeselve (set sect. S). Fire fighert z"s weer self-cntined bre~ing equipmentl anlly protective clogung.
SECTION 5. REACTIMiY DATA :' &#xfd;~.. . Sulfwic acid isatable und r no a! conditions of w~e and storage. ft does not mdeWg buazadus polynerizatlos.
Iti s a smog miners! acid ieacfti wiffi beam and metals. The coocaakate acid Is ams a dehydratig sgent; pck-ung up ontsturt reAdiy from Me at or alter nukteals.
Hydroge gas may be generated within a 112504 container.
Vent druma coutiously.
This material reacts exoldiertnlcafly with waler (Acid should always be added alowly In water. Waler added so acid can sme bofling and tncoontrole spleashing of die scid.) Sulfur oxides ca result from decomposition and from oxidizing reactions of Wilflurc acid.0002319&WWM Expires On: 17?US-*% n2w,4 VJ-kM-"2-W4-M&ERL NA&ME SULFURIC AMI, CONCEMMTR.FD oTHER FM GMAT ONS-.Oil of Vliol.c Hydzo4ea Sulfate; H 2$0 4; CAS #7664-93-9W A Allied Corpmorton, P0 Box 20641. Macristown, NJ 07960; Telephone:
M61KMF PPE: Sd Svc Sect. K 0 &#xfd;-SECTION
: 2. -INGREDIENTS AND HAZARDS HAAD DATA ttydiup Sulfate (140046) 93-9 4-bw TW-4 1 Wgtm 3 WderBalacee HuWM. Mist Inhalation Material is Obtained by the reaction of S03 and water. Cncotai crli M~o: t Effects2)w low Isnzepr ltvels. fach as 0.02% =ax of iton a Fe&#xfd; Poparties vary wdit 112S4 amlnL Rat. Or.11. Curent OSHA satndard and ACGOi (19985-6)
TLV. NIOSH has a 10-lw LDWo 2140 mwkft TWA. 404hr. work week, ofIl nmgr 3.  -SECTION 3.PHYSICLDAA.
aned to: ???? ~FOR INFORMATION ONLY EnrnO~i No. 9 2/86 SUJLFURC ACID, CONCENTRATED (Rev. C) eq~i St :SECTION 6. HEALTH HAZARD INFORMATION 1TLV: ....Concestratd malwki acdd is a stng minera acid an naidizi agent, and a dehydrating agent ifati is rapidly damagingo inal human tissue wish which is coma in contact Ingestion may cause -vme injury or death. Eye conact produces evan or permaneinjury.
Inhalation of anmim amadLge bol t upper respirgory Irct ad do lungs. Suluric acid is not listed as a carcinoge by li KMW. tARC, or OSHA. FIRST1 AM;: EYE Imflus Ru yes " uding under eyeld) with plenty or running water for a lat 15 minumts. Speed Wm diutiog and out acid with water is ezvemely important if permanent ee damage is In be avoided.
Obtain medical help a an=o u paossible0 2M "WA': m,,al&U flush afheeda m" with water, removing *ontaminased clohng h under the safet shower. Cooaue washing with waler and get medical aetnion 5 JINA LTON: Remove *. Rettore breathing.
CalDa physician Immediately.
k QGES11OQ : Dikit acid nmedajly with rge mouns of milk or water. thn give mflk of magnesia lo neutralize.
Never jive mnythint by mout to Sunconscioas person. Do ot induce vomiting; f it occurs spontaneously.
continue an adminhser fluid. Obtain medica anention asoon ra possible.0 Maintain observatio of patcit for possible delayed onset of pulmonamy edema.
* GET MEDICAL HELP -In plant, paramedic.
omnmunity.
SECTION 7. SPI, LEAK.-AND DISPOSAL PROCEDURES
.. Handle mijor spills by a predetermined plan. Contact supplier for assistance In this plannbing in meeting Inca reguladtions and for disposing of laig Notify safeWy pc-soonel.
Provide optimum veotilation; vapors ar extbnely irritating.
Stop leak if you can do so wthout risk. Cleanup personnel need agains inhalation or cootact. Keep upwind. Contain spill. MWowr icaks or spirts can be diluted with much water and neutralized with soda ash or Jim. If water is noo available, cover contaminaftd aea with sand, ashes, or grav and neutralze cautiously with soda ash or lime. DISEDAL- Follow Federal, staLe, and loca regulations.
Runoff lo sewer may create hydrogen Sss, which is a fire or explosion hazam. EPA (CWA) RQ 1000 lbs. (40 CFR 117).  :SECTION 8. SPECIAL PROTECTION INFORMATION Provide general ventiation to met TLV requiremew io th worplace.
Whenr mists am up Io S0 mgtui , a hih uffiiency particulafe respirator wih full feiece is warranted; a type-C suppher-air rtspirator with f faceplece operated In pressuredemand mode is used 0o 100 msmwn. Avoid eye contact by use of chemical safety Mokges or face shield wbem splashing may occur. Acid-resistant clofting.
aidi as rubber gloves, pron boots, and suits, Is recommended to avoid body contact Eyewash fountain and safety showers with deluge type of heads should be mali available where this material is bandid or Nore& Cotact lenses pose a special hsbm; soft lenses may absorb and all kues concentrate britanta.
Comprehensive preplacemnt and amual medical examinations with emphasis on dental aumion eudopulmonaz system. and mucous membrane inition ad coqh m idicated.
SECTION 9. SPECIAL PRECAUTIONS AND Sulfuric wcd W carboys or drums should be wooed in rican ventilated Morage aras having scid-reisatutfloors with good drnag. Keep out of dkiect snliht, do not Sore above 9.F (2C). Storage facilities am so be fm o i material, metallic powders, chromates, chiorates, nitrates, carbides, oxidizabl,, etc. Soda ash sand, or ltme sould be kept In geAral stge or wo am for emergency mue. Protect containers against physical damage. Gan botes need exa pcouxtion.
Sulfuric amid is hNgiy cortosive I most metals, ecialy below 77% H2304. Avoid brtahing mist or vonL. Avoid contact with sin or eyes. Do not ingest. Do not add water In concentrated acid. Drums may contain hydrogen gas. so open cautiously.
Use nonsparking tools fie of oil, dirt, and grit and vapor-proof electrical fixturns DOT Classificatioo:
Corrouive Miateral.
ID No.: UN 1330 Label: Corrosive Data Source(s)
Code- 1-12 19,20,24, 26, 31, 37-39, 42,82. CK hdpn~i. wtrs n tI,, ty ~idee, nrerphue m Approvals .&#xfd; ./u. ho bm Wan U an propusib , of a ,umse= cA Medical Revew Copyright 0 February .1 000240.aned to: ????FOR INFORMATION ONLY E~xpires On: %7-NOV.;.02'99(TUE) 10:59 HOUGHTON CHEMICAL YF'H-0&#xfd;9-1998 0~9!15 FROM TEL: 16172542713 I&#xfd;A7FEIAL SAPLrTY, ATA BELLACIDE(R) 32Z 595 -~41 2.U.S../CANADA VE~RSION EFFECTIVE:
06/28,-95 P. 002 S 161 S4'13 F.02 PF&#xfd;'RINT.ED
*FOR.................
FMIC CORPORATION P~RODUCT ;NAME...............
SYNO..............
INFORM'ATIION PROVIDED BY-:~ :EI1ERG;NC'Y PHONE NVMBERS nEDIqAL4I....
..
* PLANlI/OTHER.
......  .,:AS 0 AN~D COMPONENTS
...~...EMERiGENqjY
'OVERVIEW
.....EVES.... ..................
* SKIN.............
INHALATUOID...............
PAD*CHEMICAL PROtDUCrtCOMPANY IDEN &#xfd;ELLACIVE 325 ~LG!CIDE &#xfd;- CTERT-SUTYLA?1INC)  CHL.ORD  Ci i-TRIAZINE; TERBUTMAL.AZINe 214C CORPORATION I 'ROCESS ADlDITIVJES DIjVISION 735 MARKET STREET 'HILADELPHZA, PA 19]O 800) 545-6532 800) 424-9300 303) 595-9048 CALL. COLLECT 304) 7S5-6UOO CALL COLLECT -COMPCSITIUN/INFOR&#xfd;iATION ON IN -(TERT-BUTYLAM INC -KCHLO3RO ( AS*: 5915-41L-3 ERCENT; 4% AT ER *HA2ZARD IDEN'TIFICAlrzON RODUCT IS STA3LE UNDER 19ORMAL Cd SE. UNDEA FIRE CONDITIONS rOx!j KIDES AND CHLORINE &#xfd;O?&#xb6;PDUNDS MAI RCDVJCT 15 SLIGHTLY itOXId BY i~r *FIRST AID MEASURE === LVSH WITH.P4ENTY OPF WATE-R. GETI TTErrrION IF IRIATO OCCURS Ai, ASH WITH PLENTY OF SOAP :AND WAT rTENT!OK IF IRRITATION OCCURS A EMOVE TQ FRESH AIR. IF SREATHr ISCOP&#xb6;FOR~T OCCURS ANDl PERSISTS.
rTENTbar4.
RINK I OR F- GLASSES OF WATER AAN DM~rING BY TOUCHING THE BACK OF' ITH A FINGER DR BY GIVINU SYRUPI EVER INDUCE VOPIITINb OR GIVE AN+ 3AN U.NCONSCIOUS PERSON.- cflNTAI IT AVAILAPLE (CONT1II1 oMC IINTED;i 0212/2,r FIFICATION kTkYLA?'IINO
-*REDIENTS a-THYLAMINO'-
rNDITIONS OF SUL-FUR BIE RELEA-oSED.
STI'ON -D PERSISTS. 
: k. GET MEDICAL ) PERSISTS.
3 DIFFIcuLTY oR' 3TAIN MEDICAL INDUCE rHE THROAT )F IPECAC, rHING BY MOUTH r A MEDICAL?ED) PAGE 01 0002411 TO Eg TU'PWRICIAN
.......
NOV. :02' 99 (TUE) 10: 59 HOUGHTON CHEMICAL TEL: 16172542713 ro :325 FAATEMAIt.
SAFETV. DATA EEL (816r125U42?jj
-4+/- -2 V.S /CAN'AD*%
VERSION EXTIN-GLJISHING MEDIA. ....... SPECI-AL FIREFIGHTING....
PRO QCfUlES DEGRE-E CF FIRE AND ....... EXPL~dslON HAZARD HAZAR-DOLIS DECOMPOSITION.,;
PRO.DaCTt PROCE-IDU*~
FOR RELEASE--T OR SPILLS. FIRE FIQHTING m'E iSURES ===: CARBON DIOXIDE, F'OAJ, DRY' CHIErt1 USE-SE&#xfd;LF CONTAINED TE ATNP41N ApI DECOMPOSITION AND COMBUSTION PRI TOX IC. TH4ERMIAL DECOM'POSITION AND RURNT1 CARBON MNOXIDE, CARBDON DrOXIDE, SULFUR OXIDES, CHLORINE coNpoUNI T.OXIC SPECIES. 
: 6. ACCIDENTAL RELEASE MEA4SURES IISOLATE AREA. WJEAR PRESCRIBED F CLOTHING AND EQUJPME&#xfd;1r.
DIKE 7C ABSORB WJITH ANl ABSOOBENT OR SHO% AN APPROVED CONTAINRR AND DISPO! THE METHOD OUTLINED UJNDER THE "T CON5IDERATIONS-SPECTIXOF.
TO DEC AREAP TOOLS AND EQUIOMENT WASW 6 ADD TO DRUMS OF WASTE ALREADY CC-~ 7HANDLING AND STORAGE VENTILATION
..............
CONTROL MIEASURES...........
RECOMMENrbED PERSONAL PROTECTIVEc EQUIPMENT RESPIRATORY,,_....:
GLOVE;............
SpiEciAl-CLODTHlNG.
.. A A*D SQVIPMENT JFOOTIWEAR.............
AVOID DIRECT CONTACT WHEN HANDLI USE WITH GENERAL ROOMI VENTII.ArxO CONTAMINATION IS EXPECTED.
KEEP CONTAINERS CLOSED WHEN NOT FROM HEAT, FLAME AND:PHYSICA DA S. EXPOSURE CONTROLS.JPERSONAL FR UNDER NORMAL COV4DrTrpNs OF USE E NOT BE A SIGNIFICANT&#xfd; CONC:ERN.
V. CONDITIONS THE PERSONAL P&#xfd;ROTECTI INDICATED BEL.OW IS R.ECOMMENDED. 
&#xfd;USE MSHAIN3DSH APPROVED ORCANIC IPROTECTION WHEN AIRBORNE VAPDR J~ USE CHEMIICAL TYPE GOGGLE9 OR FACi USE IMPERVIOUS GLOVES,.
WEAR IMPERVIOUS APRON AND, GAUNrL SPLAS.HING IS EXPECTED DURING~ L10k NORMAL WORKSHOES EXCEPT IN CONDi~ WHERE RUBBER OVERSHOES OR ROOTS REIUIRED.PAD ICaNT!Ik P-03'FMC;AWATER SPRAY 'AR ATVS.)bUCTS MAY BE il0 ?AY PRODUCE !NITROGESN AND ROTECTIVE
*CONFINE SPILL. EL WASTE INTO E Of FOLLOWING tS aAL. ONTAMINATE SPILL: ITH WATER AND 4lG THIS P*RODUCT 4 WHEN AIRBORNE&#xfd;N USE. IACE.PROTECTi)TECTION =wm :POSURE S14OULD IDER UNUSUAL 'E EIUIPM'Ercr ESP IRATORY EXP'ECTED'.
SHIELD. TS WHEN ED TRANSFER.
IONS OF SPILI-S OULD BE LJED) PAGE 02 P. 003'i.r F!00024'f-TAN--oe-iggs 09: 15 FROM TO DIELLACIDE(-4 i 2 EFFECTIVE!
06/28/VZ I NOV. -02' 99(TUE) 10:59 HOUGHTON CHEMICAL Y~N-39-9~B 09:16 FpIoti 1&#xfd;ATFAIAL SAWFLTY DATA'-is I TEL: 16172542713
*11 0 BELLACIDEAR)
:32 5915 V.S.ICANADA VERSION EFFECTIYE; 06/28/95 PF 0NED_2/2319t, P. 004 FMC?IELlINGtrFREEZING POINT....
BOILVNG POINT..............  .VAPOR PRESSUIRE
....~.......
VAPOk DENSITY (AIR=1)...: -RDOOM TEMfPERATURE
.........
APPEARANCE AN~D STATE ODOR....*........................
SPECIFIC GRAV-ITY (H20=1). f SOLUBILITY&#xfd; IN HZ0 % 'BY WT.,T %. 'OLATIFLESt......
EVAPOftAfION RATE.... ....  (BIJTYL ACETATEuI)
PH fAS ~... .... PH C17. SZDLUTION)
.... ODOR THRESHOLD.
..,.. ... .... tDlENSZTY
.(l~fKL-----------..
PARTMTON COEFFICIENT
... N-OCCTANOL IUATER FLASK PCLItNT.-.
........-: AUrOIGNIT1ION TEJIPERATVRE.:
FLAMMABLE LZM3TS UPPER..  ,(A-IRY ILaW~ER..:
EXPLOSIV~E OROPERPTIES'....
4: OXIDIZING PROPERTIEs
... SOLU~BILrTy....................  -FAT- SOLUB~ILITY (SOLVENT -OIL)'STABILITY..'..
,.........
HAZARDOUS POLYf15RIZATION.:
copWiTiowsio.
AVOID,.......
M&#xb6;ATERIALS TO AVOID ........
MAJOR: dO'N7ArtN4ANTS THAT.. 9QfR'jltjro-';, INSTAB"ILITY' rNCOnMPATIB
:LlTY ...... HAZARO~t PCOMPOSITION..t PRODUCTS SENSITIV'ITY TO MECH ....... IM7PACT SENSITrVlrTi To3 STATIC...,.
D'ISCHARGE 9.PHYSICAL AND CHEM&#xfd;ICAL PROPERI NOT AVATLARLE NOT AVAILABLE NOT AVAILABLE NOT APPLICABLE WHITE TO BEIGE SLIGHT CHALKYf 1.0 NOT AVAILABLE NOT AVAILABLE NOT AVAILARLt 7-y, NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT NOT AVAILAIILC AVAI LABL.E AVAI LABLE AVAILABLE APPLICABLE AVAI LABLE APPLICA3LE APPLICABLE APPLICABLE APPLICABLE AVAI LABDLE 10. STBLT A AGUEdUS DISPERSIC DOR ND RE'ACTIVITY
=--o'STABLE WILL NOT OCCURi AVOID STORAGE AT EXTR; ENE TEMPERA' NOT AVAILABLE'STRONG ACIDS AND ALKAL.1ES T14ERJ'tAL DECOMPOSITION AND- BURNINt CARBON MONOxine,, CARBON DIOXIDE,.
SULPUR OXIDES, CHLDR iNE Car&#xb6;POUNDi TOXIC SPEciEs.
NONE NONE--------1I. TOXICOLOGICAL NO a-Tm EYE OaTT PAD NON-JRRITANT (RABBIT)*1 ES N ats~w w a = ==URES.  "tAY PRODUCE NITROGEN AND AND~ OTHEaR (CEJNTi&#xfd;$ED)
PAGE 03 000243+-mc-I ?w, 4 7-713,-41 2 NOV. -02 99CTUE) 10:59 HOUGHTON CHEMICAL JAN-oq-i99e aq:16 F~ROM TEL: 16172542713 1Arpmf&L SAFETY DA.A BELLACIDE(R) 325-NAD VERION.SKIN CON&#xfd;TACT ............ 
~sHI A3~2RTID............  .INHLATON
............... 
:ACUTE EFFEtTS F~ OVERIEXPESURE .CHRONIC EFFECTS FROM.....:
OVERE.XPOSURE (tFFEC'TB CaNSIDEREn INCLUDE: SENSITIVrTIES,
* CA RC-ZNGENICITYJ TE RATOG-ENI CITY, MU-TAGEN rcxrY, SYNERGISTI C PRODUCTS, AND ANY "MEDICAL CDNDITIONS
* GENERALLY RECOGNIZED' AS BEINC AGGRAV.ATED sY EXPOSURE., !ENvIRONMENTAL:FA~TE.....,..
ENVI1RONJIENTAL EFFECTS...:I TE DIlsp~lSAL WAS IPAD EFFECTIVEi 06/?S/95 P 11, TOXICOLOGICAL INIFORMATION NON-IRRITANT fRABDITI' NON-SENSITTZER (GUINA PIC) LD50 > 4400 MG/KrG (R&#xfd;ABBr, NO DATA AVAILABLE t LD50 2350 MG/KG (RAT) PRODUCT IS SLIGHTLY &#xfd;OrXIC By ING ANIM9AL STUDIES INDICATED EFFECTS ~TESTES, TYVrnUS AND STOMACH WHEN APPLIED DERMALLY.
LONG-TERM ANI tHE ACTIVE rNGREDIENT INDICATED LYMPH NODES, THY'MUS AND SPLEEN F AND DERMIAL EXPOSURE; A SMALL iNCI INcIDENce OF "AMr&#xb6;DRY TUMODRS WASI INHALATION OR INCEST ON O7F ETYHLJ RESULT rN CENT'JRAL NEOVOUS SYSTEM LIVER AND KIDNEY DAM4GAE ANJD FETO' TERATOCENICrTY. 
: 12. EhLOLDGCAL-INFORMATION SEWAGE BACTERIAL TOXICITY.INHIBITORY CONCENTRATION ON RES?" AEROBIC WARTE IJATERL-rC20.
IC50; NO DATA AVAILABLE FOP THE PRODUCT BELOW IS FOR TERBUTHS'LAZINE, THEI INGREDIENTZ FrSH TOXICITY RLuwGILL:
96 HR LC~o = 7.8 PP" RAINBOW TROlUT: 96 A~R LC50 3. INVERTEBRATE TOXICITY DAPHNIA MAGNA: 4A HR ECMD 39 ( AVIAN TOXICITY MALLARD DUCK: ORAL LD50 > 2510 BOBWHITE QUAIL: S DAY D.IETARY E MALL.ARD DUCKT A DAY DIETARY LC----=-=~13,~ DISPOSAL CONSIDERATIONS
~~~ METHOD_._.
OPEN DUMPINC OR BURNING OF THI51S~ PROHIBITED-AN ACCEPTABLE METHOD( TO BURN IN AN INCINEOATIOR IN ACCO~t LOCAL. STATE AND FEDERAL EmVIRONN5 7PULfP STANJDA~bS AND :'REGjLJ4TONS.'
ITHE APPROPRIATE REGULATORY 4CENCI:E CONTACTED PRIOR TO VISPOSAL.  (CONTIN~jJ P. 005 6~61+S47+/-
P.ON THE LIVER, 0 IROOICT WAS IAL STUDIES WITRH' 'OXIC EFFECTS INf )LLOWIjNa ORAL tEASED ICTED IN RATS. 7bNE CLYCOL MAY DEPRESSION, OXI1CITV AND IRA~TION OF 1Ca0 > 100 PPM' *INFOR14ATION 4IAJOR PPM 30 > 5620 PPM 5 nia 'PPM OP DISPOSAL DANCE WI1TH 3SHOULD BE 'D PACE 04 ALL'1 000244 TO 91617&#xfd;542713 P.05 NOV. 02'99(TUE) 11:00 HOUGHTON CHEMICAL TEL:16172542713 BELLACJDE(R) 325 5915 U.S./CANAD, VERSION DOT PROPERISHrPPING NAME.: IATA. ..... .... ..... INDC ...... .............
DOT CLASS IICATION ....... DOT LABELSI ...............
DOT MARKING ..............
DOT PLACARD ................
UN NUMBER ................
HAZARDOU'S SUBSTANCE/RO..., 49 STCC NUMBER ..........
PRECAUTIONS TO BE TAKEN..IN TRANSPORTATION OTHER SH .IPFING ...........
INFORMATION OSHA EXPOSURE LrmrTs SUBSTANCE(S)
...........
OSHA PEL-TWA .......... 
*ST&#xfd;L .............
CEILING. .............
; SKIN DESICNATION.
A CQiH TL4-TWA ..........
: STfiL ..............
1 CEZL!ND ..........
SKIN DESIGNATION.:!
TARGET IORGAN EFFECTS......
CARCLNOGENIC POTENTIAL...
REGULATED BY OSHA ...... LISTED OD NTP REPORT...;
IARC GROWP i, 2As 2B... U.S. EPA REOUlReMENTS RELEASE &#xfd;EPORTING CERCLA (40 CFR 302) LISTED SOBSTANCE(S)....:
ROe.............
PAtEGORY.
RCRA WASTE ND..,,. VNLZ STED: SUBSTANCE'(S)..  .., .d ,. ., CHARACTERISTIC...
RCRA WASTE NO,.... SARA TITLE II SEC 313 LISTED TOXIC CHEMICAL,.:
INVENTORY REPORTINGC PAD-41 p I EFFECTIVE, 06128/95 14. TRANSPORT INFORMATION
====q NOT REGULATED AS A HAZARdOVS MIA DOT 49 CFR 171.01. NOT PECULATED NOT REGULATED NOT APPLICABLE NOT REOUIRED NOT REGUIRED NOT REQUIRED NOT APPLICABLE NOT APPLICABLE NOT AVAILABLE KEEP CONTAINER TIGHTLY CLOSED. PHYSICAL DAMAGE. NONE IS. REGULATORY NONE NOT APPLICABLE NOT APPLICABLE NOT APPLICAeLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE LIVER, TESTES, NO NO NO NO NONE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NONE NOT APPLICABLE 7OT APPLICABLE NOT APPLICABLE INFORNATI C THYMUS, .tiOMACH, NONE (CONTI?'FMC 4: -- -P1 T PUNTED: 'ERIAL BY U.S. 2ROTECT AGAINST PLEEN UED) PAGE 05 0021-5 MATERIAL SAGTV  TO P. 006 ei? I& ?15 lp.e .F- M C NOV.:02'99(TUE) 11:00 HOUGHTON CHEMICAL TEL:16172542713 RELLACIDE(R) 325 5915 U.S./CANADA VERSION SARA TITLE III SEC 31113tZ (40 CFR 3701
* UB$TANcE(B)..,.........,.
HAZARD CATEGORY ........
PLANNI'N:
THRESHDLD'.
.... EMERGENYv PLANNJNC SARA TITLE:III SEC 3O2-3D3 (40 CFR 355) LISTED SUBSTANCE(Sl
.... R4.......
;..............
PLANNING THRESHOLD.....:
U.S. TSCA STATUS .........
CANADA INGREDIENT.
DISCLOSURE LIST SUBSTANCES
), ..........
; CONTROL.L.ED!
PRODUCT ....... : HAZARD SYMBOLS ...........
: CLASS & DIVISION .........
PRODUCT IDENTIFICATIDN NO: DOMESTIC SUBSTANCE LIST..: CEPA PRIORiTY LIST ....... CARCINOGENICITY ACGIH APPENDIX A ....... Al -CDNFIRMED HUMAN-.: Ai -SUSPECTED HUMAN...
IARC "R.RUPi I altR ...... .. LABEL LANGUAGE (US/CANADA)
HEALTH-.'
............
PHYSICAL ............
HANDLINC AND STCR4CE...
: FiRST AIb ..............
: STATE REGULATIONS.._......:
PAD-41 2 EFFECTIVE:
06/28/95 I*15. REGULATORY 3NFORMATI1N NOT APPLICABLE DELAYED (CHRONIC)
NOT APPLICABLE NONE NOT NOT YES NOT NOT NOT NOT NOT NOT NOT W==HELLTH.HAZARD kPPLICABLE APPLICABLE CCOMPONENTS)
EVALUATED EVALUATED SVALUATED EVALUATED EVALUATED EVALUATED EVALUATEE FOR FOR FOR FOR FDR FOR FOR CANADA CANADA CANADA CANADA CANADA CANADA CANADA NO NO NO NO FOR UNITED STATES ONLY U.S., CAUTION- HARMFUL IF SWALL THROUGH THE SKIN. 4VOID 'CONTACl CLOTHING.
WASH THOROUGHLY AFTEf REMOVE AND WASH CONT MINATEDCL!
REUSE. NOT APPLICABLE KEEP OUT OF REACH OF' CHILDREN.
DO NOT CONTAMINATE UAT?,R; FOOD STORAGE AND DISPOSAL.
PROTECT FIRST AID IN CASE OF CONTACTt EYES: FLUSH EYES WITH PLENTY O0 LEASE 15 MINUTES. GET MEDICAL A SKIN: PLVCH SKIN WITH PLENTY OF WITH MILD SOAP AND-WATER.
INGESTION:
IF CONSC;IOUS, GIVE P AND INDUCE VOMITING tY PLACrNG F OF THROAT. GET MEDICAL ATTENTID NONE KNOWN (CONTI 25-42713 P. 07 4fMC.OWED OR ASOSRSED 1 "i WITH 'SKIN A?.Jo ilHANDLING.
tHIN4G ; FEED BY fOM FREEZIN, WATER FOR AT iWATER OR 1IASMt i ; i LENTY OF WATER iNGEI IN BMClPACE 06 000?1'VATERIAL SAFETY OAIA.4 TO P. 007.T*&#xfd;'-09-1998 09: Le FRal'PNTED : 02/23/96 E 1 NOV.-02' 99(TUE) 11:00 HOUGHTON CHEMICAL TEL:16172542713 BELLACIDECR) 325 5915 U.S./CANADA VERSION----- ==;--- ==== ==== =nwC PRODUCT USeS .............
NFPA 704 HEALTI4 ... FLAMli.sIL iTy .... REACTIVITY
..........
i SPECIAL HAZARD...
ciDrmGFR bF HAZARD 0 -NO HAZARD 4 oEv-RE HA.iARD)-41 2 EFFECTIVE:
06/28195 16. OTHER INFORMATI
.. ALGICIDE REGISTERED UNDER EP4 NO. 279-313i IMPORTANT; THIS MATeERIAL IS NOT; USE IN PRODUCTS FOR ,I4HICk PROLON WITH MUCOUS MEMBRANES OR:ABRADED IMPLANTATION WITHIN THE HUMAN EO SPECIFICALLY INTENDED, UNLESS THI PRODUCT HAS BEEN TESTED IN ACCOR FOOD AND DRUG ADMINisTRATION AND APPLICABLE SAFETY TESTING RECUIR OF THE WIDE RANGE OF SUCH POTENT FMC CORPORATION IS NOT ABLE TO RI NATERIAL AS SAFE ANVI EFFECTIVE Fi ASSUMES NO LIABILITY1 FOR ANY SUCi I 0 THE CONTENTS AND FOR&#xfd;MAT OF THIS M ACCORDANCE WZTH OSHA HAZJAR CoCMM CANADA'S WORKPLACE .AZARDOUS KATE 7NFORMATION SYSTEM (&#xfd;WHM!S).PAD PRINTED; 02/23/96-- INTENDED FOR ;ED'CONTACT SKIN. OR )Y, IS FINISHED )ANCE WITH THE 'OR OTHER MENTS. BECAUSE AL USES, COMMEND THIS R SUCH USES ANO USES.SDS ARE IN NICATICN AND RIAL PAGE 07 ii JArtA -L-.A 09:18 FRL-01 SAFETY DATik TO P. 008"I. '*1 () () ?17 P.MC -FMC': i;4271:S I I {!I Bayer 43 1MATERIAL SAFETY DATA SHEET BAYER CORPORATION PRODUCT SAFETY & REGULATORY AFFAIRS 100 Bayer Road Pittsburgh, PA 15205-9741 TRANSPORTATION EMERGENCY NON-TRANSPORTATION CALL CHEMTREC:
800-424-9300 BAYER EMERGENCY PHONE...:
(412) 923-1800 INTERNATIONAL:
703-527-3887 BAYER INFORMATION PHONE.: (800) 662-2927 1. CHEMICAL PRODUCT IDENTIFICATION:
PRODUCT NAME .........: Bayhibit AM Inhibitor PRODUCT CODE ........ ..V801 CHEMICAL FAMILY .....: Phosphonates CHEMICAL NAME ....... 2-phosphono-1,2,4-butanetricarboxylic acid aqueous solution SYNONYMS ............
:.PBTC FORMULA ..............
: C7H1109P in H20 2. COMPOSITION/INFORMATION ON INGREDIENTS:
INGREDIENT NAME /CAS NUMBER EXPOSURE LIMITS CONCENTRATION
(%) HAZARDOUS INGREDIENTS 2-phosphono-1,2,4-butanetricarboxylic acid 37971-36-1 OSHA : Not Established Approx. 50 % ACGIH: Not Established
: 3. HAZARDS IDENTIFICATION:
* EMERGENCY OVERVIEW * "* CAUTION! Color: Colorless to yellowish; Form: Liquid; * "* Odor: Very slight odor; May cause eye irritation; Contact * "* with metals liberates flammable gas; Corrosive to steel or * "* aluminum; Use cold water spray to cool fire-exposed
* "* containers to minimize the risk of rupture; Irritating
* "* gases/fumes may be given off during burning or thermal
* Product Code: V801 MSDS Page 1 Approval date: 11/18/1998 Continued on next page 10/25/99 08:33 Bayer Corporation pq /Iu 3. HAZARDS IDENTIFICATION (Continued)
------------------------------------------
* decomposition.
* POTENTIAL HEALTH EFFECTS: ROUTE(S) OF ENTRY ...................
Eye-Contact; Skin Contact; Inhalation HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:
ACUTE EFFECTS OF EXPOSURE ..... : On the basis of Animal Toxicity testing (see Section 11), we would expect this product to be moderately irritating to the eyes, with symptoms such as tearing, reddening and swelling.
We would also expect this product to be non-irritating to the skin and to be essentially non-toxic by ingestion.
CHRONIC EFFECTS OF EXPOSURE...:
Prolonged or repeated skin contact could result in skin irritation.
Possible symptoms include itching, reddening, swelling, rash and scaling. Based on animal test results, no mutagenic or teratogenic effects are expected.
Also, sub-chronic three (3) month animal feeding studies were conducted without any adverse effects.
CARCINOGENICITY
...............
: This product is not listed by NTP, IARC or regulated as a carcinogen by OSHA. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE ...... : Persons with pre-existing eye conditions may be more susceptible to the effects of overexposure to this product.
EXPOSURE LIMITS ................
: Not established for this product. 
--- ------------------------------------------------------------------------
: 4. FIRST AID MEASURES:
--- ------------------------------------------------------------------------
FIRST AID FOR EYES ...... : Flush eyes with water for at least 15 minutes.
Consult a physician if irritation persists.
FIRST AID FOR SKIN ...... : Wash thoroughly with soap and water. Consult a physician if irritation develops.
FIRST AID FOR INHALATION:
Remove to fresh air. Consult a physician if breathing is difficult.
FIRST AID FOR INGESTION.:
Consult a physician. 
--- ------------------------------------------------------------------------
: 5. FIRE FIGHTING MEASURES:
--- -------------------------------------------------------------------------
FLASH POINT .......................
: Greater than 212 F (100 C); DIN 51758. AUTO-IGNITION TEMPERATURE
....... : Greater than 932 F (500 C); DIN 51794. EXTINGUISHING MEDIA .............
: Water;-Foam; Carbon Dioxide Product Code: V801 MSDS Page 2 Approval date: 11/18/1998 Continued on next page el0Y0 9
-Uv/Lo/utjou:j5:
nayer sorporativn pa /+/-v 5. FIRE FIGHTING MEASURES (Continued)
SPECIAL FIRE FIGHTING PROCEDURES:
Under fire conditions irritating and/or toxic gases and aerosols may be present. Firefighters should wear full protective clothing and self-contained breathing apparatus. 
---- -----------------------------------------------------------------------
: 6. ACCIDENTAL RELEASE MEASURES:
---- -----------------------------------------------------------------------
SPILL OR LEAK PROCEDURES
..........
: Utilize recommended protective clothing and equipment.
Spills should be taken up with a suitable absorbent and placed in containers.
Spill area can be washed with water. Collect wash water for approved disposal.
Bayhibit AM may be eliminated from sewage water via precipitation by flocculation with iron (III) or aluminum salt.  ---- -----------------------------------------------------------------------
: 7. HANDLING AND STORAGE: ---- -----------------------------------------------------------------------
STORAGE TEMPERATURE(MIN/MAX):
Ambient/122 F (50 C). SHELF LIFE ....................
At least two (2) years. SPECIAL SENSITIVITY
.........
:.None known. HANDLING/STORAGE PRECAUTIONS:
Do not store in unlined steel containers as Bayhibit AM solution will dissolve steel and other metals, causing the generation of hydrogen gas (flammable).
Steel or metal containers must have a complete polyethylene liner on sides, top and bottom. Repack only into approved containers.
Store away from alkalis, food and beverages.
Handle as any moderately strong acid would be handled. Freezing of this product will not effect its quality. Keep away from food, drink and animal feeds.  --- ------------------------------------------------------------------------
: 8. PERSONAL PROTECTION:
--- ------------------------------------------------------------------------
EYE PROTECTION REQUIREMENTS
........ : Chemical workers splash goggles.
SKIN PROTECTION REQUIREMENTS
....... : Rubber, PVC, Nitrile gloves, aprons and other splash protection as appropriate for the conditions of use. Employees should wash their hands and face before eating, drinking or using tobacco products.
VENTILATION REQUIREMENTS
............
: Local exhaust ventilation at work area. RESPIRATOR REQUIREMENTS
............
:.None required under normal conditions of use. ADDITIONAL PROTECTIVE MEASURES ..... .Safety showers and eyewash facilities should be available.
Employees should be trained in the safe use and handling of hazardous chemicals.
Product Code: V801 MSDS Page 3 Approval date: 11/18/1998 Continued on next page 0002 &#xfd;5 0
: 9. PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL FORM ..........
COLOR ..................
ODOR ...................
MOLECULAR WEIGHT ....... pH ....................
BOILING POINT ..........
MELTING/FREEZING POINT. VISCOSITY
..............
SOLUBILITY IN WATER ... SPECIFIC GRAVITY ...... BULK DENSITY ........... 
% VOLATILE BY VOLUME...
VAPOR PRESSURE ........Liquid Colorless to yellowish Very slight odor ...: Approx. 270 for PBTC (10 % solution)
Approx. 1.1 (Initial):
212 F (100 C) Approx. 5 F (-15 C) ...: (Dynamic):
15 to 25 mPas @ ...: Miscible 1.27 to 1.30 @ 68 F (20 C) Not Established 50 to 55 % 19.6 mbar @ 68 F (20 C); 107 mbar @ 122 F (50 C)10. STABILITY AND REACTIVITY:
--- -----------------------------------
-------------------------------------
STABILITY
....................
Under normal conditions of use and storage, the product is stable. HAZARDOUS POLYMERIZATION...:
Will not occur. INCOMPATIBILITIES
........... .Steel, bases, sodium hypochlorite solution and strong alkalis (vigorous reaction which generates heat due to neutralization process).
Bayhibit AM may be added safely to dilute alkali solutions under controlled conditions, i.e. adding slowly with constant mixing. INSTABILITY CONDITIONS
..... : (see INCOMPATIBLE MATERIALS).
DECOMPOSITION TEMPERATURE..:
No decomposition below 212 F (100 C). DECOMPOSITION PRODUCTS ..... : Thermal decomposition may emit phosphoric acid, carbon monoxide, carbon dioxide and other unidentified by-products. 
--- ------------------------------------------------------------------------
: 11. TOXICOLOGICAL INFORMATION:
--- ------------------------------------------------------------------------
ACUTE TOXICITY ORAL LD50 ..........
: Greater than 6,500 mg/kg (Rat). (1) INHALATION LC50 .... : Aerosol concentrations of up to 3,000 mg/m3 were tolerated without development of symptoms.
(2) EYE EFFECTS ........ : Moderately irritating to rabbit eyes. (1) SKIN EFFECTS ....... : Non-irritating to rabbit skin (24 hrs.). (1) SUBCHRONIC TOXICITY...
: Feeding experiment/test over a three month period: In tests, doses of up to 6,800 mg/kg were tolerated without any adverse effect.  (2)Product Code: V801 Approval date: 11/18/1998 MSDS Page 4 Continued on next page@ 68 F (20 C) 68 F (20 C) l0/Z//98 O:S: sayer corporation Pt /iv 11. TOXICOLOGICAL INFORMATION (Continued)
CHRONIC TOXICITY ...... .Data not established for product.
MUTAGENICITY
..........
..Salmonella/microsome test (Ames test): No evidence of mutagenic effects. (2) REPRODUCTION
..........
: Pregnant rats were administered doses of up to 1,000 mg/kg body weight; no evidence of possible embryotoxicity or teratogenicity were found. (2) (1) Tests at the Institute for Toxicology of Bayer AG.  (2) Tests performed with Bayhibit S (sodium salts): Data recalculated to correspond with Bayhibit AM.  --- ------------------------------------------------------------------------
: 12. ECOLOGICAL INFORMATION:
--- ------------------------------------------------------------------------
AQUATIC TOXICITY ...........
: ACUTE BACTERIA TOXICITY:
No harmful effects to Escherichia coli at 105,000 mg/l, 24 hrs. and Pseudomonas fluorescens at 105,000 mg/l, 24 hrs. (3); DAPHNIA TOXICITY:
No harmful effects to daphnia magna Strauss at 300 mg/l, 24 hrs. (3); FISH TOXICITY:
Rainbow trout (Salmo gairdneri)
LCo = 5,300 mg/l, 48 hrs. (3); OTHER AQUATIC TOXICITY:
No harmful effect to Scenedesmus quadricauda (green algae) at 1,300 mg/l, 24 hrs. (3); BIOLOGICAL DEGRADATION:
17 % after 28 days (Zahn-Wellens Test) (3) NOTE: Based on experience to date, no interference to biological purification installations if product is used appropriately.
(4) (3) Tests performed with neutralized solution -results recalculated for Bayhibit AM.  (4) Tests carried out in the biological laboratories of the Environmental Protection Department of Bayer AG.  --- ------------------------------------------------------------------------
: 13. DISPOSAL CONSIDERATIONS
--- ------------------------------------------------------------------------
WASTE DISPOSAL METHOD ....... : May incinerate or dispose of in closed containers at suitable deposit site if in accordance with federal, state and local environmental control regulations.
Empty packing materials should be disposed of at authorized incineration installations in accordance with applicable regulations. 
--- ------------------------------------------------------------------------
: 14. TRANSPORTATION INFORMATION:
--- ------------------------------------------------------------------------
TECHNICAL SHIPPING NAME ........ : 2-phosphono-l,2,4-butanetricarboxylic acid in water FREIGHT CLASS BULK .............
: Cleaning or Washing Compounds, NOI, Liquid FREIGHT CLASS PACKAGE ..........
: Cleaning or Washing Compounds, NOI, Liquid Product Code: V801 MSDS Page 5 Approval date: 11/18/1998 Continued on next page
: 14. TRANSPORTATION INFORMATION (Continued)
-------------------------------------------------
PRODUCT LABEL ....................
: Bayhibit AM Inhibitor DOT (DOMESTIC SURFACE)PROPER SHIPPING NAME ...........
: Corrosive Liquid, HAZARD CLASS OR DIVISION ....... : 8 UN/NA NUMBER ....................
: UN3265 PACKING GROUP ...................
:III DOT PRODUCT RQ lbs (kgs) ....... : None HAZARD LABEL(s)...................
: Corrosive HAZARD PLACARD(s)
..............
: Corrosive Acidic, Organic, N.O.S.IMO / IMDG CODE (OCEAN)PROPER SHIPPING NAME ...........
:.Corrosive Liquid, Acidic, Organic, N.O.S. HAZARD CLASS DIVISION NUMBER...:
8 UN NUMBER ........................
UN3265 PACKAGING GROUP ................ .III HAZARD LABEL(s)...................
Corrosive HAZARD PLACARD(s)
................
Corrosive ICAO / IATA (AIR) PROPER SHIPPING NAME ...........
: Corrosive Liquid, Acidic, Organic, N.O.S. HAZARD CLASS DIVISION NUMBER...:
8 UN NUMBER ........................
: UN3265 SUBSIDIARY RISK ..................
: None PACKING GROUP ....................
:III HAZARD LABEL(s) ..................
: Corrosive RADIOACTIVE?......................
: Non-Radioactive PASSENGER AIR -MAX. QTY ....... : 5 L PASSENGER PACKING INSTRUCTION..:
818 CARGO AIR -MAX. QTY ...........
: 60 L CARGO AIR PACKING INSTRUCTION..:
820 --- ------------------------------------------------------------------------
: 15. REGULATORY INFORMATION:
--- ------------------------------------------------------------------------
OSHA STATUS ..................
: This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA STATUS ..................
: On TSCA Inventory CERCLA REPORTABLE QUANTITY..:
None. SARA TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES..:
None. Product Code: V801 MSDS Page 6 Approval date: 11/18/1998 Continued on next page ju/Zo/tid va:aq 15ayur 1011 P0 f.LV 10/25/99 08:34 Bayer Corporation pb /+/-u 15. REGULATORY INFORMATION (Continued)
SECTION 311/312 HAZARD CATEGORIES
..... : Immediate Health Hazard SECTION 313 TOXIC CHEMICALS
....... : None. RCRA STATUS .................
: When discarded in its purchased form, this product meets the criteria of corrosivity, and should be managed as a hazardous waste (EPA Hazardous Waste Number D002). (40 CFR 261.20-24)
-pH is less than 2. The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements.
For details on your regulatory requirements you should contact the appropriate agency in your state. COMPONENT NAME /CAS NUMBER CONCENTRATION STATE CODE --- -------------------------------------------------------------------------
2-phosphono-1,2,4-butanetricarboxylic acid 37971-36-1 Approx. 50 % PA3 Water 7732-18-5 Approx. 50 % PA3 Cadmium 7440-43-9
< 0.02 ppm* (1) CA Lead 7439-92-1
< 0.02 ppm* (1) CA Mercury 7439-97-6
< 0.001 ppm* (1) CA Nickel NJ4 3, NJ4 7440-02-0 0.2 ppm* CA --- ------------------------------------------------------------------------
CA = California Proposition 65 NJ4 = New Jersey Other -included in 5 predominant ingredients
> 1% PA3 = Pennsylvania Non-hazardous present at 3% or greater.
MASSACHUSETTS SUBSTANCE LIST (MSL) Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identified when present in products.
To the best of our knowledge, this product contains no substances at a level which could require reporting under the statute.
* Please note that these were random sample analyses and content may vary from batch to batch.  (1) Value indicated is the detection limit.Product Code: V801 Approval date: 11/18/1998 MSDS Page 7 Continued on next page IV-/ILOI vo.3, Day.uZ &#xfd;Q.[VU&#xa3;.1&.Lo11
.,LV" .V 16. OTHER INFORMATION:
EMIS RATINGS: Health Flammability Reactivity 1 1 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe Bayer's method of hazard communication is comprised of Product Labels and Material Safety Data Sheets. EMIS ratings are provided by Bayer as a customer service.REASON FOR ISSUE .... PREPARED BY .........
APPROVED BY .........
APPROVAL DATE ....... SUPERSEDES DATE ..... MSDS NUMBER ............... Revise Emergency Overview Section ...... Ann M. Colo ...... J. M. Mostowy ...... 11/18/1998
...... 09/30/1996
...... 01998 This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Bayer Corporation.
The data on this sheet relates only to the specific material designated herein. Bayer Corporation assumes no legal responsibility for use or reliance upon these data.  --- -------------------------------------------------------------------------
Product Code: V801 Approval date: 11/18/1998 MSDS Page 8 Last page BETZDEARBORN MATERIAL Betz~earborn SAFETY DATA SHEET EFFECTIVE DATE: 08-MAR-1999 PRINTED DATE: 14-JUN-1999
: 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : DEPOSITROL PY5206 PRODUCT APPLICATION AREA: WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT. COMPANY ADDRESS: BetzDearborn Inc. 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) -355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
This product is subject to the Pennsylvania and New Jersey Worker and Community Right to Know Law. HAZARDOUS INGREDIENTS:
This product is not hazardous as defined by OSHA regulations.
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at Pennsylvania thresholds for carcinogens.
CONTINUED PAG E 1 PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999 NON-HAZARDOUS INGREDIENTS:
CHEMICAL NAME 7732-18-5 WATER TRADE SECRET (N320) TSRN: 125438 -6148 CONTINUED CAS#PAGE 2 N~l_57 PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999
: 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION May cause slight irritation to the skin. May cause slight irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract. DOT hazard is not applicable Emergency Response Guide is not applicable Odor: Mild; Appearance:
Pale Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight irritation to the skin. ACUTE EYE EFFECTS: May cause slight irritation to the eyes. ACUTE RESPIRATORY EFFECTS: Mists/aerosols may cause irritation to upper respiratory tract. INGESTION EFFECTS: May cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS: No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin. PAGE 3 CONTINUED PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999
: 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F > 93C P-M(CC) 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill. 
: 7) HANDLING AND STORAGE HANDLING:
Alkaline.
Do not mix with acidic material.
STORAGE: Keep containers closed when not in use. Protect from freezing.
Do not store at elevated temperatures.
PAGE 4 CONTINUED PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS This product is not hazardous as defined by OSHA regulations.
ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.270 Vapor Pressure (mmHG) ~ 18.0 Freeze Point (F) 27 Vapor Density (air=1) < 1.00 Freeze Point (C) -3 Viscosity(cps 70F,21C) 22 % Solubility (water) 100.0 Odor Mild Appearance Pale Yellow Physical State Liquid Flash Point P-M(CC) > 200F > 93C pH As Is (approx.)
13.1 Evaporation Rate (Ether=1)
< 1.00 NA = not applicable ND = not determined CONTINUED PAGE 5 PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur: INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "B" 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: J.,uu mg/ig 28 Day Oral RAT: 1,000 mg/kg/day NOTE -No clear indications of treatment related toxicity(dose adjusted to 100% active) Dermal LD50 RABBIT: >1,000 mg/kg NOTE -Estimated value Skin Irritation Score RABBIT: 0.3 NOTE -DOT HM181: noncorrosive Eye Irritation Score RABBIT: 3.3 NOTE -Maximum score at 48 hrs; completely reversible by day 4 Non-Ames Mutagenicity MOUSE: NEGATIVE NOTE -In Vivo Bone Marrow Micronucleus Assay :)AGE 6 CONTINUED a I
* Iz fJUJ]
PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999
: 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Acute Bioassay LC50: 1680 mg/L No Effect Level: 1350 mg/L Daphnia magna 48 Hour Static Acute Bioassay LC50: 1635 mg/L No Effect Level: 870 mg/L Mysid Shrimp 48 Hour Static Renewal Bioassay LC50: 9900 mg/L 5% Mortality:
4000 mg/L Sheepshead Minnow 96 Hour Static Renewal Bioassay LC50: 28300 mg/L No Effect Level: 20000 mg/L BIODEGRADATION COD (mg/gm): TOC (mg/gm): BOD-5 (mg/gm): BOD-28 (mg/gm): 130 70 9 9 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is: D002=Corrosive(pH).
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material.14) TRANSPORT INFORMATION DOT HAZARD: UN / NA NUMBER: DOT EMERGENCY RESPONSE GUIDE Not Applicable Not applicable
#: Not applicable CONTINUED PAGE 7 PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999
: 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS: Product is non-hazardous under Section 311/312 SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds
: 16) OTHER INFORMATION NFPAIHMIS Health Fire Reactivity Special (1) Protective Equipment CODE TRANSLATION 1 1 0 ALK B Slight Hazard Slight Hazard Minimal Hazard pH above 12.0 Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE MSDS status: 21-MAY-1997 08-MAR-1999 REVISIONS TO SECTION: 12 SUPERCEDES
** NEW ** 21-MAY-1997 PAGE 8 000A,(;3 DEFAULTCSID->
6107?47205 (SOURCE: BHRFACTS)MSDS Number. S3362 -- -Effective Date: 02/01/98 I I I MSDS Material Safety Data Sheet /From: Mallinckrodt Baker, Inc. 222 Red School Lane Phillipsburg, NJ 08865 I NCKRODT .B 24 Hour Emergency Telephone:
90D-859-2151 CHEMTREC:
1-800-424-9300 National Response In Canada CANUTEC: 613-996-66 Outside U.S. and Canada Chemtrec:
202-483-7616 NOTE: CHEMTREC, CANUTEC and National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals.
All non-emergency questions should be directed to Customer Service (1 -800-582-2537) for assistance.
SODIUM CHROMATE MSDS Number: S3362 -- Effective Date: 02/01/98 1. Product Identification Synonyms:
Chromic acid, disodium salt, tetrahydrate; Sodium Chromate, Tetrahydrate CAS No.: 7775-11-3 Molecular Weight 234.03 Chemical Formula: Na2CrO4.4H20 Product Codes: J.T. Baker: 3640 Mallinckrodt:
7592 2. Composition/Information on Ingredients Ingredient CAS No Sodium Chromate 7775-11-3 Percent Hazardous 99 -100%3. Hazards Identification Emergency Overview Yes End of Page: 1 -Continued on next page I 0000_64A 11/17/99 11:09:0?Page 082 1999-11-17 at 11:07 DEFAULTCSID->
6167747285 (SOURCE: BIEFACTS)MSDS Number. S3362 --- Effective Date: 02/01/98 DANGER! STRONG OXIDIZER.
CONTACT WITH OTHER MATERIAL MAY CAUSE A FIRE. CORROSIVE CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT.
HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE RESPIRATORY SYSTEM, LIVER, KIDNEYS, EYES, SKIN AND BLOOD. MAY CAUSE ALLERGIC REACTION.
CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
J.T. Baker SAF-T-DATA (tin) Ratings (Provided here for your convenience)
......................
......................------------------------------------------------------------.. . Health Rating: 4 -Extreme (Cancer Causing) Flammability Rating 0 -None Reactivity Rating 3 -Severe (Oxidizer)
Contact Rating: 3 -Severe (Corrosive)
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow Stripe (Store Separately)
...............
...............
..............------------------------------------------------------------.. . Potential Health Effects Inhalation:
Corrosive.
Extremely destructive to tissues of the mucous membranes and upper respiratory tract. May cause ulceration and perforation of the nasal septum. Symptoms may include sore throat, coughing, shortness of breath, and labored breathing.
May produce pulmonary sensitization or allergic asthma. Higher exposures may cause pulmonary edema. Ingestion:
Corrosive.
Swallowing can cause severe bums of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea.
May cause violent gastroenteritis, peripheral vascular collapse, dizziness, intense thirst, muscle cramps, shock, coma, abnormal bleeding, fever, liver damage and acute renal failure.
Skin Contact: Corrosive.
Symptoms of redness, pain, and severe burn can occur. Dusts and strong solutions may cause severe irritation.
Contact with broken skin may cause ulcers (chrome sores) and absorption, which may cause systemic poisoning, affecting kidney and liver functions.
May cause skin sensitization.
Eye Contact: Corrosive.
Contact can cause blurred vision, redness, pain and severe tissue bums. May cause corneal injury or blindness.
Chronic Exposure:
Repeated or prolonged exposure can cause ulceration and perforation of the nasal septum, respiratory irritation, liver and kidney damage and ulceration of the skin. Ulcerations at first may be painless, but may penetrate to the bone producing "chrome holes." Known to be a human carcinogen.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, asthma, allergies or known sensitization to chromic acid or chromates may be more susceptible to the effects of this material. 
: 4. First Aid Measures O001&#xfd;G 5 End of Page: 2- Continued on next page Fage 003 11/17/99 11:09:2B 1999-11-17 at 11:07 1DEFAULTCSID->
6187747285 (SOURCE: BIRFACTS)MSDS Number: S3362 --- Effective Date: 02/01/98 Inhalation:
Remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING.
Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately.
Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately. 
: 5. Fire Fighting Measures Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Releases oxygen, upon decomposition, which enhances combustion.
Explosion:
Contact with oxidizable substances may cause extremely violent combustion.
Fire Extinguishing Media: Flood with large amounts of water. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal.
US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities.
The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 
: 7. Handling and Storage 00k0 46 End of Page: 3 -Continued on next page Page 004 11/17/99 11:10]:01 1999-11-17 at 11:07 DEFflULTCSID->
6187747285 (SOURCE: BIRFACTS)MSDS Number. S3362 --- Effective Date: 02/01/98 Keep in a tightly closed container.
Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities.
Do not store on wooden floors. Wear special protective equipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace.
Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 
: 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): For chromic acid and chromates, as CrO3 0.1 mg/m3 (ceiling)
-ACGIH Threshold Limit Value (TLV): For water-soluble Cr(VI) compounds, as Cr = 0.05 mg/m3 (TWA), Al -confirmed human carcinogen.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices , most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest- For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible.
Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance:
Yellow, deliquescent crystals.
000.6?End of Page: 4 -Continued on next page 11/17/99 11:10:29 Page 805 1999-11-17 at 11:07 DEFAULTCSID->
filB7747205 (SOURCE: BREFACTS)MSDS Number. S3362 --- Effective Date: 02/01/98 Odor. Odorless.
Solubility:
Completely soluble in water. Density-.
No information found. pH: Alkaline % Volatiles by volume @ 21C (70F): 0 Boiling Point: No information found. Melting Point 792C (1458F) Vapor Density (Air=l): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1):
No information found. 10. Stability and Reactivity Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Burning may produce chrome oxides. Hazardous Polymerization:
Will not occur. Incompatibilities:
Flammable and combustible material.
Any combustible, organic or other readily oxidizable material (paper, wood, sulfur, aluminum or plastics).
Conditions to Avoid: Heat, incompatibles. 
: 11. Toxicological Information Investigated as a tumorigen, mutagen, reproductive effector. 
-\Cancer Lists\ -----------------------------------------------------
---NTP Carcinogen--
Ingredient Known Anticipated IARC Category.End of Page: 5 -Continued on next page9 1 11/17/99 11:11:12 Page 006i 1999-11-17 at 11:07 DEFAULTCSID->
6187747205 (SOURCE: BERFACTS)MSDS Number. S3362 --Effective Date: 02/01/98 Sodium Chromate (7775-11-3)
Yes No 12. Ecological Information Environmental Fate: When released into the soil, this material may leach into groundwater.
When released into water, this material is not expected to evaporate significantly.
This material may bioaccumulate to some extent. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition.
Environmental Toxicity:
This material is expected to be toxic to aquatic life. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility.
Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements. 
: 14. Transport Information International (Water, I.M.O.) Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.(SODIUM CHROMATE)
Hazard Class: 9 UN/NA: UN3077 Packing Group: III Information reported for product/size:
2.5KG 15. Regulatory Information
-\Chemical Inventory Status -Part 1\ -------------------------------
Ingredient TSCA EC Japan Australia OOO4-&#xfd;-g3 End of Page: 6- Continued on next page 1 11/1?/99 11:11:31 Pdge 007 1999-11-17 at 11:07 DEFAULTCSID->
6187747285 (SOURCE: BIRFACTS)MSDS Number. S3362 --- Effective Date: 02/01/98 Sodium Chromate (7775-11-3)
Yes Yes Yes-\Chemical Inventory Status -Part 2\ --------------------------------
Ingredient
--Canada-Korea DSL NDSL Phil.Sodium Chromate (7775-11-3)
Yes Yes No--------\Federal, State & International Regulations
-Part 1\-------------SARA 302- ------ SARA 313--...
Ingredient RO TPQ List Chemical Catg Sodium Chromate (7775-11-3)
No No No Chromium com--------\Federal, State & International Regulations
-Part 2\-------------RCRA- -TSCA Ingredient CERCLA 261.33 8(d)Sodium Chromate (7775-11-3) 10 No No Chemical Weapons Convention:
SARA 311/312: Acute: Yes Reactivity:
Yes (Mix No TSCA 12(b): Yes Chronic: Yes Fire: Yes ture / Solid)CDTA: Yes Pressure:
No WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S)
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. Australian Hazchem Code: No information found. Poison Schedule:
S6 WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Ratings: Health: 3 Flammability-Reactivity.
Other: Oxidizer Label Hazard Warning: DANGER! STRONG OXIDIZER.
CONTACT WITH OTHER MATERIAL MAY CAUSE A FIRE. CORROSIVE.
CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. HARMFU IF SWALLOWED OR INHALED. AFFECTS THE RESPIRATORY SYSTEM, LIVER, KIDNEYS, EYES, SKIN AND BLOOD. MAY CAUSE ALLERGIC REACTION.
CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
Label Precautions:
Keep from contact with clothing and other combustible materials.
End of Page: 7 -Continued on next page1 Yes Yes 11/17/99 11:11:53 Page 008lf 1999-11-17 at 11:07 OW%&#xfd;&#xfd;70 DEFflULTCSID->
618774725 (SOURCE: BE]RFACTS)
MSDS Number. S3362--- Effective Date: 02/01/98 Do not get in eyes, on skin, or on clothing.
Do not breathe dust or mist from solutions.
Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling.
Store in a tightly closed container.
Do not store near combustible materials.
Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING.
Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases get medical attention immediately.
Product Use: Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3, 6, 16. Disclaimer:
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy.
This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
Prepared by: Strategic Services Division Phone Number: (314) 539-1600 (U.S.A.) 9000 71 End of Page: 8 -End of document 11/17/99 11:12 :Z2 Page 009 1999-11-17 at 11:07 MATERAL SAF ATA COIL-RDTEAHE SECTiON 1 CHEMICAL PRODUCT ANP COMPANY IDENTFIJCA 7ION PRODUCT NAME: C.iVRiter PRODUCT CODE$: 82612, 8214, 8261 1 CHEMICAL FAMILY; "ileu l a'nf rlTane MSD0IO,0 Var. No.J tr. Date September 8, 19f C/2 'cl13S9~01332 Wdl :OT: SS, 021300 MANUFACTURE
/ SUPPLIER EMERGENCY TELEPHONE NUMBERS: RectorSeal Che"ae 24 hours: (800) 4244300 2601 Spenwick RectorSeal:
(713) 263-4001 Houston, Texas 77055 USA NON EMERGENCY TELEPHONE NUMBERS: Technical Service; (B00) 231-3345 SECTION 2 COMPOSTION
/ INFORMA T1ON ON INGREDIENTS APPROX HAZARDOUS COMPONENT, CAS NO. ?a OSHA PEL ACGIH TLV OTHER LMITS _!MIr NFPA Glycol ther EB 111-7"-2 1-5 25 ppm T5 ippm N/A iD H2.rZ,R0 SECTION 3 HAZARDS IDENTIFICATION
 
==SUMMARY==
OF ACUTE HAZARDS Irritation to eyes, nose, and throat; drowsiness, narcosis, fremors. and other CN0 effeGts at bigh concentrabons.
Sidn irrftaon, denrnatds, and deraling.
PRIMARY ROUTE OF EXPOSURE StfNS AND SYMPTOMS ROUTFJ-j INHALATION:
Nasal and respkatory irritaborn, dizziness, narcosis, hvadaoht, nautea, CNS depression, Yes and unconsciousness.
EYE CONTACT: Waterig, blurred vision, inflammation.
and irritation which Gan result in corneal injury, Yes SKIN CONTACT: Initation, Yes Nausea, vomiting; CNS depression:
irritation of gastrointestinal tract, liver and peritoneal wall; No lung congestion. 
 
==SUMMARY==
OF CtHRONIC HAZARDS! Sidn irritation, dermatltis, and derailing.
Possible liver and kidney damage. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSUREt Individuals with pre-existirLg or chronic diseases of the eyes, skin, respiratory system, cardiovascular
: system, system, liver, or kidrteyt may hnve increased sutsptlbility to excessive exposure.
SECTION 4 FIRST AID MEASURES INHALATION:
Lf overcome by exposure, remove victim to fr-h ofr imneodiatety.
Give oxygen or arificial respiration as needed. Obtain emergency medical attention.
Prompt action I6 , ,1*AI. EYE CONTACT: immediately flush with large amounts of water for at leaot 15 minute. tet pnrompt mecdical attention.
SKIN CONTACT: Wash with soap and water. Remove contaminated clothing, INGESTION:
Give large amounts of water, DO NOT induce vomiting.
Keep at rest. Get prompt medical attention, SECTION 5 FIRE FIGHTING MFASVRES FLASH POINT: None FLAMMABILITY LIMIIS: LEL N/D UEL; N/D EXTINGUISHINC MEDIA! Use agents suitable for surrounding fires. SPECIAL FIRE FIGHTING PROCEDURES:
Wear self-contained full face piece breathing apparatus and lufl body protective clothing.
Hazardous
-,,eempaitfio products possible (see Section 10)- Evacuate area. Dike area as run-off may create additional environmental contamination.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Material will not s$1utail eombusrton.
SECONL 6 ACCIDENTAL R.EA SE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS REL.ABED OR SPILLED: Remove all sources of ignition.
Use absorbent materials to prevent foolg hazard and to contain. Ventlate area with nat~ral or expion;of-praof, forced air ventlation.
Avoid flushing it sewers, drains, Watrways, and soil. Wear protecoive clothing and respiratory protection during cleanup. Ajee, if product Is subject to CERCLA reporlting (see Section 15) notify the National Resporne Center. SECTION 7 STORAGE AND HANDLING PRECAUTIONS TO BE TAKEN IN HANOLINO AND STORING: Keep Gontainqr closed ad tpight when not in use. Do not store near hent, wparKs. or open flames. If transferring this material to Qther ground all containers to avoid staic &letteldty buildup and discharge wbich may ignite flammable vapors. OTHER PRECAUTIONS:
Avoid prolonged or rep ated conlact with skin or clothing.
Empty containerm may contain residues and vapors: treat as if full and observe all products precautions.
Do not reuse empty containers.
KEEP OUT OF REACH OF CHILDRPN.
Page 1 of 2 E/2' *~
MAITERIAL SAFETY DATA SHEUT-C I R T m MS08110S0 Vet. N". vein. m"t Sqpi~mbor 8, i1999 SECTION a. E S RE CONTROLS/-PER-SONA-LPROT -C-77tI RESqpIRATORY PROlEGlION (SPECIFY TYPE;): In confir~ed, Poo0lY ventilated aroas, use NIOSHIMSI4A approved air puttyig or supplied air respirators V/ENTIATIONJ-LOCAL EXHAUST- Acceptable Spftial: NIA MECHANCAL (GENERAL).
P 1'.erable OTHER. NIA PROTeCTWV GLOVES: Wear non-pormeablealgvou,~
EYE PROTECTION:
tOhcmical 3plash goggleb (ANSI Z-87,1 or equivalenlt)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
CoYmbI~ rew~fi@:ded.
WORKJI4YCIENIC PRACTICES!
Where use can resuilt in skin contact. wu~h exposed imas thioroughly before eating, dunking. amoking, or leaving work area. Laurtder c htaminated clothing before reuse ,CTJON 9 PHYSICAL AND CH IQ P ER77ES BOILING POINT. 212'F (110"') Q@760mm HS SPECIFIC GRAVITY ("20 r11): 0-99 VAPOR PRESSURE (nmn Hg)., 17 C 68l1F (2M0) MELTING POINT. NIA VAPOR DENSITY (AIRt 1): NIA EVAPORATION RATE (ETHYL ACETATE I)- < 1 SOLUBILITY IN WATER: Soluble APPEARANCEIODOR:
Green Liquid STABIUTY., Stable OONDITIONS TO AVOID: Heat, sparks, open flamnes, arid W~ong olddizers.
INCOMPATIBILITY (MATERIALS TO AVOID)- Oxidizers, 2cids anid bases. HAZARDOUS DECOMPOSITION PRODUCTS:
CO, C02, and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION:
Will not occur.CARCINOVIENIOITY SUESTAticE Glyool Ether ES AWL4UANCE GLycaL Ether ES NTP.: No CA3 NO Iii 2 FOOD CHAIN CON4 POTENTIAL None SEC17O 11 TO0X1CQL0GY IffEMA7O IARC MONOGRAPHS:
No OSHA REGVLAT~rJ--
No LDOW Oral-Rat W50Q;470 MW4k LOSO Inhalation-R~at TCtxc:200 pprniel-.CT1ON 12 ECOL99!PAL INPONWATIN AtERWL %OX;Cf BOO NIA 26Pa AQUA719C TyXICrry 1000 uopm/24 hr~bdne shrimpflLm SEc7oIji 13 gISPOSAL CONSIMER-A77ONS WASTE DISPOSAL METHOD: Dispose of absorbed materials and riquid waste in aqordqCe with all local, state and federal regulAloris SECTION 14 1RANSPORPA77ON INOMAA7701Y DOT; Noo-Regulated OCEAN (IMDO). Non-Regutaetd AIR (LATA)- Non-Regliated WHMIS (CANADA):
Non-Regulated SUBSTANCE Glycol Ether EB SARA 213 Yes SECTION 15 REGULATORY INFO I?-AIA TI SAI~j!fNTORY CERCLA.&R!9 RC ODER yes NfA N/A SE77N 6gTHEFOM0 "Af770 This documnent is prepared pLirsuait to the OSH-A Hazardous Comnoimutigh
$tandard (29 CFR 1910.12a0).
The informationi ereln Is given in good faithi, but no warranty, express or implied is made- Corisdt Rectot~eal for huttiel ilifomaton:
(710)263-4501.
Page 2 of 2&#xa3;/T d 194Oi32&#xfd;4 LJH0T!T 6G,~ 02 _L3O C/T 'd 10/20/99 WED 14:35 FAX 214 337 8854 VRII M ~ 0 PROOUCT: ACTI-KLEAN MANUFACTURED BY: Virgkni KMP Corporation 4100 Plainumn Way Delt1as, Toma 715237 OSHA H.arfdous Components (29 CFR 1910.1200)
Efthlenie gy1coI monobuty1 ether (GAS# 111 -76.2) Dodecqbmenze sulforilc acdd (CAS# Z7176-87.0)
ACTI-KLEAN Mdaftea Safety Data sheet SECTION I -COMPANY IDENTIFICATION CAT. NO.: AK-I, AK-6. AK-65 TELEPHONE NUMBERS: Oftie: I-(24) 330-7731 Eme~recy OW.) 1-(800 424-93QO SECTION lI -HAZARDOUS iNGREDIENTS EXPOSURE LIMITS: a HR. TWA OSHA PEL AQGIH TLV 25 ppm (skin) 25 ppm (skin) NE NE SECTION III -HAZARDS IDENTIFICATION EMERGENCY OVERVIEW; WARNING] Eye and skin Irritant.
Hmmffui If sva~lowed or inhaled.
POTENTIAL HEALTH EFFECTS: ~INALATION:
Inhalatlon of vapors In high concentmljon may cause headache, nausea, vomtngV.
EYE CONTACT: Irritaltion develops hnmerdtely on comtact SKIINCONTACT:
Irritaftio develops on Cofitact INGESTION:
iarmful If swallowed.
May caue headache, nausea, vomriting.
CHRONIC Effects: Not estabtisled.
NOTE'. CARCINOGENICflY:
LISTED IN NTP? No 1A01"~ Al-SECTION IV -FIRST AID MEASURES lINALATIKN:
ROMM victim; to fresh ai ar4 I neededL hnmedltel begtn artficia respkration.
Gb, o~e O If breathV is totnored.
Got emergency medics] help. Contact a ptryelcan khiimedtly EYE CONTACT: Flush evas ith water for 15 mn~uft& Get medca attention if symnpbos develop and persist SMD CONTACT: Flush wiwateror soap and efor 1 ismI.. or munl itrces havebeeremoved Seek medical attention V slmptoma develo wid INGESTION:
Do noot induce vomftVng Rinseemouth olwith watwr e (Wmnmedlataredledialatuetion.
SECTION V. FIE FIGHTING MEASURES RAS PINO T MWES ME~OD: Not flammable
-aqueous soluftmo FLAMMABLE LIMITS: NA LOWER: NA UPPEPUNA AJUrObGOT1ON TEMPERATURE:
ME OGENRALHAZARD FIRE FIGHTING IlNSTRUCTIONS:
Ajproech ftr from Wp~nd sd.Avoid breathing erAWe tpmes, mist or vapors on the dowmw4nd side. Fn~htera wear -rbxv dcihkW Old Self cOntalned WrstIhkt apparatus.
EXTINJGUISHG EIWXA, DrY Poyf, Cardo dkbdde (C0 2). WMte11og or spay. HIAZARDOUJS COMBUSTION PRODUCTS:
Acrid smoke, krlftln and tondo fumes of SO,, H28, Pj,. SECTION VT -MCinENjmj RELEASE MEASURES LAND SPUA.. SMALL SPILLS Flush 1o sewerV1~hr I@ antourtsof water. 10 pwts watto Ipert pmduc LARGE SPILLS: Pick up with abeorbert mlads Pbio n non4euaft mtdrnV sfor prpwrdspoeal orn mu. WATER SPILL:- NWPa~ rper auihorkles.
Cleain tip bakiftftImp~smediately Io preveri "oi or water catn InhaWL SECTION VOI -HANDILING AND STORAGE HANIXUNG Avoid monact wfth skin, "ae. and clottg. After handing this prdut4 wash hwans before eating, drhn&#xfd;n, or anoldog. if COfltate oown. remove contaminated clott*,g.
If needed, b"i first aid acumo showen in section IV. taunder oontafti~nted clothng Weore raiue STORAGE.~
Store avy from food shtufs ooo;-  VIRGINIA KMP 19002 10/20/99 WED 14:35 FAX 214 337 8854 VRII I ~ 0 ACTI-KLEAN SECTION VIII -EXPOSURE CONTROLSIPERSONAL PROTECTION ENGINEERING CONTROLS:
Local etad~a ventlalo PERSONAL PROTECTION:
Respratory Protection not normall needed under normal conditbon o( use. Use rubber or latex glome, chemictal goggles or tiil face shlelds. Use boots, apron, drench showers eye wash as needed for protection against sits and/or splahes VAPOR PRESSURE:
NtO VAPOR DENSITY (Ak=1I): ND SPECIFIC GRAVITY (H200l).'
1.02 EVAPORATION RATE (SuAcu1):
<1 SOLUBITfY IN WATER:- Complete VOC PQL: pH1:11-12 FREEZING POINT: NO BOILING POINT: 212 F APPEARANCE
& ODOR, Green liquid.SECTION X -STABILITY AND REACTIVITY-I STABILITY:
Stable. CONDITIONS TO AVOID: High temperatre.
MATERMAS TO AVOID; O~ddlzers.
HAZARDOUS DECOMPOSITION PRODUCTS:
SO%, " 2 S. MOW fndM fmcombUStion
-smolce8an tao* fuMes. HAZARDOUS POLYMERIZATION:
WE! not occur.E#Wilene o4=w edtfierw TOLo: 600 nflt (oral -v rnn) TCLO: 195 ppm/81 (hih -hwTu ) GIT TCLO: 100 ppm Onh -human) NOSE, EYM CNs LDSD- 470 nMgf (arid -rat) Daeq bro attrd aidLC5O: 2900 n~3  (Intm- ra) Dodcylbezen s~onc Smd DS 506500 rToilg (oral -fmouse) HarroMttoaquati ife invery low concetratis.
Ethylene Ghpookonobuy~ether 1400Dppnul24 hrl brdesrm p /Tus ___ ~Dodecyl benzene sufonlof acId 5-15 ppml guppv/wUlbialcn SECTION Xli -DISPOSAL CONSIDERATIONS Olepos.as hazaidous iasW Classffication an documentatio Is requird before disposL Follow d ocastate andafodasi eglafton.
L SECTION XIV -TRANSPORTATION INFORMATMO PROPM SHIPPING NMAME Not regulated If contaener ho"d hs thaun 1175 galons HAZARDCLASS:
NA I=1F'CATION NUMBER: NA Aepeaftwie Qaunuty MRQ: 1175 galon (dodecjA benirmne K~fonic acid). b~wtsmailna NA TMA (roalo Substance ControAct):
Components Ofu prouc -x Welited on the TSCA lIwenwcy.
CERCLA (Copre~xhensive Envromnmenta Responsa, Conipenkgalh and LISWily Act) Repoiablequ
~isitlo75 gaons(dodecylbenznearfmenacid.
ConAct bocef muthortlos for other feprli~ eurements.
SARA TITTLE 111 (Superfund Amendments ed Reaufhiorlzaun AC:Q: Section 313:, Etyen G"y Morrobuty Ether (a *w so" atae 1096 CALIFORNIIA PROPOSITION 65: Not Mutod. SECTION XVI -OTHER INFORMATIO State Rgflt4o.IKiow Ptcglmrs MAk NJ. PA N eaotlvtkag0 MIS Protecve Equlpmen X See yourwpeviw PmPved by. Vlgknla MQP Corpoatim eion:Z1S This bifiamtlon Is furished without waffanty, enx02W~e Or bV*Bid. euoept ftht It is accurate to thv W megehof Wgt KP rhevda seand: 11/ re ratdOty to Spc dicNImre designated kheen Wulnis KPM mammas no legal reeponsibfty for use or relinc ipo fis tmat daa ailsshL L-Q003 VIRGINIA KNF Assigned to: ???? PRIFRAINOL FOR INFORMATION ONLY__.Aterlal Safety Data Shoot , abe uW t ap with 4Sw .Hazard Co~w~a3nStandard 1110-ZM &Wr UI be U.S. Departmqnt of Labor OccuPationaJSafety and Health Admlntstgatlon (Non-Mandatory Form)I.T '1d P,.V 4 N/A 5nePrmu"~
WucilyJ OSH-A 174, Sept 1W8!OOO#-,;G*k."WA wu.aorwIu aewrauna%
.:.- ,*- 0MS No;. 1218-"072
.. g SOEn7TY f4s Used m Lawe Aw "0Q .. ...N* --i ao t o amr~fayhe uio pialo .&#xfd;Bydrm 1500 SERIS &mawrmaA 19 *v&Ieb U C m )8r& be m k-" or r4ca V
* Mmmatu*r Nan* gawpon~y 76leph~of Nun"e 1WIPAS IN'I'ENMTIOMAI CORORATION 616-875-7234 -mass P"7Malb urea CA% Ua.04d ZIPMv Coe)Dweponet Numbvo- Por blotmahj P,0, BOX 14 616-875-7234
* 1DStV~L.I 4,94126- 1-9 swwna~ 01 I4pareI (cp")a Sectlon 1 -Hazardous IngredlentsfikdnUty WnormUon.
.... Jilawdmw Components (Speollo ChwrW oW1 lenmyOnwron Nemnes) C$si PEL ACOIH 1TV F= SOCi~on III PhyslcaVjchqemlc Chsrseterlaoce soikvpown 212-F 98-c SPolIAc Gravity (H 3 0 in )08 Va*porPrmwe (mm- H9) POiWn 1.080 =qpo Daniz R *1) 100oazo c NIA' .p&#xfd; r I v i n *w* * * * * .4 ( B u t y A c e t a t e 1 ) N / A -4 p awram Odor A-A BLUM WINhML i) Sectlon IV -Fire and Explosion Hazard Dati
* P C"l Po I M sawo Used) FIV nc i una I a Is N/A 4JE s"NAW me N/A N/A SpeCWa Fire Fsghiin Pmc.~dut.#
N/A *UJuwaul Fire anK&Wdxt~
HtAi N/A Expires On: ? .-~~7e P.71 ~'~./ a 0r4 / 17-Assigned to: ???? FOR INFORMATION ONLY Expires On: ? $06jo Reactivity Data 6tXI W j-, .:,DRYXNG TO SKIN .'' ~ .fktiw~omS Vq=N*rS1L4)n or Sypioducw I.CHtwdoul may 00w ICAX0W 1 uAvoid I4 N/A W41 Not Oocu ~$co~V1 Health Hazard Data 1C0nwoQwidir N TP? IAPIQ momwa'pfr?
wSM Regubo? NO ~~o Exposuref MAY OLTSE RMflES QE SKrN FOR SENSITIVE:
INDIVIMWAS jMod"a Conditior
;&#xfd;Gvrnrafy A~qravatvd by Exposure NONE KNOWNN !ermetpnvy and First Aid Psocadu'e KI K" IF SWA1tC4M, DO NOT INDUCE V10MITING, GIVE LARGE AlMOIM OF WTER, SEEJK MEDICAL AF7 ION~ *7~1lf onV11 -Precautions for Safe Handling and Use Stop& to Ba Taken In Caso Mal"J I& AelauWaa ci pWod EWSH THROUGH NORMAL SANITARY SEWER SYSTEM' Wisu LARGE AMUNI' OF WATER SAM ASK =BV.FT ~ F:FR AT. STATE AND LOCAL LAWS .iicautiDul to0Be Taken ki Nv~l~ng atW $o&ig KEE ERCE4 FREEZING S70RE BMqEM' 35"AND 100 f ,"Xw Picauions
.4,3ecl1on Vill -Control Measures Ieslrloy Po~tln (p~T NO T RBQUIRED 'W10 SED AS DIRBCT'ED
!rftn Loc4J Exhaust p~a RUBBR Ey P1, SAF`I'? GLASSES ewir Proioc~va Clolhing ix EquIpmrent
=Y ~FYTRR!) iokxygeno Pac~osNOT REVIRMl Pago 2 &GP~SM~.3/)l O'NEILL INDUSTRIES INC TEL No.215-535-6007 Jun 6.94 9:40 No.005 P.02 MATERIAL SAFETY DATA SHEET Z2z 31 ORGANIC ORANGE SECTION I -IDENTIFICATION COMPANY NAME .............
7O'Neill Indust7ies, Inc. 5101 Comly St. Phila., Pa. 19135 PHONE NUMBER .............
(215) 333-5700 EMERGENCY PHONE NUMBER...
800-255-3924 EFFECTIVE DATE ...........
4/1/89 REVISED DATE .............
3/31/94 CHEMICAL NAME .............
Orange Distillate tRADE NAM. ...............
ORANiC ORANGE SECTION II -INGREDIENTS COMPONENTS PERCENT TLV (Units) PROD. CAS # 1,8(9)-p-Methadiene
>95% Not 5989-27-5 established Nonylphenoxy-
<5% Not 26027-38-3 polyethoxyethanol establ ished SECTION III -PHYSICAL DATA BOILING Point(F) .........
175.50C SOLUBILITY IN H20 ........ Emulsifiable kPPEARANCE/ODOR
..........
Clear colorless liquid, citrus odor SPECIFIC GRAVITY (H20=l). .85 PH........................
SECTION IV -FIRE AND EXPLOSION DATA FLASH POINT ...............
l5bF Closed Cup EXTINGUISH MEDIA .........
Use foam, dry chemical, or CO* FOR FIRE .................
Minimize breathing vapor or fumes. Cool fire exposed containers.
Do not enter confined fire-spaces without proper protective clothing, Including self contained air supply. JNUSUAL FIRE HAZARD ...... Burning liberates carbon monoxide, carbon dioxide and smoke. aum-- =M3umma -3~= 3 3 =W a=3 a w= m = ====zm =m "Mmam www walakS SECTION V -REALTH EL'JARD DATA )VER EXPOSURE EFFECTS....
Liquid may be irritating to eyes and skin. Vapor is irritating to throat and lungs.  ?IRST AID PROCEDURES.....
EYES; Immediately flush eyes with water for at least 15 minutes. Seek medical attention immediately.
SKIN; Wash with water. If irritation develops or persists seek medical attention.
INHALATION; Remove to fresh air. INGESTION:
DO NOT INDUCE VOMITING.
Give large quantities of water. Get medical attention immediately. 
*um m m m wcnu a ==m=a =am= awn a= caw==== Maocmu nmumm mmawmm 3ECTION VI -REACTIVITY DATA :HEMICAL STABILITY
....... Stable 0002_ 7s Assigned to: ????FOR INFORMATION ONLY Expires On: "
O'NEILL INDUSTRIES INC TEL No.215-535-6007 Jun 6,94 9:40 No.O05-P.03 e -,o 3S 2 MATERIAL SAFETY DATA SHEET ORGANIC ORANGE CONDITIONS TO AVOID ...... Excessive heat and flames. Avoid strong oxidizing agents. INCOMPATIBLE MATERIALS...
Strong acids, strong oxidizers DECOMPOSITION PRODUCTS...
Carbon dioxide, carbon monoxide HAZARDOUS POLYMERIZATION.
Will not occur POLYMERIZATION AVOID.....
SECTION VII -SPILL OR LEAX PROCEDURE amameammanaazmmmaeaaaammmmaaaxmuama~=mammaaaaam .mum ammmmftmmm FOR SPILL ...............
Absorb with inert material and dispose of in accordance with applicable regulations.
WASTE DISPOSAL METHOD....
DispoBe of according to all local, state, and federal regulations.
ECTrION VIII -SPECIAL PROTECTION RESPIRATORY PROTECTION...
None needed under normal conditions VENTILATION
..............
Local PROTECTIVE GLOVES ........ Rubber EYE PROTECTION
...........
Chemical goggles DTHER PROTECTIVE EQUIPMENT
...............
HANDLING AND STORAGE.....
STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT AND FLAMES. USE WITH ADEQUATE VENTILATION.
KEEP OUT OF REACH OF CHILDREN.
WEAR SAFETY GOGGLES AND RUBBER GLOVES WHEN HANDLING THIS PRODUCT.
SECTION IX -SPECIAL PRECAUTIONS DOT SHIPPING NAME ........ Combustible liquid, n.o.s., NA 1993, PG III DOT LABEL REOUIRED ....... None required REPORTABLE QUANTITY (RQ). N/A A{A NUMBER ................
NA 1993 UN NUMBER ................
N/A 'OMMENTS The information contained herein is furnished without warranty of any cind. Employers should use this information only as a supplement to other Lnformation gathered by them to assure proper use of these materials and the 3afety and health of employees.
000179 Assigned to: ????FOR INFORMATION ONLY Expires On: \??
-/0. -20 MATERIAL SAFETY DATA SHEET Penetone Corporation, 74 Hudson Ave., Tenafly, NJ 07670 CITRIKLEEN Page: 1 of 4 Date Prepared:
July 28, 1994 MSDS No.: 1850-407S SECTION 1 PRODUCT IDENTIFICATION
& EMERGENCYINFORMATION PRODUCT NAME: CITRIKLEEN GENERAL USE: Cleaning, degreasing PRODUCT DESCRIPTION:
Solvent emulsion GENERIC INGREDIENTS:
Water, d'limonene, surfactants, coupling agents, alkanolamine EMERGENCY TELEPHONE NUMBERS: PENETONE 201-567-3000 CHEMTREC 800-424-9300 SECTION 2 HAZARDOUS INGREDIENT SECTION This product is hazardous as defined in 29 0FR1910.1200.
OSHA HAZARD: FLAMMABLE, CORROSIVE OSHA HAZARDOUS INGREDIENTS EXPOSURE LIMITS 8 hrs. TWA (ppm) CAS# OSHA PEL ACGIH TLV D'limonene 5989-27-5 not established not established Monoethanolamine 141-43-5 3 3 SECTION 3 HEALTH INFORMATION
& PROTECTION EMERGENCY OVERVIEW:
Clear amber liquid with citrus odor. Flammable.
Can be corrosive to eyes, skin, and respiratory tract POTENTIAL HEALTH EFFECTS: EYE CONTACT: May cause irritation or bums to eyes on prolonged contact. High vapor concentrations may be irritating.
SKIN CONTACT: Frequent or prolonged contact may irritate or dry the skin, cause dermatitis or cause bums. Skin contact may aggravate an existing dermatitis condition INHALATION:
High vapor/aerosol concenrations are irritating or may cause burns to the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous system effects.
INGESTION:
Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting.
This may cause severe and delayed health effects such as inflammation of the lungs and infection of the bronchi. Ingestion may cause irritation of or burns to the digestive tract-SQ CITRIKLEEN Page: 2 of 4 Date Prepared:
July 28, 1994 MSDS No.: 1850-407S CHRONIC: Inflammation of mucous membranes and respiratory tract may occur upon prolonged breathing of mist. Ingestion of large amounts of d'limonene has caused kidney and liver damage in male rats but not in female rats or mice of both species.
Ingestion of large amounts of monoethanolarrine has caused kidney and liver damage in laboratory animals.
FIRST AID MEASURES:
EYE CONTACT: Flush eyes with large amounts of water. See physician immediately.
SKIN CONTACT: Flush skin with large amounts of water. Remove contaminated clothing and launder before reuse. If skin irritation develops or persists, consult physician.
INHALATION:
Remove person to fresh air. Administer oxygen or artificial respiration as needed. Call a physician immediately.
INGESTION:
If swallowed, give plenty of milk or water. DO NOT INDUCE VOMITING.
Use a stomach pump. Call a physician immediately.
WORKPLACE EXPOSURE CONTROLS:
PERSONAL PROTECTION:
Safety glasses are recommended for all workplace conditions.
Solvent resistant gloves should be used. Other protective gear, including splash proof goggles or face shield, rubber boots, apron, gauntlets, or rain gear should be wom depending on how the product is used. VENTILATION:
None needed under normal use conditions.
For enclosed areas, or where large amounts of the product are being used, the use of fans or other mechanical ventilation is recommended.
An organic vapor mask should be used if the TLV is exceeded and a particle mask if the product is sprayed. DO NOT MIST THIS PRODUCT. Use coarse spray only. SECTION 4 FIRE & EXPLOSION HAZARDS FLASH POINT: 125&deg;F PMCC, 165*F COC FLAMMABLE LIMITS: not determined AUTOIGNITION TEMPERATURE:
not determined GENERAL HAZARD: Flammable liquid. Can form flammable mixtures at or above the flash point. Containers can rupture and explode under fire conditions due to pressure and vapor buildup.
FIRE FIGHTING:
Either allow fire to bum out under controlled conditions or extinguish with water, foam, or dry chemical.
Cool exposed containers with water spray. HAZARDOUS COMBUSTION PRODUCTS:
Smoke, fumes, and oxides of carbon, nitrogen, and sulfur. SECTION 5 SPILL CONTROL MEASURES LAND SPILL: Eliminate sources of ignition.
For snall spills, use absorbent material such as towels or absorbent powders. Put all material into proper waste disposal container with lid tightly covered. Solvent soaked materials may spontaneously combust. For larger spills, dike spill, recover free liquid, and use absorbent material to dry area. Rinse area with water. Put all material into appropriate waste containers.
00 081 CITRIKLEEN Page: 3 of 4 Date Prepared:
July 28, 1994 MSDS No.: 1850-407S WATER SPILL: Remove product from water surface by skimming or with suitable absorbents.
This product contains surfactants which will cause it to disperse in water. Localized high concentrations of this product may cause fish lklls, but no persistent or long term effects will result. Check with local environmental regulatory agencies for reporting requirements.
SECTION 6 HANDLING & STORAGE STORAGE TEMPERATURE, OF: ambient. DO NOT STORE ABOVE 120 Deg. F. KEEP FROM FREEZING.
GENERAL: Keep away from heat sources, open flames, and other ignition sources. Do not store near strong oxidants.
SECTION 7 TYPICAL PHYSICAL & CHEMICAL PROPERTIES BOILING POINT, OF: VAPOR PRESSURE, mm Hg at 20&deg;C: About 212 equal to water EVAPORATION RATE, Acetone = 1: VAPOR DENSITY (Air = 1): equal to water equal to water SOLUBILITY IN WATER: WT% ORGANIC VOLATILES:
emulsifies about 30 SPECIFIC GRAVITY at 75*F: pH: 0.98 10.2 ODOR AND APPEARANCE:
clear amber liquid with citrus odor SECTION 8 REACTIVITY DATA GENERAL: This product is stable and hazardous polymerization will not occur. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Strong oxidizing agents. SECTION 9 REGULATORY INFORMATION DEPARTMENT OF TRANSPORTATION (DOT): PROPER SHIPPING NAME: FLAMMABLE LIQUID, CORROSIVE, N.O.S.  (contains dlimonene and ethanolamine)
HAZARD CLASS: 3 IDENTIFICATION NUMBER: UN 2924 LABEL: FLAMMABLE, CORROSIVE FLASH POINT: 125&deg;F TCC TSCA: The ingredients in this product are listed on the TSCA inventory.
CERCLA: This product contains no CERCLA reportable materials.
Contact local authorities to determine if there may be other local reporting requirements.
0000 -8;4 PACKING GROUP: Ill pH: 10.2 CITRIKLEEN Page: 4 of 4 Date Prepared:
July 28, 1994 MSDS No.: 1850-407S RCRA HAZARD CLASS: D001 Ignitable hazardous waste D002 Corrosive hazardous waste SARA TITLE III: 311/312 HAZARD CATEGORIES:
Acute health, Chronic health, Fire 313 REPORTABLE INGREDIENTS:
Diethylene glycol monobutyl ether CAS# 112-34-5 <5 wt% NEW JERSEY RIGHT-TO-KNOW INFORMATION:
This product contains water (CAS# 7732-18-5), d'limonene (CAS# 5989-27-5), monoethanolammonium dodecylbenzene sulfonate (CAS# 26836-07-7), nonylphenol ethoxylate (CAS# 9016-45-9), diethylene glycol monobutyl ether (CAS# 112-34-5), and monoethanolamine (CAS# 141-43-5).
CAUFORNIA PROPOSITION 65 INFORMATION:
This product does not contain any chemicals recognized by the state of California to cause cancer and/or birth defects or reproductive harm. SCAQMD INFORMATION:
Is mere a photochemically reactive material present? Yes What is the % by volume of photochemically reactive material?
about 30 What is the VOC content? 310 g/l What is the vapor pressure of VOC's? 0.14 mm Hg @ 20 0 C SECTION 10 NOTES HAZARD RATING SYSTEMS: HMIS NFPA KEY HEALTH 1 1 4 = Severe FLAMMABILITY 2 2 3 = Serious REACTIVITY 0 0 2 = Moderate 1 = Slight 0 = Minimal REVISION
 
==SUMMARY==
: SUPERSEDES ISSUE DATE: Change in Section 6 September 28, 1993 FOR ADDITIONAL PRODUCT INFORMATION, CONTACT YOUR SALES ENGINEER FOR ADDITIONAL IEALTI-VSAFETY INFORMATION.
CALL 201-567-3000 THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONS&DERED TO BE DEPENDABLE AND ACCLRATE TO THE BEST OF PENETONES KNOWLEDGE THE INFORMATION RELATES TO THS SPECIFIC MATERIAL.
IT MAY NOT BE VALID FOR THIS MATERIAL IF USED IN COMBINATION WITH ANY OTHER MATERIALS OR INANY PROCESS. IT :S THE USERS RESPONSIBILITY TO SATISFY ONESELF AS TO THE SUITABILITY AND COMPLETENESS OF THIS INFORMATION 7OR H:S OWN PARICULAR USE 000 483 MATERIAL SAF+/-I: ILY)AIA b~MI+/-I L4 G&#xfd; (Ess~ontiall Skmilef to 10 OSHA.2@) .'-/) SECTION I MRODUCT NAME MSA ,'1EA1TS-8AN1T1ZZR II lIMie Safety Appliances Company POTuLACIIE 18599-03 "JNUFACWlRIA 600 Penn Center Boulevard 0a DaY .P. eodutsar _______Pittsbgrs~h.
PA J5235&sect; --T11 Mr outSft W119EMeCy PHONE NO. 'I412-273-&#xfd;5500 OATS *SECTION It -INGREDIUNTS
*ACTWVE flIGREDIENTSs
: 5. 50tOIM CAP30NATE 497-19-8.
42.2 TRISODIUM PHODSP3RATE 7601-54-9 10.0 ALKMh (C14, 50%1-C12, 40%; C16o 10%) DIMETHML BNZYL AMMONIUM CHLOR~IDES 139-08-2 2.5 INERT flGREDIENT'St 45.3 GODIVM TRIPOLYPHOSPHATE 7758-29-4
*SODIIM, BICARBONATE 144-55-8 WATER7721 ISOMERIC LINEAR~ ALCOHOLS (Cll-C3.5)
POLYERTOXY WTBANOLS 6813 1-40-8* TETANOL 64-17-5 ISOBORNYL ACETATE 12S-12-2 SECTION III -PHYSICAL DATA 1110LIN POINTr t* IF. SPECIFI GRAV ~y (M2 0 1)08 VAPOR PRESSUAR Imm Mg.) %VOLATILE BY VOLUME N VAPOR DENSITY (AIRM I) EVAPORATION RATE l SOLUD".1TY IN WATER 20 ON1 AOUEOUS SOLUTION -9. 5 1- SO APPEARANCE FRAGRANT BLEND OF WHITE POWDER$ AND ODOR4 ______________SECTION IV- FIRE AND EXPLOSION DATA FLASH POINT fM.Uod vseo) 240 F-7 LAMMABLE LIMITS ILeI- A lug) NA VITINQUISMNG MEDIA WATEk SpRAY (FOG). FOAM. DRY CF!MCA.CRBNDIXD SPECIAL FIREU AL A B N I X D PaIHI1N PROCEDUME BLANKET FIRE WITH EXTINGUISHING MEDIUM UNUSUAL FIRE AND 001LOUJON HAZARDS 0 00 ,1:8 4 PRODUCT. IS NONREACTIVE -AND DOES NOTJ +/-IU.JJ.'X PORT'V Assiqned to: ????FOR INFORMATION ONLY Expires On: -
A.. t.FOR INFORMATION ONLYi iN --SECTION V HEALTH HAZARD DATA SKIN CONTACT WITH POWDER MAY CAUSE BURNS. FLUSH AFFECTED AREA WITH CLEAN WATER. EYE CONTACT WITS POWDER MAY CAUSE CORNEAL BURNS. AVOID RUBBING EYES BECAUSE WATER INSOLUBLE PARTICLES MAY SCRATCH CORNEA. IMMEDIATELY FLUSH EYES WITH CLEAN WATER WHILE HOLDING EYELIDS APART. CONTINUE FLUSHING FOR AT LEAST 15 MINUTES OR UNTIL IRRITATION SUBSIDES.
CONSULT PHYSICIAN AS SOON AS POSSIBLE.
INHALATION OF A LARGE ENOUGH QUANTITY TO POSE A SIGNIFICANT HEALTH RaARD IS IMPROBABLE.
INGESTION OF POWDER IS HARMFUL OR FATAL. SHOULD INGESTION OCCUR, DRINK MILK, RAW EGG WHITE, OR GELATIN SOLUTION, OR LARGE QUANTITIES OF WATER. 4"~cr~I am-pp e'T~% A&#xfd;?x~ AS POSSIBLE.SECTION VI- REACTIVITY DATA .UNSTABE CONDITIONS STAAMrY U LTO STABLE X AVo,. HAZARDOUS MAY OCCUR CONDmONS , ,, TO POLYMERIZATION WILL NOT. OCCUR X AVOIo NONE "nAZARDOUS "IONPOSITION UNDETER PRODUCTS INCOMPAnDKMN.r OXIDIZING AGENTS (MATERIALS TO AVOID) SOAP AND M&#xfd;=QN, C SURFACTANTS -DRACTTVATR SECTION VII -SPILL OR LEAK PROCEDURES So TO BE TAKEN #4 CASE MATERIAL SWEEP UP 15 RELEASED OR 9tJ.SM WATE DISPOSAL REMOVE TO SANITARY LANDFILL AWAY FROM WATER SUPPLIES UMEOD DESTROY EMPTY CONTAINERS SECTION VIII -SPECIAL PROTECTION INFORMATION R&IPWATORY NOT REQUIRED PROTECTION SPECIAL PLOTECrIo1 NOT REQUIRED PROTECTION NOT REQUIRED SECTION IX -SPECIAL PRECAUTIONS SPECIAL NANOLINO NOT REQUIRED PRECAUTIONS EIAL NOT REQUIRED.
MINIMUM SHELF LIFE 6 MONTHS. FOR TORAo .MAXIMUM SHELF LIFE AVOID HIGH HUMIDITY AND STORE IN .PRECAkUTION S OTHER elm l%YrNfl D 'rn7 T r..n 00Oc,__85r I m 1 _Assianed to: ?7??FOR INFORMATION ONLY Expires On: k?,7&#xfd;TNt7_7_1 OCT 19 1999 1G:50 FR C&K GIB ENUIRMTL-MTLEG10 582 G8G5 TO 91G107747205 L TM A'0ITERIAL SATF IY DAT A SHET ! '" :: : ": '~ ~ ~ ~..' ..i ..... '. .... : " ' &deg; " .." ' ' " "" ' " " ' ..! PRODUCT NAME: INTRACID RHODAMINE WT LIQUID PRODUCT COQE : A34517LI00 CHEMICAL FAMILY; Xanthene dye PREPARER:
Health & Safety Department DATE R D 10/19/19R9 REVISION DATE; 09/20/159 SUPPLIED BY: Crompton & Kn'owlea C51ors Inc. P. 0- Box 341 Reading, PA 19603 Phone: 61D-582-6765 24 Hr. Emergency Phone: CEEMTREC 1-800-424-9300 CANUTEC: For chemical emergencies in Canada, call CANTUC at 1 613-996-(;$65, _ _ .-. .... .~. HAZARDOUS COMFONENTS ACGIH TLV: ACGIH Short OSHA PEL: OSHA Short NJ Trade Component Percent Term Exposure Term Exposure Secret Limin (STEL) Linit (STEL) Registratio value: value: n Number: 10001400 inrellitik acid 3 N.E .E. .E .E. NON-HAZARDOUS COMPONENTS ACGIH TLV: ACGIH Short OSHA PEL: OSHA Short NJ Trade Componezn Percent Term Exposure Term Exposure Secret Limit (STEL) Limit (STEL) ReStratjio value: value: n Number: __________
1 &sect;odium chloride 7 N.E. .. .E. 7647-14-5 rade S3e6 ct Dye 10 to 20 N.E. .E. N-E, N.E. -5646P, compound 5 Page 1 Of 6 O008G P. 02 OCT 19 1999 1G:50 FR C&K GIB ENU]RMTL-MTLSS10 582 6895 TO 91G107747205 PRODUCT: A34517LI00 INTRACID RHODAMINE WT LIQUID 773..1w 5 70 1 N.E.[..[.E RII'S ... ... , ~4,, L'y1/4 >~ A~&A. AV~.: 7... ...........
: -. ....................
.. ... .! ..... ...... .. EZMRGENCY OVERVIEW:
Warning: Causes eye irritation.
May cause skin irritation.
EFFECTS FROM ACUTE 9XPOSURE:
EYE CONTACT: Irritating to the eyes SKIN CONTACT- May be irritating to the skin, INHALATION:
None known. INGESTION:
None known CHRONIC OVEREXPOSURE EFFECTS: Not known, CARCINOGENICITY; NTP -No, IARC -No, OSHA Regulated
-No PRINCIPLE ROUTES OF EXPOSURE:
None known. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Not known. EYES: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
SKIN:, in case of contact, immediately flush skin with plenty of soap and water for at least is minutes. Get medical attention.
INHALATION:
If inhaled, remove to freah air. If not breathing give artificial respiration, preferably mouth-to-mouth.
If breathing
+/-s difficult give oxygen. Get medical attention.
INGESTION!
If swallowed, induce vomiting immediately by giving two glasses of water and sticking fingers down throat; never give anything to an unconscious person. Get medical attention.  '% .... ...,u ... ' .1 ..... .',, .j.Page 2 Of 6 P. 03 OCT 19 1999 16:50 FR C&K GIB ENVIRMTL-MTLS610 5B2 6665 TO 91610??47205 PRODUCT: A34517L100 INTRACID R/iODAMINE WT LIQUID FLASH POINT: N.A. METHOD; N.A. IGNITION TEMP: N.D. FLAMMABLE LIMITS IN AIR -LOWER (%): N.A. FLAMEABLE LIMITS IN AIR -UPPER (%): N.A. EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Water Fog FIRE FIGHTING PROCEDURES:
Cool exposed containers with water spray after extingushing fire. UNUSUAL HAZARDS; None known. ADDITIONAL FIRE AND EXPLOSION DATA: As in any fire, wear self-contained breathing apparatus and full protective equipment. 
... ...--.-' -., ., , .... ., .- .... .... ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wear appropriate safety equipment.
contain and clean up spill immediately.
Prevent from entering floor drains. Sweep powders carefully minimizing dusting. Shovel all spill mler~ials into disposal drums and follow disposal inatructions.
Scrub spill area with detergent and flush with copious amounts of water.  -.. -..... ...., _ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE; 'Keep container closed when not in use. OTHER STORAGE AND HANDLING DATA: In accord with good industrial practice, handle with care and avoid personal contact.
EXPOSURE CONTROLS:
Local exhaust ventilation may be necessary to control air contaminants during the use of this product.
RESPIRATORY PROTECTION; If exposure to dust, mist, and/or vapors is likely, a NIO1H approved respirator with a protection factor of ID is recommended-See MSDS section 2 for information on the hazardous ingredients.
PROTECTIVE GLOVES: Wear chemical resistant rubber gloves and long sleeved clothing.
EYES: wear safety glasses or goggles to protect against exposure.
CLOTHING; Wear overalls, apron, or other protective clothing to minimize skin contaqt, OTN3R PERSONAL PROTECTION DATA: None known. HYGIENIC PRACTICES:
Avoid contact with eyes and skin. Avoid inhalation of dusts and vapors. Wash thoroughly after handling.
Keep containers closed when not in use-M. , .MW MR M a M1.~ I. 'A PHYSICAL STATE; ...........
LIQUID COLOR 4  ............
..........
RED ODOR; ...... SOLUBILITY IN WATER (20&deg;C). 0ooo0dc _ss8 Page 3 Of 6 P. 04 OCT 19 1999 16:51 FR C&K GIB ENVIRMTL-MTLS610 582 6665 TO 91610?747205 PRODUCT: A34537LI00 INTRACID RHODAMINE WT LIQUID SPECIFIC GRAVITY: ......................
1.13 DENSITY C 256C: pH: 10.5 @ 1.01 MELTING POINT; ... ................
.. .D. BOILING POINT: ...N.A FREEZING POINT : ...................
.............
N.D. VAPOR DENSITY (AIR=l)= ....1.. IS HEAVIER THAN AIR EVAP. RATE (BUTYL ACETATE=1)}:
..... SLOWER THAN BUTYL ACETATE VOC CONTENT (%): ..... N.D. VAPOR PRESSURE (nm/Hg @ 20C): N.D. STABILITY DATA; STABLE POLYMERIZATION:
Will not occur HAZARDOUS DECOMPOSITION PRODUCTS:
Burning will produce oxides of carbon, nitrogen and/or sulfur. INCOMPATIBILITY (MATERIALS TO AVOID): None known. CONDITZONS/HAZARDS TO AVOID: None known.  ., ....-.. ..-......
......I....ACUTE ORAL LDS0 (mg/kg) : .................
-o Data ACUTE DERMAL LD50 (mg/kg): .............
No Informaition ACUTE INHALATION LCBO (mg/L): ...... No Data IRRITATION TO (skin, eyes, respiratory)
None. ADDITIONAL TOXICOLOGY INFORMATION:
.....one known.-..v ________________________________________________............
"*.* .-...--...--..-.....-
ECOTOXICOLOGICAL INFORMATION:
No data is available at this time.' ' ' ' " " ~... .. .. .. .. .. ....... ,.' -'rf ..... .... ....-.. ..- --',- ----
-.l ,,:." DISPOSAL OF WASTE METHOD: Bury or incinerate according to federal, state, and local regulations.
CONTAINER DISPOSAL:
Containers should be triple rinsed, according to foederal regulations and/or good waste management practice.-5 DOT Proper Shipping Name: DOT Technical Name: DOT Primary Hazard Class:.NOt DOT Regulated
...............
N A . S............
.N .A .Page 4 Of 6 00OSi9 P. 05 I OCT 19 1999 16:51 FR CSK GIB ENVIRMTL-MTLS610 582 6665 TO 916107747205 PRODUCT: A34517LI00 INTRACID RHODAMINE WT LIQUID DOT Secondary Hazard Class; ... N.A. UT /NA NUMBER; ........ ................
N.A. DOT PACKING GROUP: ....N.A. DOT EMERGENCY RESPoNSE INFORMATION:
.........
........ Keep unnecessary people away. Isolate area and deny entry. Stay upwind. Keep out of low areas. Call CHEMTREC at 1-800-424-9300 for emergency assistance. 
........................
............
For chemical emergencies in Canada, call CANUTEC at 1-613-996-66.9 SARA SECTION 302; None Found SARA (311, 312) HAZARD CLASS; IMMEDIATE HEALTH HAZARD SARA (313) CREMWICALS!
THIS PRODUCT DOSS NOT CONTAIN A TOXIC CHEMICAL POR ROUTINE ANNTJAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SECTION 31V (40 CFR 372) AMOUNT OF SARA (313) REPORTABLE CHEMICAL (%): No SARA (313) Reportable Chemicals.
METAL CONTENT: This product is not a metallized dye. TSCA INVENTORY STATUS: All components of this product are included on the TSCA Section 8 Inventory.
CALIFORNIA PROPOSITION 65 CHEMICALS:
None TSCA SECTION 12(B) EXPORT REGULATIONS; This product is not subject to TSCA 12(b) Export Regulations.
GERMAN AMINES/MraOPEAN UNION AMINES: This product does not contain any compounds that would be prohibited under the current German/European Union regulations regarding cleavable amine compounds.  , ,)t 1~.w .; ... ..... .. ... " , ." .. ...ij... HAZARD RATING SYSTEMS HKICS: FLAMMABILITY I , REACTIVITy 0 , HEALTH 2 ADDITIONAL INFORMATION:
NONE Page 5 Of 6 !0..,.P. OE OCT 19 1999 16:51 FR C&K GIB ENUIRITL-MTLS610 522 G665 TO 91107?747205 PRODUCT: A34517L10Q INTRACID RHODAMINE WT LIQUID REASON FOR UPDATE: Product review-DISCLAIMER:
Crompton & Knowles warrants that this product confsrms to the chemical description on the label and is reasonably fit for the specific purposes referred to in its directions for use, subject to inherent risks referred to in the Material Safety Data Sheet for this product. Crompton & Knowles makes no other express Qr implied warranty.
In no case shall Crompton & knowleg be liable for consequenrial, special, or indirect damages resulting from the use or handling of this product. 
"51D O OfM S Page G Of S OOOcr~l** TOTAL PAPE.07 **P. 07 Asindt:??
O NOMTO NYEoreOn SPWN TM04C&#xfd;QCA.
CO., INC. MATERlIFI SAF DATA SHET 76/"'? A- I e>/ Z I ONC IIOT A t FROUCT NAME OR NME (as It appes an label) SD-20 (BULK) N*&FACTURERn S MFIE D0I4CY TELEPHONE MO. Spartan Chemical Co., Inc. (419) 531-5551 AORL-SS (NUBIER, S7RET, CITY, -STATE No ZIP CODE) MAPWACT1RER'S NO. 110 N. Westwood Ave., Toledo, OH 43607 00-503-6728 I SEICTION n I HAZIAq5 INIrEDIENTS I 1 I I -Table Z-1-A ICAS REGISTRY NO. I 01I OCHEICAL E(S) I TMS I STEM ICeingI N I I I II ,,.f'w 5 I mgI 3  I II4 NO HAZARDOUS INGREDIENTS AT 1% OR GREATER CONCENTRATION t nrVul TTY BOILING POINT 212 OF DC VAPOR PIESSURE -18 075OF -C X mmH9_.-_PSi VWM- DEI6TY (AIR -1) Unknown SOILIL17Y IN WATER Complete PHYSICAL DATA SPECYIC (RAVITY (-420 1) 1.074 EVAPORATION RATE (but. ace. =) <1 APARANCE AND ODOR Blue, citrus odor Concentrate 11.0-11.5 PERCNT SOLID BY WEIGHT Wx) 15-17 IS MATERIAL:
GAS PASTE R.A9 POINT -None SECTION IV FIRE AND EXPLOSION HAZAD DATA NE7HOD USED -ASTN -092 FLAMMAi3LE LI ENITS -n/a EXTINGUISHIN EDIA n/a SPECIAL FIRE FIGHTINC PROCEDRS n/a UNUSUAL FIE AND EXPLOSION HAqZARDS n/a I I Assigned to: ????FOR INFORMATION ONLY Expires On:'"--'(LIQUII) SOILID POWDER!
Assigned to: ???? FRIFRAINOL xie n ?SCTION V -WEALmTH H [DATA EFC OF VS 0FOSU -CONDITIONS TO AVOID THRESH)LD LIMIT VALUE -Not established Avoid eye contact; may cause eye Irritation.
PRIY ROES OF TRY INVfATIN SKIN CONTACT OTHER (SPECIFY)
CONDITIONS AGGRAVATED BY USE own ERGCY AND FIRST AM) PROEDRES -In case of contact immediately flush eyes with plenty of water for at least 15 minutes; call a physician.
Flush skin with water. Wash clothing before reuse. If swallowed, give large quantities of water or fruit juice. Call a physician Immediately.
SECTION VI -I.ACTMTY DATA STABILITY:
UNSTABLE STABLE X IM14PATIBILITY (MARMALS TO AVOID) None HAZARDOUS PRDUCETS None XZ19as MAY OCCUR PO2LYNEIZATION:
WILL NOT OCCUR X SECTION VII -SPILL OR LEAK PROCEDURS S T1 7 BE0 TAKEN IN CASE MATERIAL IS REASED OR SPILLED Flush with water to sanitary sewer system. WASTE DISPOSAL METHOD Same as above. SECTION VIII -SPECIAL PROTECTION IFORMATIUN FESPIATORY PROTECTION (SPECIFY TYPE) Nothing special VETILATION
-Good general ventilation should be sufficient for most conditions.
Local exhaust ventilation may be necessary for some operations.
PROTECTIVE GLOVES (SPECIFY TYPE) EYE PROTECTION (SPECIFY TYPE) If desired If desired OTHER PROTECTIVE EWLUFMENT n/a SECTION IX -SPECIAL P kRCAUTIONS FW1XUTIONS TO BE TAKEN IN HAINLINC AN STORItC Nothing special 0I" PRECAUTIONS Nothing special Spartan Chemical Co., Inc. SD-20 (BULK) Ref: 29 CFR 1910:1200 (OSM)TITIE DATE  Thomas J. Director of Pesearch 3une 1, 1990 Septeber 20, 1985*SCC6/90 Copyrighted:
Spartan Chemical Co., Inc. -For Use Only By Authorized Spartan Distributors.
00O-93 FOR INFORMATION ONLY Expires .On: \??Assianed to: ????-Tde'17&#xfd;&#xfd; 5&#xfd;&#xfd;-'-' '7 Sent By: SYNTECH PRODUCTS;SynTech Products Corporation 520 E. Woodruff Avenue Toledo, Ohio 43624 (419) 241-1215 419 241 6943;Section I -Product Identification Product Name; Effective Date: Touch It Up De-Contaminant*
6-99
* Do NOT use this product as a skin de-contamintt Section II -Hazardous Ingredients Chemical Name CAS# WT% 2 Butoxy Ethanol 111-76-2 1% + Other ingrdicrnts
-Iro~de Secret Propane/Butane 74-98-6/106-97-8 6-10% *All constitucnts are listed on the TSCA inventory.
Boiling Range; Vapor Pressure (psig) in Can (0@, 75"F: Solubility in Water of Coneentrate!
Specific Gravity of Concentrate:
% Volatile:
Flash Point of Spray: Appe-rance and Odor of Spray; pH: PEL 50ppm 1000ppm TLV 50 Skin contact 1oooppm Section III -Physical Data N.D. 65 Complete 1.036 7.49 None to I 50F. *Fag Open Cup White foam, perfume odor 11-12 Section IV -Fire and Explosion Hazard Data Flammability as per CPSC Flame Extension Test: Non-Flammable Flammable Limits: LEL: NI/A UEL, N/A Extinguishing Media; Foam, dry chemical, carbon dioxide Special Fire Fighting Procedures:
Keep containers ooL. IU;e equipment to protect personnel against rupturing, or venting containers.
Fire and Explosion Hazards: Above 120PF, containers may vent, rupture, or burst Section V -Reactivity Data Chemical Stability!
Stable Conditions to Avoid; D)o not expose to temperatures above 120,F. Incompatibilit" (Materials to Avoid): Strong oxidizers, acids or bancs, selected amines. Hazardous Decomposition Prodstets!
Thermal decomposition may produce carbon monoxide and/or carbon dioxide.
Hazardous Polymerization:
Will NOT occur 00;4z94 CARCIG No No 19 Oct'99 4:41PM;Job 386;Page 2/3 Material Safety Data Sheet 24 Hour -Call INFOTRAC 1-800-535-5053 HMIS Rating H-i F-0 R-0 19 Oct'99 4:41PM;Job 386;Page 312 Section VI -Health Hazard Data Effects of Overexposure Eyes: Minor irritation Skin: No evidence of adverse effect from available information Ingestion:
Can cause gastrointestinal irritation, vomiting, and diarrhea.
Inhalation; Product exists as foam. Inhalation of the foam could cause asphyxiation, Emergeuey and First Aid Procedures*
*Caution!
Do NOT use this product as a skin de-contaminant Eyes! Flush with water for at least 15 minutes, Skin: Wash exposed area with water and soap. Ingestion:
Do not induce vomiting.
Get medical attention.
Inhalation:
Treat for asphyxiation.
Section VII -Spill or Leak Procedures Stcps to be taken in case container is punctured and material is released:
Clean up area by mopping or with absorbent materials and place in closed containers for disposal.
Consult federal.
state, or local disposal authorities for approved disposal procedures.
Waste Disposal Method: When used properly aerosol products do not generate hazardous waste. Empty d&-pressurized containers can not be reused and should be wrapped an put in trash collection.
Cans which are pressurized or contain liquid must be disposed of in a permitted waste management facility.
Consult federal, state, and local disposal authorities for approved procedures Section VIII -Special Protection Information Specific Personal Protective Equipment Respiratory Protection:
Under normal ronditions no respiratory protection is required.
Ventilation:
Normal venitlation adequate.
Protective Gloves: None required, protective gloves may be worn. Eye, Protection:
None required, chemical splash goggles may be worn Section IX -Special Precautions Keep from freezing Keep away from children Special precautionary statement:
Please read and follow the directions on the product label. T"hey are you best guide to using this product in the most effective way, and give the necessary safety precautions to protect your health. The above infornmation percains to this product as currently formulated, arid is based in the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition.
We make no warranties, express or implied, and assume no liability in connection with any use of the inforoniion Prepared by J. Rose Signature MSDS -Touch It Up*000.93 Sent By: SYNTEOH PRODUCTS;419 241 6943; Assjqned to: ???? FOR INFORMATION ONLY Expires On: ''?JUL 28 '95 10: 1IAM HARRISSLIRG PAPER CO E P. -G NRt1JCO, Inc, 4501 Flat Rock Road P.O. Box 4684 -NPhi ladelphia, PA 19127 215-482-9182 30592 Tracy Rood IUOtbridge, OH 43405 4 19-666-86 TO c6-IQ--7q MATERIAIL SAFEWY DATR SHEET -601 lRI-OMOM-PHOSPHATE .Page 1 t 10(Section I -IDENTIFICATION I HMIS MRTIIIOS NAMICO Propr-ietary Home: 601 HRMI-LO NON-PHOSPHRTE .J-- ---I Chemical Hmawe: MAHe t 2 DOT Proper Shippin~g Nlame: Compound, C) eoni mg, So I Id IFlommvability W DOT Hazard I .D. Mo.: OOT Hazard Description; I Raoctiuitg 01 DOT Hazard Label Required:
4 a Severe hazard Date of Issas: JUN 21 91 .1 = Serious hazard Supencedes tISDS da ted: MIAR 22 90 2 = Moderate hazard Prepared by: George Sas 1 = SI ight hazar-d 0 -Minimal hazard Suection 11 -INDREDIENT IIIFORIIATIONi Chemical /Common Naa~e Sodium carbonate PlO-A-Zeol ite Sodium carbonate Sw Soium metas~ I i ccte Soim cteridl ae bettoterprngrureetudeth pefr memnt CA$ Nlo. 6834-92-0 7647-14-5 Weight 10-50 10-50 10-50 10-50 10-50, ACG1H TLU HIE HE ME OSHR PEL (mg/1i3)_
ME HIE MIE ME ME and Reauthorization Ret of 1985 (SAIRA) T itie IlI), Section 313 and 40 CFFR Part 372. Section III -PHYrSlCRL OATAR Boiling Point-(F)
MR Specific Graufty CLUater-l)
MR Vapor PrQgsurBa (mm Hq) MR 3 Liolatile by Volume HA Vapor Density (Air-1> wA EvaPormtion Rate (Water~l>
MR Solubility in Waoter Complete pH NR Rppeatarnce
& Odor, White free-flowimg powder Section IV -FiRE t EXPLOSION HAZARD DRTA Flash Point<F) NfR Method Used MR LEL (Lower Explosion Limit) "iA UEL. <Upper Explosion Limit) HA Extingiishirng Mledia NA .Special Procedures MA Unusual Fire and MR Exp I as ion Haxar~ds ,--continued on additionoi page4~s)-0UM.;&#xfd;lr, Assioned to: ????FOR INFORWIATION ONLY Expires On:
Assigned to: ???? FRIFRAINOL xie n ?JLL 29 '95 10:11IM HARRISBURG PRPER CO P. 5/6 HRMiICO, Inc.  --. 4501 FIat Rock Roto P.O. Box 4684 Philadelphio, PR 19127 30092 Tracy Roocd Wolbridge, OH 43415 4 19-6615-86 10 Section U -HEALTH HP4ZRRD DATR MITERIRL SRFE-TY RTR SHEET 50 1 NM I -LO MON-PHOSPHATE Page 2 ecx of 3 X-1" $ -Threshold Limit UVtue Routes of Exposure Effects of Overexposure Corcinogenicity Eye or skin contact, ingestion.
Contact with eyes or skin can cause severe Irritation.
This product is not considered to be a carcinogen bu the KTP, IRRC, or OSHA.EMIERGENICY FIRST RID PROCEDURES Eyes Thoroughly irrigate at once with running water for at least 15 mhinutes.
Get immediate medical attention.
Skin Flush with plenty of water. Ingestion Howe victim drink large quantities of1 woter or milk to dilute the product. DO MOT INDUCE UOMITING.
Get IMMEOIATE medical attention.
MOTE: Never give anythFng by mouth to an unconscious or convulsing victim. Inhalation MR Other MR Section VI -REACTIUITY DATA Stability Stable Conditions to Avoid Hone known Incompatible Mlterials lNone known Hazardous Decompos i t i on None known Products Hazardous Polymerization WIll not occur Cond i t i ons to Avo i d None known -continued on addltlonal page(s)-00O$.97 FOR INFORMATION ONLY Expires On: \??Assianed to: 777?
Asine. o... FRIFOMTINOLYEoresO:
JUL 28 '95 10B:1iM HARRISEURG PAPER CO U P. 6/6 NAMICO, Inc. S4CI1 Flat Rock Road P.O. Box 4684 "Philadelphio0 PR 19127 30592 Tracy Road Walbridge, OH 43465 4 1J-656-B8510 Steps to be taken In case Sweep up, Rinse spill area well withh'oter.
material is released Or spilled Woste Cisp$sol Method DISPOSER MUST COMPLY WITH AL.L FEDERRL, STATE, RAD LOCFL RAN 131SC<RBE LAWIS. Section UII -SPECIAL IO IWFORMRTTIOM Respiratory Protection None required UentilJation Rdequate 0 loves Rubber or neoprene Eije Protection Safety goggles Other Protective Equipment None required Section IX -SPECIAL PRECPAUTIONS Precautions in Handling Store in a tightly cfozed container.
and Starage Other Precout ions KEEP OUT OF RERCH OF CHI.LDREN.
NR -Not Applicable, N Not EstabI ished, NND- No t Vetermined for this product The information herein is given in good faith and is compiled from Miaterial Safety Mato Sheets furnishid bIy&#xfd; our, supp i ers. No worranty, expres or impI tied, I amod& or intended.
ftn w" of this information must be determined bij the user to be in occordance with applicoble Federal, State, and Io=1 laws and regulations.
!1RTERIf.
SAFETY DATA SHEET 501 HRM I-LO NON-PHOSPHATE page 3 000%98 Assi~qned to: ????FOR INFORMATION ONLY Expires On: "'-
BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 22-AUG-1995 PRINTED DATE: 19-OCT-1999 o BetzDearborn
: 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : POWERLINE INHIBITOR-PPL10 PRODUCT APPLICATION AREA: WATER-BASED CORROSION INHIBITOR.
COMPANY ADDRESS: BetzDearborn 4636 Somerton Road , Trevose, PA 19053 Information phone number: 215 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA)2) COMPOSITION I INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS#CHEMICAL NAME 7632-00-0 SODIUM NITRITE Oxidizer; toxic (by ingestion);
potential blood toxin No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
PAGE 1 CONTINUED OOOZ- 93 PRODUCT NAME : POWERLINE INHIBITOR-PPL1O EFFECTIVE DATE: 22-AUG-1995
: 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING May cause moderate irritation to the skin. Severe irritant to the eyes. Mists/aerosols cause irritation to the upper respiratory tract. DOT hazard: ORS (when container
> RQ) Emergency Response Guide #31 Odor: Mild; Appearance:
Light Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: Flood with water. Use of C02 or foam may not be effective.
POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause moderate irritation to the skin. ACUTE EYE EFFECTS: Severe irritant to the eyes. ACUTE RESPIRATORY EFFECTS: Mists/aerosols cause irritation to the upper respiratory tract. INGESTION EFFECTS: May cause gastrointestinal irritation with possible nausea, vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy.
TARGET ORGANS: Prolonged or repeated exposures may cause CNS depression and/or toxicity to the blood. MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
Causes irritation of the skin, eyes, and/or respiratory system. PAGE 2 CONTINUED 000300 PRODUCT NAME : POWERLINE INHIBITOR-PPL10 EFFECTIVE DATE: 22-AUG-1995
: 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: Flood with water. Use of C02 or foam may not be effective.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F > 93C P-M(CC) MISCELLANEOUS:
ORS (when container
> RQ) NA3082;Emergency Response Guide #31 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill. 
: 7) HANDLING AND STORAGE HANDLING:
Contains an oxidizer.
Avoid all contact with reducing agents, oils, greases, organics and acids. Do not allow to dry. STORAGE: Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use. PAGE 3 CONTINUED OOO(s3O1 PRODUCT NAME : POWERLINE INHIBITOR-PPL10 EFFECTIVE DATE: 22-AUG-1995
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION.
CHEMICAL NAME EXPOSURE LIMITS SODIUM NITRITE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
rubber gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Gray. (70F,21C)
Freeze Point (F) Freeze Point (C) Viscosity(cps 70F,21C)1.107 19 -7 8 Odor Appearance Physical State Flash Point P-M(CC) pH As Is (approx.)
Evaporation Rate (Ether=l)
NA = not applicable ND = not determined PAGE 4 Vapor Pressure (mmHG) Vapor Density (air=l) % Solubility (water) Mild Light Yellow Liquid > 200F > 93C 9.0 < 1.00 CONTINUED DOOOO2-18.0 < 1.00 100.0 PRODUCT NAME : POWERLINE INHIBITOR-PPL1O EFFECTIVE DATE: 22-AUG-1995
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "B" 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: 570 mg/kg NOTE -Estimated value Dermal LD50 RABBIT: >5,000 mg/kg NOTE -Estimated value 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY No Data Available.
BIODEGRADATION COD (mg/gm): 42 Calculated TOC (mg/gm): Inorganic, N/A BOD-5 (mg/gm): Inorganic, N/A BOD-28 (mg/gm): Inorganic, N/A 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is: Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material. 
: 14) TRANSPORT INFORMATION DOT HAZARD: ORS (when container
> RQ) UN / NA NUIMBER: NA3082 DOT EMERGENCY RESPONSE GUIDE #: 31 PAGE 5 CONTINUED 000 303 PRODUCT NAME : POWERLINE INHIBITOR-PPL10 EFFECTIVE DATE: 22-AUG-1995
: 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): 72 gallons due to SODIUM NITRITE; SARA SECTION 312 HAZARD CLASS: Immediate(acute);
Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
CAS# CHEMICAL NAME 7632-00-0 SODIUM NITRITE RANGE 11.0-15.0%
CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds
: 16) OTHER INFORMATION CODE TRANSLATION Health Fire Reactivity Special (1) Protective Equipment 2 1 0 NONE B Moderate Hazard Slight Hazard Minimal Hazard No special Hazard Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: MSDS status: 22-AUG-1995 REVISED FORMAT SUPERCEDES
** NEW **000a04 NFPA/HMIS PAGE 6 10/20/99 WED 15:11 FAX. 513 482 7353 MATERIAL SAFETY DATA SHEEr _&#xfd;2. Y -COBRATEC TT-50S PRODUCT CODE: X18WT7440 Page I of 7 August 16, 1999 SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATIOM MANUFACTURER:
PMC SPECIALTIES GROUP,INC.
ADDRPS: 501 Murray Road Cincinnati, OH 45217 EMERGENCY TELEPHONE:
(513) 242-3300 (USA) FOR TRANSPORTATION EMERGENCY:
(800) 424-9300 (USA) CHEMICAL NAME AND SYNONYMS:
Sodium Tolyltriazole, 50% Water Solution TRADE NAMES AND SYNONYMS:
COBRATECO TT-50S CHIEMICAL FAMILY: Triazole FORMULA: C 7 H 6 N 3 Na SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS Material Sodium Tolyltriazole Water Sodium Hydroxide CAS No. 64665-57-2 7732-18-5 1310-73-2 49.5-5 .0 48.5-50.0
<0.5 Pikase t*quest a copy of Teahnicl flulletin
#: COR4333 for additional intlormation.
000.05 081699 01002 FKA PG 10/20/99 WED 15:11 FAX 513 482 7353 PFiA PFG Q]003 MATERIAL SAFETY DATA SHEET COBRATEC 9 TT-50S PRODUCT CODE: XI8W17440 Page 2 of 7 August 16, 1999 1,!_3_TjQN_.3 HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS: jOTirrrS OF ENTRY Eye contact, skin contact/absorption, ingestion and inhalation.
EYES Material is corrosive.
Contact with the eyes may severely damage delicate eye tissue. Material is corrosive.
Prolonged contact can be destructive to tissue. INGESTIN Material is corrosive.
Harmful if swallowed.
INHALATION Material is corrosive.
Harmful if inhaled.
CHRONIC EFFECTSICARCINOGENICITY CARCINOGENICITY:
None of the components in this material are listed by TARC, NTP, 0SHA, Or ACGIH as a carcinogen, 000306 10/20/99 WED 15:12 FAX 513 482 7353 MATERIAL SAFETY DATA SHEET COBRATECO TT-50S PRODUCT CODE: X18WT7440 Page 3 of 7 August 16, 1999 IFINHALED If affected, remove from exposure-Restore breathing.
Keep warm and quiet. GeO medical attention.
IF OX.iSK Wash affected area thoroughly with soap and water. Remove contaminated clothing, jewelry, etc. Get medical attention.
IF IN EYES Flush eyes with large amounts of water for 15 minutes. Get medical attention.
IF SWALLOWED Never give anything by mouth to an unconscious person- DO NOT INDUCE VOMITING.
Give large amounts of water- Get medical attention SECTION 5 FIRE FIGHTING MEASURES FLASH POINT: AUTOIGNITION TEMPERATURE:
FLAMMABLE LIMITS IN AIR: E XTXNGISHING MEDIA: Not Applicable Not Applicable Not Applicable Not Applicable SPECIAL FIRE FIGHTING PROCEDURES:
Full protective equipment including self contained breathing apparatus should be used. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent Get medical attention-Water may be used to cool and protect closed containers exposed to extreme heat. LUNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode (due to the build-up Of pressure) when exposed to extreme heat.000307 10004PG 10/20/99 WED 15:12 FAX 513 482 7353 MATERIAL SAFETY DATA SHEET COBRATECO TT-SOS PRODUCT CODES: X18W77440 Page 4 of 7 August 16, 1999 7SECTION 6 ACCIDENTAL RELEASE MEASURERS Use proper personal protective equipment.
Isolate and secure the area and follow the appropriate emergency guidelines.
Collect the material with inert absorbent and place in a covered waste disposal container.
STORAGE INFORMATION CORROSIVE MATERIAL Avoid contact with skin, eyes and clothing.
DO NOT TAKE INTERNALLY_
Clean up spills immediately.
Keep containers tightly closed when not in use. Store only in containers which are resistant to caustic solutions.
SEC TI CONTR_
PROTECTION NFPA BASED RATINGS: Health: 3, Flammability:
0, Reactivity:
0 H.MIS RATINGS: Health: 3, Flammability:
0, Reactivity:
0, PPE: F WHMS CLASSIFICATION; D-2-(B),E RESPIRATORY PROTECTION:
If personal exposure cannot be controlled below applicable exposure limits by ventilation, wear respiratory devices approved by NIOSH/MSHA for protection against mists and vapors VENTILATION:
Local exhaust is recommended.
PROTECTIVE GLOVES: Rubber, vinyl or other impervious material if skin contaci can not be avoided.
EYE PROTECTION:
Use safety glasses with unperforated side shields, or full face shield when danger of splashing is great. OTHER PROTECTIVE EQUIPMENT:
Rubber apron or similar protective clothing to prevent contact with skin or clothes.
EXP.Q5._RE GUIDELINICS Sodium Hydroxide TWA = 2 mg/m"1 000-308 FKA PG zoos 10/20/99 WED 15:12 FAX 513 482 7353 MATERIAL SAFETY DATA SHEET COBRATEC' TT-50S PRODUCT CODE: XISW77440 Page 5 of 7 August 16, 1999 SICTTON 9 PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: FREEZING POINT: SPECIFIC GRAVITY: BULK DENSITY: VAPOR PRESSURE AT 200 C: VAPOR DENSITY (air= 1): SOLUBILITY IN WATER % BY WT at 206 C: % VOLATILES BY VOLUME: EVAPORATION RATE: APPEARANCE AND ODOR: 100 0 C -80C 1.19 @ 24 0 C Not Applicable 0.04 mmn Hg Not Applicable Miscible in all proportions 50% as water Not Applicable Clear yellow to amber solution, characteristic odor, pH =13.5 STABILITY:
Stable INCOMPATIBILITY:
Strong Oxidizing Agents, Strong Acids. HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: Carbon Dioxide, Carbon Monoxide, Nitrogen oxides, HCN possible in reducing atmospheres.
HAZARDOUS POLYMERIZATION:
Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Oral l.D 5 0 (rat) Eye and Skin Irritant 920 mglkg (Male) 640 rug/kg (Fenale) Can cause severe irritation 000309 Q 006 PKA PG 10/20/99 WED 15:12 FAX 513 482 7353 MATERIAL SAFETY DATA SHEET COBRATEC' T1-50S PRODUCT CODE: X18WT7440 Page 6 of 7 August 16, 1999 SECTION 12 ECOLOGTCAL INFORMATION Bluegill Sunfish (96 hr. LC(o) Daphnia Magna (48 hr. LC,,) Rainbow Trout (96 hr. LCq)191.2 mg/I 245.7 mg/l 23.7 mg/l WASTE DISPOSAL METHOD: Dispose of in accordance with federal, state and local disposal regulations.
D.O.T. SHIPPING NAME: D.O.T. HAZARD CLASS: U.N. NUMBER: PACKAGING GROUP: PRODUCT RQ (LBS): D.O.T. LABEL: D.O.T. PLACARD: Caustic Alkali Liquids, no-s- (Sodium Hydroxide) 8 UNI719 PGIL 1,000 lbs as Sodium Hydroxide Corrosive Corrosive U.S. FEDERAL RF1GULATIONS:
Sodium Tolyhriazple (CAS No. 64665-57-21 is contained on The fol)o~wngchcmical lists: I TSCA Inveftory List 0001310 PKA FG Q907 10/20/99 WED 15:13 FAX 513 482 7353 PItA PG MATERIAL SAFETY DATA SHEET COBRATECO TT-$0S PRODUCT CODE: XISWT7440 Page 7 of 7 August 16, 1999 o008 SECION 15 REGULATORY INFORMATION (CONT.J Sodium Hydroxide (GAS NoQ 1310-73-2) is contained on the following chemiral lists: 1. Clean Water Act Section 311 Hazardous Substances (ref.: Suspect Chemicals Sourcebook 1997) 2. CERCLA HIazardous Substances (ref.: Suspect Chemicals Sourcebook 1997) 3. OSHA Air Contaminants (ref.: Suspect Chemicals Sourcebook 1997) 4. American Council of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value Chemicals (ref.: Suspect Chemicals Sourcebook 1997) 5. OSHA Table Z-1-A (revokedl (ref.: Suspect Chemicals Sourcebook 1997) 6. DOT Hazardous Materials (ref.: Suspect Chemicals Sourcebook 1997) 7. DOT Hazardous Substances Other Than Radionuclides; and Radionuclides (ref.: Suspect Chemicals Sourcebook 1997) 8. Massachusetts Substance List (ref.: Suspect Chemicals Sourcebook 1997) 9_ New Jersey Right To Know Hazardous Substance List (ref.: Suspect Chemica,'
Sourcebook 1997) NJIS -- Special Health Hazard (ref.: Suspect Chemicals Sourcebook 1997) 10. Pennsylvania Hazardous Substance List (ref.: Suspect Chemicals Sourcebook 1997) PAI E = Environmental Hazard INTERNATIONAL REGULATIONS:
SodiumTnlyltriazole (CAS No. 64665-57-2) is contained on the following chemical lists: 1. Canadian Domestic Substance List S odj.vmlvdroxide (CAS No. 1310-73-2) is con3ained on the following chemical lists: 1. Canadian Workplace Hazardous Materials Information System (W1-MIS) CN 1 = Ingredient must be disclosed at concentration of I % (ref.: Suspect Chemicals Sourcebook 1997) 2. Canadian Domestic Substance List SUC-_TiDN-16 16_DIRR INFO RMA.TION REASON FOR ISSUE: New format and verification of information.
MSDS NUMBER: XI8WT7440 PREPARED:
August 16, 1999 SUPERSEDES; March 3, 1998 Tie icf<m'rn~rio ct taitzd i.q k.au.d On [hr kl4iIa aivailable to us and is believed tts be correct as of the Li t- prrcpared; howrver. PMC SPECIALTII"S GROUP. INC. makes no warranty.
expressed or implied, regarding itc occur;,-y (Pf the-e tLdta or the re.sults to be cul[aiined frOtti Ohe Use Lhereof n nJ M-13 ill OJtm Oct. 20 1999 04:19PM P2 BRIGHT DYESTM MATERIAL SAFETY DATA SHEET FLT YELLOW/GREENTM LIQUID CONCENTRATE PAGE 1 OF 3 MSDS PREPARATION INFORMATION PREPARED BY: T. P. MULDOON (937) 773-0600 DATE PREPARED:
1/1/99 PRODUCT INFORMATION MAUNFACTURED BY: KINGSCOTE CHEMICALS 9676 NORTH LOONEY RD. PIQUA, OHIO 45356 CHEMICAL NAME NOT APPLICABLE CHEMICAL FORMULA ---------------------------------------
NOT APPLICABLE CHEMICAL FAMILY .......................................................
AQUEOUS DYE PRODUCR HAZARDOUS INGREDIENTS NONE PER 29 CFR 1910.1200 PHYSICAL DATA PHYSICAL STATE ..........................................................
LIQUfD ODOR AND APPEARANCE
.............................................
YELLOW/GREEN, WITH NO APPARENT ODOR SPECIFIC GRAVITY ........................................................
: i. i. VAPOR DENSITY (,rm Hg @ 25 0 C) ................................
-23.75 -rjeo VAPOR DENSITY (AIR =1) ...............................................
-0.6 --I 1,-- -?EVAPORATION RATE (Butyl Acetate = 1) ------------------------
-1.8 BOILING POINT .............................................................
100 degrees C (212 dogrets F) FREEZING POINT ..........................................................
0 degrees C (32 degrees F) pH ............................-.....................................................
8.0 OR ABOVE SOLUBILITY IN WATER. HIGHLY SOLUBLE SOLUBILITY IN WATER.. ...............................................
HI LYS L 1 E FIR *AZARD CONDITION OF FLAMMABILITY
................
NON-FLAMABLE MEANS OF EXTINCTION
---------------------
WATER FOG, CARBON DIOXIDE. OR DRY CHEMICAL FLASH POINT AND METHOD------------------NOT APPLICABLE UPPER FLAMABLE LIMIT ---------------------
OT APPLICABLE LOWER FLAMA8LE LIMIT NOT APPLCABLE LOWER FLAMABLE LIM~q" ..........................................
C TA P IA L AGTO-IGNITION TEMPERATURE
..................................
NOT APPLICABLE HAZARDOUS COMBUSTION PRODUCTS ----------
NOT APPLICABLE UNUSUAL FIRE HAZARD .......................................
NOT APPLICABLE 0001312 FROM : KINGSCOTE PHONE NO. :
Oct. 20 1999 04:19PM P3 BRIGHT DYESTM MATERIAL SAFETY DATA SHEET FLT YELLOW/GREENTM LIQUID CONCENTRATE PAGE 2 OF 3 EXPLOSION HAZARD SENSITIVITY TO STATIC DISCHARGE
..........................
NOT APPLICABLE SENSITIVITY TO MECHANICAL IMPACT .................-----
NOT APPLICABLE REACTIVITY DATA PRODUCT STABILITY
....................................................
STABLE PRODUCT INCOMPATIBILITY
-......................................
NONE KNOWN CONDITIONS OF REACTIVITY
...................
NOT APPLICABLE HAZAkDOUS DECOMPOSITION PRODUCTS ................
NONE KNOWN TOXICOLOGICAL PROPERTIES SYMPTOMS OF OVER EXPOSURE FOR EACH POTENTIAL ROUTE OF ENTRY: INHTIALLATION, ACUTE ..................................................
NO HARMFUL EFFECTS EXPECTED.
INHALATION, CHRONIC .................------
NO HARMFUL EFFECTS EXPECTED.
SKIN CONTACT ------------------------------
WILL TEMPORARILY GIVE SKIN A YELLOW/GREEN COLOR. EYE-CONTACT----------------NO HARMFUL EFFECTS EXPECTED EYE CONTACT ...............................................................
N A M U P E T X E T D INGESTION
..................................
URINE MAY BE A YELLOW/GREEN COLOR UNTIL THE DYE HAS BEEN WASHED THROUGH THE SYSTEM EFFECTS OF ACUTE EXPOSURE ....................................
NO HARMFUL EFFECTS EXPECTED EFFECTS OF CHRONIC EXPOSURE ----..........
NO HARMFUL EFFECTS EXPECTED THRESHOLD OF LIMIT VALUE ------------------
NOT APPLICABLE CARCINOGENICITY .NOT LISTED AS A KINOWN OR SUSPECTED CARCINOGEN BY IARC, NTP OR OSHA TERATOGENICITY NONE KNOWN TOXICOLOGY SYNERGISTIC PRODUCTS ...........
NONE KNOWN PREVENTATIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT GLOVES .....................................
RUBBER RESPIRATORY
................................
USE NISOH APPROVED DUST MASK IF DUSTY CONDITIONS EXIST. CLOTHINGG
.................................
PROTECTIVE CLOTHING SHOULD BE WORN WV ERE CONTACT IS UNAVOIDABLE.
OTH ---.................................
HAVE ACCESS TO EMERGENCV EYEWASH.000313 FROM : KINGSCOTE PHONE NO. :
FROM : KINGSCOTE PHONE NO. Oct. 20 1999 04:20PM P4 BRIGHT DYESTM MATERIAL SAFETY DATA SHEET FLAT YELLOW/GREENTm LIQUID CONCENTRATE PAGE 3 OF 3 " PREVENTATIVE MEASURES (CONT.) ENGINEERING CONTROLS ..................
NOT NECESSARY UNDER NORMAL CONDITIONS, USE LOCAL VENTILATION IF DUSTY CONDITIONS EXIST. SPILL OR LEAK RESPONSE ......................
CLEAN UP SPILLS IMMEDIATELY, PREVENT FROM ENTERING DRAIN. USE ABSORBANTS AND PLACE ALL SPILL MATERIALS IN WASTE DISPOSAL CONTAINER-FLUSH AFFECTED AREA WITH WATER. WASTE DISPOSAL----------------------------
INCINERATE OR REMOVE TO A SUITABLE SOLID WASTE DISPOSAL SITE, DISPOSE OF ALL WASTES IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
RANDELING PROCEDURES AND EQUIPMENT
..............
NO SPECIAL REQUIREMENTS.
STORAGE REQUIfEMENTS
-------------------------------------------
STORE AT ROOM TEMPERATURE BUT ABOVE THE FREEZING POINT OF WATER. SHIPPING INFORMATION E.......................KP FROM FREEZING FIRST AID MEASURES FIRST AID EMERGENGY PROCEDURES EYE CONTACT ...............................................................
FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT .-------------------------------------------------------------
WASH SKIN THOROUGHLY WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INHALATION
.................................................................
IF DUST IS INHALED, MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT GIVE OXYGEN AND GET IMMEDIATE MEDICAL ATTENTION.
INGESTION
.......................................................
DRINK PLENTY OF WATER AND INDUCE VOMITING.
GET MEPICAL ATTENTION IF LARGE QUANTITIES WERE INGESTED OR IF NAUSEA OCCURS. NEVER GIVE FLUIDS OR INDUCE VOMITING IF TIE PERSON IS UNCONSCIOUS OR HAS CONVULSIONS.
SPECIAL NOTICE ALL INFORMATION, RECOMMENDATIONS AND SUGGESTIONS APPEARING HEREIN CONCERNING THIS PRODUCT ARE BASED UPON DATA OBTAINED PROM MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES; HOWEVER, KINGSCOTE CHEMICALS MAKES NO WARRANTY, REPRESENTATION OR GUARANTEE AS TO THE ACCURACY, SUFFICIENCY OR COMPLETENESS OF THE MATERIAL SET FORTH HEREIN. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY AND SUITABILITY OF HIS OWN USE, HANDLING, AND DISPOSAL OF THE PRODUCT. ADDITIONAL PRODUCT LITERATURE MAY BE AVAILABLE UPON REQUEST. SINCE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE BY KINOSCOTE CHEMICALS AS TO THE EFFECTS OF SUCH USE, THE RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THE PRODUCT, NOR DOES KINGSCOTE CHEMICALS ASSUME ANY LIABILITY ARISING OUT OF USE BY OTHERS OF THE PRODUCT REFERRED TO HEREIN. THE DATA IN THE MSDS RELATES ONLY TO SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS END OF MATERIAL SAFETY DATA SHEET o00o: 4 APR 26 '95 03:02PM POLYPURE INC 2012925295 MATERIAL SAFETY DATA SHEET Clarifloc C-9490 Poiymer .3;Z1 j 05'POLYPURE INC.One Gatehall Drive Parsippany, New Jersey 07054 Phone Numbers (201) 292-2900 EMERGENCY CONTACTS:
CHEMTREC (800) 424.9300 Date Issued January25, 1995 Supersedes MSDS Dated July15. 1991 H M IS Health 1 Fire 2 Reactivity 0 I. Identification and Physical Data Product Name C-9490 Polymer Product Class Cationic Polyacrylamide DOT Hazard Class Combustible Liquid for bulk shipments only; see Sec. XIV 1D Number NA1993 Shipping Name Combustible Liquid, n.o.s., NA 1993, PG Ill. (Contains Petroleum Distillate)
Appearance and Odor White liquid emulsion with slight orga NFPA Health 1 Fire 2 Reactivity 0 Vapor Pressure at 200 C Not determined Vapor Density Heavier than air Volatile Org. Compounds Not determined
% Volatile By Volume 50-70% Boiling Range 100' Cand above Specific Gravity 1.0 (approximately)
Solubility In Water -10 % (forms gel) Evaporation Rate Not determined Melting Point Not applicable
.11. Hazardous Ingredients Chemical Name LigH Hydrtraels Petroleum Digtllaie Ethaozyiatea Branched -- Not EsLaLished s# TWA TLV for matemiala is about 100 3rm.=AS Number 64742-47-8 68412-54-" TWA TLV #8 OSHA PEt. STEL TLV Il1. Fire and Explosion Data LEL 0-9% (estimate)
Flashpoint
> 65 IC (Setaflash Closed Cup) Extinguishing Media Use carbon dioxide or dry chemical for small fires and fog or loam for large fires. Unusual Fire and Explosion Hazards When exposed to extreme heat, dosed containers may rupture due to buildup of pressure and release ignitable vapors- Water can cause extremely slippery floor surfaces.
Special Fire Fighting Procedures Wear self-contaied breathing apparatus and complete personal protective equipment when entering confined areas where there is potential for exposure to vapors or combustion products.
To me bew ol our KonMomi. the MiiuiflM0f corwainrd harem i Is accrae. Mowfeflr o wIhatsVoer is asnumea tor the or compmrom of un Irnn a Pm nainrarL.
FinaJ detwmrniral 0c1 ofntk oS maitarii is the sole rewondikty of Ins user. ANl maltais may r ordm unkr inIhi 1`1rs and should be uid wth cao. Aitiough eamdaesc nm d bed h/elin, we cannot gumante tttmaseare Bra onw a hazard 0 a= 900311 C P. 2/5 APR 26 '95 03:02PM POLYPURE INC 2012925295 IV. Reactivity Data Stable yes Hazardous Polymerization?
no Conditions To Avoid Avoid open flames, hot surfaces or other ignition sources.
Materials To Avoid Strong oxidizing agents Hazardous Decomposition Products Normally stable. Combus on products may include ammonia and oxides of carbon and nitrogen.
V. Health Hazard Data Effects of Overexposure Ingestion Contrns rmterials may be toxi. May cause irnmaton of V Contains materials rhat if aspirated te krigs dafng ingestion or vonring, may cause pulnonary injury and Possibly deavl. Inhalation Breathig vapomr mrst may imrte respiratory system and cause brearring diffullmS.
Efafcts on the central nervous system rrmy indude headaches, wekness, iz2inass arid Skin Absorption Product contfbs amonts of acryarTede.
Prolonged exposure to liquid or dned product may cause numbness. "inging or weeklees in extreis~s.
Skin Contact Contains matenais that may cause moderate skin Irritation.
Prolonged exposure may cause drying or defailing and at t skim Eye Contact Product contam matnrs wtich can cause severn eye intatlon.
Permanent damiage Is possible if corntact is prolonged.
Chronic Effects Breaftng vapors or mist may aggravate pre-existing syrnptois of asthrm or oilw lung disorders.
Repeated exposure to taeanixarits of arytdA __ in liquid or dried product may cause development Ot neurotoaxsological effects.
Emergency and First Aid Procedures Eye Contact ImmedWely flush wit Water for 15 minutes or loner. Lift upper ard lower eye lis to armu removal of chemicaL Get medicalun . Skin Contact Wash sian with soap and water. Renove and launder contaminated dothing before reuse. Get medical auenflon if Intln pees. Ingestion DO NOT INDUCE VOMmNG If vicdm Is conscious and alert, give 2 -3 glasses of water to drink GET IMMEDIATE MEDICAL ATTENTION.
Inhalation Move subjiecto ftsh air. Amnirster artficial respiratbi If requird. Get medical assisance.
CWMWO C4MPdelwVm 9igmema, 2 19W5 P. 3/5 PaW2914 APR 26 '95 03:02PM POLYPURE INC 2012925295 p /VI. Sp~ill Or Leak Procedures Steps to Be Taken In Case Material is Released or Spilled Vonratealsamand remove igoruci swoarc D~kn soli aM collIect for dispasa or reuse. Absorb residues withi nert mratetanal wicooilct*2r nfspowl Fkus area with wraisi. Prevent polyrner and wtstungs from entering surtace w~atem Wet polymer may cas very SliPPery contfton.
Waste Disposal Method incinerare or pinace in chewihai laMUhm inacnoraric v~t federal. Stae and local reqAaflon The rmaerial as Sold, is not a haza&#xfd;;u waste txilr axrea, RCRA ragulaftom.
VII. Special Protection Information Respiratory Protection Itffizstng condbons ext weow NIOS approved mist respumor.
Ventilation Nasiralor general vetl~latofliS 8dequ bformwralconrdzfinS Local venfariabo Is rooonmended to Contrw wiposioa from opewabons MWt can generate nerosolS.
M;M O Ct VepOs. Protective Gloves Neeprerw.
polywloy, buty! rubber or nmtre rubber gloves are recomnmeded.
Eye Protection Cherrical splasm goggles.
Other Protective Equipment For operabons wheare contact can occur coveralls, apron and rubber foot coverings am recorrmended.
A safety shower and eye w--h laotit shotl be available.
Vill. Special Precautions Spifs of proiluct or solutorI may ceime slippery floor surftacs.IX. State R-T-K Information Chemical Name UgMi lHyrotlumsd Petroleum Distluate EthoxylRed NOnyiphOWl, Brace cauonic Polynzcrflamld.
Nwor"ruc Sarifactarv; WSWe AcrylaMide PapS&4 StOre at temperatureS bet~wen 0 and 40*C. Keep container closed when not In use.CAS Number 64742-47-8 6841 2-5" 69418-2&4 1335-4" 7732-18-5 79-06-1 Comment , 0.1 1'Oi0 44 Pam,-O~ -- o FMjwwjiY 2&. 105 C 9OW-VI?P. 4/5 RPR 26 '95 03:03PM POLYPURE INC 2012925295 P. 5/5 X. SARA Title III Section 313 Information Not Applicable Xi. RCRA Information Not regulated as a hazardous waste. DispOSal Code Nonm XII. CERCLA Information Not Applcable XIII. California Proposition 65 Information Product contains detectable amounts of acrylamide (CAS# 79-06-1) which is known to the State of California to be a carinogen.
XIV. Other Information All components of this product are listed in the TSCA inventory.
Acrylamide is described as reasonably anticipated to be a carcinogen by the National Toxicology Program (NTP) and as a probable carcinogen by the Intermational Agency for Research on Cancer (IARC). The D.O.T. defines Combustible Liquid as a hazard class only for bulk packagings, i.e. when a single packaging has a minimum capacity greater than 450 L (119 gallons).Pa't 4 CWWU0 C-9"S 0M Man JmWy 25. 9M 900:48 (I Nalco Replix dominoFAX Server NALCO MATERIAL SAFETY DATA PRODUCT NALCO 9905 FLOCCULANT Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I-M-ALERT SECTION 01 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION TRADE NAME: NALCO 9905 FLOCCULANT DESCRIPTION:
Cationic polyacrylamide NFPA 704M/HMIS RATING: 1/1 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY 0 OTHER 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS Our hazard evaluation of the ingredient(s) under OSHA's Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous.
SECTION 03 HAZARD IDENTIFICATION EMERGENCY OVERVIEW:
CAUTION! May cause irritation to skin and eyes. Avoid contact with eyes. Avoid prolonged or repeated contact with skin; Avoid breathing dust. Do not take internally.
PRIMARY ROUTE(S) OF EXPOSURE:
Eye, Skin, Inhalation EYE CONTACT: May cause irritation with prolonged contact.
SKIN CONTACT: May cause irritation with prolonged contact.
INHALATION:
May cause slight irritation to the respiratory tract and lungs. SYMPTOMS OF EXPOSURE:
A review of available data does not identify any symptoms from exposure.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
SECTION 04 FIRST AID INFORMATION EYES: Flush with water for 15 minutes. Call a physician.
SKIN: Wash thoroughly with soap and rinse with water. Call a physician.
INGESTION:
Induce vomiting.
Give water. Call a physician.
INHALATION:
Remove to fresh air. Treat symptoms.
NOTE TO PHYSICIAN:
No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be PAGE 1 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER -NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000 0400 19 10/21/99 08:29:40 page 3 Nalco Replix dominoFAX Server NALCO MATERIAL SAFETY DATA PRODUCT NALCO 9905 FLOCCULANT 10/21/89 08:29:40 Page 4 Emengency Telephone Number Medical (800) 462-5378 (24 hours) (800) I-M-ALERT used to control symptoms and clinical condition.
CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 05 FIRE FIGHTING IMASURES FLASH POINT: Not applicable EXTINGUISHING MEDIA: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions.
SECTION 06 ACCIDENTAL RELEASE MEASURES IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (800) I-M-ALERT or (800) 462-5378.
SPILL CONTROL AND RECOVERY:
Solid spills: Sweep or vacuum up and reclaim into recovery or salvage drums for disposal.
Wear the protective equipment specified in Section I0. Refer to CERCLA in Section 15. NOTE: Solutions of product are extremely slippery. 
--------------------------
w------------------------------------------------------
SECTION 07 HANDLING AND STORAGE Storage : Keep container closed when not in use. SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION RESPIRATORY PROTECTION:
Respiratory protection not normally needed. If significant dusting occurs, wear a NIOSH approved or equivalent dust respirator.
For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a positive pressure, self-contained breathing apparatus is recommended.
VENTILATION:
If significant dusting occurs, local exhaust ventilation is recommended.
PROTECTIVE EQUIPMENT:
No special precautions.
Avoid eye and skin PAGE 2 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER -NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000 000320 Nalco Replix dominoFAX Server NALCO MATERIAL SAFETY DATA PRODUCT NALCO 9906 FLOCCULANT Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I-M-ALERT contact, and inhalation of dust. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. HUMAN EXPOSURE CHARACTERIZATION:
Based on Nalco's recommended product application and our recommended personal protective equipment, the potential human exposure is: MODERATE.
SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES COLOR: White FORM: Powder ODOR: Slight ammoniacal BULK DENSITY: 45.3 lbs/ft3 SOLUBILITY IN WATER: Completely pH (at 1%) = 3 -4 ASTM E-70 FLASH POINT: Not applicable NOTE: These physical properties are typical values for this product.
SECTION 10 STABLILITY AND REACTIVITY INCOMPATIBILITY:
Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS:
In the event of combustion CO, C02, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment.
SECTION 11 TOXICOLOGICAL INFORMATION TOXICITY STUDIES: Toxicity studies have been conducted on this product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS) : LD50 = Greater than 2 g/kg HUMAN HAZARD CHARACTERIZATION:
Based on our hazard characterization, the potential human hazard is: LOW SECTION 12 ECOLOGICAL INFORMATION BIOCHEMICAL OXYGEN DEMAND (5-day BOD): 5,000 mg/L PAGE 3 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000 "no -21 10/21/99 08:29:40 page 5 10/21/99 08:29:40 NALCO Nalco Replix dominoFAX Server Page 6 MATERIAL SAFETY DATA PRODUCT NALCO 9906 FLOCCULANT Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I-M-ALERT CHEMICAL OXYGEN DEMAND (COD): 225,000 mg/L If released into the environment, see CERCLA in Section 15. ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION:
Based on our Hazard Characterization, the potential environmental hazard is: HIGH. Based on Nalco's recommended product application and the product's characteristics, the potential environmental exposure is: LOW.  -------------------------------------------------------------------------------------
SECTION'13 DISPOSAL CONSIDERATIONS
-------------------------------------------------------------------------------------
DISPOSAL:
If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. As a non-hazardous solid waste, it can be disposed of in an industrial waste landfill in accordance with local, state, and federal regulations. 
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SECTION 14 TRANSPORTATION INFORMATION
-------------------------------------------------------------------------------------
PROPER SHIPPING NAME/HAZARD CLASS MAY VARY BY PACKAGING, PROPERTIES, AND MODE OF TRANSPORTATION.
TYPICAL PROPER SHIPPING NAMES FOR THIS PRODUCT ARE: ALL TRANSPORTATION MODES : PRODUCT IS NOT REGULATED DURING TRANSPORTATION
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SECTION 15 REGULATORY INFORMATION
-------------------------------------------------------------------------------------
The following regulations apply to this product.
FEDERAL REGULATIONS:
OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, none of the ingredients in this product are hazardous.
CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 PAGE 4 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER -NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000 000,32 Nalco Replix dominoFAX Server NALCO MATERIAL SAFETY DATA PRODUCT NALCO 9905 FLOCCULANT 10/21/99 08:29:40 Page 7 Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I-M-ALERT (TITLE III) -SECTIONS 302, 311, 312 AND 313: SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CPR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 and 312 -MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 -LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: Consult Section 13 for RCRA classification.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CER 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, Sec. Il (40 CFR 60), Sec. 112 (40 CFR 61, 1990 Amendments), Sec. 611 (40 CFR 82, CLASS I and II Ozone depleting substances):
This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: This product does not contain any chemicals which require warning under California Proposition
: 65. MICHIGAN CRITICAL MATERIALS:
This product does not contain ingredients listed on the Michigan Critical Materials Register.
PAGE 5 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER -NAPERVILLE, ILLINOIS 60563-1198 AREA (630)305-1000 000,3,,?3 Nalco Replix dominoFAX Server NALCO MATERIAL SAFETY DATA PRODUCT NALCO 9905 FLOCCULANT Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) I-M-ALERT STATE RIGHT TO KNOW LAWS: This product does not contain ingredients listed by State Right To Know Laws. INTERNATIONAL REGULATIONS:
This is not a WHMIS controlled product under The House of Commons of Canada Bill C-70.  ------ ------------------------------------------------
:------------------
SECTION 16 OTHER INFORMATION
----------------------------------------------------------------------------
None ------ ------------------------------------------------------------------
SECTION 17 RISK CHARACTERIZATION
----------------------------------------------------------------------------
Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices.
We have evaluated our product's risk as follows: "* The human risk is: LOW.  "* The environmental risk is: LOW. Any use inconsistent with Nalco's recommendations may affect our risk characterization.
Our sales representative will assist you to determine if your product application is consistent with our recommendations.
Together we can implement an appropriate risk management process.
This product material safety data sheet provides health and safety information.
The product is to be used in applications consistent with our product literature.
Individuals handling this product should be informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations.
Please consult your local sales representative for any further information. 
------ ------------------------------------------------------------------
SECTION 18 REFERENCES
----------------------------------------------------------------------------
Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH. Hazardous Substances Data Bank, National Library of Medicine, Bethesda, PAGE 6 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER -NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000 000-U24 10/21/99 08 :29 :40 Page 8 Nalco Replix dominoFAX Server NALCO MATERIAL SAFETY DATA PRODUCT NALCO 9906 FLOCCULANT Emergency Telephone Number Medical (800) 462-5378 (24 hours) (800) i-M-ALERT Maryland (CD-ROM version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (CD-ROM version), Micromedex, Inc., Englewood, CO. Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, Ohio (CD-ROM version), Micromedex, Inc., Englewood, CO. Shepard's Catalog of Teratogenic Agents (CD-ROM version), Micromedex, Inc., Englewood, CO. Suspect Chemicals Sourcebook (a guide to industrial chemicals covered under major regulatory and advisory programs), Roytech Publications (a Division of Ariel Corporation), Bethesda, MD. The Teratogen Information System, University of Washington, Seattle, Washington (CD-ROM version), Micromedex, Inc., Englewood, CO.PREPARED BY: William S. Utley, DATE CHANGED: 08/13/1998 PhD., DABT, Manager, Product Safety DATE PRINTED: 03/28/1999 PAGE 7 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER
* NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000 rtm) 5 10/21/89 08:29:40 page 9 Assigned to: ???? FOR INFORMATION ONLY Expires On:.4 w MATERIAL SAFETY BASF Corporation Chemicals Division 100 Cbrry Wit Moad. Pargipplay.
New Jernty 070b4, (2011 $f3IS00 DATA SHEET PRODUCT NUMBEFt 5B1770 241-7 Antifreeze Forimulation TR 241-7 Antifreeze FAv, -sti.o 1t00 ..t ,tie Contains.Ithylene Glycol 107-21-1 -95 50 PPM tei1n O-SHA PrOP11e1tary additives C5 Not established SARA Title 1:1 Sect. 2113: Listed. NE, ffilJIM SPECIFIC : GRAVITYt ORt~~ DUL DENSITY: 1.123 FLAMMABILTY LIMITS I IR (% BY VOL) LOWER: NAN/A EXTINGUISHING Use water fog, alcohol foam, C 02 or dry chemical MEDIUtM etinguishing media. NFPA: 1/1/0 SPEChIAL Firefighters should be equipped with self-contained FIREFIGHTING breathing apparatus and turnout gear. Avoid brathlng PROCEDURES vapor$0 of heated or rn:f z Vi....pe -a .-I .- M nttrFIRE AND EXPLOSION I r i" po flFs' May Trove, to a soUrve of ignition and f lash back..4 OHENMTRIEC 800--424-g30
,201-316-3000 BASF I 0001_11;46 Assigned to: ????FOR INFORMATION ONLY Exp~ires On: ' I Assigned to: 7??? FOR INFORMATION ONLY Expires On: W? c2o(Y ftnartl St.? tIE EMOCO. --0.8 *4 ISana Sam, U t. OOUJ ''' '' -S -'* TOXICOLOGICAL TEST DATA: RESULT: 24 1-7 Ant If reeze Pornal at ion ethylene Glycol Rat. Oral 1.050 5.5 glkg. Htawn, Reported Lethal Dose 100 cs.c Silicates eye anet skin irritant borates Moderately toxic by ingst ion EFFECTS OP OVEREKPOSURE Contact with this product causes eye end skin irritation.
Inhalation of vapors or mists may be irritating to the respiratory tract. IWngeton of about 100 ml. of ethylene glycol may result in saute poisoning, which is characterized by severe abdominal disturbances.
central nerymias system depression and possible respiratory or renal failure.
Prolonged Inhalation of the vapors may cause unconsciou~sness an increased lymlphocyte counts. Chronic over-exposure may lead to liver, degeneration and severe renal damage. Animal studies indicate that ethylene glycol may be emtryotoxic and tearatogenic by the oral and Inhalation routes. FIRST AID PROCEDURES: "Ee-Imudi ately wash eyes Wi th runn Ing water f or 15 mi nut*$. If Irritation develops, consult a physician.
Skin-Wash effected areas with soap and water. Remove and launder, contaminated clothing before reuse. If Irritation develops.
consult a physician.
tIngestion-If swallowed, dilute with water and immediately induce vomilting.
Never give fluids or induce vomiting If the victim Is unconscious or having convulsions.
Get Iug. edlat medicel *attention.
Inhalation-move to fresh air. Aid in breathing, If necessary.
and got Ivmnediate medical attention.
CORRITONSIV TO MEA:ID N/OIDZR.A RESPIRATORY PRCOTECSTION POUTS / EYEZPRDOTECTION:
EIf O splahin cno occur, s hmclgglso ulfc POROTECIVE CLOMTHING Use rubberER glvsNponaosos ETIAIOf oa xautt oto vapors or mists.aegnrtd eraNOHMK apTrEve oraiN/prmitrsprtr EYE ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~~ u PRTCIN Ifr spahn.a cuueceia oge r ulfc DP;'3 B/87 000327 FOR INFORMATION ONLY Expires On: X??Assioned to: ????rRA3c z vrl 44 Asneto???FOR INFORMATION ONLY Ex-ires On: C1 ehI./ q!Aquatic toxicity ratIrV: T1006 1000-100 ppm.SPILL AND LEAK PROCEDURES:
Spills should be contained, solidified, eInd placed In suitable contailnes for disposal.
This aaterPil is not regulated under RCRA or CEROLA (S'uperfund,).
Clean up quickly as spills are a slippinIg hazard. HAZARDOUS SUBSTANCE SUPERFUND.
No RO (Ibs). WASTE DISPOSAL METHOD:.
Incinerate or bury in a licensed facility.
Do not discharge into waterways.
Discharge to seoer systems with prior approvals is acceptable.
HAZARDOUS WASTE 40CFR261:
NO HAZARDOUS WASTE NUMBER CONTAINER DISPOSAL Dispose of In licensed facility.
Recoimend crrushinr or other means to prevent unauthorized reuse. D.O.T. PROPER HIPPING NAME R49C FR172.101-102)
HAZARDOUS SUBSTANCE EUE(49CFR CERCLA LIST) None NO REPORTABLE QUANTITY (RQ) Nor* D.O.T. HAZARD CLASSIFICATION 4CFR172.101-102)
PRIMARY SECONDARY None N/A D.O.T. LABELS 49CFRI72.101-102)
D.O.T PLACARDS IPOISON CONSTITUENT REQUJIRED (CFR172.504)
(49CFR172.203{K)
NoeNone N/A BILL OF LADING DESFCRIPTION Ant ifreze reparations, Proprietary (Ethylene Glycol Base) CC NO. ".32 UN/NA CODENone DATE PREPARED&#xfd; 2 / 5 / 85 UPDATED: 2 / 24 / 59 WHILE BASF CORPORATION BELIEVES THE DATA SET FORTH HEREIN ARE ACCURATE AS OF THE DATE HEREOF, BASF CORPORATION MAKES NO WARRANTY WITH RESPECT THEREIO AND EXPRESSLY DISCLAIMS ALL LIABLITY FOR RELIANCE THEREON.
SUCH DATA ARE OFFERED SOLELY FOR YOUR CONSIDERATION.INVESTIGATION.
AND VERIFICATION.
"00O03Z8 Assianed to: ????FOR INFORMATION ONLYt"J n *--? BII Assigned to: ???? FOR INFORMATION ONLY Expires On: \?? PRODUCT NUMBER: 581770 241-7 AntIfreeze Foraulation 241-7 Antifreeze Formulation WARNING: CONTAINS ETHYLENE GLYCOL (CAS No.: 107-21-1).
CONTACT MAY CAUSE TEMPORARY EYE AND SKIN IRRITATION.
INGESTION NAY RESULT IN ACUTE POISONING.
CHARACTERIZED BY SEVERE ABDOMINAL DISTURBANCES.
CENTRAL NERVOUS SYSTEM DEPRESSION AND POSSIBLE RESPIRATORY OR RENAL FAILURE. PROLONGED INHALATION OF VAPORS NAY RESULT IN IRRITATION OR NCOONSCIOUSNESS.
CHRONIC OVEREXPOSURE MAY LEAD TO LIVER AND KIDNEY DAMAGE. ETHYLENE GLYCOL WAS TERATOGENIC IN LABORATORY ANIMAL STUDIES.
FIRST AID. tyes-Ius.ediately wash eyes with running water for 1 mitnuteS.
If irritation develops, consult a physician.
Skin-Wash affected areas with soap and water. Remove mnd launder cbntaminated clothing befor* rouse. If irritation develops, consult a physician.
Ingestion-If swallowed, dilute with water and immieiatoly induce vomiting.
Never give fluids or induce vomiting if the victim Is unconscious or having convulsions.
Get Immediate medical attention.
Inhalation-Novo to fresh *ir. Aid In breathing, It necessary.
and get Immediate medical attention.
I4NDLING AND STORAGE: Keep containers closed. In case of spill, clean up quickly as product Is slippery.
Wash away small amounts With cool water. Absorb large amounts with absorbent mterial or dike.and pump Into drums for proper disposal.
Incinerate or bury In an approved landfill under guidanOe of local EPA. Prevent run-off onto p4ublic lend or into waterways.
IN CASE OF FIRE: Use water fog, alcohol foam, CO2 or dry chemical extinguishing media. Firefighters should be equipped with *l0f-contmined apparatus and turnout gear. Vapors from heated product can travel to source of Ignition and flash back. Moderate explosion hazard when exposed to flame. EMPTY CONTAINERS:
All labeled precautIon$
must be observed When handling.
storing and transporting etpty containers due to product residues.
Do not reuse this container unless it is professionally cleaned and reconditioned.
DISPOSAL:
Spill material.
unused contents and empty containers must be disposed of In accordance with local, state and federal regulations.
Refer to our Material Safety Data Sheet for specific disposal instructions.
IN CASE OF CHEMICAL EMERGENCY:
Coll CHIETREC day or night for assistance and Information concerning spilled material, fire, exposure and other chemical accidents.
OO-424- 9300. ATTENTION:
This product Is sold solely for use by industrial institutions.
Refer to our Technical Bulletin and Material Safety Data Sheet regarding safety, usage, applications, hazards, procedures and disposal of this product.
Consult your. supervisor for additional information.
CAS No.: 107-21-1.
Made in U.S.A. Industrial and Performance Chemicals 0289PAGE 4 OF 4 PAGE 4 OF 4 VM1105 O/V Assigned to: ???FOR INFORMATION ONLY Expires On: (qgp Manufactursr ProChem Inc. 526 Roosevelt Rd. Rockford, IL 61109 Phone: (815)39a-1785 Fax: (B15)398-lI11
-IDENTIFICATICr Product Name: 4ron (I 1) Oxalate Formula: Fe2(C204)3 45H20 Chamical Nature: Salt X Activity:
100 Revision Date: 1/9/-PG"PHYSICAL DATA Boiling Point: Melting Point: Specific Gravity: Vapor Pressure at 20-C: Vapor Densitu (Air-- 1): Solubility in H20: Percent Volatiles by Weight: Ionic Nature: Appearance and Odor.Not Applicable Decomposes&
100oC No Date No Date No Date Soluble In hot water Not Applicable Yes Light green Powder, Odorless HAZARDOUS INGREDIENTS Material Iron (111) Oxelate CASw 146g-07-9 z too.*TLV/PEL Not Established
'JOO;IdU Ote: G66 &#xfd;:r&#xfd; Assigned to: ???? FOR INFORMATION ONLY Expires On: \?? FIRE AND EXPLOSION HAZARD DATA Flash Point. Not Established Autoignitlon TemperatUret No Date Flammable Limits In Air, 2 bg Volume: Low-sr No Date Upper No Data Extinguishing Media: Use water, carbon dioxide, dry chemical extinguishing agents, dryeand, or drg ground dolomite.
Special Fire Figh~tg Procedures:
Wear NIOS H/MSHA approved self contalned breathing apparatus, flame and chemical resistant clothing; hats, boots, and gloves. If without risk remove material from fIrs area. Unusual Fire and Explosion Hazards: Combustible when exposed to prolonged heat or flame. Heating to decomposition emits toxic fumes. HEALTH HAZARD DATA Threshold Limit Value: Not Established Effects of Overexposure:
Corrosive viW inhalation and ingestion, has a caustic effect on the mouth, esophagus, and stomach.
May cause sever damage to kidneys. An Irritant to akin, egos, and mucous membranes.
Emergency and First Aid Procedures:
Remoye from exposure.
Egos: Flush with copious amounts of water for at least 15 minutes, Skin: Remove any contaminated clothing.
Flood skin with large volumes of water for 15 minutes. Ingsstion/Inhalation:
Seek prompt, competent medical attention.
REACTIVITY DATA Stability:
Stable Conditions to Avoid: Heating to decomposition Incompatabilitg:
Furfuryl alcohol, silver, sodium chlorite, sodium hgpochlorits L6. 90 000,331 Assigned to: ???? FOR INFORMATION ONLY Expires On: ? Hazardous Decomposition Products:
When heated to decompositi emits toxic fumes. Hazardous PolUmsrizaeton:
Will- not occur Conditions to Avoid: Not Applicable SPILL OR LEAK PROCEDURES Steps to be takenif materiel Is Spilled or Released:
Wearling full protective clothing and respiratory protection, % eliminate all sources of Ignition.
Cover spill with dry send or dry Vflrmlcullte,.
mix well and carefully transfer to a well-marked container.
Close container tightly. Submit or retain for disposal.
Waste Disposal Method: Consult state, local, and federal regulations for proper disposal.
SPECIAL PROTECTION INFORMATION Respiratory Protection:
NIOSH/MSHA approved high efficiency particulate respirator for ordinary use and self-contained breathing apparatus for emergency use. Ventilation-Local exhaust: Fume hood Mechanical:
Not adequate Special: Not required Other. Not required Protective Gloves- Rubber Eye Protection:
Full face shield and chemical safety goggles Other Protective Equipment:
Lab coat and apron, flame and chemical resistant coveralls, eewash capable of sustained flushing, safety drench shower and hygienic faci Iiti s for washing.00033; FOR INFORMATION ONLY S..........'
TRANSPORTATION INFORMATION-U.S.
D.D.T.Per 49CFR 172. 101 Proper Shipping Name: Not regulated Hazard Classification:
None UN -0: None Employers should rae this. information only as a supplement to other Information gathered b .them, and should make Independent Judgement of suitability of this Information to ensure proper use and protect the health end safe ty of employees.
This information ts furnished Without warranty, and any use of the product not in conformance with this Material Saf ety Date Sheet, or in combination with ang other product or process, Is the responsibilitU of the user..,1 T 06C 5;Assigned to: ????Expires On: X?? LA. 4/0 C L&#xfd;j ON I ?12P:)Q.1id Se'&#xfd; I L.-6. 90 "Dly Assigned to: ???? FOR INFORMATION ONLY -^-Betz earborn 3-2 130 Expires On: '-?BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 20-APR-1998 PRINTED DATE: 29-APR-1998
: 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: POLYFLOC CP1 160 PRODUCT APPLICATION AREA: FLOCCULANT.
COMPANY ADDRESS: BetzDearborn Inc., Water Management Group 200 Witmer Road, Horsham PA 19044 Information phone number (21 5) -773-6131 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
This product is subject to the Pennsylvania and New Jersey Worker and Community Right to Know Law. HAZARDOUS INGREDIENTS:
This product is not hazardous as defined by OSHA regulations.
No component is considered to be a carcinogen by the National Toxicology Program, the International Aqgency for Research on Cancer, or the ' Occupational Safety and Health Administration at Pennsylvania thresholds for carcinogens.
PAGE 1 CON 8N CONTINUED FOR INFORMATION ONLY 2-. /,30 PRODUCT NAME: POLYFLOC CP1 160 EFFECTIVE DATE: 20-APR-1998 NON-HAZARDOUS INGREDIENTS:
CAS#CHEMICAL NAME 7732-18-5 69418-26-4 PAGE 2 o WATER. ETHANAMI{NIUM,N,N,N-TRIMETHYL
[(1-OXO-2 PROPMUL)OXY]
-CHLORIDE, POLYMER WITH 2- PROPENAMIDE CONTINUED 000.335 Expires On: W??Assigned to: ????
Assigned to: "7 FOR INFORMATION ONLY Expires On: PRODUCT NAME: POLYFLOC CP1 160 EFFECTIVE DATE: 20-APR-1998
-3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION May cause slight irritation to the skin. Potential eye irritant due to mechanical action only. Dusts may cause irritation to the upper respiratory tract. DOT hazard is not applicable Emergency Response Guide Is not applicable Odor: None; Appearance:
White, Powder Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight irritation to the skin. ACUTE EYE EFFECTS: Potential eye irritant due to mechanical action only. ACUTE RESPIRATORY EFFECTS: Dusts may cause irritation to the upper respiratory tract. INGESTION EFFECTS: May cause slight gastrointestinal irritation.
TARGET ORGANS: No evidence of potential chronic effects, MEDICAL CONDMONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin. PAGE 3 CONTINUED 000t3G3--
Assigned to: ????FOR INFORMATION ONLY Expires On: \?? 'Vi )PRODUCT NAME : POLYFLOC CP1.160 EFFECTIVE DATE: 20-APR-1998
: 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to'an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 20OF > 93C P-M(CC) 6) ACCIDENTAL RELEASE MEASURES PROTECTION ANDSPILL CONTAINMENT:
Ventilate area: Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water, Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill.7) HANDLING AND STORAGE 'HANDLING:
Normal chemical handling.
STORAGE: Keep containers closed when not in use. Keep dry.PAGE 4 I CONTINUED 0003-37 Assigned to: ???? FOR INFORMATION ONLY Expires On: ? PRODUCT NAME: POLYFLOC CP1 160 EFFECTIVE DATE: 20-APR-1998
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS This product is not hazardous as defined by OSHA regulations.
ENGINEERING CONTROLS:
Adequate ventilation to maintain dust concentrations below the exposure limit of 10 mg/m3(PEL/TLV) for nuisance dusts. PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
rubber gloves- Wash off after each use. Replace as necessary.
EYE PROTECTION:
airtight chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Density 43.200 lb/cu. Vapor Pressure (mHEG) < 0.1 Freeze Point (F) NA Vapor Density (air-I) < 1.00 Freeze Point (C) NA Viscosity(cps 70Fo21C) NA % Solubility (water) -2.0 Odor None Appearance 4hlite Physical State Powder Flash Point P-M(CC) > 200F > 93C pH 0.5% Sol. (approx.)
 
===4.2 Evaporation===
 
Rate (Ether-i)
< 1.00 NA = not applicable ND = not determined PAGE 5 CONTINUED 000338-Assigned to: ????Expires On: \??FOR INFORMATION ONLY -A/3.7 PRODUCT NAME: POLYFLOC CP1 160 EFFECTIVE DATE: 20-APR-1998
: 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires),yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
'A "l 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: Carcinogenicity DOG: NOTE -One year dog study had Carcinogenicity RAT: NOTE -Two year rat study had Dermal LD50 RABBIT: NOTE,- Non-toxic even at high Eye Irritation Score RABBIT: NOTE -Mechanical irritation Skin Sensitization G.PIG:>5,000 mg/kg NEGATIVE no adverse effects.
NEGATIVE no adverse effects. 
>2,000 mg/kg dose levels NEGATIVE 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Renewal Bioassay LC50: 5.9 mg/L No Effect Level: 2.3 mg/L Daphnia magna 48 Hour Static Renewal Bioassay LC50: 158 mg/L No Effect Level: 15 mg/L BIODEGRADATION COD (mg/gm): TOC (mg/gm): BOD-5 (mg/gm): BOD-28 (mg/gm): 1100 369 122 165 PAGE 6.,-6 7 CONTINUED 000,31319 FOR INFORMATION ONLY ~, /~I Expires On: "? 4 ,t&#xfd;PRODUCT NAME : POLYFLOC CP1 160 EFFECTIVE DATE: 20-APR-1998
: 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is: Not applicable.
Please be advised; however, that state and local requirements for waste.disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material. 
: 14) TRANSPORT INFORMATION
-DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT-EMERGENCY RESPONSE GUIDE #: Not applicable
: 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS: Product is non-hazardous under Section 311/312 SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA-thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present-at OSHA thresholds PAGE 7 p.CONTINUED 00034 Assigned to: ????
Assigned to: ????FOR INFORMATION ONLY Expires On: \?PRODUCT NAME : POLYFLOC CP1160 EFFECTIVE DATE: 20-APR-1998
: 16) OTHER INFORMATION NFPA/IHMIS Health Fire Reactivity Special (1) Protective Equipment CODE TRANSLATION I Slight Hazard 1 Slight Hazard 0 Minimal Hazard NONE No special Hazard B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE MSDS status: REVISIONS TO SECTION: 11-FEB-1998 20-APR-1998
;EDIT:9 SUPERCEDES
** NEW ** 11-FEB- 1998 PAGE 8 q 000341 Assigned to: ???? FOR INFORMATION ONLY V BetzDearborn BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DAT-E;-1 6aMAR-1998 PRINTED DATEI:= 29-APR-1998
-Expires On:'-?b211131 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: POLYFLOC API 100 PRODUCT APPLICATION AREA: FLOCCULANT.
COMPANY ADDRESS: BetzDearborn Inc., Water Management Group 200 Witmer Road, Horsham PA 19044 Information phone number (215) -773-6131 EMERGENCY TELEPHONE (HEALTH/ACCIDENT):
(800)-877-1940 (USA) 2) COMPOSITION
/ INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
This product is subject to the Pennsylvania and New Jersey Worker and Community Right to Know Law. HAZARDOUS INGREDIENTS.
This product is not hazardous as defined by OSHA regulations.
No component is considered to be a carcinogen by the National Toxicology ProgramI the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at Pennsylvania thresholds for carcinogens.
PAGE 141j CONTINUED 000341 FOR INFORMATION ONLY PRODUCT NAME: POLYFLOC APl 100 EFFECTIVE DATE: 16-MAR-1998 NON-HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NIAME 7732-18-5 25085-02-3 PAGE 2 o6,'WATER ACRYLAMEDE/SODIUM ACRYLATE COPOLYMER CONTINUED 000343 Expires On: X??Assigned to: ????
Assigned to: ???? FOR INFORMATION ONLY Expires On: PRODUCT NAME: POLYFLOC AP1 100 EFFECTIVE DATE: 16-MAR-1998
: 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION May cause slight irritation to the skin. May cause moderate irritation to the eyes. Dusts may cause irritation to the upper respiratory tract. DOT hazard is not applicable Emergency Response Guide is not applicable Odor: None; Appearance:
White, Powder Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical/C02/foam or water--Slippery condition; use sand/grit.
POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight'irritation to the skin. ACUTE EYE EFFECTS: May cause moderate irritation to the eyes. ACUTE RESPIRATORY EFFECTS: Dusts may cause irritation to the upper respiratory tract. INGESTION EFFECTS: May cause slight gastrointestinal irritation with possible nausea,
* vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS: -No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known. SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin. PAGE"3O -CONTINUED 000344 Assigned to: ???? FOR INFORMATION ONLY Expires On: \?? PRODUCT NAME : POLYFLOC API100 EFFECTIVE DATE: 16-MAR-1998
: 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing.
Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting.
Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical/C02/foam or water--Slippery condition; use sand/grit.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F > 93C P-M(CC) 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment.
Contain and absorb on absorbent material.
Place in waste disposal container.
Flush area with water. Wet area may be slippery.
Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -Incinerate or land dispose in an approved landfill. 
: 7) HANDLING AND STORAGE HANDLING:
Normal chemical handling.
STORAGE: Keep containers closed when not in use. Reasonable and safe chemical storage. Keep dry. PAGE 4 CONTINUED 000345 FOR INFORMATION ONLY ijo /._Expires On: ? "y f'PRODUCT NAME : POLYFLOC AP1100 EFFECTIVE DATE: 16-MAR-1998
: 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS This product is not hazardous as defined by OSHA regulations.
ENGINEERING CONTROLS:.
adequate ventilation PERSONAL-PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE.EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
airtight chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Density Freeze Point (F) Freeze Point (C) Viscosity(cps 70F,21C)42.000 lb/cu. NA NA NA Vapor Pressure (mmHG) Vapor Density (air-i) % Solubility
(,meter)< 1.0 < 1.00 1.0 Odor Appearance Physical State Flash Point P-M(CC) pH 5% Sol. (approx.)
Evaporation Rate (Ether-i)NA = not applicable ND = not determined PAGE 5 oIf CONTINUED 00034G -None White Powder > 200F 7.0 < 1.00> 93C Assigned to: ????
FOR INFORMATION ONLY PRODUCT NAME: POLYFLOC AP1 100 EFFECTIVE DATE: 16-MAR-1 998 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur. INCOMPATIBILITIES:
May react with strong oxidizers, DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: "A" 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: >5,000 mg/kg 28 Day Oral RAT/DOG: NEGATIVE NOTE -Rat tun-year feed: no adverse.effects.
Dog one-year feed: no adverse effects.
Dermal LD50 RABBIT: >2,000 mg/kg NOTE -Non-toxic at high dose levels Skin Irritation Score RABBIT: NEGATIVE Eye Irritation Score RABBIT: SLIGHT Skin Sensitization G.PIG: NEGATIVE PAGE CONTINUED 000347 Expires On:\7 Assigned to: ????
Assigned to: ???? FOR INFORMATION ONLY Expires On: PRODUCT NAME: POLYFLOC API 100 EFFECTIVE DATE: 16-MAR-1998
: 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 72 Hour Static Screen 0% Mortality:
100 mg/L Daphnia magna 48 Hour Static Screen No mortality was observed in highest concentration tested. 0% Mortality:
500 mg/L Bluegill Sunfish 96 Hour Static Screen 0% Mortality:
300 mg/L Fathead Minnow 96 Hour Static Screen No mortality was observed in highest concentration tested. 0% Mortality:
500 mg/L Ceriodaphnia 48 Hour Static Acute Bioassay LC50: 5 mg/L No Effect Level: 1.6 mg/L BIODEGRADATION.
COD (mg/gm): 2970 TOC (mg/gm): 680 BOD-5 (mg/gm): 1 BOD-28 (mg/gm): 22 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations.
Consult state and local regulations regarding the proper disposal of this material. 
: 14) TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable PAGE 7 6 CONTINUED Assigned to: ????Expires On: \??FOR INFORMATION ONLY 3;&#xfd; 131/PRODUCT NAME: POLYFLOC APl 100 EFFECTIVE DATE: 16-MAR-1998
: 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent present at OSHA thresholds USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS: SEC.G6,L1 SARA SECTION 312 HAZARD CLASS: Product.is non-hazardous under Section 3111312 SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION.
: 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds
: 16) OTHER INFORMATION NFPA/HMIS Health 1 Fire 1 Reactivity 0 Special NONE (1) Protective Equipment B (1) refer to section 8 of MSDS for recommendations.
CODE TRANSLATION Slight Hazard Slight Hazard Minimal Hazard No special Hazard Goggles,Gloves additional protective equipment CHANGE LOG EFFECTIVE DATE MSDS status: 16-MAR-1998 REVISIONS TO SECTION: SUPERCEDES
** NEW **-PAGE 8 9f Assigned to: ???? FOR INFORMATION ONLY Exnires On: From : WJARREN Dl ST.PHONE No. :40895306 Post-it, FAX Not -7671 Dst/;7 *-.&#xfd;1 P aII Phone a Apr.25 1995 ?:7404M P01 727 South 13th Street Omaha, Nebraska 68102 800-432-9306 FAX 402-341-8654 MATERIAL SAFETY DATA SHEET IDnNT=Il (As used on label and list): SKIN CONTACM: No cij SIMIIRA AN1TFRrZMCOOLANT are expected under andelpai PRODUCT CODE: SIOIAFGP NFPA Hzr bp-ification Saft Brands C.rporation 2849 River Road CouncilBhuffs, IA 51501 Emergency (402) 341-9397 Information (800) 432-9306 Clentre (800) 424-9300 Reisod: 08-18-94~Seio H C n/inoo >2 COMPOENT NAME % PELUMIST PEL VAPOR Sadium NltraI. ' ine" esia i CAS 1344-Y)0 NOm-IAZARDOUS DpI .Gg.eET> I *A 94 57-Si-G 3 (Does not contain IARC, N'P, OSHA and ACGIH lim cacinogons greater than 0.1%) EYE CONTACT. May cause jin"o eye irri-taon.
;nifieamr adverme efrects ted conditions of normal u68. Repoated proloned exposr may cause slight flking, tenderness, and coftenin 8 of A'in. IDH]ALATION:
No significant adverse effectc are expected under anticipated condiionc of normal use. feffects do occar. refer to FIRST AID section.  "YNGEMlON;:
No significant affects are expected under anticipated oonditionar ofnosmal use. Ex~castvt ingestion may cause central nevous "yem efiectF.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
as above MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Material and/or its crassion may aggmavate preIxisting eye discase.
OTHER HEALTH WNFORMATION:
none EYE CONTACr: Immediately rinse with clean water for 20-30 minutes. Retrcti eyelids olfen. Obtain medical attention if pain. blinking, lears or redness pers.is, SKIN CONTACT. Product is not expected to pru'csnt a sig-idlcaut skin harard under anticipated conditions of normal uso. TNHALATION:
If overcome by exposure, removo to fresh air immediately.
Give oxygen or artificial respiration as needed. ObWin emergecy medical attention.
Prompt action Is essefnial.
INGESTION-:
If large quantity is swallowed, give a pint of lukewaim water if victim iF completely conscious and alert. If large quantities am consunwd minduc vomiting.
Obsin emergency medical attention.
I S894-63b 000310 Health: 0 ]Fire: I Reactivity:
0 o -Least I -Slight 2 -Moderate 3 -]ah 4 -Extrmec V..pytlass OtyuuiJ walt , I'Mdadwry Additivn 17- ......- ...Assigned to: ????FOR INFORMATION ONLY Expires On:'-"~-4 Assianed to: ???? FOR INFORIVATION ONLYExisOn
?From : UARREN DIST.PHONE No. : 4022895306 Apr.25 1995 7:41AM P02 ?c .2-&#xfd;'CARCINOGENICITY:
n/a Plasi Point (deg ); 211 Flmanmablu or E~xplosive Lmilss (appioxiinale
% by volume in air) LEL" 2.4 WEL: 17.4 EXrTIN(UISHIHN MDIA: calbon dry chemical, alcohol type foam, IscT spray, water fog SPECIAL FrE HGHIUlNG PROCEDUIREB:
Wear poritive pressure, self contained breathing apparta amd other protective apparatus as warranted.
Fight fire from dittance or protected location -heat may build up presure and rupture doted containers.
Liquid may form slippery film. Use water spray or fog for cooling, solid stream may spread firo as burning liquid will float on water. Avoid frothing/steam explosion.
Notify authoritics if liquid enters sewers/public waters. UNUSUAL FIRE AND EXPLOSION HAZARDS: Heat from fire cangenerate flanmmable vapor. When rnixed with air and axposed to ignition sourcoe vapors can bum in open or explode if confined.
Vapors may be heavier than air and travel long distanoes along ground bcforc igniting and flashng back. Pine sprays and mists may be combustible at temperatures below normal ni-slh point. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Prevent flow to sewers and public waters as it muy contaminate said water. Restrict water usage to pr-vent slip/fall hazard. Suak up small pills with ineit solids. Dike and recover large land spills. Notify appropriate audiorides if product enters any waterway.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE,:
Storo in lightly closed and properly vented containerg, away from beat, sparks, open flame, and strong oxidizing agents.RESPIRATORY PROThCTION:
No special protectdon equipment is recommended under normal conditions of anticipated use with adequato vcniation.
VENTILATION:
Adequate general ventilation is required, local exhaust is recommended if possible.
P1T7O CTnVR GLOVES: not required EYW PROTECTION:
Chemical splash goggleu or full face shield musnt be worn when posibility far cyo coact due to splahhing or Vpraying liquid, airborne particles, or vapor. Contact uIonsa should not be worn OTHER PROTECTIVE EQUIPMENT:
none WORK FRACTICES/&NGINEERNG CONTROLS:
Keep containers closed when not in ulse. PERSONAL HYGIENE: If product handling results in *in conact, wash hands and othcr.exposed ares with mild soap and water before eating. drnking.
smoking, or using toilet facilities.
Promptly Tcmovo soiled clothing and wash thoroughly before reuse. Boiaing Point (deg F): 365 Specific Gravity (II20-1):
1.04 Vapog Pcas*ac (Imu HS); <0.1 Melting Point (deg F): -76 Vapor Density (Air--I) 2.6 Solubiity in Water :complete Evaporation Rate (n-butyl Acet-te1):
slight APPEARALCE AND ODOR: da-k gram. slightly viscous almost odorless liquid STABILITY:
stable CONDITIONS TO AVOID: Icat, sparks, open flnme INCOMPATMILITY (MATERIALS TO AVOID). strong alkalis, stmung oxidizing agent HAZARDOUS DECOMPOSmON OR BYPRODUCTS:
caibon monoxide and othcr toxic vapors HAZARDOUS POLYMV RIZATION:
not e'peVcd to ocu 2 00013151 Expires On: 1??Assianed to: ????FOR INFORMATION ONLY Assigned to: 7??? FOR INFORMATION ONLYExreOn?
From : IJPRREN DIST. PHONE No. 4022695306 Apr. 25 1.99 7:41A~M P03 COMMITONS TO AVOID:, n/ Sec Section IV No chemnicals in this -product are subject to the reporting requ~irememts of CMC.T.A.
WASTE DISPOSAL NMTHOD: L-andfill solids at pesninttod sthetsi~ng registercd transporters.
Bumri concentrated liquide. avoiding 10ameoantc, and axturino emissonx comply with applicable reguationv.
Dilute aqueous waste may biodegrade.
butt avoid overloading plant biomass and atsuring offluont complies wvith applicable regulations. 
-09io' -XfV Tasr nomdu This product is not rMIMate by MOT W~UMS clasification, for product: ri/a This product has beena classified in accordance with the hazard criteria of the CMf and Chc NMSS cwostaals all the lnforntationi roquircd by thz CFRL This material saftsy data sheet and tba iztfmaation it contains is oflered to )vuj in good fath as accuraic.
We kayo rviewed any inforrmation contained in lhe (IatA zheet which we receivtd from mowccg outsdc our cotapany and wc bclieve that informaton to br. correct but cannot guarantee its accuracy or cooapletencs.
Health anid safety precautions in this data shcet nay not bo, adequate for all individuals and/or situations.
it Is tho uscs's abligatiwn to evaluate anid sate this proiduct safely and to comply with all applicablo laws and rcgulstions.
No0 sttmesntn nade in this data sheet shall be construed am pcrniduson or recommnrnmsatlon for the use of any product in a mannecr that might infkiriga axisting patents. No warranty is made, cithcr expresse of Implied.
3 000315Z Assigned to: ????Expires On: "?
Assigned to: ???? FOR INFORMATION ONLY \~JLU WSTERN CHEMICAL INTERNATIONAL, INC. 2939 N. 67TH4 PLACE, SCOTTSDALE, AZ 85251 (602) gg0-9487 8-:o~ 1HEALTH IfL 199..4 S(OO'ESLR3Q FOR 111COfC MOUIREMfi4YS tLMA~ COMPOUND.
CLEANING LIOtTIDIC0MBtJS.
L10. NA 1270DO.T.CLASSIFICATION.
s v w#4tt Y^ acc # AT00 P2.)H pet 411 101 1 1i 0 1 I* IDENTIFICATION~
1PROQUCINAME "E~PA 2000" WCI-140 EMERGENCY PHONE (602) 99D-9487 'P-LPfIAnRLR M. Mlichaels DATE PREPARED 8/18/92 NONE OF THE WxAECNNTS WNTHIS FORMULATION ARE FOUND ON ANY LISTS OF HAZARDOUS, CARC4NOGCNIC OR BANNED CHEMICAL ACE~NTS Oft MAIlE RIALS CEINF PATE D BY THEM. AGENCIES INVE S1IOAT ED INCLUDE TilE EPA.. FD.A., NATIONAL.
CANCER VIlST1TUTE-.NATIONAJ.
SCrN.Wr rOILNI)AT00ON.
0 S.HA. (FEDERAL AMD CALFORNIhLI.
THlE CONSUMER PRODUCT SAFETY COMMISSION.
D.0 T. ISAFETY INSTITUTE AND SPECIAL PilOGnAMS ALVAINIS 7 RATION), AND THE NATIONAL.
TOXICQQ~Y PMRQGR. THE FOF4AJL ATMI IS~ A I AADF ArPRF T AND CCM.PLIES WITH 2WZFA XVII .s1O1. 120. SFCTION(i).ITRADE SECRE TS 11 -HAZARDOUS INORIEDENTS
!PHNC'PLE COMPONENT;S) (CH4EMICAL NAME sj CASN 1Wv PEL ALIP'HATIC HYDROCARBONS CIO-C 1 4  64742-47-8 200 200 PARAFFINIC HYDROCARBONS 64742-88-8 200 200 !D-LlM0N&E
-5989-27-5 None None "EPA 2000" formula to a trade secret and complies with 29 CFR 1910.1200, Section Mi Trade Secrete. VOC (Volatile Organie Compounds is within Air Quality Emission Standuards (California-All Districts).
No Ingredients listefd 4under Ca.Stem DrInk(Ing.
6Toxic Chemical Enforcement Act (1986). OSHA Hatard Claqr LJ 1i~ NON HAZARDOUS LIqUI ; RCRA Hazardous Waste Class 40 CPR 261.2 WA E 1TCLP Waste Class 40 CPR 261.4 -NON HAZARDOUS WASTE 19 BO!L ING POINT (ff)2-90F lI SPHY ECAL D ATA T s113s._&#xfd; 0.810 VA POkPRE SSURE phlg/nmnHg.
@250C 1 Ph HI/D JVAPOR DENSITY (Air .1) 3 EVAPORATION RATE Butyl Acetateali<
torn onso' orui Fea druerm.-r SDLUB L rIN N WV. A PPAC v R ANC bAT 'MSL othe hish FL eMNIBEr e LII S LourcN/NI CO.. Dry Power, CT SPCA IR FIHIGPOEUECasBPoeue H~rARDWSMAY OCCUR IPOLYMERtZATION WILL NOT OCC..,A XONDITIO4S TO AVOID None Known 00035j3 Expires On: \??
FOR INFORMATION ONLY Expires On: '? 2 ,or,."_S.- 1O. a7 Y- LLHHAZAR!D ATA IRV;E(S)OFENTRY.
INHALATION?
Unlikely SI"? Possble IINGESTIN?
Unikely )iEARTH HAZARDS (ACUTE AND CHROVWC) Product has low vapor pressure and should not present a hazard under normal working conditions.
SIGNSAND SYMPTOMOFEXPOSVRE Product considered safe under normal usage. Over exposure, !however, may result in the following:
INHALATION:
Dizziness; SKIN/EYES:
Irritation; .INGESTION:
Gastro-inteatinal irritation.
CARCHNOGOICITY.
jNTP? No- 1 L&RC MONOGRAPHS?
No OSA REOOrot No ICD61CAL CONDITONS GENE RALLY AogQRAVATTtV bY ExPOSURE Hone Known EMERGENCYANOFIRSTAIDPROCEOURES INHALATION:
Remove to fresh air; SKIN: Wash with soap and water; EYES: Flu*sh with water for 15 minutes. If irritation persists, seek !tedical attention.
INGESTION:
be not induce vomiting, get medical attention.
I VII -PRECAUT;404 FOR SAFE HANDLINO AND USE SIEPSIOE TAKENINCASEMATERIAL:SRELEASEODRSPILLED.
Allow small spills to evaporate.
Larger l .iLe b o1llacted
&rnd japeased of properly in aecordanoo uith roaUlstiQlsol.
IWAS)EDISPOSALMETNOO:
EPA 2000 has a high BTU value. Waste product can, therefore, be nlxed with normal waste oil for burning as industrial fuel. It can also be recycled or reclaimed.
PR5CAVTIOK$
TO BE TAKEN IN HANDLINGOAD STORING.
Store in cool, dry area away from heat. Keep container tightly closed when product is not being used, Vill .o NITOL MEASUREtS Not required if TLV kept below PPM RE SPIRATORY PROTECTION
{$PEC"Y ?'YI=E VENTILATION LOCAL EXHAUST Adequate SPECIAL None MECHANICAL (GENEAL) Adequate OTHER None PAOTECTiVEG LOVES Nitrile /PVC Goggles/Safety Glasses O'THE R PROTECTIVE CLOTHING OR None required WORKHYGIENICPRACTICES Keep eye wash in vicinity.
Wash with soap 6 water before handling food. k, 1,1 *E 6[.E.t~ P..a. 7. ~'.1 ' CGI.T..a'E 0 ... *4 d.A We~~V~ .C I-f i~,t~ -tC.P q ?-~I 6 ETIO *#OR004 BAR E DA1 04EX I NPCE AS C' .9 9'e 0 t'O.14 &40? a.O .CEIL$~'~L ALL~C.VI'C .CA rVUiJY hC(OVA'E N. E(vIA C".C WJV~A%.tf A6.D10 4 IDft l WaUMOL IkOULD NOT K COHFUUO W31ft hOOA tOLj.OW3 a. V100'10. DF I Jb~f AOv .00.01041 PI4JE8 QA INSAA0 , AtC RI b %01:44~ NWAAP.ANTV IAlsoms 0Z1.P~AD CW PEA1 IV TN. t S Ok OT.IRHWIST 6 MADE D010354 Assigned to: ????
Assigned to: ????67,07/12 OSISO FOR INFORMATION ONLY 3 617 762 1095$RVOGRAH Expires On: N?? 0I BA VOURAN 2"&#xfd; KX< P.O. amx 130, 0206o 7] Emergency Telephone:
(617) 762-5400 MATERIAL SAFETY DATA SHEET TRADE RAME: SAVOGtCA%
TqS vith ph@ophat EFFECTIVE PATE& Mrch. CNEMICAL NAME: Mixture C.A.S. No.: Not Applicabl e a &#xa2;pst: OrTENGROI 001 SNIPPING MAINE AND LAlJLINGI Cleaning Compound -mot regulated under 5000 pounds SICIION 2 NA: Sodium Phosphate#, trIbasi. crystatlint Sodium S@9qutcsrbonfte, crystalline ZA3POUS IIGREO[ENTS LUA.9. Be 101016-9-0 533-96-0 KLo A20 Expeosure QudeltnalL mot easeblished mot established Average elemental phosphorous content 7.32 in the form of phosphates.
Equivelent of 17 gross per Cup of powder.SECTION $PNYSICAL DATA Doiling Point: P SO0"C pelting Poift: NA Vapor Pressure:
NA Specific gravity: NA Density: 60 -75 tbsgft 3 SECTION 4 I Volatilte NA EvaporatiOn Rate: NA Solubility In wAtort Noderat# pN (1 In 1tO): 1$ 12 Appearancet White crystaltine solid FIRE AND EXPLOSION DATA FtA$N P011: Not applicable FLANNAULE LIMITts Not epptlcoble EXTICUISHIVO MEDIA1 Nonfilmmobte NAU isOUI DECOMPFhOM it PROoUCIt&
Nay form toxic a carbon monoxide, etc. when heated to high temperalt SPECIAL FIgEFIIHT3NO paOCEDURESI Sotutions In Nate Wear full protective ctotkiins.
UNUSUAL FINE AND EXPLOSION UAZARDS: Not applicable ateriaota carbon dioxide, r ra r are moderately to strong alkaline.SECTION 5 hEALTH OAZARD DATA TRItESHOLD LIMIT VA1UE: S#e SOction 2 EFFECTS OF EIP.OSUEII
-RoUte of Entry -A CiUT (1mmediCte) g.: toan &#xa2;euse Sovers irritation and burning and transeat Intjury to cornea.  &X.j!: IrritstIing may cause chemical burns and dermatitis.  .Inhalation.
Inhalation of dust can cause nasel end respiratory IrrStlOt0n.
111.1ligjinh' Nay aeuse irritation and Chemical burns to the gastrolntettlnaL tract. IFFECTS OF EXPOSURE -L CHONIC (delayed);
gone known carcifnogmnicltYI TP? so JARC NONOGCAPNI?
SNo O$SA REOULATED?
No FlIRST Alk: Y.S.A: Flush eyes with plenty of running loter for at least 15 minutes. Mold eyelids apart to ensura complete IrrigatiOn of sit tissue. Got medical attentlon promptly.
LL-z Remove &#xa2;ontaaiflittd clothing and wash skin thoroughly with water. If irritation OCCurs get medical attention promptly.
Thoroughly Mash contaminated clothing before reu*e InhalationL:
If Illness occurs, remove patient to fresh air. If breathing is difficult.
give oxygen. If breathing has rtopped, start artificial respiration.
Get modlcil attention promptly.
Slytlognt RNever vivo anything by mouth to an unconSCioUs person. If swalowloe DO NOT INDUCE VOMITINO.
Give torso quantities of water (It available give several glass*& of milk). if vomiting occurs spontaneously keep airway t.o.r and give more water. Got medical attention promptly.
If symptoms indicate, apply treatment as appropriate for corrosive alkeli substance.
000:355 Assianed to: 7??? FOR INFORMATION ONLY Expires On: OueftyPtoducfE Since 1676 pmm w~tmnmToggon.
mis 0jazCa , A~*Mou pnawal'. gdjWU r1NfIA4 "V WWxCJ.* r611 U400. 0 Vlgawinv~
wras to V010 1" P. 0. WK= 7M4E. 10 Ai e, Ko3 I'.O ~ ~ ~ ~ ~ P OH MM Aaes 10) 421 40Wc 3( SP A-pS IN~ Peg. 2 of 2 Nsos TeP SECTION 6 REACTIVITY DATA STAIILITI-:
Sthbte "HAIARDOUS POLlN RrZAT4OZ:
riLL Inot ocfUr. INCOWPATIlSLITY faetoristl to ovoid):'Ssi Io utt& In water are highly aikatIne and may produce hydrogen gas when in contact with aluminum.
Vitt react with acids to born carbon dioxide. Naterial fa hygroscopic and tends to coke. CONCITIONS 10 AVOIDz See $ *ECTION 4 -UNUSUAL FIRE AND EXPLOSICN HAZARDS.0 SECTION 7 SPILL O LEAK PROCEOURES S7EPS TO St TAKEN IN CASI NATERIAL IS REILESED OR SPILLEO: Review USECIIOK 4 -UNUSUAL FIRE AND EXPLOSION MAZARDS.SMALL SPLLLS: Sweep up matertia and transfer to contuiners.
Thoroughly sweep preo to clean up residue. Remaining residue may be vaohed awVy vith water. LARGE JL : same as for *matt spills. DISPOSAL OF VAyUE: SmeaL quantities Pay be deposited In general trash end residue 4lushed down drain with water. Large spiLls -Deposit containers in posted toxic substances end ftill in accordance with locaL. state and federal regutations.
trisodium phosphate has a reportable quantity (R0) of S00O tbs. SECTION 8 SPECIAL PROTECTIOk INFDRNAIION VE1TJLCQTION:
Use total exhaust to control dust 4ormation RESPIEAYORY PROTECTION:
Weer NIOSH/NSNA approved dust respirator, if duet fa formed Industrial quality cotton lined neoprene gloves with close fitting wristlets.
TEY PNOTECTION:
Chemical goggles or safety toasses with side shield. OTHER PROTECTIVE EQUIPNENT:
No special protective clothing needed; however, wear Long sLeeved shirts with long pants to protect skin against splashes and spiLLs. SECtION 9 SPECIAL PRECAUTIONS gNPTIED COKTAINERIt Empty continerAs may be Incinerated or discarded with general trash. Large containers shauld be completely emptied before disposal.
because empty .containers say contain residues which ore hazardous, sli precautions given on this sheet should be observed.
PRECAUTIONS to NE TAKEN iN HAN LING AND STORINg: store in dry place. Molsture can cause coking. Keep *way from acids of all types. voter solutions can be corrosive to alumfium and generate hydrogen.
NOTEr judgement of potential hazards of this mixture Is based on Information avullable about individual components listed under SECTION 2 -NAZARDOUS INOREVIENTS.
Direct testing of mixture has not been one. Information given herein Is betieved to be accurate and is given In goad faith; however.
no warranty either expressed or implied io made. It Is strongly suggested that veors confitr in advonce of need that the information is current and applicable to their cituetlone.
Note The sate or use of cleaners Containing Phosphates Is prohibited in some states end tocalities.
Assioned to: ????FOR INFORMATION ONLY Expires On:'-?
Assigned to: ????FOR INFORMATION ONLY 0xyChemExpires On: %?? 32" 59? [,iJn-('la MATERIAL SAFETY DATA SHEET 1 MSDS NUMBER : M5389 MSDS DATE : 04-09-90 PRODUCT NAME : 50% CAUSTIC SODA SOLUTION 24 HOUR EMERGENCY PHONE: (716) 278-7021 I. PRODUCT IDENTIFICATION HMIS HAZARD RATINGS HEALTH HAZARD 3 FIRE HAZARD 0 REACTIVITY 2 Based on the National Paint & Coatings Association HMIS rating system. SARA/TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health: YES Reactive Hazard: YES Delayed (Chronic)
Health: NO Sudden Release of Pressure:
NO Fire Hazard: NO MANUFACTURER'S:
NAME AND ADDRESS Occidental Chemical Corporation Customer Service. Occidental Tower. P 0 Box 809050, Dallas. Texas 75380 Telephone (1-800-752-5151)
CHEMICAL NAME: Sodium Hydroxide CAS NUMBER: 1310-73-2 SYNONYMS/COMMON NAMES: Sodium Hydroxide; NaOH CHEMICAL FORMULA: NaOH DOT PROPER SHIPPING NAME: Sodium Hydroxide.
Liquid DOT HAZARD CLASS: Corrosive Material DOT I.D. NUMBER: UNI824 DOT HAZARDOUS SUBSTANCE:
RO 1000# II. HEALTH HAZARD INFORMATION EMERGENCY AND FIRST AID PROCEDURES EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION.
IMMEDIATELY flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart to ensure flushing of entire surface. Washing eyes within several seconds is essential to achieve maximum effectiveness.
SEEK MEDICAL ATTENTION IMMEDIATELY.
CA5
* Ehinlcol ab.tract Service Numb-r ND
* Na me.ltnt IhFiraotltn futt not evillible pa.
* 0510* PiItMIsSIbIS 6IK..sUPe LO..t *O ieplitPi Limit T!V 5*01[ Tr.tShld Liit VaIwo. Currnt a .$ @tC 119.0*5 ifl.0 tiet N, .Not ilIibli 1MPgSVANT; Te1 e f1f1atIfll pf...ntld h.lrEi .yiiti nOt 01irint~tt.
SiS ptgpitld by Ofpltini t ecithtl rolso.mil aMOt O t'" end IocurItI "s th a best o# 0uP -nMIW0a..
NO WAAAITY U, SN ARA TY , IXP ISI 0E !NPLOI IN to INS PINPNRNCS.
iT&lhITy.
DR I ORNWZ5EN S115 intoriNatin I$ not Int:ndd t. OS
* 4llohJVI : I ills hit end of tob, h-ndlIng ind stun;.. Oihst *.ots,5 "ay l1-li- Othlr tr on r f *Itlt}i ia$1dsretiifS.
WhVil Sal. iS~tIOhNI
*ir@Nlbil 101 be hipy .o, nd %a q4woto.fit ragordinQ oIls h in 0SI pnoI*ogi ., Sep. he Iling ott IO. risflint thOtpOfl~tlb&#xb6;ty OF Inll oUltoMil.
NO r gg-ttnS -it flS in. Insenusa so. end nothint heremn shll b. o.mntr2ud as C rolno4td44tiol to IlFtltag any hlNlNtltg ptlfnto -r V1ItS CfY P4d&fil, SIIti Sm t*Otl -lVE.o000, I' FOR INFORMATION ONLY OCCIDENTAL CHEMICAL Page 2 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION II. HEALTH HAZARD INFORMATION (Continued)
SKIN: IMMEDIATELY wash with plenty of water for at least 15 minutes.
Remove contaminated clothing and footwear.
Wash Clothing before reuse and discard footwear which cannot be decontaminated.
SEEK MEDICAL ATTENTION IMMEDIATELY, .INHALATION:
Remove to fresh air; If breathing is difficult have trained person administer oxygen. If respiration stops, give mouth-to-mouth resuscitation.
GET MEDICAL ATTENTION.
INGESTION:
NEVER give anything by mouth to an unconscious person, If swallowed, DO NOT INDUCE VOMITING.
Give large quantities of water. If available, give several glasses of milk. If vomiting occurs spontaneously, keep airway clear. SEEK MEDICAL ATTENTION IMMEDIATELY.
ROUTES OF EXPOSURE INHALATION:
Airborne concentrations of dust, mist, or spray of this product may cause damage to the upper respiratory tract and lung tissue proper which could produce chemical pneumonia, depending upon severity of exposure.
SKIN: This product Is destructive to tissue contacted and produces severe burns. A latent period may exist between exposure and sense of Irritation.
EYE CONTACT: This product is destructive to eye tissues on contact, Will cause severe burns that result In damage to the eyes and even bl indness.
INGESTION:
This product, if swallowed, can cause severe burns and complete tissue perforation of mucous membranes of the mouth, throat, esophagus, and stomach.
EFFECTS OF OVEREXPOSURE ACUTE: Corrosive to all body tissues with which it comes in contact.
The effect of local dermal exposure may consist of multiple areas of superficial destruction of the skin or of primary Irritant dermatitis.
Similarly, inhalation of dust, spray, or mist may result In varylng degrees of Irritation or damage to the respiratory tract tissues and an increased susceptibility to respiratory illness. These effects occur only when the TLV is exceeded.
CHRONIC: No known chronic effects.
TOXICOLOGY DATA: Caustic soda is a corrosive material.
Acute Oral LD50 = 140-340 mg/kg (rat) Acute Dermal LD50 -1350 mg/kg (rabbit) Human Dermal Exoosure Regardless of concentrations, the severity of damage and extent of its irreversibility Increases with length of contact time. Prolonged contact with even dilute sodium hydroxide solution can cause a high degree of tissue destruction.
The latent perlod, following skin contact during which no sensation of Irritation occurs, varies from several hours for e.4 -4% solution to 3 minutes with 25 -50% solution.
000o'58 Assigned to: 7????Expires On: \--
Assioned to: ???? FOR INFORMATION ONLY Expires On: \??OCCIDENTAL CHEMICAL MSDS NUMBER: M5389 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION Page 3 of 9 04-09-90 III. IMPORTANT COMPONENTS CAS NUMBER / NAME 1310732 Sodium EXPOSURE LIMITS PEL-2 mg/m3, .CeilinQ TLV-2 mg/m3, Ceiling COMMON NAMES: CAUSTIC SODA hydroxide (Na(OH))PERCENTAGE VOL WT Listed On(List Legend Below): 13 is 21 7647145 Sodium chloride (NaCl)PERCENTAGE VOL WT EXPOSURE LIMITS PEL-None established TLV-None establ ished COMMON NAMES: SALT Listed On(List Legend Below): 23 ND 0.80- t. 30 water EXPOSURE LIMITS PEL-Not Established TLV-Not Established PERCENTAGE VOL WT COMMON NAMES: Listed On(List Legend Below): 19 23 See Section II All components of this product that are required to be on the TSCA Inventory are listed on the Inventory.
Not listed as carcinogen
-IARC. NTP. OSHA LIST LEGEND 13 PA ENVIROMENTAL HAZ SUBSTANCE 19 PA REQUIREMENT-3% OR GREATER 23 NJ REQUIREMENT-1% OR GREATER 18 NY HAZARDOUS SUBSTANCES 21 NJ SPECIAL HEALTH HAZ SUB IV. FIRE AND EXPLOSION DATA FLASH POINT: NA AUTOIGNITION TEMPERATURE:
Nonflammable FLAMMABLE LIMITS IN AIR, % BY VOLUME- UPPER: NA LOWER: NA EXTINGUISHING MEDIA: This product is not combustible.
Water spray, foam, carbon dioxide or dry chemical may be used where this product is stored. SPECIAL FIRE rIGHTING PROCEDURES:
Wear full protective clothing.
Avoid direct contact of this product with water as this can cause a violent exothermic reaction.
UNUSUAL FIRE AND EXPLOSION HAZARD: None. See Reactivity (Section VII).0001359 ND 45.50-51 7732185 NO 49-51.50 FOR INFORMATION ONLY Expires On: V??Assigned to: ????4L Assigned to: ???? FOR INFORMATION ONLY Expires On:" OCCIDENTAL CHEMICAL Page 4 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION V. SPECIAL PROTECTION VENTILATION REQUIREMENTS:
Special ventilation Is not required under normal use. Use local exhaust ventilation where dust, mist. or spray may be generated.
NOTE: Where carbon monoxide or other reaction products may be generated, special ventilation may be required.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY:
Respiratory protection is not required under normal use. Use NIOSH/MSHA approved respirators where dust, mist, or spray may be generated.
EYE: Wear chemical safety goggles plus full face shield to protect against splashing.
GLOVES: Chemical resistant gloves should be worn. Gloves may be decontaminated by washing with mild soap and water. Natural end butyl rubber have been suggested.
OTHER CLOTHING AND EQUIPMENT:
Impervious protective clothing and chemically resistant safety shoes should be worn to minimize contact. Wash contaminated clothing with soap and water and dry before reuse. Showers and eyewash facilities should be accessible.
MONITORING EXPOSURE BIOLOGICAL:
NA PERSONAL/AREA:
Use NIOSH Analytical Method No. 7401. VI. PHYSICAL DATA BOILING POINT V 760 mm Hg: 143 0 C (289*F) FREEZING POINT: 12.IC (540F) VAPOR PRESSURE:
13 mm Hg a 5G&deg;C SPECIFIC GRAVITY (H20-1): 1.54 0 15.60C SOLUBILITY IN H20 % BY WT: Completely soluble VAPOR DENSITY (Air-1): NA APPEARANCE AND ODOR: Clear liquid with no distinct odor. pH: 7.5% solution has pH 14.e DENSITY: 12.8 lb/gal 000,3(0 Assigned to: ???? FRIFRAINOL xie n ?OCCIDENTAL CHEMICAL Page 5 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAM E: 50% CAUSTIC SODA SOLUTION . VII. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY:
Under normal conditions, this product is stable. INCOMPATIBILITY:
See Handling and Storage (Section VIII). Avoid direct contact with water. This product may be added slowly to water or acids with dilution and agitation to avoid a violent exothermic reaction.
When handling this product, avoid contact with aluminum, tin, zinc, and alloys containing these metals. Do not mix with strong acids without dilution and agitation to prevent violent or explosive reaction.
Avoid contact with leather, wool, acids, organic halogen compounds and organic nitro compounds.
HAZARDOUS DECOMPOSITION PRODUCTS:
None known. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:
Material is not known to polymerize.
VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS:
Do not get Into eyes, on skin, on clothing.
Avoid breathing dust, mists, or spray. Do not take internally.
Use with adequate ventilation and employ respiratory protection when exposure to dust, mist or spray is possible.
When handling, wear chemical splash goggles, face shield, rubber gloves and protective clothing.
Wash thoroughly after handling or contact -exposure can cause burns which are not immediately painful or visible.
Keep container closed. Product can react violently with water, acids, and other substances
-read Special Mixing and Handling Instructions below carefully before using. Product Is corrosive to tin. aluminum, zinc and alloys containing these metals, and will react violently with these metals In powder form. Hazardous carbon monoxide gas can form upon contact with food and beverage products in enclosed spaces and can cause death. Follow appropriate tank entry procedures (ANSI Z117.1-1977).
SPECIAL MIXING AND HANDLING INSTRUCTIONS Product can react violently with water. Considerable heat Is generated when product Is mixed with water. Therefore, when making solutions always carefully follow these steps; ALWAYS wear ALL protective clothing described above. NEVER add water to product. ALWAYS add product -with constant stirring slowly to surface of lukewarm (80-1 0 0F) water, to assure product is being completely dissolved as It is added. If product is added too rapidly, or without stirring, and becomes concentrated at bottom of mixing vessel, excessive heat may be generated, resulting in DANGEROUS boiling and spattering, and a possible IMMEDIATE AND VIOLENT ERUPTION of highly caustic solution. 
.0003w FOR INFORMATION ONLY Expires On: \??Assioned to: ????
Assigned to: ?'?? FOR INFORMATION ONLY Expires On:" OCCIDENTAL CHEMICAL Page 6 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION VIII. HANDLING AND STORAGE (Continued)
SPECIAL MIXING AND HANDLING INSTRUCTIONS (Continued)
NOTE: Never add more product than can be absorbed by solution while maintaining temperature below 200*F (a sea level) to prevent boiling and spattering.
Product can react EXPLOSIVELY with acids, aldehydes, and many other organic chemicals
-when mixing product with solutions containing such chemicals, follow all of above mixing instructions, and add product very gradually, while stirring constantly.
ALWAYS empty and clean containers of all residues before adding product, to avoid possible EXPLOSIVE reaction between product and unknown residue.
Returnable containers should be shipped in accordance with suJpplier's recommendations.
Return shipments should comply with all federal, state, and DOT regulations.
All residual caustic soda should be removed from containers prior to disposal.
IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Leaks should be stopped. Spills should be contained and cleaned up immediately, Spills should be removed by using a vacuum truck. Neutralize remaining tv-aces of material with any dilute inorganic acid such as hydrochloric, sulfuric, nitric, phosphoric, and acetic acid. The spill area should then be flushed with water followed by liberal Covering of sodium bicarbonate.
All clean-up material should be removed and placed in approved containers, labeled and stored In a safe place to await proper treatment or disposal.
Spills on areas other than pavement.
e.g., dirt or sand. may be handled by removing the affected soils and placing In approved containers.
Persons performing clean-up work should wear adequate personal protective equipment and clothing.
Spills or releases should be reported.
if required, to the appropriate local, state and federal regulatory agencies.
CAUTION: Caustic soda may react violently with acids and water. WASTE DISPOSAL METHOD: The materials resulting from clean-up operations may be hazardous wastes and, therefore, subject to specific regulations.
Package, store, transport, and dispose of all clean-up materials and any contaminated equipment In accordance with all applicable federal, state, and local health and environmental regulations.
Shipments of waste materials may be subject to manifesting requirements per applicable regulations.
Appropriate disposal will depend on the nature of each waste material and should be performed by competent and properly permitted contractors.
Ensure that all responsible federal, state, and local agencies recelve proper notification of spill and disposal methods.
OO03bZ to: ???? FOR INFORMATION ONLY Expires On: OCCIDENTAL CHEMICAL Page 7 of 9 MSDS NUMBER: M5389 04-t9-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION X. ADDITIONAL INFORMATION OSHA Standard 29CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, material safety data sheeots, training and access to written records. We request that you. and it Is your legal duty to. make all information in this Material Safety Data Sheet available to your employees.
To aid our customers In complying with regulatory requirements, SARA Title III hazard categories for this product are indicated in Section I. If the word "YES" appears next to any category, this product may be reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details.
X1. PREPARATION INFORMATION For additional Non-Emergency health, safety, or environmental information telephone (716Y 286-3081, or write to: Occidental Chemical Corporation Product Stewardship Department Suite 400 350 Rainbow Boulevard South Niagara Falls, NY 14302 For Emergencies:
24 HOUR EMERGENCY PHONE: (716) 278-7021 This MSDS replaces MSDS Number- M5389 dated 07-14-89. 
*L O00g433 Assiolned to: 7???7 FOR INFORMATION ONLY Expires On: W?7 Assigned to: ?'?? FOR INFORMATION ONLY Expires On: -, OCCIDENTAL CHEMICAL Page 8 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION WARNING LABEL INFORMATION SIGNAL WORD: DANGER! STATEMENT OF HAZARDS: CAUSES SEVERE BURNS TO SKIN. EYES AND MUCOUS MEMBRANES.
CONTACT WITH EYES CAN CAUSE PERMANENT EYE DAMAGE. INHALATION OF DUST, MIST, OR SPRAY CAN CAUSE SEVERE LUNG DAMAGE. CAN REACT VIOLENTLY WITH WATER. ACIDS. AND OTHER SUBSTANCES.
PRECAUTIONARY STATEMENTS:
Do not get into eyes. on skin, on clothing.
Avoid breathing dust, mist, or spray. Do not take internally.
Use with adequate ventilation and employ respiratory protection when exposure to dust, mist. or spray is possible.
When handling, wear chemical splash goggles, face shield, rubber gloves and protective clothing.
Wash thoroughly after handling or contact -exposure can cause burns which are not immediately painful or visible.
Keep container closed. Product can react violently with water, acids, and other substances
-read Handling and Storage .Instructions carefully before using. Product Is corrosive to tin. aluminum, zinc. and alloys containing these metals, and will react violently with these metals in powder form. Hazardous carbon monoxide gas can form upon contact with food and beverage products in enclosed spaces and can cause death. Follow appropriate tank entry procedures (ANSI Z117.1-1977).
FIRST AID: IN CASE OF CONTACT: FOR EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION.
IMMEDIATELY flush eyes with large amounts of water for at least 15 minutes forcibly hol.ding lids apart to ensure flushing of entire surface. Washing eyes within several seconds Is essential to achieve maximum effectiveness.
SEEK MEDICAL ATTENTION IMMEDIATELY.
FOR SKIN: IMMEDIATELY wash with plenty of water for at least 15 minutes.
Remove contaminated clothing and footwear.'
Wash clothing before reuse and discard footwear which cannot be decontaminated.
SEEK MEDICAL ATTENTION IMMEDIATELY.
IF INHALED: Remove to fresh air. If breathing Is difficult, have trained person administer oxygen. If respiration stops, give mouth-to-mouth resuscitation.
GET MEDICAL ATTENTION.
IF SWALLOWED:
NEVER give anything by mouth to an unconscious person. If swallowed.
DO NOT INDUCE VOMITING Give large quantities of water. If available, give several glasses of milk. If vomiting occurs spontaneously, keep airway clear. SEEK MEDICAL ATTENTION IMMEDIATELY.
IN CASE OF: SPILL OR LEAK: Leaks should be stopped. Spills, after containment, should be shoveled up or removed by vacuum truck (if liquid) to chemical waste area. Neutralize residue with dilute acid, flush spill area with water followed by liberal covering of sodium bicarbonate.
Dispose of wash water and spill by-products according to federal, state, and local regulations.
01 000364 Assigned t:o: ????FOR INFORMATION ONLY Expires On: "-7 Assiqned to: 7??? FOR INFORMATION ONLY Expires On: \??OCCIDENTAL CHEMICAL Page 9 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION WARNING LABEL INFORMATION (Continued)
HANDLING AND STORAGE: Considerable heat Is generated when product is mixed with water. Therefore, when making solutions always carefully follow these steps: ALWAYS wear ALL prescribed protective clothing.
NEVER add water to product. ALWAYS add product -with constant stirring slowly to surface of lukewarm (80-1490F) water, to assure product Is being completely dissolved as It is added. If product Is added too rapidly, or without stirring, and becomes concentrated at bottom of mixing vessel, excessive heat may be generated.
resulting in DANGEROUS boiling and spattering, and a possible IMMEDIATE AND VIOLENT ERUPTION of highly Caustic solution.
NOTE: Never add more product than can be absorbed by solution while maintaining temperature below 200*F (@ sea level) to prevent boiling and spattering.
Product can react EXPLOSIVELY with acids, aldehydes, and many other organic chemicals
-when mixing product with solutions containing such chemicals, follow all of above mixing instructions, and add product gr~y gradually, while stlrrino constantly.
ALWAYS empty and clean containers of all residues before adding product, to avoid possible EXPLOSIVE reaction between product and unknown residue.
Returnable containers should be shipped in accordance with supplier's recommendations.
Return shipments should comply with all federal, state, and DOT regulations.
All residual caustic soda should be removed from containers prior to disposal.
DISPOSAL:
The materials resulting from clean-up operations may be hazardous wastes and, therefore, subject to specific regulations.
Package. store, transport, and dispose of all clean-up materials and any contaminated equipment in accordance with all applicable federal, state, and local health environmental regulations.
Shipments of waste materials may be subject to manifesting requirements per applicable regulations.
Appropriate disposal will depend on the nature of each waste material and should be performed by competent and properly permitted contractors.
Ensure that all responsible federal, state, and local agencies receive proper notification of disposal.
INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS:
This product contains:
CAS# NAME 1310732 Sodium hydroxide (Na(OH)) 7647145 Sodium chloride (NaCl) 7732185 Water EMIS RATING SYSTEM: HEALTH 3 FOR INDUSTRIAL USE ONLY FLAMMABILITY 0 LABEL REACTIVITY 2 040X5389 0003-6 Assioned to: ?7???FOR INFORMATION ONLY Expires On: N??
3600-PM-WQ0008 Rev 7197 NF SECTION C -(continued)
N/A IV. (Continued) 2,3 Information and Analysis of Effluent Quality for Other Potentially Toxic Pollutants Known or Expected to be Present in the Discharge (Read instructions carefully and use the tabular format and additional pages, where necessary, to present the required information.)
PDES Number PA Average Effluent Analytical Outfall Chemical Substance or Compound Reason for Presence in Discharge Concentration Detection Level _______________________________W
/gI) W /ig1)I I I I I I I I 0047325 iII -I NPDES Number PA 0047325 SECTION C -(continued)
IV. (Continued)
: 4. Any other toxic chemicals known or expected to be present in the discharge. 
: a. GC/MS "Five Peaks" pollutants (see instructions)
Ouffall Number N/A Group Analytical Average Maximum No. Samples Number Chemical Substance or Detection Effluent Effluent Positive (3-7) Compound Name Limit Concentration Concentration
/ (pg/I) (pg/I) (Wg/I) No. Analyzed I / I / I I / / / / / t / t / / / / / / / Use additional sheets for additional pollutants, and for each Outfall reported. 
[] If additional peaks were not available for one or more groups with the method used, check here and attach an explanation of why the method was selected. 
-26 0003 7G*3600-PM-WQ0008 Rev 7197 3600-PM-WQO0008 Rev 7197 SECTION C -(continued)
IV. (Continued)
: 4. b. Other Chemicals NPDES Number PA Outfall Number N/A Indicate if Average Presence is Substance Reason for Presence in Discharge Concentration Know (o (pg/I) Known (K) or Suspected (S)____ 1 ________ .1 ___ 1 ___F I 4 4 r 4 r 4 Provide additional sheets if necessary  000,3G8 0047325 I I I I 3600-PM-WQ0008 Rev 7/97 SECTION C -(continued)
N/A V. HAZARDOUS SUBSTANCE SPILL REPORTING REQUIREMENT EXEMPTION (Optional) (See Instructions)
NPDES Number PA-28-0047325 NPDES Number PA 0047325 SECTION C -(continued)
VI. ANTICIPATED ENVIRONMENTAL PROTECTION IMPROVEMENTS OR RELATED CHANGES A. Are you now required by any federal, state or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application?
This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions.
[] YES (complete the following table)Z NO (go to B)B. OPTIONAL:
You may attach additional sheets describing any additional environmental pollution control programs (or other production projects) which may affect your discharges which you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction.
N/A E MARK "X" IF DESCRIPTION OF ADDITIONAL PROGRAMS IS ATTACHED VII. BIOLOGICAL TOXICITY TEST DATA Do you know or have reason to believe that any acute or chronic or biological toxicity tests were made in the last three (3) years on any of the facility's discharges or on a receiving water in relation to a discharge?
E] YES Z NO If yes, attach any information which you have available on the purpose and nature of such testing, and the test results.
All dischargers are encouraged to perform biological toxicity testing. The Department may require biomonitoring testing be conducted after your application is received.
The Department may be contacted for protocols. 000370 1. IDENTIFICATION OF 2. AFFECTED OUTFALLS 4. FINAL COMPLIANCE CONDITION, 3. BRIEF DESCRIPTION OF PROJECT DATE AGREEMENT, ETC. a. No b. Source of Discharge
: a. Required b. Projected________________________
: a. & a 3600-PM-WQOOOS Rev 7197 3600-PM-WQ0008 Rev 7/97 SECTION D -Stormwater Discharges Associated with Industrial Activity I. Outfall Location For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number D. Receiving Water (List) B. Latitude C. Longitude (Name) N/A I I 4 * + I I I. I I I I 4. 4 4. .,. I I 4. 1 4 4 + 1 1 II. Improvements A. Are you now required by any federal, state, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment or practices or any other environmental programs which may affect the discharges described in this application?
This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders and grant or loan conditions.
E] Yes 0 No 2. Affected Outfalls 4. Final Compliance
: 1. Identification of Conditions, 3. Brief Description of Project Date Agreements, Etc. number source of discharge
: a. req. b. proj. N/A I + I I 4 4- I 3 + 4. I r+ t I + I- I I + I I 4 I- I 1 + 1 I r_____________________________
___________________
1 B. You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction.
1ll. Site Drainage Map Attach a site map showing topography (or indicating the outline of drainage areas served by-the outfall(s) covered in the application if a topographic map is unavailable) depicting the facility including:
each of its intake and discharge structures; the drainage area of each stormwater outfall; paved areas and buildings within the drainage area of each stormwater outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structural control measure to reduce pollutants in stormwater runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units (including each area not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34); each well where fluids from the facility are injected underground; springs, and other surface water bodies which receive stormwater discharges from the facility.000371 0047325 NPDES Number PA 3600-PM-WQ0008 Rev 7/97 SECTION D (Continued)
IV. Narrative Description of Pollutant Sources NPDES Number PA 0047325 A. For each outfall, provide an estimate of the area (include units) of impervious services (including paved areas and building roofs) drained to the outfall, and an estimate of the total surface area drained by the outfall.Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units) (provide units) N/A B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to stormwater; method of treatment, storage, or disposal; past and present materials management practices employed, in the last three years, to minimize contact by these materials with stormwater runoff, materials loading and access areas; and the location, manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied.
N/A C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in stormwater runoff; and a description of the treatment the stormwater receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge.
Outfall List Codes from Number Treatment Table 1 (EPA Table No. 2 Fl) N/A V.. Nonstormwater Discharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstorm water discharges and that all nonstormwater discharges from these outfall(s) are identified in Section C of this application for this outfall.
Name and Official title (type or print) Signature Date Signed N/A B. Provide a description of the method used, the date of any testing, and the on-site drainage points that were directly observed during a test.N/A VI. Significant Leaks or Spills Provide existing information regarding the history of significant spills of toxic or hazardous pollutants at the fac including the approximate date and location of the spill or leak, and the type and amount of material released.N/A-31 -00037?4 SECTION D (Continued)
PART VII-E -Additional Stormwater Information Submission Use this page to list any toxic pollutants as required in Part VII-E of Section D, or to provide explanation of why sampling couldn't be performed.
N/A 000373 0047325 3600-PM-WQ0008 Rev 7/97 NPDES Number PA-32 -00037,3 3600-PM-WQ0008 Rev 7/97 SECTION D (Continued)
VII. Discharge Information NPDES Number PA 0047325 A, B, C, & D: See Instructions before proceeding.
Complete one set of tables for each outfall. Annotate the outfall number in the space provided.E. List any substance(s) or a component of a substance(s) listed in Table 5 which you currently use or manufacture as an intermediate or final product or byproduct.
If none, indicate so. N/A VIII. Biological Toxicity Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? D Yes (list all such pollutants below and explain the purpose and nature of such testing.)
[] No (go to Section IX) N/A 0003371 3600-PM-WQOOO8 Rev 7197 SECTION D (Continued)
NPDES Number PA VII. Discharge Information (Continued from previous page) N/A Part A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.
Pollutant Maximum Values Average Values Number and (include units) (include units) of Storm Sources of Pollutants CAS Number Grab Sample Taken During Grab Sample Taken During Events (if available)
First 30 Minutes First 30 Minutes Sampled Oil and Grease Biological Oxygen Demand (BOD5) Chemical Oxygen Demand (COD) Total Suspended Solids (TSS) Total Kjeldahl Nitrogen Nitrate Plus Nitrite Nitrogen Total Phosphorus pH (Min./Max.)
Part B -List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and requirements.
Pollutant Maximum Values Average Values Number and (include units) (include units) of Storm a Events Sources of Pollutants CAS Number Grab Sample Taken During Grab Sample Taken During Sampled (if available)
First 30 Minutes First 30 Minutes 4- 1 t I L 4. 4 I 4 4. I 4- 4. 4. I 4- 4. 4. I 4- 4. 1* I 4 I- I-34-000375 0047325 3600-PM-WQ0008 Rev 7/97 SECTION D (Continued)
NPDES Number PA 0047325 NIA Part C -List each pollutant shown in Tables 5, 6, and 7 (EPA Table Nos. 2F-2, 2F-3, and 2F-4 respectively) that you know or have reason to believe is present. See the instructions for additional details and requirements.
Complete one table for each outfall.
Pollutant Maximum Values Average Values Number and (include units) (include units) of Storm CAS Number Grab Sample Taken During Grab Sample Taken During Events Sources of Pollutants (if available)
First 30 Minutes First 30 Minutes Sampled Part D -Provide data for the storm event(s) which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. 6. 7. 8. Date of Duration Total Rainfall Number of Hours Between Maximum Flow Rate Total Flow From Season Form of Storm of Storm During Storm Event Beginning of Storm Meas- During Rain Event Rain Event Sample Precipitation Event (in minutes) (in inches) ured and End of Previous (gallons per minute (gallons or was (rainfall, Measurable Rain Event or specily units) specify units) Taken snowmelt)
N/A 9. Provide a description of the method of flow measurement or estimate.
N/A 000376 0047325 3600-PM-wQaoO8 Rev 7197 NPOES Number PA SECTION E -MISCELLANEOUS INFORMATION SUBMISSION
: 1. CONTRACTED ANALYTICAL ASSISTANCE Did a contract laboratory or consulting firm perform any of the analyses required by this application?
Z Yes, their name(s), address(es) and list(s) of the [ No analyses performed are given below: Name Address Analytical Laboratory Services, Inc.34 Doewood Lane Middletown, PA 17057 Phone (717) 944 -5541 Name Address Teledyne Brown Enq.. (Isotopes) 50 Van Buren Avenue_P.O. Box 1235 Westwood, NJ 07675-1235 Phone (201) 664 -7070 Name Address PPL, Inc. Susquehanna Steam Electric Station P.O. Box 467 Berwick, PA 18603 Phone (570) 542 -3995 Types of Analyses Performed:
Group 1,2,3,4,5,7 Attne Sue Baer Types of Analyses Performed:
Group 8 Attn: Al Hogan Types of Analyses Performed:9C, 10C. 110, 12C Attn* Sandra Lewis (cont.)000377-36 -I =S..... .r 34 Doawood Lane 50 Van Buren Avenue'3600-PM-WQ0008 Rev 7/97 NPIDES Number PA 3600-PM-WQOOO8 Rev 7/97 NPDES Number PA 0047325 SECTION E -MISCELLANEOUS INFORMATION SUBMISSION I. CONTRACTED ANALYTICAL ASSISTANCE Did a contract laboratory or consulting firm perform any of the analyses required by this application?
[ Yes, their name(s), address(es) and list(s) of the r No analyses performed are given below: Name Renchmark Analvtics Types of Analyses Performed:
8C, I 4777 Saucon Creek Road (on some of the samples)Center Valley, PA 18034-9004 Phone (610)974-8100 Name Address EcologyV III RRcoloBox 1795 Berwick, PA 18603 Phone (570) 542 -2191 Name Kirby Memorial Health Center Address 71 N. Franklin Street Wilkes-Barre, PA 18701-1391 Phone (570) 823 -5450 Types of Analyses Performed:
9C. 1I0C. 11 C. 12C Attn: Terry Soya Types of Analyses Performed:
14C (all) Attn: Danielle Cappellini 0003,78 Address 5C RR 1. Box 1795 Phone (570) 542 -2191 0047325 3600-PM-WQ0008 Rev 7/97 NPDES Number PA 0047325 3600-PM.WQOOO8 Rev 7197 NPDES Number PA SECTION E -MISCELLANEOUS INFORMATION SUBMISSION (continued)
I1. OTHER INFORMATION N/A 1. For New Dischargers Only:[] Check if Not Applicable
: a. Have there been any technical evaluations performed concerning your anticipated wastewater treatment or control facilities (including engineering reports or pilot plant studies)?
Check the appropriate box below.F-- Yes D No b. If yes, briefly describe such evaluations and the resulting reports which have been prepared.c. Provide the name and location of any existing plant(s) which, to the best of your knowledge, resembles your planned operation with respect to items produced, production processes, wastewater constituents or wastewater treatment.
Name Location 2. For All Dischargers: (Optional)
If necessary, use attached sheets to expand upon responses to any of the above Questions, or to call attention to any other information you feel should be considered in establishing permit limitations for the proposed or existing facility. 000379 3600-PM-WQ0008 Rev 7197 NPDES Number PA-37-000379 SECTION F -CERTIFICATION AND SIGNATURE OF APPLICANT I certify under penalty of law that this document and all attachments were prepared under my. direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,. accurate, and complete.
I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.
NPDES Number PA Robert F. Saunders VP-Nuclear Site Operations Print Name and Title of Person Signing (570 ) 542-3256 Telephone Number of Person Signing Signature of Applicant/,2 -.Z Date Application Signed Sworn and subscribed to before me this ...A .day of Af.L...,19 Y Notary Public Notarial Seal 7 Sandra K. Lines. Notary Public Salem Twp., Luzerne County My Commission Expires Sept. 24. 2001 Member. 13miylvania Association ot nJotarres Notary Seal Please note below the name, address and telephone number of the individual that should be contacted in the event additional information is required: (If same as Item i.C., in Section A, please state). Name Jerome S. Fields Address: PPL, Inc. (GENA93).2 N. 9th Street, Allentown PA 18101-1179 Telephone:
*(610 ) 774-7889 000380 0047325 i , 360D-PM-WQ0008 Rev 7/97-38-000380 3600-PM-WQOOO8 Rev 7/97 Checklist Pep COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL RESOURCES PERMIT APPLICATION
-GENERAL INFORMATION APPLICANT'S
%fCHECKLIST Please check the following list to make sure that you have included all the required information.
Place a checkmark in the column provided for all items completed and/or provided.
Failure to provide all of the requested information will delay the processing of the application and may result in the application being placed on hold with no action, or will be considered withdrawn and the application file closed.Check (X) Item if Included General Information form attached (4000-PM-DFOOOOI)
(01 30-PM-DPCO001)
X Three (3) copies of application package submitted X Original copy of application notarized X Additional copy for ECHD, ACHD, and DRBC Application Fee $500.00 X Proper evidence of Act 14 municipality, county notification X Proof of local newspaper public notice (for new and substantially changed discharges only) SECTION A -APPLICANT IDENTIFIER Requirement Check (X) SECTION B -GENERAL INFORMATION if Included 1. SIC Codes x 2. General Description and Nature of Business X 3. Past and Current NPDES and WQM Part II Permits 4. Topographic Map X 5. Outfall Location (submit copy of Topo Map with discharge location)
X 6. Preparedness, Prevention, and Contingency (PPC) Plans See note page 2 7. Line Drawing x 8. Site Plan and Stormwater Runoff for outfalls discharging BOTH stormwater and x process wastewater
: 9. New Source Determination 000381 3600-PM-WQ0008 Rev 7197 Checklist SECTION C -DATA REQUIREMENTS FOR PROCESS, NCCW, AND SANITARY WASTEWATER DISCHARGES RequiementCheck (X) Requirement if Included I. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES X II. SOURCES OF WASTEWATER CONTRIBUTING TO OUTFALLS 1. Process Wastewater X 2. Other Wastewater X 3. Total Process, Miscellaneous, NCCW and Sanitary Wastewater
: 4. Process Wastewater Combined with Stormwater Ill. REQUIRED AND OPTIONAL ANALYSES 1. Optional Site-Specific Toxics Data 2. Summary of Required Analyses Worksheet
: 3. Analyses Results X IV. INFORMATION ON OTHER POTENTIALLY TOXIC POLLUTANTS KNOWN OR EXPECTED TO BE PRESENT IN THE DISCHARGE
: 1. Chemical Additives X 2,3 Other Potentially Toxic Pollutants 4a. GC/MS Five Peaks Pollutants 4b. Other Chemicals V. HAZARDOUS SUBSTANCE SPILL REPORTING REQUIREMENT EXEMPTION VI. ANTICIPATED ENVIRONMENTAL PROTECTION IMPROVEMENTS VII. BIOLOGICAL TOXICITY TEST DATA SECTION D -"STORMWATER DISCHARGES ASSOCIATED WITH INDUSTRIAL ACTIVITY" RequiementCheck (X) Requiementif Included 1. IF REQUIRED TO COMPLETE THIS SECTION, ALL PARTS ARE COMPLETE SECTION E -MISC. INFORMATION SUBMISSION (To be Completed by All Applicants)
Check (X) Requirement if Included I. CONTRACTED ANALYTICAL ASSISTANCE X I[. OTHER INFORMATION SECTION F -CERTIFICATION AND SIGNATURES OF APPLICATION (To Be Completed by All Applicants)
Requirement Check (X) if Included Robert F. Saunders, VP-Nuclear Site Operations X 000382-40 -}}

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