ML14122A060

Zion Nuclear Power Station, Units 1 and 2, Radioactive Effluent Release Report, Radioactive Effluent Control Program Report, Offsite Dose Calculation Manual and Process Control Program for 2013

ML14122A060
Person / Time
Site:	Zion  File:ZionSolutions icon.png
Issue date:	04/28/2014
From:	Bouchard G H ZionSolutions
To:	Document Control Desk, NRC/FSME
References
ZS-2014-0100
Download: ML14122A060 (24)

Text

ZIONSOLUTIONSLLC An Emr dtloSfl CompanyApril 28, 2014 ZS-2014-0100 U.S. Nuclear Regulatory Commission ATTN: Document Control DeskWashington, DC 20555-0001 Zion Nuclear Power Station, Units I and 2Facility Operating License Nos. DPR-39 and DPR-48NRC Docket Nos. 50-295, 50-304 and 72-1037

Subject:

Radioactive Effluent Release Report, Radioactive Effluent Control Program Report,Offsite Dose Calculation Manual and Process Control Program for 2013.In accordance with Facility Operation License Nos. DPR-39 and DPR-48, Appendix A,Technical Specification 5.7.3, "Radioactive Effluent Release Report,"

for Zion Nuclear PowerStation, Units 1 and 2, this is the submittal of a Radioactive Effluent Release Report for the year2013. The report is required to be submitted prior to May 1, 2014 and is provided asAttachments 1 through 6 to this letter. A listing of commitments contained in this submittal isprovided in Attachment

1. Certificate of Compliance No. 1031 for the MAGNASTOR SYSTEM, Appendix A, Technical Specifications 5.1.1 and 5.1.3 require submittal of an AnnualRadioactive Effluent Control Program report which is included in this document.

Pursuant to 10 CFR 50.4 and Technical Specification 5.6.1 .c. there were changes made to theZion Station Offsite Dose Calculation Manual (ODCM) during the period of January throughDecember 2013. Attachment 1, Supplemental Information, summarizes the changes made to theODCM during the calendar year of 2013. Attachment 7 is a copy of Zion Station ODCM, currentas of December 31, 2013.There are no new regulatory commitments in this submittal.

If you have any questions about this submittal please contact Mr. Christopher Keene at(224)789-4073.

Respectfully, VP Operations

& Engineering

& Decommissioning Plant ManagerZionSolutions, LLCA 00101 Shiloh Boulevard, Zion -IL 60099(224) 789-4016

• Fax: (224) 789-4008

• www.zionsolutionscompany.com ZionSolutions, LLCZS-2014-0 100Page 2 of 2Attachments:

1. Supplemental Information

2. Effluent

& Waste Disposal Summary2.1. Unit 1 Gaseous Effluent2.2. Unit 2 Gaseous Effluent2.3. Liquid Effluent2.4. Direct Radiation 2.5. LLIYs2.6. Error Estimation

3. Solid Waste and Irradiated Fuel Shipments

4. Radiological Impact on Man4.1. 40CFR190

& 1OCFR72 Compliance summary4.2. Unit 14.3. Unit 24.4. ISFSI4.5. Combined 40CFR190 report5. Meteorology Data6. Errata Data from previous years7. Zion Station ODCM8. ZS-WM-123 Process Control Program Requirements cc: John Hickman, U.S. NRC Senior Project ManagerService List Zion Nuclear Power Station, Unit 1 and 2 License Transfer Service Listcc:Alan ParkerPresident Projects GroupEnergySolutions 1009 Commerce Park Drive, Ste. 100Oak Ridge, TN 37830John SaugerSenior VP & General ManagerZionSolutions, LLC101 Shiloh Boulevard Zion, IL 60099Gary BouchardVP Ops, Engineering, andDecommissioning Plant ManagerZionSolutions, LLC101 Shiloh Boulevard Zion, IL 60099Gerard van Noordenmen VP Regulatory AffairsZionSolutions, LLC101 Shiloh Boulevard Zion, IL 60099Dan ShrumSenior VP Regulatory AffairsEnergySolutions 423 West 300 South, Ste. 200Salt Lake City, UT 84101Russ WorkmanGeneral CounselEnergySolutions 423 West 300 South, Ste. 200Salt Lake City, UT 84101Alwyn C. SettlesSection Head, Nuclear Facility Inspection Bureau of Nuclear Facility SafetyIllinois Emergency Management Agency1011 North St., PO Box 250Mazon, IL 60444Kent McKenzieEmergency Management Coordinator Lake County Emergency Management Agency1303 N. Milwaukee AvenueLibertyville, IL 60048-1308 Regional Administrator U.S. NRC, Region III2443 Warrenville RoadLisle, IL 60532-4352 John E. MatthewsMorgan, Lewis & Bockius LLP1111 Pennsylvania Avenue, NWWashington, DC 20004 ZionSolutions LLCZS-2014-0100:

Attachment I -Supplemental Information

1. Regulatory Limits: The dose to a member of the public fi'om direct radiation, liquid andgaseous effluents released friom each unit to areas at or beyond site boundary shall belimited to the following:

a. Fission and Activation products:

i. Tech Spec Whole Body: 500 norero/year ii. Tech Spec Skin: 3000 morem/year

b. Particulates with half-lives

> 8 days, tritium and Iodine:i. Tech Spec Organ: 1500 orero/year ii. 1 OCFR50 Organ: 7.5 mrem/quarter, 15 mrem/year

c. Liquid Effluents:

i. IOCFR50 Whole body: 1.5 mrem/quarter, 3 mrem/year ii. IOCFR50 Organ: 5 torem/quarter.

10 torem/year

d. Combined dose to real individual beyond controlled area:i. 10CFR72 Whole body: 25 torem/year ii. IOCFR72 Thyroid:

75 mrem/year iii. 1OCFR72 Organ: 25 mrem/year

2. Effluent Concentration Limits (ECL): Limits used in determining allowable release ratesor concentrations.

a. Gaseous Effluents:

I OCFR20 Appendix B Table 2 Column 1.b. Liquid Effluents:

10 X IOCFR20 Appendix B Table 2 Column 2.3. Measurements and Approximations of Total Radioactivity.

a. Fission and Activation Products:

100% Kr-85 is assumed in calculations sinceother isotopes have decayed.

Vent stack activity is continuously monitored forfission and activation gases.b. Particulate and tritium releases are continuously monitored and samples collected and analyzed weekly. Particulate filters are sent to an independent lab forquarterly composite analysis.

Tritium activity is monitored in gaseous releasesfrom evaporation of water in the spent fuel pool and water filled reactor cavities.

c. Liquid effluents are continuously monitored and isotopic analysis performed weekly.d. Occupancy factors to accurately estimate dose due to habits of the real individual that are used to calculate maximum exposed member of the public are discussed in ES&H Technical Support Document 13-009 "Member of the Public Dose fromAll Onsite Sources."

4. Batch Releases:

a. Liquid: There were no liquid batch releases in 2013.b. Gaseous:

There were no gaseous batch releases in 2013.5. Abnormal Releases:

a. Liquid: There were no liquid abnormal releases in 2013.b. Gaseous:

there were no gaseous abnormal releases in 2013.

ZionSolutions LLCZS-2014-01 00: Attachment I -Supplemental Information

6. Gaseous and Liquid Waste Treatment Systems and Process Control ProgramZion Station ODCM Section 12.7.2 pursuant to ODCM Section 12.7.4 requires majorchanges to the Gaseous and Liquid Waste Treatment Systems to be reported in theAnnual Radioactive Effluent Release Report. There are major changes ongoing with thephysical configuration of the liquid radwaste system. along with associated DSAR andODCM descriptive changes; however the changes were not completed and furtherrevisions were being evaluated as of Dec. 3 1, 2013; therefore the completed changepackage will be submitted in the reporting year during which the change was complete.

Zion Station ODCM Section 12.6.2 requires major changes to the Process ControlProgram(PCP) to be submitted in the Annual Radioactive Effluent Release Report. Therewere no major changes to the PCP.The Waste Gas Hold-up System was permanently vented. In Zion's defueledconfiguration this system is no longer applicable.

In Zion's defueled configuration, the charcoal iodine removal system is no longerapplicable.

Due to radioactive decay and no means of production, radioactive iodine is not a concernat Zion.7. Limiting Conditions of Operation (LCOs)Zion Station ODCM Section 12.7.2 requires explanation as to why the inoperability ofliquid or gaseous monitoring instrumentation was not corrected within the time specified in the ODCM to be submitted with the Annual Radioactive Effluent Release Report.There are no such occurrences.

8. Liquid Holdup Tanks and Gas Storage TanksZion Station ODCM Section 12.7.2 requires a description of events leading to liquidholdup tanks or gas storage tanks exceeding technical specification limits to be includedin the Annual Radioactive Effluent Release Report.The contents of the six gas decay tanks have been sampled and determined to havenegligible activity.

The Gas Decay Tanks have been abandoned in place.No liquid holdup tanks exceeded the limits of Permanently Defueled Technical Specifications 5.6.3 during 2013.9. Offsite Dose Calculation Manual (ODCM)Changes to the ODCM are required by Zion Station Permanently Defueled Technical Specification 5.6. 1. and ODCM Section 12.6.3 to be submitted as part of, or concurrent with, the Annual Radioactive Effluent Release Report.

ZionSolutions LLCZS-2014-0100:

Attachment I -Supplemental Information A summary of changes made to the ODCM during 2013 and an entire copy of tileODCM, current as of December 31, 2013 are required to be submitted.

Revisions to ODCM and Process Control Program are listed below:a. ODCM Revisions:

Chapter Section Description 10 10.2.1 Grammatical change10 10.2.1 .1 Renamed Boric Acid Monitor Tank to Lake Release Tank;There are 2 Lake Release tanks in the new system each with anominal capacity of 35,000 gallons.10 10.2.1.2 Added section:

The existing Holdup Tanks are added as thededicated location to receive and store unprocessed liquidwaste.10 10.2.2.1 Revised the discussion of monitoring releases.

The newradiation monitor OR-PRO4 monitors the release from the LakeRelease tank that is discharging.

Previously, the radiation monitor was located in the AB at the 542' elevation and theisolation valve was approximately 250 feet downstream of theradiation monitor which provided a margin of time for themonitor to process an alarm and close the valve prior to therelease entering the discharge canal. This was necessary due tothe discharge line connecting to the discharge canaldownstream of the dilution flow stream. As such, any waterthatentered the canal would be released to the lake with thedilution flow such that when the release is terminated, thatwater is stagnant in the canal and does not enter into thedilution stream.10 10.2.3.1 Changed "condenser cooling" water to "service" water.Renamed Boric Acid Monitor Tank to Lake Release Tank.10 10.2.3.2.1 Renamed Boric Acid Monitor Tank to Lake Release Tank10 10.2.4 Renamed Boric Acid Monitor Tank to Lake Release Tank.I I Table I I-I.b Section b. added to include new control air sample location12 Table 12.5-1.b Section b. added to include new control air sample locationI 1 Table I -I .2.b Added control TLD locationII Table I I-1.2.c & II- Added sections

c. and d. To include TLD's placed for ISFSI1.2.d background trending.

Added section to re-establish 5 mile ringREMP TLD's.I I Figure I 1-1 Renamed to figure I 1-la. and updated with new REMPmonitoring locations 11 Figure I l-lb. Figure added to show5 mile ring TLD placement locations 12 Table 12.5-1 Updated table for new TLD locations.

12 Table 12.3-2.A

& Removed Sr-89 from analysis, added Ni-6312.3-2.B12 Table 12.4-1.C

& Removed Sr-89 friom analysis, added Ni-6312.4- 1.D ZionSolutions LLCZS-2014-0100:

Attachment 1 -Supplemental Information Chapter Section Description 12 Table 12.4-1 Note c. Removed Sr-89 from analysis, added Ni-6312 Table 12.2-1. .A Renamed Boric Acid Monitor Tanks (BAMT) to Lake ReleaseTanks.12 Table 12.2- 1. I.A. 1 Changed OR-PRO5 to OR-PRO412 Table 12.2-1.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank #112 Table 12.2-1.3.B

& Added Item 3.B and 3.B.1I Lake Release tank #2 is monitored 12.2-1.3.B.

I for flow from new flow meter OFI-WD-006 12 Table 12.2-2. I.A & Renamed Boric Acid Monitor Tank to Lake Release Tank.12.2-2. I.A. 112 Table 12.2-2.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank #112 12.2-2.3.b

& 12.2- Lake Release Tank #2 is monitored for flow from new flow2.3.b. 1 meter OFI-WD006 12 Table 12.3-2.1

.A Renamed Boric Acid Monitor Tank to Lake Release Tank.12 Table 12.2-4.3.A.4 Added Item A.4 to include 0RT-AR2412 Table 12.2-4 Note 3 Changed note to include ORT-AR2412 Table 12.2-3.3.A.4 Added section 4 to include ORT-AR2412 Table 12.2-3 Deleted surveillance 13 subsections 1-4 and added surveillance Surveillance 13 for ORT-AR2410 r 15 Table 10-2 Corrected inadvertently changed table from previous revision.

12 Table 12.2-3.3.A.2 Surveillance requirement of 0RT-AR22 changed from 14 to 12to match ORT-AR21.

App. A A.0 Added instance of I OCFR72App. A A.4 Added several instances of IOCFR72"App. A A.4.1.2)

Added *ISFSI" to clarify contained sourcesApp. A A.5.1 .1 Added requirements for Zion to comply with I OCFR72App. A A.5.1.2 Added instance of"IOCFR72" App. A A.5.2 Added instance of IOCFR72.104 and added "ISFSI" toexample of sourcesApp. A A.5.2 Added instance of I OCFR72 to compliance assessment requirements App. A A.5.3 Added ISFSI direct dose contribution in compliance methodology, provided references to ISFSI NAC dosecalculation for methodology, added reference to TSD#1 3-002for occupancy factor determinations and additional regulatory requirements of IOCFR72 as additional regulations requiring compliance.

App. A Table A-I Added IOCFR72 to Compliance matrix.App. A Table A-4 Added IOCFR72.104(a) dose limit requirements.

12 Table 12.2-4 Changed ORT-AR24 Channel function chest to QApp. A Section A.5.3 Paragraphs l&3: Changed wording referring to TSD#13-002 to: TSD 13-008 "Evaluation of Independent Spent FuelStorage Installation and Associated Process Dose Rates" andTSD 13-009 "Member of the Public Dose from All Onsitesources"12 Table 12.2-1 Added item 4.A Dilution flow instrument OFIT-SW54 12 Table 12.2-2 Item 3.A. I Changed "channel calibration to include sensor ZionSolutions LLCZS-2014-0100:

Attachment I -Supplemnental Information Chapter Section Description 12 12.2-2 Item 3.B.1 Changed "channel calibration" to include sensor12 12.2-2 Added Item 4.A OFIT-SW54 dilution flowrate instrument.

12 12.2-I Modified surveillance

1. Added Plant Manager Approvalrequired for all releases without a rad monitor.Chapter Section Description I I Table 1 I-1 .b Section b. added to include new control air sample location12 Table 12.5-I .b Section b. added to include new control air sample location11 Table 11-1.2.b Added control TLD locationI I Table I I-1.2.c & I 1- Added sections

c. and d. To include TLD's placed for ISFSI1.2.d background trending.

Added section to re-establish 5 mile ringREMP TLD's.I I Figure I I-1 Renamed to figure 1 I -Ia. and updated with new REMPmonitoring locations II Figure I1-I b. Figure added to show 5 mile ring TLD placement locations 12 Table 12.5-1 Updated table for new TLD locations.

12 Table 12.3-2.A

& Removed Sr-89 from analysis, added Ni-6312.3-2.B12 Table 12.4-1.C

& Removed Sr-89 from analysis, added Ni-6312.4- 1.D12 Table 12.4-1 Note c. Removed Sr-89 from analysis, added Ni-6312 Table 12.2-1. I .A Renamed Boric Acid Monitor Tanks (BAMT) to Lake ReleaseTanks.12 Table 12.2-1 I.A.1 Changed OR-PRO5 to OR-PRO412 Table 12.2-1.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank #I12 Table 12.2-1.3.B

& Added Item 3.B and 3.B. I Lake Release Tank #2 is monitored 12.2-1.3.B.

I for flow from new flow meter OFI-WD-006 12 Table 12.2-2. I.A & Renamed Boric Acid Monitor Tank to Lake Release Tank.12.2-2.1

.A. 112 Table 12.2-2.3.A Renamed Boric Acid Monitor Tank to Lake Release Tank # I12 12.2-2.3.b

& 12.2- Lake Release Tank #2 is monitored for flow from new flow2.3.b. I meter OFI-WD006 12 Table 12.3-2. .A Renamed Boric Acid Monitor Tank to Lake Release Tank.12 Table 12.2-4.3.A.4 Added Item A.4 to include ORT-AR2412 Table 12.2-4 Note 3 Changed note to include ORT-AR2412 Table 12.2-3.3.A.4 Added section 4 to include ORT-AR2412 Table 12.2-3 Deleted surveillance 13 subsections 1-4 and added surveillance Surveillance 13 for ORT-AR2410 r 15 Table 10-2 Corrected inadvertently changed table from previous revision.

12 Table 12.2-3.3.A.2 Surveillance requirement of ORT-AR22 changed from 14 to 12to match ORT-AR2 1.App. A A.0 Added instance of IOCFR72App. A A.4 Added several instances of"IOCFR72" App. A A.4.1.2)

Added "ISFSI" to clarify contained sourcesApp. A A.5.1.1 Added requirements for Zion to comply with IOCFR72App. A A.5.1.2 Added instance of"IOCFR72"'

ZionSolutions LLCZS-2014-01 00: Attachment I -Supplemental Information Chapter Section Description App. A A.5.2 Added instance of IOCFR72.104 and added "ISFSI" toexample of sourcesApp. A A.5.2 Added instance of 1OCFR72 to compliance assessment requirements App. A A.5.3 Added ISFSI direct dose contribution in compliance methodology, provided references to ISFSI NAC dosecalculation for methodology, added reference to TSD# 13-002for occupancy factor determinations and additional regulatory requiremnents of IOCFR72 as additional regulations requiring compliance.

App. A Table A-I Added 10CFR72 to Compliance matrix.App. A Table A-4 Added IOCFR72.104(a) dose limit requirements.

12 Table 12.2-4 Changed ORT-AR24 Channel function chest to QApp. A Section A.5.3 Paragraphs 1&3: Changed wording referring to TSD 13-002to: TSD 13-008 "Evaluation of Independent Spent.uel Storage Installation and Associated Process Dose Rates" andTSD 13-009 "Meemberof the Public Dose from All Onsitesources"12 Table 12.2-1 Added item 4.A Dilution flow instrument OFIT-SW54 12 Table 12.2-2 Item 3.A. I Changed "channel calibration to include sensor12 12.2-2 Item 3.B. 1 Changed "channel calibration" to include sensor12 12.2-2 Added Item 4.A OFIT-SW54 dilution flowrate instrument.

12 12.2-1 Modified surveillance

1. Added plant Manager Approvalrequired for all releases without a rad monitor.b. Process Control Program (PCP) ZS-WM-123 Revisions:

Section Description of change3.8 Definition of Process Control Program revised for clarity and to match Reg.guide 1.21 rev.14.2.1.7 Revised notation to references 5.10 Revised Reference Attachment 3 Bead ion exchange resin dewatering criteria wording revised.Section 2.0Attachment 3 Miscellaneous metals and irradiated hardware dewatering criteria wordingSection 3.0 revised.Section Description of change3.8 Definition of Process Control Program revised for clarity and to match Reg.guide 1.21 rev.l4.2.1.7 Revised notation to references 5.10 Revised Reference Attachment 3 Bead ion exchange resin dewatering criteria wording revised.Section 2.0Attachment 3 Miscellaneous metals and irradiated hardware dewatering criteria wordingSection 3.0 revised.

ZionSolutions, LLCZS-2014-0100:

Attachment 2- Effluent

& Waste Disposal SummaryAttachment 2.1 -Unit I Gaseous ReleasesGASEOUS EFFLUENTS

-SUMMATION OF ALL RELEASESUnit 1 Vent StackREPORT FOR 2013 Units QTR 1Fission and Activation Gases1. Total Release Ci <LLD2. Avg. Release Rate uCi/sec <LLDIodine-131

1. Total Release Ci <LLD2. Avg. Release Rate uCi/sec <LLDParticulates Half Life >= 8 days1. Total Release Ci <LLD2. Avg. Release Rate uCi/sec <LLDQTR 2 QTR 3 QTR 4 YEAR<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLDTritium1. Total Release Ci 9.35E-03.

6.5OE-032. Avg. Release Rate uCi/sec 0.D0E+00 0.00E+007.50E-03 9.10E-03 3.25E-020.OOE+00 0.00E+00 0.00E+00GASEOUS EFFLUENTS

-GROUND RELEASES

-CONTINUOUS MODEREPORT FOR 2013Fission and Activation IodinesParticulates Half LifeTritiumH-3Totals for PeriodUnits QTR 1Gases <LLD<LLD>= 8 days<LLDCi 9.35E-03Ci 9.35E-03QTR 2<LLD<LLD<LLD6.50E-036.50E-03QTR 3<LLD<LLD<LLD7. SE-037. 50E-03QTR 4<LLD<LLD<LLD9. 10E-039. lOE-03YEAR<LLD<LLD<LLD3.25E-023. 25E-02GASEOUS EFFLUENTS

-GROUND RELEASES

-BATCH MODEREPORT FOR 2013No Batch Releases.

Units QTR 1 QTR 2 QTR 3 QTR 4 YEARLLD values are listed on attachment 2.5 ZionSohittions.

LLCZS-2014-0100:

Attachment 2- Effluent

& Waste Disposal SummaryAttachment 2.2 -Unit 2 Gaseous ReleasesGASEOUS EFFLUENTS

-SUMMATION OF ALL RELEASESUnit 2 Vent StackREPORT FOR 2013Fission and Activation

1. Total ReleaseAvg. Release RateUnitsGasesCiuCi/secQTR 1 QTR 2 QTR 3 QTR 4Iodine-131

1. Total Release Ci2. Avg. Release Rate uCi/secParticulates Half Life >= 8 days1. Total Release Ci2. Avg. Release Rate uCi/secTritium1. Total Release Ci2. Avg. Release Rate uCi/sec<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLDYEAR<LLD<LLD<LLD<LLD<LLD<LLD9.35E-03 6.50E-03 7.50E-03 9.10E-03 3.25E-02).OOE+00 0.OOE-i00 0.OOE+00 0.OOE+00 0.OOE+D0GASEOUS EFFLUENTS

-GROUND RELEASES

-CONTINUOUS MODEREPORT FOR 2013Fission and Activation IodinesParticulates Half LifeUnits QTR 1Gases <LLD<LLD>= 8 days<LLDQTR 2<LLD<LLD<LLDQTR 3<LLD<LLD<LLD7.50E-037. 50E-03QTR 4<LLD<LLD<LLD9. lOE-039. IOE-03YEAR<LLD<LLD<LLD3. 25E-023.25E-02TritiumH-3 Ci 9.35E-03 6.50E-03Totals for Period Ci 9.35E-03 6.50E-03GASEOUS EFFLUENTS

-GROUND RELEASES

-BATCH MODEREPORT FOR 2013 UnitsNo Batch Releases.

QTR 1 QTR 2 QTR 3QTR 4 YEARLLD values are listed on attachment 2.5 ZionSolutions, LLCZS-2014-01 00: Attachment 2- Effluent

& Waste Disposal SummaryAttachment 2.3 -Liquid Effluent ReleasesLIQUID EFFLUENTS

-SUMMATION OF ALL RELEASESREPORT FOR 2013Fission and Activation

1. Total Release2. Avg. Release RateUnits QTR 1GasesCi <LLDuCi/sec <LLDQTR 2 QTR 3 QTR 4 YEARIodine-131

1. Total Release Ci <LLD2. Avg. Release Rate uCi/sec <LLDParticulates Half Life >= 8 days1. Total Release Ci <LLD2. Avg. Release Rate uCi/sec <LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLD<LLDVolume of liquid waste gallons 8.91E+05 9.50E+05 7.09E+05 6.27E+05 3.18E+06Volume of dil. water gallons 3.24E+08 3.28E+08 3.31E+08 3.31E+08 1.31E+09LIQUID EFFLUENTS

-BATCH MODEREPORT FOR 2013 Units QTR 1 QTR 2No batch releases.

LLD values are listed in attachment 2.5QTR 3 QTR 4 YEAR ZionSohitions, LLCZS-2014-0100:

Attachment 2- Effluent

& Waste Disposal SummaryAttachment 2.4-Direct Radiation Unit Qtr I Qtr 2 Qtr 3 Qtr 4 2013 annualdose(rnrero) cdose(mremn) dose(rnrem) dose(mrem) dose(mrern)

Unit i 2.34E+00 0.OOE+00 O.OOE+00 0.OOE+00 2.34E+00Unit 2 2.34E+00 O.OOE+00 O.OOE+00 0.OOE+00 2.34E+00ISFSI O.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 ZionSohltions, LLCZS-2014-0100:

Attachment 2- Effluent

& Waste Disposal Sumnmnary Attachment 2.5-LLD's Various detectors were used on different counting platforms for the gaseous and liquid weeklyeffluent samples.

The lower limit of detection(LLD) accompanies each counted sample and isverified to meet the following maximum LLD's:A. LiquidSample frequency Type of analysis Lower Limit of Detection (LLD) uCi/mLWeekly/prior to each release Principal Gamma Emitters:

<5.OOE-07 Dissolved and Entrained

< 1.00E-05GasesMonthly composite Tritium <I .OOE-05Gross Alpha <l.OOE-07 Quarterly composite Sr-90 5.OOE-08Fe-55, Ni-63 1.OOE-06B. GaseousSample frequency Type of analysis Lower Limit of Detection (LLD) uCi/mLContinuous/daily/weekly Principle gamma emitters

<1 .OOE-i IContinuous Noble gas < .OOE-06Monthly Noble Gas / Principle gamma <1.OOE-04 emittersTritium 1.OOE-06Quarterly composite Sr-90 <1.OOE-l IFe-55 <3.OOE- IINi-63 <I.OOE- I1Gross Alpha <1.OOE-1 I

ZionSolutions, LLCZS-2014-0100:

Attachment 2- Effluent

& Waste Disposal SummaryAttachment 2.6-Error Estimation Estimates of Total ErrorThe following is a calculated estimate of the maximum potential total error associated with reported values in the Annual Radioactive Effluent Release Report. The Total Erroris determined by calculating the square root of the sum of the squares of the individual errors.a. Gaseous Effluents Sampling ErrorCalibration ErrorCounting Statistics ErrorSsninle Vcinhrn FErrnr5%10%17%1 0%Total Error 23%b. Liquid Effluents Sampling Error 5%Calibration Error 10%Counting Statistics Error 16%Sample Volume Error 2%Total Error 20%

ZionSolutions.

LLCZS-2014-0100:

Attachment 3- Solid Waste and Irradiated Fuel Shipments A. Solid Waste Shipped Offsite for Burial or Disposal (Not irradiated fuel)1. Types of WasteTotal Total Est. TotalTypes of Waste Quantity Activity Period(m 3) (Ci) Error %a. Spent resins, filter sludges, 3.78E+02 2.26E+01 2013 2.50E+01evaporator

bottoms, etc.b. Dry compressible waste. 90'E+04 l.38E+0 2013 2.50E+0lcontaminated equip, etc.c. Irradiated components, control 4.40E+03 1.73E+03 2013 2.50E+0Irods, etc.d. Other (describe) 0.OOE+00 O.O0E+00 2013 0.OOE+00 ZionSolutions.

LLCZS-2014-0100:

Attachment 3- Solid Waste and Irradiated Fuel Shipments

2. Estimate of major nuclide composition (by waste type)Major Nuclide Waste Type a. Waste Type b. Waste Type d. Waste Type d.Composition Resins, sludges DAW Irradiated Other %bottoms (%) contaminated components

(%)equipment

(%)Ag-I 1i0m O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00Am-241 1.20E-03 5.48E-02 O.OOE+00 O.OOE+00C- 14 1.93E-02 1.47E-01 4.97E-02 O.OOE+00Ce- 144 5.20E-03 3.07E-0 I O.OOE+00 O.OOE+00Cm-242 O.OOE+00 3.OOE-04 O.OOE+00 O.OOE+00Cm-243 5.OOE-04 1.81 E-02 O.OOE+00 O.OOE+00Cm-244 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00Co-60 1.51E+O1 3.53 E+OI 5.80E+O1 O.OOE+00Cs- 134 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00Cs-137 3.42E+00 2.28E+0 I 5.30E-03 O.OOE+00Fe-55 9.28E-02 1.77E+OI 8.67E+00 O.OOE+00H-3 5.OOE-03 3.44E-01 1.20E-0I O.OOE+001-129 4.OOE-04 1.25E-02 O.OOE+00 O.OOE+00Mn-54 O.OOE+00 3.80E-02 2.80E-03 O.OOE+00Nb-94 2.40E-02 6.69E-02 1.00E-03 O.OOE+00Ni-59 1.01E+00 4.51E-0I 3.03E-01 O.OOE+00Ni-63 8.OOE+O1 2.16E+OI O.OOE+00 O.OOE+00Ni-63am O.OOE+00 O.OOE+00 3.28 E+O I O.OOE+00Np-237 O.OOE+00 O.OOE+00 O.OOE+00 O.OOE+00Pu-238 6.OOE-04 5.37E-02 O.OOE+00 O.OOE+00Pu-239 3.OOE-04 1.73E-02 O.OOE+00 O.OOE+00Pu-240 O.OOE+00 0.00E+00 O.OOE+00 O.OOE+00Pu-241 1.41E-01 1.70E-0I 2.OOE-04 O.OOE+00Pu-242 O.OOE+00 8.OOE-04 O.OOE+00 O.00E+00Ra-226 O.OOE+00 O.OOE+00 7.OOE-04 O.OOE+00Sb-125 3.68E-02 2.43E-0I 3.OOE-04 O.OOE+00Sr-89 8.90E-03 8.24E-02 O.OOE+00 O.OOE+00Sr-90 I. II E-0 I 2.09E-0 I 1.00E-04 O.OOE+00Tc-99 4.60E-03 2.03 E-01 I.OOE-04 O.OOE+00Zn-65 5.58E-02 2.01E-0I O.OOE+00 O.OOE+00 ZionSolutions, LLCZS-2014-0100:

Attachment 3- Solid Waste and Irradiated Fuel Shipments

3. Solid Waste Disposition Number of Shipments Mode of Transportation 10 Truck22 RailI TruckDestination Clive CWFClive BWFWCSIB. Irradiated Fuel Shipments (disposition)

Number of Shipments Mode of Transportation Destination 0 N/A N/AC. Changes to the Process Control Program:Changes to the PCP are included in Attachment I along with changes to the ODCM.

ZionSolttions, LLCZS-2014-0100:

Attachment 4- Radiological Impact on ManAttachment 4.1 -40CFRI90

& IOCRF72 Compliance SummaryUNIT 1, 2 & ISFSI (DOCKET Numbers 50-295, 50-304 & 72-1037)EXECUTIVE SUMMARYA review of 2013 effluent data indicates that the activity released from the station was far belowany regulatory limit. There was no noble gas released in 2013. This trend can be attributed to theshutdown of both units since late September 1997.AirborneDose to Maximally Dose to Maximally Exposed Receptor fi'om Exposed Receptor fromUnit I Unit 2Gamma Air 0.OOE+00 mrad 0.00E+00 mradBeta Air 0.OOE+00 mrad 0.OOE+00 mradTotal Body 0.OOE+00 nirem 0.00E+00 mremSkin 0.OOE+00 mrem 0.OOEE+00 mrem8.25E-05 mrem (Child 8.25E-05 mrem (ChildOrgan Liver) Liver)AquaticThere was NO Aquatic release of radioactivity from Zion Station for 2013.Dose to Maximally Dose to Maximally Exposed Receptor (Any) Exposed Receptor (Any)from Unit I from Unit 2Total Body 0 mrem 0 mremOrgan 0 mrem 0 mremDirect Radiation Dose toDose to Maximally Dose to Maximally Maximally Exposed Member of the Exposed Member of the Exposed Memberpublic from Unit I public from Unit 2 of the public fromISFSITotal Body 2.34E+00mrem 2.34E+00mrem 0.00E+00mrem ZionSolutions.

LLCZS-2014-0100:

Attachment 4- Radiological Impact on ManAttachment 4.2 -Unit II. Unit I (Docket Number 50-295)A. 10 CFR20 & 40CFRI90 Compliance Assessment:

The demonstration of compliance with 40CFR 190 will be used to demonstrate compliance with IOCFR20.1. Total Effective Dose Equivalent

2. 40 CFR 190 Whole body limit3. 40 CFR 190 Max exposed organ4. % Whole body limit5. % Max exposed organ6.2.34+00 torero/year 25 mrem/year 25 mrem (75 nirem thyroid)9.36E+00%

9.36E+00%

child liver (3.12E+00%

thyroid)Quarter IQuarter 2Quarter 31.91 E-05m remQuarter 44.63E-05mremTotalTEDE 2.34E+00 1.65E-05imll rex poe R reetrB. Maximally Exposed Receptor:

2.34E+00rnrernI. AirborneYearly limit % ofQtr Obi I" Qtr 2,,d Qtr 3" Qtr Qtr IOCFR 50 2(113 YearlyApp. 1 20p1 limitGamma air (mrad) 5.0 0.OOE+00 0.00E+00 0 (i0E+00 0.(iE+00 10.0 O.00E+00 0.00E+00Beta Air (mrad) 10.0 O.00E+00 0.00E+00 O.00E+00 0.00E+i00 20.0 O.OOE+00 O.OOE+00Total Bodv (mnrem) 7.5 2 38E-05 1.65E-05 1.91E-05 4.63E-05 15.0 8.25E-05 5.50E-06Skin imrem) 7.5 0 00E+00 0.00E+00 0.i00E+00 0.00E+00 15.0 0 0(F+00+1 0.OOE+00Organ lmrem) 7.5 2.38E-05 1.65E-05 1.91E-05 4.,3E-05 15.0 8.25E-05 5 50E-06Critical Organ Child liver Child liver Child liver Child liver Child liver Child2. AquaticYearly limit Total Dose % ofQtr Obi I" Qtr 2"' Qtr 3O Qtr 4" Qtr 10CFR 50 Y Yearl,App. I limitTotal Body (mireml 2.5 O.0(E+00 (l.0IE+0(i 0.00E+001 0.00E+00 3.0. 0.0E+00 O.OOE+0 }Organ (mi1relnl 2.5 0.OOE+00 (lOOE+00

-(i.00E+tV{}

0.00E+00 10(0 j(OE+G0 0.00E+00Critical Organ NA NA NA NA NA NA3. DirectIaly limit Total Dose % ofJtr Oi I" Qtr Qir 3' Qr 4dQtr eary 4 22013 YearlyIF limitTotal body (mremr 6.25 2.34E+ G.OOF--E+00

).OE+00 l 0.0(E+(10 25 V 2.34E+ i1 9.36E-02 ZionSolutions.

LLCZS-20 14-0100:

Attachment 4- Radiological Impact on ManAttachment 4.3 -Unit 2II. Unit 2 (Docket Number 50-304)A. 10 CFR20 & 40CFR190 Compliance Assessment:

The demonstration of compliance with 40CFRI90 will be used to demonstrate compliance with IOCFR20.1. Total Effective Dose Equivalent

2. 40 CFR 190 Whole body limit3. 40 CFR 190 Max exposed organ4. % Whole body limit5. % Max exposed organ2.34E+00 mrem/year 25 mrem/year 25 mrem (75 mrem thyroid)9.36E+00%

9.36E+00%

child liver (3.12E+00%

thyroid)Quarter ITEDE 2.34E+00mremQuarter 21.65E-05mremQuarter 31.9 iE-05m re11iQuarter 44.63E-05mremTotal2.34E+00mnremB. Maximally Exposed Receptor:

1. AirborneYearly limitQtr Obi I" Qtr 2 Qtr 3 Qtr 4h QIr I OCFR 50 Total Dose % of m early______ l 2013 limitApp. IGamma air (mrad) 5 0 0.OOE+O0 0.00E+00 0.00E+00 0.00E+00 10.0 (.00E+00 O.00E+00Beta Air (mrad) 10.(0 0.00E+00 0.00E+00 O.00El00 0.0OE+00 20.0 0.OOE+00 (i.OOE+-00 Total Body (mremn 75 2.38E-05 1.65F-05 1.91E-05 4.63E-05 150 8.25E-05 5.50E-06Skin (tmremr) 7.5 0 00E++00 .00E+/-0('

0.E .OE+-ioo 0.)O-E+10 15.0 0 00E+00 ( ()OE+0-()

Organ (mrem) 7.5 2.38E-05 1.65E-05 1.91E-05 4.63E-05 15.0 8.25E-05 5.50E-06Critical Organ Child liver Child liver Child liver Child liver ___ _ Child liver Child liver2. AquaticQtr d rYearly limit Total Dose % ofQtr Obj I" Qtr Qtr 3 Otr 4' Qtr I OCFR 50 2013 YearlyApp. I limitTotal Body (itoern) 2.5 0 OOE+00 0.00E+00 O.OO0E+ 0.00E+00 30 0 OOE+00 E O0.OOE+IO Organ Imrem) 2.5 0.OF+00Et O.O(Fi00 0.O.E+O0 010FE+00 10.0 0.OOE+00 0.00E+00Critical Orian NA NA NA NA NA NA3. Directoil "Qtr 2' tr 3 d' Qt Yearly limit Total Dose % ofQtr Ob I. 0 __2__t_3__

t 4' QtrI [40C e19l. 2013r I I lim itTlotal body, i nrem ) 1 625 2.34E+00 IO.00E+O00 O.OOE+ )O O.OOE+O0 25.C0.E00 O.OOE+00.0.E+I ZionSolutions, LLCZS-2014-0 100: Attachment 4- Radiological Impact on ManAttachment 4.4 -ISFSIIll. ISFSI (Docket Number 72-1037)A. 1OCFR72 & 40CFR190 Compliance Assessment:

1. Total Effective Dose Equivalent 0.00+00 mrem/year

2. 40 CFRI90 / IOCFR72 Whole body limit 25 morem/year

3. 40 CFRI190 / I OCFR72 Max exposed organ 25 mrem (75 nirem thyroid)4. % Whole body limit 0.OOE+00%

5. % Max exposed organ(child liver/thyroid) 0.OOE+00%

/ O.OOE+00%

Quarter I Quarter 2 Quarter 3 Quarter 4 TotalTEDE 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00m rem mrem m rem iIre m IrenmB. Maximally Exposed Receptor:

I. DirectYearly limit Total Dose % ofQtr Obj I" Qtr 2,d Qtr 3rd Qtr 4h Qtr 40CFR9/ 213 YearlyI OCFR72.104 limitTotal body (torem) 6.25 O.O0E+00 I O.OOE+O O.OOE+00 0 OOE+00 25.1) O.OOE+00 I0.0(E+O(,

ZionSolutions, LLCZS-2014-01 00: Attachment 4- Radiological Impact on ManAttachment 4.5 -Combined 40CRF 190 ReportIV. Combined 40CFR190 Report:40CFR190 URANIUM FUEL CYCLE DOSE REPORTGAS ANNUAL DOSE SUMMARYYear .....................

2013From Unit ................

1To Unit ................

2Coefficient Type ....... HistGas Receptor

............

5 CotDistance (meters)

.....Compass Point ..........

NAoricalmposite Crit. Receptor

-IP0.00=== MAXIMUM PERIOD DOSEDose AgePeriod Group OrganQuarter 1 CHILD LIVERQuarter 2 CHILD LIVERQuarter 3 CHILD LIVERQuarter 4 CHILD LIVERAnnual CHILD LIVER=== MAXIMUM PERIOD DOSEDose AgePeriod Group OrganQuarter 1 CHILD T-ODYQuarter 2 CHILD TBODYQuarter 3 CHILD TBODYQuarter 4 CHILD TBODYAnnual CHILD TBODYTO LIMIT (Any Organ)--------========

Dose Limit Admin Admin %(mrem) Period Limit of Limit4.76E-05 Quarter 5.63E+/-00 8.46E-043.30E-05 Quarter 5.63E+00 5.87E-043.82E-05 Quarter 5.63E+00 6.79E-044.63E-05 Quarter 5.63E+00 8.24E-041.65E-04 Annual 1.13E+01 1.47E-03TO LIMIT (Tot Body))-----------=------

Dose Limit Admin Admin %(mrem) Period Limit of Limit4.76E-05 Quarter 5.25E+/-00 9.O-E-043.30E-05 Quarter 5.25E+00 6.29E-043.82E-05 Quarter 5.25E+00 7.28E-044.63E-05 Quarter 5.25E+00 8.82E-041.65E-04 Annual 1.05E+0l 1.57E-03T.Spec T.Spec 0Limit of Limit7.50E+00 6.35E-047.50E+00 4.41E-047.50E+00 5.10E-047.50E+00 6.18E-041.50E+01 1.10E-03T.Spec T.Spec %Limit of Limit7.50E+00 6.35E-047.50E+00 4.41E-047.50E+00 5.10E-047.50E+00 6.18E-041.50E+01 1.10E-03 ZionSolutions, LLCZS-2014-0100:

Attachment 4- Radiological Impact on ManAttachment 4.5(continued)

-Combined 40CRF 190 Report40CFRi90 URANIUM FUEL CYCLE DOSE REPORTCOMBINED MAXIMUM ANNUAL DOSE SUMMARYYear .............

From Unit ........To Unit ..........

Liquid Receptor..

Coefficient Type.Gas Receptor

.....Distance (meters)Compass Point ....2013..Historical

...... 5 Composite Crit. Receptor0.00..NAIPMAXIMUM PERIOD DOSEDose AgePeriod Group OrganQuarter 1 CHILD LIVERQuarter 2 CHILD LIVERQuarter 3 CHILD LIVERQuarter 4 CHILD LIVERAnnual CHILD LIVER=== MAXIMUM PERIOD DOSEDose AgePeriod Group OrganQuarter 1 CHILD T-ODYQuarter 2 CHILD TBODYQuarter 3 CHILD TBODYQuarter 4 CHILD TBODYAnnual CHILD TBODYTO LIMITDose(ntrem)4. 76E-Q3. 30E-03.82E-04.63E-01.65E-0TO LIMITDose(mrem)4. 76E-03.30E-03. 82E-04.63E-01. 65E-0(Any Organ)Limit AdminPeriod Limit5 Quarter 5.63E+005 Quarter 5.63E+005 Quarter 5.63E+005 Quarter 5.63E+004 Annual 1.13E+01(Tot Body) )Limit AdminPeriod Limit5 Quarter 5.25E+005 Quarter 5.25E+005 Quarter 5.25E+005 Quarter 5.25E+004 Annual 1.05E+01Admin %of Limit8.46E-045. 87E-046.79E-048.24E-041.47E-03Admin %of Limit9. 06E-046.29E-047.28E-048.82E-041. 57E-03T. SpecLimit7.50E+007. 50E+007. 50E+007. 50E+001.50E+01T. SpecLimit7. 50E+007. 50E+007. 50E+007. 50E+001.50E+01T.Specof Limit6. 35E-044.41E-045. l0E-046. 18E-041. lOE-03T.Spec %of Limit6. 35E-044 .41E-045. l0E-046. 18E-041. l0E-03